CN110144611B - A kind of magnesium alloy surface corrosion-resistant and wear-resistant composite coating and preparation method thereof - Google Patents
A kind of magnesium alloy surface corrosion-resistant and wear-resistant composite coating and preparation method thereof Download PDFInfo
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- CN110144611B CN110144611B CN201910496770.2A CN201910496770A CN110144611B CN 110144611 B CN110144611 B CN 110144611B CN 201910496770 A CN201910496770 A CN 201910496770A CN 110144611 B CN110144611 B CN 110144611B
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- 238000000576 coating method Methods 0.000 title claims abstract description 136
- 229910000861 Mg alloy Inorganic materials 0.000 title claims abstract description 134
- 239000011248 coating agent Substances 0.000 title claims abstract description 130
- 239000002131 composite material Substances 0.000 title claims abstract description 43
- 230000007797 corrosion Effects 0.000 title claims abstract description 32
- 238000005260 corrosion Methods 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 134
- 229910052742 iron Inorganic materials 0.000 claims abstract description 66
- 229920000767 polyaniline Polymers 0.000 claims abstract description 66
- 238000004070 electrodeposition Methods 0.000 claims abstract description 29
- 238000001755 magnetron sputter deposition Methods 0.000 claims abstract description 22
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 19
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 18
- 238000005498 polishing Methods 0.000 claims description 18
- ABBQHOQBGMUPJH-UHFFFAOYSA-M Sodium salicylate Chemical compound [Na+].OC1=CC=CC=C1C([O-])=O ABBQHOQBGMUPJH-UHFFFAOYSA-M 0.000 claims description 16
- 229960004025 sodium salicylate Drugs 0.000 claims description 16
- 238000004544 sputter deposition Methods 0.000 claims description 15
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 12
- 229910052786 argon Inorganic materials 0.000 claims description 9
- 239000003792 electrolyte Substances 0.000 claims description 9
- 125000004122 cyclic group Chemical group 0.000 claims description 7
- 238000002484 cyclic voltammetry Methods 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 6
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 claims description 6
- 229910052697 platinum Inorganic materials 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 244000137852 Petrea volubilis Species 0.000 claims description 5
- 238000000861 blow drying Methods 0.000 claims description 3
- 238000007747 plating Methods 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 230000004580 weight loss Effects 0.000 abstract description 12
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract description 10
- 238000002791 soaking Methods 0.000 abstract description 5
- 239000011780 sodium chloride Substances 0.000 abstract description 5
- 230000003247 decreasing effect Effects 0.000 abstract description 4
- 230000002195 synergetic effect Effects 0.000 abstract description 4
- 238000012986 modification Methods 0.000 description 19
- 230000004048 modification Effects 0.000 description 19
- 238000005299 abrasion Methods 0.000 description 9
- 238000000227 grinding Methods 0.000 description 6
- 230000001276 controlling effect Effects 0.000 description 5
- 230000007547 defect Effects 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 3
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- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
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- 229910003460 diamond Inorganic materials 0.000 description 1
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- 238000004090 dissolution Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
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- 238000002474 experimental method Methods 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003562 lightweight material Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/20—Metallic material, boron or silicon on organic substrates
- C23C14/205—Metallic material, boron or silicon on organic substrates by cathodic sputtering
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
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- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
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- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D9/00—Electrolytic coating other than with metals
- C25D9/02—Electrolytic coating other than with metals with organic materials
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Abstract
本发明为一种镁合金表面耐蚀耐磨复合涂层及其制备方法。该复合涂层由电化学沉积与磁控溅射复合镀膜方法制备，由内而外依次为聚苯胺涂层和铁涂层，铁涂层厚度为40～90μm，聚苯胺涂层厚度为60～120μm。所述镁合金为商业化AZ系、ZK系和WE系镁合金板材。本发明得到的复合涂层通过铁和聚苯胺的协同效应，可在保证导电性的基础上，同时提高镁合金表面的耐腐蚀性能和耐磨性，该复合涂层使镁合金在3.5％NaCl溶液中浸泡10天后的失重量下降15.1％～34.1％；此外，表面磨损量下降8.7％～62.3％。
The invention relates to a corrosion-resistant and wear-resistant composite coating on the surface of a magnesium alloy and a preparation method thereof. The composite coating is prepared by electrochemical deposition and magnetron sputtering composite coating method. From the inside to the outside, it is a polyaniline coating and an iron coating. The thickness of the iron coating is 40-90 μm, and the thickness of the polyaniline coating is 60- 120μm. The magnesium alloys are commercial AZ series, ZK series and WE series magnesium alloy sheets. The composite coating obtained by the invention can improve the corrosion resistance and wear resistance of the surface of the magnesium alloy on the basis of ensuring electrical conductivity through the synergistic effect of iron and polyaniline. The composite coating makes the magnesium alloy in 3.5% NaCl After soaking in the solution for 10 days, the weight loss decreased by 15.1% to 34.1%; in addition, the surface wear amount decreased by 8.7% to 62.3%.
Description
Technical Field
The invention belongs to the field of magnesium alloy surface modification, and particularly relates to a composite coating method of electrochemical deposition and magnetron sputtering.
Background
Under the background that the current human living environment is increasingly worsened and the energy storage capacity is totally insufficient, the energy conservation and emission reduction of the automobile are particularly urgent, the oil consumption can be effectively reduced and the emission can be reduced on the premise that the strength and the safety performance of the whole automobile are guaranteed by the light weight of the automobile, and the method is an important technical means for the sustainable development of the automobile industry. The magnesium alloy as a typical light-weight material for automobiles has the advantages of small density, high specific strength and specific modulus, good shock absorption, convenient cutting processing and easy recovery, and can be used for manufacturing engine cylinder blocks and transmission shellsParts such as body, steering wheel, door, wheel hub, etc. However, there are two major problems faced in the practical use of magnesium alloys. (1) The corrosion resistance is poor: the MgO oxide layer formed on the surface of the magnesium alloy is loose and porous and is easy to be converted into Mg (OH) in a humid environment2Hydroxide layer of in the presence of Cl-Form MgCl with high solubility2Chloride, the mechanical strength of which is reduced due to the continuous expansion of pitting corrosion, even the cracking is caused; (2) poor surface abrasion resistance: the magnesium alloy has small surface hardness and low strength, and is easy to wear under the action of complex variable loads, so that the mechanical property of a matrix is reduced.
The surface modification technology can effectively improve the comprehensive performance of the surface of the magnesium alloy by preparing the functional coating with a specific tissue structure, so that the magnesium alloy meets the harsh requirements in practical application. Common magnesium alloy surface modification technologies comprise surface oxidation, high-energy beam modification, coating and the like, wherein an electrochemical deposition method is high in coating efficiency, low in equipment cost and small in environmental pollution; the magnetron sputtering method has the advantages of uniform and compact film layer, less internal defects, controllable process parameters and good repeatability. The two methods are matched for use, so that the technological advantages of chemical coating and physical coating can be fully exerted, and the high-performance coating with excellent comprehensive performance is prepared on the surface of the magnesium alloy.
Research shows that the degradable metallic iron has high mechanical strength and low degradation rate, the corrosion rate of the degradable metallic iron can be regulated and controlled by modifying the magnesium alloy on the surface of the iron coating, and the mechanical property of the surface of the degradable metallic iron is improved; however, direct contact between iron and magnesium alloy is liable to cause galvanic corrosion, and the more active magnesium alloy is used as an anode to accelerate dissolution. The conductive polyaniline is a novel functional polymer, can make up for the defects of most high polymer electrical insulation, has the advantages of good corrosion resistance and simple and convenient synthesis, and can improve the corrosion resistance and the electrical property of the magnesium alloy simultaneously by using the polyaniline coating surface to modify; however, polyaniline has low mechanical strength and is easy to wear and lose efficacy. Therefore, the iron/polyaniline composite coating with a double-layer structure can be prepared on the surface of the magnesium alloy by a composite coating method of electrochemical deposition and magnetron sputtering, the coating has the advantages of conductivity, corrosion resistance and high hardness, the outer iron coating provides mechanical strength, and the inner polyaniline coating can prevent direct contact between iron and the magnesium alloy to avoid galvanic corrosion.
Disclosure of Invention
The invention provides a corrosion-resistant wear-resistant composite coating and a preparation method thereof, aiming at the problems of poor corrosion resistance and insufficient surface wear resistance of magnesium alloy. The composite coating is of a double-layer structure and sequentially comprises a polyaniline coating and an iron coating from inside to outside, the outer iron coating provides mechanical strength, and the inner polyaniline coating can prevent iron from directly contacting with magnesium alloy so as to avoid galvanic corrosion. The composite coating can improve the corrosion resistance and the wear resistance of the surface of the magnesium alloy on the basis of ensuring the conductivity through the synergistic effect of iron and polyaniline.
The technical scheme of the invention is as follows:
the composite coating is of a double-layer structure and sequentially comprises a polyaniline coating and an iron coating from inside to outside, wherein the thickness of the iron coating is 40-90 mu m, and the thickness of the polyaniline coating is 60-120 mu m.
The preparation method of the corrosion-resistant wear-resistant composite coating on the surface of the magnesium alloy comprises the following steps:
the first step is as follows: mechanical polishing of magnesium alloy original surface
Sanding the original surface of the magnesium alloy with sand paper, mechanically polishing with an alumina polishing powder, then ultrasonically cleaning in absolute ethyl alcohol, and blow-drying to obtain a polished surface of the magnesium alloy;
the magnesium alloy is a commercial AZ series, ZK series and WE series magnesium alloy plate;
the second step is that: preparation of polyaniline coating on magnesium alloy surface by electrochemical deposition
Performing electrochemical deposition on the polished surface of the magnesium alloy by using a cyclic voltammetry method, selecting a three-electrode system, selecting a working electrode as the magnesium alloy, a counter electrode as a platinum sheet, a reference electrode as a saturated calomel electrode, performing electrochemical deposition at the temperature of 20-30 ℃, wherein an electrolyte is a sodium salicylate solution containing 0.01-0.2M of aniline, the cyclic potential interval is-0.4-1.5V, the scanning rate is 35-85 mV/s, and the cycle number is 10-20, so as to obtain the magnesium alloy with the polyaniline coating on the surface;
the concentration of the sodium salicylate solution is 0.1-0.2M, and the thickness of the polyaniline coating is 60-120 mu M;
preferably, 0.05-0.15M aniline is added into 0.1M sodium salicylate solution to prepare electrolyte, the circulating potential interval is-0.1-1.2V, the scanning speed is 45-75 mV/s, and the circulating frequency is 12-16;
the third step: preparation of iron coating on magnesium alloy surface by magnetron sputtering
Putting the magnesium alloy with the polyaniline coating on the surface obtained in the second step into a cavity of a magnetron sputtering coating machine, selecting high-purity iron as a cathode target source, and controlling the vacuum degree to be 5.0 multiplied by 10-4Starting arc starting sputtering when Pa is reached, wherein the pressure of argon is 0.2-1.0 Pa, the sputtering power is 150-300W, and the coating time is 2-4 h, so that the magnesium alloy with the iron/polyaniline composite coating on the surface is obtained;
the purity of the high-purity iron is 99.9%, and the thickness of the iron coating is 40-90 mu m;
preferably, the argon pressure is 0.4-0.8 Pa, the sputtering power is 180-260W, and the coating time is 2.5-3.5 h.
The surface modification method can prepare the iron/polyaniline composite coating with a double-layer structure on the surface of the magnesium alloy, and the coating has the advantages of conductivity, corrosion resistance and wear resistance and can improve the comprehensive performance of the surface of the magnesium alloy. The electrochemical deposition method has the advantages of high coating efficiency, low equipment cost and small environmental pollution; the magnetron sputtering method has the advantages of uniform and compact film layer, less internal defects, controllable process parameters and good repeatability. Through the optimized combination of the electrochemical deposition and the magnetron sputtering process parameters, the high-quality iron/polyaniline composite coating can be prepared, and meanwhile, the electrical property and the corrosion resistance of the surface of the magnesium alloy are improved, so that the magnesium alloy meets the complex and various use requirements.
The invention organically combines the electrochemical deposition and the magnetron sputtering to form the composite coating method, which has the advantages that:
(1) the inventor obtains the optimal process parameters of electrochemical deposition and magnetron sputtering through a large number of experiments: for electrochemical deposition, a cyclic voltammetry method and a three-electrode system are selected, 0.05-0.15M aniline is added into 0.1M sodium salicylate solution to prepare electrolyte, the cyclic potential range is-0.1-1.2V, the scanning rate is 45-75 mV/s, and the cycle number is 12-16; for magnetron sputtering, the argon pressure is 0.4-0.8 Pa, the sputtering power is 180-260W, and the coating time is 2.5-3.5 h. Within the process parameter range, the iron/polyaniline composite coating which is uniform, compact, high in bonding strength and has a double-layer structure can be prepared.
(2) The polyaniline coating prepared by the electrochemical deposition method can provide excellent corrosion resistance and good conductivity for the magnesium alloy, and the iron coating prepared by the magnetron sputtering method can improve the mechanical property of the surface of the magnesium alloy. The inner polyaniline coating can prevent the outer iron coating from directly contacting with the magnesium alloy to avoid galvanic corrosion, and the outer iron coating can make up for the defect of poor wear resistance of the inner polyaniline coating. The synergistic effect of iron and polyaniline can improve the corrosion resistance and the surface wear resistance of the magnesium alloy on the basis of ensuring the conductivity of the magnesium alloy. The weight loss of the magnesium alloy after surface modification is reduced by 15.1-34.1% after the magnesium alloy is soaked in 3.5% NaCl solution for 10 days; in addition, the surface abrasion loss is reduced by 8.7 to 62.3 percent.
Drawings
FIG. 1: the microscopic morphology of the iron/polyaniline composite coating on the surface of the magnesium alloy in example 1.
FIG. 2: comparative curves of corrosion properties of magnesium alloys before and after surface modification in example 1.
FIG. 3: a comparison graph of the surface wear topography of the magnesium alloy before and after surface modification in example 1; wherein, fig. 3a is a surface wear topography of the magnesium alloy before surface modification, and fig. 3b is a surface wear topography of the magnesium alloy after surface modification.
Detailed Description
The present invention will be described in further detail with reference to the accompanying drawings and examples.
The invention relates to a magnesium alloy surface modification method based on an electrochemical deposition and magnetron sputtering composite coating method, which comprises the following steps:
the first step is as follows: mechanical polishing of magnesium alloy original surface
Pretreating the original surface of the magnesium alloy, grinding the magnesium alloy on 500#, 1000#, 1500# and 2000# waterproof abrasive paper respectively to remove surface oxide skin and impurities, then mechanically polishing the ground surface by using 0.3 mu m aluminum oxide polishing powder until surface scratches are removed, finally ultrasonically cleaning the magnesium alloy in absolute ethyl alcohol for 15min, and drying the magnesium alloy by cold air to obtain the polished surface of the magnesium alloy.
The second step is that: preparation of polyaniline coating on magnesium alloy surface by electrochemical deposition
Performing electrochemical deposition on the polished surface of the magnesium alloy by using a cyclic voltammetry method, selecting a three-electrode system, selecting a working electrode as the magnesium alloy, a counter electrode as a platinum sheet, a reference electrode as a saturated calomel electrode, adding a proper amount of aniline into a 0.1M sodium salicylate solution at the electrochemical deposition temperature of 25 ℃, preparing the sodium salicylate solution with the aniline concentration of 0.01-0.2M, using the sodium salicylate solution as an electrolyte, preferably 0.05-0.15M aniline, wherein the cyclic potential range is-0.4-1.5V, preferably-0.1-1.2V, the scanning speed is 35-85 mV/s, preferably 45-75 mV/s, the cycle frequency is 10-20, preferably 12-16, and obtaining the magnesium alloy with the polyaniline coating on the surface.
The third step: preparation of iron coating on magnesium alloy surface by magnetron sputtering
Putting the magnesium alloy with the polyaniline coating on the surface obtained in the second step into a cavity of a magnetron sputtering coating machine, selecting 99.9 percent of high-purity iron as a cathode target source, and controlling the vacuum degree to be 5.0 multiplied by 10-4And starting arc starting sputtering when Pa is reached, wherein the pressure of argon gas is 0.2-1.0 Pa, preferably 0.4-0.8 Pa, the sputtering power is 150-300W, preferably 180-260W, and the coating time is 2-4 h, preferably 2.5-3.5 h, so that the magnesium alloy with the iron/polyaniline composite coating on the surface is obtained.
The microstructure analysis of the iron/polyaniline composite coating on the surface of the magnesium alloy prepared by the surface modification method disclosed by the invention shows that the composite coating has a double-layer structure, the outer layer is an iron coating, the inner layer is a polyaniline coating, the coating is perfectly combined with the magnesium alloy matrix and the coatings, the coating is uniform and compact, and no obvious defect exists in the coating.
The details are described below with reference to specific embodiments.
Example 1:
the first step is as follows: mechanical polishing of magnesium alloy original surface
Pretreating the original surface of the AZ91 magnesium alloy, grinding the surface on 500#, 1000#, 1500# and 2000# water sand paper respectively to remove surface oxide skin and impurities, then mechanically polishing the ground surface by using 0.3 mu m aluminum oxide polishing powder until surface scratches are removed, finally ultrasonically cleaning the surface in absolute ethyl alcohol for 15min, and drying the surface by cold air to obtain the AZ91 magnesium alloy polished surface.
The second step is that: preparation of polyaniline coating on magnesium alloy surface by electrochemical deposition
Performing electrochemical deposition on the polished surface of the AZ91 magnesium alloy by using a cyclic voltammetry method, selecting a three-electrode system, adding a proper amount of aniline into a 0.1M sodium salicylate solution at the electrochemical deposition temperature of 25 ℃ by using a working electrode which is a magnesium alloy with the surface area of 10mm multiplied by 10mm, a counter electrode which is a platinum sheet with the surface area of 10mm multiplied by 10mm and a reference electrode which is a saturated calomel electrode, preparing the sodium salicylate solution with the aniline concentration of 0.05M as an electrolyte, wherein the cyclic potential interval is-0.1-1.2V, the scanning rate is 45mV/s, and the cycle number is 12, thus obtaining the AZ91 magnesium alloy with the polyaniline coating on the surface.
The third step: preparation of iron coating on magnesium alloy surface by magnetron sputtering
Placing the AZ91 magnesium alloy with polyaniline coating on the surface obtained in the second step into a cavity of a magnetron sputtering coating machine, selecting 99.9% high-purity iron as a cathode target source, and controlling the vacuum degree to be 5.0 multiplied by 10-4Starting arc striking and sputtering when Pa is reached, wherein the argon pressure is 0.4Pa, the sputtering power is 180W, and the film plating time is 2.5h, so that the AZ91 magnesium alloy with the iron/polyaniline composite coating on the surface is obtained.
The sample prepared in example 1 was subjected to structural analysis and performance testing:
(1) microscopic morphology of iron/polyaniline composite coating on surface of AZ91 magnesium alloy
And observing the microscopic morphology of the iron/polyaniline composite coating by adopting a scanning electron microscope. As shown in the attached figure 1, the iron/polyaniline composite coating obtained in example 1 has a double-layer structure, the outer layer is an iron coating with the thickness of about 40 microns, the inner layer is a polyaniline coating with the thickness of about 60 microns, the coating is uniform and compact, and the coating is well combined with an AZ91 magnesium alloy matrix.
(2) Comparison of corrosion properties of AZ91 magnesium alloys before and after surface modification
A soaking test is adopted to analyze the corrosion performance change of the AZ91 magnesium alloy before and after surface modification, the surface area of a sample to be tested is 10mm multiplied by 10mm, the other surfaces are sealed by chloroprene rubber, the testing temperature is 25 ℃, the sample is immersed in 3.5 percent NaCl solution for 10 days, then the sample is taken out and the surface corrosion product is cleaned, and the weight loss is weighed after drying. As can be seen from the attached figure 2, the weight loss of the AZ91 magnesium alloy before and after surface modification in example 1 is increased along with the increase of the soaking time, the change rate of the weight loss is gradually reduced, and the weight loss at the end of soaking reaches a relatively stable state. The final weight loss of the AZ91 magnesium alloy in the 10-day soaking period before and after surface modification is 45.1 +/-1.7 mg/cm2And 32.9. + -. 1.9mg/cm2The iron/polyaniline composite coating reduces the weight loss of the AZ91 magnesium alloy by 27.1 percent and improves the corrosion resistance.
(3) Comparison of surface wear morphology of AZ91 magnesium alloy before and after surface modification
And analyzing the wear resistance change of the AZ91 magnesium alloy before and after surface modification by adopting a scratch test, pressing a diamond pressure head in a rhombohedral cone shape to a certain depth along the normal direction of the surface of the sample, continuously increasing the load from 0 to 10N, simultaneously translating the pressure head on the surface of the sample along the direction vertical to the axial direction, observing the wear morphology by adopting a scanning electron microscope, and measuring the wear loss by using a white light interferometer. As can be seen from FIG. 3, in example 1, the surface of AZ91 magnesium alloy before surface modification had deep grinding marks, wide size, rough shape, and wear loss of (2.42. + -. 0.09). times.106μm3(ii) a After surface modification, AZ91 magnesium alloy has slight grinding scar, narrow size, smooth appearance and abrasion loss of (2.21 +/-0.08) multiplied by 106μm3(ii) a The iron/polyaniline composite coating reduces the abrasion loss of AZ91 magnesium alloy by 8.7%, and improves the surface abrasion resistance.
Example 2:
the first step is as follows: mechanical polishing of magnesium alloy original surface
Pretreating the original surface of the ZK61 magnesium alloy, grinding the original surface on 500#, 1000#, 1500# and 2000# water sand paper respectively to remove surface oxide skin and impurities, then mechanically polishing the ground surface by using 0.3 mu m aluminum oxide polishing powder until surface scratches are removed, finally ultrasonically cleaning the surface in absolute ethyl alcohol for 15min, and drying the surface by cold air to obtain the ZK61 magnesium alloy polished surface.
The second step is that: preparation of polyaniline coating on magnesium alloy surface by electrochemical deposition
Performing electrochemical deposition on the polished surface of the ZK61 magnesium alloy by using cyclic voltammetry, selecting a three-electrode system, adding a proper amount of aniline into a 0.1M sodium salicylate solution at the electrochemical deposition temperature of 25 ℃ by using a working electrode which is a magnesium alloy with the surface area of 10mm multiplied by 10mm, a counter electrode which is a platinum sheet with the surface area of 10mm multiplied by 10mm and a reference electrode which is a saturated calomel electrode, preparing the sodium salicylate solution with the aniline concentration of 0.10M as an electrolyte, wherein the cyclic potential interval is-0.1-1.2V, the scanning rate is 60mV/s, and the cycle number is 14, so as to obtain the ZK61 magnesium alloy with the polyaniline coating on the surface.
The third step: preparation of iron coating on magnesium alloy surface by magnetron sputtering
Putting the ZK61 magnesium alloy with polyaniline coating on the surface obtained in the second step into a cavity of a magnetron sputtering film plating machine, selecting 99.9 percent high-purity iron as a cathode target source, and controlling the vacuum degree to be 5.0 multiplied by 10-4Starting arc striking and sputtering when Pa is reached, wherein the argon pressure is 0.6Pa, the sputtering power is 220W, and the coating time is 3.0h, so that the ZK61 magnesium alloy with the iron/polyaniline composite coating on the surface is obtained.
Through structural analysis and performance detection, the thickness of the outer iron coating in the iron/polyaniline composite coating obtained in example 2 is about 60 micrometers, and the thickness of the inner polyaniline coating is about 80 micrometers; the weight loss of the ZK61 magnesium alloy after being soaked in 3.5 percent NaCl solution for 10 days before and after surface modification is respectively 32.4 +/-1.2 mg/cm2And 27.5. + -. 1.4mg/cm2The weight loss is reduced by 15.1%; in addition, the iron/polyaniline composite coating ensures that the surface abrasion loss of the ZK61 magnesium alloy is from (3.41 +/-0.19) multiplied by 106μm3Down to (1.96 +/-0.12) x 106μm3The abrasion loss decreased by 42.5%.
Example 3:
the first step is as follows: mechanical polishing of magnesium alloy original surface
Pretreating the original surface of WE54 magnesium alloy, grinding on 500#, 1000#, 1500# and 2000# water sand paper respectively to remove surface oxide skin and impurities, then mechanically polishing the ground surface by using 0.3 mu m aluminum oxide polishing powder until surface scratches are removed, finally ultrasonically cleaning in absolute ethyl alcohol for 15min, and blow-drying by cold air to obtain the WE54 magnesium alloy polished surface.
The second step is that: preparation of polyaniline coating on magnesium alloy surface by electrochemical deposition
Performing electrochemical deposition on the WE54 magnesium alloy polished surface by using cyclic voltammetry, selecting a three-electrode system, wherein a working electrode is a magnesium alloy with the surface area of 10mm multiplied by 10mm, a counter electrode is a platinum sheet with the surface area of 10mm multiplied by 10mm, a reference electrode is a saturated calomel electrode, the electrochemical deposition temperature is 25 ℃, adding a proper amount of aniline into 0.1M sodium salicylate solution, preparing the sodium salicylate solution with the aniline concentration of 0.15M as electrolyte, and obtaining the WE54 magnesium alloy with a polyaniline coating on the surface, wherein the cyclic potential range is-0.1-1.2V, the scanning rate is 75mV/s, and the cycle number is 16.
The third step: preparation of iron coating on magnesium alloy surface by magnetron sputtering
Placing the WE54 magnesium alloy with polyaniline coating on the surface obtained in the second step into a cavity of a magnetron sputtering coating machine, selecting 99.9% high-purity iron as a cathode target source, and controlling the vacuum degree to be 5.0 multiplied by 10-4And starting arc striking and sputtering when the pressure is Pa, wherein the pressure of argon is 0.8Pa, the sputtering power is 260W, and the coating time is 3.5h, so that the WE54 magnesium alloy with the iron/polyaniline composite coating on the surface is obtained.
Through structural analysis and performance detection, the thickness of the outer iron coating in the iron/polyaniline composite coating obtained in example 3 is about 90 μm, and the thickness of the inner polyaniline coating is about 120 μm; the weight loss of WE54 magnesium alloy after being soaked in 3.5% NaCl solution for 10 days before and after surface modification is 26.1 +/-0.6 mg/cm2And 17.2. + -. 1.1mg/cm2The weight loss is reduced by 34.1 percent; in addition, the WE54 magnesium alloy surface abrasion quantity is from (2.76 +/-0.09) × 10 by the iron/polyaniline composite coating6μm3Down to (1.04. + -. 0.09) × 106μm3The abrasion loss decreased by 62.3%.
The magnesium alloy with the iron/polyaniline composite coating on the surface prepared by the method has the advantages of conductivity, corrosion resistance and wear resistance, the outer iron coating provides mechanical strength, the inner polyaniline coating can prevent direct contact between iron and the magnesium alloy to avoid galvanic corrosion, and the synergistic effect of the iron coating and the polyaniline coating can improve the comprehensive performance of the surface of the magnesium alloy.
The above description is only for the preferred embodiment of the present invention and is not intended to limit the scope of the present invention, and all equivalent structural changes made by using the contents of the present specification and the drawings, or any other related technical fields, are included in the scope of the present invention.
The invention is not the best known technology.
Claims (2)
1. The corrosion-resistant and wear-resistant composite coating on the surface of the magnesium alloy is characterized in that the composite coating is of a double-layer structure and sequentially comprises a polyaniline coating and an iron coating from inside to outside, the thickness of the iron coating is 40-90 mu m, and the thickness of the polyaniline coating is 60-120 mu m;
the preparation method of the corrosion-resistant wear-resistant composite coating on the surface of the magnesium alloy comprises the following steps:
the first step is as follows: mechanical polishing of magnesium alloy original surface
Sanding the original surface of the magnesium alloy with sand paper, mechanically polishing with an alumina polishing powder, then ultrasonically cleaning in absolute ethyl alcohol, and blow-drying to obtain a polished surface of the magnesium alloy;
the second step is that: preparation of polyaniline coating on magnesium alloy surface by electrochemical deposition
Performing electrochemical deposition on the polished surface of the magnesium alloy by using a cyclic voltammetry method, selecting a three-electrode system, selecting a working electrode as the magnesium alloy, a counter electrode as a platinum sheet, a reference electrode as a saturated calomel electrode, performing electrochemical deposition at the temperature of 20-30 ℃, wherein an electrolyte is a sodium salicylate solution containing 0.01-0.2M of aniline, the cyclic potential interval is-0.4-1.5V, the scanning rate is 35-85 mV/s, and the cycle number is 10-20, so as to obtain the magnesium alloy with the polyaniline coating on the surface;
the concentration of the sodium salicylate solution is 0.1-0.2M, and the thickness of the polyaniline coating is 60-120 mu M;
the third step: preparation of iron coating on magnesium alloy surface by magnetron sputtering
Putting the magnesium alloy with the polyaniline coating on the surface obtained in the second step into magnetron sputteringIn the cavity of film-plating machine, high-purity iron is selected as cathode target source, and its vacuum degree is 5.0X 10-4Starting arc starting sputtering when Pa is reached, wherein the pressure of argon is 0.2-1.0 Pa, the sputtering power is 150-300W, and the coating time is 2-4 h, so that the magnesium alloy with the iron/polyaniline composite coating on the surface is obtained;
the thickness of the iron coating is 40-90 mu m;
in the preparation method, in the second step, 0.05-0.15M aniline is added into 0.1M sodium salicylate solution to prepare electrolyte, the circulating potential interval is-0.1-1.2V, the scanning rate is 45-75 mV/s, and the circulating frequency is 12-16;
in the third step, the argon pressure is 0.4-0.8 Pa, the sputtering power is 180-260W, and the coating time is 2.5-3.5 h;
the magnesium alloy is a commercial AZ series, ZK series and WE series magnesium alloy plate.
2. The magnesium alloy surface corrosion-resistant wear-resistant composite coating according to claim 1, wherein in the preparation method, the purity of the high-purity iron is 99.9%.
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