CN109824383A - A kind of copper red matt furnace transmutation glaze and preparation method thereof - Google Patents
A kind of copper red matt furnace transmutation glaze and preparation method thereof Download PDFInfo
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Abstract
The present invention relates to the present invention relates to ceramic glaze technical fields, and in particular to a kind of copper red matt furnace transmutation glaze and preparation method thereof.For the copper red matt furnace transmutation glaze by ground coat enamel and overglaze group, ground coat enamel includes purification potassium feldspar, animal bone ash, purification quartz, lime, talcum, purification cordierite, carbonic acid silicon, copper oxide, tin oxide, zinc oxide, aluminium oxide, barium carbonate and boron；Overglaze includes purification potassium feldspar, purification quartz, talcum, basic zirconium phosphate, titanium oxide, tin oxide, frit, purification dolomite, zinc oxide and copper oxide.Preparation method includes: to prepare ground coat enamel glaze slip；Prepare overglaze glaze slip；Prepare ground coat enamel；Prepare overglaze.The present invention solves the problems, such as that furnace transmutation glaze manufacture difficulty is high in the prior art and transmutation effect is poor, and the furnace transmutation glaze function admirable being prepared, thermal stability, water absorption rate and the lead of product, the amount of dissolution of cadmium can meet the relevant criterion of domestic ceramic product.
Description
Technical field
The present invention relates to ceramic glaze technical fields, and in particular to a kind of copper red matt furnace transmutation glaze and preparation method thereof.
Background technique
Porcelain is fired by porcelain stone, kaolin, quartz, mullite etc., and outer top application has nature of glass glaze or colored drawing
Sundries.The molding of porcelain will by passing through (about 1280 DEG C -1400 DEG C) of high temperature firings in kiln, the glaze colours on porcelain surface can because
The difference of temperature and various chemical changes occur.The porcelain tire of sintering generally contain only 3% less than ferro element, and it is waterproof, because of it
The common people of more cheap cost and wear-resisting fluid-tight characteristic widely all over the world are used.
Burning makes porcelain, all to it is found not to be expected shape or glaze colours after opening kiln, so that spy occurs sometimes for porcelain handed down from ancient times
Different situation person can say it is " transmutation "." unofficial history compilation " is said: " it is both a matter that porcelain, which has, then Cheng Yizhi, is both of the same colour, Cheng Yi then
Color person, water and soil are closed, and impersonal force can ingeniously add, the meaning transmutation for being." to sum up, transmutation be broadly divided into deformation, discoloration,
It is rotten etc. several.Furnace transmutation glaze is that implements unexpected glaze colours effect occur in sintering process.There are many containing in kiln
Pigmentation element may show unexpected glaze colours effect through oxidation or reduction, porcelain after kiln discharge.Because furnace transmutation glaze shows
In accidental, form is special, and people do not know its principle again, only knows and changes in roasting process in kiln and obtain, therefore referred to as " furnace transmutation glaze ",
Common saying has " transmutation is unparalleled ", just refers to changing unpredictably for furnace transmutation glaze, unique.Furnace transmutation glaze is innovated when being Yongzheng towards imitative an ancient unit of weight kiln
Kind is preferred with harmony, Gan Erchao product, and glaze colours is based on red, and blending, it is sky blue, bluish white, green, brown etc. variegated to trickle, like fire
It is rich in variety as flame, wherein partially red title " flame is red ", partially blue title " flame is green ".
As people go deep into furnace transmutation glaze understanding, the beauty of defect of transmutation also gradually obtains liking for people, and kiln fire is to glaze
Defect caused by face is seen and allows people to enjoy endless aftertastes instead long afterwards.In multicoloured coloured glaze, furnace transmutation glaze porcelain seems very solely
It is special and marvellous.
Usual Bristol glaze, which becomes, is divided into two kinds according to glazing process.It applies one is single glaze and is burnt on green body, due to glaze
The variation such as disturbance of attribute and firing atmosphere of itself, to generate splendid colorful glaze.Another kind is exactly that ground coat enamel adds overglaze,
Even a variety of overglazes, which overlap, is burnt into and generates the effect got along swimmingly with each other.If coming by the coloring metal oxide of furnace transmutation glaze
Point, then it is broadly divided into copper system furnace transmutation glaze and iron series furnace transmutation glaze two major classes.It is generally acknowledged that copper system furnace transmutation glaze is fired under reducing atmosphere,
And iron series column furnace transmutation glaze can be then burnt under reducing atmosphere and oxidizing atmosphere.
For copper oxide in lime glaze, being mostly under oxidizing atmosphere is in green, but will become blue in the strong glaze of alkalinity, if plus
The amount entered very also will become black metal glaze greatly, and red is presented under reducing atmosphere.
It is well known that a series of extremely complex physical and chemical changes can occur in sintering process for porcelain, especially
Different transmutation effects is generated, is formulated, technique etc. is affected, therefore, the manufacture difficulty of furnace transmutation glaze is high, transmutation effect
Fruit is poor, is just particularly important to the research of furnace transmutation glaze.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, and provide a kind of copper red matt furnace transmutation glaze and its preparation side
Method solves the problems, such as that furnace transmutation glaze manufacture difficulty is high in the prior art and transmutation effect is poor, the furnace transmutation glaze performance being prepared
Excellent, thermal stability, water absorption rate and the lead of product, the amount of dissolution of cadmium can meet the relevant criterion of domestic ceramic product.
The purpose of the present invention is achieved through the following technical solutions:
A kind of copper red matt furnace transmutation glaze, the copper red matt furnace transmutation glaze are made of ground coat enamel and overglaze, and the ground coat enamel is applied to ceramics
On green body, the overglaze is applied on the ground coat enamel:
The ground coat enamel includes the component of following parts by weight: 25 ~ 35 parts of potassium feldspar of purification, and 1.8 ~ 2.2 parts of animal bone ash, purification quartz
12 ~ 18 parts, 9 ~ 11 parts of lime, 4 ~ 6 parts of talcum, 4 ~ 6 parts of cordierite of purification, 8 ~ 12 parts of carbonic acid silicon, 1.5 ~ 2.5 parts of copper oxide, oxygen
Change 4 ~ 6 parts of tin, 4 ~ 6 parts of zinc oxide, 5 ~ 8 parts of aluminium oxide, 12 ~ 18 parts of barium carbonate, 15 ~ 25 parts of boron；
The overglaze includes the component of following parts by weight: 15 ~ 25 parts of potassium feldspar of purification, 8 ~ 12 parts of purification quartz, and 4 ~ 6 parts of talcum,
8 ~ 12 parts of basic zirconium phosphate, 4 ~ 8 parts of titanium oxide, 4 ~ 6 parts of tin oxide, 35 ~ 45 parts of frit, 6 ~ 10 parts of dolomite are refined, zinc oxide 6 ~ 10
Part, 1.5 ~ 2.5 parts of copper oxide.
Ground coat enamel is by purification potassium feldspar, animal bone ash, quartz, lime, talcum, purification cordierite, carbonic acid silicon, copper oxide, oxygen
It is formed after changing tin, zinc oxide, aluminium oxide, barium carbonate and boron mixing, wherein potassium feldspar and cordierite are by purification rear impurity content
Few, transmutation effect is good in the ground coat enamel of firing, produces adaptable, high yield rate after burning, be not in conventional furnace transmutation glaze pinhole,
The defects of crawling.
Cordierite, copper oxide and zinc oxide etc. are added, the furnace transmutation glaze of multiple color can be made, keeps ceramic transmutation glaze colours color
More abundant, product is more beautiful and generous；Add cordierite property of glaze it is good, firing temperature have a wide reach, firing process
Stablize；The liquid phase that cordierite pyrolytic generates can promote the formation of mullite crystal, there is the formation of mullite crystal in glaze layer
Conducive to the effect for generating matt, this matt furnace transmutation glaze glaze is fine and smooth, and color is soft, and thermal stability, chemical stability are excellent, makes
It is better than the matt furnace transmutation glaze of other materials with performance.
It is further preferred that the ground coat enamel includes the component of following parts by weight: 28 ~ 32 parts of potassium feldspar of purification, animal bone ash
1.9 ~ 2.1 parts, 14 ~ 16 parts of purification quartz, 4.5 ~ 5.5 parts of talcum, refines 4.5 ~ 5.5 parts of cordierite, carbonic acid silicon by 9 ~ 11 parts of lime
9 ~ 11 parts, 1.8 ~ 2.2 parts of copper oxide, 4.5 ~ 5.5 parts of tin oxide, 4.5 ~ 5.5 parts of zinc oxide, 6 ~ 7 parts of aluminium oxide, barium carbonate 14 ~
16 parts, 18 ~ 22 parts of boron；
The overglaze includes the component of following parts by weight: 18 ~ 22 parts of potassium feldspar of purification, 9 ~ 11 parts of purification quartz, talcum 4.5 ~ 5.5
Part, 9 ~ 11 parts of basic zirconium phosphate, 5 ~ 7 parts of titanium oxide, 4.5 ~ 5.5 parts of tin oxide, 38 ~ 42 parts of frit, 7 ~ 9 parts of dolomite are refined, oxidation
7 ~ 9 parts of zinc, 1.8 ~ 2.2 parts of copper oxide.
It is further preferred that the lime is technical pure lime burning；The carbonic acid silicon is technical pure carbonic acid silicon；The oxygen
Change copper is technical pure copper oxide；The tin oxide is technical pure tin oxide；The zinc oxide is technical pure zinc oxide；The oxidation
Aluminium is technical pure aluminium oxide；The barium carbonate is technical pure barium carbonate；The titanium oxide is technical pure titanium oxide.
It is further preferred that the preparation process of the purification potassium feldspar are as follows: it is put into calcining furnace after crushing potassium feldspar,
Temperature is that 2 ~ 3h is calcined at 800 ~ 900 DEG C, crosses 200 meshes, obtains purification potassium feldspar；
The preparation process of the purification cordierite are as follows: be put into calcining furnace after crushing cordierite, in the case where temperature is 750 ~ 800 DEG C
2 ~ 3h is calcined, 200 meshes are crossed, obtains purification cordierite；
The preparation process of the purification dolomite are as follows: be put into calcining furnace after crushing dolomite, be 850 ~ 1000 DEG C in temperature
2 ~ 3h of lower calcining crosses 200 meshes, obtains purification dolomite；
The preparation process of the purification quartz are as follows: be put into calcining furnace after crushing quartz, forged at being 850 ~ 1000 DEG C in temperature
2 ~ 3h is burnt, 200 meshes are crossed, obtains purification quartz.
The preparation method of above-mentioned copper red matt furnace transmutation glaze, includes the following steps:
Step 1: preparing ground coat enamel glaze slip: potassium feldspar, animal bone ash, purification quartz, stone will be refined according to the proportion of the parts by weight
It is crushed to after ash, talcum, purification cordierite, carbonic acid silicon, copper oxide, tin oxide, zinc oxide, aluminium oxide, barium carbonate and boron mixing
Partial size mesh number >=200 mesh, powder is stirred, then mixed-powder is crossed 200 meshes, obtains ground coat enamel raw material, then ground coat enamel is former
Material and purified water carry out ball milling, and glaze slip crosses 180 meshes after ball out, obtains ground coat enamel glaze slip, for use；
Step 2: preparing overglaze glaze slip: potassium feldspar, purification quartz, talcum, phosphoric acid will be refined according to the proportion of the parts by weight
Partial size mesh number >=200 mesh are crushed to after zirconium, titanium oxide, tin oxide, frit, purification dolomite, zinc oxide and copper oxide mixing, it will
Powder is stirred, then mixed-powder is crossed 200 meshes, obtains overglaze material, then overglaze material and purified water are carried out ball milling,
Glaze slip crosses 180 meshes after ball out, obtains overglaze glaze slip, for use；
Step 3: preparing ground coat enamel: by the direct glaze spraying of ground coat enamel glaze slip in step 1 on ceramic body, glaze spraying specific gravity be 1.20 ~
1.60g/ml is burnt into a reducing atmosphere after spraying three times to get ground coat enamel；
Step 4: preparing overglaze: by the direct glaze spraying of overglaze glaze slip in step 2 on ground coat enamel, glaze spraying specific gravity be 1.00 ~
1.30g/ml is burnt into a reducing atmosphere after spraying three times to get overglaze.
Copper oxide is added in the ground coat enamel and overglaze of furnace transmutation glaze, firing is presented red in a reducing atmosphere, is in temperature
20 ~ 40min is burnt at 1210 ~ 1250 DEG C, glaze is smoothly regular, and transmutation is obvious, and red glaze colourless striped is precipitated obvious；In ground coat enamel
Middle addition animal bone ash keeps its glaze smooth, and pin hole is few, improves the quality of glaze.
Further, the mass ratio of the step 1 ground coat enamel raw material, purified water and ball is 1:(0.9 ~ 1.1): (1.8 ~
2.2)；The mass ratio of overglaze material, purified water and ball is 1:(0.8 ~ 1.0 in the step 2): (1.6 ~ 1.8).
Further, glaze spraying specific gravity is 1.35 ~ 1.45g/ml in the step 3；Glaze spraying specific gravity is in the step 4
1.20~1.25g/ml。
Further, firing temperature is 1210 ~ 1250 DEG C in the step 3, and firing time is 20 ~ 40min；The step
Firing temperature is 1210 ~ 1250 DEG C in rapid four, and firing time is 20 ~ 40min.
It is further preferred that firing temperature is 1230 DEG C in the step 3, firing time 40min；The step 4
Middle firing temperature is 1230 DEG C, firing time 40min.
The beneficial effects of the present invention are:
1. ground coat enamel is by purification potassium feldspar, animal bone ash, quartz, lime, talcum, purification cordierite, carbonic acid silicon, copper oxide, oxidation
It is formed after tin, zinc oxide, aluminium oxide, barium carbonate and boron mixing, wherein potassium feldspar and cordierite are few by purification rear impurity content,
Transmutation effect is good in the ground coat enamel of firing, produces adaptable, high yield rate after burning, is not in pinhole, the rolling of conventional furnace transmutation glaze
The defects of glaze；
2. adding cordierite, copper oxide and zinc oxide etc., the furnace transmutation glaze of multiple color can be made, keep ceramic transmutation glaze colours color
More abundant, product is more beautiful and generous；Add cordierite property of glaze it is good, firing temperature have a wide reach, firing process
Stablize；The liquid phase that cordierite pyrolytic generates can promote the formation of mullite crystal, there is the formation of mullite crystal in glaze layer
Conducive to the effect for generating matt, this matt furnace transmutation glaze glaze is fine and smooth, and color is soft, and thermal stability, chemical stability are excellent, makes
It is better than the matt furnace transmutation glaze of other materials with performance；
3. being added with copper oxide in the ground coat enamel and overglaze of furnace transmutation glaze, firing is presented red in a reducing atmosphere, is in temperature
20 ~ 40min is burnt at 1210 ~ 1250 DEG C, glaze is smoothly regular, and transmutation is obvious, and red glaze colourless striped is precipitated obvious；In ground coat enamel
Middle addition animal bone ash keeps its glaze smooth, and pin hole is few, improves the quality of glaze.
4. copper red matt furnace transmutation glaze ceramic produced by the present invention also has good wearability and thermal shock resistance, can
It is widely used in domestic ceramics.
Specific embodiment
Technical solution of the present invention is described in further detail combined with specific embodiments below, but protection scope of the present invention is not
It is confined to as described below.
Embodiment 1
A kind of copper red matt furnace transmutation glaze, the copper red matt furnace transmutation glaze are made of ground coat enamel and overglaze, and the ground coat enamel is applied to ceramics
On green body, the overglaze is applied on the ground coat enamel:
The ground coat enamel includes the component of following parts by weight: 25 parts of potassium feldspar of purification, and 1.8 parts of animal bone ash, 12 parts of purification quartz, stone
9 parts of ash, 4 parts of talcum, 4 parts of cordierite of purification, 8 parts of carbonic acid silicon, 1.5 parts of copper oxide, 4 parts of tin oxide, 4 parts of zinc oxide, aluminium oxide 5
Part, 12 parts of barium carbonate, 15 parts of boron；
The overglaze includes the component of following parts by weight: 15 parts of potassium feldspar of purification, 8 parts of purification quartz, and 4 parts of talcum, basic zirconium phosphate 8
Part, 4 parts of titanium oxide, 4 parts of tin oxide, 35 parts of frit, refine 6 parts of dolomite, 6 parts of zinc oxide, 1.5 parts of copper oxide；
The lime is technical pure lime burning；The carbonic acid silicon is technical pure carbonic acid silicon；The copper oxide is technical pure oxidation
Copper；The tin oxide is technical pure tin oxide；The zinc oxide is technical pure zinc oxide；The aluminium oxide is technical pure oxidation
Aluminium；The barium carbonate is technical pure barium carbonate；The titanium oxide is technical pure titanium oxide；
The preparation process of the purification potassium feldspar are as follows: be put into calcining furnace after crushing potassium feldspar, calcined at being 800 DEG C in temperature
3h crosses 200 meshes, obtains purification potassium feldspar；
The preparation process of the purification cordierite are as follows: be put into calcining furnace after crushing cordierite, calcined at being 750 DEG C in temperature
3h crosses 200 meshes, obtains purification cordierite；
The preparation process of the purification dolomite are as follows: be put into calcining furnace after crushing dolomite, calcined at being 850 DEG C in temperature
3h crosses 200 meshes, obtains purification dolomite；
The preparation process of the purification quartz are as follows: it is put into calcining furnace after crushing quartz, calcines 3h at being 850 DEG C in temperature,
200 meshes are crossed, purification quartz is obtained.
The preparation method of above-mentioned copper red matt furnace transmutation glaze, includes the following steps:
Step 1: preparing ground coat enamel glaze slip: potassium feldspar, animal bone ash, purification quartz, stone will be refined according to the proportion of above-mentioned parts by weight
It is crushed to after ash, talcum, purification cordierite, carbonic acid silicon, copper oxide, tin oxide, zinc oxide, aluminium oxide, barium carbonate and boron mixing
Partial size mesh number >=200 mesh, obtains ground coat enamel raw material, then by ground coat enamel raw material, purified water and ball according to mass ratio is that 1:0.9:1.8 is carried out
Ball milling, glaze slip crosses 180 meshes after ball out, obtains ground coat enamel glaze slip, for use；
Step 2: preparing overglaze glaze slip: potassium feldspar, purification quartz, talcum, phosphoric acid will be refined according to the proportion of above-mentioned parts by weight
Partial size mesh number >=200 mesh are crushed to after zirconium, titanium oxide, tin oxide, frit, purification dolomite, zinc oxide and copper oxide mixing, are obtained
Ball milling is carried out for 1:0.8:1.6 according to mass ratio to overglaze material, then by overglaze material, purified water and ball, out glaze slip mistake after ball
180 meshes obtain overglaze glaze slip, for use；
Step 3: preparing ground coat enamel: by the direct glaze spraying of ground coat enamel glaze slip in step 1 on ceramic body, glaze spraying specific gravity is 1.20g/
Ml is burnt into a reducing atmosphere after spraying three times, and firing temperature is 1210 DEG C, and firing time is 40min to get ground coat enamel；
Step 4: preparing overglaze: by the direct glaze spraying of overglaze glaze slip in step 2 on ground coat enamel, glaze spraying specific gravity is 1.00g/ml,
It is burnt into a reducing atmosphere after spraying three times, firing temperature is 1210 DEG C, and firing time is 40min to get overglaze.
Embodiment 2
A kind of copper red matt furnace transmutation glaze, the copper red matt furnace transmutation glaze are made of ground coat enamel and overglaze, and the ground coat enamel is applied to ceramics
On green body, the overglaze is applied on the ground coat enamel:
The ground coat enamel includes the component of following parts by weight: 35 parts of potassium feldspar of purification, and 2.2 parts of animal bone ash, 18 parts of purification quartz, stone
11 parts of ash, refines 6 parts of cordierite, 12 parts of carbonic acid silicon, 2.5 parts of copper oxide, 6 parts of tin oxide, 6 parts of zinc oxide, aoxidizes by 6 parts of talcum
8 parts of aluminium, 18 parts of barium carbonate, 25 parts of boron；
The overglaze includes the component of following parts by weight: 25 parts of potassium feldspar of purification, 12 parts of purification quartz, and 6 parts of talcum, basic zirconium phosphate 12
Part, 8 parts of titanium oxide, 6 parts of tin oxide, 45 parts of frit, refine 10 parts of dolomite, 10 parts of zinc oxide, 2.5 parts of copper oxide；
The lime is technical pure lime burning；The carbonic acid silicon is technical pure carbonic acid silicon；The copper oxide is technical pure oxidation
Copper；The tin oxide is technical pure tin oxide；The zinc oxide is technical pure zinc oxide；The aluminium oxide is technical pure oxidation
Aluminium；The barium carbonate is technical pure barium carbonate；The titanium oxide is technical pure titanium oxide；
The preparation process of the purification potassium feldspar are as follows: be put into calcining furnace after crushing potassium feldspar, calcined at being 900 DEG C in temperature
2h crosses 200 meshes, obtains purification potassium feldspar；
The preparation process of the purification cordierite are as follows: be put into calcining furnace after crushing cordierite, calcined at being 800 DEG C in temperature
2h crosses 200 meshes, obtains purification cordierite；
The preparation process of the purification dolomite are as follows: be put into calcining furnace after crushing dolomite, forged at being 1000 DEG C in temperature
2h is burnt, 200 meshes are crossed, obtains purification dolomite；
The preparation process of the purification quartz are as follows: it is put into calcining furnace after crushing quartz, calcines 2h at being 1000 DEG C in temperature,
200 meshes are crossed, purification quartz is obtained.
The preparation method of above-mentioned copper red matt furnace transmutation glaze, includes the following steps:
Step 1: preparing ground coat enamel glaze slip: according to above-mentioned parts by weight proportion will refine potassium feldspar, animal bone ash, quartz, lime,
Partial size is crushed to after talcum, purification cordierite, carbonic acid silicon, copper oxide, tin oxide, zinc oxide, aluminium oxide, barium carbonate and boron mixing
Mesh number >=200 mesh obtains ground coat enamel raw material, then ground coat enamel raw material, purified water and ball is carried out ball according to mass ratio for 1:1.1:2.2
Mill, glaze slip crosses 180 meshes after ball out, obtains ground coat enamel glaze slip, for use；
Step 2: preparing overglaze glaze slip: potassium feldspar, quartz, talcum, basic zirconium phosphate, oxygen will be refined according to the proportion of above-mentioned parts by weight
Partial size mesh number >=200 mesh are crushed to after changing titanium, tin oxide, frit, dolomite, zinc oxide and copper oxide mixing, obtain overglaze original
Material, then overglaze material, purified water and ball are subjected to ball milling according to mass ratio for 1:1.0:1.8, glaze slip crosses 180 meshes after ball out,
Overglaze glaze slip is obtained, for use；
Step 3: preparing ground coat enamel: by the direct glaze spraying of ground coat enamel glaze slip in step 1 on ceramic body, glaze spraying specific gravity is 1.60g/
Ml is burnt into a reducing atmosphere after spraying three times, and firing temperature is 1250 DEG C, and firing time is 20min to get ground coat enamel；
Step 4: preparing overglaze: by the direct glaze spraying of overglaze glaze slip in step 2 on ground coat enamel, glaze spraying specific gravity is 1.30g/ml,
It is burnt into a reducing atmosphere after spraying three times, firing temperature is 1250 DEG C, and firing time is 20 ~ min to get overglaze.
Embodiment 3
A kind of copper red matt furnace transmutation glaze, the copper red matt furnace transmutation glaze are made of ground coat enamel and overglaze, and the ground coat enamel is applied to ceramics
On green body, the overglaze is applied on the ground coat enamel:
The ground coat enamel includes the component of following parts by weight: 28 parts of potassium feldspar of purification, and 1.9 parts of animal bone ash, 14 parts of purification quartz, stone
9 parts of ash, 4.5 parts of talcum, 4.5 parts of cordierite of purification, 9 parts of carbonic acid silicon, 1.8 parts of copper oxide, 4.5 parts of tin oxide, zinc oxide 4.5
Part, 6 parts of aluminium oxide, 14 parts of barium carbonate, 18 parts of boron；
The overglaze includes the component of following parts by weight: 18 parts of potassium feldspar of purification, 9 parts of purification quartz, and 4.5 parts of talcum, basic zirconium phosphate 9
Part, 5 parts of titanium oxide, 4.5 parts of tin oxide, 38 parts of frit, refine 7 parts of dolomite, 7 parts of zinc oxide, 1.8 parts of copper oxide；
The lime is technical pure lime burning；The carbonic acid silicon is technical pure carbonic acid silicon；The copper oxide is technical pure oxidation
Copper；The tin oxide is technical pure tin oxide；The zinc oxide is technical pure zinc oxide；The aluminium oxide is technical pure oxidation
Aluminium；The barium carbonate is technical pure barium carbonate；The titanium oxide is technical pure titanium oxide；
The preparation process of the purification potassium feldspar are as follows: be put into calcining furnace after crushing potassium feldspar, calcined at being 850 DEG C in temperature
2.5h crosses 200 meshes, obtains purification potassium feldspar；
The preparation process of the purification cordierite are as follows: be put into calcining furnace after crushing cordierite, calcined at being 880 DEG C in temperature
2.5h crosses 200 meshes, obtains purification cordierite；
The preparation process of the purification dolomite are as follows: be put into calcining furnace after crushing dolomite, calcined at being 950 DEG C in temperature
2.5h crosses 200 meshes, obtains purification dolomite；
The preparation process of the purification quartz are as follows: be put into calcining furnace after crushing quartz, calcined at being 950 DEG C in temperature
2.5h crosses 200 meshes, obtains purification quartz.
The preparation method of above-mentioned copper red matt furnace transmutation glaze, includes the following steps:
Step 1: preparing ground coat enamel glaze slip: according to above-mentioned parts by weight proportion will refine potassium feldspar, animal bone ash, quartz, lime,
Partial size is crushed to after talcum, purification cordierite, carbonic acid silicon, copper oxide, tin oxide, zinc oxide, aluminium oxide, barium carbonate and boron mixing
Mesh number >=200 mesh obtains ground coat enamel raw material, then ground coat enamel raw material, purified water and ball is carried out ball according to mass ratio for 1:1.0:2.0
Mill, glaze slip crosses 180 meshes after ball out, obtains ground coat enamel glaze slip, for use；
Step 2: preparing overglaze glaze slip: potassium feldspar, quartz, talcum, basic zirconium phosphate, oxygen will be refined according to the proportion of above-mentioned parts by weight
Partial size mesh number >=200 mesh are crushed to after changing titanium, tin oxide, frit, dolomite, zinc oxide and copper oxide mixing, obtain overglaze original
Material, then overglaze material, purified water and ball are subjected to ball milling according to mass ratio for 1:0.9:1.7, glaze slip crosses 180 mesh after ball out
Sieve, obtains overglaze glaze slip, for use；
Step 3: preparing ground coat enamel: by the direct glaze spraying of ground coat enamel glaze slip in step 1 on ceramic body, glaze spraying specific gravity is 1.45g/
Ml is burnt into a reducing atmosphere after spraying three times, and firing temperature is 1230 DEG C, and firing time is 30min to get ground coat enamel；
Step 4: preparing overglaze: by the direct glaze spraying of overglaze glaze slip in step 2 on ground coat enamel, glaze spraying specific gravity is 1.25g/ml,
It is burnt into a reducing atmosphere after spraying three times, firing temperature is 1230 DEG C, and firing time is 30min to get overglaze.
Embodiment 4
A kind of copper red matt furnace transmutation glaze, the copper red matt furnace transmutation glaze are made of ground coat enamel and overglaze, and the ground coat enamel is applied to ceramics
On green body, the overglaze is applied on the ground coat enamel:
The ground coat enamel includes the component of following parts by weight: 32 parts of potassium feldspar of purification, and 2.1 parts of animal bone ash, 16 parts of purification quartz, stone
11 parts of ash, 5.5 parts of talcum, 5.5 parts of cordierite of purification, 11 parts of carbonic acid silicon, 2.2 parts of copper oxide, 5.5 parts of tin oxide, zinc oxide 5.5
Part, 7 parts of aluminium oxide, 16 parts of barium carbonate, 22 parts of boron；
The overglaze includes the component of following parts by weight: 22 parts of potassium feldspar of purification, 11 parts of purification quartz, and 5.5 parts of talcum, basic zirconium phosphate
11 parts, 7 parts of titanium oxide, 5.5 parts of tin oxide, 42 parts of frit, refine 9 parts of dolomite, 9 parts of zinc oxide, 2.2 parts of copper oxide；
The lime is technical pure lime burning；The carbonic acid silicon is technical pure carbonic acid silicon；The copper oxide is technical pure oxidation
Copper；The tin oxide is technical pure tin oxide；The zinc oxide is technical pure zinc oxide；The aluminium oxide is technical pure oxidation
Aluminium；The barium carbonate is technical pure barium carbonate；The titanium oxide is technical pure titanium oxide；
The preparation process of the purification potassium feldspar are as follows: be put into calcining furnace after crushing potassium feldspar, calcined at being 850 DEG C in temperature
2.5h crosses 200 meshes, obtains purification potassium feldspar；
The preparation process of the purification cordierite are as follows: be put into calcining furnace after crushing cordierite, calcined at being 880 DEG C in temperature
2.5h crosses 200 meshes, obtains purification cordierite；
The preparation process of the purification dolomite are as follows: be put into calcining furnace after crushing dolomite, calcined at being 900 DEG C in temperature
2.5h crosses 200 meshes, obtains purification dolomite；
The preparation process of the purification quartz are as follows: be put into calcining furnace after crushing quartz, calcined at being 900 DEG C in temperature
2.5h crosses 200 meshes, obtains purification quartz.
The preparation method of above-mentioned copper red matt furnace transmutation glaze, includes the following steps:
Step 1: preparing ground coat enamel glaze slip: according to above-mentioned parts by weight proportion will refine potassium feldspar, animal bone ash, quartz, lime,
Partial size is crushed to after talcum, purification cordierite, carbonic acid silicon, copper oxide, tin oxide, zinc oxide, aluminium oxide, barium carbonate and boron mixing
Mesh number >=200 mesh obtains ground coat enamel raw material, then ground coat enamel raw material, purified water and ball is carried out ball according to mass ratio for 1:1.1:2.0
Mill, glaze slip crosses 180 meshes after ball out, obtains ground coat enamel glaze slip, for use；
Step 2: preparing overglaze glaze slip: potassium feldspar, quartz, talcum, basic zirconium phosphate, oxygen will be refined according to the proportion of above-mentioned parts by weight
Partial size mesh number >=200 mesh are crushed to after changing titanium, tin oxide, frit, dolomite, zinc oxide and copper oxide mixing, obtain overglaze original
Material, then overglaze material, purified water and ball are subjected to ball milling according to mass ratio for 1:0.9:1.8, glaze slip crosses 180 meshes after ball out,
Overglaze glaze slip is obtained, for use；
Step 3: preparing ground coat enamel: by the direct glaze spraying of ground coat enamel glaze slip in step 1 on ceramic body, glaze spraying specific gravity is 1.35g/
Ml is burnt into a reducing atmosphere after spraying three times, and firing temperature is 1250 DEG C, and firing time is 40min to get ground coat enamel；
Step 4: preparing overglaze: by the direct glaze spraying of overglaze glaze slip in step 2 on ground coat enamel, glaze spraying specific gravity is 1.20g/ml,
It is burnt into a reducing atmosphere after spraying three times, firing temperature is 1250 DEG C, and firing time is 40min to get overglaze.
Embodiment 5
A kind of copper red matt furnace transmutation glaze, the copper red matt furnace transmutation glaze are made of ground coat enamel and overglaze, and the ground coat enamel is applied to ceramics
On green body, the overglaze is applied on the ground coat enamel:
The ground coat enamel includes the component of following parts by weight: 30 parts of potassium feldspar of purification, and 2.0 parts of animal bone ash, 15 parts of purification quartz, stone
10 parts of ash, refines 5 parts of cordierite, 10 parts of carbonic acid silicon, 2.0 parts of copper oxide, 5 parts of tin oxide, 5 parts of zinc oxide, aoxidizes by 5 parts of talcum
6 parts of aluminium, 15 parts of barium carbonate, 20 parts of boron；
The overglaze includes the component of following parts by weight: 20 parts of potassium feldspar of purification, 10 parts of purification quartz, and 5 parts of talcum, basic zirconium phosphate 10
Part, 6 parts of titanium oxide, 5 parts of tin oxide, 40 parts of frit, refine 8 parts of dolomite, 8 parts of zinc oxide, 2.0 parts of copper oxide；
The lime is technical pure lime burning；The carbonic acid silicon is technical pure carbonic acid silicon；The copper oxide is technical pure oxidation
Copper；The tin oxide is technical pure tin oxide；The zinc oxide is technical pure zinc oxide；The aluminium oxide is technical pure oxidation
Aluminium；The barium carbonate is technical pure barium carbonate；The titanium oxide is technical pure titanium oxide；
The preparation process of the purification potassium feldspar are as follows: be put into calcining furnace after crushing potassium feldspar, calcined at being 850 DEG C in temperature
3h crosses 200 meshes, obtains purification potassium feldspar；
The preparation process of the purification cordierite are as follows: be put into calcining furnace after crushing cordierite, calcined at being 800 DEG C in temperature
3h crosses 200 meshes, obtains purification cordierite；
The preparation process of the purification dolomite are as follows: be put into calcining furnace after crushing dolomite, calcined at being 900 DEG C in temperature
3h crosses 200 meshes, obtains purification dolomite；
The preparation process of the purification quartz are as follows: it is put into calcining furnace after crushing quartz, calcines 3h at being 900 DEG C in temperature,
200 meshes are crossed, purification quartz is obtained.
The preparation method of above-mentioned copper red matt furnace transmutation glaze, includes the following steps:
Step 1: preparing ground coat enamel glaze slip: according to above-mentioned parts by weight proportion will refine potassium feldspar, animal bone ash, quartz, lime,
Partial size is crushed to after talcum, purification cordierite, carbonic acid silicon, copper oxide, tin oxide, zinc oxide, aluminium oxide, barium carbonate and boron mixing
Mesh number >=200 mesh obtains ground coat enamel raw material, then ground coat enamel raw material, purified water and ball is carried out ball according to mass ratio for 1:1.0:2.0
Mill, glaze slip crosses 180 meshes after ball out, obtains ground coat enamel glaze slip, for use；
Step 2: preparing overglaze glaze slip: potassium feldspar, quartz, talcum, basic zirconium phosphate, oxygen will be refined according to the proportion of above-mentioned parts by weight
Partial size mesh number >=200 mesh are crushed to after changing titanium, tin oxide, frit, dolomite, zinc oxide and copper oxide mixing, obtain overglaze original
Material, then overglaze material, purified water and ball are subjected to ball milling according to mass ratio for 1:0.9:1.7, glaze slip crosses 180 meshes after ball out,
Overglaze glaze slip is obtained, for use；
Step 3: preparing ground coat enamel: by the direct glaze spraying of ground coat enamel glaze slip in step 1 on ceramic body, glaze spraying specific gravity is 1.40/
Ml is burnt into a reducing atmosphere after spraying three times, and firing temperature is 1230 DEG C, and firing time is 40min to get ground coat enamel；
Step 4: preparing overglaze: by the direct glaze spraying of overglaze glaze slip in step 2 on ground coat enamel, glaze spraying specific gravity is 1.20g/ml,
It is burnt into a reducing atmosphere after spraying three times, firing temperature is 1230 DEG C, and firing time is 40min to get overglaze.
Embodiment 6
A kind of copper red matt furnace transmutation glaze, the copper red matt furnace transmutation glaze are made of ground coat enamel and overglaze, and the ground coat enamel is applied to ceramics
On green body, the overglaze is applied on the ground coat enamel:
The ground coat enamel includes the component of following parts by weight: 30 parts of potassium feldspar of purification, and 2.0 parts of animal bone ash, 15 parts of purification quartz, stone
10 parts of ash, refines 5 parts of cordierite, 10 parts of carbonic acid silicon, 2.0 parts of copper oxide, 5 parts of tin oxide, 5 parts of zinc oxide, aoxidizes by 5 parts of talcum
6 parts of aluminium, 15 parts of barium carbonate, 20 parts of boron；
The overglaze includes the component of following parts by weight: 20 parts of potassium feldspar of purification, 10 parts of purification quartz, and 5 parts of talcum, basic zirconium phosphate 10
Part, 6 parts of titanium oxide, 5 parts of tin oxide, 40 parts of frit, refine 8 parts of dolomite, 8 parts of zinc oxide, 2.0 parts of copper oxide；
The lime is technical pure lime burning；The carbonic acid silicon is technical pure carbonic acid silicon；The copper oxide is technical pure oxidation
Copper；The tin oxide is technical pure tin oxide；The zinc oxide is technical pure zinc oxide；The aluminium oxide is technical pure oxidation
Aluminium；The barium carbonate is technical pure barium carbonate；The titanium oxide is technical pure titanium oxide；
The preparation process of the purification potassium feldspar are as follows: be put into calcining furnace after crushing potassium feldspar, calcined at being 900 DEG C in temperature
2.5h crosses 200 meshes, obtains purification potassium feldspar；
The preparation process of the purification cordierite are as follows: be put into calcining furnace after crushing cordierite, calcined at being 800 DEG C in temperature
2.5h crosses 200 meshes, obtains purification cordierite；
The preparation process of the purification dolomite are as follows: be put into calcining furnace after crushing dolomite, calcined at being 900 DEG C in temperature
2.5h crosses 200 meshes, obtains purification dolomite；
The preparation process of the purification quartz are as follows: be put into calcining furnace after crushing quartz, calcined at being 900 DEG C in temperature
2.5h crosses 200 meshes, obtains purification quartz.
The preparation method of above-mentioned copper red matt furnace transmutation glaze, includes the following steps:
Step 1: preparing ground coat enamel glaze slip: according to above-mentioned parts by weight proportion will refine potassium feldspar, animal bone ash, quartz, lime,
Partial size is crushed to after talcum, purification cordierite, carbonic acid silicon, copper oxide, tin oxide, zinc oxide, aluminium oxide, barium carbonate and boron mixing
Mesh number >=200 mesh obtains ground coat enamel raw material, then ground coat enamel raw material, purified water and ball is carried out ball according to mass ratio for 1:1.0:2.0
Mill, glaze slip crosses 180 meshes after ball out, obtains ground coat enamel glaze slip, for use；
Step 2: preparing overglaze glaze slip: potassium feldspar, quartz, talcum, basic zirconium phosphate, oxygen will be refined according to the proportion of above-mentioned parts by weight
Partial size mesh number >=200 mesh are crushed to after changing titanium, tin oxide, frit, dolomite, zinc oxide and copper oxide mixing, obtain overglaze original
Material, then overglaze material, purified water and ball are subjected to ball milling according to mass ratio for 1:0.9:1.7, glaze slip crosses 180 meshes after ball out,
Overglaze glaze slip is obtained, for use；
Step 3: preparing ground coat enamel: by the direct glaze spraying of ground coat enamel glaze slip in step 1 on ceramic body, glaze spraying specific gravity is 1.40/
Ml is burnt into a reducing atmosphere after spraying three times, and firing temperature is 1230 DEG C, and firing time is 40min to get ground coat enamel；
Step 4: preparing overglaze: by the direct glaze spraying of overglaze glaze slip in step 2 on ground coat enamel, glaze spraying specific gravity is 1.20g/ml,
It is burnt into a reducing atmosphere after spraying three times, firing temperature is 1230 DEG C, and firing time is 40min to get overglaze.
Copper red matt furnace transmutation glaze ceramics, performance such as 1 institute of table are made respectively according to the method preparation of embodiment 1- embodiment 6
Show, according to " domestic ceramics device thermal stability determination method " (GB/T 3298-91), takes 5 for every group in embodiment 1- embodiment 6
Ceramic product is tested, and is calculated as 1#, 2#, 3#, 4#, 5# respectively.According to " domestic ceramics device water absorption rate measuring method " (GB/
T3299-1996), in embodiment 1- embodiment 6 every group take 3 ceramic products to be tested, be calculated as 1#, 2#, 3# respectively.According to
" domestic ceramics device lead, quantity of cadmium release measuring method " (GB3534-83) takes 6 ceramic products for every group in embodiment 1- embodiment 6
It is tested, is calculated as 1#, 2#, 3#, 4#, 5#, 6# respectively.
From table 1 it follows that -20 ~ 180 DEG C of heat exchanges are once flawless, it can be assumed that assert copper red matt furnace transmutation glaze
Thermal stability it is qualified.Water absorption rate is not more than 3%, it can be assumed that assert that the water absorption rate of copper red matt furnace transmutation glaze is qualified.Pb(ppm)
The amount of dissolution is respectively less than 0.1, Cd(ppm) the amount of dissolution is respectively less than 0.01.To sum up, it can be assumed that copper red matt furnace transmutation glaze lead, cadmium are molten
Output complies with the national standard requirements.
The above is only a preferred embodiment of the present invention, it should be understood that the present invention is not limited to described herein
Form should not be regarded as an exclusion of other examples, and can be used for other combinations, modifications, and environments, and can be at this
In the text contemplated scope, modifications can be made through the above teachings or related fields of technology or knowledge.And those skilled in the art institute into
Capable modifications and changes do not depart from the spirit and scope of the present invention, then all should be in the protection scope of appended claims of the present invention
It is interior.
Claims (9)
1. a kind of copper red matt furnace transmutation glaze, the copper red matt furnace transmutation glaze is made of ground coat enamel and overglaze, and the ground coat enamel is applied to pottery
On porcelain billet body, the overglaze is applied on the ground coat enamel, it is characterised in that:
The ground coat enamel includes the component of following parts by weight: 25 ~ 35 parts of potassium feldspar of purification, and 1.8 ~ 2.2 parts of animal bone ash, purification quartz
12 ~ 18 parts, 9 ~ 11 parts of lime, 4 ~ 6 parts of talcum, 4 ~ 6 parts of cordierite of purification, 8 ~ 12 parts of carbonic acid silicon, 1.5 ~ 2.5 parts of copper oxide, oxygen
Change 4 ~ 6 parts of tin, 4 ~ 6 parts of zinc oxide, 5 ~ 8 parts of aluminium oxide, 12 ~ 18 parts of barium carbonate, 15 ~ 25 parts of boron；
The overglaze includes the component of following parts by weight: 15 ~ 25 parts of potassium feldspar of purification, 8 ~ 12 parts of purification quartz, and 4 ~ 6 parts of talcum,
8 ~ 12 parts of basic zirconium phosphate, 4 ~ 8 parts of titanium oxide, 4 ~ 6 parts of tin oxide, 35 ~ 45 parts of frit, 6 ~ 10 parts of dolomite are refined, zinc oxide 6 ~ 10
Part, 1.5 ~ 2.5 parts of copper oxide.
2. a kind of copper red matt furnace transmutation glaze according to claim 1, which is characterized in that the ground coat enamel includes following parts by weight
Component: purification 28 ~ 32 parts of potassium feldspar, 1.9 ~ 2.1 parts of animal bone ash, purification quartz 14 ~ 16 parts, 9 ~ 11 parts of lime, talcum 4.5
~ 5.5 parts, 4.5 ~ 5.5 parts of cordierite are refined, 9 ~ 11 parts of carbonic acid silicon, 1.8 ~ 2.2 parts of copper oxide, 4.5 ~ 5.5 parts of tin oxide, is aoxidized
4.5 ~ 5.5 parts of zinc, 6 ~ 7 parts of aluminium oxide, 14 ~ 16 parts of barium carbonate, 18 ~ 22 parts of boron；
The overglaze includes the component of following parts by weight: 18 ~ 22 parts of potassium feldspar of purification, 9 ~ 11 parts of purification quartz, talcum 4.5 ~ 5.5
Part, 9 ~ 11 parts of basic zirconium phosphate, 5 ~ 7 parts of titanium oxide, 4.5 ~ 5.5 parts of tin oxide, 38 ~ 42 parts of frit, 7 ~ 9 parts of dolomite are refined, oxidation
7 ~ 9 parts of zinc, 1.8 ~ 2.2 parts of copper oxide.
3. a kind of copper red matt furnace transmutation glaze according to claim 1 or 2, which is characterized in that the lime is forged for technical pure
Burnt lime；The carbonic acid silicon is technical pure carbonic acid silicon；The copper oxide is technical pure copper oxide；The tin oxide is industrial pure oxygen
Change tin；The zinc oxide is technical pure zinc oxide；The aluminium oxide is technical pure aluminium oxide；The barium carbonate is technical pure carbonic acid
Barium；The titanium oxide is technical pure titanium oxide.
4. a kind of copper red matt furnace transmutation glaze according to claim 1 or 2, which is characterized in that the system of the purification potassium feldspar
Standby process are as follows: be put into calcining furnace after crushing potassium feldspar, calcine 2 ~ 3h at being 800 ~ 900 DEG C in temperature, cross 200 meshes, obtain
To purification potassium feldspar；
The preparation process of the purification cordierite are as follows: be put into calcining furnace after crushing cordierite, in the case where temperature is 750 ~ 800 DEG C
2 ~ 3h is calcined, 200 meshes are crossed, obtains purification cordierite；
The preparation process of the purification dolomite are as follows: be put into calcining furnace after crushing dolomite, be 850 ~ 1000 DEG C in temperature
2 ~ 3h of lower calcining crosses 200 meshes, obtains purification dolomite；
The preparation process of the purification quartz are as follows: be put into calcining furnace after crushing quartz, forged at being 850 ~ 1000 DEG C in temperature
2 ~ 3h is burnt, 200 meshes are crossed, obtains purification quartz.
5. a kind of described in any item preparation methods of copper red matt furnace transmutation glaze of claim 1-4, which is characterized in that including as follows
Step:
Step 1: preparing ground coat enamel glaze slip: potassium feldspar, animal bone ash, purification quartz, stone will be refined according to the proportion of the parts by weight
It is crushed to after ash, talcum, purification cordierite, carbonic acid silicon, copper oxide, tin oxide, zinc oxide, aluminium oxide, barium carbonate and boron mixing
Partial size mesh number >=200 mesh obtains ground coat enamel raw material, then ground coat enamel raw material and purified water is carried out ball milling, and glaze slip crosses 180 mesh after ball out
Sieve, obtains ground coat enamel glaze slip, for use；
Step 2: preparing overglaze glaze slip: potassium feldspar, purification quartz, talcum, phosphoric acid will be refined according to the proportion of the parts by weight
Partial size mesh number >=200 mesh are crushed to after zirconium, titanium oxide, tin oxide, frit, purification dolomite, zinc oxide and copper oxide mixing, are obtained
Ball milling is carried out to overglaze material, then by overglaze material and purified water, glaze slip crosses 180 meshes after ball out, overglaze glaze slip is obtained, to
With；
Step 3: preparing ground coat enamel: by the direct glaze spraying of ground coat enamel glaze slip in step 1 on ceramic body, glaze spraying specific gravity be 1.20 ~
1.60g/ml is burnt into a reducing atmosphere after spraying three times to get ground coat enamel；
Step 4: preparing overglaze: by the direct glaze spraying of overglaze glaze slip in step 2 on ground coat enamel, glaze spraying specific gravity be 1.00 ~
1.30g/ml is burnt into a reducing atmosphere after spraying three times to get overglaze.
6. a kind of preparation method of copper red matt furnace transmutation glaze according to claim 5, which is characterized in that in the step 1
The mass ratio of ground coat enamel raw material, purified water and ball is 1:(0.9 ~ 1.1): (1.8 ~ 2.2)；Overglaze material, purifying in the step 2
The mass ratio of water and ball is 1:(0.8 ~ 1.0): (1.6 ~ 1.8).
7. a kind of preparation method of copper red matt furnace transmutation glaze according to claim 5, which is characterized in that in the step 3
Glaze spraying specific gravity is 1.35 ~ 1.45g/ml；Glaze spraying specific gravity is 1.20 ~ 1.25g/ml in the step 4.
8. a kind of preparation method of copper red matt furnace transmutation glaze according to claim 5 or 7, which is characterized in that the step
Temperature when being burnt into three is 1210 ~ 1250 DEG C, and firing time is 20 ~ 40min；In the step 4 be burnt into when temperature be
1210 ~ 1250 DEG C, firing time is 20 ~ 40min.
9. a kind of preparation method of copper red matt furnace transmutation glaze according to claim 8, which is characterized in that in the step 3
Firing temperature is 1230 DEG C, firing time 40min；Firing temperature is 1230 DEG C in the step 4, and firing time is
40min。
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