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CN113336574B - Dull transmutation pink wiredrawing glaze and preparation method thereof - Google Patents

Dull transmutation pink wiredrawing glaze and preparation method thereof Download PDF

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Publication number
CN113336574B
CN113336574B CN202010134546.1A CN202010134546A CN113336574B CN 113336574 B CN113336574 B CN 113336574B CN 202010134546 A CN202010134546 A CN 202010134546A CN 113336574 B CN113336574 B CN 113336574B
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glaze
parts
pink
matt
wiredrawing
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CN113336574A (en
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陈元昊
李建民
陈丽雪
陈伟毅
陈伟斌
陈能慈
陈能谨
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Fujian Dehua Porcelain Culture Co ltd
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Fujian Dehua County Porcelain Culture Co ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes

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  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
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Abstract

The invention provides a matt fambe pink wiredrawing glaze and a preparation method thereof, belonging to the field of ceramics. The glaze of the matt fambe pink wiredrawing glaze provided by the invention comprises the following components in parts by mass: 33-37 parts of potash feldspar, 9-11 parts of barium carbonate, 12-14 parts of kaolin, 4.5-5.5 parts of zinc oxide, 14-16 parts of dolomite, 9-11 parts of bone ash, 11-13 parts of talc and 4.5-5.5 parts of scarlet pigment. The matt furnace transmutation pink wiredrawing glaze provided by the invention presents pink regular stripe sub-gloss texture, and is beautiful and durable to look. In addition, the glaze used by the matt furnace transmutation pink wiredrawing glaze provided by the invention does not contain heavy metals such as lead, cadmium and the like, and has the advantages of environmental protection and no toxicity.

Description

Dull transmutation pink wiredrawing glaze and preparation method thereof
Technical Field
The invention relates to the field of ceramics, in particular to a matt fambe pink wiredrawing glaze and a preparation method thereof.
Background
The ceramic not only can be used as a vessel, but also can be used as an ornament. Along with the improvement of living standard of people, people pursue the appearance of ceramics to be higher and higher, and ceramic glazes with various colors appear on the market. However, no matt furnace transmutation pink wiredrawing glaze is available in the market at present, and the preference of young consumers cannot be met.
Disclosure of Invention
The invention aims to provide a matt fambe pink wiredrawing glaze and a preparation method thereof, and provides a novel ceramic glaze which presents pink regular stripe sub-gloss texture and can meet the consumer groups who like the pink wiredrawing glaze.
In order to achieve the above object, the present invention provides the following technical solutions:
the invention provides a matt transmutation pink drawing glaze, wherein a glaze of the matt transmutation pink drawing glaze comprises the following components in parts by mass: 33-37 parts of potash feldspar, 9-11 parts of barium carbonate, 12-14 parts of kaolin, 4.5-5.5 parts of zinc oxide, 14-16 parts of dolomite, 9-11 parts of bone ash, 11-13 parts of talc and 4.5-5.5 parts of scarlet pigment.
Preferably, the glaze of the matt famille rose drawing glaze comprises the following components in parts by mass: 35 parts of potash feldspar, 10 parts of barium carbonate, 13 parts of kaolin, 5 parts of zinc oxide, 15 parts of dolomite, 10 parts of bone ash, 12 parts of talc and 5 parts of scarlet pigment.
Preferably, the alkaline components in the glaze formula of the matt fambe pink wiredrawing glaze comprise potassium oxide, sodium oxide, zinc oxide, calcium oxide, magnesium oxide, barium carbonate and phosphorus hexaoxide, wherein the molar ratio of the potassium oxide, the sodium oxide, the zinc oxide, the calcium oxide, the magnesium oxide, the barium carbonate and the phosphorus hexaoxide is 0.114: 0.03-0.05: 0.15-0.16: 0.22-0.23: 0.22-0.24: 0.16-0.17: 0.07-0.077; the ratio of the total amount of alkaline components in the glaze formula of the matt famille pink wiredrawing glaze to the amount of alumina, silica and titanium dioxide is 1: 0.16-0.18: 0.64-0.65: 0.09-0.10.
Preferably, the molar ratio of the potassium oxide, the sodium oxide, the zinc oxide, the calcium oxide, the magnesium oxide, the barium carbonate and the phosphorus hexaoxide is 0.114:0.038:0.152:0.227:0.229:0.164: 0.076; the ratio of the total amount of the basic components to the amount of the alumina, silica, titania is 1:0.167:0.644: 0.093.
The invention also provides a preparation method of the matt fambe pink wiredrawing glaze, which comprises the following steps:
mixing glaze of the matt famille rose pink drawing glaze except the bright red pigment with water, and performing ball milling to obtain premixed slurry;
mixing the premixed slurry with a scarlet pigment to obtain glaze slurry;
glazing the whole surface of the ceramic blank by adopting the glaze slurry to obtain a matt fambe pink wiredrawing glaze blank;
and carrying out oxidation sintering on the matt famille pink drawing glaze blank to obtain the matt famille pink drawing glaze.
Preferably, the oxidizing firing is performed in an air atmosphere, and the oxidizing firing temperature is 1230 to 1250 ℃.
Preferably, the concentration of the glaze slurry is 38-42 Baume degrees.
Preferably, the ball milling time is 16-20 h.
Preferably, the mass ratio of the glaze of the matt furnace transmutation pink wiredrawing glaze except the bright red pigment to water is 100: 75-85.
Preferably, after the mixing of the premixed slurry and the scarlet pigment is completed, the screening is further carried out, and the mesh number of a screen used for screening is 150-170 meshes.
The invention provides a matt transmutation pink drawing glaze, wherein a glaze of the matt transmutation pink drawing glaze comprises the following components in parts by mass: 33-37 parts of potash feldspar, 9-11 parts of barium carbonate, 12-14 parts of kaolin, 4.5-5.5 parts of zinc oxide, 14-16 parts of dolomite, 9-11 parts of bone ash, 11-13 parts of talc and 4.5-5.5 parts of scarlet pigment. The matt furnace transmutation pink wiredrawing glaze provided by the invention presents pink regular stripe sub-gloss texture, and is beautiful and durable to look. In addition, the glaze used by the matt furnace transmutation pink wiredrawing glaze provided by the invention does not contain heavy metals such as lead, cadmium and the like, and has the advantages of environmental protection and no toxicity.
The invention also provides a preparation method of the matt furnace transmutation pink wiredrawing glaze, which adopts one-time glazing, saves labor and materials, adopts an oxidation firing method for firing, can ensure full combustion, and has the advantage of environmental protection.
Drawings
FIG. 1 is a physical representation of the matt kilned pink drawn glaze obtained in example 1.
Detailed Description
The invention provides a matt transmutation pink drawing glaze, wherein a glaze of the matt transmutation pink drawing glaze comprises the following components in parts by mass: 33-37 parts of potash feldspar, 9-11 parts of barium carbonate, 12-14 parts of kaolin, 4.5-5.5 parts of zinc oxide, 14-16 parts of dolomite, 9-11 parts of bone ash, 11-13 parts of talc and 4.5-5.5 parts of scarlet pigment. The glaze used by the matt fambe pink drawing glaze provided by the invention does not contain heavy metals such as lead, cadmium and the like, and has the advantages of environmental protection and no toxicity.
In the invention, the glaze of the matt fambe pink wiredrawing glaze preferably comprises the following components in parts by mass: 35 parts of potash feldspar, 10 parts of barium carbonate, 13 parts of kaolin, 5 parts of zinc oxide, 15 parts of dolomite, 10 parts of bone ash, 12 parts of talc and 5 parts of scarlet pigment.
In the invention, the alkali components in the glaze formula of the matt fambe pink wiredrawing glaze comprise potassium oxide, sodium oxide, zinc oxide, calcium oxide, magnesium oxide, barium carbonate and phosphorus hexaoxide, wherein the molar ratio of the potassium oxide, the sodium oxide, the zinc oxide, the calcium oxide, the magnesium oxide, the barium carbonate and the phosphorus hexaoxide is preferably 0.114: 0.03-0.05: 0.15-0.16: 0.22-0.23: 0.22-0.24: 0.16-0.17: 0.07-0.077, more preferably 0.114:0.038:0.152:0.227:0.229:0.164: 0.076; the ratio of the total amount of alkaline components in the glaze formula of the matt famille pink drawn glaze to the amount of alumina, silica and titanium dioxide is preferably 1: 0.16-0.18: 0.64-0.65: 0.09-0.10, and more preferably 1:0.167:0.644: 0.093.
The matt fambe pink wiredrawing glaze provided by the invention is pink regular stripe matt texture, and is beautiful and durable.
The invention also provides a preparation method of the matt fambe pink wiredrawing glaze, which comprises the following steps:
mixing glaze of the matt furnace transmutation pink wiredrawing glaze except the bright red pigment with water, and performing ball milling to obtain premixed slurry;
mixing the premixed slurry with a scarlet pigment to obtain glaze slurry;
adopting the glaze slurry to glaze the whole surface of the ceramic blank body to obtain a matt famille pink wiredrawing glaze blank body;
and oxidizing and sintering the matt furnace transmutation pink wiredrawing glaze blank to obtain the matt furnace transmutation pink wiredrawing glaze.
The glaze of the matt furnace transmutation pink wiredrawing glaze except the scarlet pigment is mixed with water and ball-milled to obtain the premixed slurry.
The invention has no special limit on the using amount of the water, can ensure that the ball milling is carried out smoothly, and a person skilled in the art can add a proper amount of water or a small amount of water according to the concentration of the glaze slurry to be prepared. In the embodiment of the invention, a small amount of water is preferably added, namely the mass ratio of the glaze of the matt furnace transmutation pink wiredrawing glaze except for the scarlet pigment to the water is preferably 100: 75-85, and more preferably 100: 80.
In the invention, the time for ball milling is preferably 16-20 h, and more preferably 18 h.
After the premixed slurry is obtained, the premixed slurry is mixed with the scarlet pigment to obtain the glaze slurry.
In the embodiment of the invention, after the premixed slurry is obtained, the scarlet pigment is preferably directly added into a ball mill containing the premixed slurry, and the ball milling is continued for 1-2 min.
After the mixing of the premixed slurry and the scarlet pigment is finished, the method preferably further comprises sieving, wherein the mesh number of a sieve used for sieving is preferably 150-170 meshes, and more preferably 160 meshes.
In the invention, the concentration of the glaze slurry is preferably 38-42 Baume degrees, and more preferably 40 Baume degrees. In the present invention, when the obtained slurry after sieving is out of the above range, the present invention preferably adjusts the concentration of the obtained slurry to obtain a glaze slurry of a desired concentration; in the embodiment of the present invention, since less water is used in preparing the premixed slurry, it is preferable to add water to the slurry obtained by sieving after the sieving to adjust the concentration of the slurry to a desired concentration.
After obtaining the glaze slurry, the invention adopts the glaze slurry to glaze the whole surface of the ceramic blank body to obtain the matt famille rose wiredrawing glaze blank body.
The glazing manner is not particularly limited in the present invention, and a conventional glazing manner may be adopted, and in the embodiment of the present invention, the glazing manner is preferably immersion glazing.
The invention can obtain the matt furnace transmutation pink wiredrawing glaze blank body by adopting one-time glazing, saves labor, has less glaze slurry consumption and saves material cost.
After the matt fambe pink drawing glaze blank body is obtained, the matt fambe pink drawing glaze blank body is subjected to oxidation sintering to obtain the matt fambe pink drawing glaze.
In the present invention, the oxidizing firing is preferably performed in an air atmosphere, and the oxidizing firing temperature is preferably 1230 to 1250 ℃, and more preferably 1240 ℃. In the present invention, the temperature rise rate of the oxidative sintering is not particularly limited, and the temperature of the oxidative sintering can be reached. In the invention, the fuel obtained by oxidizing and burning can be fully and completely burnt so as to reduce the generation of pollutants; in addition, the oxidizing sintering can be finished at low temperature, and the method has the advantages of environmental protection and low consumption.
After the completion of the oxidative firing, the resulting matt pinkish drawn glaze is preferably furnace cooled to room temperature in the present invention.
The invention will be described in detail with reference to the following examples, but they should not be construed as limiting the scope of the invention.
Example 1
(1) Weighing the glaze material according to the following weight parts:
35 parts of potash feldspar, 10 parts of barium carbonate, 13 parts of kaolin, 5 parts of zinc oxide, 15 parts of dolomite, 10 parts of bone ash, 12 parts of talc and 5 parts of scarlet pigment;
the glaze material comprises the following basic components in a molar ratio: a mixture of potassium oxide, sodium oxide, zinc oxide, calcium oxide, magnesium oxide, barium carbonate and diphosphorus hexaoxide at 0.114:0.038:0.152:0.227:0.229:0.164: 0.076; the ratio of the total amount of the basic components to the amount of the alumina, silica and titanium dioxide is 1:0.167:0.644: 0.093;
(2) mixing potash feldspar, barium carbonate, kaolin, zinc oxide, dolomite, bone ash and talc to obtain a raw material premix; mixing the raw material premix with water according to the mass ratio of 100:80, and performing ball milling for 18 hours to obtain premix slurry;
adding a bright red material into the premixed slurry, maintaining the rotating speed, continuing ball milling for 1min, and then sieving the obtained slurry with a 160-mesh sieve to obtain glaze slurry;
dipping the ceramic blank in the glaze slurry to obtain a matt furnace transmutation pink wiredrawing glaze blank;
and (3) heating the matt furnace transmutation pink drawing glaze blank body to 1240 ℃ in the air atmosphere, and then cooling the matt furnace transmutation pink drawing glaze blank body to room temperature along with a furnace to obtain the matt furnace transmutation pink drawing glaze.
The appearance of the matt pinkish glaze obtained in this example is shown in FIG. 1. As can be seen from FIG. 1, the matt furnace pink drawn glaze obtained in this example exhibited a pink regular striped matt texture, which was aesthetically pleasing and pleasing to the eye.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.

Claims (8)

1. The matt fambe pink drawing glaze is characterized in that a glaze of the matt fambe pink drawing glaze comprises the following components in parts by mass: 33-37 parts of potash feldspar, 9-11 parts of barium carbonate, 12-14 parts of kaolin, 4.5-5.5 parts of zinc oxide, 14-16 parts of dolomite, 9-11 parts of bone ash, 11-13 parts of talc and 4.5-5.5 parts of a scarlet pigment;
the alkali components in the glaze formula of the matt fambe pink wiredrawing glaze comprise potassium oxide, sodium oxide, zinc oxide, calcium oxide, magnesium oxide, barium carbonate and phosphorus hexaoxide, wherein the molar ratio of the potassium oxide, the sodium oxide, the zinc oxide, the calcium oxide, the magnesium oxide, the barium carbonate and the phosphorus hexaoxide is 0.114: 0.03-0.05: 0.15-0.16: 0.22-0.23: 0.22-0.24: 0.16-0.17: 0.07-0.077; the ratio of the total amount of alkaline components in the glaze formula of the matt famille pink wiredrawing glaze to the amount of alumina, silica and titanium dioxide is 1: 0.16-0.18: 0.64-0.65: 0.09-0.10;
the preparation method of the matt fambe pink wiredrawing glaze comprises the following steps:
mixing glaze of the matt furnace transmutation pink wiredrawing glaze except the bright red pigment with water, and performing ball milling to obtain premixed slurry;
mixing the premixed slurry with a scarlet pigment to obtain glaze slurry;
glazing the whole surface of the ceramic blank by adopting the glaze slurry to obtain a matt fambe pink wiredrawing glaze blank;
oxidizing and sintering the matt fambe pink drawing glaze blank body to obtain matt fambe pink drawing glaze;
the temperature of the oxidation sintering is 1230-1250 ℃;
and after the premixed slurry and the scarlet pigment are mixed, sieving is further carried out, and the mesh number of a sieve used for sieving is 150-170 meshes.
2. The matt transmutation pink drawing glaze according to claim 1, wherein the glaze of the matt transmutation pink drawing glaze comprises the following components in parts by mass: 35 parts of potash feldspar, 10 parts of barium carbonate, 13 parts of kaolin, 5 parts of zinc oxide, 15 parts of dolomite, 10 parts of bone ash, 12 parts of talc and 5 parts of scarlet pigment.
3. The matt-fammed pink drawn glaze according to claim 1, wherein the molar ratio of potassium oxide, sodium oxide, zinc oxide, calcium oxide, magnesium oxide, barium carbonate and phosphorus hexaoxide is 0.114:0.038:0.152:0.227:0.229:0.164: 0.076; the ratio of the total amount of the basic components to the amount of the alumina, silica, titania is 1:0.167:0.644: 0.093.
4. A method for preparing a matt fammed pink drawn glaze according to any one of claims 1 to 3, comprising the steps of:
mixing glaze of the matt furnace transmutation pink wiredrawing glaze except the bright red pigment with water, and performing ball milling to obtain premixed slurry;
mixing the premixed slurry with a scarlet pigment to obtain glaze slurry;
glazing the whole surface of the ceramic blank by adopting the glaze slurry to obtain a matt fambe pink wiredrawing glaze blank;
and oxidizing and sintering the matt furnace transmutation pink wiredrawing glaze blank to obtain the matt furnace transmutation pink wiredrawing glaze.
5. The method according to claim 4, wherein the oxidizing firing is performed in an air atmosphere.
6. The method according to claim 4, wherein the glaze slurry has a concentration of 38 to 42 Baume degrees.
7. The preparation method of claim 4, wherein the ball milling time is 16-20 h.
8. The preparation method according to claim 4, characterized in that the mass ratio of the glaze material to water of the matt kiln pink wire-drawing glaze except for the scarlet pigment is 100: 75-85.
CN202010134546.1A 2020-03-02 2020-03-02 Dull transmutation pink wiredrawing glaze and preparation method thereof Active CN113336574B (en)

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