CN109384389A - A kind of manufacturing method of Antique Imitation Tiles clear frit - Google Patents
A kind of manufacturing method of Antique Imitation Tiles clear frit Download PDFInfo
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- CN109384389A CN109384389A CN201811193662.XA CN201811193662A CN109384389A CN 109384389 A CN109384389 A CN 109384389A CN 201811193662 A CN201811193662 A CN 201811193662A CN 109384389 A CN109384389 A CN 109384389A
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- glaze
- clear frit
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- imitation tiles
- antique imitation
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 56
- 230000008569 process Effects 0.000 claims abstract description 54
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 34
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002002 slurry Substances 0.000 claims abstract description 22
- 238000007641 inkjet printing Methods 0.000 claims abstract description 21
- 238000000498 ball milling Methods 0.000 claims abstract description 18
- 239000011787 zinc oxide Substances 0.000 claims abstract description 17
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 16
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims abstract description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims abstract description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000001035 drying Methods 0.000 claims abstract description 12
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000010304 firing Methods 0.000 claims abstract description 11
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000292 calcium oxide Substances 0.000 claims abstract description 10
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 10
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 10
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 8
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000032683 aging Effects 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 239000011734 sodium Substances 0.000 claims abstract description 7
- 239000006004 Quartz sand Substances 0.000 claims abstract description 6
- 238000005202 decontamination Methods 0.000 claims abstract description 6
- 230000003588 decontaminative effect Effects 0.000 claims abstract description 6
- 235000013312 flour Nutrition 0.000 claims abstract description 6
- 239000004615 ingredient Substances 0.000 claims abstract description 6
- 229910052742 iron Inorganic materials 0.000 claims abstract description 6
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011265 semifinished product Substances 0.000 claims abstract description 6
- 238000007873 sieving Methods 0.000 claims abstract description 6
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims abstract description 6
- DQMUQFUTDWISTM-UHFFFAOYSA-N O.[O-2].[Fe+2].[Fe+2].[O-2] Chemical compound O.[O-2].[Fe+2].[Fe+2].[O-2] DQMUQFUTDWISTM-UHFFFAOYSA-N 0.000 claims abstract description 5
- CSSYLTMKCUORDA-UHFFFAOYSA-N barium(2+);oxygen(2-) Chemical compound [O-2].[Ba+2] CSSYLTMKCUORDA-UHFFFAOYSA-N 0.000 claims abstract description 5
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 5
- 239000000470 constituent Substances 0.000 claims abstract description 5
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 5
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims abstract description 5
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 5
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910001950 potassium oxide Inorganic materials 0.000 claims abstract description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910001948 sodium oxide Inorganic materials 0.000 claims abstract description 5
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 5
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 5
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract 3
- 230000005484 gravity Effects 0.000 claims description 6
- 239000010456 wollastonite Substances 0.000 claims description 5
- 229910052882 wollastonite Inorganic materials 0.000 claims description 5
- 235000013339 cereals Nutrition 0.000 claims description 3
- 239000004575 stone Substances 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 4
- 229910052782 aluminium Inorganic materials 0.000 claims 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 4
- 229910052760 oxygen Inorganic materials 0.000 claims 4
- 239000001301 oxygen Substances 0.000 claims 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 12
- 230000000149 penetrating effect Effects 0.000 abstract description 6
- 238000004806 packaging method and process Methods 0.000 abstract description 4
- 238000003860 storage Methods 0.000 abstract description 4
- 239000000454 talc Substances 0.000 abstract description 4
- 235000012222 talc Nutrition 0.000 abstract description 4
- 229910052623 talc Inorganic materials 0.000 abstract description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 30
- 239000000919 ceramic Substances 0.000 description 15
- 230000000694 effects Effects 0.000 description 12
- 239000011449 brick Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000005034 decoration Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 230000003373 anti-fouling effect Effects 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000003670 easy-to-clean Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical group [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
- Finishing Walls (AREA)
Abstract
A kind of manufacturing method of Antique Imitation Tiles clear frit, process flow: sorting → debugging formula → ingredient → ball milling → except iron → sieving decontamination → glaze slurry is aging → draw glaze glazing line → adjusting glaze slip technological parameter → glaze cabinet to apply clear frit → inkjet printing → glaze cabinet and apply drying → high temperature firing → semi-finished product process → sorting → packaging → storage before clear frit (or dry granular) → kiln；The weight percent of its primary raw material: 5~10% zinc oxide of potassium sodium mountain flour 30~45% quartz sand, 0~8% aluminium oxide, 5~12% delustering agent, 10~15% kaolin, 3~5% silicon ash 8~12% burns 3~8% sodium tripolyphosphate of talcum, 0.5%~0.8% sodium cellulose glycolate (CMC) 0.1~0.5%；Its chemical constituent: 10~15% aluminum oxide AL of igloss (LOSS)2O315~18% silica SiO240~50% di-iron trioxide Fe2O30.45% calcium oxide CaO of <, 1~6% magnesia MgO, 1~6% potassium oxide K21~4% sodium oxide molybdena Na of O21~5% titanium dioxide TiO of O20.35% zirconium dioxide ZrO of <20~6% strontium oxide strontia SrO of < 0.015% barium monoxide BaO, 10~20% zinc oxide ZnO, 0~2.5% phosphorus pentoxide P2O50~2.5%.Glaze of the present invention one integrated mass in conjunction with green body, texture are penetrating, gentle soft.
Description
Technical field
The present invention relates to a kind of manufacturing method of brick glaze modelled after an antique, in particular to a kind of manufacturing method of Antique Imitation Tiles clear frit.
Background technique
China is the Production of Ceramics big country in the world, household china and decorative ceramics product, the world yield Jun Ju for building bathroom ceramics
It is the first.
Ceramic antique bricks are most popular kinds in building decoration, with continuing for building decoration upsurge, ceramic antique bricks
Design incorporated more artistic elements and scientific and technological content is increasing.
Ceramic antique bricks in the decorative applications of people from parlor to kitchen, toilet, balcony and wall, the room on ground it is empty
Between, and due to the cost performance of ceramic antique bricks, its enabling in public is made more to account for the significant proportion of ceramic tile.
Currently, ceramic antique bricks production generallys use the production of simple glaze technology, but due to technology level,
Appointed condition and raw material limitation, product in the market is almost stereotyped, and pattern and quality effect homogeneity are serious, pattern letter
Single, color is dull.
With economical fast development and continuous improvement of people's living standards, consumer starts the decoration to indoor environment
Effect has requirements at the higher level, and the color that consumer prefers Antique Imitation Tiles is richer, and pattern is more generous and naturally true to nature, and texture is more like big
The object of nature.
A kind of ceramic whiteware high-performance glaze and preparation method thereof is disclosed in the prior art, and ceramic whiteware high-performance glaze is by such as
Lower component composition: water mill potassium feldspar, kaolin burn talcum, dolomite, barium carbonate, calcining zinc oxide, water mill quartz, and glaze is steady
Determine agent, coefficient of expansion regulator.The production method of ceramic whiteware high-performance glaze includes the following steps: stock, aging and glaze firing.
The melting temperature of the glaze is high, and its melt temperature scope is wide, reaches 1290~1330 DEG C, glaze is by kiln temperature influence of fluctuations
Small, glaze pin hole is few, and glaze is bright smooth, and glaze superficial expansivity is adjustable, so that ceramic body surface increases a stress, reaches
In 200 DEG C~20 DEG C indehiscent effects of rapid heat cycle.
A kind of clear frit and manufacture craft are also disclosed in the prior art, by potassium feldspar, Longyan kaolin, quartz, oxidation
Zinc and barium carbonate form by mass percentage, and above-mentioned raw materials are uniformly mixed to and are added water, are sufficiently stirred, and mesh screen is crossed after ball milling,
Clear frit glaze is applied on the porcelain billet surface baked, is sent into heating-up furnace and fires, fired through staged high temperature three times, kiln discharge is cooling
, the transparent glaze formula is reasonable, and the glazing effect for the clear frit produced is stablized, the exquisitely carved glazing effect of crystal is showed,
Indefectible, homogeneous exquisiteness is high-quality, beautiful and generous.
Above-mentioned clear frit manufacture craft is complicated, energy consumption is high, and glaze texture is undesirable, and glaze separator bar in conjunction with green body is bright
It is aobvious, do not accomplish the seamless combination of glaze and green body, is unable to satisfy the demand of client.
Summary of the invention
It is an object of the invention to overcome the deficiencies of existing technologies, provide a kind of texture it is natural, it is gentle it is penetrating, with green body knot
Close the manufacturing method of the Antique Imitation Tiles clear frit of one integrated mass.
The purpose of the present invention is what is be achieved through the following technical solutions:
A kind of manufacturing method of Antique Imitation Tiles clear frit, the process flow of the manufacturing method include:
Glaze glazing line is drawn in sorting → debugging formula → ingredient → ball milling → except iron → sieving decontamination → glaze slurry is aging →
→ adjust drying → high temperature firing → semi-finished product process → sorting → packaging before glaze slip technological parameter → inkjet printing → kiln
→ storage；
Glaze cabinet, which is added, between the adjusting glaze slip technological parameter process and inkjet printing process applies clear frit process；
Add that glaze cabinet is secondary to apply clear frit process before the inkjet printing process and kiln between drying process；
The weight percent of the Antique Imitation Tiles clear frit primary raw material are as follows: 30~45% quartz sand 0~8% of potassium sodium mountain flour
5~10% zinc oxide of aluminium oxide 5~12% delustering agent, 10~15% kaolin, 3~5% wollastonite 8~12%, which is burnt, to be slided
3~8% sodium tripolyphosphate of stone, 0.5%~0.8% sodium cellulose glycolate (CMC) 0.1~0.5%；
The mass percent of the chemical constituent of the Antique Imitation Tiles clear frit primary raw material are as follows: igloss (LOSS) 10~15%
Aluminum oxide AL2O315~18% silica SiO240~50% di-iron trioxide Fe2O30.45% calcium oxide of <
1~6% magnesia MgO of CaO, 1~6% potassium oxide K21~4% sodium oxide molybdena Na of O2The titanium dioxide of O1~5% TiO2<
0.35% zirconium dioxide ZrO20.015% barium monoxide BaO of <, 10~20% zinc oxide ZnO, 0~6% strontium oxide strontia SrO0~
2.5% phosphorus pentoxide P2O50~2.5%.
A kind of manufacturing method of Antique Imitation Tiles clear frit, the process flow of the manufacturing method include:
Glaze glazing line is drawn in sorting → debugging formula → ingredient → ball milling → except iron → sieving decontamination → glaze slurry is aging →
→ adjust drying → high temperature firing → semi-finished product process → sorting → packaging before glaze slip technological parameter → inkjet printing → kiln
→ storage；
Glaze cabinet, which is added, between the adjusting glaze slip technological parameter process and inkjet printing process applies clear frit process；
Glaze cabinet is added before the inkjet printing process and kiln between drying process and applies transparent dry granular process；
The weight percent of the Antique Imitation Tiles clear frit primary raw material are as follows: 30~45% quartz sand 0~8% of potassium sodium mountain flour
5~10% zinc oxide of aluminium oxide 5~12% delustering agent, 10~15% kaolin, 3~5% wollastonite 8~12% is burnt
3~8% sodium tripolyphosphate of talcum, 0.5%~0.8% sodium cellulose glycolate (CMC) 0.1~0.5%；
The mass percent of the chemical constituent of the Antique Imitation Tiles clear frit primary raw material are as follows: igloss (LOSS) 10~15%
Aluminum oxide AL2O315~18% silica SiO240~50% di-iron trioxide Fe2O30.45% calcium oxide of <
1~6% magnesia MgO of CaO, 1~6% potassium oxide K21~4% sodium oxide molybdena Na of O2The titanium dioxide of O1~5% TiO2<
0.35% zirconium dioxide ZrO20.015% barium monoxide BaO of <, 10~20% zinc oxide ZnO, 0~6% strontium oxide strontia SrO0~
2.5% phosphorus pentoxide P2O50~2.5%.
Glaze slurry biodiversity percentage in the ball milling process are as follows: 30%~34%.
Glaze slurry fineness (250 mesh screen residue) weight percent in the ball milling process are as follows: 0.2~0.7%.
Glaze slurry specific gravity in the ball milling process are as follows: 1.70~1.80g/cm3。
Glaze flow rate of slurry in the ball milling process are as follows: 30~50S.
Ball-milling Time (based on 5 tons of balls of standard) the < 7h.
Glaze slurry specific gravity in the glazing process are as follows: 1.40~1.50g/cm3。
Glaze spraying glaze slurry weight is (500x500 disk): 100~150g/ disk in the glazing process.
Adobe temperature in the glazing process are as follows: 70~85 DEG C.
Adobe temperature in the inkjet printing process are as follows: 40~65 DEG C.
It is described to apply dry granular slurry specific gravity in transparent dry granular process are as follows: 1.30~1.50g/cm3。
The spray drying grain slurry weight of applying in transparent dry granular process is (500x500 disk): 50~80g/ disk.
Drying temperature before the kiln: 150~250 DEG C, arid cycle before kiln: 3~5min.
The firing temperature: 1180~1250 DEG C.
The firing period: 50~90min.
The present invention by adopting the above technical scheme after can be had the advantages that:
1, creative.The crystalistic sense that the present invention is directed to traditional Antique Imitation Tiles glaze is not strong, influences the defect of pattern expressive force, selects
With the glaze raw material of the high grade of transparency of high potassium, sodium content, glaze formula of the invention 30~45% quartz sand 0 of potassium sodium mountain flour~
8%, 5~10% zinc oxide of aluminium oxide 5~12% delustering agent, 10~15% kaolin, 3~5% wollastonite 8~12% burns talcum 3
In the range of 0.5%~0.8% sodium cellulose glycolate of~8% sodium tripolyphosphate (CMC) 0.1~0.5%, gained glaze is had more
Permeability makes pattern have more expressive force, the soft and moist nature of glaze texture.
2, good product performance.The present invention is directed to traditional Antique Imitation Tiles using the production technology for applying common overglaze+inkjet printing, produces
Product base glaze separates obviously, decorates unnatural defect.The Antique Imitation Tiles produced using Antique Imitation Tiles clear frit of the invention, are taken and are applied
Bright glaze+inkjet printing+combination process for applying clear frit (or dry granular) makes product pattern have more three-dimensional sense；Due in the present invention
The permeability of clear frit is strong, can eliminate the separation of product base glaze, make glaze one integrated mass in conjunction with green body, keep product texture closer
It is natural.
3, good product quality.In the present invention texture of clear frit it is natural, it is gentle it is penetrating, in conjunction with green body one integrated mass, and
Using ink-jet technology, the native texture that product is fine and smooth, high-grade is assigned, product pattern is fine and smooth, the abundant and naturally, penetrating temperature of texture
Moisten and soft.Both the brief, random of Antique Imitation Tiles style is protruded, the products characteristics such as pattern is changeable, and when meeting consumer to the modern times
Pursuit still, the indoor decoration grade of General Promotion and effect；Product has wear-resisting, anti-dirt-proof simultaneously, and anti-soda acid corrodes, low
Water absorption rate, green, the performance characteristics of safety of low-activity, thus the welcome by the numerous consumer groups.
4, energy-saving.The present invention is to reach the texture of Antique Imitation Tiles, by well-designed formula, selects high potassium, sodium content
The high grade of transparency glaze raw material, and the partially short working condition of raw material Ball-milling Time is all realized using superfine powder, by
Being reduced to for 12 hours 7 hours or less (based on 5 tons of balls of standard) for common glaze Ball-milling Time, can save energy 40%；And component design is suitable
Fast burning is closed, production yields is improved, reduces the consumption of fuel, reached certain consumption reduction effect, can save energy 5~10%.
5, health environment-friendly.Using the product of Antique Imitation Tiles clear frit of the present invention manufacture in the premise for guaranteeing treatment effect texture
Under, the introducing of strict control radiological materials, it is ensured that meet the standard of the A class green building material of national standard (GB2001-6566).
Product produced by the present invention, selected high-quality raw material, well-designed formula make glaze reach hard wear resistant, anti-pollution
Performance, anti-soda acid, low water absorption, high breaking resistance, green, the safe and environment-friendly quality product of low-activity ensure consumer
Health.
6, texture is mellow and full, and sense of touch is fine and smooth.Clear frit+ink-jet is used using brick product modelled after an antique manufactured by clear frit of the present invention
The production technology of printing+dry granular (clear frit), product surface texture is mellow and full, and sense of touch exquisiteness is soft and moist, and the product that Antique Imitation Tiles are presented is special
Color.
7, product decoration is good.InkJet printing processes are used using brick product modelled after an antique manufactured by clear frit of the present invention, are produced
Product pattern texture is clear and abundant, and texture is penetrating and gentle, and stereovision is three-dimensional, and overall effect is high-grade elegant.And existing common skill
The product pattern of art manufacture is not fine and smooth, and unintelligible, texture is poor.
8, easy to use, easily arrange.Using brick product modelled after an antique manufactured by clear frit of the present invention since brick body consistency is high,
The densified sintering product of glaze, to make spot that can not penetrate into, antifouling property is strong, easy to clean, and low water suction, antifouling in use
It is good, anti-aging, more easy to clean and maintenance.
9, durable.Stablized using brick product modelled after an antique physical and chemical performance manufactured by clear frit of the present invention, acid and alkali-resistance
It is anti-to hold intensity height, by time environmental influence very little, can keep for a long time such as new feeling, long service life.
10, applied widely.It is naturally changeable using Antique Imitation Tiles product design style manufactured by clear frit of the present invention, it is luicd and elegant
Free from vulgarity, natural, graceful and poised elegance, texture is gentle and fine and smooth, caters to consumer for the aesthetic pursuit of back to nature, is applicable to household paving
Any space of patch, luxury clubhouse, star hotel, office building, the ground such as public space, in building, exterior wall etc..Also may be used simultaneously
It is pieced together by cutting, the techniques such as engraving keep space performance more perfect, beautiful.Not by use environment conditionality, can be widely applied
In various inner-outer walls and ground decoration.
11, market economy remarkable benefit.Naturally beautiful, the matter using Antique Imitation Tiles product appearance manufactured by clear frit of the present invention
Sense is high-grade, since its own has the advantage that the high demand of today's society of adapting to, it is contemplated that and profit increases by 80% than common ceramic tile,
Benefit is evident for market economy.
Specific embodiment
Below in conjunction with specific embodiment, invention is further described in detail: table 1
Table 2
A kind of process flow of the manufacturing method of Antique Imitation Tiles clear frit includes:
Glaze glazing line is drawn in sorting → debugging formula → ingredient → ball milling → except iron → sieving decontamination → glaze slurry is aging →
→ adjust drying → high temperature firing → semi-finished product process → sorting → packaging before glaze slip technological parameter → inkjet printing → kiln
→ storage；
Glaze cabinet, which is added, between the adjusting glaze slip technological parameter process and inkjet printing process applies clear frit process；
Add that glaze cabinet is secondary to apply clear frit (or transparent dry granular) work before the inkjet printing process and kiln between drying process
Sequence.
The selected high-quality raw material of the present invention, well-designed formula, glaze texture are natural, gentle penetrating, muddy in conjunction with green body
So one, using clear frit product low water absorption of the present invention, glaze hard wear resistant, antifouling property, resistance to acid and alkali, high cracking resistance are strong
Degree, low-activity are superior to common tile product.
It is reachable using clear frit Antique Imitation Tiles performance made of manufacture craft of the invention: product water absorption rate average value≤
0.03%, monolithic value≤0.05%, glossiness≤6, wear resistance 116~131, External Exposure Index 0.39, Outreach services 0.69,
Performance parameter ratio is better than common ceramic tile.
The prior art can be used in other Processes and apparatus of the invention.
Highly preferred embodiment of the present invention has illustrated, and those skilled in the art make further according to the present invention
Expansion is each fallen among protection scope of the present invention.
Claims (11)
1. a kind of manufacturing method of Antique Imitation Tiles clear frit, the process flow of the manufacturing method include:
Glaze glazing line → tune is drawn in sorting → debugging formula → ingredient → ball milling → except iron → sieving decontamination → glaze slurry is aging →
Drying → high temperature firing → semi-finished product process → sorting → is packed → is entered before section glaze slip technological parameter → inkjet printing → kiln
Library；It is characterized by:
Glaze cabinet, which is added, between the adjusting glaze slip technological parameter process and inkjet printing process applies clear frit process；
Add that glaze cabinet is secondary to apply clear frit process before the inkjet printing process and kiln between drying process；
The weight percent of the Antique Imitation Tiles clear frit primary raw material are as follows: 30~45% quartz sand of potassium sodium mountain flour, 0~8% oxygen
Change 5~12% delustering agent of aluminium, 10~15% kaolin, 5~10% zinc oxide, 3~5% wollastonite 8~12% and burns cunning
3~8% sodium tripolyphosphate of stone, 0.5%~0.8% sodium cellulose glycolate (CMC) 0.1~0.5%；
The mass percent of the chemical constituent of the Antique Imitation Tiles clear frit primary raw material are as follows: 10~15% 3 oxygen of igloss (LOSS)
Change two aluminium AL2O315~18% silica SiO240~50% di-iron trioxide Fe2O30.45% calcium oxide CaO 1 of <
1~6% potassium oxide K of~6% magnesia MgO21~4% sodium oxide molybdena Na of O21~5% titanium dioxide TiO of O2<
0.35% zirconium dioxide ZrO20.015% barium monoxide BaO of <, 10~20% zinc oxide ZnO, 0~6% strontium oxide strontia SrO 0
~2.5% phosphorus pentoxide P2O50~2.5%.
2. a kind of manufacturing method of Antique Imitation Tiles clear frit, the process flow of the manufacturing method include:
Glaze glazing line → tune is drawn in sorting → debugging formula → ingredient → ball milling → except iron → sieving decontamination → glaze slurry is aging →
Drying → high temperature firing → semi-finished product process → sorting → is packed → is entered before section glaze slip technological parameter → inkjet printing → kiln
Library；It is characterized by:
Glaze cabinet, which is added, between the adjusting glaze slip technological parameter process and inkjet printing process applies clear frit process；
Glaze cabinet is added before the inkjet printing process and kiln between drying process and applies transparent dry granular process；
The weight percent of the Antique Imitation Tiles clear frit primary raw material are as follows: 30~45% quartz sand of potassium sodium mountain flour, 0~8% oxygen
Change 5~12% delustering agent of aluminium, 10~15% kaolin, 5~10% zinc oxide, 3~5% wollastonite 8~12% and burns cunning
3~8% sodium tripolyphosphate of stone, 0.5%~0.8% sodium cellulose glycolate (CMC) 0.1~0.5%；
The mass percent of the chemical constituent of the Antique Imitation Tiles clear frit primary raw material are as follows: 10~15% 3 oxygen of igloss (LOSS)
Change two aluminium AL2O315~18% silica SiO240~50% di-iron trioxide Fe2O30.45% calcium oxide CaO 1 of <
1~6% potassium oxide K of~6% magnesia MgO21~4% sodium oxide molybdena Na of O21~5% titanium dioxide TiO of O2<
0.35% zirconium dioxide ZrO20.015% barium monoxide BaO of <, 10~20% zinc oxide ZnO, 0~6% strontium oxide strontia SrO 0
~2.5% phosphorus pentoxide P2O50~2.5%.
3. a kind of manufacturing method of Antique Imitation Tiles clear frit according to claim 1 or 2, it is characterised in that: the ball milling work
Glaze slurry biodiversity percentage in sequence are as follows: 30%~34%.
4. a kind of manufacturing method of Antique Imitation Tiles clear frit according to claim 1 or 2, it is characterised in that: the ball milling work
Glaze slurry fineness (250 mesh screen residue) weight percent in sequence are as follows: 0.2~0.7%.
5. a kind of manufacturing method of Antique Imitation Tiles clear frit according to claim 1 or 2, it is characterised in that: the ball milling work
Glaze slurry specific gravity in sequence are as follows: 1.70~1.80g/cm3, glaze flow rate of slurry in the ball milling process are as follows: 30~50S.
6. a kind of manufacturing method of Antique Imitation Tiles clear frit according to claim 1 or 2, it is characterised in that: the glazing work
Glaze slurry specific gravity in sequence are as follows: 1.40~1.50g/cm3, glaze spraying glaze slurry weight is (500x500 in the glazing process
Disk): 100~150g/ disk.
7. a kind of manufacturing method of Antique Imitation Tiles clear frit according to claim 1 or 2, it is characterised in that: the glazing work
Adobe temperature in sequence are as follows: 70~85 DEG C, adobe temperature in inkjet printing process are as follows: 40~65 DEG C.
8. a kind of manufacturing method of Antique Imitation Tiles clear frit according to claim 1 or 2, it is characterised in that: done before the kiln
Dry temperature: 150~250 DEG C, arid cycle before kiln: 3~5min.
9. a kind of manufacturing method of Antique Imitation Tiles clear frit according to claim 1 or 2, it is characterised in that: the firing temperature
Degree: 1180~1250 DEG C, the firing period: 50~90min.
10. a kind of manufacturing method of Antique Imitation Tiles clear frit according to claim 2, it is characterised in that: described to apply transparent dry
Dry granular slurry specific gravity in grain process are as follows: 1.30~1.50g/cm3。
11. a kind of manufacturing method of Antique Imitation Tiles clear frit according to claim 2, it is characterised in that: described to apply transparent dry
Dry granular slurry weight is (500x500 disk): 50~80g/ disk in grain process.
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| CN111439988A (en) * | 2020-04-06 | 2020-07-24 | 广东昊晟陶瓷有限公司 | High-whiteness glazed tile and preparation method thereof |
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| CN114195496A (en) * | 2021-11-29 | 2022-03-18 | 广东德利丰家居有限公司 | Preparation method of terrazzo-like ceramic plate with concave-convex texture and ceramic plate |
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| CN112876077A (en) * | 2021-03-05 | 2021-06-01 | 广东新润成陶瓷有限公司 | Protective glaze for matte antique brick, antique brick and preparation method of protective glaze |
| CN112876077B (en) * | 2021-03-05 | 2022-05-27 | 广东新润成陶瓷有限公司 | Protective glaze for matte antique brick, antique brick and preparation method of protective glaze |
| CN114195496A (en) * | 2021-11-29 | 2022-03-18 | 广东德利丰家居有限公司 | Preparation method of terrazzo-like ceramic plate with concave-convex texture and ceramic plate |
| CN114105476A (en) * | 2021-12-18 | 2022-03-01 | 新明珠集团股份有限公司 | Polishing-free glaze, ceramic tile and preparation method thereof |
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