CN109535878A - One kind is containing colorful stone-like coating of sand and preparation method thereof - Google Patents
One kind is containing colorful stone-like coating of sand and preparation method thereof Download PDFInfo
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- CN109535878A CN109535878A CN201811521783.2A CN201811521783A CN109535878A CN 109535878 A CN109535878 A CN 109535878A CN 201811521783 A CN201811521783 A CN 201811521783A CN 109535878 A CN109535878 A CN 109535878A
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- base paint
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- pregel
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- 239000011248 coating agent Substances 0.000 title claims abstract description 65
- 238000000576 coating method Methods 0.000 title claims abstract description 65
- 239000004576 sand Substances 0.000 title claims abstract description 52
- 238000002360 preparation method Methods 0.000 title claims abstract description 30
- 239000003973 paint Substances 0.000 claims abstract description 61
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 45
- 150000001412 amines Chemical class 0.000 claims abstract description 36
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 36
- 239000003755 preservative agent Substances 0.000 claims abstract description 34
- 230000002335 preservative effect Effects 0.000 claims abstract description 34
- 239000007788 liquid Substances 0.000 claims abstract description 33
- 239000000839 emulsion Substances 0.000 claims abstract description 31
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000005469 granulation Methods 0.000 claims abstract description 27
- 230000003179 granulation Effects 0.000 claims abstract description 27
- 229920002678 cellulose Polymers 0.000 claims abstract description 21
- 235000010980 cellulose Nutrition 0.000 claims abstract description 21
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 239000000080 wetting agent Substances 0.000 claims abstract description 19
- 239000000945 filler Substances 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 239000006185 dispersion Substances 0.000 claims description 25
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 24
- 239000002562 thickening agent Substances 0.000 claims description 20
- -1 alcohol ester Chemical class 0.000 claims description 14
- 238000002156 mixing Methods 0.000 claims description 13
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 claims description 9
- 239000003086 colorant Substances 0.000 claims description 9
- 239000003112 inhibitor Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 4
- 239000012071 phase Substances 0.000 claims description 3
- 238000003860 storage Methods 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 5
- 239000004579 marble Substances 0.000 abstract description 4
- 239000002244 precipitate Substances 0.000 abstract description 4
- 238000005253 cladding Methods 0.000 abstract description 2
- 239000002585 base Substances 0.000 description 66
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 40
- 239000000047 product Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 9
- 239000013068 control sample Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 6
- 239000004575 stone Substances 0.000 description 6
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical group CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 4
- 238000013329 compounding Methods 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- 241000276489 Merlangius merlangus Species 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 239000000440 bentonite Substances 0.000 description 3
- 229910000278 bentonite Inorganic materials 0.000 description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003906 humectant Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 1
- JCTXKRPTIMZBJT-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,3-diol Chemical compound CC(C)C(O)C(C)(C)CO JCTXKRPTIMZBJT-UHFFFAOYSA-N 0.000 description 1
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical group CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229910001051 Magnalium Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 229940097037 decylene glycol Drugs 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- ICUTUKXCWQYESQ-UHFFFAOYSA-N triclocarban Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 ICUTUKXCWQYESQ-UHFFFAOYSA-N 0.000 description 1
- 229960001325 triclocarban Drugs 0.000 description 1
- 235000013618 yogurt Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses one kind containing colorful stone-like coating of sand and preparation method thereof, is related to building coating technical field.The raw material of stone-like coating includes granulation liquid and continuous phase, and the mass ratio of granulation liquid and continuous phase is (60-80): (40-20), and the granulation liquid includes color-mixed base paint and sand, and the mass ratio of the color-mixed base paint and sand is 100:(50-80)；The color-mixed base paint includes following components in percentage by weight: hydrophobically modified celluloses 0.8-1.2%；Defoaming agent 0.2-0.4%；Wetting agent 0.2-0.4%；Coalescing agent 0.5-0.7%；Filler 10-15%；Multifunction amine auxiliary agent 0.1-0.2%；Preservative 0.3-0.5%；Acrylic emulsion 20-30%；Mill base 1-5%；Pregel 8-12%；Surplus is water.After cured later of the present invention film forming, color spot is clear, true to nature, has the verisimilitude of the lithotomes such as cladding marble coated on exterior wall, embody building it is muddy as day at decorative effect；The present invention is by choosing component and controlling the proportion of each component so that stone-like coating storage stability is good, storage 6 months it is not stratified, do not precipitate.
Description
Technical field
The present invention relates to building coating technical field, more specifically, it relates to it is a kind of containing the colorful stone-like coating of sand and its
Preparation method.
Background technique
Imitation stone lacquer is that a kind of decorative effect exactly likes marble, granitic thick matter exterior wall decorating coating.Mainly using various
The particle of color is formulated.Building after imitation stone lacquer finishing, has natural true natural colour, give it is graceful and
Humorous, serious aesthetic feeling.It is suitable for the indoor and outdoor decoration of all kinds of buildings, especially decorates on curved-surface building object, Ke Yishou
To vivid, the effect of back to nature.Imitation stone lacquer has fire prevention, waterproof, acid and alkali-resistance, anti-pollution, nontoxic, tasteless, bonding force
By force, the features such as will never fade, can effectively stop extraneous adverse circumstances and corrode building, extends the service life of building.
A kind of rock colored stone sheet stone-like coating is disclosed in the Chinese invention patent of Publication No. CN106433359A, by
The each component of following weight percent is made: silicone acrylic emulsion 26-38%, venamul 1-3%, polyaminoester emulsion 2-
5%, decylene glycol ester 1.7-2.2%, 2,2,4- trimethylpentanediol -1,3 mono isobutyrate 0.8-1.5%, propylene glycol 1-2%,
The carboxymethyl chitosan acetum 0.5-2% of deionized water 20-30%, 1.5wt%, trichlorocarbanilide 0.1-0.2%, sulphur
Sour polysaccharide 0.05-0.1%, defoaming agent 0.1-0.15%, PH regulator 0.1-0.2%, thickener 1-3%, sliver 25-
30%.
Above-mentioned patent is using sliver as color spot, and sliver is easy emersion coating in spraying, and the color spot formed is easy drift
It floats on exterior coating, the flexible vividness of color spot is poor, causes its fidelity poor.
Summary of the invention
In view of the deficienciess of the prior art, the purpose of the present invention one is to provide a kind of colorful stone-like coating containing sand,
Have the advantages that color spot is clear, true to nature.
The purpose of the present invention two is to provide a kind of preparation method of colorful stone-like coating containing sand, clear with color spot,
Advantage true to nature.
To achieve the above object one, the present invention provides the following technical scheme that
A kind of colorful stone-like coating containing sand, raw material include granulation liquid and continuous phase, and the mass ratio of granulation liquid and continuous phase is
(60-80): (40-20), the granulation liquid include color-mixed base paint and sand, and the mass ratio of the color-mixed base paint and sand is
100:(50-80)；The base paint includes following components in percentage by weight:
Hydrophobically modified celluloses 0.8-1.2%；
Defoaming agent 0.2-0.4%；
Wetting agent 0.2-0.4%；
Coalescing agent 0.5-0.7%；
Filler 10-15%；
Multifunction amine auxiliary agent 0.1-0.2%；
Preservative 0.3-0.5%；
Acrylic emulsion 20-30%；
Mill base 1-5%；
Pregel 8-12%；
Surplus is water.
By using above-mentioned technical proposal, the present invention mixes colours to base paint using mill base, hydrophobically modified celluloses, profit
After humectant and pregel are used in compounding, sand and color-mixed base paint can be made to form thick fluid, advantageously formed independent
Color spot avoids mill base dispersion and colour mixture；Coalescing agent and acrylic emulsion are conducive to color spot cured later film forming, color spot is clear,
It is true to nature；And color-mixed base paint storage stability is good, storage 6 months it is not stratified, do not precipitate.
Further preferably, the pregel includes following components in percentage by weight:
Preservative 0.1-0.3%；
Aluminium-magnesium silicate 6-10%；
Surplus is water.
By using above-mentioned technical proposal, aluminium-magnesium silicate has unique three-dimensional space chain structure and special needle, stick
Shape crystal structure, thus have unusual colloid and absorption property.Its thickening property, suspension, colloid shake to melt and have excellent performance,
The association networks that " card palace " formula is formed in aqueous medium, improve the stability of coating.
Further preferably, the continuous phase includes following components in percentage by weight:
Preservative 0.4-0.6%；
Mould inhibitor 0.5-1%；
Ethylene glycol 2-3%；
12 2-4% of alcohol ester；
Acrylic emulsion 45-55%；
Multifunction amine auxiliary agent 0.4-0.6%；
Thickener 1-2%；
Surplus is water.
By using above-mentioned technical proposal, the main component of continuous phase is similar to granulation liquid, and compatibility is good, enables granulation liquid
It is enough evenly dispersed.
Further preferably, the viscosity number of the continuous phase is 115-120KU.
By using above-mentioned technical proposal, the viscosity number of continuous phase is too big, is unfavorable for the dispersion of granulation liquid, and continuous phase is glued
Angle value is too small, is unfavorable for spraying film forming.
Further preferably, the granulation liquid further includes following components in percentage by weight:
Alkaline thickener 0.2-0.3%；
Multifunction amine auxiliary agent 0.1-0.2%；
Pregel 20-25%；
Color-mixed base paint 65-70%；
Surplus is water.
By using above-mentioned technical proposal, alkaline thickener, multifunction amine auxiliary agent, pregel and water are mixing uniformly to form
Liquid is wrapped up, after color-mixed base paint is added in package liquid, stirring is broken up, and color-mixed base paint is sufficiently wrapped up by package liquid, is conducive to shape
At independent color spot, mill base dispersion and colour mixture are avoided.
To achieve the above object two, the present invention provides the following technical scheme that
A kind of preparation method of the colorful stone-like coating containing sand, which comprises the following steps:
Step 1 prepares pregel, and preservative, aluminium-magnesium silicate, water are mixed and is uniformly dispersed, obtains pregel；
Step 2 prepares base paint, divides after hydrophobically modified celluloses, defoaming agent, wetting agent, coalescing agent, filler, water are mixed
It dissipates uniformly, adds multifunction amine auxiliary agent, preservative, acrylic emulsion and be uniformly dispersed, be slow added into pregel and be uniformly dispersed,
Obtain base paint；
Step 3 prepares color-mixed base paint, and according to the corresponding mill base of template mixing color, the mill base of different colours is separately added into
It is uniformly dispersed in corresponding base paint, obtains color-mixed base paint；
Step 4 prepares granulation liquid, and alkaline thickener, multifunction amine auxiliary agent, pregel, water are mixed evenly, added
Color-mixed base paint stirs evenly, and is distributed color-mixed base paint in pelletized form, obtains granulation liquid；
Step 5 prepares continuous phase, and water, preservative, mould inhibitor, ethylene glycol are sequentially added under stirring and is uniformly mixed, is obtained
It is added in mixed liquor, stirs evenly after mixing to mixed liquor, then by alcohol ester 12, acrylic emulsion, multifunction amine auxiliary agent,
Obtain continuous phase；
Step 6 prepares finished product coating, granulation liquid is slowly added in continuous phase, is mixed evenly, and obtains finished product coating.
By using above-mentioned technical proposal, after hydrophobically modified celluloses, wetting agent and pregel are used in compounding, sand can be made
Son and color-mixed base paint form thick fluid, advantageously form independent color spot, avoid mill base dispersion and colour mixture；Coalescing agent
Be conducive to color spot cured later film forming with acrylic emulsion, color spot is clear, true to nature；And color-mixed base paint storage stability is good,
Storage 6 months it is not stratified, do not precipitate.
Further preferably, the step 2 specifically includes: base paint is prepared, by hydrophobically modified celluloses, defoaming agent, profit
It is uniformly dispersed after humectant, coalescing agent, filler, water mixing, rate of dispersion is 1700-1900 revs/min, jitter time 15-
25 minutes, multifunction amine auxiliary agent, preservative, acrylic emulsion dispersion are added when rate of dispersion is dropped to 400-500 revs/min
Uniformly, jitter time is 4-6 minutes, is slow added into pregel and is uniformly dispersed, and rate of dispersion is 850-950 revs/min, dispersion
Time is 8-12 minutes, obtains base paint.
By using above-mentioned technical proposal, on the one hand each component is stirred evenly, it is suitable on the other hand can to obtain viscosity
In base paint.
Further preferably, the pH of the finished product coating is 8-9, viscosity number 95-100KU.
By using above-mentioned technical proposal, stone-like coating of the invention is alkalescent system, by controlling pH and viscosity number,
Raising storage stability is not only improved, spraying film forming is also beneficial to, viscosity number is tested using stormer viscosity meter STM-IV (B).
In conclusion compared with prior art, the invention has the following advantages:
(1) present invention mixes colours to base paint using mill base, and hydrophobically modified celluloses, wetting agent and pregel are used in compounding
Afterwards, sand and color-mixed base paint can be made to form thick fluid, advantageously forms independent color spot, mill base is avoided to disperse and mix
Color；Coalescing agent and acrylic emulsion are conducive to color spot cured later film forming, and color spot is clear, true to nature, are coated on exterior wall with dry
Hang the verisimilitude of the lithotomes such as marble, embody building it is muddy as day at decorative effect；
(2) present invention passes through the proportion chosen component and control each component, so that stone-like coating storage stability is good, stores 6
The moon is not stratified, does not precipitate；
(3) stone-like coating provided by the invention belongs to Water-borne modification product, and VOC content is less than 15g/L, is far below China's exterior coating
120g/L limit value as defined in standard, it is environmentally protective.
Specific embodiment
Below with reference to embodiment, the present invention will be described in detail.
A kind of embodiment 1: preparation method of the colorful stone-like coating containing sand, comprising the following steps:
Step 1 prepares pregel, and preservative, aluminium-magnesium silicate, water are mixed, 60 points are dispersed under 1500 revs/min of speed
Clock obtains pregel, and pregel includes following components in percentage by weight: preservative 0.1%；Aluminium-magnesium silicate 6%；Surplus is
Water, the main component of preservative are Kathon CGs.
Step 2 prepares base paint, and hydrophobically modified celluloses, defoaming agent, wetting agent, coalescing agent, filler, water are mixed
After be uniformly dispersed, rate of dispersion be 1700 revs/min, jitter time be 25 minutes, when rate of dispersion is dropped to 400 revs/min
It adds multifunction amine auxiliary agent, preservative, acrylic emulsion to be uniformly dispersed, jitter time is 6 minutes, is slow added into pregel
It is uniformly dispersed, rate of dispersion is 850 revs/min, and jitter time is 12 minutes, obtains base paint；
Step 3 prepares color-mixed base paint, and according to the corresponding mill base of template mixing color, the mill base of different colours is separately added into
It is uniformly dispersed in corresponding base paint, adds sand, obtain color-mixed base paint, the mass ratio of color-mixed base paint and sand is
100:50；
Color-mixed base paint includes following components in percentage by weight:
Hydrophobically modified celluloses 0.8%；
Defoaming agent 0.2%；
Wetting agent 0.2%；
Coalescing agent 0.5%；
Filler 10%；
Multifunction amine auxiliary agent 0.1%；
Preservative 0.3%；
Acrylic emulsion 20%；
Mill base 1%；
Pregel 8%；
Surplus is water.
Wherein, hydrophobically modified celluloses is hydrophobically modified hydroxyethyl cellulose, and defoaming agent is defoaming agent NXZ, defoaming agent NXZ
It is the hydrophobic gas-phase silica of mineral oil and metal soap defoaming agent；Wetting agent is high-performance Cationic thickeners, trade mark FT-
417；Coalescing agent is alcohol ester 12；Filler includes the powdered whiting of bentonite, kaolin and 400 mesh, the weight hundred of three
Ratio is divided to be followed successively by 0.5%, 4.5%, 5%；Multifunction amine auxiliary agent is AMP-95, and chemical name is 2- amino-2-methyl -1- third
Alcohol；Preservative is Kathon CG；Mill base is available from the aqueous color paste of Guangdong Ke Di new material Science and Technology Ltd..
Step 4 prepares granulation liquid, and alkaline thickener, multifunction amine auxiliary agent, pregel, water are mixed evenly, then
Color-mixed base paint is added, stirs evenly, is distributed color-mixed base paint in pelletized form, obtain granulation liquid；
Granulation liquid includes following components in percentage by weight: alkaline thickener 0.2%；Multifunction amine auxiliary agent 0.1%；Pregel
20%；Color-mixed base paint 65%；Surplus is water；Alkaline thickener is the happy suitable hydrophobically modified alkali-soluble emulsion type in ROHM AND HAAS Asia
Thickener, trade mark TT935, the multifunction amine auxiliary agent trade mark are AMP-95, and chemical name is 2-amino-2-methyl-1-propanol.
Step 5 prepares continuous phase, and water, preservative, mould inhibitor, ethylene glycol mixing are sequentially added under stirring
It is even, mixed liquor is obtained, then alcohol ester 12, acrylic emulsion, multifunction amine auxiliary agent are added in mixed liquor after mixing, stirred
5 minutes, continuous phase is obtained, the viscosity number of continuous phase is 115KU；
Continuous phase includes following components in percentage by weight: preservative 0.6%；Mould inhibitor 1%；Ethylene glycol 3%；Alcohol ester 12
4%；Acrylic emulsion 55%；Multifunction amine auxiliary agent 0.6%；Thickener 2%；Surplus is water；Multifunction amine auxiliary agent A MP-95,
Chemical name is 2-amino-2-methyl-1-propanol, and thickener is the mixture that TT-935 is mixed with water with weight ratio for 1:1.
Step 6 prepares finished product coating, granulation liquid is slowly added in continuous phase, and the mass ratio of granulation liquid and continuous phase is
60:20 is mixed evenly, and revolving speed is 200 revs/min, obtains finished product coating, the pH of finished product coating is 8, and viscosity number is
95KU。
Embodiment 2: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, pregel
Including following components in percentage by weight: preservative 0.2%；Aluminium-magnesium silicate 8%；Surplus is water.
Embodiment 3: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, pregel
Including following components in percentage by weight: preservative 0.3%；Aluminium-magnesium silicate 10%；Surplus is water.
Embodiment 4: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, step 3
The mass ratio of middle color-mixed base paint and sand is 100:65.
Embodiment 5: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, step 3
The mass ratio of middle color-mixed base paint and sand is 100:80.
Embodiment 6: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, base of mixing colours
Plinth enamel-cover includes following components in percentage by weight:
Hydrophobically modified celluloses 1.0%；
Defoaming agent 0.3%；
Wetting agent 0.3%；
Coalescing agent 0.6%；
Filler 12%；
Multifunction amine auxiliary agent 0.15%；
Preservative 0.4；
Acrylic emulsion 25%；
Mill base 3%；
Pregel 10%；
Surplus is water；Filler includes the powdered whiting of bentonite, kaolin and 400 mesh, and the weight percent of three is followed successively by
0.4%, 5.6%, 6%.The pH of finished product coating is 8.5, viscosity number 98KU.
Embodiment 7: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, base of mixing colours
Plinth enamel-cover includes following components in percentage by weight:
Hydrophobically modified celluloses 1.2%；
Defoaming agent 0.4%；
Wetting agent 0.4%；
Coalescing agent 0.7%；
Filler 15%；
Multifunction amine auxiliary agent 0.2%；
Preservative 0.5；
Acrylic emulsion 30%；
Mill base 5%；
Pregel 12%；
Surplus is water；Filler includes the powdered whiting of bentonite, kaolin and 400 mesh, and the weight percent of three is followed successively by
0.4%, 7.6%, 7%.The pH of finished product coating is 9, viscosity number 100KU.
Embodiment 8: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, granulation liquid
Mass ratio with continuous phase is 70:30.
Embodiment 9: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, granulation liquid
Mass ratio with continuous phase is 80:40.
Embodiment 10: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, continuously
The viscosity number of phase is 118KU, and continuous phase includes following components in percentage by weight:
Preservative 0.4%；
Mould inhibitor 0.5%；
Ethylene glycol 2%；
Alcohol ester ten two 2%；
Acrylic emulsion 45%；
Multifunction amine auxiliary agent 0.4%；
Thickener 1%；
Surplus is water.
Embodiment 11: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, continuously
The viscosity number of phase is 120KU, and continuous phase includes following components in percentage by weight:
Preservative 0.5%；
Mould inhibitor 0.8%；
Ethylene glycol 2.5%；
Alcohol ester ten two 3%；
Acrylic emulsion 50%；
Multifunction amine auxiliary agent 0.5%；
Thickener 1.5%；
Surplus is water.
Embodiment 12: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, it is granulated
Liquid includes following components in percentage by weight: alkaline thickener 0.25%；Multifunction amine auxiliary agent 0.15%；Pregel 22%；It adjusts
Color base paint 68%；Surplus is water.
Embodiment 13: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, it is granulated
Liquid includes following components in percentage by weight: alkaline thickener 0.3%；Multifunction amine auxiliary agent 0.2%；Pregel 25%；Toning
Base paint 70%；Surplus is water.
Embodiment 14: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, step
Two specifically include: preparing base paint, divide after hydrophobically modified celluloses, defoaming agent, wetting agent, coalescing agent, filler, water are mixed
It dissipates uniformly, rate of dispersion is 1800 revs/min, and jitter time is 20 minutes, and rate of dispersion is dropped to 450 revs/min of Shi Zaijia
Enter multifunction amine auxiliary agent, preservative, acrylic emulsion to be uniformly dispersed, jitter time is 5 minutes, is slow added into pregel dispersion
Uniformly, rate of dispersion is 900 revs/min, and jitter time is 10 minutes, obtains base paint.
Embodiment 15: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, step
Two specifically include: preparing base paint, divide after hydrophobically modified celluloses, defoaming agent, wetting agent, coalescing agent, filler, water are mixed
It dissipates uniformly, rate of dispersion is 1900 revs/min, and jitter time is 15 minutes, and rate of dispersion is dropped to 500 revs/min of Shi Zaijia
Enter multifunction amine auxiliary agent, preservative, acrylic emulsion to be uniformly dispersed, jitter time is 4 minutes, is slow added into pregel dispersion
Uniformly, rate of dispersion is 950 revs/min, and jitter time is 8 minutes, obtains base paint.
Comparative example 1: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, by silicic acid
Magnalium replaces with the organic siliconresin of equal weight percent.
Comparative example 2: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, it will be hydrophobic
Modified cellulose replaces with the ethyl cellulose of equal weight percent.
Comparative example 3: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, base of mixing colours
Wetting agent is not added in plinth paint.
Comparative example 4: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, base of mixing colours
Plinth enamel-cover includes following components in percentage by weight:
Hydrophobically modified celluloses 0.5%；
Defoaming agent 0.2%；
Wetting agent 0.1%；
Coalescing agent 0.5%；
Filler 10%；
Multifunction amine auxiliary agent 0.1%；
Preservative 0.3%；
Acrylic emulsion 20%；
Mill base 1%；
Pregel 6%；
Surplus is water.
Comparative example 5: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, continuous phase
Including following components in percentage by weight: preservative 0.6%；Mould inhibitor 1%；Ethylene glycol 1%；Alcohol ester ten two 1%；Propylene yogurt
Liquid 40%；Multifunction amine auxiliary agent 0.6%；Thickener 0.5%；Surplus is water.
Comparative example 6: a kind of preparation method of the colorful stone-like coating containing sand, difference from example 1 is that, step 2
It specifically includes: preparing base paint, by hydrophobically modified celluloses, defoaming agent, wetting agent, coalescing agent, filler, water, multifunction amine
Auxiliary agent, preservative, acrylic emulsion, pregel are uniformly dispersed, and rate of dispersion is 2000 revs/min, and jitter time is 10 minutes,
Obtain base paint.
Comparative example 7: imitative stone is prepared using the embodiment 1 in the Chinese invention patent of Publication No. CN106433359A and is applied
Material.
Test an ocular estimate
Test specimen: the stone-like coating obtained in embodiment 1-15 is sprayed on substrate, and test specimen 1-15 is used as after parching,
The stone-like coating obtained in comparative example 1-7 is sprayed on substrate, as control sample 1-7 after parching.
Test method: test specimen 1-15 and control sample 1-7 are compared with true stone material template respectively, and to emulation
Degree and color spot clarity score respectively, and minimum 0 point, highest 100 is divided.
Test result: the appraisal result of test specimen 1-15 and control sample 1-7 are as shown in table 1.As shown in Table 1, implement
The fidelity and color spot clarity of example 1-15 scores at 90 points or more, and the scoring of control sample 1-7 is at 41 points hereinafter, right
The fidelity of product 1-3 and color spot clarity scoring summation are below test specimen 1 in the same old way, illustrate the present invention using mill base to basis
Qi Jinhang toning, after hydrophobically modified celluloses, wetting agent and pregel are used in compounding, can be such that sand and color-mixed base paint is formed
Thick fluid advantageously forms independent color spot, avoids mill base dispersion and colour mixture；Coalescing agent and acrylic emulsion are conducive to
Color spot cured later film forming, color spot is clear, true to nature, has the verisimilitude of the lithotomes such as cladding marble, body coated on exterior wall
Existing building it is muddy as day at decorative effect.
The appraisal result of table 1 test specimen 1-15 and control sample 1-7
Test two performance tests
Test specimen: using the stone-like coating obtained in embodiment 1-15 as test specimen 1-15, by what is obtained in comparative example 1-7
Stone-like coating is used as control sample 1-7.
Test method: test sample is detected according to the method in JG/T24-2000 SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS
The drying time of product 1-15 and control sample 1-7, water resistance, alkali resistance, adhesion strength and thermal storage stability.
Test result: the test result of test specimen 1-15 and control sample 1-7 are as shown in table 2.As shown in Table 2, it tests
Drying time, water resistance, alkali resistance, adhesion strength and the thermal storage stability of sample 1-15 meets the requirements of the standard, and right
Product 1-7 occurs being layered after 30 days, has precipitating in the same old way, and thermal storage stability does not meet standard requirements, illustrates that the present invention passes through
It chooses component and controls the proportion of each component, it is not stratified after long-time storage, do not sink so that stone-like coating storage stability is good
It forms sediment.
The test result of table 2 test specimen 1-15 and control sample 1-7
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-described embodiment,
All technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art
For those of ordinary skill, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (8)
1. a kind of colorful stone-like coating containing sand, which is characterized in that its raw material includes granulation liquid and continuous phase, granulation liquid and continuous phase
Mass ratio be (60-80): (40-20), the granulation liquid includes color-mixed base paint and sand, the color-mixed base paint and sand
Mass ratio be 100:(50-80)；The color-mixed base paint includes following components in percentage by weight:
Hydrophobically modified celluloses 0.8-1.2%；
Defoaming agent 0.2-0.4%；
Wetting agent 0.2-0.4%；
Coalescing agent 0.5-0.7%；
Filler 10-15%；
Multifunction amine auxiliary agent 0.1-0.2%；
Preservative 0.3-0.5%；
Acrylic emulsion 20-30%；
Mill base 1-5%；
Pregel 8-12%；
Surplus is water.
2. one kind colorful stone-like coating containing sand according to claim 1, which is characterized in that the pregel includes following heavy
Measure the component of percentage:
Preservative 0.1-0.3%；
Aluminium-magnesium silicate 6-10%；
Surplus is water.
3. one kind colorful stone-like coating containing sand according to claim 1, which is characterized in that the continuous phase includes following heavy
Measure the component of percentage:
Preservative 0.4-0.6%；
Mould inhibitor 0.5-1%；
Ethylene glycol 2-3%；
12 2-4% of alcohol ester；
Acrylic emulsion 45-55%；
Multifunction amine auxiliary agent 0.4-0.6%；
Thickener 1-2%；
Surplus is water.
4. one kind colorful stone-like coating containing sand according to claim 1, which is characterized in that the viscosity number of the continuous phase is
115-120KU。
5. one kind colorful stone-like coating containing sand according to claim 1, which is characterized in that the granulation liquid further includes following
The component of weight percent:
Alkaline thickener 0.2-0.3%；
Multifunction amine auxiliary agent 0.1-0.2%；
Pregel 20-25%；
Color-mixed base paint 65-70%；
Surplus is water.
6. a kind of preparation method of the colorful stone-like coating containing sand, which comprises the following steps:
Step 1 prepares pregel, and preservative, aluminium-magnesium silicate, water are mixed and is uniformly dispersed, obtains pregel；
Step 2 prepares base paint, divides after hydrophobically modified celluloses, defoaming agent, wetting agent, coalescing agent, filler, water are mixed
It dissipates uniformly, adds multifunction amine auxiliary agent, preservative, acrylic emulsion and be uniformly dispersed, be slow added into pregel and be uniformly dispersed,
Obtain base paint；
Step 3 prepares color-mixed base paint, and according to the corresponding mill base of template mixing color, the mill base of different colours is separately added into
It is uniformly dispersed in corresponding base paint, obtains color-mixed base paint；
Step 4 prepares granulation liquid, and alkaline thickener, multifunction amine auxiliary agent, pregel, water are mixed evenly, added
Color-mixed base paint stirs evenly, and is distributed color-mixed base paint in pelletized form, obtains granulation liquid；
Step 5 prepares continuous phase, and water, preservative, mould inhibitor, ethylene glycol are sequentially added under stirring and is uniformly mixed, is obtained
It is added in mixed liquor, stirs evenly after mixing to mixed liquor, then by alcohol ester 12, acrylic emulsion, multifunction amine auxiliary agent,
Obtain continuous phase；
Step 6 prepares finished product coating, granulation liquid is slowly added in continuous phase, is mixed evenly, and obtains finished product coating.
7. a kind of preparation method of colorful stone-like coating containing sand according to claim 6, which is characterized in that the step 2
It specifically includes: preparing base paint, disperse after hydrophobically modified celluloses, defoaming agent, wetting agent, coalescing agent, filler, water are mixed
Uniformly, rate of dispersion is 1700-1900 revs/min, and jitter time is 15-25 minute, rate of dispersion drop to 400-500 turn/
It adds multifunction amine auxiliary agent, preservative, acrylic emulsion when minute to be uniformly dispersed, jitter time is 4-6 minutes, then slowly adds
Enter pregel to be uniformly dispersed, rate of dispersion is 850-950 revs/min, and jitter time is 8-12 minutes, obtains base paint.
8. a kind of preparation method of colorful stone-like coating containing sand according to claim 6, which is characterized in that the finished product applies
The pH of material is 8-9, viscosity number 95-100KU.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111363436A (en) * | 2020-04-29 | 2020-07-03 | 广东法兰迪涂料有限公司 | A kind of water-based colorful paint and preparation method thereof |
| CN111925700A (en) * | 2020-07-29 | 2020-11-13 | 广西瑞顺建材有限公司 | Base paint of water-based stone-like coating and preparation method thereof |
| CN112574627A (en) * | 2020-11-30 | 2021-03-30 | 三棵树(上海)新材料研究有限公司 | Marble-like water-based reflective heat-insulation exterior wall sand-containing multicolor paint and preparation method thereof |
| CN113621292A (en) * | 2021-08-24 | 2021-11-09 | 广东美涂士建材股份有限公司 | Mirror-surface colorful stone-like paint for exterior wall |
| CN114479589A (en) * | 2022-01-25 | 2022-05-13 | 福州居家逸涂料科技有限公司 | Hemp color stone paint and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120264859A1 (en) * | 2011-04-18 | 2012-10-18 | Jianming Xu | Copolymer dispersion for water whitening resistant coatings |
| CN107117872A (en) * | 2017-05-08 | 2017-09-01 | 福建华夏蓝新材料科技有限公司 | A kind of super-hydrophobic colorful true mineral varnish coating and preparation method thereof |
-
2018
- 2018-12-12 CN CN201811521783.2A patent/CN109535878A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120264859A1 (en) * | 2011-04-18 | 2012-10-18 | Jianming Xu | Copolymer dispersion for water whitening resistant coatings |
| CN107117872A (en) * | 2017-05-08 | 2017-09-01 | 福建华夏蓝新材料科技有限公司 | A kind of super-hydrophobic colorful true mineral varnish coating and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 杨成德: "《涂料开发与试验》", 28 February 2015, 科学技术文献出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111363436A (en) * | 2020-04-29 | 2020-07-03 | 广东法兰迪涂料有限公司 | A kind of water-based colorful paint and preparation method thereof |
| CN111925700A (en) * | 2020-07-29 | 2020-11-13 | 广西瑞顺建材有限公司 | Base paint of water-based stone-like coating and preparation method thereof |
| CN112574627A (en) * | 2020-11-30 | 2021-03-30 | 三棵树(上海)新材料研究有限公司 | Marble-like water-based reflective heat-insulation exterior wall sand-containing multicolor paint and preparation method thereof |
| CN113621292A (en) * | 2021-08-24 | 2021-11-09 | 广东美涂士建材股份有限公司 | Mirror-surface colorful stone-like paint for exterior wall |
| CN114479589A (en) * | 2022-01-25 | 2022-05-13 | 福州居家逸涂料科技有限公司 | Hemp color stone paint and preparation method thereof |
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