CN102876143A - Marble paint and preparation method thereof - Google Patents
Marble paint and preparation method thereof Download PDFInfo
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- CN102876143A CN102876143A CN2012103190761A CN201210319076A CN102876143A CN 102876143 A CN102876143 A CN 102876143A CN 2012103190761 A CN2012103190761 A CN 2012103190761A CN 201210319076 A CN201210319076 A CN 201210319076A CN 102876143 A CN102876143 A CN 102876143A
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Abstract
The invention discloses marble paint and a preparation method thereof. The marble paint comprises the following components in part by weight: 0.1 to 2 parts of cellulose, 0.1 to 3 parts of pH conditioning agent, 200 to 450 parts of emulsion, 5 to 32 parts of film forming aid, 0.1 to 8 parts of preservative, 500 to 900 parts of quartz sand, 0.1 to 8 parts of thickening agent, 2 to 30 parts of antifreezing agent, 30 to 110 parts of colorful particle, 0.1 to 5 parts of defoaming agent and 50 to 100 parts of water. According to the production process of the marble paint, the raw materials are uniformly mixed at the temperature of below 45 DEG C. The marble paint has high scrubbing resistance, water resistance, artificial aging resistance, stain resistance, alkali resistance and hydrophobic performance; simultaneously, the paint can be coated on the surface of a substrate through spraying, brushing or rolling; and a good decorative effect is achieved.
Description
Technical field
The present invention relates to paint field, particularly, the present invention relates to the emulation coating field.
Background technology
As everyone knows, natural granite building material is a kind of finishing material of top grade, and is very concerned on market.But, this natural granite building material, reserves are limited, and its decorative pattern and color have determinacy, and can not regenerate, so, adopt natural granite building material more and more difficult as building and ornament materials.Marble is compared with stone material, has following characteristics: (1) is construction easily: compare with stone material, the parian lacquer can be used for dissimilar metope, cylinder, end faces; (2) protective: the same with real stone material, waterproof is not affected by environmental pollution; (3) transportation is convenient: lighter than Bartlit, and easily transportation; (4) color: multiple color is available; (5) expense: the cost ratio natural marble cheap 70% of product.This product main component is natural marble powder, and marmorean effect is arranged.Also Just because of this, the production of true mineral varnish, parian lacquer has just become the hot issue in building decoration field.In recent years, the stone-simulative paint surface layer was moulded the stone field in covil construction exterior wall, upholstery and gardens and was widely used, and had serious, elegant and harmonious sensation with back to nature.
CN 102617071A discloses the true mineral varnish of a kind of high gloss, parian lacquer, it is characterized in that it is made by the raw material of the white proportion by subtraction of following weight: organosilicon crylic acid latex 20.7-25.8%; The HEC hydroxy ethyl fiber cellulose solution 4-6% of concentration 2.5%; Film coalescence aid alcohol ester 12 0.5-0.7%; Ethylene glycol 0.35-0.45%; The color sand 10.4-15.5% of 40-80 order; The color sand 15.5-20.6% of 80-120 order; The color sand 36.1-41.3% of 120-20 order; Mould inhibitor 0.008-0.012%; Sanitas 0.008-0.012%; Sterilant 0.008-0.012%; Moisturizing light agent 0.35-0.45%; Dye leveller 0.5-0.74%.Add sliver, be the parian lacquer.This marble lacquer has good ornamental, but the performances such as abrasion resistance, drying property, didirtresistance have much room for improvement.
CN 101358105A discloses a kind of synthesis of artificial marble lacquer, and mainly by raw material: color sand, organosilicon crylic acid latex, plasma water, Mierocrystalline cellulose, organic amine, second are two liquor-saturated, multifunctional assistant, defoamer, mould inhibitor, film coalescence aid are made.This marble lacquer has good contamination resistance energy, but it contains a large amount of volatile organic matters, and the performance such as drying property, tack can not be satisfied the demand.
Therefore, develop a kind of have excellent ornamental, and has excellent recovery, low temperature crease resistance and snappiness, excellent weather resisteant, resistance to crocking, anti-ly put washing property on the skin, water-proof breathable properties is good, extremely strong sticking power and alkali resistance, aqueous, environmental protective, nontoxic, tasteless marble lacquer is the technical barrier in affiliated field.
Summary of the invention
For the deficiencies in the prior art, one of purpose of the present invention is to provide a kind of marble lacquer.
Described marble lacquer comprises according to parts by weight:
Wherein, described Mierocrystalline cellulose can be 0.11 part, 0.12 part, 0.2 part, 0.5 part, 0.8 part, 0.9 part, 1.3 parts, 1.6 parts, 1.9 parts, 1.95 parts, 1.98 parts, 1.99 parts etc.
Described pH adjusting agent can be 0.11 part, 0.12 part, 0.2 part, 0.5 part, 0.9 part, 1.3 parts, 1.6 parts, 2.4 parts, 2.9 parts, 2.95 parts, 2.98 parts, 2.99 parts etc.
Described emulsion can be 200.1 parts, 200.2 parts, 201 parts, 202 parts, 210 parts, 250 parts, 290 parts, 350 parts, 370 parts, 390 parts, 430 parts, 445 parts, 448 parts, 449 parts, 449.8 parts, 449.9 parts etc.
Described film coalescence aid can be 5.1 parts, 5.2 parts, 6 parts, 8 parts, 15 parts, 25 parts, 29 parts, 30 parts, 31 parts, 31.5 parts, 31.8 parts, 31.9 parts etc.
Described sanitas can be 0.11 part, 0.12 part, 0.2 part, 0.5 part, 1 part, 3 parts, 5 parts, 7 parts, 7.5 parts, 7.8 parts, 7.9 parts, 7.95 parts, 7.98 parts, 7.99 parts etc.
Described quartz sand can be 500.1 parts, 500.2 parts, 500.3 parts, 501 parts, 510 parts, 530 parts, 58 parts, 650 parts, 710 parts, 760 parts, 810 parts, 860 parts, 890 parts, 895 parts, 898 parts, 899 parts, 899.8 parts, 899.9 parts etc.
Described thickening material can be 0.11 part, 0.12 part, 0.2 part, 0.5 part, 1 part, 3 parts, 5 parts, 7 parts, 7.5 parts, 7.8 parts, 7.9 parts, 7.95 parts, 7.98 parts, 7.99 parts etc.
Described frostproofer can be 2.1 parts, 2.2 parts, 2.5 parts, 3 parts, 6 parts, 11 parts, 16 parts, 21 parts, 26 parts, 28 parts, 29 parts, 29.7 parts, 29.8 parts, 29.9 parts etc.
Described colorful particle can be 30.1 parts, 30.2 parts, 30.3 parts, 31 parts, 60 parts, 90 parts, 107 parts, 108 parts, 109 parts, 109.7 parts, 109.8 parts, 109.9 parts etc.
Described defoamer can be 0.11 part, 0.12 part, 0.2 part, 0.7 part, 1.3 parts, 1.8 parts, 2.2 parts, 3.6 parts, 4.7 parts, 4.8 parts, 4.9 parts etc.
Described water can be 50.1 parts, 50.2 parts, 50.3 parts, 51 parts, 55 parts, 64 parts, 76 parts, 87 parts, 94 parts, 97 parts, 98 parts, 99 parts, 99.8 parts, 99.9 parts etc.
Preferably, described marble lacquer comprises according to parts by weight:
Further preferred, described marble lacquer comprises according to parts by weight:
Particularly preferably, described marble lacquer is composed of the following components according to parts by weight:
Mierocrystalline cellulose among the present invention is the compound that contains the cellulosic structure unit, can comprise, for example, use acid, hydroxyl in the esterified celluloses such as lipid acid, nitric acid and the Mierocrystalline cellulose esterification product for preparing, by making the Mierocrystalline cellulose esterification product that contains the polymerizable unsaturated group and the multipolymer of polymerizable unsaturated monomer reaction preparation etc., the Mierocrystalline cellulose esterification product that wherein contains the polymerizable unsaturated group obtains by introduce the polymerizable unsaturated group in Mierocrystalline cellulose esterification product.
Preferably, described Mierocrystalline cellulose is a kind or at least 2 kinds combination in soluble cotton, butyric acid rhodia, rhodia, propionic acid rhodia, Vltra tears, Natvosol, carboxymethyl cellulose, the ether of cellulose, particularly preferably Vltra tears and/or Natvosol.
Mierocrystalline cellulose and filmogen have good consistency, and can improve resulting drying property of filming and adhesivity.
Preferably, described pH adjusting agent is selected from organic such as the AMP-95(2-amino-2-methyl-1-propyl alcohol of U.S.'s Angus (ANGUS) company) and/or mineral-type such as ammoniacal liquor, particularly preferably AMP-95.
Preferably, described emulsion is styrene-acrylic resin emulsion and/or organosilicon acrylic resin emulsion, and one of ordinary skill in the art can be by commercial or utilize prior art/new technology to prepare.
Preferably, described film coalescence aid is a kind or at least 2 kinds combination in propylene glycol monomethyl ether, propandiol butyl ether, alcohol ester 12, Diethylene Glycol butyl ether or the phenylcarbinol.
Preferably, described sanitas is benzoglyoxaline ester class (Nordes EPW), Dao Weixier-75,1,1 kind or at least 2 kinds combination in 2-benzisothiazole-3-ketone (BIT), Kathon CG class (MIT and (B) CMIT) or the phenylformic acid are particularly preferably Kathon CG class and/or phenylformic acid.
Preferably, described quartz sand is 150 ~ 300 order quartz sands, further preferred 180 ~ 250 orders, particularly preferably 230 orders.
Preferably, described frostproofer is ethylene glycol and/or propylene glycol, is particularly preferably ethylene glycol.
Described colorful particle can be granules of pigments, also can be other material particle of dyeing, such as stained glass particle, colored plastic particle or the colored grains of sand etc.Preferably, described colorful particle size is 150 ~ 300 orders, further preferred 180 ~ 250 orders, particularly preferably 230 orders.
Preferably, described defoamer is mineral oil antifoam agent or silicone antifoam agent.
Preferably, described water is deionized water.
Described marble lacquer also can contain other component, such as wetting agent, mould inhibitor, flow agent, frostproofer, photostabilizer etc., and one of ordinary skill in the art can add a kind or at least 2 kinds combination wherein as required.
Preferably, described wetting agent is tensio-active agent.
One of purpose of the present invention also is to provide a kind of production technique of described marble lacquer.
Described production technique may further comprise the steps:
(1) add entry, add Mierocrystalline cellulose and pH adjusting agent under 300 ~ 500r/min stir speed (S.S.), improve stir speed (S.S.) to 700 ~ 900r/min, stir, temperature is controlled at below 45 ℃;
(2) add defoamer, frostproofer, film coalescence aid, sanitas, below 45 ℃, under 500 ~ 700r/min rotating speed, stir;
(3) under 500 ~ 700r/min stir speed (S.S.), add emulsion, stirred at least 5 minutes;
(4) add quartz sand, improve stir speed (S.S.) to 700 ~ 900r/min, the colorful particle of rear adding that stirs below 45 ℃, stirs.
Preferably, step (4) is carried out afterwards step (5) and is added the thickening material adjusting viscosity, obtains marble lacquer.
Preferably, stir speed (S.S.) is 350 ~ 450r/min before step (1) middle adding Mierocrystalline cellulose and the pH adjusting agent, is particularly preferably 400r/min.
Preferably, stir speed (S.S.) is 750 ~ 850r/min after step (1) middle adding Mierocrystalline cellulose and the pH adjusting agent, is particularly preferably 800r/min.
Preferably, temperature is below 40 ℃ in the step (1).
Preferably, temperature is below 40 ℃ in the step (2).
Preferably, stir speed (S.S.) is 550 ~ 650r/min in the step (2), is particularly preferably 600r/min.
Preferably, stir speed (S.S.) is 550 ~ 650r/min in the step (3), is particularly preferably 600r/min.
Preferably, churning time is at least 8 minutes in the step (3), particularly preferably stirs 10 ~ 15 minutes.
Preferably, stir speed (S.S.) is 750 ~ 850r/min in the step (4), is particularly preferably 800r/min.
Preferably, temperature is below 40 ℃ in the step (4).
Part of the present invention refers to parts by weight.Parts by weight unit of the present invention is identical.
The prepared marble lacquer of the present invention has following advantage:
(1) coating has good elasticity, excellent recovery, low temperature crease resistance and snappiness;
(2) excellent weather resisteant, resistance to crocking, anti-ly put washing property on the skin, water-proof breathable properties is good;
(3) extremely strong sticking power and alkali resistance;
(4) aqueous, environmental protective, nontoxic is tasteless;
(5) decorate properties is excellent, can create the marbling effect of various different colors.
Embodiment
For ease of understanding the present invention, it is as follows that the present invention enumerates embodiment.Those skilled in the art should understand that described embodiment helps to understand the present invention, should not be considered as concrete restriction of the present invention.
Embodiment 1
(1) claim 70 parts of deionized waters to drop in the reactor, then start high speed dispersor control rotating speed 400r/min, take by weighing 0.7 part of Mierocrystalline cellulose and 1 part of AMP-95 input reactor, rotating speed is brought up to 800r/min to being uniformly dispersed, and temperature is controlled at below 40 degree;
(2) take by weighing 1 part of mineral oil antifoam agent, 8 parts of ethylene glycol, 25 parts of alcohol esters 12,4 portions of sanitass, rotating speed is reduced to 600r/min, and temperature is controlled at below 40 degree, is uniformly dispersed;
(3) take by weighing 400 parts of organosilicon acrylic resins and drop in the reactor, rotating speed 600r/min disperseed 10-15 minute;
(4) take by weighing 600 part of 300 order quartz sand and drop in the still, rotating speed is brought up to 800r/min, takes by weighing 40 part of 280 colorful sandstone particle of order after being uniformly dispersed and drops in the still, and temperature is controlled at below 40 degree, is uniformly dispersed;
(5) take by weighing 3 parts of thickening material adjusting viscosities.
Embodiment 2
(1) claim 50 parts of deionized waters to drop in the reactor, then start high speed dispersor control rotating speed 500r/min, take by weighing 0.1 part of Vltra tears and 3 parts of AMP-95 input reactors, rotating speed is brought up to 900r/min to being uniformly dispersed, and temperature is controlled at below 45 degree;
(2) take by weighing 0.1 part of silicone antifoam agent, 2 parts of propylene glycol, 32 parts of propandiol butyl ethers, 0.1 part of phenylformic acid, rotating speed is reduced to 500r/min, and temperature is controlled at below 45 degree, is uniformly dispersed;
(3) take by weighing 450 parts of styrene-acrylic resins and drop in the reactor, rotating speed 700r/min disperseed 16 minutes;
(4) take by weighing 500 part of 150 order quartz sand and drop in the still, rotating speed is brought up to 900r/min, takes by weighing 30 part of 260 colorful sandstone particle of order after being uniformly dispersed and drops in the still, and temperature is controlled at below 45 degree, is uniformly dispersed;
(5) take by weighing 0.1 part of thickening material adjusting viscosity.
Embodiment 3
(1) claim 100 parts of deionized waters to drop in the reactor, then start high speed dispersor control rotating speed 300r/min, take by weighing 2 parts of Natvosols and 0.1 part of ammoniacal liquor input reactor, rotating speed is brought up to 700r/min to being uniformly dispersed, and temperature is controlled at below 43 degree;
(2) take by weighing 5 parts of silicone antifoam agents, 30 parts of propylene glycol, 5 part 2,2,4-trimethylammonium-1,3-pentanediol-mono isobutyrate, 8 portions of Kathon CG class sanitass, rotating speed is reduced to 700r/min, and temperature is controlled at below 43 degree, is uniformly dispersed;
(3) take by weighing 200 parts of styrene-acrylic resins and drop in the reactor, rotating speed 500r/min disperseed 10 minutes;
(4) take by weighing 900 part of 150 order quartz sand and drop in the still, rotating speed is brought up to 700r/min, takes by weighing 110 part of 280 colorful sandstone particle of order after being uniformly dispersed and drops in the still, and temperature is controlled at below 43 degree, is uniformly dispersed;
(5) take by weighing 8 parts of thickening material adjusting viscosities.
Embodiment 4
(1) claim 80 parts of deionized waters to drop in the reactor, then start high speed dispersor control rotating speed 450r/min, take by weighing 1 part of Natvosol and 2 parts of AMP-95 input reactors, rotating speed is brought up to 850r/min to being uniformly dispersed, and temperature is controlled at below 38 degree;
(2) take by weighing 4 parts of mineral oil antifoam agents, 10 parts of ethylene glycol, 7 parts of phenylcarbinols, 3 portions of Kathon CG class sanitass, rotating speed is reduced to 650r/min, and temperature is controlled at below 38 degree, is uniformly dispersed;
(3) take by weighing 300 parts of styrene-acrylic resins and drop in the reactor, rotating speed 650r/min disperseed 5 minutes;
(4) take by weighing 600 part of 220 order quartz sand and drop in the still, rotating speed is brought up to 860r/min, takes by weighing 40 part of 170 colorful sandstone particle of order after being uniformly dispersed and drops in the still, and temperature is controlled at below 38 degree, is uniformly dispersed;
(5) take by weighing 2 parts of thickening material adjusting viscosities.
Comparative Examples 1
Adopt the disclosed parian lacquer of CN 102617071A to be Comparative Examples.Its preparation method comprises: with organosilicon crylic acid latex 23.3%, concentration is 2.5% HEC Natvosol 5.3%, film coalescence aid alcohol ester ten two 0.61%, ethylene glycol 0.4%, the color sand 12.76% of 60 orders, the color sand 18% of 100 orders, the color sand 38.6% of 160 orders, China section 108 mould inhibitors 0.01%, China's section's 981 sanitass 0.01% and sterilant HF 0.0% together pack in the stirring tank, stirring velocity is 17 rev/mins, churning time is 90 minutes, treat that HEC Natvosol particle dissolves fully, it is evenly mixed after, add again concentration and be 50% titanium dioxide solution 0.6%, continue to stir 20 minutes, stirring velocity still is 17 rev/mins, adds concentration again and be 1% polyacrylamide solution 0.4%, continues to stir 20 minutes again, stirring velocity is 17 rev/mins still, becomes thick true mineral varnish finished product; 3% of its weight of adding water stirs while adding in the thick true mineral varnish finished product of making, and dilutes evenly, is the true mineral varnish of high gloss, in the finished barrel of packing into; 1.8% of the true mineral varnish finished weight of the described high gloss of adding black sand stone sliver in the true mineral varnish finished product of high gloss is the parian lacquer, and 1.8% black sand stone sliver adds when construction.
Adopt GB/T9755-2001 that embodiment 1-4 and Comparative Examples 1 are tested, test result is as shown in table 1.
Table 1
Shown in upper table 1, each component concentration of marble lacquer of the present invention is reasonable, cooperatively interacts, and makes it have excellent scrub resistance, water tolerance, artificial ageing resistance, resistance to soiling, alkali resistance and hydrophobicity.Simultaneously, can spray, brushing or roller coat be to matrix surface, has excellent decorative effect.
Applicant's statement, the present invention illustrates detailed process equipment and process flow process of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned detailed process equipment and process flow process, does not mean that namely the present invention must rely on above-mentioned detailed process equipment and process flow process and could implement.The person of ordinary skill in the field should understand, any improvement in the present invention to the interpolation of the equivalence replacement of each raw material of product of the present invention and ancillary component, the selection of concrete mode etc., all drops within protection scope of the present invention and the open scope.
Claims (10)
1. a marble lacquer is characterized in that, described marble lacquer comprises according to parts by weight:
2. marble lacquer as claimed in claim 1 is characterized in that, described marble lacquer comprises according to parts by weight:
3. marble lacquer as claimed in claim 1 is characterized in that, described marble lacquer comprises according to parts by weight:
4. marble lacquer as claimed in claim 1 is characterized in that, described marble lacquer is composed of the following components according to parts by weight:
5. such as each described marble lacquer of claim 1-4, it is characterized in that, described Mierocrystalline cellulose is a kind or at least 2 kinds combination in soluble cotton, butyric acid rhodia, rhodia, propionic acid rhodia, Vltra tears, Natvosol, carboxymethyl cellulose, the ether of cellulose, particularly preferably Vltra tears and/or Natvosol;
Preferably, described pH adjusting agent is AMP-95 and/or ammoniacal liquor, particularly preferably AMP-95;
Preferably, described emulsion is styrene-acrylic resin emulsion and/or organosilicon acrylic resin emulsion.
6. such as each described marble lacquer of claim 1-5, it is characterized in that described film coalescence aid is a kind or at least 2 kinds combination in propylene glycol monomethyl ether, propandiol butyl ether, alcohol ester 12, Diethylene Glycol butyl ether or the phenylcarbinol;
Preferably, described sanitas is a kind or at least 2 kinds combination in benzoglyoxaline ester class, Dao Weixier-75, BIT, Kathon CG class or the phenylformic acid, is particularly preferably Kathon CG class and/or phenylformic acid;
Preferably, described quartz sand is 150 ~ 300 order quartz sands, further preferred 180 ~ 250 orders, particularly preferably 230 orders;
Preferably, described frostproofer is ethylene glycol and/or propylene glycol, is particularly preferably ethylene glycol.
7. such as each described marble lacquer of claim 1-6, it is characterized in that described colorful particle size is 150 ~ 300 orders, further preferred 180 ~ 250 orders, particularly preferably 230 orders;
Preferably, described defoamer is mineral oil antifoam agent or silicone antifoam agent;
Preferably, described water is deionized water.
8. such as the production technique of each described marble lacquer of claim 1-7, may further comprise the steps:
(1) add entry, add Mierocrystalline cellulose and pH adjusting agent under 300 ~ 500r/min stir speed (S.S.), improve stir speed (S.S.) to 700 ~ 900r/min, stir, temperature is controlled at below 45 ℃;
(2) add defoamer, frostproofer, film coalescence aid, sanitas, below 45 ℃, under 500 ~ 700r/min rotating speed, stir;
(3) under 500 ~ 700r/min stir speed (S.S.), add emulsion, stirred at least 5 minutes;
(4) add quartz sand, improve stir speed (S.S.) to 700 ~ 900r/min, the colorful particle of rear adding that stirs below 45 ℃, stirs.
9. the production technique of marble lacquer as claimed in claim 8 is characterized in that, step (4) is carried out afterwards step (5) and added the thickening material adjusting viscosity, obtains marble lacquer;
Preferably, stir speed (S.S.) is 350 ~ 450r/min before step (1) middle adding Mierocrystalline cellulose and the pH adjusting agent, is particularly preferably 400r/min;
Preferably, stir speed (S.S.) is 750 ~ 850r/min after step (1) middle adding Mierocrystalline cellulose and the pH adjusting agent, is particularly preferably 800r/min;
Preferably, temperature is below 40 ℃ in the step (1).
10. the production technique of marble lacquer as claimed in claim 8 or 9 is characterized in that, temperature is below 40 ℃ in the step (2);
Preferably, stir speed (S.S.) is 550 ~ 650r/min in the step (2), is particularly preferably 600r/min;
Preferably, stir speed (S.S.) is 550 ~ 650r/min in the step (3), is particularly preferably 600r/min;
Preferably, churning time is at least 8 minutes in the step (3), particularly preferably stirs 10 ~ 15 minutes;
Preferably, stir speed (S.S.) is 750 ~ 850r/min in the step (4), is particularly preferably 800r/min;
Preferably, temperature is below 40 ℃ in the step (4).
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| CN103694816A (en) * | 2013-11-12 | 2014-04-02 | 孙光华 | Modification method for cloth stamping acrylic resin coating material |
| CN103788878A (en) * | 2013-07-18 | 2014-05-14 | 宝鸡市嘉利来建材装饰有限责任公司 | Roller coating type simulated face brick coating and construction method |
| CN104119033A (en) * | 2013-04-26 | 2014-10-29 | 亿利资源集团有限公司 | Aqueous sand-based paint and preparation method thereof |
| CN104119034A (en) * | 2013-04-26 | 2014-10-29 | 亿利资源集团有限公司 | Aqueous sand-based paint and preparation method thereof |
| CN104310851A (en) * | 2014-10-08 | 2015-01-28 | 郎溪县华晶绝缘材料有限公司 | Really stone paint formula and production process thereof |
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| CN104119033A (en) * | 2013-04-26 | 2014-10-29 | 亿利资源集团有限公司 | Aqueous sand-based paint and preparation method thereof |
| CN104119034A (en) * | 2013-04-26 | 2014-10-29 | 亿利资源集团有限公司 | Aqueous sand-based paint and preparation method thereof |
| CN103788878A (en) * | 2013-07-18 | 2014-05-14 | 宝鸡市嘉利来建材装饰有限责任公司 | Roller coating type simulated face brick coating and construction method |
| CN103788878B (en) * | 2013-07-18 | 2016-09-07 | 宝鸡市嘉利来建材装饰有限责任公司 | A kind of roller coat type emulation face brick coating |
| CN104591598B (en) * | 2013-10-31 | 2017-03-15 | 北新集团建材股份有限公司 | A kind of true mineral varnish and preparation method thereof, construction method |
| CN104591598A (en) * | 2013-10-31 | 2015-05-06 | 北新集团建材股份有限公司 | Real stone paint, and preparation method and construction method thereof |
| CN103694816A (en) * | 2013-11-12 | 2014-04-02 | 孙光华 | Modification method for cloth stamping acrylic resin coating material |
| CN104310851A (en) * | 2014-10-08 | 2015-01-28 | 郎溪县华晶绝缘材料有限公司 | Really stone paint formula and production process thereof |
| CN104673021A (en) * | 2015-03-09 | 2015-06-03 | 广西启利新材料科技股份有限公司 | Stone-like paint prepared from ultra-thin colored slices |
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| CN106082794A (en) * | 2016-06-28 | 2016-11-09 | 郭舒洋 | A kind of preparation method of the true mineral varnish of high durable |
| CN106590268A (en) * | 2016-11-14 | 2017-04-26 | 北京卫星制造厂 | Real-stone paint and preparation method thereof |
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