CN103694816A - Modification method for cloth stamping acrylic resin coating material - Google Patents
Modification method for cloth stamping acrylic resin coating material Download PDFInfo
- Publication number
- CN103694816A CN103694816A CN201310561944.1A CN201310561944A CN103694816A CN 103694816 A CN103694816 A CN 103694816A CN 201310561944 A CN201310561944 A CN 201310561944A CN 103694816 A CN103694816 A CN 103694816A
- Authority
- CN
- China
- Prior art keywords
- acrylic resin
- coating material
- solvent
- cellulose acetate
- coated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004925 Acrylic resin Substances 0.000 title claims abstract description 26
- 229920000178 Acrylic resin Polymers 0.000 title claims abstract description 26
- 239000011248 coating agent Substances 0.000 title claims abstract description 19
- 238000000576 coating method Methods 0.000 title claims abstract description 19
- 239000004744 fabric Substances 0.000 title claims abstract description 13
- 239000000463 material Substances 0.000 title abstract 5
- 238000002715 modification method Methods 0.000 title abstract 2
- 239000002904 solvent Substances 0.000 claims abstract description 12
- 229920002301 cellulose acetate Polymers 0.000 claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 11
- 238000009835 boiling Methods 0.000 claims description 9
- 239000003973 paint Substances 0.000 claims description 9
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical group CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 8
- 229920000742 Cotton Polymers 0.000 claims description 8
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052782 aluminium Inorganic materials 0.000 abstract description 3
- 238000012546 transfer Methods 0.000 abstract description 3
- 238000009776 industrial production Methods 0.000 abstract description 2
- 238000009966 trimming Methods 0.000 abstract description 2
- 239000000020 Nitrocellulose Substances 0.000 abstract 1
- 229920001220 nitrocellulos Polymers 0.000 abstract 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 4
- 239000004926 polymethyl methacrylate Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 210000002469 basement membrane Anatomy 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000013459 approach Methods 0.000 description 1
- 230000009193 crawling Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 210000004379 membrane Anatomy 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention discloses a modification method for a cloth stamping acrylic resin coating material, wherein an acrylic resin, nitrocellulose, cellulose acetate and a solvent are subjected to mixing dissolving to prepare the coating material with a solid content of 20% so as to be coated. According to the present invention, the prepared coating material with the solid content of 20% is adopted to coated, such that surface release layer transfer is smoothly achieved in the case of no influence on the trimming property and the color layer and aluminum layer binding force, the large-scale industrial production is successfully achieved, and production efficiency and product quality stability are improved and the production cost is substantially reduced compared with the conventional coating material.
Description
Technical field
The present invention relates to the method for modifying of acrylic resin paint for a kind of boiling hot cloth.
Background technology
When boiling hot cloth is gold stamping for cloth with anodized aluminium, require coating to have certain rigidity and fragility to reach good transfer effect, and such coating resin is often large to the sticking power of BOPET, is difficult for shifting.Therefore, existing technical scheme is, before being coated with dye layer, is first coated with one deck release layer, makes the chromatograph can be separated with base membrane layer.Because this layer of release layer is very thin and water white transparency, whether have holiday and the problem such as crawling even, greatly increased the risk that gilding film is produced if being difficult in process of production detect, affect the stability of product, increased a lot of production costs simultaneously.
Summary of the invention
Technical problem to be solved by this invention is just to provide the method for modifying of acrylic resin paint for a kind of boiling hot cloth, by the modification to coating resin acrylic resin, do not affecting under its prerequisite of peeling off effect, reduce its sticking power to basement membrane, reached and need not be coated with release layer and also can have good transfer effect.
For solving the problems of the technologies described above, the present invention adopts following technical scheme: the method for modifying of acrylic resin paint for a kind of boiling hot cloth, using acrylic resin and soluble cotton, cellulose acetate and solvent dissolving to be mixed with solid content is that 20% coating is coated with.
As preferably, the blending ratio of described acrylic resin, soluble cotton, cellulose acetate and solvent is as follows: acrylic resin 30～36: soluble cotton and cellulose acetate 4～10: solvent 60.
As preferably, described solvent is butanone or pimelinketone.
As preferably, the molecular weight of described acrylic resin is 70000～90000.
The present invention has mainly adopted two kinds of approach to solve the problem of reduction coating to basement membrane sticking power:
The one, by using PMMA(acrylic resin) and NC(soluble cotton), CAB(cellulose acetate) these coating blend very little to basement membrane sticking power, to reduce its sticking power.
The 2nd, by adopting the PMMA(acrylic resin of the wider plastics level of molecular weight distribution) do chromatograph coating.
Finally be mixed with solid content and be 20% coating coating, in the situation that not affecting trimming and chromatograph aluminium lamination bonding force, realizing smoothly face release layer shifts, and successfully realize large-scale industrial production, this coating, compare with existing coating, not only improved the stability of production efficiency and quality product, and greatly reduce production cost.
Embodiment
Embodiment, adopt the PMMA(acrylic resin that molecular weight is 70000～90000), with NC(soluble cotton), CAB(cellulose acetate) mix, blending ratio (weight) is as follows: acrylic resin 30～36, modifier (comprising NC and CAB) 4～10, solvent 60.With butanone, pimelinketone equal solvent dissolves, and is finally mixed with solid content and is 20% coating coating.
For scalding a method of modifying for acrylic resin paint for cloth, the method comprises following processing step:
1. first by formula, solvent is added in reactor, be heated to 70 ℃ of left and right simultaneously and stir;
When stirring PMMA(acrylic resin) and CAB(cellulose acetate) in input reactor, stir about 1 hour;
After 3 solids such as grade all dissolve and mix, measure solid content (38～42%), and add butanone to adjust accordingly according to theoretical value;
4. slowly stir half an hour last feed filling.
Claims (4)
1. a method of modifying for acrylic resin paint for boiling hot cloth, is characterized in that: using acrylic resin and soluble cotton, cellulose acetate and solvent dissolving to be mixed with solid content is that 20% coating is coated with.
2. the method for modifying of acrylic resin paint for boiling hot cloth according to claim 1, is characterized in that: the blending ratio of described acrylic resin, soluble cotton, cellulose acetate and solvent is as follows: acrylic resin 30～36: soluble cotton and cellulose acetate 4～10: solvent 60.
3. the method for modifying of acrylic resin paint for boiling hot cloth according to claim 1, is characterized in that: described solvent is butanone or pimelinketone.
4. the method for modifying of acrylic resin paint for boiling hot cloth according to claim 1, is characterized in that: the molecular weight of described acrylic resin is 70000～90000.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310561944.1A CN103694816A (en) | 2013-11-12 | 2013-11-12 | Modification method for cloth stamping acrylic resin coating material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310561944.1A CN103694816A (en) | 2013-11-12 | 2013-11-12 | Modification method for cloth stamping acrylic resin coating material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103694816A true CN103694816A (en) | 2014-04-02 |
Family
ID=50356490
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310561944.1A Pending CN103694816A (en) | 2013-11-12 | 2013-11-12 | Modification method for cloth stamping acrylic resin coating material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103694816A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109321041A (en) * | 2018-09-17 | 2019-02-12 | 浙江大高包装材料有限公司 | A kind of release coating of boiling hot cloth type anodized aluminium and preparation method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5450532A (en) * | 1977-09-30 | 1979-04-20 | Kansai Paint Co Ltd | Low temperature-curable high solid coating composition |
| CN1070931A (en) * | 1992-11-04 | 1993-04-14 | 王南 | Pit-sheel emulsion type coating stuff for leather |
| US5450532A (en) * | 1993-04-29 | 1995-09-12 | Hewlett-Packard Company | Cache memory system for a color ink jet printer |
| CN101928492A (en) * | 2010-09-01 | 2010-12-29 | 浙江阳阳包装有限公司 | Specific coloring agent for electric aluminum coating and preparation method thereof |
| CN102876143A (en) * | 2012-08-31 | 2013-01-16 | 芜湖县双宝建材有限公司 | Marble paint and preparation method thereof |
-
2013
- 2013-11-12 CN CN201310561944.1A patent/CN103694816A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5450532A (en) * | 1977-09-30 | 1979-04-20 | Kansai Paint Co Ltd | Low temperature-curable high solid coating composition |
| CN1070931A (en) * | 1992-11-04 | 1993-04-14 | 王南 | Pit-sheel emulsion type coating stuff for leather |
| US5450532A (en) * | 1993-04-29 | 1995-09-12 | Hewlett-Packard Company | Cache memory system for a color ink jet printer |
| CN101928492A (en) * | 2010-09-01 | 2010-12-29 | 浙江阳阳包装有限公司 | Specific coloring agent for electric aluminum coating and preparation method thereof |
| CN102876143A (en) * | 2012-08-31 | 2013-01-16 | 芜湖县双宝建材有限公司 | Marble paint and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109321041A (en) * | 2018-09-17 | 2019-02-12 | 浙江大高包装材料有限公司 | A kind of release coating of boiling hot cloth type anodized aluminium and preparation method |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140402 |