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CN109437652A - A kind of enhancing gypsum reaction glue and its preparation method and application - Google Patents

A kind of enhancing gypsum reaction glue and its preparation method and application Download PDF

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Publication number
CN109437652A
CN109437652A CN201811357255.8A CN201811357255A CN109437652A CN 109437652 A CN109437652 A CN 109437652A CN 201811357255 A CN201811357255 A CN 201811357255A CN 109437652 A CN109437652 A CN 109437652A
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CN
China
Prior art keywords
parts
gypsum
sodium
polyethylene glycol
enhancing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811357255.8A
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Chinese (zh)
Inventor
曾强
何计宏
何金韦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chongqing Jian Gong Construction Industry Technology Research Institute Co Ltd
Chongqing Jiehong Viscose Research Institute Co Ltd
Original Assignee
Chongqing Jiehong Viscose Research Institute Co Ltd
Chongqing Jian Gong Construction Industry Technology Research Institute Co Ltd
Chongqing Construction Engineering Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by Chongqing Jiehong Viscose Research Institute Co Ltd, Chongqing Jian Gong Construction Industry Technology Research Institute Co Ltd, Chongqing Construction Engineering Group Co Ltd filed Critical Chongqing Jiehong Viscose Research Institute Co Ltd
Priority to CN201811357255.8A priority Critical patent/CN109437652A/en
Publication of CN109437652A publication Critical patent/CN109437652A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • C04B40/0042Powdery mixtures

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of enhancing gypsum reaction glue and its preparation method and application, and it includes sodium carbonate, diatomite, citric acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, pentaerythrite, polyethylene glycol, polyethylene glycol oxide ether, calcium carbonate, sorbierite etc. which, which reacts collagen material,.Enhancing gypsum reaction glue is used for gypsum partition board, assembled architecture gypsum cast in situs insulating layer, gypsum leveling putty, gypsum coating, plaster decoration line, gypsum adorned board, gypsum insulation material, the application property of plastering can be greatly improved, water resistance, adhesive strength, compression strength, solve conventional gypsum product picking, dispersion after water logging, bonding force is low, use the drawback that the time is short, remarkable in economical benefits improves, expand the use scope of plastering, support can be recycled, improve the utilization rate of national economy, reduce environmental pollution, it is the ideal adding raw materials of natural energy-saving product.

Description

A kind of enhancing gypsum reaction glue and its preparation method and application
Technical field
The invention belongs to the field of building materials, are to solve to apply because of improvement for replacing conventional gypsum slow setting glue specifically Low intensive problem not resistant to water is dropped between working hour, greatly improves the adhesive strength and soaking-resistant of plastering, extends stone The service life of cream product reduces production cost, accomplishes non-toxic and tasteless enhancing gypsum reaction glue and its preparation method and application.
Background technique
Domestic universal gypsum slow setting glue has only been accomplished to improve the application property of plastering at present, but substantially reduces gypsum The adhesive strength of product influences the water resistance of plastering, shortens the service life of plastering, increases the economy of user Burden, artificially increases overall cost.In order to improve such case, we have developed with great concentration this core material, accomplish Plastering construction is smooth, increases the adhesive strength and compression strength of plastering, improves the water resistance of plastering, make gypsum The service life of product increases, and expands the purposes of gypsum, the utilization rate for improving gypsum mineral resources thereby reduces nature The loss of resource.
Summary of the invention
In view of this, improving the quality of plastering as a practitioner conscientious, increase the purposes of gypsum, Assembled architecture and traditional architecture are promoted to the utilization rate of gypsum, has invented this enhancing gypsum reaction glue.The product improves The application property of plastering, water resistance, adhesive strength, compression strength.It is dissipated after solving conventional gypsum product picking, water logging Change, the drawback that bonding force is low, short using the time.Economic benefit is significantly improved, the use scope of plastering is expanded, support can follow Ring uses, and improves the utilization rate of national economy, reduces environmental pollution.
To realize the above-mentioned technical purpose, The technical solution adopted by the invention is as follows:
A kind of enhancing gypsum reaction glue, the enhancing gypsum reaction glue are prepared by following weight parts raw material: sodium carbonate 0.3-0.8 parts, 20-40 parts of diatomite, 1-2 parts of citric acid, 1-3 parts of sodium metasilicate, 2-5 parts of sodium gluconate, benzene sulfonic acid sodium salt 0.4-0.8 Part, 5-10 parts of pentaerythrite, 2-5 parts of polyethylene glycol, 0.01-0.04 parts of polyethylene glycol oxide ether, 20-40 parts of dry powder, sorbierite 10-30 parts.
Preferably as a kind of one kind of enhancing gypsum reaction glue of the present invention, the enhancing gypsum reaction glue is by following weight parts Raw material is prepared: 0.3 part of sodium carbonate, 30 parts of diatomite, 1.7 parts of citric acid, 1 part of sodium metasilicate, 3 parts of sodium gluconate, benzene sulfonic acid 0.4 part of sodium, 7 parts of pentaerythrite, 3 parts of polyethylene glycol, 0.04 part of polyethylene glycol oxide ether, 40 parts of dry powder, 13.56 parts of sorbierite.
Preferably as a kind of another kind of enhancing gypsum reaction glue of the present invention, the sodium carbonate, diatomite, citric acid, silicon Sour sodium, sodium gluconate, benzene sulfonic acid sodium salt, pentaerythrite, polyethylene glycol, polyethylene glycol oxide ether, dry powder, the granularity of sorbierite exist It is more than 300 mesh.
The present invention also provides a kind of preparation methods of above-mentioned enhancing gypsum reaction glue: by sodium carbonate, diatomite, lemon Acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, pentaerythrite, polyethylene glycol, polyethylene glycol oxide ether, dry powder, sorbierite are by weight Amount proportion is added in heating stirring machine, heats while stirring, to moisture content≤3% in material, stops heating, is put into cooling bucket It is interior to room temperature when, crushing filters to enhance gypsum reaction glue.
One kind of preparation method as present invention enhancing gypsum reaction glue preferably, is heated to 70 DEG C, stirring while stirring Time is 40 minutes.
The present invention also provides the application that above-mentioned enhancing is high reaction glue, by the enhancing gypsum react glue be used for gypsum every Wallboard, assembled architecture gypsum cast in situs insulating layer, gypsum leveling putty, gypsum coating, plaster decoration line, gypsum decorative Plate, gypsum insulation material.
The utility model has the advantages that
Enhancing gypsum provided by the invention reaction glue is used for gypsum partition board, assembled architecture gypsum cast in situs heat preservation Layer, gypsum leveling putty, gypsum coating, plaster decoration line, gypsum adorned board, gypsum insulation material, can greatly improve gypsum The application property of product, water resistance, adhesive strength, compression strength solve dispersion, bonding force after conventional gypsum product picking, water logging It is low, improved using time short drawback, remarkable in economical benefits, expand the use scope of plastering, support can be recycled, mention The high utilization rate of national economy, reduces environmental pollution, is the ideal adding raw materials of natural energy-saving product.
Detailed description of the invention
The present invention can be further illustrated by the nonlimiting examples that attached drawing provides;
Fig. 1 is the preparation flow figure that enhancing gypsum of the invention reacts glue.
Specific embodiment
In order to make those skilled in the art that the present invention may be better understood, with reference to the accompanying drawings and examples to this hair Bright technical solution further illustrates.
A kind of enhancing gypsum reaction glue, the enhancing gypsum reaction glue are prepared by following weight parts raw material: sodium carbonate 0.3-0.8 parts, 20-40 parts of diatomite, 1-2 parts of citric acid, 1-3 parts of sodium metasilicate, 2-5 parts of sodium gluconate, benzene sulfonic acid sodium salt 0.4-0.8 Part, 5-10 parts of pentaerythrite, 2-5 parts of polyethylene glycol, 0.01-0.04 parts of polyethylene glycol oxide ether, 20-40 parts of dry powder, sorbierite 10-30 parts.
The enhancing gypsum reaction glue is prepared by following raw materials: 0.3 part of sodium carbonate, 30 parts of diatomite, citric acid 1.7 Part, 1 part of sodium metasilicate, 3 parts of sodium gluconate, 0.4 part of benzene sulfonic acid sodium salt, 7 parts of pentaerythrite, 3 parts of polyethylene glycol, polyethylene glycol oxide ether 0.04 part, 40 parts of dry powder, 13.56 parts of sorbierite.
The sodium carbonate, diatomite, citric acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, pentaerythrite, polyethylene glycol, Polyethylene glycol oxide ether, dry powder, the granularity of sorbierite is more than 300 mesh.
The preparation method of enhancing gypsum reaction glue in the present embodiment, first reacts various oxide spinels in glue for enhancing gypsum Sodium, diatomite, citric acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, pentaerythrite, polyethylene glycol, polyethylene glycol oxide ether, round trip flight Powder, after sorbierite reheats reaction 40-60 minutes by setting weight part after mixing, when holding moisture≤3% after, it is to be cooled After crush, rear be sieved (300 mesh of vibrating screen) claims scale to be packaged, and specific production procedure is as shown in Figure 1.
The application of the enhancing gypsum reaction glue of this implementation, is used for gypsum partition board, assembly for enhancing gypsum reaction glue Formula building gypsum cast in situs insulating layer, gypsum leveling putty, gypsum coating, plaster decoration line, gypsum adorned board, gypsum are protected Adiabator, application property, water resistance, adhesive strength, compression strength, the solution conventional gypsum product that can greatly improve plastering fall Dispersion, bonding force are low after powder, water logging, are improved using time short drawback, remarkable in economical benefits, and that expands plastering uses model It encloses, supports can be recycled, improve the utilization rate of national economy, reduce environmental pollution, be that the ideal of natural energy-saving product adds Add raw material.Combined with specific embodiments below, the present invention is further illustrated.
Embodiment one
In the present embodiment, the enhancing gypsum reaction glue is prepared by following raw materials: 0.3 part of sodium carbonate, diatomite 30 Part, is gathered 1.7 parts of citric acid, 1 part of sodium metasilicate, 3 parts of sodium gluconate, 0.4 part of benzene sulfonic acid sodium salt, 7 parts of pentaerythrite, 3 parts of polyethylene glycol 0.04 part of ethylene oxide ether, 40 parts of dry powder, 13.56 parts of sorbierite.
In the present embodiment, the sodium carbonate, diatomite, citric acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, Ji Wusi Alcohol, polyethylene glycol, polyethylene glycol oxide ether, dry powder, the granularity of sorbierite is more than 300 mesh.
Embodiment two
In the present embodiment, the enhancing gypsum reaction glue is prepared by following raw materials: 0.8 part of sodium carbonate, diatomite 22 Part, 1.3 parts of citric acid, 2.4 parts of sodium metasilicate, 3.3 parts of sodium gluconate, 0.6 part of benzene sulfonic acid sodium salt, 8 parts of pentaerythrite, polyethylene glycol 3 Part, 0.03 part of polyethylene glycol oxide ether, 35 parts of dry powder, 23.57 parts of sorbierite.
In the present embodiment, the sodium carbonate, diatomite, citric acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, Ji Wusi Alcohol, polyethylene glycol, polyethylene glycol oxide ether, dry powder, the granularity of sorbierite is more than 300 mesh.
Embodiment three
In the present embodiment, the enhancing gypsum reaction glue is prepared by following raw materials: 0.5 part of sodium carbonate, diatomite 37 Part, 1.6 parts of citric acid, 2.1 parts of sodium metasilicate, 4.3 parts of sodium gluconate, 0.6 part of benzene sulfonic acid sodium salt, 6.6 parts of pentaerythrite, polyethylene glycol 2.4 parts, 0.035 part of polyethylene glycol oxide ether, 33 parts of dry powder, 11.865 parts of sorbierite.
In the present embodiment, the sodium carbonate, diatomite, citric acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, Ji Wusi Alcohol, polyethylene glycol, polyethylene glycol oxide ether, dry powder, the granularity of sorbierite is more than 300 mesh.
Example IV
In the present embodiment, the enhancing gypsum reaction glue is prepared by following raw materials: 0.45 part of sodium carbonate, diatomite 21 Part, 1.8 parts of citric acid, 2.8 parts of sodium metasilicate, 2.2 parts of sodium gluconate, 0.5 part of benzene sulfonic acid sodium salt, 9.8 parts of pentaerythrite, polyethylene glycol 3.2 parts, 0.02 part of polyethylene glycol oxide ether, 39 parts of dry powder, 19.23 parts of sorbierite.
In the present embodiment, the sodium carbonate, diatomite, citric acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, Ji Wusi Alcohol, polyethylene glycol, polyethylene glycol oxide ether, dry powder, the granularity of sorbierite is more than 300 mesh.
Embodiment five
In the present embodiment, the enhancing gypsum reaction glue is prepared by following raw materials: 0.45 part of sodium carbonate, diatomite 35 Part, 1.3 parts of citric acid, 2.7 parts of sodium metasilicate, 2 parts of sodium gluconate, 0.5 part of benzene sulfonic acid sodium salt, 5.2 parts of pentaerythrite, polyethylene glycol 2 Part, 0.02 part of polyethylene glycol oxide ether, 38 parts of dry powder, 12.83 parts of sorbierite.
In the present embodiment, the sodium carbonate, diatomite, citric acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, Ji Wusi Alcohol, polyethylene glycol, polyethylene glycol oxide ether, dry powder, the granularity of sorbierite is more than 300 mesh.
Embodiment six
In the present embodiment, the enhancing gypsum reaction glue is prepared by following raw materials: 0.55 part of sodium carbonate, diatomite 40 Part, 1.33 parts of citric acid, 1.5 parts of sodium metasilicate, 4 parts of sodium gluconate, 0.55 part of benzene sulfonic acid sodium salt, 8.8 parts of pentaerythrite, polyethylene glycol 2 parts, 0.03 part of polyethylene glycol oxide ether, 25 parts of dry powder, 16.24 parts of sorbierite.
In the present embodiment, the sodium carbonate, diatomite, citric acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, Ji Wusi Alcohol, polyethylene glycol, polyethylene glycol oxide ether, dry powder, the granularity of sorbierite is more than 300 mesh.
Embodiment seven
In the present embodiment, the enhancing gypsum reaction glue is prepared by following raw materials: 0.62 part of sodium carbonate, diatomite 37.61 parts, it is 1.6 parts of citric acid, 2.5 parts of sodium metasilicate, 2.2 parts of sodium gluconate, 0.45 part of benzene sulfonic acid sodium salt, 7.2 parts of pentaerythrite, poly- 2.8 parts of ethylene glycol, 0.02 part of polyethylene glycol oxide ether, 20 parts of dry powder, 25 parts of sorbierite.
In the present embodiment, the sodium carbonate, diatomite, citric acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, Ji Wusi Alcohol, polyethylene glycol, polyethylene glycol oxide ether, dry powder, the granularity of sorbierite is more than 300 mesh.
Embodiment eight
In the present embodiment, the enhancing gypsum reaction glue is prepared by following raw materials: 0.72 part of sodium carbonate, diatomite 20 Part, 1.24 parts of citric acid, 1.3 parts of sodium metasilicate, 3.1 parts of sodium gluconate, 0.75 part of benzene sulfonic acid sodium salt, 8.9 parts of pentaerythrite, poly- second two 4.8 parts of alcohol, 0.04 part of polyethylene glycol oxide ether, 33.85 parts of dry powder, 25.3 parts of sorbierite.
In the present embodiment, the sodium carbonate, diatomite, citric acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, Ji Wusi Alcohol, polyethylene glycol, polyethylene glycol oxide ether, dry powder, the granularity of sorbierite is more than 300 mesh.
Embodiment nine
In the present embodiment, the enhancing gypsum reaction glue is prepared by following raw materials: 0.77 part of sodium carbonate, diatomite 29.43 parts, it is 1.8 parts of citric acid, 2.2 parts of sodium metasilicate, 3.1 parts of sodium gluconate, 0.77 part of benzene sulfonic acid sodium salt, 6.6 parts of pentaerythrite, poly- 4.4 parts of ethylene glycol, 0.03 part of polyethylene glycol oxide ether, 22 parts of dry powder, 28.9 parts of sorbierite.
In the present embodiment, the sodium carbonate, diatomite, citric acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, Ji Wusi Alcohol, polyethylene glycol, polyethylene glycol oxide ether, dry powder, the granularity of sorbierite is more than 300 mesh.
Embodiment ten
In the present embodiment, the enhancing gypsum reaction glue is prepared by following raw materials: 0.8 part of sodium carbonate, diatomite 32.5 parts, 1.95 parts of citric acid, 1.34 parts of sodium metasilicate, 2.5 parts of sodium gluconate, 0.63 part of benzene sulfonic acid sodium salt, 6.1 parts of pentaerythrite, 4.35 parts of polyethylene glycol, 0.01 part of polyethylene glycol oxide ether, 30.02 parts of dry powder, 19.8 parts of sorbierite.
In the present embodiment, the sodium carbonate, diatomite, citric acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, Ji Wusi Alcohol, polyethylene glycol, polyethylene glycol oxide ether, dry powder, the granularity of sorbierite is more than 300 mesh.
Enhancing gypsum provided by the invention reacts glue, can greatly improve the application property of plastering, water resistance, be bonded by force Degree, compression strength solve conventional gypsum product picking, after water logging dispersion, bonding force it is low, using time short drawback, economical imitate Benefit significantly improves, and expands the use scope of plastering, supports can be recycled, and improves the utilization rate of national economy, reduces Environmental pollution is the ideal adding raw materials of natural energy-saving product.
A kind of enhancing gypsum reaction glue provided by the invention and its preparation method and application is described in detail above. The explanation of specific embodiment is merely used to help understand method and its core concept of the invention.It should be pointed out that for this technology For the those of ordinary skill in field, without departing from the principle of the present invention, several improvement can also be carried out to the present invention And modification, these improvements and modifications also fall within the scope of protection of the claims of the present invention.

Claims (6)

1. a kind of enhancing gypsum reacts glue, it is characterised in that: the enhancing gypsum react glue prepared by following weight parts raw material and At: 0.3-0.8 parts of sodium carbonate, 20-40 parts of diatomite, 1-2 parts of citric acid, 1-3 parts of sodium metasilicate, 2-5 parts of sodium gluconate, benzene sulfonic acid 0.4-0.8 parts of sodium, 5-10 parts of pentaerythrite, 2-5 parts of polyethylene glycol, 0.01-0.04 parts of polyethylene glycol oxide ether, dry powder 20-40 Part, 10-30 parts of sorbierite.
2. a kind of enhancing gypsum according to claim 1 reacts glue, it is characterised in that: the enhancing gypsum reaction glue is under It states raw material to be prepared: 0.3 part of sodium carbonate, 30 parts of diatomite, 1.7 parts of citric acid, 1 part of sodium metasilicate, sodium gluconate 3 Part, 0.4 part of benzene sulfonic acid sodium salt, 7 parts of pentaerythrite, 3 parts of polyethylene glycol, 0.04 part of polyethylene glycol oxide ether, 40 parts of dry powder, sorbierite 13.56 parts.
3. a kind of enhancing gypsum according to claim 1 or 2 reacts glue, it is characterised in that: the sodium carbonate, diatomite, Citric acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, pentaerythrite, polyethylene glycol, polyethylene glycol oxide ether, dry powder, sorbierite Granularity more than 300 mesh.
4. a kind of preparation method of enhancing gypsum reaction glue as described in any one of claims 1-3, it is characterised in that: by carbonic acid Sodium, diatomite, citric acid, sodium metasilicate, sodium gluconate, benzene sulfonic acid sodium salt, pentaerythrite, polyethylene glycol, polyethylene glycol oxide ether, round trip flight Powder, sorbierite are added in heating stirring machine by weight ratio, heat while stirring, to moisture content≤3% in material, stop adding Heat, when being put into cooling bucket to room temperature, crushing filters to enhance gypsum reaction glue.
5. a kind of preparation method of enhancing gypsum reaction glue according to claim 4, it is characterised in that: heat while stirring To 70 DEG C, mixing time is 40-60 minutes.
6. a kind of application of enhancing gypsum reaction glue according to claim 1-3, it is characterised in that: by the increasing Strong gypsum reaction glue is applied for gypsum partition board, assembled architecture gypsum cast in situs insulating layer, gypsum leveling putty, gypsum Material, plaster decoration line, gypsum adorned board, gypsum insulation material.
CN201811357255.8A 2018-11-15 2018-11-15 A kind of enhancing gypsum reaction glue and its preparation method and application Pending CN109437652A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07172899A (en) * 1994-10-03 1995-07-11 Hanasakadan:Kk Ornamental material for building
CN1454945A (en) * 2003-05-30 2003-11-12 重庆大学 Environmental-protection type gypsum-based putty powder for building

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07172899A (en) * 1994-10-03 1995-07-11 Hanasakadan:Kk Ornamental material for building
CN1454945A (en) * 2003-05-30 2003-11-12 重庆大学 Environmental-protection type gypsum-based putty powder for building

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Effective date of registration: 20190614

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Applicant before: Chongqing Jian Gong Construction Industry Technology Research Institute Co., Ltd.

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Application publication date: 20190308