CN108157375A - A kind of bactericidal composition containing flutianil and its application - Google Patents
A kind of bactericidal composition containing flutianil and its application Download PDFInfo
- Publication number
- CN108157375A CN108157375A CN201611117539.0A CN201611117539A CN108157375A CN 108157375 A CN108157375 A CN 108157375A CN 201611117539 A CN201611117539 A CN 201611117539A CN 108157375 A CN108157375 A CN 108157375A
- Authority
- CN
- China
- Prior art keywords
- flutianil
- powdery mildew
- pyraclostrobin
- trifloxystrobin
- bactericidal composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- KGXUEPOHGFWQKF-ZCXUNETKSA-N flutianil Chemical compound COC1=CC=CC=C1N(CCS\1)C/1=C(C#N)/SC1=CC(C(F)(F)F)=CC=C1F KGXUEPOHGFWQKF-ZCXUNETKSA-N 0.000 title claims abstract description 92
- 239000000203 mixture Substances 0.000 title claims abstract description 40
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 24
- 241000221785 Erysiphales Species 0.000 claims abstract description 51
- 239000005869 Pyraclostrobin Substances 0.000 claims abstract description 35
- 239000005857 Trifloxystrobin Substances 0.000 claims abstract description 35
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 claims abstract description 35
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 claims abstract description 35
- 239000005784 Fluoxastrobin Substances 0.000 claims abstract description 24
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims abstract description 24
- 239000004480 active ingredient Substances 0.000 claims abstract description 7
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- 229920005551 calcium lignosulfonate Polymers 0.000 description 4
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- 239000006184 cosolvent Substances 0.000 description 3
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- VBBRYJMZLIYUJQ-UHFFFAOYSA-N cyclopropanone Chemical compound O=C1CC1 VBBRYJMZLIYUJQ-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000010410 dusting Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- GQBJGCRYICJRII-UHFFFAOYSA-N formaldehyde 2-(2-phenylethyl)phenol Chemical compound C=O.C1(=CC=CC=C1)CCC1=C(C=CC=C1)O GQBJGCRYICJRII-UHFFFAOYSA-N 0.000 description 1
- XUZHLZDRCCUWEV-UHFFFAOYSA-N formaldehyde;methyl naphthalene-1-sulfonate Chemical compound O=C.C1=CC=C2C(S(=O)(=O)OC)=CC=CC2=C1 XUZHLZDRCCUWEV-UHFFFAOYSA-N 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 229960002900 methylcellulose Drugs 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 210000003470 mitochondria Anatomy 0.000 description 1
- 230000002438 mitochondrial effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 229940068968 polysorbate 80 Drugs 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229940068984 polyvinyl alcohol Drugs 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003548 thiazolidines Chemical class 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of bactericidal composition containing flutianil, active ingredient is made of A and B, and A flutianil, B are any one in Fluoxastrobin, pyraclostrobin and trifloxystrobin, and the mass ratio of A and B are 1 ︰, 50~50 ︰ 1.The composition synergistic effect is apparent, and preventive effect is high, is suitable for preventing the multiple diseases on gourd, fruit and vegetable, is particularly suitable for preventing powdery mildew.
Description
Technical field
The present invention relates to a kind of bactericidal composition more particularly to one kind with flutianil Bactericidal composites as main component
Object and its application for preventing corps diseases, belong to technical field of pesticide.
Background technology
Powdery mildew is the plant disease as caused by the Erysiphaceae (Erysiphacesae) in fungi.Such as：By standing grain white powder
Cereal powdery mildew caused by bacterium (Ery-siphe graminis)；By Siberian cocklebur monofilament shell (Sphaerotheca fuliginea)
The powdery mildew of the various plants such as caused melon, beans, crudefiber crop；It is careless as caused by strawberry snag shell (Uncinula necator)
Certain kind of berries powdery mildew；Mulberry, pears, persimmon, walnut, chestnut, lichee, papaya etc. as caused by hazel ball pin shell (Phyllactinia corylea)
The powdery mildew of more than 80 kinds of trees；The powdery mildew of Flowers of Rosa as caused by rose monofilament shell (Sphaerotheca pannosa)
Deng.
In the prevention of powdery mildew, benzimidazole, triazole bactericidal agent are relied primarily at present.These medicaments are because long-term
Using different degrees of drug resistance has been produced, control effect reduces.In addition, triazole type medicament when dosage is big to crop
Growth has inhibiting effect, easily causes poisoning.
Flutianil be thiazolidines fungicide, molecular formula：C19H14F4N20S2, molecular weight 426.5.The medicament passes through suppression
The mycelia of pathogen processed grows and takes effect.Flutianil is in extremely low concentration (10mg/L) to diseases such as the powdery mildews of gourd, fruit and vegetable
The tall and erect effect of evil tool.
For flutianil as a kind of new type bactericide, current production and application cost is higher, and individually makes for a long time
With also there is very big resistance risk.
Invention content
The object of the present invention is to provide a kind of synergistic effect is apparent, good, the at low cost, resistance risk to powdery mildew control effect
Low bactericidal composition.
It is a further object of the present invention to provide the applications of the bactericidal composition.
Inventor has been surprisingly found that flutianil and Fluoxastrobin or pyrrole by a large amount of indoor biometrics and field control effectiveness test
Azoles kresoxim-methyl or trifloxystrobin after mixture, have significant synergistic effect to diseases such as powdery mildews in certain proportion.
The Fluoxastrobin (azoxystrobin)：Strobilurin fungicide, molecular formula C22H17N3O5.Efficiently, extensively
Spectrum, to almost all of mycota (Ascomycotina, Basidiomycotina, Mastigomycotina and Deuteromycotina) disease such as white powder
Disease, rust, glume blight, net blotch, downy mildew, late blight, epidemic disease, rice blast etc. have good activity.It is sprayed available for cauline leaf
Mist, seed treatment can also carry out soil treatment, be mainly used for cereal, rice, peanut, grape, potato, fruit tree, vegetables, coffee
Coffee, lawn etc..The mechanism of action destroys the energy synthesis of germ, tool protection is treated and rooted out to inhibit sick fungal mitochondria breathing
Triple function.
The pyraclostrobin (pyraclostrobin)：Strobilurin fungicide, molecular formula C19H18ClN3O4。
Wide-spectrum bactericide has protection, treatment, blade infiltration conduction.For mitochondrial respiratory inhibitor.Pyraclostrobin is to cucumber
Powdery mildew, downy mildew and banana freckle, leaf spot, the late blight of potato, downy mildew of garpe etc. have very good effect.
The trifloxystrobin (trifloxystrobin)：Strobilurin fungicide, molecular formula C20H19F3N2O4.Tool
Have efficiently, wide spectrum, protection, treat, root out, permeating, systemic activity, resistance of rainwater washing against, the lasting period length etc. characteristics.Except to white powder
Disease, leaf spot have outside special efficacy, have good work to rust, downy mildew, late blight, damping-off, scab of apple, sclerotinia sclerotiorum
Property.
Fluoxastrobin, pyraclostrobin, trifloxystrobin are strobilurin fungicides well known in the art, can be by each
Kind commercial channel obtains.
In order to overcome the deficiencies of the prior art, the technical scheme is that in this way solving：It is a kind of to contain flutianil's
Bactericidal composition, containing effective constituents A and B, A flutianil, B are in Fluoxastrobin, pyraclostrobin and trifloxystrobin
Any one, A is 1 ︰, 50~50 ︰ 1 with B mass ratioes, and preferred mass ratio is 1:30~30:1.
The composition can be processed into the arbitrary dosage form agriculturally allowed, and preferable dosage form has missible oil, microemulsion, water and milk
Agent, suspending agent, suspension emulsion, wettable powder or water dispersible granules.
In the bactericidal composition of the present invention, the mass accumulation percentage composition of effective constituents A and B are 5%~85%, remaining is
Auxiliary agent and filler or diluent.
The dosage form of above-mentioned bactericidal composition further includes auxiliary agent and other contributes to drug effect in addition to including effective constituents A and B
The substance of performance.Missible oil includes organic solvent, cosolvent and emulsifier；Microemulsion includes organic solvent, emulsifier and water；Water and milk
Agent includes organic solvent, dispersant, emulsifier and water；Suspending agent includes water, dispersant, thickener, antifreezing agent and wetting agent；It can
Wet powder includes wetting agent, dispersant and filler；Water dispersible granules include dispersant, disintegrant, filler and wetting agent.More than
All it is to commonly use in pesticidal preparations or allow the various composition used, is not particularly limited, specific ingredient and dosage will according to formula
It asks and is determined by simple experiment.Such as：
Organic solvent may be selected isopropanol, dimethylbenzene, N,N-dimethylformamide, ring ethyl ketone, toluene, dimethyl sulfoxide (DMSO),
Methanol, ethyl alcohol, trimethyl cyclic ethylene ketone, n-octylpyrrolidone, N-Methyl pyrrolidone, propyl alcohol, butanol, ethylene glycol, diethyl
It is one or more in glycol, ethylene glycol monomethyl ether, butyl ether, ethyl acetate, vegetable oil.
N-Methyl pyrrolidone, dimethylformamide, ethyl alcohol, the third ethyl alcohol, one kind in acetone or more may be selected in cosolvent
Kind.
Sodium lignin sulfonate, calcium lignosulfonate, pull open powder, calcium dodecyl benzene sulfonate, polycarboxylic acids may be selected in dispersant
Salt, alkyl benzene sulfonate calcium salt, alkyl phenol polyoxyethylene ether, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, glycerin fatty
It is one or more in acid ester polyoxyethylene ether.
Emulsifier may be selected that agricultural emulsifier NO.600 (phenyl phenol polyoxyethyl ether), (phenethyl phenol polyoxyethanyl gathers agriculture breast 1601
Propenyl ether), agriculture breast No. 500 (alkyl benzene calcium sulfonates), OP series phosphate (thermally coupled distillation columns), No. 600
Phosphate (phenyl phenol polyoxyethanyl ether phosphate), styrene polyoxyethylene rice ammonium sulfate, alkyl biphenyl ether disulfonic acid magnesium salts,
Triethanolamine salt, agriculture breast 400 (benzyl xylenol polyoxyethyl ether), Nongru-700 number (alkyl phenolic resin polyoxyethyl ether),
Agriculture breast 36 (phenethyl phenol formaldehyde resin polyoxyethyl ether), agriculture breast 1600 (phenethyl phenol polyoxyethanyl polypropylene-base ether),
No. 33 ethylene oxide-propylene oxide block copolymer, OP serial (nonylphenol polyoxyethylene ether), agriculture breast (alkylaryl polyoxies third
Alkene polyoxyethylene ether), agriculture breast 34 (alkylaryl polyoxyethylene poly-oxygen propylene aether), Span series (sorbitol anhydride monostearate
Ester), TWEEN Series (sorbitan fatty acid ester polyoxyethylene ether), one kind in AEO serial (fat alcohol alcohol polyoxyethylene ether)
It is or a variety of.
Antifreezing agent may be selected one or more in glycerine, urea, ethylene glycol, propylene glycol.
Methyl naphthalene sulfonate formaldehyde condensate, lauryl sodium sulfate, Negel, alkylbenzene may be selected in wetting agent
It is one or more in sulfoacid calcium, tea seed cake, spaonin powder, silkworm excrement, spaonin powder, bay alcohol radical sodium sulphate, washing powder, pull open powder.
One kind in ammonium sulfate, urea, bentonite, aluminium chloride, citric acid, succinic acid, sodium bicarbonate may be selected in disintegrant
It is or a variety of.
Thickener may be selected in xanthans, hydroxymethyl cellulose, methylcellulose, aluminum magnesium silicate, polyvinyl alcohol it is a kind of or
It is a variety of.
White Carbon black, ridge soil, precipitated calcium carbonate, talcum, montmorillonite or convex-concave stick stone, float stone, brickbat, Hai Pao may be selected in filler
It is one or more in stone or bentonite and non-adsorbent calcium soil or sand.
Product described in the invention can be provided in the form of finished product preparation, i.e., each substance has mixed in composition, combination
The ingredient of object can also be provided with unit dose form, directly mixed, be then diluted to required in proportion in bucket or tank using preceding
Concentration.
The bactericidal composition of the present invention is particularly suitable for prevention powdery mildew.The composition of the present invention can be by common method
Using such as cast, injection, spraying, dusting, distribution or smoke, amount of application changes with weather condition or crop condition.
Compared with prior art, the present invention its advantage is：1st, composition synergistic effect is apparent, and preventive effect is notable compared with single dose
It improves；2nd, after drug effect improves, the effective ingredient consumption in field declines, and reduces production and application cost, reduces pesticide residue
And environmental pollution；3rd, composition is made of the active ingredient of different role mechanism, and action site increases, and is conducive to overcome and delay
The generation of germ drug resistance.
Specific embodiment
The present composition has apparent synergistic function to Powdery Mildew etc., rather than just two kinds of pharmacy effects
Simple addition, this can from following toxicity test test result in be clear that.
Bioassay example 1：Composition tests the Toxicity Determination of cucurbits powdery mildew bacterium
Subjects are cucumber powdery mildew's pathogen (Sphaerotheca fuliginea).
Test method：Reference《People's Republic of China (PRC) agricultural industry criteria NY/T 1156.11-2008》.Choose growth potential
Consistent potting two panels leaf period cucumber seedling, is sprayed with Potter spray towers under 50PSI pressure, per basin 5mL.Each medicament is set
Put 5 concentration gradients.It is 3 × 10 to carry out inoculum density afterwards for 24 hours5The cucumber powdery mildew's pathogen conidial suspension of a spore/mL.
To spray the cucumber seedling of equivalent clear water as blank control.Cucumber seedling is put into greenhouse after inoculation and is cultivated.After 10d, according to cucumber
The morbidity grade scale investigation disease index of powdery mildew, and calculate control effect.
Powdery mildew of cucumber severity Scaling standard：
0 grade：Blade disease-free spot；
1 grade：Lesion area accounts for the area of entire blade below 5%；
3 grades：Lesion area accounts for the 6%~10% of the area of entire blade；
5 grades：Lesion area accounts for the 11%~25% of entire blade area；
7 grades：Lesion area accounts for the 25%~50% of entire blade area；
9 grades：Lesion area accounts for more than 50% entire blade area.
The expection effect (i.e. theoretical control effect, %) of mixture of active principles determined using Colby formula and with observation
To effect compare：
Colby formula：E=X+Y-X*Y/100
E：When active components A uses a concentration of a, active constituent B that compositions contemplated during a concentration of b is used to imitate in composition
Power.
X：Effect when active components A dosage is a.
Y：Effect when active constituent B dosages are b.
Illustrate that mixture has synergistic effect when the practical control effect observed is more than expected preventive effect.
Toxicity test result is referring to table 1 to table 3.
1 flutianil of table is with azoxystrobin compound to the pot experiment measurement result of cucumber powdery mildew's pathogen
2 flutianil of table compounds the pot experiment measurement result to cucumber powdery mildew's pathogen with pyraclostrobin
3 flutianil of table compounds the pot experiment measurement result to cucumber powdery mildew's pathogen with trifloxystrobin
It is anti-that result of the test shows that flutianil is compounded in a certain range with Fluoxastrobin or pyraclostrobin or trifloxystrobin
Cucumber powdery mildew's pathogen is controlled, there is synergistic effect.
In order to make the purpose , technical scheme and advantage of the present invention be clearer, the present invention is real with preparation in detail below
Example illustrates, but the present invention is limited to absolutely not these examples.As described below is only the preferable embodiment of the present invention, is only used to solve
The present invention is released, therefore can not be interpreted as the limitation to the scope of the claims of the present invention.It should be pointed out that all essences in the present invention
All any modification, equivalent and improvement done within refreshing and principle etc., should all be included in the protection scope of the present invention.Cause
This, the protection domain of patent of the present invention should be determined by the appended claims.
Missible oil embodiment
Pesticide active ingredient, emulsifier, solvent are mixed in proportion, are mixed in modulation kettle, until completely dissolved,
Remaining solvent is slowly added into again, uniform oil phase is obtained after being sufficiently stirred, missible oil product is made.
Embodiment 1,51%flutianil 〃 Fluoxastrobin missible oil
Flutianil 50%, Fluoxastrobin 1%, agriculture breast No. 500 2% (emulsifiers), dimethylbenzene (solvent) are supplemented to
100%.
Embodiment 2,31%flutianil 〃 Fluoxastrobin missible oil
Flutianil 30%, Fluoxastrobin 1%, POLYSORBATE 80 3% (emulsifier), toluene (solvent) are supplemented to 100%.
Embodiment 3,51%flutianil 〃 pyraclostrobin missible oils
Flutianil 50%, pyraclostrobin 1%, agricultural emulsifier NO.600 2% (emulsifier), dimethylbenzene (solvent) are supplemented to
100%.
Embodiment 4,31%flutianil 〃 pyraclostrobin missible oils
Flutianil 30%, pyraclostrobin 1%, agriculture breast No. 1,600 3% (emulsifiers), toluene (solvent) are supplemented to
100%.
Embodiment 5,51%flutianil 〃 trifloxystrobin missible oil
Flutianil 50%, trifloxystrobin 1%, agriculture breast No. 500 2% (emulsifiers), dimethylbenzene (solvent) are supplemented to
100%.
Embodiment 6,31%flutianil 〃 trifloxystrobin missible oil
Flutianil 30%, trifloxystrobin 1%, agriculture breast No. 1,601 3% (emulsifiers), toluene (solvent) are supplemented to 100%.
Microemulsion, aqueous emulsion embodiment
By each group distribution ratio, active component is dissolved in solvent and cosolvent, adds in surfactant, is uniformly mixed system
Obtain oil phase.Water-soluble component and water are mixed to prepare water phase, then oil phase is added in water phase or water phase is added in oil phase, side edged
Microemulsion or aqueous emulsion is made in stirring.
Embodiment 7,5%flutianil 〃 azoxystrobin microemulsions
Flutianil 2.5%, Fluoxastrobin 2.5%, cyclohexanol (solvent) 10%, agriculture breast No. 500 8% (emulsifier), agricultures
Newborn No. 600 5% (emulsifiers), agriculture breast No. 1,600 5% (emulsifiers), sldium lauryl sulfate 2% (wetting agent), ethylene glycol 5% are (anti-
Freeze agent), water be supplemented to 100%
Embodiment 8,11%flutianil 〃 azoxystrobin water emulsions
Flutiani l0%, Fluoxastrobin 1%, DMF (solvent) 5%, toluene 8% (solvent), glycerine (antifreezing agent) 5%, benzene
Ethyl phenol polyethenoxy ether (emulsifier) 10%, calcium dodecyl benzene sulfonate (wetting agent) 5%, water are supplemented to 100%
Embodiment 9,5%flutianil 〃 pyraclostrobin microemulsions
Flutianil 2.5%, pyraclostrobin 2.5%, toluene 8% (solvent), agriculture breast No. 500 8% (emulsifier), agricultures
Newborn No. 600 5% (emulsifiers), agriculture breast No. 1,600 5% (emulsifiers), sldium lauryl sulfate 2% (wetting agent), ethylene glycol 5% are (anti-
Freeze agent), water be supplemented to 100%
Embodiment 10,11%flutianil 〃 pyraclostrobin aqueous emulsions
Flutianil 10%, pyraclostrobin 1%, DMF (solvent) 5%, cyclohexanol (solvent) 10%, glycerine are (antifreeze
Agent) 5%, phenethyl phenol polyethenoxy ether (emulsifier) 10%, calcium dodecyl benzene sulfonate (wetting agent) 5%, water is supplemented to
100%
Embodiment 11,5%flutianil 〃 trifloxystrobin microemulsions
Flutianil 2.5%, trifloxystrobin 2.5%, toluene 8% (solvent), agriculture breast No. 500 8% (emulsifier), agriculture breasts
No. 600 5% (emulsifiers), agriculture breast No. 1,600 5% (emulsifiers), sldium lauryl sulfate 2% (wetting agent), ethylene glycol 5% are (antifreeze
Agent), water be supplemented to 100%
Embodiment 12,11%flutianil 〃 trifloxystrobin water emulsions
Flutianil0%, trifloxystrobin 1%, DMF (solvent) 5%, cyclohexanol (solvent) 10%, glycerine (antifreezing agent) 5%,
Phenethyl phenol polyethenoxy ether (emulsifier) 10%, calcium dodecyl benzene sulfonate (wetting agent) 5%, water are supplemented to 100%
Suspension emulsion embodiment
The each components such as active ingredient, dispersant, wetting agent, antifoaming agent, thickener and water are mixed in the ratio of formula
It is even, semi-finished product are obtained after sand milling or high speed shear, mends to be mixed with water after analysis and filter up to suspending agent.
Stable dense suspension first is made in solid active ingredient.Using high-shear mixer, by liquid active ingredient breast
Liquid phase is added in suspension, and suspension emulsion is made.
Embodiment 13,31%flutianil 〃 Fluoxastrobin suspending agents
Flutianil 1%, Fluoxastrobin 30%, sodium lignin sulfonate (dispersant) 5%, alkyl phenol polyoxyethylene ether 8%
(wetting agent), propylene glycol 2% (antifreezing agent), xanthans 1% (thickener), organosilicon 2% (antifoaming agent), water are supplemented to 100%
Embodiment 14,51%flutianil 〃 Fluoxastrobin suspending agents
Flutianil 1%, Fluoxastrobin 50%, calcium lignosulfonate (dispersant) 5%, alkyl phenol polyoxyethylene ether 8%
(wetting agent), propylene glycol 2% (antifreezing agent), xanthans 1% (thickener), organosilicon 2% (antifoaming agent), water are supplemented to 100%
Embodiment 15,31%flutianil 〃 pyraclostrobin suspending agents
Flutianil 1%, pyraclostrobin 30%, calcium lignosulfonate (dispersant) 6%, alkyl phenol polyoxyethylene ether
6% (wetting agent), propylene glycol 2% (antifreezing agent), xanthans 1% (thickener), organosilicon 2% (antifoaming agent), water are supplemented to
100%
Embodiment 16,51%flutianil 〃 pyraclostrobin suspension emulsions
Flutianil 1%, pyraclostrobin 50%, sodium lignin sulfonate (dispersant) 5%, alkyl phenol polyoxyethylene ether
6% (wetting agent), propylene glycol 2% (antifreezing agent), xanthans 1% (thickener), organosilicon 2% (antifoaming agent), water are supplemented to
100%
Embodiment 17,31%flutianil 〃 trifloxystrobin suspending agents
Flutianil 1%, trifloxystrobin 30%, calcium lignosulfonate (dispersant) 8%, alkyl phenol polyoxyethylene ether 8%
(wetting agent), propylene glycol 2% (antifreezing agent), xanthans 1% (thickener), organosilicon 2% (antifoaming agent), water are supplemented to 100%
Embodiment 18,51%flutianil 〃 trifloxystrobin suspending agents
Flutianil 1%, trifloxystrobin 50%, sodium lignin sulfonate (dispersant) 7%, alkyl phenol polyoxyethylene ether 8%
(wetting agent), propylene glycol 2% (antifreezing agent), xanthans 1% (thickener), organosilicon 2% (antifoaming agent), water are supplemented to 100%
Water dispersible granules embodiment
Pesticide activity component, auxiliary agent and filler are mixed in proportion, through air-flow crushing, then add the water of 15-20%, through pinching
It closes, be granulated, is dry, water dispersible granules product is made in screening.Capital equipment：Mixing machine, airslide disintegrating mill, kneader, extruding are made
Grain machine, drying equipment (drying chamber or fluid bed).
Embodiment 19,85%flutianil 〃 azoxystrobin water dispersible granules
Flutianil 50%, Fluoxastrobin 35%, neopelex 2% (wetting agent), sodium lignin sulfonate 4%
(dispersant), ammonium sulfate 2% (disintegrant), kaolin (filler) to 100%
Embodiment 20,85%flutianil 〃 pyraclostrobin water dispersible granules
Flutianil 50%, pyraclostrobin 35%, neopelex 2% (wetting agent), lignin sulfonic acid
Sodium 5% (dispersant), ammonium sulfate 3% (disintegrant), White Carbon black (filler) to 100%
Embodiment 21,85%flutianil 〃 trifloxystrobin water dispersible granules
Flutianil 45%, trifloxystrobin 40%, neopelex 2% (wetting agent), sodium lignin sulfonate 6%
(dispersant), ammonium sulfate 2% (disintegrant), talcum powder (filler) to 100%
Wettable powder embodiment
Pesticide activity component, auxiliary agent, filler are mixed in proportion, obtained wettable powder is remixed after air-flow crushing.It is main
Want equipment：Mixing machine, airslide disintegrating mill.
Embodiment 22,50%flutianil 〃 Fluoxastrobin wettable powders
Flutianil 15%, Fluoxastrobin 35%, bay alcohol radical sodium sulphate 4% (wetting agent), mersolates 7%
(dispersant), white carbon 8% (filler), kaolin (filler) to 100%
Embodiment 23,11%flutianil 〃 Fluoxastrobin wettable powders
Flutianil 1%, Fluoxastrobin 10%, bay alcohol radical sodium sulphate 4% (wetting agent), mersolates 7% (point
Powder), white carbon 8% (filler), talcum powder (filler) to 100%
Embodiment 24,50%flutianil 〃 pyraclostrobin wettable powders
Lutianil 10%, pyraclostrobin 40%, bay alcohol radical sodium sulphate 4% (wetting agent), mersolates
7% (dispersant), white carbon 8% (filler), diatomite (filler) to 100%
Embodiment 25,11%flutianil 〃 pyraclostrobin wettable powders
Flutianil 1%, pyraclostrobin 10%, bay alcohol radical sodium sulphate 4% (wetting agent), mersolates
7% (dispersant), white carbon 8% (filler), kaolin (filler) to 100%
Embodiment 26,50%flutianil 〃 trifloxystrobin wettable powders
Flutianil 5%, trifloxystrobin 45%, bay alcohol radical sodium sulphate 4% (wetting agent), mersolates 7% (point
Powder), white carbon 8% (filler), diatomite (filler) to 100%
Embodiment 27,11%flutianil 〃 trifloxystrobin wettable powders
Flutianil 1%, trifloxystrobin 10%, bay alcohol radical sodium sulphate 4% (wetting agent), mersolates 7% (point
Powder), white carbon 8% (filler), talcum powder (filler) to 100%
Field information example 1：Flutianil is with azoxystrobin compound to the field control effectiveness test of powdery mildew of cucumber
Four meeting of test site Guangdong.Test medicine and dosage are shown in Table 4, often handle 4 cells and repeat, each plot area 20
Square metre.Carry out first time dispenser in the early stages of disease, even spraying is sprayed onto until blade drips, using clear water processing to be empty
White control.Second of medicine is applied after 7 days.The incidence of 7 days investigation powderys mildew of cucumber before first time medicine and after second of medicine.Often
Cell is using 5 points of samplings, and every is investigated two plants, and every plant is investigated all blades, and the percentage of entire leaf area is accounted for lesion area
It is recorded to be classified.Calculate each processing disease index and control effect.
Grade scale：
0 grade：Disease-free spot；
1 grade：Lesion area accounts for less than 5% entire leaf area；
3 grades：Lesion area accounts for the 6%-15% of entire leaf area；
5 grades：Lesion area accounts for the 16%-25% of entire leaf area；
7 grades：Lesion area accounts for the 26%-50% of entire leaf area；
9 grades：Lesion area accounts for more than 50% entire leaf area.
Drug effect computational methods：
As can be seen from Table 4：Flutianil, Fluoxastrobin single dose are respectively 78.0% and to the preventive effect of powdery mildew of cucumber
73.9%, and bactericidal composition of the embodiment of the present invention is significantly increased in preventive effect, minimum preventive effect is 87.7%, up to
92.4%.The result of field trial fully shows that flutianil is significant with having after azoxystrobin compound to powdery mildew of cucumber
Synergistic function, in the case where effective ingredient consumption is reduced compared with single dose, control effect greatly improves.Therefore, of the present invention group
Closing object has the beneficial effect for reducing cost, delaying drug resistance, reduction spraying times and pesticide residue.
4 flutianil of table is with azoxystrobin compound to the field test results of powdery mildew of cucumber
Field information example 2：Flutianil is with azoxystrobin compound to the field control effectiveness test of powdery mildew of strawberry
Test site Guangdong Qingyuan.Test medicine and dosage are shown in Table 5, often handle 4 cells and repeat, each plot area 20
Square metre.Carry out first time dispenser in the early stages of disease, even spraying is sprayed onto until blade drips, using clear water processing to be empty
White control.Second of medicine is applied after 7 days.The incidence of 7 days investigation powdery mildew of strawberries before first time medicine and after second of medicine.Often
Cell is using 5 points of samplings, and every is investigated two plants, and every plant is investigated all blades, and the percentage of entire leaf area is accounted for lesion area
It is recorded to be classified.Calculate each processing disease index and control effect.
Grade scale and drug effect computational methods are the same as Field information example 1.
As can be seen from Table 5：Flutianil, Fluoxastrobin single dose are respectively 77.9% and to the preventive effect of powdery mildew of strawberry
75.6%, and bactericidal composition of the embodiment of the present invention is significantly increased in preventive effect, minimum preventive effect is 86.3%, up to
91.9%.The result of field trial fully shows that flutianil is significant with having after azoxystrobin compound to powdery mildew of strawberry
Synergistic function, in the case where effective ingredient consumption is reduced compared with single dose, control effect significantly improves.Therefore, of the present invention group
Closing object has the beneficial effect for reducing cost, delaying drug resistance, reduction spraying times and pesticide residue.
5 flutianil of table is with azoxystrobin compound to the field test results of powdery mildew of strawberry
Field information example 3：Flutianil compounds the field control effectiveness test to powdery mildew of cucumber with pyraclostrobin
Test site Zhaoqing Guangdong.Test medicine and dosage are shown in Table 6, often handle 4 cells and repeat, each plot area 20
Square metre.Carry out first time dispenser in the early stages of disease, even spraying is sprayed onto until blade drips, using clear water processing to be empty
White control.Second of medicine is applied after 7 days.The incidence of 7 days investigation powderys mildew of cucumber before first time medicine and after second of medicine.Often
Cell is using 5 points of samplings, and every is investigated two plants, and every plant is investigated all blades, and the percentage of entire leaf area is accounted for lesion area
It is recorded to be classified.Calculate each processing disease index and control effect.
Grade scale and drug effect computational methods are the same as Field information example 1.
As can be seen from Table 6：Flutianil, pyraclostrobin single dose are respectively 75.5% to the preventive effect of powdery mildew of cucumber
With 72.4%, and bactericidal composition of the embodiment of the present invention is significantly increased in preventive effect, and minimum preventive effect is 86.2%, up to
To 90.1%.The result of field trial fully shows that flutianil has powdery mildew of cucumber after being compounded with pyraclostrobin
Significant synergistic function, in the case where effective ingredient consumption is reduced compared with single dose, control effect greatly improves.Therefore, originally
Inventive composition has the beneficial effect for reducing cost, delaying drug resistance, reduction spraying times and pesticide residue.
6 flutianil of table compounds the field test results to powdery mildew of cucumber with pyraclostrobin
Field information example 4：Flutianil compounds the field control effectiveness test to powdery mildew of strawberry with pyraclostrobin
Test site Hengyang, Hunan Province.Test medicine and dosage are shown in Table 7, often handle 4 cells and repeat, each plot area 20
Square metre.Carry out first time dispenser in the early stages of disease, even spraying is sprayed onto until blade drips, using clear water processing to be empty
White control.Second of medicine is applied after 7 days.The incidence of 7 days investigation powdery mildew of strawberries before first time medicine and after second of medicine.Often
Cell is using 5 points of samplings, and every is investigated two plants, and every plant is investigated all blades, and the percentage of entire leaf area is accounted for lesion area
It is recorded to be classified.Calculate each processing disease index and control effect.
Grade scale and drug effect computational methods are the same as Field information example 1.
As can be seen from Table 7：Flutianil, pyraclostrobin single dose are respectively 77.9% to the preventive effect of powdery mildew of strawberry
With 75.2%, and bactericidal composition of the embodiment of the present invention is significantly increased in preventive effect, and minimum preventive effect is 89.2%, up to
To 92.4%.The result of field trial fully shows that flutianil has powdery mildew of strawberry after being compounded with pyraclostrobin
Significant synergistic function, in the case where effective ingredient consumption is reduced compared with single dose, control effect significantly improves.Therefore, originally
Inventive composition has the beneficial effect for reducing cost, delaying drug resistance, reduction spraying times and pesticide residue.
7 flutianil of table compounds the field test results to powdery mildew of strawberry with pyraclostrobin
Field information example 5：Flutianil compounds the field control effectiveness test to powdery mildew of cucumber with trifloxystrobin
Test site Guangdong Zengcheng.Test medicine and dosage are shown in Table 8, often handle 4 cells and repeat, each plot area 20
Square metre.Carry out first time dispenser in the early stages of disease, even spraying is sprayed onto until blade drips, using clear water processing to be empty
White control.Second of medicine is applied after 7 days.The incidence of 7 days investigation powderys mildew of cucumber before first time medicine and after second of medicine.Often
Cell is using 5 points of samplings, and every is investigated two plants, and every plant is investigated all blades, and the percentage of entire leaf area is accounted for lesion area
It is recorded to be classified.Calculate each processing disease index and control effect.
Grade scale and drug effect computational methods are the same as Field information example 1.
As can be seen from Table 8：Flutianil, trifloxystrobin single dose are respectively 75.1% and to the preventive effect of powdery mildew of cucumber
72.2%, and bactericidal composition of the embodiment of the present invention is significantly increased in preventive effect, minimum preventive effect is 84.4%, up to
87.8%.The result of field trial fully shows that flutianil is significant with having after trifloxystrobin compounding to powdery mildew of cucumber
Synergistic function, in the case where effective ingredient consumption is reduced compared with single dose, control effect greatly improves.Therefore, of the present invention group
Closing object has the beneficial effect for reducing cost, delaying drug resistance, reduction spraying times and pesticide residue.
8 flutianil of table compounds the field test results to powdery mildew of cucumber with trifloxystrobin
Field information example 6：Flutianil compounds the field control effectiveness test to powdery mildew of strawberry with trifloxystrobin
Test site Guangdong Deqing.Test medicine and dosage are shown in Table 9, often handle 4 cells and repeat, each plot area 20
Square metre.Carry out first time dispenser in the early stages of disease, even spraying is sprayed onto until blade drips, using clear water processing to be empty
White control.Second of medicine is applied after 7 days.The incidence of 7 days investigation powdery mildew of strawberries before first time medicine and after second of medicine.Often
Cell is using 5 points of samplings, and every is investigated two plants, and every plant is investigated all blades, and the percentage of entire leaf area is accounted for lesion area
It is recorded to be classified.Calculate each processing disease index and control effect.
Grade scale and drug effect computational methods are the same as Field information example 1.
As can be seen from Table 9：Flutianil, trifloxystrobin single dose are respectively 78.7% and to the preventive effect of powdery mildew of strawberry
74.7%, and bactericidal composition of the embodiment of the present invention is significantly increased in preventive effect, minimum preventive effect is 89.6%, up to
93.7%.The result of field trial fully shows that flutianil is significant with having after trifloxystrobin compounding to powdery mildew of strawberry
Synergistic function, in the case where effective ingredient consumption is reduced compared with single dose, control effect significantly improves.Therefore, of the present invention group
Closing object has the beneficial effect for reducing cost, delaying drug resistance, reduction spraying times and pesticide residue.
9 flutianil of table compounds the field test results to powdery mildew of strawberry with trifloxystrobin
Claims (5)
1. a kind of bactericidal composition containing flutianil, it is characterised in that：Containing effective constituents A and B, A flutianil,
B is any one in Fluoxastrobin, pyraclostrobin and trifloxystrobin, and the mass ratio of A and B are 1 ︰, 50~50 ︰ 1.
2. bactericidal composition according to claim 1, it is characterised in that：The mass ratio of effective constituents A and B for 1 ︰ 30~
30 ︰ 1.
3. bactericidal composition according to claim 1 or 2, it is characterised in that：The mass accumulation of active ingredient in composition
Percentage composition is 5%~85%.
4. bactericidal composition according to claim 3, it is characterised in that：Dosage form is missible oil, microemulsion, aqueous emulsion, suspension
Agent, suspension emulsion, wettable powder or water dispersible granules.
5. application of the bactericidal composition described in claim 1 in prevention gourd, fruit and vegetable powdery mildew.
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|---|---|---|---|---|
| IT202100001316A1 (en) * | 2021-01-25 | 2022-07-25 | Guangzhou Baiyun Shijing Xingchen Ltd | EMULSIFIABLE BACTERICIDE CONCENTRATE |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010029030A2 (en) * | 2008-09-12 | 2010-03-18 | Basf Se | Fungicidal mixtures |
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2016
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010029030A2 (en) * | 2008-09-12 | 2010-03-18 | Basf Se | Fungicidal mixtures |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT202100001316A1 (en) * | 2021-01-25 | 2022-07-25 | Guangzhou Baiyun Shijing Xingchen Ltd | EMULSIFIABLE BACTERICIDE CONCENTRATE |
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Application publication date: 20180615 |