CN108124862B - Synergistic auxiliary agent of pesticide for killing borers and use method thereof - Google Patents
Synergistic auxiliary agent of pesticide for killing borers and use method thereof Download PDFInfo
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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Abstract
本发明属于害虫化学防治技术领域,具体涉及一种杀螟药剂的增效助剂及其使用方法,优选的杀螟药剂为水胺硫磷、三唑磷、阿维菌素、氯虫苯甲酰胺和乙基多杀菌素。所选的增效助剂为异构醇醚,优选异构十三醇聚氧乙烯醚。将异构十三醇聚氧乙烯醚加入到预先兑水配制好的杀螟药液中,其使用浓度为0.033%‑0.067%。混合均匀后即可喷雾使用。本发明可以明显提高不同杀螟药剂对水稻螟虫的防治效果,可以实现药剂减量控害的目的,且该增效助剂具有成本低和使用方便的特点。The invention belongs to the technical field of chemical pest control, and in particular relates to a synergist for a borer agent and a method for using the same. amide and spinosad. The selected synergist is an isomeric alcohol ether, preferably isotridecanol polyoxyethylene ether. The isotridecanol polyoxyethylene ether is added to the mothicide liquid prepared by mixing with water in advance, and its use concentration is 0.033%-0.067%. After mixing evenly, it can be sprayed. The invention can obviously improve the control effect of different borer pesticides on rice borers, can achieve the purpose of reducing the amount of the pesticides and controlling the damage, and the synergist has the characteristics of low cost and convenient use.
Description
技术领域technical field
本发明涉及害虫化学防治领域,具体地说,涉及一种杀螟药剂的增效助剂及其使用方法。The invention relates to the field of chemical pest control, in particular, to a synergist of a borer medicament and a method for using the same.
背景技术Background technique
农药是农业生产中必不可少的生产资料,在防控病虫草害,保障作物安全生产方面发挥了极其重要的作用。但无论何种药剂,靶标只有接触并吸收了足量的农药才能充分发挥农药的作用。钻蛀性害虫生存在寄主植物组织内,而这些寄主植物组织的表皮富含蜡质,常规的药剂很难穿透这层屏障,因此防效往往不理想。增效剂是一类对靶标无生物活性的化合物,与药剂混用后,能降低药剂的表面张力,提高药剂的展布、分散和渗透能力,有利于药液在植物组织表面铺展和向植物组织内部渗透,有的还可以抑制有害生物体内的解毒代谢,从而提高农药的生物活性和防治效果。Pesticides are an indispensable means of production in agricultural production, and play an extremely important role in preventing and controlling diseases, pests and weeds and ensuring safe crop production. But no matter what kind of agent, the target can only fully play the role of the pesticide if it contacts and absorbs a sufficient amount of the pesticide. Boring pests live in host plant tissues, and the epidermis of these host plant tissues is rich in wax, and it is difficult for conventional chemicals to penetrate this barrier, so the control effect is often unsatisfactory. Synergist is a kind of compound that has no biological activity to the target. After mixing with the agent, it can reduce the surface tension of the agent, improve the spreading, dispersing and penetrating ability of the agent, which is beneficial to the spread of the liquid on the surface of the plant tissue and to the plant tissue. Internal penetration, and some can also inhibit the detoxification metabolism of harmful organisms, thereby improving the biological activity and control effect of pesticides.
二化螟是水稻的主要害虫,以幼虫钻蛀入水稻叶鞘组织和水稻茎秆为害,俗称“钻心虫”。危害分蘖期水稻造成枯鞘和枯心苗;危害孕穗、抽穗期水稻,造成枯孕穗和白穗;危害灌浆、乳熟期水稻,造成半枯穗和虫伤株,造成严重的经济损失。由于药剂的长期不合理应用,使得二化螟的抗药性问题越来越严重:1990~2000年,浙江、江苏等地陆续监测到甲胺磷、杀虫单、三唑磷的高抗药性种群;2000年~2012年,对杀虫单、三唑磷、氟虫腈的抗药性水平较高;2012年以后,对生产上常用的三唑磷、氯虫苯甲酰胺、氟虫双酰胺、阿维菌素等杀螟药剂的抗药性突出。在江西、湖南和浙江等地的高抗区域,现有杀螟药剂对抗性二化螟的防效极低,防治失败的稻田比比皆是。因此,急迫需要研发提高现有杀螟药剂的防治效果的相关技术,及时高效地控制二化螟为害,以保障我国粮食安全生产。Diploid borer is the main pest of rice, and its larvae bore into rice leaf sheath tissue and rice stalk to damage, commonly known as "borer". Harm the tillering stage rice and cause dead sheaths and dead heart seedlings; damage the booting and heading stage rice, causing dead booting and white ears; damage the grain-filling and milk-maturing stage rice, causing half dead ears and insect-injured plants, causing serious economic losses. Due to the long-term and unreasonable application of chemicals, the problem of drug resistance of Dilophos is more and more serious: from 1990 to 2000, high-drug-resistant populations of methamidophos, insecticide and triazophos were successively monitored in Zhejiang, Jiangsu and other places. ; From 2000 to 2012, the level of resistance to insecticides, triazophos, and fipronil was relatively high; after 2012, the resistance to triazophos, chlorantraniliprole, fipronil, The resistance to vermectin and other pesticidal agents is outstanding. In the high-resistance areas of Jiangxi, Hunan, and Zhejiang, the control efficiency of the existing borer-killing agents against the resistant Dilophos is extremely low, and there are many rice fields with control failures. Therefore, there is an urgent need to research and develop related technologies to improve the control effect of existing insecticides, so as to timely and efficiently control the damage caused by Diploxin, so as to ensure the safe production of food in my country.
发明内容SUMMARY OF THE INVENTION
针对上述技术问题,本发明提供了一种杀螟药剂的增效助剂及其使用方法,对防治二化螟的药剂具有优良的增效作用。具体技术方案为:In view of the above-mentioned technical problems, the present invention provides a synergistic adjuvant of a borer medicament and a method for using the same, which has an excellent synergistic effect on the medicament for preventing and controlling the borer. The specific technical solutions are:
选择异构醇醚作为杀螟药剂的增效助剂,将异构醇醚加入到预先兑水配制好的杀螟药液中,混合均匀后即可喷雾使用,异构醇醚在杀螟药液中的体积浓度为0.033%-0.067%。Select iso-alcohol ether as the synergist of the borer agent, add the iso-alcohol ether to the borer liquid prepared by mixing water in advance, and then spray it after mixing evenly. The volume concentration in the liquid is 0.033%-0.067%.
所述杀螟药剂为有机磷类、氨基甲酸酯类、沙蚕毒素类、大环内酯类和双酰胺类药剂,优选为水胺硫磷、三唑磷、阿维菌素、氯虫苯甲酰胺和乙基多杀菌素,使用时根据该药剂品种的推荐使用剂量和配制方法配制成农药溶液。Described borer medicament is organophosphorus, carbamate, necrotoxin, macrolide and bisamide medicament, preferably ammonium phosphine, triazophos, abamectin, chlorantraniliprole Formamide and spinosad are formulated into pesticide solutions according to the recommended dosage and preparation method of the chemical species.
所述异构醇醚优选为异构十三醇聚氧乙烯醚。The isomeric alcohol ether is preferably isomeric tridecanol polyoxyethylene ether.
异构醇醚是性能优良的非离子表面活性剂,是高效的乳化剂、渗透剂和润湿剂,已广泛应用于洗涤日化、纺织、皮革以及其他化工行业。优选异构十三醇聚氧乙烯醚,该助剂具有十三碳的长碳链结构,使得体系具有卓越的乳化稳定性和空间稳定性;具有非格尔伯特醇,含小支链的烷基醇,支链多,渗透能力强,对提高乳液附着力有促进作用;不含苯环结构,不含APEO,易生物降解。其Isomerized alcohol ethers are non-ionic surfactants with excellent performance, and are highly efficient emulsifiers, penetrants and wetting agents. They have been widely used in washing daily chemicals, textiles, leather and other chemical industries. Isotridecanol polyoxyethylene ether is preferred, the adjuvant has a long carbon chain structure of thirteen carbons, which makes the system have excellent emulsion stability and steric stability; non-Guerbet alcohol, small branched alcohol Alkyl alcohol has many branches and strong penetrating ability, which can promote the adhesion of emulsions; it does not contain benzene ring structure, does not contain APEO, and is easily biodegradable. That
本发明的有益效果在于:The beneficial effects of the present invention are:
本发明提供了一种杀螟药剂的增效助剂,该助剂与杀螟药剂混合喷施,使用方法简单,具有较强的杀虫增效作用,即在药量减施的情况下,仍然能够保证药剂的防治效果。本发明是实现农药减量控制螟害的一项创新,必将对推进农业面源污染治理,建设资源节约型、环境友好型社会,保障农业生产安全、农产品质量安全和生态环境安全,促进农业可持续发展,产生积极而深远的影响。The invention provides a synergistic adjuvant for a borer agent. The adjuvant and the borer agent are mixed and sprayed. The use method is simple and has a strong synergistic effect on insecticides, that is, when the dosage is reduced, the The control effect of the chemical can still be guaranteed. The invention is an innovation to realize pesticide reduction and control of borer damage, which will definitely promote agricultural non-point source pollution control, build a resource-saving and environment-friendly society, ensure agricultural production safety, agricultural product quality safety and ecological environment safety, and promote agricultural production. Sustainable development has a positive and far-reaching impact.
具体实施方式Detailed ways
以下通过具体实施例对本发明作进一步说明,并结合相应试验进一步说明本发明的有益效果。但本发明的内容并不局限于此,不能因此而理解为对本发明范围的限制。The present invention will be further described below through specific examples, and the beneficial effects of the present invention will be further described in conjunction with corresponding experiments. However, the content of the present invention is not limited to this, and therefore should not be construed as limiting the scope of the present invention.
实施例1Example 1
在30kg水中加入5%阿维菌素乳油100ml混匀,然后按0.033%的比例加入异构十三醇聚氧乙烯醚10ml并搅拌混匀。Add 100 ml of 5% abamectin EC to 30 kg of water and mix well, then add 10 ml of isotridecyl polyoxyethylene ether at a ratio of 0.033% and stir and mix well.
实施例2Example 2
在30kg水中加入5%阿维菌素乳油100ml混匀,然后按0.067%的比例加入异构十三醇聚氧乙烯醚20ml并搅拌混匀。Add 100 ml of 5% abamectin EC to 30 kg of water and mix well, then add 20 ml of isotridecanol polyoxyethylene ether at a ratio of 0.067%, and stir and mix well.
实施例3Example 3
在30kg水中加入30%水胺·三唑磷乳油200ml混匀,然后按0.033%的比例加入异构十三醇聚氧乙烯醚10ml并搅拌混匀。Add 200 ml of 30% water amine·triazophos emulsifiable concentrate to 30 kg of water and mix well, then add 10 ml of isotridecanol polyoxyethylene ether at a ratio of 0.033% and stir and mix well.
实施例4Example 4
在30kg水中加入30%水胺·三唑磷乳油200ml混匀,然后按0.067%的比例加入异构十三醇聚氧乙烯醚20ml并搅拌混匀。Add 200 ml of 30% water amine·triazophos EC to 30 kg of water and mix well, then add 20 ml of isotridecanol polyoxyethylene ether at a ratio of 0.067% and stir and mix well.
实施例5Example 5
在30kg水中加入6%乙基多杀菌素悬浮剂50ml混匀,然后按0.033%的比例加入异构十三醇聚氧乙烯醚10ml并搅拌混匀。Add 50 ml of 6% spinosad suspending agent to 30 kg of water and mix well, then add 10 ml of isotridecanol polyoxyethylene ether at a ratio of 0.033%, and stir and mix well.
实施例6Example 6
在30kg水中加入6%乙基多杀菌素悬浮剂50ml混匀,然后按0.067%的比例加入异构十三醇聚氧乙烯醚20ml并搅拌混匀。Add 50 ml of 6% spinosad suspending agent to 30 kg of water and mix well, then add 20 ml of isotridecanol polyoxyethylene ether at a ratio of 0.067% and stir and mix well.
实施例7Example 7
在30kg水中加入20%氯虫苯甲酰胺悬浮剂20ml混匀,然后按0.033%的比例加入异构十三醇聚氧乙烯醚10ml并搅拌混匀。Add 20 ml of 20% chlorantraniliprole suspending agent to 30 kg of water and mix well, then add 10 ml of isotridecanol polyoxyethylene ether at a ratio of 0.033%, and stir and mix well.
实施例8Example 8
在30kg水中加入20%氯虫苯甲酰胺悬浮剂20ml混匀,然后按0.067%的比例加入异构十三醇聚氧乙烯醚20ml并搅拌混匀。Add 20 ml of 20% chlorantraniliprole suspending agent to 30 kg of water and mix well, then add 20 ml of isotridecanol polyoxyethylene ether at a ratio of 0.067%, and stir and mix well.
田间药效试验Field efficacy test
按照农药田间药效试验准则(一)GB/T17980.1-2000的要求,对上述实施例开展了防治二化螟的田间药效试验。According to the requirements of Pesticide Field Efficacy Test Guidelines (1) GB/T17980.1-2000, the field efficacy test for the prevention and control of Chilo amphia was carried out for the above examples.
采用田间随机区组设置小区,小区面积为90m2/小区,每处理重复3次,每个小区喷施药液4kg,另设只用同量药剂而不加助剂的处理以及空白处理为对照。在二化螟1-2龄幼虫发生高峰期采用电动喷雾器均匀喷雾施药1次,当田间螟虫为害基本稳定时(在空白对照区受害状明显时),取样调查水稻总株数、受害株数,计算防治效果。The plots were set up in random blocks in the field, the plot area was 90m 2 / plot, each treatment was repeated 3 times, and each plot was sprayed with 4 kg of liquid medicine, and the treatment with only the same amount of drug without adjuvant and the blank treatment were set as controls . In the peak period of occurrence of 1-2 instar larvae of S. chinensis, an electric sprayer was used for uniform spraying once. When the damage of the field borer was basically stable (when the damage was obvious in the blank control area), the total number of rice plants and the number of injured plants were sampled and investigated. control effect.
试验结果见表1。从表1可以看出,5%阿维菌素乳油与助剂异构十三醇聚氧乙烯醚混用处理(实施例1和实施例2)对二化螟的防治效果分别为60.5%和70.5%,均明显高于单用等量5%阿维菌素乳油的处理的防治效果(49.9%);30%水胺·三唑磷乳油与助剂异构十三醇聚氧乙烯醚混用处理(实施例3和实施例4)对二化螟的防治效果分别为70.1%和54.6%,均明显高于单用等量30%水胺·三唑磷乳油处理的防治效果(42.3%);6%乙基多杀菌素悬浮剂与助剂异构十三醇聚氧乙烯醚混用处理(实施例5和实施例6)对二化螟的防治效果分别为75%和84.6%,均明显高于单用等量6%乙基多杀菌素悬浮剂处理的防治效果(72.9%);20%氯虫苯甲酰胺悬浮剂与助剂异构十三醇聚氧乙烯醚混用处理(实施例5和实施例6)对二化螟的防治效果分别为59.8%和44.4%,均明显高于单用等量20%氯虫苯甲酰胺悬浮剂处理的防治效果(23.4%)。此外,所有药剂与助剂混用的处理的水稻生长正常,无药害症状发生。上述结果表明,助剂异构十三醇聚氧乙烯醚对阿维菌素、乙基多杀菌素、水胺·三唑磷和氯虫苯甲酰胺均具有明显的增效作用。The test results are shown in Table 1. As can be seen from Table 1, the control effects of 5% Abamectin EC and the adjuvant isomerized tridecanol polyoxyethylene ether mixed treatment (Example 1 and Example 2) were 60.5% and 70.5%, respectively, on the control effect of Dilophos %, were significantly higher than the control effect of the treatment with the same amount of 5% abamectin EC alone (49.9%); 30% water amine·triazophos EC and auxiliary isomerized tridecanol polyoxyethylene ether mixed treatment (Example 3 and Example 4) The control effect of Dilophos is 70.1% and 54.6% respectively, which are significantly higher than the control effect (42.3%) of the single use of the same amount of 30% hydrazine·triazophos EC; The control effects of 6% spinosad suspending agent and the adjuvant isotridecanol polyoxyethylene ether (Example 5 and Example 6) were 75% and 84.6%, respectively, which were significantly higher. The control effect of using the same amount of 6% spinosad suspending agent alone (72.9%); 20% chlorantraniliprole suspending agent and adjuvant isotridecanol polyoxyethylene ether mixed treatment (Example 5 and Example 6), the control effects on Diploxinus are 59.8% and 44.4%, respectively, which are significantly higher than the control effects (23.4%) of the single treatment with an equal amount of 20% chlorantraniliprole suspending agent. In addition, all the treated rice treated with the mixture of medicaments and auxiliaries grew normally, and no phytotoxic symptoms occurred. The above results show that the adjuvant isotridecanol polyoxyethylene ether has obvious synergistic effect on abamectin, spinosad, water amine triazophos and chlorantraniliprole.
表1杀螟药剂与助剂混用防治二化螟试验结果Table 1 The results of the test results of the mixed use of the borer agent and the adjuvant to prevent and control the stem borer
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| CN110150269A (en) * | 2019-06-03 | 2019-08-23 | 江苏省苏科农化有限责任公司 | A kind of compound synergist |
| CN111493067B (en) * | 2020-04-15 | 2021-11-09 | 上海抚佳精细化工有限公司 | Pesticide combination synergist and application thereof |
| CN112438270B (en) * | 2020-12-18 | 2021-12-21 | 浙江天丰生物科学有限公司 | Metamifop emulsifiable concentrate and preparation method thereof |
| CN116636544B (en) * | 2023-04-14 | 2025-07-25 | 山东京博农化科技股份有限公司 | Synergistic auxiliary agent and indoxacarb and lufenuron liquid preparation |
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| JPH059103A (en) * | 1991-07-01 | 1993-01-19 | Dainippon Jochugiku Co Ltd | Carboxylic ester derivative-containing insecticide/insect-proofing agent for clothes |
| JPH0517312A (en) * | 1991-07-05 | 1993-01-26 | Dainippon Jochugiku Co Ltd | Insecticidal, moth-proofing and vermin-repelling agent containing carboxylic acid ester derivative and volatile at normal temperature, and insecticidal, moth-proofing and vermin-repelling method using the same |
| CN101507432B (en) * | 2009-04-02 | 2012-12-19 | 河北省林业科学研究院 | Carvacrol micro-emulsion and production technique thereof |
| CN101856036B (en) * | 2010-06-13 | 2013-06-19 | 南京农业大学 | Biological weed control compound and preparation method thereof |
| CN102308845A (en) * | 2011-05-22 | 2012-01-11 | 覃终 | Preparation and applications of atomizing agent with pesticide and deratization functions |
| CN103081912B (en) * | 2013-01-25 | 2014-12-10 | 浙江农林大学 | Celastrus angulatus and cnidium lactone compounded pesticide and preparation method thereof |
| CN106689122B (en) * | 2016-12-12 | 2018-04-06 | 北京广源益农化学有限责任公司 | The spray adjuvantses and application that agricultural aviation plant protection spraying or ultra-low volume spray use |
| CN107041366A (en) * | 2016-12-14 | 2017-08-15 | 东至绿洲环保化工有限公司 | A kind of bleeding agent added applied to agricultural chemicals |
| CN106665569B (en) * | 2016-12-16 | 2020-10-27 | 江苏钟山化工有限公司 | Flying-prevention aid and preparation method thereof |
| CN107156120A (en) * | 2017-04-24 | 2017-09-15 | 东莞市隆海新材料科技有限公司 | A kind of environment-friendly pesticide and preparation method thereof |
| CN107318880A (en) * | 2017-07-20 | 2017-11-07 | 佛山市普尔玛农化有限公司 | A kind of composition pesticide of containing fluopyram, pyraclostrobin and imidacloprid |
| CN107219338A (en) * | 2017-07-25 | 2017-09-29 | 江西省农业科学院植物保护研究所 | Method for measuring bioactivity of pesticide to chilo suppressalis |
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