CN107318880A - A kind of composition pesticide of containing fluopyram, pyraclostrobin and imidacloprid - Google Patents
A kind of composition pesticide of containing fluopyram, pyraclostrobin and imidacloprid Download PDFInfo
- Publication number
- CN107318880A CN107318880A CN201710596843.6A CN201710596843A CN107318880A CN 107318880 A CN107318880 A CN 107318880A CN 201710596843 A CN201710596843 A CN 201710596843A CN 107318880 A CN107318880 A CN 107318880A
- Authority
- CN
- China
- Prior art keywords
- seed treatment
- seed
- imidacloprid
- fluopyram
- pyraclostrobin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 239000000203 mixture Substances 0.000 title claims abstract description 38
- 239000005906 Imidacloprid Substances 0.000 title claims abstract description 35
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 229940056881 imidacloprid Drugs 0.000 title claims abstract description 35
- 239000005783 Fluopyram Substances 0.000 title claims abstract description 31
- KVDJTXBXMWJJEF-UHFFFAOYSA-N fluopyram Chemical compound ClC1=CC(C(F)(F)F)=CN=C1CCNC(=O)C1=CC=CC=C1C(F)(F)F KVDJTXBXMWJJEF-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 239000005869 Pyraclostrobin Substances 0.000 title claims abstract description 23
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 239000000575 pesticide Substances 0.000 title description 4
- 201000010099 disease Diseases 0.000 claims abstract description 13
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 13
- 241000244206 Nematoda Species 0.000 claims abstract description 5
- 241001414989 Thysanoptera Species 0.000 claims abstract description 4
- 241001498622 Cixius wagneri Species 0.000 claims abstract description 3
- 241000918585 Pythium aphanidermatum Species 0.000 claims abstract description 3
- 241001530056 Athelia rolfsii Species 0.000 claims abstract 2
- 239000011248 coating agent Substances 0.000 claims description 19
- 239000000725 suspension Substances 0.000 claims description 18
- 239000000375 suspending agent Substances 0.000 claims description 15
- 239000003094 microcapsule Substances 0.000 claims description 13
- 241000607479 Yersinia pestis Species 0.000 claims description 6
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims 2
- 230000009418 agronomic effect Effects 0.000 claims 2
- 241000498255 Enterobius vermicularis Species 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 241000209140 Triticum Species 0.000 abstract description 10
- 235000021307 Triticum Nutrition 0.000 abstract description 10
- 238000013329 compounding Methods 0.000 abstract description 6
- 230000002195 synergetic effect Effects 0.000 abstract description 6
- 240000007594 Oryza sativa Species 0.000 abstract description 3
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 3
- 240000008042 Zea mays Species 0.000 abstract description 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract description 3
- 235000005822 corn Nutrition 0.000 abstract description 3
- 235000009566 rice Nutrition 0.000 abstract description 3
- 241001136249 Agriotes lineatus Species 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 30
- 241000894006 Bacteria Species 0.000 description 19
- 239000003795 chemical substances by application Substances 0.000 description 15
- 150000003217 pyrazoles Chemical class 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 239000013530 defoamer Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 238000012545 processing Methods 0.000 description 8
- 239000004576 sand Substances 0.000 description 8
- 230000002265 prevention Effects 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 6
- 241000238631 Hexapoda Species 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- -1 Alkyl phenol formaldehyde resin Chemical compound 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 239000002775 capsule Substances 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- WHDHEVMINMZADQ-UHFFFAOYSA-N [F].N1C=CC=C1 Chemical compound [F].N1C=CC=C1 WHDHEVMINMZADQ-UHFFFAOYSA-N 0.000 description 4
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 4
- 230000002528 anti-freeze Effects 0.000 description 4
- 239000008346 aqueous phase Substances 0.000 description 4
- 239000003899 bactericide agent Substances 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 230000010534 mechanism of action Effects 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000010008 shearing Methods 0.000 description 4
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 4
- 239000004299 sodium benzoate Substances 0.000 description 4
- 235000010234 sodium benzoate Nutrition 0.000 description 4
- 229920001285 xanthan gum Polymers 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 241000243785 Meloidogyne javanica Species 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 241000125167 Rhopalosiphum padi Species 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 241000233791 Ustilago tritici Species 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 230000009931 harmful effect Effects 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 230000000361 pesticidal effect Effects 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000009331 sowing Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 150000003852 triazoles Chemical class 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 1
- 241001414720 Cicadellidae Species 0.000 description 1
- 206010011224 Cough Diseases 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 108010072039 Histidine kinase Proteins 0.000 description 1
- 241001272567 Hominoidea Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 108090000723 Insulin-Like Growth Factor I Proteins 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 235000003228 Lactuca sativa Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241001363490 Monilia Species 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- 206010062701 Nematodiasis Diseases 0.000 description 1
- BOLQUPOXTWHXIX-UHFFFAOYSA-N OC1=CC=CC=C1.C=1C=CC=CC=1C=C(C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound OC1=CC=CC=C1.C=1C=CC=CC=1C=C(C=1C=CC=CC=1)C1=CC=CC=C1 BOLQUPOXTWHXIX-UHFFFAOYSA-N 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 241000283984 Rodentia Species 0.000 description 1
- 102000013275 Somatomedins Human genes 0.000 description 1
- 102000019259 Succinate Dehydrogenase Human genes 0.000 description 1
- 108010012901 Succinate Dehydrogenase Proteins 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000005667 attractant Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000004166 bioassay Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000006013 carbendazim Substances 0.000 description 1
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000031902 chemoattractant activity Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000006806 disease prevention Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 244000053095 fungal pathogen Species 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000002438 mitochondrial effect Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- SDIDYFBTIZOPLA-UHFFFAOYSA-N n-ethylbenzamide Chemical class CCNC(=O)C1=CC=CC=C1 SDIDYFBTIZOPLA-UHFFFAOYSA-N 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 238000009666 routine test Methods 0.000 description 1
- 230000035040 seed growth Effects 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01C—PLANTING; SOWING; FERTILISING
- A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
- A01C1/08—Immunising seed
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Soil Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of seed treatment compositions containing fluopyram, pyraclostrobin and imidacloprid, the weight ratio of fluopyram, pyraclostrobin and imidacloprid is 1 15 in the seed treatment compositions:1‑20:1 50, preferably 2 12:2‑15:3‑15；The seed treatment component compounding of the present invention is reasonable, it is not simple superposition after compounding each other, certain synergistic function can be shown, the seed treatment of the present invention is applied to prevent and treat multiple kinds of crops such as grub, plant hopper, thrips, wireworm, nematode of the crop such as corn, wheat, paddy rice etc., and for preventing and treating the diseases such as stem rot, smut, damping-off, samping off, banded sclerotial blight.
Description
Technical field
The invention belongs to seed treatment field, and in particular to be seed treatment composition for disease-prevention and insecticide, institute
Seed treatment composition active component is stated including at least fluopyram, pyraclostrobin and imidacloprid, the seed treatment
For preventing and treating various soil insects and disease.
Background technology
Agriculture field produces the crop of many kinds such as beans, fruit, lettuce, wheat, barley, corn and paddy rice
Deng.Many is all that, by seed growth, and physics is damaged caused by seed resists unfavorable storage or environmental condition in these crops
Harmful connate ability is different, and all these abilities for all influenceing it to grow up to adult plants in the future.In addition, seed holds very much
It is vulnerable to infringement of the phytopathogen including fungi, bacterium, virus and nematode and for relying on them as food source
Insect, birds, the infringement of rodent and other biological are fragile.Fungi is economically most important phytopathogen group
One of body, and can cause can sale of foodstuffs, fiber and feed huge annual loss.It is used as replacing for traditional extensive spraying agricultural chemicals
Change, seed treatment compositions must are fulfilled for many particular/special requirements, these requirements are applied to seed including them in commercial plant
Applicability, good fluidity of the active component to the seed of bonding and the processing of the seed of processing.Certainly, the seed of processing
It must remain able to sprout.
The seed treatment kind for being applied to wheat in the market is more, mainly with triazole bactericidal agent, cough up bacterium
Based on the medicaments such as nitrile, carbendazim, jinggangmeisu, due to using all the year round, higher resistance has been produced；On the other hand, triazole type kind
Subprocessing agent security is poor, influences emerging and growing for wheat.Therefore, new efficient, the safe medicament of exploitation is needed badly.
Fluopyram is the new pyridine base ethyl benzamide series bactericidal agent of Beyer Co., Ltd's exploitation, by hindering to breathe
The electro transfer of succinate dehydrogenase in chain and suppress mitochondrial respiratory, fluopyram can be used for preventing and treating 70 various crops on
Disease is especially excellent to diseases control caused by sclerotinite, ash arrhizus bacteria, Monilia germ and Powdery Mildew.In addition, patent
Document, CN103298341B discloses application of the fluopyram in terms of crops nematode is prevented and treated.
The pyraclostrobin mainly transfer relevant by suppressing glucose phosphorylated, and suppress the growth of fungal mycelium,
Ultimately result in germ dead.The mechanism of action is unique, with existing bactericide no interactions resistance.Bactericide resistance action group in the world
FRAC thinks that the mechanism of action of pyraclostrobin is the activity for the histidine kinase for influenceing osmotic pressure Regulate signal related.
Imidacloprid is nicotinoids ultra high efficiency insecticide, and with wide spectrum, efficient, low toxicity, low-residual, insect is not likely to produce anti-
Property, the features such as to people, animal, plant and natural enemies security, and have tag, the multiple action such as stomach toxicity and interior suction.It is mainly used in preventing and treating thorn
Suction mouthpart insect, such as aphid, aleyrodid, leafhopper, thrips etc..
The pesticide active ingredient of different cultivars, the different mechanism of action is subjected to mixture, synergistic effect significantly formula can be with
Preventive effect, reduction dosage and use cost are greatly improved, residues of pesticides and environmental pollution is reduced.At present, existing pyraclostrobin
The seed treatment product related to imidacloprid, but there are no what is compounded on fluopyram, pyraclostrobin and imidacloprid
Relevant report.
The content of the invention
It is an object of the invention to provide a kind of seed treatment compositions, active component product in the seed treatment compositions
Plant the different, mechanism of action different, synergistic function can be reached each other, the use effect of seed treatment can be improved
Really, expand preventing and treating spectrum, can diseases prevention again can insect prevention, meanwhile, seed treatment compositions of the invention can improve the sprouting of seed
Rate and planting percent.
The seed treatment compositions of the present invention, which are particularly suitable for use in, prevents and treats various crop such as corn, wheat, paddy rice crop
Grub, plant hopper, thrips, wireworm, nematode etc., it is and withered for preventing and treating stem rot, smut, damping-off, samping off, line
The diseases such as disease.
Another object of the present invention is to provide a kind of method for handling seed, this method is included seed, sowing seed
Medium contacted with seed treatment compositions of the present invention.
" medium of sowing seed " of the present invention refers to any life being adapted to by seed-grown plants and/or seedling
Long environment such as soil and other somatomedins.
In order to achieve the above object, the present invention is adopted the following technical scheme that：
A kind of seed treatment compositions, its active component at least includes fluopyram, pyraclostrobin and imidacloprid, its
In, the weight ratio of fluopyram, pyraclostrobin and imidacloprid is in 1-15:1-10:When in the range of 1-50, prevention effect phase
To more excellent, certain synergistic function is mutually shown in the proportion, it is possible to reduce pesticide activity component makes
Consumption, improves prevention effect.
Further, the weight ratio of fluopyram, pyraclostrobin and imidacloprid is excellent in the seed treatment compositions
Elect 2-12 as:2-15:3-15.
Further, the weight percentage of composition shared by active component is 5-70% in the seed treatment compositions,
Preferably 10-50%, remaining is the auxiliary element commonly used during seed treatment is processed.
Further, the seed treatment compositions are that suspension seed-coating agent, seed treatment dispersible pulvis, seed treatment are micro-
Any of capsule suspending agent, seed treatment microcapsule suspension-suspendinagent agent etc..
It is preferred that, the formulation of the seed treatment compositions is suspension seed-coating agent, and the auxiliary agent of addition is wetting agent, disperseed
Agent, film forming agent, defoamer, antifreeze, colouring agent and water.
Further, the method for application of the seed treatment compositions can also be relatively flexible, both can be with foliar spray, can be with
Soil pour and drip irrigation, it can also be used to seed treatment, it is notable that seed treatment compositions be used for foliar spray when according to
Its different consumption of crop also should be different, and described consumption can be according to the ordinary technical knowledge of those skilled in the art
Determine to obtain with routine test means.
Further, the seed treatment compositions protect seed and germination plant by handling seed from phytopathy
The invasion and attack of fungal pathogenses.
Further, seed treatment compositions of the invention can with other active components, for example insecticide, attractant,
Nematicide, fungicide, plant growth regulator, herbicide, safener, synergist, fertilizer etc. are used in mixed way.
Compared with prior art, seed treatment compositions of the invention have the beneficial effect that：
1st, in seed treatment compositions of the invention, after active component pyraclostrobin, fluopyram and imidacloprid compounding
Certain synergistic function is shown to the preventing and treating of pest and disease damage in certain limit；
2nd, after seed treatment compositions of the invention processing seed, disease can either be prevented and kill off, insect pest can be prevented and kill off again, can also be entered
One step prevents and treats nematodiasis, is conducive to saving medication labour；
3rd, seed treatment compositions of the invention are conducive to the sprouting and growth of seed to crop safety.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.As described below is only the present invention preferably embodiment, is used only for explaining
The present invention, but can not be therefore understands that being the limitation to the scope of the claims of the present invention.It should be pointed out that it is all the present invention spirit and
Any modification, equivalent substitution or improvement for being made within principle etc., should be included in the scope of the protection, therefore,
The protection domain of patent of the present invention should be determined by the appended claims.
First, example of formulations
1st, embodiment 1:12% fluopyram pyraclostrobin imidacloprid microcapsule suspension-suspension seed-coating agent（4:3:5）
Fluopyram 4.0%
Pyrazoles ether bacterium fat 3.0%
Imidacloprid 5.0%
Cyclohexanone 15.0%
Alkyl phenol formaldehyde resin polyoxyethylene ether sodium sulphate 1.5%
APES phosphate 1.5%
Alkylnaphthalene sulfonate 4.0%
PPG 2.0%
Modified diphenylmethane diisocyanate 1.0%
Bright red mill base 2.0%
Sodium carboxymethylcellulose 0.4%
Xanthans 0.1%
Aluminium-magnesium silicate 1.0%
Sodium benzoate 0.4%
Propane diols 4.0%
Defoamer 0.5%
Water surplus
The specific procedure of processing of the microcapsule suspension-suspension seed-coating agent is：By in above-mentioned formula by suitable quantity of water and alkyl phenol polyoxy
Ethene ether phosphate, antifreeze and defoamer are well mixed through high speed shear, add imidacloprid and continue to shear mixing, Ran Houjin
Enter in horizontal sand mill and grind, make particle diameter all in below 5UM, imidacloprid suspending agent part is made；By formula by fluorine pyrrole bacterium acyl
Amine, pyrazoles ether bacterium fat, cyclohexanone add oiliness encystation monomer, emulsifying agent mixing after the reactor dissolving with heated constant temperature
It is uniform that as oil phase, suitable quantity of water and aqueous monomers are well mixed as aqueous phase, under high-speed shearing machine 1500r/min speed, by
Aqueous phase adds oil phase and sheared about 20 minutes, and opening stirring makes encystation monomer slowly occur polymerisation formation capsule skin, opens 60 degree
Constant temperature solidifies capsule skin, 3 hours hardening times, to be restored to this formula microcapsule suspending agent part made after room temperature；Will be obtained
Microcapsule suspending agent part adds suspending agent part, and stirring adds mill base, film forming agent, dispersant, preservative and is made of the present invention
Containing fluopyram, pyrazoles ether bacterium fat, microcapsule suspension-suspension seed-coating agent of imidacloprid suspending agent.
2nd, embodiment 2:20% fluopyram pyraclostrobin imidacloprid microcapsule suspension-suspension seed-coating agent（2.8:
2.2:14）
Fluopyram 3.8%
Pyrazoles ether bacterium fat 2.2%
Imidacloprid 14.0%
C9 solvent naphthas 18.0%
Isomerous tridecanol polyoxyethylene ether 5%
Triphenylethylene phenol polyethenoxy ether phosphate 1.5%
Dispersing agent NNO 4.0%
PPG 2.0%
Modified diphenylmethane diisocyanate 1.0%
Bright red mill base 2.0%
Polyvinyl alcohol 1.0%
Xanthans 0.1%
Aluminium-magnesium silicate 1.0%
Sodium benzoate 0.4%
Propane diols 4.0%
Defoamer 0.5%
Water surplus
The specific procedure of processing of said composition microcapsule suspension-suspension seed-coating agent is：By in above-mentioned formula by suitable quantity of water and triphen second
Alkene phenol polyethenoxy ether phosphate, antifreeze and defoamer are well mixed through high speed shear, add imidacloprid continuation shearing mixed
It is even, ground subsequently into horizontal sand mill, make particle diameter all in below 5UM, imidacloprid suspending agent part is made；Will by formula
Fluopyram, pyrazoles ether bacterium fat, C9 solvent naphthas after the reactor dissolving with heated constant temperature, add oiliness encystation monomer,
Emulsifying agent is well mixed as oil phase, and suitable quantity of water and aqueous monomers are well mixed as aqueous phase, in high-speed shearing machine 1500r/min
Under speed, aqueous phase is added into oil phase and sheared about 20 minutes, opening stirring makes encystation monomer slowly occur polymerisation formation capsule skin,
Opening 60 degree constant temperature makes the solidification of capsule skin, 3 hours hardening times, to be restored to this formula microcapsule suspending agent part made after room temperature；
Obtained microcapsule suspending agent part is added into suspending agent part, stirring adds mill base, film forming agent, dispersant and is made of the present invention
Containing fluopyram, pyrazoles ether bacterium fat, microcapsule suspension-suspension seed-coating agent of imidacloprid suspending agent.
3rd, embodiment 3:28% fluopyram pyraclostrobin imidacloprid suspension seed-coating agent（11.8:9:7.2）
Fluopyram 11.8%
Pyrazoles ether bacterium fat 9%
Imidacloprid 7.2%
Isomerous tridecanol polyoxyethylene ether 1.0%
EO-PO block copolymers 1.2%
Acrylic acid graft copolymer 4.0%
Bright red mill base 2.0%
Polyvinyl alcohol 1.2%
Xanthans 0.1%
Aluminium-magnesium silicate 1.0%
Sodium benzoate 0.4%
Propane diols 4.0%
Defoamer 0.5%
Water surplus
The specific preparation method of the suspension seed-coating agent is：By in above-mentioned formula by water and wetting agent, dispersant, antifreeze and
Defoamer is mixed, well mixed through high speed shear, adds fluopyram, pyrazoles ether bacterium fat, imidacloprid, is continued shearing and is mixed,
Ground subsequently into horizontal sand mill, sand grinding process temperature may not exceed 35 degree, particle diameter is adjusted in entering for below 5UM after sand milling
Kettle processed, mill base, film forming agent, thickener stir about 40 minutes is added in modulation kettle is made of the present invention and contain fluorine pyrrole bacterium acyl
Amine, pyrazoles ether bacterium fat, the suspension seed-coating agent of imidacloprid.
4th, embodiment 4:24% fluopyram pyraclostrobin imidacloprid suspension seed-coating agent（2.2：13.6：8.2）
Fluopyram 2.2%
Pyrazoles ether bacterium fat 13.6%
Imidacloprid 8.2%
Aliphatic alcohol polyoxyvinethene phosphate 1.0%
EO-PO inlay and break copolymers 2.0%
Acrylic acid graft copolymer 2.0%
Bright red mill base 2.0%
Polyvinyl alcohol 1.2%
Xanthans 0.1%
Aluminium-magnesium silicate 1.0%
Sodium benzoate 0.4%
Urea 4.0%
Defoamer 0.5%
Water surplus
The specific procedure of processing of said composition suspension seed-coating agent agent is：By in above-mentioned formula by water and wetting agent, dispersant, freeze proof
Agent and defoamer mixing, it is well mixed through high speed shear, fluopyram, pyrazoles ether bacterium fat, imidacloprid are added, continues to shear
Mix, ground subsequently into horizontal sand mill, sand grinding process temperature may not exceed 35 degree, and particle diameter is below 5UM's after sand milling
Into modulation kettle, mill base, film forming agent, thickener stir about 40 minutes are added in modulation kettle it is made of the present invention and contain fluorine
Pyrrole bacterium acid amides, pyrazoles ether bacterium fat, the suspension seed-coating agent of imidacloprid.
2nd, Assays Example
1st, controlling object：Wheat aphid, wheat root-knot nematode, loose smut of wheat；
2nd, test method：Subjects are arranged in the peasant household farmland of Shandong Shouguang City grandson market town one and carried out, Application Example 1-4's
Seed treatment suspending agent handles wheat seed, and experiment sets comparative example as follows：（1）Comparative example 1：19.5% pyraclostrobin fluorine
Pyrrole bacterium acid amides suspension seed-coating agent（15+4.5）；（2）Comparative example 2:24% fluopyram imidacloprid suspending agent（4+20）；（3）It is right
Ratio 3：21.8% pyraclostrobin imidacloprid suspension seed-coating agent（13.6+8.2）；（4）Comparative example 4：48% fluopyram is hanged
Floating seed coat agent；（5）Comparative example 5：18% pyraclostrobin suspension seed-coating agent；（6）Comparative example 6：600g/L imidacloprid suspended seed coatings
Agent；
Respectively with the seed treatment processing wheat seed of embodiment and reference examples, sowed after drying, test process, consumption and anti-
Control effect as shown in table 1, preventive effect calculation formula is as follows：
Bioassay results are as shown in table 1, as shown in Table 1, right after fluopyram, pyraclostrobin and imidacloprid are compounded
Wheat aphid, loose smut of wheat, the preventing and treating of wheat root-knot nematode are shown after preferable prevention effect, three's compounding, with list
Agent is compared, and can increase the preventing and treating spectrum of single dose, and a drug first goes out preferable prevention effect to three kinds of equal tables of pest and disease damage, and from
Table 1 is not as can be seen that the effect after three's compounding is simple superposition, but shows certain collaboration after both compoundings
Synergistic effect, it is possible to reduce pesticide activity component usage amount, improves prevention effect；In addition, not finding the suspended seed coating of the present invention
Agent produces harmful effect to wheat seeding rate, and poisoning generation is also not observed, and shows the seed treatment of the present invention to crop
It is safe；The especially seed treatment of embodiment 3, the preventing and treating to each pest and disease damage shows excellent significant effect,
It is worth in the popularization and application in production.
Claims (6)
1. a kind of seed treatment compositions, it is characterised in that active component includes fluopyram, pyraclostrobin and pyrrole worm
Quinoline.
2. seed treatment compositions according to claim 1, it is characterised in that the fluopyram, pyraclostrobin
It is 1-15 with the weight ratio with imidacloprid:1-20:1-50.
3. seed treatment compositions according to claim 2, it is characterised in that the weight is than preferably 2-12:2-15:
3-15。
4. the seed treatment compositions according to any one claim in claim 1-3, it is characterised in that the kind
Subprocessing composition is suspension seed-coating agent, seed treatment dispersible pulvis, seed treatment microcapsule suspending agent, seed treatment micro-capsule hang
It is any in floating-suspending agent.
5. seed treatment compositions according to claim 4 are used for the purposes for preventing and treating diseases and pests of agronomic crop.
6. purposes according to claim 5, it is characterised in that the diseases and pests of agronomic crop is grub, plant hopper, thrips, gold
It is any in pin worm, nematode, stem rot, smut, damping-off, samping off, banded sclerotial blight.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710596843.6A CN107318880A (en) | 2017-07-20 | 2017-07-20 | A kind of composition pesticide of containing fluopyram, pyraclostrobin and imidacloprid |
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| CN201710596843.6A CN107318880A (en) | 2017-07-20 | 2017-07-20 | A kind of composition pesticide of containing fluopyram, pyraclostrobin and imidacloprid |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108124862A (en) * | 2017-12-21 | 2018-06-08 | 江西省农业科学院植物保护研究所 | Synergistic auxiliary agent of pesticide for killing borers and use method thereof |
| CN108184893A (en) * | 2018-03-14 | 2018-06-22 | 安徽丰乐农化有限责任公司 | A kind of compounding seed coat agent of pyraclostrobin-containing, shenqinmycin and imidacloprid |
| CN108464309A (en) * | 2018-05-30 | 2018-08-31 | 广东和利农种业股份有限公司 | Contain pyraclostrobin, fluopyram and the seed treatment compositions of chlopyrifos, preparation method and applications |
| CN110384010A (en) * | 2019-08-20 | 2019-10-29 | 淮安市植保植检站 | The method that top spray applies root-pouring method prevention and treatment Snakegourd Fruit thrips in conjunction with punching |
| CN111602663A (en) * | 2019-02-25 | 2020-09-01 | 中国农业大学 | Suspended thread-killing seed coating agent |
| CN112385649A (en) * | 2019-08-16 | 2021-02-23 | 南京科翼新材料有限公司 | Efficient auxiliary agent suitable for pesticide suspension seed coating agent and application method thereof |
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| CN103298341A (en) * | 2010-09-22 | 2013-09-11 | 拜耳知识产权有限责任公司 | Use of active ingredients for controlling nematodes in nematode-resistant crops |
| CN105766986A (en) * | 2016-01-14 | 2016-07-20 | 河北野田农用化学有限公司 | Pesticide composition, and preparation method and application thereof |
| CN106922728A (en) * | 2017-04-26 | 2017-07-07 | 广东省农业科学院植物保护研究所 | A kind of suspension seed-coating agent for preventing and treating brassicaceous vegetable phyllotreta striolata |
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| CN103298341A (en) * | 2010-09-22 | 2013-09-11 | 拜耳知识产权有限责任公司 | Use of active ingredients for controlling nematodes in nematode-resistant crops |
| CN105766986A (en) * | 2016-01-14 | 2016-07-20 | 河北野田农用化学有限公司 | Pesticide composition, and preparation method and application thereof |
| CN106922728A (en) * | 2017-04-26 | 2017-07-07 | 广东省农业科学院植物保护研究所 | A kind of suspension seed-coating agent for preventing and treating brassicaceous vegetable phyllotreta striolata |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108124862A (en) * | 2017-12-21 | 2018-06-08 | 江西省农业科学院植物保护研究所 | Synergistic auxiliary agent of pesticide for killing borers and use method thereof |
| CN108184893A (en) * | 2018-03-14 | 2018-06-22 | 安徽丰乐农化有限责任公司 | A kind of compounding seed coat agent of pyraclostrobin-containing, shenqinmycin and imidacloprid |
| CN108464309A (en) * | 2018-05-30 | 2018-08-31 | 广东和利农种业股份有限公司 | Contain pyraclostrobin, fluopyram and the seed treatment compositions of chlopyrifos, preparation method and applications |
| CN111602663A (en) * | 2019-02-25 | 2020-09-01 | 中国农业大学 | Suspended thread-killing seed coating agent |
| CN112385649A (en) * | 2019-08-16 | 2021-02-23 | 南京科翼新材料有限公司 | Efficient auxiliary agent suitable for pesticide suspension seed coating agent and application method thereof |
| CN110384010A (en) * | 2019-08-20 | 2019-10-29 | 淮安市植保植检站 | The method that top spray applies root-pouring method prevention and treatment Snakegourd Fruit thrips in conjunction with punching |
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