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CN109197889A - A kind of seed treatment compositions of pyraclostrobin-containing, carboxin and clothianidin - Google Patents

A kind of seed treatment compositions of pyraclostrobin-containing, carboxin and clothianidin Download PDF

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Publication number
CN109197889A
CN109197889A CN201811032356.8A CN201811032356A CN109197889A CN 109197889 A CN109197889 A CN 109197889A CN 201811032356 A CN201811032356 A CN 201811032356A CN 109197889 A CN109197889 A CN 109197889A
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CN
China
Prior art keywords
seed treatment
pyraclostrobin
carboxin
clothianidin
seed
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Pending
Application number
CN201811032356.8A
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Chinese (zh)
Inventor
蔡丹群
黄卫荣
王世银
彭军
吴光辉
刘世勇
陈锐东
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Guangdong Guangkang Biochemical Polytron Technologies Inc
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Guangdong Guangkang Biochemical Polytron Technologies Inc
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Application filed by Guangdong Guangkang Biochemical Polytron Technologies Inc filed Critical Guangdong Guangkang Biochemical Polytron Technologies Inc
Priority to CN201811032356.8A priority Critical patent/CN109197889A/en
Publication of CN109197889A publication Critical patent/CN109197889A/en
Pending legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01C—PLANTING; SOWING; FERTILISING
    • A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01C—PLANTING; SOWING; FERTILISING
    • A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/06—Coating or dressing seed
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01C—PLANTING; SOWING; FERTILISING
    • A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/08—Immunising seed
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/32—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pretreatment Of Seeds And Plants (AREA)

Abstract

The invention discloses the seed treatment compositions of a kind of pyraclostrobin-containing, carboxin and clothianidin, it is characterized in that, the active constituent of the composition includes pyraclostrobin, carboxin and clothianidin, the pyraclostrobin, carboxin and clothianidin weight ratio are 1-20:1-20:5-50, and it is 10%~75% that wherein pyraclostrobin, carboxin and clothianidin, which account for the weight percentage of composition,；The dosage form of seed treatment compositions of the present invention includes seed treatment suspending agent, seed treatment emulsion, seed treatment liquor, seed treatment dispersible pulvis, seed treatment microcapsule suspending agent, seed treatment microcapsule suspension-suspendinagent agent；Seed treatment compositions synergistic function of the invention is obvious, especially significant to peanut damping-off, peanut root rot and peanut grub synergy.

Description

A kind of seed treatment compositions of pyraclostrobin-containing, carboxin and clothianidin
Technical field
The invention belongs to technical field of pesticide, are related to a kind of seed treatment compositions, and in particular to pyraclostrobin-containing withers The seed treatment compositions of rust spirit and clothianidin.
Background technique
Pyraclostrobin (Pyraclostrobin), chemical name are as follows: N- [2- [[1- (4- chlorobenzene) -1H- pyrazole-3-yl] Oxygen methyl] phenyl]-N- methoxy methyl carbamate, molecular formula are as follows: C19H18ClN3O4, it is kresoxim-methyl class fungicide, has wider Fungicidal spectrum and higher bactericidal activity, mainly pass through and inhibit the related transfer of glucose phosphorylated, and inhibit hypha,hyphae The growth of body eventually leads to germ death, and the mechanism of action is unique, without cross-resistance with existing fungicides.Pyraclostrobin can be controlled Most of diseases such as Ascomycetes processed, Basidiomycetes, deuteromycetes, Oomycete, the growth to spore germination and leaf intramatrical mycelium There is very strong inhibiting effect, there is protection and therapeutic activity, there is permeability and local systemic activity, the lasting period is long, resistance to rainwater It washes away.Pyraclostrobin be widely used in prevent and treat wheat, rice, peanut, grape, vegetables, potato, banana, fruit tree, walnut, Disease on tea tree, tobacco and ornamental plant, lawn, not only toxicity is low for the compound, to non-target organism safety, and to making User and environment safety are friendly.
Carboxin (carboxin) belongs to benzamides compound, chemical name: 5,6- dihydro -2- methyl-1s, 4- oxygen sulphur Miscellaneous -3- Formanilide, molecular formula: C12H13NO2S is a kind of heterocyclic nitrogen-group fungicide with systemic action.It can penetrate into rudiment Seed and kill intraseminal germ, to the irritating effect of plant growth, and can make to increase production.For preventing and treating by rest fungus, black powder The caused disease in various crop such as bacterium, Rhizoctonia solani Kuhn.
Clothianidin, chemical name: (E) -1- (the chloro- 1,3-thiazoles -5- ylmethyl of 2-) -3- methyl -2-2- nitroguanidine, is one Class highly effective and safe, highly selective novel pesticide, act on it is similar with nicotinic acetylcholine receptor, with tag, stomach toxicity and Systemic activity.It is mainly used for preventing eliminating aphis on rice, vegetables, fruit tree and other crops, leafhopper, thrips, the Semipteras, sheath such as plant hopper Wing mesh, Diptera and certain Lepidoptera class pests insecticide, have efficiently, wide spectrum, dosage is few, toxicity is low, the drug effect lasting period It is long, to crop without phytotoxicity, using it is safe, with conventional pesticide no interactions resistance the advantages that, have brilliant interior suction and osmosis, be Substitute the another kind of high-toxic organic phosphorus pesticide.
For crops in plantation and growth course, the quality of seed quality directly affects the growth of crop, and seed is from broadcasting Kind is gnawed to the seedling stage vulnerable to by the pathogen infection in seed carrying and soil, insect, and seed decay, incompleteness etc. is caused to ask Topic influences germination, the growth of seed, reduces sowing planting percent.Seed-borne fungi is the first dip dyeing source for causing disease, is being grown Season can cause infecting, occur, spread and endangering again for disease；And after seed-borne disease occurs, growth, development, production to crop Amount and quality all have a significant impact；Insect also bites the rhizome of crops seedling stage, seriously affects surviving for crop except bite seed Rate.
Carrying out chemicals treatment to seed using seed coat agent is to prevent and treat subterranean pest-insect and crops soil biography, the economy of seed-borne disease Easy one of method.Seed coat agent is a kind of for crop or other plant seed treatment, the pesticide system with film forming characteristics Agent, it can be formed by curing in the surface of the seed and referred to as plant the film of clothing, and the substances slow release such as contained pesticide and seed manure can kill It goes out subterranean pest-insect, seedling stage pest, there is prevention and treatment sprout term disease and systemic disease, improve percentage of seedgermination, promote seedling health Growth and other effects.
Summary of the invention
The purpose of the present invention is being directed to the deficiency of prior art problem, provide it is a kind of have synergistic and delaying drug resistance with And the general wide seed treatment compositions of prevention and treatment, the active constituent of the seed treatment compositions includes pyraclostrobin, carboxin And clothianidin.
To achieve the above object, the present invention adopts the following technical solutions to achieve:
The seed treatment compositions of a kind of pyraclostrobin-containing, carboxin and clothianidin, active constituent includes pyrazoles ether bacterium Ester, carboxin and clothianidin, wherein pyraclostrobin, carboxin and clothianidin weight ratio are 1-20:1-20:5-50.
Further, the pyraclostrobin, carboxin and clothianidin weight ratio are preferably 1-10:1-10:5-30.
Further, the pyraclostrobin, carboxin and clothianidin weight ratio are further preferably 1-8:1-5:10-25.
The seed treatment compositions of a kind of pyraclostrobin-containing, carboxin and clothianidin, active component pyrazoles ether bacterium The weight percentage that ester, carboxin and clothianidin account for composition is 10%~75%.
Further, active component pyraclostrobin, carboxin and clothianidin account for composition weight percentage it is preferred It is 15%~50%.
Can auxiliary agent well known to active constituent and pesticide field be added by known method in seed treatment compositions of the present invention It is prepared into the dosage form for being suitble to use, including but not limited to seed treatment suspending agent, seed treatment emulsion, seed treatment liquor, kind Any one of subprocessing dispersible pulvis, seed treatment microcapsule suspending agent, seed treatment microcapsule suspension-suspendinagent agent etc..
The auxiliary agent include but is not limited to include solvent, dispersing agent, emulsifier, binder, antifreezing agent, defoaming agent, coating Agent, pH adjusting agent and dyestuff.
Further, the solvent is water acetone, butanone, cyclohexanone, toluene, dimethylbenzene, trimethylbenzene, durene, pyrrole Pyrrolidone, N-Methyl pyrrolidone, DMAC N,N' dimethyl acetamide, dimethylformamide, vegetable oil, petroleum ether, acetonitrile, deionization One of water etc. is a variety of.
Further, the dispersing agent is selected from polycarboxylate, lignosulfonates, alkylnaphthalene sulfonate, alkyl phenol polyoxy One of vinethene is a variety of.
Further, the emulsifier is selected from castor oil polyoxyethylene ether, alkyl phenol formaldehyde resin polyoxyethylene ether, sorb Alcohol acid anhydride monostearate, sorbitan monostearate polyoxyethylene ether, agriculture breast 2201, agriculture breast 1601#, detergent alkylate sulphur One of sour calcium is a variety of.
Further, the binder be selected from polyvinyl alcohol, soluble starch, xanthan gum, sucrose, hydroxyethyl cellulose, Soluble starch, polyethylene glycol, methylcellulose, sticky kaolin, one of attapulgite, paraffin, rosin or a variety of.
Further, the antifreezing agent is selected from ethylene glycol, propylene glycol, glycerol, urea, inorganic salts (such as sodium chloride), third One of triol, polyethylene glycol, sorbierite, urea are a variety of.
Further, the defoaming agent is selected from silicone oil, silicone compound, C10-20Saturated fat acids compound, C8-10 One of fatty alcohols, hexanol, butanol, octanol are a variety of.
Further, the coating agent is selected from polyvinyl alcohol, polyvinylpyrrolidone, polyester resin, acrylic acid and synthesizes and gathers Close object, acrylic resin film forming agent, butadiene resin film forming agent, polyurethane finishing agent, one of cellulose nitrate film forming agent or It is a variety of.
Further, the pH adjusting agent be selected from ammonium hydroxide, potassium hydroxide, sodium hydroxide, hydrochloric acid, acetic acid, citric acid, One of phosphoric acid etc. is a variety of.
Further, the dyestuff in disperse red, disperse blue, disperse violet, active red, reactive blue, active yellow one Kind.
Seed treatment compositions of the invention can also be applied with other active ingredient combinations, other active constituent examples Such as fungicide, bactericide, attractant, insecticide, acaricide, nematicide, plant growth regulator, herbicide, peace Full agent, fertilizer or semiochemical etc..
The present invention creatively by pyraclostrobin, carboxin and clothianidin compounding or mixture, can prevent and treat Cereal and A variety of pest and disease damages on industrial crops especially have apparent synergistic effect to peanut grub, peanut damping-off, peanut root rot.
The invention solves the defect existing in the background technology, the present invention have it is following the utility model has the advantages that
(1) seed treatment compositions of the present invention are desinsection and the combination except disease, can generate higher synergistic effect, Effective component usage amount is reduced, times for spraying is reduced, it is time saving, laborsaving, a variety of insect pests and disease can be prevented and treated simultaneously, especially to life Grub, peanut damping-off, peanut root rot have apparent synergistic effect, reduce drug cost.
(2) composition pesticide of the present invention is answered with fungicide pyraclostrobin, carboxin and insecticide clothianidin Match or mixture, mixed composition expands insecticidal spectrum, primary application can insect prevention remove disease again.
(3) compared with single dose, the composition preventive effect is obviously increased, and the lasting period is long, plays synergy by rationally compounding Effect, reduces times for spraying, dosage, reduces the harm to environmental ecology.
(4) according to pest and pathogen drug resistance theory and practice, the application of the present composition effectively can overcome and prolong The generation for having delayed pathogen and pest resistance to insecticide extends the service life of pesticide.
(5) seed treatment compositions of the invention can remarkably promote seed germination and plant growth to seed safety, into And improve crop yield.
Specific embodiment
To better describe the present invention, following exemplary embodiment is provided.Content mentioned by embodiment cannot recognize To be limitation of the invention, the selection of material prescription can be according to the actual situation by other equivalent or replacing with similar purpose It is replaced for feature.That is, being such as not particularly limited, each feature is a series of equivalent or similar characteristics a example, this The protection scope of the technical solution of invention is subject to claim and is limited.
One, example of formulations
Implement 1:36% pyraclostrobin carboxin clothianidin suspension seed-coating agent (3+5+28)
The suspension seed-coating agent the preparation method comprises the following steps: by above-mentioned formula by deionized water and dispersing agent, thickener, emulsification Agent, antifreezing agent, permanent bordeaux, polyvinyl alcohol, defoaming agent mixing, are uniformly mixed through high speed shear, and addition pyraclostrobin, wither rust Spirit, clothianidin continue shearing and mix, subsequently into grinding in horizontal sand mill, make preparation partial size all at 7 μm hereinafter, to obtain the final product 36% pyraclostrobin carboxin clothianidin suspension seed-coating agent.
Embodiment 2:24% pyraclostrobin carboxin clothianidin seed treatment emulsion (5+4+15)
The specific procedure of processing of the composition seed treatment emulsion are as follows: 1. press formula for pyraclostrobin, carboxin, thiophene worm Amine etc. puts into reaction kettle, then puts into DMF, dimethyl sulfoxide, certain herbaceous plants with big flowers amide, dimethylbenzene equal solvent；2. stirring all molten to material Solution is to transparent；3. be then added remaining material, such as emulsifier, stirring is withered rust to transparent to get 24% pyraclostrobin Clever clothianidin seed treatment emulsion.
Embodiment 3:15% pyraclostrobin carboxin clothianidin seed treatment liquor (1.5+3.5+10)
The seed treatment liquor the preparation method comprises the following steps: 1. by formula by pyraclostrobin, carboxin, clothianidin using molten Agent dimethyl sulfoxide, cyclohexanone, certain herbaceous plants with big flowers amide, abscisic acid, DMF, methanol are sufficiently dissolved to transparent；2. emulsifier is then added, stir It is transparent to mix solution；3. by polyethylene glycol-6000, proline then add water and stir be dissolved to it is transparent；4. the water that step 3. is made Phase liquid is added in the liquid that step 2. makes, and stirring can be prepared by 15% pyraclostrobin carboxin clothianidin to transparent Seed treatment liquor.
Embodiment 4:45% pyraclostrobin carboxin clothianidin suspension seed-coating agent (3+2+40)
The specific procedure of processing of the composition suspension seed-coating agent are as follows: 1. press formula for pyraclostrobin, carboxin, clothianidin Etc. all materials and part water after mixing evenly, pre-processed in next step with colloid mill uniform；2. by the material of the first step successively into Enter a second level sand mill to be sanded；3. second step and material are carried out shearing homogenizing, and the ejected wash water of surplus is added, shearing is equal Even 45% pyraclostrobin carboxin clothianidin suspension seed-coating agent to obtain the final product.
Embodiment 5:48% pyraclostrobin carboxin clothianidin suspension seed-coating agent (5+8+35)
The specific procedure of processing of the composition suspension seed-coating agent are as follows: 1. press formula for pyraclostrobin, carboxin, clothianidin Etc. all materials and part water after mixing evenly, pre-processed in next step with colloid mill uniform；2. by the material of the first step successively into Enter a second level sand mill to be sanded；3. second step and material are carried out shearing homogenizing, and the ejected wash water of surplus is added, shearing is equal Even 48% pyraclostrobin carboxin clothianidin suspension seed-coating agent to obtain the final product.
Embodiment 6:18.8% pyraclostrobin carboxin clothianidin seed treatment microcapsule suspending agent (3.8+5+10)
The specific procedure of processing of the seed treatment microcapsule suspending agent are as follows: 1. press formula for pyraclostrobin, carboxin, thiophene worm Amine etc. puts into reaction kettle, and capsule material oil phase is then added, and partial emulsifier is added；2. 55-60 DEG C is heated under stiring, until being formed Transparent solution；3. water is then added, 55-60 DEG C of heat preservation is simultaneously stirred under shearing, and water phase and film forming agent is then added, and keeps the temperature 30 points Then clock is cooled to room temperature；3. permanent bordeaux, aluminium-magnesium silicate and partial emulsifier are ground into suspending agent；4. as water was making It is added excessively in journey, partial moisture can be removed after the completion of third step；5. the 3rd, 4 liang of step material is mixed about 10-20 points of shearing Clock is up to 18.8% pyraclostrobin carboxin clothianidin seed treatment microcapsule suspending agent of pyrrole.
Two, Assays Example
1, controlling object: peanut damping-off, peanut root rot, peanut grub
2, test method: subjects carry out with being arranged in yiyang, hunan city peanut, at the seed of Application Example 1-6 Compositions-treated peanut seed is managed, test setting control treatment is as follows: (1) it is outstanding to compare 1:8.8% pyraclostrobin carboxin Floating seed coat agent (3.8+5)；(2) 2:32% pyraclostrobin clothianidin suspension seed-coating agent (4+28) is compareed；(3) 3:40% is compareed Carboxin clothianidin suspension seed-coating agent (2+38)；(4) 4:18% pyraclostrobin suspension seed-coating agent is compareed；(5) 5:6% is compareed Carboxin suspension seed-coating agent；(6) 6:48% clothianidin suspension seed-coating agent is compareed.The seed of embodiment and control treatment group is used respectively Inorganic agent handles peanut seed, sows after drying, test process, dosage and control efficiency are as shown in table 1, and preventive effect calculation formula is such as Under:
Prevention and treatment of the 1 different disposal medicament of table to peanut pest and disease damage
By the bioassay test result of upper table 1 it is found that by pyraclostrobin, carboxin and clothianidin combined application in Peanut seed can effectively prevent peanut damping-off, peanut root rot and peanut grub, and diseases prevention insect prevention reduces labor intensive, Compared to the preventive effect of single-activity and the two compounding, the composition is synergistic significant, thereby reduces dosage and drug cost, And the sustainable development for being conducive to ecological environment during test, has no that the peanut of processing has phytotoxicity generation, illustrates the composition To crop safety within the scope of recommended drug amount, it is worth promoting and applying on the market.
Based on the above description of the preferred embodiments of the present invention, through the above description, related personnel completely can be with Without departing from the scope of the technological thought of the present invention', various changes and amendments are carried out.The technical scope of this invention It is not limited to the contents of the specification, it is necessary to determine the technical scope according to the scope of the claims.

Claims (8)

1. the seed treatment compositions of a kind of pyraclostrobin-containing, carboxin and clothianidin, which is characterized in that the composition Active constituent includes pyraclostrobin, carboxin and clothianidin, and the pyraclostrobin, carboxin and clothianidin weight ratio are 1- 20:1-20:5-50。
2. the seed treatment compositions of a kind of pyraclostrobin-containing according to claim 1, carboxin and clothianidin, special Sign is: the pyraclostrobin, carboxin and clothianidin weight ratio are preferably 1-10:1-10:5-30.
3. the seed treatment compositions of a kind of pyraclostrobin-containing according to claim 1, carboxin and clothianidin, special Sign is: the pyraclostrobin, carboxin and clothianidin weight ratio are further preferably 1-8:1-5:10-25.
4. the seed treatment compositions of a kind of pyraclostrobin-containing according to claim 1, carboxin and clothianidin, special Sign is: the weight percentage that the pyraclostrobin, carboxin and clothianidin account for composition is 10%~75%.
5. the seed treatment compositions of a kind of pyraclostrobin-containing according to claim 1, carboxin and clothianidin, special Sign is: the weight percentage that the pyraclostrobin, carboxin and clothianidin account for composition is 10%~75%.
6. a kind of pyraclostrobin-containing, carboxin described in any one of -5 claims and clothianidin according to claim 1 Seed treatment compositions, it is characterised in that: the dosage form of the seed treatment compositions is seed treatment suspending agent, seed treatment cream Agent, seed treatment liquor, seed treatment dispersible pulvis, seed treatment microcapsule suspending agent, seed treatment microcapsule suspension-suspendinagent agent Any one of.
7. the seed treatment compositions of a kind of pyraclostrobin-containing according to claim 6, carboxin and clothianidin are used for The purposes for preventing and treating diseases and pests of agronomic crop.
8. purposes according to claim 7, which is characterized in that the corps diseases are peanut damping-off, Roots of Peanut Maize ear rot and peanut grub.
CN201811032356.8A 2018-09-05 2018-09-05 A kind of seed treatment compositions of pyraclostrobin-containing, carboxin and clothianidin Pending CN109197889A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110476960A (en) * 2019-09-19 2019-11-22 河北省农林科学院植物保护研究所 Clothianidin film slow-release seed treatment suspending agent and the preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101087531A (en) * 2004-12-24 2007-12-12 拜尔农作物科学股份公司 Insecticides based on selected neonicotinoids and strobilurins
CN104604927A (en) * 2015-01-30 2015-05-13 北农（海利）涿州种衣剂有限公司 Seed-treating agent containing clothianidin, pyraclostrobin and metconazole
CN105875594A (en) * 2016-05-13 2016-08-24 创新美兰（合肥）股份有限公司 Pyraclostrobin, thiamethoxam and carboxin compound suspended seed coating and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101087531A (en) * 2004-12-24 2007-12-12 拜尔农作物科学股份公司 Insecticides based on selected neonicotinoids and strobilurins
CN104604927A (en) * 2015-01-30 2015-05-13 北农（海利）涿州种衣剂有限公司 Seed-treating agent containing clothianidin, pyraclostrobin and metconazole
CN105875594A (en) * 2016-05-13 2016-08-24 创新美兰（合肥）股份有限公司 Pyraclostrobin, thiamethoxam and carboxin compound suspended seed coating and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110476960A (en) * 2019-09-19 2019-11-22 河北省农林科学院植物保护研究所 Clothianidin film slow-release seed treatment suspending agent and the preparation method and application thereof
CN110476960B (en) * 2019-09-19 2021-06-15 河北省农林科学院植物保护研究所 Clothianidin film slow-release seed treatment suspension and its preparation method and application

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Application publication date: 20190115