CN102113516A - Insect killing compound containing chlorantraniliprole - Google Patents
Insect killing compound containing chlorantraniliprole Download PDFInfo
- Publication number
- CN102113516A CN102113516A CN2010100038439A CN201010003843A CN102113516A CN 102113516 A CN102113516 A CN 102113516A CN 2010100038439 A CN2010100038439 A CN 2010100038439A CN 201010003843 A CN201010003843 A CN 201010003843A CN 102113516 A CN102113516 A CN 102113516A
- Authority
- CN
- China
- Prior art keywords
- rynaxypyr
- mass
- pesticidal combination
- kinds
- accounts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 title claims abstract description 89
- 239000005886 Chlorantraniliprole Substances 0.000 title abstract description 5
- 241000238631 Hexapoda Species 0.000 title description 10
- 150000001875 compounds Chemical class 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract description 18
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 claims abstract description 13
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 claims abstract description 10
- 239000005875 Acetamiprid Substances 0.000 claims abstract description 10
- 239000005663 Pyridaben Substances 0.000 claims abstract description 10
- DWFZBUWUXWZWKD-UHFFFAOYSA-N pyridaben Chemical compound C1=CC(C(C)(C)C)=CC=C1CSC1=C(Cl)C(=O)N(C(C)(C)C)N=C1 DWFZBUWUXWZWKD-UHFFFAOYSA-N 0.000 claims abstract description 10
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical group CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 claims abstract description 8
- IRUJZVNXZWPBMU-UHFFFAOYSA-N cartap Chemical compound NC(=O)SCC(N(C)C)CSC(N)=O IRUJZVNXZWPBMU-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229960001952 metrifonate Drugs 0.000 claims abstract description 8
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 claims abstract description 8
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 claims abstract description 7
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 claims description 38
- 230000000361 pesticidal effect Effects 0.000 claims description 28
- 239000000843 powder Substances 0.000 claims description 24
- 238000009736 wetting Methods 0.000 claims description 23
- -1 chlopyrifos Chemical compound 0.000 claims description 21
- 239000000375 suspending agent Substances 0.000 claims description 21
- 238000009825 accumulation Methods 0.000 claims description 20
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 18
- 239000004562 water dispersible granule Substances 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 17
- 239000004530 micro-emulsion Substances 0.000 claims description 15
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 13
- 229910052731 fluorine Inorganic materials 0.000 claims description 13
- 239000011737 fluorine Substances 0.000 claims description 13
- 239000004615 ingredient Substances 0.000 claims description 11
- KDGQGEKLPWYCGO-UHFFFAOYSA-N 1-butoxybutane;urea Chemical compound NC(N)=O.CCCCOCCCC KDGQGEKLPWYCGO-UHFFFAOYSA-N 0.000 claims description 8
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 239000004202 carbamide Substances 0.000 claims description 7
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 claims description 7
- QYMMJNLHFKGANY-UHFFFAOYSA-N profenofos Chemical compound CCCSP(=O)(OCC)OC1=CC=C(Br)C=C1Cl QYMMJNLHFKGANY-UHFFFAOYSA-N 0.000 claims description 7
- 241000607479 Yersinia pestis Species 0.000 abstract description 10
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 5
- 235000009566 rice Nutrition 0.000 abstract description 5
- 229920000742 Cotton Polymers 0.000 abstract description 4
- 235000013399 edible fruits Nutrition 0.000 abstract description 4
- 230000000749 insecticidal effect Effects 0.000 abstract description 4
- 230000002195 synergetic effect Effects 0.000 abstract description 4
- 235000013311 vegetables Nutrition 0.000 abstract description 4
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 abstract description 2
- 230000001934 delay Effects 0.000 abstract description 2
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004480 active ingredient Substances 0.000 abstract 3
- NPWRZDAOZCTPKY-UHFFFAOYSA-N C(CC)Br.[P] Chemical compound C(CC)Br.[P] NPWRZDAOZCTPKY-UHFFFAOYSA-N 0.000 abstract 1
- JFLRKDZMHNBDQS-UCQUSYKYSA-N CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C Chemical compound CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C JFLRKDZMHNBDQS-UCQUSYKYSA-N 0.000 abstract 1
- 239000005944 Chlorpyrifos Substances 0.000 abstract 1
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 239000005930 Spinosad Substances 0.000 abstract 1
- 239000005937 Tebufenozide Substances 0.000 abstract 1
- 230000001186 cumulative effect Effects 0.000 abstract 1
- WOWBFOBYOAGEEA-UHFFFAOYSA-N diafenthiuron Chemical compound CC(C)C1=C(NC(=S)NC(C)(C)C)C(C(C)C)=CC(OC=2C=CC=CC=2)=C1 WOWBFOBYOAGEEA-UHFFFAOYSA-N 0.000 abstract 1
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 abstract 1
- QBSJMKIUCUGGNG-UHFFFAOYSA-N isoprocarb Chemical compound CNC(=O)OC1=CC=CC=C1C(C)C QBSJMKIUCUGGNG-UHFFFAOYSA-N 0.000 abstract 1
- 239000002547 new drug Substances 0.000 abstract 1
- 229940014213 spinosad Drugs 0.000 abstract 1
- QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 description 17
- 239000003814 drug Substances 0.000 description 16
- 230000008569 process Effects 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 239000005995 Aluminium silicate Substances 0.000 description 7
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 7
- 241000500437 Plutella xylostella Species 0.000 description 7
- 235000012211 aluminium silicate Nutrition 0.000 description 7
- 239000002131 composite material Substances 0.000 description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 7
- 150000002825 nitriles Chemical class 0.000 description 7
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- 150000005215 alkyl ethers Chemical class 0.000 description 6
- 229940077388 benzenesulfonate Drugs 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 241000255777 Lepidoptera Species 0.000 description 5
- 238000003556 assay Methods 0.000 description 5
- 239000012752 auxiliary agent Substances 0.000 description 5
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 238000012856 packing Methods 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 241000008892 Cnaphalocrocis patnalis Species 0.000 description 4
- 241000209094 Oryza Species 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 206010033799 Paralysis Diseases 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 241001486250 Etiella zinckenella Species 0.000 description 2
- 241000256247 Spodoptera exigua Species 0.000 description 2
- 241000985245 Spodoptera litura Species 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- 210000004894 snout Anatomy 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 description 1
- 239000005660 Abamectin Substances 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000256844 Apis mellifera Species 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 241000665051 Chilo sacchariphagus indicus Species 0.000 description 1
- 241000426497 Chilo suppressalis Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241001498622 Cixius wagneri Species 0.000 description 1
- 241000238557 Decapoda Species 0.000 description 1
- 241000738498 Epitrix pubescens Species 0.000 description 1
- 241000255967 Helicoverpa zea Species 0.000 description 1
- 241000346285 Ostrinia furnacalis Species 0.000 description 1
- 241001253920 Ryania Species 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 241000255901 Tortricidae Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- ZXQYGBMAQZUVMI-XDHOZWIPSA-N [cyano-(3-phenoxyphenyl)methyl] 3-[(e)-2-chloro-3,3,3-trifluoroprop-1-enyl]-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)C(\C=C(\Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-XDHOZWIPSA-N 0.000 description 1
- 229950008167 abamectin Drugs 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical group 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
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- 231100000636 lethal dose Toxicity 0.000 description 1
- 231100000225 lethality Toxicity 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- NNKVPIKMPCQWCG-UHFFFAOYSA-N methamidophos Chemical compound COP(N)(=O)SC NNKVPIKMPCQWCG-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 230000004118 muscle contraction Effects 0.000 description 1
- 230000003387 muscular Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明公开了含有氯虫苯甲酰胺的杀虫组合物，其中由两种有效成份A和B组成，A成份是氯虫苯甲酰胺，B成份是高效氯氰菊酯、三氟氯氰菊酯、毒死蜱、丙溴磷、敌百虫、丁醚脲、溴虫腈、甲胺基阿维菌素苯甲酸盐、多杀菌素、虫酰肼、氟铃脲、溴虫腈、哒螨灵、啶虫脒、异丙威、杀虫双、杀螟丹中的一种，所述两种有效成份A和B组成质量比为1∶60～60∶1。所述两种有效成份A和B的累积质量百分比占总质量的1％～85％。本发明利用两种活性组份混配，具有明显的增效作用，可减少有效成份用药量，延缓害虫害螨对新药剂氯虫苯甲酰抗药性的产生。本发明可用于防治水稻、棉花、蔬菜、果树等上的多种害虫。The invention discloses an insecticidal composition containing chlorantraniliprole, which consists of two active ingredients A and B, the A component is chlorantraniliprole, and the B component is beta-cypermethrin, cyhalothrin, chlorpyrifos, and propyl bromide Phosphorus, trichlorfon, diafenthiuron, chlorfenapyr, emamectin benzoate, spinosad, tebufenozide, hexaflumuron, chlorfenapyr, pyridaben, acetamiprid, One of isoprocarb, dimehypo and cartap, the mass ratio of the two active ingredients A and B is 1:60-60:1. The cumulative mass percentage of the two active ingredients A and B accounts for 1%-85% of the total mass. The invention utilizes two kinds of active components to mix, which has obvious synergistic effect, can reduce the dosage of the active components, and delays the occurrence of pest mite resistance to the new drug chlorantraniliprole. The invention can be used to prevent and control various pests on rice, cotton, vegetables, fruit trees and the like.
Description
Technical field
The present invention relates to a kind of agricultural insecticidal medicament, especially relate to the Pesticidal combination and the application thereof that contain Rynaxypyr.
Background technology
On January 1st, 2007, the contour malicious agricultural chemicals of acephatemet is forbidden comprehensively, and fluorine worm nitrile becomes one of high-toxic pesticide substitute of national agrotechnical center emphasis popularization simultaneously, has been the principal item of domestic rice district control rice leaf roller, snout moth's larva so far.Yet, on February 1st, 2009, general office of the Ministry of Agriculture sends about printing and distributing the notice of " the 8th national agriculture chemical registration evaluation committee fourth plenary session summary ", from on July 1st, 2009, except that health usefulness, part dry land coating agent for seed, stop to sell and using the pesticidal preparations that is used for otherwise fluorine-containing worm nitrile composition within the border in China.Stopping using of fluorine worm nitrile, mainly contain the factor of three aspects: at first, fluorine worm nitrile is very big to aquatile toxicity, and is unfriendly to environment; Secondly, 2008 a lot of at home local, and rice leaf roller, snout moth's larva etc. resistance occurs to fluorine worm nitrile, and fluorine worm nitrile effect obviously reduces than before; The superseded paces of Rynaxypyr listing quickening fluorine worm nitrile of the 3rd, 2008 year Du Pont.
Rynaxypyr (chlorantraniliprole), efficient, interior suction, good penetrability, the lasting period is long, little poison.Can be used for preventing and treating nearly all lepidoptera pests such as diamond-back moth, rice leaf roller, striped rice borer, paddy stem borer, prodenia litura, beet armyworm, lima bean pod borer, corn borer.Its mechanism of action is by activating the ryania acceptor in the insect muscle, cause the unconfined release of internal calcium ion, stop contraction of muscle, thereby make insect stop to get food rapidly, occur that muscular paralysis, vigor disappear, paralysis, until death.Insect eats paralysis and stops to cause harm from getting, and only needs the time of a few minutes.And this composition is to not injury substantially such as aquatiles such as fish, shrimp, honeybee, predation mite.Can prevent and treat multiple lepidoptera pest.
But the insecticide that contains a kind of active constituent is to agricultural insect management, and often because of using continuously, insect is easy to generate pesticide resistance, and medication causes the pollution grows worse of environment etc. often.Advantage of the present invention and good effect are that the agricultural chemicals with two kinds of different structures, the mechanism of action carries out composite, be the control resistant insect, enlarge insecticidal spectrum and improve the effective way of drug effect, the more important thing is and avoid or delay the generation of insect new composition Rynaxypyr resistance.
Summary of the invention
The objective of the invention is to: provide the Pesticidal combination that contains Rynaxypyr of a kind of efficient, wide spectrum, low toxicity, with cause harm multiple lepidoptera pest on paddy rice, cotton, vegetables, the fruit tree etc. of control.
To achieve these goals, technical scheme of the present invention is: the Pesticidal combination that a kind of chloride worm benzamide is provided, wherein, form by two kinds of effective ingredient A and B, the A composition is a Rynaxypyr, the B composition is a beta-cypermethrin, Cyhalothrin, chlopyrifos, Profenofos, chlorophos, the butyl ether urea, chlorfenapyr, emamection benaoate, pleocidin, the worm hydrazides, fluorine bell urea, chlorfenapyr, pyridaben, Acetamiprid, different the third one-tenth, dimehypo, a kind of in the cartap, it is 1: 60～60: 1 that described two kinds of effective ingredient A and B form mass ratio.
Preferably, described two kinds of effective ingredient A and B composition mass ratio is 1: 50～5: 1.
Preferably, the mass accumulation percentage of described two kinds of effective ingredient A and B accounts for 1%～85% of gross mass.
Preferably, the mass accumulation percentage of described two kinds of effective ingredient A and B accounts for 0.6%～82% of gross mass.
Preferably, the described Pesticidal combination that contains Rynaxypyr can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules, microemulsion or suspending agent.
The invention has the advantages that: the present invention utilizes two kinds of active constituents to be mixed, and has obvious synergistic effect, can reduce the effective ingredient dosage, delays insect evil mite to the drug-fast generation of new medicament chlorine worm benzoyl.The present invention can be used for preventing and treating the various pests on paddy rice, cotton, vegetables, the fruit tree etc.
Embodiment
The invention will be further described below in conjunction with preferred embodiment, but the present invention never is limited to following embodiment.Each component percentage composition all by quality ratio in following examples.
Embodiment one
10.2% Rynaxypyr butyl ether urea, promptly both mass ratioes are 1: 50 wetting powder
Common process is formed, wherein
Rynaxypyr 0.2%
Butyl ether urea 10%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 6%
Sodium methylene bis-naphthalene sulfonate 8%
Kaolin is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises soluble liquid, water dispersible granules, microemulsion or suspending agent.The mass accumulation percentage of described Rynaxypyr and butyl ether urea accounts for 10.2% of gross mass.
At first former medicine, auxiliary agent, filler are mixed in proportion, and fully stir, pulverize then, after the assay was approved, wetting powder can carry out the packing of product.
Embodiment two
3% Rynaxypyr Cyhalothrin, promptly both mass ratioes are 1: 5 microemulsion
Common process is formed, wherein
Rynaxypyr 0.5%
Cyhalothrin 2.5%
N, dinethylformamide 6%
Glycerine 8%
Calcium dodecyl benzene sulfonate 4%
Tween 80 12%
Water is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or suspending agent.The mass accumulation percentage of described Rynaxypyr and Cyhalothrin accounts for 3% of gross mass.
Embodiment three
20.5% Rynaxypyr and dursban, promptly both mass ratioes are 1: 40 suspending agent
Common process is formed, wherein
Rynaxypyr 0.5%
Chlopyrifos 20%
Polyoxyethylene alkyl ether 1.2%
Polyoxyethylene nonylphenol ether 1.4%
Sodium alkyl benzene sulfonate 1.0%
Magnesiumaluminumsilicate 0.05%
Glycerine 3%
Water is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or microemulsion.The mass accumulation percentage of described Rynaxypyr and chlopyrifos accounts for 20.5% of gross mass.
Embodiment four
12% Rynaxypyr Profenofos, promptly both mass ratioes are 5: 1 water dispersible granules
Common process is formed, wherein
Rynaxypyr 10%
Profenofos 2%
Fatty alcohol 6%
Ammonium sulfate 5%
Kaolin is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises wetting powder, soluble liquid, microemulsion or suspending agent.The mass accumulation percentage of described Rynaxypyr and Profenofos accounts for 12% of gross mass.
Embodiment five
82% Rynaxypyr chlorophos, promptly both mass ratioes are 1: 40 soluble powder
Common process is formed, wherein
Rynaxypyr 2%
Chlorophos 80%
Lauryl sodium sulfate is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises wetting powder, water dispersible granules, microemulsion or suspending agent.The mass accumulation percentage of described Rynaxypyr and chlorophos accounts for 82% of gross mass.
Embodiment six
6% Rynaxypyr beta-cypermethrin, promptly both mass ratioes are 1: 3 suspending agent
Common process is formed, wherein
Rynaxypyr 1.5%
Beta-cypermethrin 4.5%
Polyoxyethylene alkyl ether 1.2%
Polyoxyethylene nonylphenol ether 1.4%
Sodium alkyl benzene sulfonate 1.0%
Magnesiumaluminumsilicate 0.05%
Propane diols 3%
Water is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or microemulsion.The mass accumulation percentage of described Rynaxypyr and beta-cypermethrin accounts for 6% of gross mass.
Embodiment seven
0.6% Rynaxypyr emamection benaoate, promptly both mass ratioes are 1: 5 microemulsion
Common process is formed, wherein
Rynaxypyr 0.1%
Methyl abamectin benzoate 0.5%
N, dinethylformamide 4%
Glycerine 2.5%
Calcium dodecyl benzene sulfonate 5%
Tween 80 16%
Water is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or suspending agent.The mass accumulation percentage of described Rynaxypyr and emamection benaoate accounts for 0.6% of gross mass.
Embodiment eight
5% Rynaxypyr pleocidin, promptly both mass ratioes are 1: 1 suspending agent
Common process is formed, wherein
Rynaxypyr 2.5%
Pleocidin 2.5%
Polyoxyethylene alkyl ether 12%
Polyoxyethylene nonylphenol ether 1.4%
Sodium alkyl benzene sulfonate 1.0%
Magnesiumaluminumsilicate 0.05%
Water is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or microemulsion.The mass accumulation percentage of described Rynaxypyr and pleocidin accounts for 5% of gross mass.
Embodiment nine
4% Rynaxypyr worm hydrazides, promptly both mass ratioes are 1: 1 suspending agent
Common process is formed, wherein
Rynaxypyr 2%
Worm hydrazides 2%
Polyoxyethylene alkyl ether 1.5%
Polyoxyethylene nonylphenol ether 1.5%
Sodium alkyl benzene sulfonate 1.0%
Magnesiumaluminumsilicate 0.05%
Glycerine 3%
Water is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or suspending agent.The mass accumulation percentage of described Rynaxypyr and worm hydrazides accounts for 4% of gross mass.
Embodiment ten
6% Rynaxypyr and hexaflumuron, promptly both mass ratioes are 1: 5 wetting powder
Common process is formed, wherein
Rynaxypyr 1%
Fluorine bell urea 5%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 6%
Sodium methylene bis-naphthalene sulfonate 8%
Kaolin is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises soluble liquid, water dispersible granules, microemulsion or suspending agent.The mass accumulation percentage of described Rynaxypyr and fluorine bell urea accounts for 6% of gross mass.
At first former medicine, auxiliary agent, filler are mixed in proportion, and fully stir, pulverize then, after the assay was approved, wetting powder can carry out the packing of product.
Embodiment 11
12% Rynaxypyr chlorfenapyr, promptly both mass ratioes are 1: 5 suspending agent
Common process is formed, wherein
Rynaxypyr 2%
Chlorfenapyr 10%
Polyoxyethylene alkyl ether 1.2%
Polyoxyethylene nonylphenol ether 1.4%
Sodium alkyl benzene sulfonate 1.0%
Magnesiumaluminumsilicate 0.05%
Propane diols 3%
Water is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or suspending agent.The mass accumulation percentage of described Rynaxypyr and chlorfenapyr accounts for 12% of gross mass.
Embodiment 12
15% Rynaxypyr pyridaben, promptly both mass ratioes are 2: 13 wetting powder
Common process is formed, wherein
Rynaxypyr 2%
Pyridaben 13%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 6%
Sodium methylene bis-naphthalene sulfonate 8%
Kaolin is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises soluble liquid, water dispersible granules, microemulsion or suspending agent.The mass accumulation percentage of described Rynaxypyr and pyridaben accounts for 15% of gross mass.
At first former medicine, auxiliary agent, filler are mixed in proportion, and fully stir, pulverize then, after the assay was approved, wetting powder can carry out the packing of product.
Embodiment 13
6% Rynaxypyr Acetamiprid, promptly both mass ratioes are 1: 1 water dispersible granules
Common process is formed, wherein
Rynaxypyr 3%
Acetamiprid 3%
Lauryl sodium sulfate 5%
Calcium lignosulfonate 8%
Sucrose 2%
Sodium methylene bis-naphthalene sulfonate 5%
Polyvinylpyrrolidone 10%
Kaolin is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises wetting powder, soluble liquid, microemulsion or suspending agent.The mass accumulation percentage of described Rynaxypyr and Acetamiprid accounts for 6% of gross mass.
Embodiment 14
10% Rynaxypyr Mobucin, promptly both mass ratioes are 1: 4 wetting powder
Common process is formed, wherein
Rynaxypyr 2%
Mobucin 8%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 6%
Sodium methylene bis-naphthalene sulfonate 8%
Kaolin is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises soluble liquid, water dispersible granules, microemulsion or suspending agent.Described Rynaxypyr accounts for 10% of gross mass with different the third one-tenth mass accumulation percentage.
At first former medicine, auxiliary agent, filler are mixed in proportion, and fully stir, pulverize then, after the assay was approved, wetting powder can carry out the packing of product.
Embodiment 15
20% Rynaxypyr dimehypo, promptly both mass ratioes are 1: 1 suspending agent
Common process is formed, wherein
Rynaxypyr 10%
Dimehypo 10%
Polyoxyethylene alkyl ether 1.2%
Polyoxyethylene nonylphenol ether 1.4%
Sodium alkyl benzene sulfonate 1.0%
Magnesiumaluminumsilicate 0.05%
Propane diols 3%
Water is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules or suspending agent.The mass accumulation percentage of described Rynaxypyr and dimehypo accounts for 20% of gross mass.
Embodiment 16
82% Rynaxypyr cartap, promptly both mass ratioes are 1: 40 wetting powder
Common process is formed, wherein
Rynaxypyr 2%
Cartap 80%
Lauryl sodium sulfate 2%
Sodium lignin sulfonate 6%
Sodium methylene bis-naphthalene sulfonate 8%
Kaolin is mended to 100%
The Pesticidal combination of described chloride worm benzamide also can be made into different application forms, comprises soluble liquid, water dispersible granules, microemulsion or suspending agent.The mass accumulation percentage of described Rynaxypyr and cartap accounts for 82% of gross mass.
At first former medicine, auxiliary agent, filler are mixed in proportion, and fully stir, pulverize then, after the assay was approved, wetting powder can carry out the packing of product.
Biological Examples one:
The examination worm is adopted the indoor diamond-back moth that connects the generation raising, and concrete grammar is:
Medicament preparation: test former medicine and provide former medicine, make the preparation that needs by I the product development center Drug Manufacturing Room of company for producer.Before the test, be mixed with different concentration gradients, 6 concentration of every proportioning according to different mix proportion schemes.
Connect worm: put into 3 in cabbage leaves dish of the same size in the 9cm culture dish, 3 instar larvaes of selecting neat uniformity are in culture dish, and every ware connects 30 of worms.
Spraying: spray under 50PSI pressure with the POTT spray tower, spray 2 milliliters of medicines at every turn.Leaf dish positive and negative is all sprayed.Spraying is from low concentration, and blank sprays the equivalent clear water.Each proportioning is provided with 6 concentration gradients, three wares of every concentration spray.Put into after having sprayed the insectary (25 ± 1 ℃, 12H/12H) in.
Investigation statistics: handle and check dead borer population after 48 hours, with Abbott formula calculation correction lethality.The appliance computer program is obtained each for the single agent lethal concentration of 50 LC50 of examination, calculates the co-toxicity coefficient (CTC value) of using medicament with according to the abundant method of Sun Yun, CTC value greater than 100 be synergistic effect, equaling 100 is addition, is antagonism less than 100.Concrete computational methods are as follows:
Set a kind of single agent (A) and be the single agent of standard, specifying its toxicity index (TI) is 100, then:
The TI of theoretical toxicity index (TTI)=each single agent of ∑ of the mixture * percentage of single agent in mixture
Result of the test sees Table 1, table 2.
Each reagent agent of table 1 is to the virulence of diamond-back moth
| Medicament | LC50(ppm) |
| Rynaxypyr | 4.46 |
| Beta-cypermethrin | 223.02 |
| Cyhalothrin | 218.24 |
| Chlopyrifos | 273.40 |
| Profenofos | 272.46 |
| Chlorophos | 284.43 |
| The butyl ether urea | 59.50 |
| Emamection benaoate | 0.40 |
| Pleocidin | 15.65 |
| The worm hydrazides | 78.90 |
| Fluorine bell urea | 10.26 |
| Chlorfenapyr | 8.22 |
| Pyridaben | 340.25 |
| Acetamiprid | 380.76 |
| Mobucin | 270.11 |
| Dimehypo | 340.37 |
| Cartap | 355.41 |
The composition of the chloride worm benzamide of table 2 is to the composite effect of diamond-back moth
| Composition | Ratio | LC50 (ppm) | CTC |
| Rynaxypyr+beta-cypermethrin | 1∶3 | 12.34 | 136.38 |
| Rynaxypyr+Cyhalothrin | 1∶5 | 18.25 | 133.04 |
| Rynaxypyr+chlopyrifos | 1∶40 | 69.68 | 159.81 |
| Rynaxypyr+Profenofos | 5∶1 | 4.48 | 119.06 |
| Rynaxypyr+chlorophos | 1∶40 | 85.49 | 131.49 |
| Rynaxypyr+butyl ether urea | 1∶50 | 33.13 | 144.58 |
| Rynaxypyr+emamection benaoate | 1∶5 | 0.31 | 152.11 |
| Rynaxypyr+pleocidin | 1∶1 | 5.5 | 126.21 |
| Rynaxypyr+worm hydrazides | 1∶1 | 6.38 | 132.31 |
| Rynaxypyr+fluorine bell urea | 1∶5 | 6.75 | 124.92 |
| Rynaxypyr+chlorfenapyr | 1∶5 | 5.53 | 130.33 |
| Rynaxypyr+pyridaben | 1∶6.5 | 28.46 | 120.91 |
| Rynaxypyr+Acetamiprid | 1∶1 | 7.51 | 117.39 |
| Rynaxypyr+Mobucin | 1∶4 | 16.34 | 128.00 |
| Rynaxypyr+dimehypo | 1∶1 | 6.37 | 138.2 |
| Rynaxypyr+cartap | 1∶40 | 109.32 | 111.20 |
From table 1 and table 2 as can be seen, with composite each composition of Rynaxypyr to the co-toxicity coefficient (CTC) of diamond-back moth all greater than 100, show that each composite effect all has synergistic effect to diamond-back moth.Each complex composition is processed into suitable formulation, but the effectively preventing rice leaf roller,, multiple lepidoptera pest such as diamond-back moth, cotton bollworm, beet armyworm, prodenia litura, lima bean pod borer, leaf roller.Because of butyl ether urea, chlorfenapyr and pyridaben have acaricidal activity, Acetamiprid and Mobucin flea beetle, aleyrodid, plant hopper etc. there is good activity, so composite dose of Rynaxypyr and butyl ether urea or chlorfenapyr or pyridaben composite dose, Rynaxypyr and Acetamiprid composite dose, Rynaxypyr and Mobucin except effective control lepidoptera pest, other insect also there is certain effect, enlarge insecticidal spectrum, reduced the medication number of times of agricultural chemicals.For the new medicament Rynaxypyr, delayed the generation of pest resistance to insecticide, can be used for preventing and treating the various pests that paddy rice, cotton, vegetables, fruit tree etc. are taken place.
Claims (5)
1. the Pesticidal combination that contains Rynaxypyr, it is characterized in that: form by two kinds of effective ingredient A and B, the A composition is a Rynaxypyr, the B composition is a kind of in beta-cypermethrin, Cyhalothrin, chlopyrifos, Profenofos, chlorophos, butyl ether urea, chlorfenapyr, emamection benaoate, pleocidin, worm hydrazides, fluorine bell urea, chlorfenapyr, pyridaben, Acetamiprid, Mobucin, dimehypo, the cartap, and it is 1: 60～60: 1 that described two kinds of effective ingredient A and B form mass ratio.
2. the Pesticidal combination that contains Rynaxypyr as claimed in claim 1 is characterized in that: it is 1: 50～5: 1 that described two kinds of effective ingredient A and B form mass ratio.
3. the Pesticidal combination that contains Rynaxypyr as claimed in claim 1 is characterized in that: the mass accumulation percentage of described two kinds of effective ingredient A and B accounts for 1%～85% of gross mass.
4. the Pesticidal combination that contains Rynaxypyr as claimed in claim 3 is characterized in that: the mass accumulation percentage of described two kinds of effective ingredient A and B accounts for 0.6%～82% of gross mass.
5. the Pesticidal combination that contains Rynaxypyr as claimed in claim 1, it is characterized in that: the Pesticidal combination of described chloride worm benzamide can be made into different application forms, comprises wetting powder, soluble liquid, water dispersible granules, microemulsion or suspending agent.
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| CN105580815A (en) * | 2014-10-18 | 2016-05-18 | 陕西美邦农药有限公司 | Pesticide composition containing ZJ3757 |
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| CN101755819A (en) * | 2009-09-24 | 2010-06-30 | 张志高 | Insecticidal composition having chlorantraniliprole |
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