CN105145601A - Pesticide composition containing pyraclostrobin and 2-(acetoxyl) benzoic acid - Google Patents
Pesticide composition containing pyraclostrobin and 2-(acetoxyl) benzoic acid Download PDFInfo
- Publication number
- CN105145601A CN105145601A CN201510439180.8A CN201510439180A CN105145601A CN 105145601 A CN105145601 A CN 105145601A CN 201510439180 A CN201510439180 A CN 201510439180A CN 105145601 A CN105145601 A CN 105145601A
- Authority
- CN
- China
- Prior art keywords
- pyraclostrobin
- acetoxyl group
- benzoic acid
- benzoic
- acetoxyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005869 Pyraclostrobin Substances 0.000 title claims abstract description 116
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 title claims abstract description 116
- 239000000203 mixture Substances 0.000 title claims abstract description 45
- 239000000575 pesticide Substances 0.000 title claims abstract description 20
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 title abstract description 7
- 201000010099 disease Diseases 0.000 claims abstract description 7
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 7
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 198
- 229960003328 benzoyl peroxide Drugs 0.000 claims description 110
- 239000005711 Benzoic acid Substances 0.000 claims description 95
- 235000010233 benzoic acid Nutrition 0.000 claims description 95
- 239000000843 powder Substances 0.000 claims description 17
- 239000000375 suspending agent Substances 0.000 claims description 16
- 239000004562 water dispersible granule Substances 0.000 claims description 16
- 238000009736 wetting Methods 0.000 claims description 16
- 241000233622 Phytophthora infestans Species 0.000 claims description 12
- 240000007594 Oryza sativa Species 0.000 claims description 10
- 235000007164 Oryza sativa Nutrition 0.000 claims description 10
- 244000061456 Solanum tuberosum Species 0.000 claims description 10
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 10
- 235000009566 rice Nutrition 0.000 claims description 10
- 208000001840 Dandruff Diseases 0.000 claims description 8
- 241000221785 Erysiphales Species 0.000 claims description 8
- 241000209140 Triticum Species 0.000 claims description 8
- 235000021307 Triticum Nutrition 0.000 claims description 8
- 240000008042 Zea mays Species 0.000 claims description 8
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 8
- 241000193738 Bacillus anthracis Species 0.000 claims description 6
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 235000005822 corn Nutrition 0.000 claims description 6
- 241000122123 Penicillium italicum Species 0.000 claims description 5
- 241000233679 Peronosporaceae Species 0.000 claims description 5
- 239000004480 active ingredient Substances 0.000 claims description 5
- 240000008067 Cucumis sativus Species 0.000 claims description 4
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 claims description 4
- 235000016623 Fragaria vesca Nutrition 0.000 claims description 4
- 240000009088 Fragaria x ananassa Species 0.000 claims description 4
- 235000011363 Fragaria x ananassa Nutrition 0.000 claims description 4
- 235000004936 Bromus mango Nutrition 0.000 claims description 2
- 244000241235 Citrullus lanatus Species 0.000 claims description 2
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 claims description 2
- 240000007228 Mangifera indica Species 0.000 claims description 2
- 235000014826 Mangifera indica Nutrition 0.000 claims description 2
- 235000009184 Spondias indica Nutrition 0.000 claims description 2
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims description 2
- 235000009973 maize Nutrition 0.000 claims description 2
- 244000052769 pathogen Species 0.000 abstract description 10
- 230000001717 pathogenic effect Effects 0.000 abstract description 9
- 238000004321 preservation Methods 0.000 abstract description 2
- 230000002265 prevention Effects 0.000 abstract description 2
- 241000233866 Fungi Species 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 230000009044 synergistic interaction Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 27
- 230000002195 synergetic effect Effects 0.000 description 25
- 230000003449 preventive effect Effects 0.000 description 24
- 239000003814 drug Substances 0.000 description 22
- 230000001988 toxicity Effects 0.000 description 22
- 231100000419 toxicity Toxicity 0.000 description 22
- 238000005507 spraying Methods 0.000 description 16
- 230000008569 process Effects 0.000 description 14
- 239000002131 composite material Substances 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 241000213004 Alternaria solani Species 0.000 description 8
- 241000159512 Geotrichum Species 0.000 description 8
- 241000813090 Rhizoctonia solani Species 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 235000020971 citrus fruits Nutrition 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 240000006497 Dianthus caryophyllus Species 0.000 description 6
- 235000009355 Dianthus caryophyllus Nutrition 0.000 description 6
- QNHCWLYFWBZVOM-UHFFFAOYSA-N benzoic acid;hydrate Chemical compound O.OC(=O)C1=CC=CC=C1 QNHCWLYFWBZVOM-UHFFFAOYSA-N 0.000 description 6
- 235000013339 cereals Nutrition 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- -1 31 grams Substances 0.000 description 4
- 241000223600 Alternaria Species 0.000 description 4
- 241000222199 Colletotrichum Species 0.000 description 4
- 241001529387 Colletotrichum gloeosporioides Species 0.000 description 4
- 244000168141 Geotrichum candidum Species 0.000 description 4
- 235000017388 Geotrichum candidum Nutrition 0.000 description 4
- 240000005074 Hymenocallis caribaea Species 0.000 description 4
- 241001344131 Magnaporthe grisea Species 0.000 description 4
- 206010064458 Penicilliosis Diseases 0.000 description 4
- 241000228150 Penicillium chrysogenum Species 0.000 description 4
- 241000233614 Phytophthora Species 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 241000489964 Fusicladium Species 0.000 description 3
- 229920001732 Lignosulfonate Polymers 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 241001465180 Botrytis Species 0.000 description 2
- 241000221787 Erysiphe Species 0.000 description 2
- 241000223218 Fusarium Species 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 241000234435 Lilium Species 0.000 description 2
- 241000228143 Penicillium Species 0.000 description 2
- 241000233626 Plasmopara Species 0.000 description 2
- 241001281802 Pseudoperonospora Species 0.000 description 2
- 241000231139 Pyricularia Species 0.000 description 2
- 241001361634 Rhizoctonia Species 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 239000004009 herbicide Substances 0.000 description 2
- 230000009916 joint effect Effects 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- 230000000361 pesticidal effect Effects 0.000 description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 description 2
- 235000012015 potatoes Nutrition 0.000 description 2
- 229960004889 salicylic acid Drugs 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 230000004083 survival effect Effects 0.000 description 2
- 230000005068 transpiration Effects 0.000 description 2
- 102100038837 2-Hydroxyacid oxidase 1 Human genes 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000233652 Chytridiomycota Species 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 241001480059 Erysiphaceae Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
- 239000005800 Kresoxim-methyl Substances 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 244000181025 Rosa gallica Species 0.000 description 1
- 235000000533 Rosa gallica Nutrition 0.000 description 1
- 241000221696 Sclerotinia sclerotiorum Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 229960001138 acetylsalicylic acid Drugs 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 150000003851 azoles Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BEHLMOQXOSLGHN-UHFFFAOYSA-N benzenamine sulfate Chemical compound OS(=O)(=O)NC1=CC=CC=C1 BEHLMOQXOSLGHN-UHFFFAOYSA-N 0.000 description 1
- 230000000443 biocontrol Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- UDHMTPILEWBIQI-UHFFFAOYSA-N butyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OCCCC)=CC=CC2=C1 UDHMTPILEWBIQI-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002190 fatty acyls Chemical group 0.000 description 1
- 244000000004 fungal plant pathogen Species 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 108010062584 glycollate oxidase Proteins 0.000 description 1
- 230000007407 health benefit Effects 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 1
- 229940073769 methyl oleate Drugs 0.000 description 1
- 230000002438 mitochondrial effect Effects 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 230000000243 photosynthetic effect Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 230000009758 senescence Effects 0.000 description 1
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a pesticide composition containing pyraclostrobin and 2-(acetoxyl) benzoic acid. The pesticide composition comprises a common auxiliary, pyraclostrobin and 2-(acetoxyl) benzoic acid, wherein the mass ratio in parts of pyraclostrobin and 2-(acetoxyl) benzoic acid is 20: 1 to 1: 20; the pyraclostrobin and 2-(acetoxyl) benzoic acid compounded have obvious synergistic interaction on yield increase of pathogens and crops, so that the pesticide composition is suitable for prevention and treatment of crop diseases caused by pathogen fungi and yield production of crops and preservation of cut flowers.
Description
Technical field
The composition pesticide that the present invention relates to, be with pyraclostrobin and 2-(acetoxyl group) benzoic acid for active ingredient, be applicable to prevent and treat by the volume increase of the fungus-caused crop pest of pathogen and wheat, corn, paddy rice, potatoes and other crops; The fresh keeping time of significant prolongation cut-flower, has preservation.
Background technology
Pyraclostrobin; english common name pyraclostrobin; for methoxy acrylic wide-spectrum bactericide; suppress mitochondrial breathing; there is protection, treatment and blade osmosis, all there is bactericidal activity to Ascomycotina, Deuteromycotina, Mastigomycotina, Zygomycotina, Basidiomycotina most plants pathogen.Pyraclostrobin is mainly used in the fungus-caused plant disease of control pathogen, as diseases such as crop powdery mildew, rust, downy mildew, late blight, gray mold, anthracnose, stalk breaks, to plant, there is health benefit simultaneously, delay the output of endogenous ethylene, opposing plant senescence.
2-(acetoxyl group) benzoic acid, english common name aspirin, can resolve into salicylic acid and acetic acid in water, salicylic acid has anti-inflammation and corrosion-resistant effect, acetic acid can suppress the biologically active of glycolate oxidase, improves the photosynthesis of flowers and trees, increases photosynthetic product.Be used in flowers and trees cultivation and not only can improve survival rate, also impel robust growth, improve resistance, improve stub survival rate, extend the flower arrangement life-span etc.2-(acetoxyl group) benzoic acid can reduce moisture transpiration in plant body, improve the ability that flowers and trees resist drought environment, can promote the closed of Stoma of Leaves, the transpiration reducing leaf water is scattered and disappeared, reduce burn, improve flowers and trees drought resisting, cold tolerance.
Found by test, pyraclostrobin and 2-(acetoxyl group) benzoic acid colletotrichum used in combination (Colletotrichum), Penicillium (Peniciliumitalicum), green mold belongs to (Peniciliumdigitatum), Geotrichum (Geotrichum), Alternaria (Alternaria), Pyricularia Sacc. (Phyricularia), Phytophthora (Phytophthora), Pseudoperonospora (Pseudoperonospora), Plasmopara (Plasmopara), Rhizoctonia (Rhizoctonia), Botrytis ((Botrytis), Fusarium (Fusarium), Fusicladium (Fusicladium), the fungal plant pathogens such as ring Fusicladium (Sphlocaea) and Erysiphaceae (Erysiphales) pathogen tool have synergistic function, especially in 20:1 ~ 1:20 proportion to colletotrichum (Colletotrichum), Penicillium (Peniciliumitalicum), Geotrichum (Geotrichum), Pyricularia Sacc. (Phyricularia), Phytophthora (Phytophthora), Alternaria (Alternaria), Erysiphe (Erysiphe) pathogen has obvious synergistic function.
Summary of the invention
It is pyraclostrobin and 2-(acetoxyl group) benzoic composition pesticide that the present invention aims to provide a kind of active ingredient, for the prevention and control of crop fungal disease, crop yield and the fresh-keeping of cut-flower provide a kind of effectively management tool.
The present invention is achieved through the following technical solutions: a kind of containing pyraclostrobin and 2-(acetoxyl group) benzoic composition pesticide, its active ingredient is pyraclostrobin and 2-(acetoxyl group) benzoic acid; Pyraclostrobin and 2-(acetoxyl group) benzoic ratio of quality and the number of copies are 20:1 ~ 1:20.
Further, described composition pesticide according to well known to a person skilled in the art method, can be mixed with the application forms of the applicable agricultural uses such as suspending agent, oil-suspending agent, water dispersible granules, wetting powder.
Described composition pesticide is also containing the usual auxiliaries of preparation needed for pesticidal preparations, usual auxiliaries is the mixing of one or more in solvent, emulsifier, wetting agent, stabilizing agent, dispersant, thickener, pH adjusting agent, defoamer, antifreezing agent, packing agent etc., be known substance, various auxiliary agents conventional in pesticidal preparations, can change to some extent according to different situations, be not particularly limited.
Composition pesticide provided by the invention, can be used for paddy rice, wheat, corn, the volume increase of potatoes and other crops and the fresh-keeping of cut-flower.
Composition pesticide provided by the invention, the method use usually adopting spraying or soak, also can adopt other operation techniques agriculturally applied as required.
Composition pesticide provided by the invention has following beneficial effect:
1, composition pesticide provided by the invention, shows obvious synergistic effect in certain ratio range, reduces the using dosage of agricultural chemicals, decreases the impact of agricultural chemicals on environment, reduces drug cost.
2, the active ingredient mechanism of action of composition pesticide provided by the invention is different, and the application of composition can delay or overcome the generation of disease drug resistance, extends the service life of medicament, is conducive to the comprehensive regulation of disease.
Embodiment
In order to understand essence of the present invention better, be described further by following examples, but the present invention is not limited to these embodiments.Following content is weight percentage or mass ratio.
According to the abundant method of Sun Yun, the synergy of pharmacy mix is evaluated according to co-toxicity coefficient (CTC), namely CTC≤80 are joint action of antagonism, and 80 < CTC < 120 are joint action of antagonism, and CTC >=120 are synergistic function.Actual measurement toxicity index (ATI)=(EC of standard agent
50the EC of/reagent agent
50) × 100; In the toxicity index × mixture of theoretical toxicity index TTI=A medicament the percentage composition+B medicament of A medicament toxicity index × mixture in the percentage composition of B medicament; Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] × 100.
Embodiment one: pyraclostrobin and 2-(acetoxyl group) benzoic acid are to the Toxicity Determination of dlumeria graminis cereal specialized form (Blumeriagraminisf.sp.tritici).
Subjects picks up from wheat powdery mildew pathogen dlumeria graminis cereal specialized form (Blumeriagraminisf.sp.tritici) in field, pot experiment method.
Table 1, pyraclostrobin and 2-(acetoxyl group) benzoic acid are to the Toxicity Determination result of dlumeria graminis cereal specialized form (Blumeriagraminisf.sp.tritici).
As shown in Table 1, pyraclostrobin and 2-(acetoxyl group) benzoic acid mixture mass ratio are between 20:1 ~ 1:20, have obvious synergistic effect to dlumeria graminis cereal specialized form (Blumeriagraminisf.sp.tritici), co-toxicity coefficient is all more than 140.
Embodiment two: pyraclostrobin and 2-(acetoxyl group) benzoic acid are to the Toxicity Determination of Penicillium notatum (Penicilliumitalicum).
Subjects is for picking up from citrusfruit penicilliosis pathogen Penicillium notatum (Penicilliumitalicum), mycelial growth method.
Table 2, pyraclostrobin and 2-(acetoxyl group) benzoic acid are to the Toxicity Determination result of Penicillium notatum (Penicilliumitalicum).
As shown in Table 2, pyraclostrobin and 2-(acetoxyl group) benzoic acid mixture mass ratio are between 20:1 ~ 1:20, and have obvious synergistic effect to Penicillium notatum (Penicilliumitalicum), co-toxicity coefficient is all more than 140.
Embodiment three: pyraclostrobin and 2-(acetoxyl group) benzoic acid are to the Toxicity Determination of phytophthora infestans (Phytophthorainfestans)
Subjects is pick up from the potato late blight pathogen phytophthora infestans (Phytophthorainfestans) in field, mycelial growth method.
Table 3, pyraclostrobin and 2-(acetoxyl group) benzoic acid are to the Toxicity Determination result of phytophthora infestans (Phytophthorainfestans).
As shown in Table 3, pyraclostrobin and 2-(acetoxyl group) benzoic acid mixture mass ratio are between 20:1 ~ 1:20, and have obvious synergistic effect to phytophthora infestans (Phytophthorainfestans), co-toxicity coefficient is all more than 160.
Embodiment four: the Toxicity Determination of pyraclostrobin and 2-(acetoxyl group) benzoic acid Rhizoctonia solani (Rhizoctoniasolani).
Subjects is the rice sheath blight disease pathogen Rhizoctonia solani Kuhn (Rhizoctoniasolani) of picking up from field, mycelial growth method.
The Toxicity Determination result of table 4, pyraclostrobin and 2-(acetoxyl group) benzoic acid Rhizoctonia solani (Rhizoctoniasolani).
As shown in Table 4, pyraclostrobin and 2-(acetoxyl group) benzoic acid mixture mass ratio are between 20:1 ~ 1:20, and Rhizoctonia solani (Rhizoctoniasolani) has obvious synergistic effect, and co-toxicity coefficient is all more than 140.
Embodiment five: pyraclostrobin 2-(acetoxyl group) benzoic acid is to the Toxicity Determination of Magnaporthe grisea (Phyriculariagrisea).
Subjects is pick up from the rice blast pathogen Magnaporthe grisea (Phyriculariagrisea) in field, mycelial growth method.
Table 5, pyraclostrobin and 2-(acetoxyl group) benzoic acid are to the Toxicity Determination result of Magnaporthe grisea (Phyriculariagrisea).
As shown in Table 5, pyraclostrobin and 2-(acetoxyl group) benzoic acid mixture mass ratio are between 20:1 ~ 1:20, and have obvious synergistic effect to Magnaporthe grisea (Phyriculariagrisea), co-toxicity coefficient is all more than 160.
Embodiment six: pyraclostrobin 2-(acetoxyl group) benzoic acid is to the Toxicity Determination of glue spore anthrax (Colletotrichumgloeosporioides).
Subjects is pick up from watermelon anthrax pathogen glue spore anthrax (Colletotrichumgloeosporioides) in field, mycelial growth method.
Table 6, pyraclostrobin and 2-(acetoxyl group) benzoic acid are to the Toxicity Determination result of glue spore anthrax (Colletotrichumgloeosporioides).
As shown in Table 6, pyraclostrobin and 2-(acetoxyl group) benzoic acid mixture mass ratio are between 20:1 ~ 1:20, have obvious synergistic effect to glue spore anthrax (Colletotrichumgloeosporioides), co-toxicity coefficient is all more than 160.
Embodiment seven: pyraclostrobin and 2-(acetoxyl group) benzoic acid are to the Toxicity Determination of alternaria solani sorauer (Alternariasolani).
Subjects is pick up from the target pathogen alternaria solani sorauer (Alternariasolani) in field, mycelial growth method.
Table 7, pyraclostrobin and 2-(acetoxyl group) benzoic acid are to the Toxicity Determination result of alternaria solani sorauer (Alternariasolani).
As shown in Table 7, pyraclostrobin and 2-(acetoxyl group) benzoic acid mixture mass ratio are between 20:1 ~ 1:20, and have obvious synergistic effect to alternaria solani sorauer (Alternariasolani), co-toxicity coefficient is all more than 150.
Embodiment eight: pyraclostrobin and 2-(acetoxyl group) benzoic acid are to the Toxicity Determination of geotrichum sp (Geotrichumcandidum).
Subjects is for picking up from citrusfruit sour rot pathogen geotrichum sp (Geotrichumcandidum), mycelial growth method.
Table 8, pyraclostrobin and 2-(acetoxyl group) benzoic acid are to the Toxicity Determination result of geotrichum sp (Geotrichumcandidum).
As shown in Table 8, pyraclostrobin and 2-(acetoxyl group) benzoic acid mixture mass ratio are between 20:1 ~ 1:20, and have obvious synergistic effect to geotrichum sp (Geotrichumcandidum), co-toxicity coefficient is all more than 160.
Below in conjunction with example of formulations to further instruction of the present invention.
Embodiment nine: (pyraclostrobin 2-(acetoxyl group) benzoic acid suspending agent).
Pulverized in advance in proportion by above-mentioned formula, then add in sand mill and grind, after high shear mixing, allotment obtains pyraclostrobin 2-(acetoxyl group) the benzoic acid suspending agent of corresponding percentage by weight.
Embodiment ten: 40% pyraclostrobin 2-(acetoxyl group) benzoic acid suspending agent.
Pyraclostrobin 308 grams, 104 grams, 2-(acetoxyl group) benzoic acid, 35 grams, lignosulfonates sodium, 31 grams, fatty acid ester sodium sulphate, to methoxyl group fatty acyl anilinesulfonic acid 5.1 grams, fatty alcohol-polyoxyethylene ether 5.1 grams, glycerine 5.2 grams, xanthans 1.1 grams, deionized water complements to 1000 grams, above-mentioned formula is pulverized in proportion in advance, add in sand mill again and grind, pyraclostrobin 2-(acetoxyl group) benzoic acid suspending agent processed is allocated after high shear mixing, after testing, pyraclostrobin content 30.2%, 2-(acetoxyl group) benzoic acid content 10.1%, total effective content 40.3%.
Embodiment 11: biocontrol of mango anthracnose.
The spraying of 100mg/kg thin up pressed by 40.3% pyraclostrobin 2-(acetoxyl group) benzoic acid suspending agent, after medicine, the preventive effect of 15 days, 30 days is 94.3%, 89.9%, 50% pyraclostrobin water dispersible granule presses 100mg/kg, 10%2-(acetoxyl group) benzoic acid wetting powder by the spraying of 100mg/kg thin up, and after medicine, 15 days, 30 days preventive effects are respectively 79.2%, 73.2% and 75.3%, 70.5%.Pyraclostrobin and the composite rear synergistic effect of 2-(acetoxyl group) benzoic acid obvious, single dose is better than to the preventive effect successful of Mango Fruit anthracnose, reduce use cost, for plantation family provides the more efficiently management tool of a kind of Mango Fruit anthracnose.
Embodiment 12: control citrusfruit penicilliosis.
The spraying of 100mg/kg thin up pressed by 40.3% pyraclostrobin 2-(acetoxyl group) benzoic acid suspending agent, after medicine, the preventive effect of 7 days, 14 days is 95.2%, 88.8%, 50% pyraclostrobin water dispersible granule presses 100mg/kg, 10%2-(acetoxyl group) benzoic acid wetting powder by the spraying of mg/kg thin up, and after medicine, 15 days, 30 days preventive effects are respectively 81.2%, 70.5% and 80.6%, 70.8%.Pyraclostrobin and the composite rear synergistic effect of 2-(acetoxyl group) benzoic acid obvious, single dose is better than to the preventive effect successful of citrusfruit penicilliosis, reduce use cost, for plantation family provides the more efficiently management tool of a kind of citrusfruit penicilliosis.
Embodiment 13: (pyraclostrobin 2-(acetoxyl group) benzoic acid oil-suspending agent).
Above-mentioned material (except organobentonite) is joined in reactor mixer together, stir 2 hours, open pan feeding valve at the bottom of still, material is injected stage sand grinding machine to grind, fineness of materials 98% after grinding is by discharging after 1-5um, material puts into high-shear emulsifying still again together with the organobentonite dissolved in advance, namely can be made into pyraclostrobin 2-(acetoxyl group) the benzoic acid oil-suspending agent of the good corresponding percentage by weight of flowing to property after emulsification.
Embodiment 14: 30% pyraclostrobin 2-(acetoxyl group) benzoic acid dispersibles oil-suspending agent.
Pyraclostrobin 153 grams, 151 grams, 2-(acetoxyl group) benzoic acid, 48 grams, lignosulfonates sodium, fatty alcohol-polyoxyethylene ether 52 grams, methyl oleate 249 grams, organobentonite 83 grams, dodecyl sodium sulfonate calcium salt 60 grams, turpentine oil complements to 1000 grams, above-mentioned formula is pulverized in proportion in advance, add in sand mill again and grind, after high shear mixing, obtained pyraclostrobin 2-(acetoxyl group) benzoic acid of allotment dispersibles oil-suspending agent, after testing, pyraclostrobin effective content 15.1%, 2-(acetoxyl group) benzoic acid effective content 15.0%, total effective content 30.1%.
Embodiment 15: prevent and treat citric acid maize ear rot.
30.1% pyraclostrobin 2-(acetoxyl group) benzoic acid oil-suspending agent presses the spraying of 100mg/kg thin up, after medicine, the preventive effect of 15 days, 30 days is 96.9%, 89.4%, 50% pyraclostrobin water dispersible granule presses 100mg/kg, 10%2-(acetoxyl group) benzene first wetting powder by the spraying of 100mg/kg thin up, and after medicine, 15 days, 30 days preventive effects are respectively 78.2%, 71.9% and 80.2%, 65.4%.Pyraclostrobin and the composite rear synergistic effect of 2-(acetoxyl group) benzoic acid obvious, single dose is better than to the preventive effect successful of citrusfruit sour rot, reduce use cost, for plantation family provides the more efficiently management tool of a kind of citrusfruit sour rot.
Embodiment 16: for preventing and treating cucumber downy mildew.
30.1% pyraclostrobin 2-(acetoxyl group) benzoic acid dispersibles oil-suspending agent and sprays by 50ga.i./ha thin up, after medicine, the preventive effect of 7 days, 14 days is 90.1%, 83.3%, 50% pyraclostrobin water dispersible granule presses 50ga.i./ha, 10%2-(acetoxyl group) benzoic acid wetting powder by the spraying of 50ga.i./ha thin up, and after medicine, 7 days, 14 days preventive effects are respectively 71.6%, 63.2% and 80.2%, 69.4%.Pyraclostrobin and the composite rear synergistic effect of 2-(acetoxyl group) benzoic acid obviously, are better than single dose to the preventive effect successful of cucumber downy mildew, reduce use cost, for plantation family provides the more efficiently management tool of a kind of cucumber downy mildew.
Embodiment 17: (pyraclostrobin 2-(acetoxyl group) benzoic acid water dispersible granules).
Above-mentioned material is added in cone-type mixer together and mixes; pulverize by airslide disintegrating mill; material after pulverizing mixes through cone-type mixer again; mixed fineness of materials 98% is by 600 mesh standard sieves; add in kneader and be kneaded into plasticity material; finally this material is put into Squeezinggranulator extruder grain, after drying, screening, after granulation, namely obtain pyraclostrobin 2-(acetoxyl group) the benzoic acid water dispersible granules of corresponding percentage by weight.
Embodiment 18: 60% pyraclostrobin 2-(acetoxyl group) benzoic acid water dispersible granules.
Pyraclostrobin 455 grams, 156 grams, 2-(acetoxyl group) benzoic acid, sodium lignin sulfonate 48 grams, shitosan 61 grams, glucose 55 grams, spaonin powder 39 grams, kaolin complements to 1000.By above-mentioned formula, pyraclostrobin 2-(acetoxyl group) benzoic acid water dispersible granules is made and is obtained in dry pulverization process, granulation, drying, screening in proportion, after testing, pyraclostrobin effective content 45.1%, 2-(acetoxyl group) benzoic acid effective content 15.1%, total effective content 60.2%.
Embodiment 19: control powdery mildew of strawberry.
60.2% pyraclostrobin 2-(acetoxyl group) benzoic acid water dispersible granules presses the spraying of 50ga.i./ha thin up, after medicine, the preventive effect of 7 days, 14 days is 84.7%, 80.6%, 50% pyraclostrobin water dispersible granule presses 50ga.i./ha, 10%2-(acetoxyl group) benzoic acid wetting powder by the spraying of 50ga.i./ha thin up, and after medicine, 7 days, 14 days preventive effects are respectively 66.6%, 55.1% and 72.3%, 66.7%.Pyraclostrobin and the composite rear synergistic effect of 2-(acetoxyl group) benzoic acid obviously, are better than single dose to the preventive effect successful of powdery mildew of strawberry, reduce use cost, for plantation family provides the more efficiently management tool of a kind of powdery mildew of strawberry.
Embodiment 20: prevent and treat potato black scurf.
60.2% pyraclostrobin 2-(acetoxyl group) benzoic acid water dispersible granules presses the spraying of 50ga.i./ha thin up, after medicine, the preventive effect of 7 days, 14 days is 87.6%, 81.4%, 50% pyraclostrobin water dispersible granule presses 50ga.i./ha, 10%2-(acetoxyl group) benzoic acid wetting powder by the spraying of 50ga.i./ha thin up, and after medicine, 7 days, 14 days preventive effects are respectively 62.3%, 51.1% and 80.5%, 67.6%.Pyraclostrobin and the composite rear synergistic effect of 2-(acetoxyl group) benzoic acid obvious, single dose is better than to the preventive effect successful of potato black scurf, reduce use cost, for plantation family provides the more efficiently management tool of a kind of potato black scurf.
Embodiment 21: (pyraclostrobin 2-(acetoxyl group) benzoic acid wetting powder).
Above-mentioned material is added in cone-type mixer together and mixes, pulverize by airslide disintegrating mill, material after pulverizing mixes through cone-type mixer again, mixed fineness of materials 98%, by 600 mesh standard sieves, obtains pyraclostrobin 2-(acetoxyl group) the benzoic acid wetting powder of corresponding percentage by weight.
Embodiment 22: 50% pyraclostrobin 2-(acetoxyl group) benzoic acid wetting powder.
Pyraclostrobin 404 grams, 107 grams, 2-(acetoxyl group) benzoic acid, lignosulfonates calcium 53 grams, lauryl sodium sulfate 47 grams, sodium butylnaphthalenesulfonate 53 grams, white carbon 57 grams, kaolin complements to 1000 grams.Mix entering in blender after above-mentioned formula in proportion coarse crushing, namely pyraclostrobin 2-(acetoxyl group) benzoic acid wetting powder is obtained again after air-flow crushing, after testing, pyraclostrobin effective content 40.1%, 2-(acetoxyl group) benzoic acid effective content 10.1%, total effective content 50.2%.
Embodiment 23: prevent and treat target.
The spraying of 50ga.i./ha thin up pressed by 50.2% pyraclostrobin 2-(acetoxyl group) benzoic acid wetting powder, after medicine, the preventive effect of 7 days, 14 days is 86.8%, 80.1%, 50% pyraclostrobin water dispersible granule presses 50ga.i./ha, 10%2-(acetoxyl group) benzoic acid wetting powder by the spraying of 50ga.i./ha thin up, and after medicine, 7 days, 14 days preventive effects are respectively 54.8%, 48.3% and 73.3%, 6.4%6.Pyraclostrobin and the composite rear synergistic effect of 2-(acetoxyl group) benzoic acid obvious, single dose is better than to the preventive effect successful of target, reduce use cost, for plantation family provides the more efficiently management tool of a kind of target.
Embodiment 24: prevent and treat potato late blight.
The spraying of 50ga.i./ha thin up pressed by 50.2% pyraclostrobin 2-(acetoxyl group) benzoic acid wetting powder, after medicine, the preventive effect of 7 days, 14 days is 85.5%, 80.3%, 50% pyraclostrobin water dispersible granule presses 50ga.i./ha, 10%2-(acetoxyl group) benzoic acid wetting powder by the spraying of 50ga.i./ha thin up, and after medicine, 7 days, 14 days preventive effects are respectively 62.2%, 49.5% and 77.2%, 70.1%.Pyraclostrobin and the composite rear synergistic effect of 2-(acetoxyl group) benzoic acid obvious, single dose is better than to the preventive effect successful of potato late blight, reduce use cost, for plantation family provides a kind of more effective management tool of potato late blight.
Embodiment 25: pyraclostrobin and 2-(acetoxyl group) benzoic acid are to the fresh-keeping test of Carnation Flower.
Cut-flower is cut stem place after treatment and is dipped in clear water, is placed in humidity 60%, preserves in the room temperature greenhouse of 12 h light 12 h dark, and the computing time that the time between wilting with fresh cut-flowers process to petal 20% is fresh keeping time, unit is sky.
Table 9, different disposal are to the fresh keeping time of fresh Carnation Flower.
As can be seen from Table 9, pyraclostrobin and the fresh Carnation Flower of 2-(acetoxyl group) benzoic acid process all can prolong storage period, and pyraclostrobin and the fresh Carnation Flower of 2-(acetoxyl group) benzoic acid process used in combination, fresh keeping time all can extend more than 50% relative to single dose, all can more than 100% be extended relative to clear water process, the fresh keeping time of the fresh Carnation Flower of significant prolongation, to combinationally use Carnation Flower fresh-keeping significant for pyraclostrobin and 2-(acetoxyl group) benzoic acid as can be seen here.
Embodiment 26: azoles kresoxim-methyl and 2-(acetoxyl group) benzoic acid are to the fresh-keeping test of cutting flower.
Cut-flower is cut stem place after treatment and is dipped in clear water, is placed in humidity 60%, and preserve in the room temperature greenhouse of 12 h light 12 h dark, the computing time being fresh keeping time to the time that petal 20% is wilted with fresh cut-flowers process, unit is sky.
Table 10, different disposal are to the fresh keeping time of scarlet cutting flower.
As can be seen from Table 10, pyraclostrobin and the scarlet cutting flower of 2-(acetoxyl group) benzoic acid process all can prolong storage period, and pyraclostrobin and the scarlet cutting flower of 2-(acetoxyl group) benzoic acid process used in combination, fresh keeping time all can extend more than 50% relative to single dose, all can more than 100% be extended relative to clear water process, the fresh keeping time of the scarlet cutting flower of significant prolongation, to combinationally use red rose cut-flower fresh-keeping significant for pyraclostrobin and 2-(acetoxyl group) benzoic acid as can be seen here.
Embodiment 27: pyraclostrobin and 2-(acetoxyl group) benzoic acid are to the fresh-keeping test of lily cut flowers.
Cut-flower is cut stem place after treatment and is dipped in clear water, is placed in humidity 60%, and preserve in the room temperature greenhouse of 12 h light 12 h dark, the computing time being fresh keeping time to the time that petal 20% is wilted with fresh cut-flowers process, unit is sky.
Table 11, different disposal are to the fresh keeping time of fresh white lily cut flowers.
As can be seen from Table 11, pyraclostrobin and the fresh white lily cut flowers of 2-(acetoxyl group) benzoic acid process all can prolong storage period, and pyraclostrobin and the fresh white lily cut flowers of 2-(acetoxyl group) benzoic acid process used in combination, fresh keeping time all can extend more than 50% relative to single dose, all can more than 100% be extended relative to clear water process, the fresh keeping time of the fresh white lily cut flowers of significant prolongation, pyraclostrobin and 2-(acetoxyl group) benzoic acid combinationally use the fresh-keeping significant of dialogue lily cut flowers as can be seen here.
Pyraclostrobin and 2-(acetoxyl group) benzoic acid are tested the production-increasing function of crop
After results after the threshing of each process fringe, random selecting 2 500 is weighed, if 2 500 weight differentials are little, then data are added and try to achieve thousand kernel weight (moisture < 13%), repeat 4 times, calculate the thousand kernel weight increasing rate often processed.
Evaluate weed killer herbicide associated form (NY/T1155.7-2006) according to Gowing method, its formula is as follows:
E
0﹦X﹢Y–XY/100
In formula, X be pyraclostrobin alone with certain dosage time thousand kernel weight increasing rate/output increasing rate to target; Y be 2-(acetoxyl group) benzoic acid alone with certain dosage time thousand kernel weight increasing rate/output increasing rate to target; E
0for the theoretical value to target thousand kernel weight increasing rate/output increasing rate when pyraclostrobin, 2-(acetoxyl group) benzoic acid two kinds of pharmacy mix; Measured value to target thousand kernel weight increasing rate/output increasing rate when E is pyraclostrobin, 2-(acetoxyl group) benzoic acid two kinds of pharmacy mix.
Evaluation criterion: as E – E
0during > 10%, be expressed as synergistic effect; As ﹣ 10%≤E – E
0when≤10%, show as summation action; As E – E
0during < ﹣ 10%, show as antagonism.
Embodiment 28: to the production-increasing function of wheat.
Table 12, pyraclostrobin and 2-(acetoxyl group) benzoic acid and mixture thereof combine and increase measurement result to thousand grain weight of wheat.
Can be learnt by table 12, obviously, all more than 15%, and synergy obviously, E-E for pyraclostrobin and the composite production-increasing function to wheat of 2-(acetoxyl group) benzoic acid
0be greater than 10%, show as synergistic function.
Embodiment 29: to the production-increasing function of paddy rice.
Table 13, pyraclostrobin and 2-(acetoxyl group) benzoic acid and mixture thereof combine and increase measurement result to paddy rice thousand kernel weight.
Can be learnt by table 13, obviously, all more than 16%, and synergy obviously, E-E for pyraclostrobin and the composite production-increasing function to paddy rice of 2-(acetoxyl group) benzoic acid
0be greater than 10%, show as synergistic function.
Embodiment 30: to the production-increasing function of corn.
Table 14, pyraclostrobin and 2-(acetoxyl group) benzoic acid and mixture thereof combine and increase measurement result to corn 100-grain weight.
Can be learnt by table 14, obviously, all more than 13%, and synergy obviously, E-E for pyraclostrobin and the composite production-increasing function to corn of 2-(acetoxyl group) benzoic acid
0be greater than 10%, show as synergistic function.
Embodiment 31: to the production-increasing function of potato.
Table 15, pyraclostrobin and 2-(acetoxyl group) benzoic acid and mixture thereof combine and increase measurement result to potato per mu yield.
Can be learnt by table 15, obviously, all more than 20%, and synergy obviously, E-E for pyraclostrobin and the composite production-increasing function to potato of 2-(acetoxyl group) benzoic acid
0be greater than 10%, show as synergistic function.
Claims (4)
1., containing pyraclostrobin and 2-(acetoxyl group) benzoic composition pesticide, it is characterized in that: active ingredient is pyraclostrobin and 2-(acetoxyl group) benzoic acid; Pyraclostrobin and 2-(acetoxyl group) benzoic ratio of quality and the number of copies are 20:1 ~ 1:20.
2. one according to claim 1 contains pyraclostrobin and 2-(acetoxyl group) benzoic composition pesticide, it is characterized in that: the formulation of described composition pesticide is the one in suspending agent, oil-suspending agent, water dispersible granules, wetting powder.
3. one according to claim 1 contains pyraclostrobin and the application of 2-(acetoxyl group) benzoic composition pesticide on control wheat powdery mildew, powdery mildew of strawberry, Penicillium italicum, citric acid maize ear rot, potato late blight, target, potato black scurf, rice sheath blight disease, rice blast, watermelon anthrax, mango anthracnose, cucumber downy mildew.
4. one according to claim 1 contain pyraclostrobin and 2-(acetoxyl group) benzoic composition pesticide the volume increase of paddy rice, wheat, corn, potato crop and cut-flower fresh-keeping on application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510439180.8A CN105145601A (en) | 2015-07-23 | 2015-07-23 | Pesticide composition containing pyraclostrobin and 2-(acetoxyl) benzoic acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510439180.8A CN105145601A (en) | 2015-07-23 | 2015-07-23 | Pesticide composition containing pyraclostrobin and 2-(acetoxyl) benzoic acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105145601A true CN105145601A (en) | 2015-12-16 |
Family
ID=54787005
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510439180.8A Pending CN105145601A (en) | 2015-07-23 | 2015-07-23 | Pesticide composition containing pyraclostrobin and 2-(acetoxyl) benzoic acid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105145601A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1242145A (en) * | 1999-07-14 | 2000-01-26 | 蒋长宁 | Application of aspirin for prepn. of 2(acetoxy) benzoic acid soluble powder used as plant growth regulator for agriculture use |
| CN1252219A (en) * | 1999-11-22 | 2000-05-10 | 张天良 | Composite germicide recompounded with basic copper sulphate and aspirin |
| CN103037696A (en) * | 2010-05-31 | 2013-04-10 | 巴斯夫欧洲公司 | Method for increasing the health of a plant |
| CN103828793A (en) * | 2014-03-26 | 2014-06-04 | 李虹锋 | Rosa chinensis cut flower preservation method |
-
2015
- 2015-07-23 CN CN201510439180.8A patent/CN105145601A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1242145A (en) * | 1999-07-14 | 2000-01-26 | 蒋长宁 | Application of aspirin for prepn. of 2(acetoxy) benzoic acid soluble powder used as plant growth regulator for agriculture use |
| CN1252219A (en) * | 1999-11-22 | 2000-05-10 | 张天良 | Composite germicide recompounded with basic copper sulphate and aspirin |
| CN103037696A (en) * | 2010-05-31 | 2013-04-10 | 巴斯夫欧洲公司 | Method for increasing the health of a plant |
| CN103828793A (en) * | 2014-03-26 | 2014-06-04 | 李虹锋 | Rosa chinensis cut flower preservation method |
Non-Patent Citations (2)
| Title |
|---|
| 吴建民: "花木栽培巧用阿司匹林", 《农家之友》 * |
| 汤菊香等: "采前氯化钙和阿司匹林处理对芍药切花保鲜的影响", 《湖北农业科学》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102172240A (en) | Bactericidal composition containing benziothiazolinone and methoxyl acrylic ester type bactericides | |
| CN101690483B (en) | Bactericidal composition containing triazole class compounds | |
| CN106359395A (en) | Bactericidal composition containing benzovindiflupyr | |
| CN101816308A (en) | Bactericidal composition | |
| CN102669181B (en) | Sterilization composition containing captan and copper calcium sulfate and application of sterilization composition | |
| CN102461514A (en) | Sterilization composition containing chlorothalonil and tebuconazole and application thereof | |
| CN101715775B (en) | Sterilizing composition containing ethirimol | |
| CN101755784A (en) | Oomycete killing composition | |
| CN101433199A (en) | Bactericidal composition | |
| CN102150675B (en) | Bactericidal composition containing captan and thiocatbamate compound | |
| CN101642130B (en) | Bactericidal composition containing iprovalicarb | |
| CN105265446A (en) | Pesticide combination containing fenaminstrobin and tetraconazole | |
| CN104970031A (en) | Pesticide composition containing pyraclostrobin and chitosan | |
| CN103385244A (en) | Bactericidal composition comprising fluxapyroxad and thiocarbamate | |
| CN102986710A (en) | Bactericidal composition containing bellkute and difenoconazole and application of composition | |
| CN108419798A (en) | A kind of bactericidal composition and its application containing alkene oxime amine | |
| CN103039493B (en) | Bactericidal composition containing active ingredients bellkute and triflumizole and application of bactericidal composition | |
| CN105145601A (en) | Pesticide composition containing pyraclostrobin and 2-(acetoxyl) benzoic acid | |
| CN104872158B (en) | Composition pesticide and its application containing Zhongshengmycin and fluorine bacterium azoles | |
| CN106259347A (en) | A kind of bactericidal composition containing Fenamidone | |
| CN103392739A (en) | Sterilizing composition containing mandipropamid and copper calcium sulphate | |
| CN103651450B (en) | Bactericidal composition containing dimoxystrobin and thiocarbamate | |
| CN103348990A (en) | Bactericidal composition containing mandipropamid and captan | |
| CN103583560B (en) | A kind of bactericidal composition containing simeconazoles and thiocarbamates | |
| CN104904734B (en) | Composition pesticide containing Zhongshengmycin and cymoxanil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151216 |