CN106359395A - Bactericidal composition containing benzovindiflupyr - Google Patents
Bactericidal composition containing benzovindiflupyr Download PDFInfo
- Publication number
- CN106359395A CN106359395A CN201610761376.3A CN201610761376A CN106359395A CN 106359395 A CN106359395 A CN 106359395A CN 201610761376 A CN201610761376 A CN 201610761376A CN 106359395 A CN106359395 A CN 106359395A
- Authority
- CN
- China
- Prior art keywords
- mefentrifluconazole
- fluorine bacterium
- bacterium azoles
- alkene fluorine
- composition pesticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a bactericidal composition containing mefentrifluconazole and benzovindiflupyr, and the weight ratio of the two active ingredients is 20: 1 to 1: 20. The weight percentage of the active ingredients in the fungicide is 2 to 80%, preferably 5 to 70%, and the remainder is allowed adjuvants and carriers in the pesticide. The bactericidal composition of the present invention has a significant synergistic effect, which can reduce the usage amount of pesticide and is environment friendly and safe.
Description
Technical field
The invention belongs to technical field of pesticide and in particular to be a kind of fluorine bacterium azoles of alkene containing benzo and mefentriflucon
The composition pesticide of azole.
Background technology
Mefentrifluconazole is BASF AG's triazole bactericidal agent newly developed, and its mechanism of action is suppression
The biosynthesiss of pathogenic bacteria ergosterol make somatic cells film function be destroyed, thus suppression or interference thalline appresorium and haustorium
Growth, mycelia and spore formation.A series of disease being mainly used in more difficult preventing and treatings has significant biological activity, is to have
The new product of epoch-making significance.Prevention effect is excellent.The chemistry knot of Novel triazole antibacterial mefentrifluconazole
Structure formula is:
Benzo alkene fluorine bacterium azoles, English name: benzovindiflupyr, trade name solatenol, molecular formula is: n- [9- (dichloro
Methyl) -1,2,3,4- tetrahydrochysene -1,4- methanonaphthalene -5- base] -3-3(difluoromethyl) -1- methyl isophthalic acid h- pyrazole-4-carboxamide.
Structural formula is as follows:
Benzo alkene fluorine bacterium azoles are wide spectrum leaf antibacterial, are succinate dehydrogenase inhibitors, act on pathogen mitochondrial respiratory
Protein complexes on electron transport chain, i.e. succinate dehydrogenase (sunccinate dehydrogenase, sdh) or succinum
Sour ubiquinone reductase (succinate ubiquinone reductase, sqr), the respiratory chain electron transmission system of impact pathogen
System, hindering the metabolism of its energy, the growth of suppression pathogen, leading to it dead, thus reaching the purpose of controlling disease.This sterilization
Agent is mainly used in bread crop, has outstanding preventive effect to the Major Diseases of the various crop such as Semen Tritici aestivi, Semen Maydiss and special crop, can be fine
Ground preventing and treating wheat leaf blight, the cercospora black spot of peanut, take-all and Semen Tritici aestivi basal stem rot, especially to Spike-stalk Brown Spot of Grape, Semen Maydiss
Helminthosporium maydis and gray mold have specially good effect, excellent to Asian Soybean Rust preventive effect.It is sterilized with methoxy acrylic and triazole type
Agent no interactions resistance, can be with various sterilization agent compounding use.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area expands year by year, and disease occurrence degree, generation quantity all increase, and in preventing and treating, difficulty increases；Separately
On the one hand, the resistance of pathogen rises under lasting medicament selection pressure year by year, and the prevention effect of single dose is had a greatly reduced quality, plant
Disease control is faced with significant challenge.
Content of the invention
Present invention aims to the deficiencies in the prior art, provide a kind of applied widely, low cost, effect are good,
The mefentrifluconazole that plant disease resistance problem can be solved is combined with the bactericide of benzo alkene fluorine bacterium azoles.
For solving above-mentioned technical problem, the present invention adopts the following technical scheme that
A kind of bactericidal composition containing mefentrifluconazole and benzo alkene fluorine bacterium azoles, described benzo alkene fluorine bacterium azoles
With mefentrifluconazole weight than for 1-50:50-1, more preferably 1-20:20-1.
Further, the percentage by weight that in described bactericidal composition, active component accounts for compositionss is 2-80%, preferably
10-50%.
Further, described bactericidal composition and known auxiliary agent and excipient are re-dubbed the dosage form allow on pesticide.Example
As being cream, wettable powder, suspending agent, aqueous emulsion, microemulsion, water dispersible granules, dispersible oil-suspending agent, dispersible
Oil preparation, dispersible agent, solvable powder, soluble granule, microcapsule suspending agent, suspension emulsion, liquor, oil preparation, microcapsule suspension emulsion, oil are outstanding
In floating agent any one.
Another object of the present invention is to providing described bactericidal composition as control rust, powdery mildew, banded sclerotial blight, leaf
Pinta, melasma, sclerotiniose, net blotch, brown spot, moire disease, gray mold, balck shank, Spike-stalk Brown Spot of Grape, Fructus Mali pumilae speckle
Defoliation, plum red leaf spot, black scurf of potato, southern blight, white star, downy mildew, leaf blight, rust, ring spot, Citrus fat
Point maculopathy, leaf mold, scab, smut, head smut, shot hole, wheat scab and take-all medicine
Application.
Compared with prior art, the invention has the benefit that 1) compared with single dose, bactericidal composition of the present invention is to above-mentioned
Described disease has notable synergistic to act on, and overcomes and delayed Drug resistance, and expanding prevention is composed hence it is evident that improve prevention effect；(2) subtract
Prevent and treat recruitment, drug cost less；(3) pesticide that is alternative conventional and being also easy to produce resistance；(4) compared with single dose, produce and use
Cost reduces.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.Described below is only the preferable embodiment of the present invention, is used only for explaining
The present invention, but can not be therefore understands that being the restriction to the scope of the claims of the present invention.It should be understood that when, all spirit in the present invention and
Any modification, equivalent or improvement of being made within principle etc., should be included within the scope of the present invention, therefore,
The protection domain of patent of the present invention should be defined by claims.
First, example of formulations
1st, embodiment 1:34% mefentrifluconazole benzo alkene fluorine bacterium azoles micro-capsule suspension
mefentrifluconazole 20%
Benzo alkene fluorine bacterium azoles 14%
Capsule heart solvent 18%
Wall material 11%
Emulsifying agent 5%
Dispersant 12%
Deionized water surplus
The preparation method of described wettable powder is: technical scheme under this invention, and above-mentioned each material is added taper to mix together
Mix homogeneously in conjunction machine, pulverizes by jet mill, and the material after pulverizing mixes through cone-type mixer again, mixed material
Fineness 98% passes through 600 mesh standard sieves, and the mefentrifluconazole benzo alkene fluorine bacterium azoles obtaining final product corresponding percentage by weight can
WP.
2nd, embodiment 2:48% mefentrifluconazole benzo alkene fluorine bacterium azoles suspending agent.
mefentrifluconazole 30%
Benzo alkene fluorine bacterium azoles 18%
Calcium dodecyl benzene sulfonate 3%
Xanthan gum 0.5%
Fatty alcohol-polyoxyethylene ether 7%
Glycerol 5%
Aluminium-magnesium silicate 0.2%
Defoamer 0.5%
Deionized water surplus
The preparation method of described suspending agent is: technical scheme under this invention, weighs active compound, the dispersion of above-mentioned formulation ratio weight
Agent, antifreezing agent, deionized water etc. are pre-mixed, and are ground after being sufficiently mixed in sand mill again, obtain institute after sand milling
Need the suspension of qualified particle diameter, add thickening agent and defoamer to obtain corresponding weight percent after the mixing shearing of efficient cutter
The mefentrifluconazole benzo alkene fluorine bacterium azoles suspending agent of ratio.
3rd, embodiment 3:30% mefentrifluconazole benzo alkene triflumizole wettable powder
mefentrifluconazole 25%
Benzo alkene fluorine bacterium azoles 5%
Sodium lauryl sulphate 5%
Dispersant nno 8%
Calcium lignosulfonate 4%
White carbon 10%
Kaolin surplus
The preparation method of described wettable powder is: technical scheme under this invention, and above-mentioned each material is added taper to mix together
Mix homogeneously in conjunction machine, pulverizes by jet mill, and the material after pulverizing mixes through cone-type mixer again, mixed material
Fineness 98% passes through 600 mesh standard sieves, and the mefentrifluconazole benzo alkene fluorine bacterium azoles obtaining final product corresponding percentage by weight can
WP.
4th, embodiment 4:22% mefentrifluconazole benzo alkene fluorine bacterium azoles dispersible oil-suspending agent
mefentrifluconazole 20%
Benzo alkene fluorine bacterium azoles 2%
Styrylphenol polyoxyethylene ether 10%
Alkylphenol polyoxyethylene 10%
Soybean oil 20%
Organobentonite 10%
Calcium dodecyl benzene sulfonate 11%
Methyl oleate surplus
Described dispersible oil-suspending agent preparation method be: above-mentioned material (except organobentonite) is added to reactor together
In mixer, stir half an hour, open bottom pan feeding valve, material is injected in multistage sand mill and grinds, the material after grinding is thin
Spend qualified rear discharging, material is put in high-shear emulsifying kettle together with organobentonite again, obtain final product corresponding after fully dispersed mixing
The mefentrifluconazole benzo alkene fluorine bacterium azoles of percentage by weight dispersible oil-suspending agent.
5th, embodiment 5:21% mefentrifluconazole benzo alkene triflumizole water dispersant.
mefentrifluconazole 20%
Benzo alkene fluorine bacterium azoles 1%
Sodium lauryl sulphate 5%
Dispersant polycarboxylate 8%
Naphthalene sulfonate 7%
Ammonium sulfate 15%
Corn starch surplus
The preparation method of described water dispersible granules is: above-mentioned each material is added in cone-type mixer together by proportioning and mixes all
Even, pulverize by jet mill, the material after pulverizing mixes through cone-type mixer again, mixed fineness of materials 98% passes through
400 mesh standard sieves, add in kneader and are kneaded into plasticity material, finally this material are put into extruding in Squeezinggranulator and make
Grain, is obtained the mefentrifluconazole benzo alkene fluorine bacterium of corresponding percentage by weight after drying, screening after pelletize
Azoles water dispersible granules.
6th, embodiment 6:30% mefentrifluconazole benzo alkene triflumizole wettable powder
mefentrifluconazole 5%
Benzo alkene fluorine bacterium azoles 25%
Sodium lauryl sulphate 5%
Dispersant nno 8%
Calcium lignosulfonate 4%
White carbon 10%
Kaolin surplus
The preparation method of described wettable powder is: technical scheme under this invention, and above-mentioned each material is added taper to mix together
Mix homogeneously in conjunction machine, pulverizes by jet mill, and the material after pulverizing mixes through cone-type mixer again, mixed material
Fineness 98% passes through 600 mesh standard sieves, obtains final product the mefentrifluconazole benzo alkene fluorine bacterium azoles of corresponding percentage by weight
Wettable powder.
7th, embodiment 7:22%mefentrifluconazole benzo alkene fluorine bacterium azoles dispersible oil-suspending agent
mefentrifluconazole 2%
Benzo alkene fluorine bacterium azoles 20%
Styrylphenol polyoxyethylene ether 10%
Alkylphenol polyoxyethylene 10%
Soybean oil 20%
Organobentonite 10%
Calcium dodecyl benzene sulfonate 11%
Methyl oleate surplus
Described dispersible oil-suspending agent preparation method be: above-mentioned material (except organobentonite) is added to reactor together
In mixer, stir half an hour, open bottom pan feeding valve, material is injected in multistage sand mill and grinds, the material after grinding is thin
Spend qualified rear discharging, material is put in high-shear emulsifying kettle together with organobentonite again, obtain final product corresponding after fully dispersed mixing
The mefentrifluconazole benzo alkene fluorine bacterium azoles of percentage by weight dispersible oil-suspending agent.
Embodiment 8:21% mefentrifluconazole benzo alkene triflumizole water dispersant
mefentrifluconazole 1%
Benzo alkene fluorine bacterium azoles 20%
Sodium lauryl sulphate 5%
Dispersant polycarboxylate 8%
Naphthalene sulfonate 7%
Ammonium sulfate 15%
Corn starch surplus
The preparation method of described water dispersible granules is: above-mentioned each material is added in cone-type mixer together by proportioning and mixes all
Even, pulverize by jet mill, the material after pulverizing mixes through cone-type mixer again, mixed fineness of materials 98% passes through
400 mesh standard sieves, add in kneader and are kneaded into plasticity material, finally this material are put into extruding in Squeezinggranulator and make
Grain, is obtained the mefentrifluconazole benzo alkene fluorine bacterium of corresponding percentage by weight after drying, screening after pelletize
Azoles water dispersible granules.
2nd, raw survey embodiment
1st, Toxicity Determination
Definite to Spike-stalk Brown Spot of Grape in order to understand that benzo alkene fluorine bacterium azoles and ipfentrifluconazole combine mixture
Virulence, the present invention is screened for its proportioning.
Target (is isolatable from Wulanchabu League of Inner Mongolia surrounding area), through Koch's Postulates checking after purification culture
It causes a disease
Property after strain is inoculated in pda culture medium, in 250c, under 90% damp condition cultivate 7d, after mycelia covers with culture dish
Break into bacteria cake with 0. 4cm card punch to use.
Benzo alkene fluorine bacterium azoles and mefentrifluconazole are measured using mycelial growth rate method and the two combines
The impact to target bacterium mycelial growth for the thing, sets the two weight proportion as 2:3,3:7,5:1,10:1,20:1,1:5,
1:10,1:20, and each single dose totally 10 kinds of chemicals treatment, each process setting 0. 125,0. 25,0. 5,1,2,4,8,
16,32mg/l totally 9 Concentraton gradient make pda flat board, setting no medicament is comparison, and every concentration is repeated 3 times, in aseptic condition
Lower by the bacteria cake accomplished fluently be inverted in each process pda flat board central authorities after, flat board is placed in 25 DEG C, under 90% damp condition cultivate,
When mycelial growth diameter reaches culture dish diameter 50% about (10d about) survey result, calculate suppression according to the following equation
Rate, and calculate each chemicals treatment to virulence regression equation, correlation coefficient, ec by dps Software of Data Statistics50And it is compounding common
Malicious coefficient.Adopt mycelial growth rate method indoors, measure the ec to bacterial strain for the different agents50, using co-toxicity coefficient computational methods,
Calculate the co-toxicity coefficient (ctc) of mixture, determine the building performance of mixture, circular is as follows:
With in mixture, a certain single dose (generally selects ec as standard agent50Junior), calculated:
Single dose toxicity index=standard agent ec50/ certain single dose ec50×100
Toxicity index × b that the toxicity index of theoretical toxicity index=a single dose × a single dose institute's accounting in mixture arranges+b single dose is mono-
Agent is in mixture institute accounting row
The ec of actual measurement toxicity index=standard single dose50The ec of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified: when ctc is more than 120, mixture has synergetic, and it is antagonism that ctc is less than when 80, and ctc is 80 ~ 120
Between be summation action.
Adopt mefentrifluconazole (a) and benzo alkene fluorine bacterium azoles (b) with different ratio to target in table 1
Indoor biometricses test, as shown in Table 1, the compositionss co-toxicity coefficient of the present invention is all higher than 120, and that is, the present composition has relatively
Good synergetic, its effect is all better than single dose kind.
2nd, field control effectiveness test
Test process: the difference of each composition of this experimental evidence sets two dosings respectively, dosing is that effective ingredient is new
The quality of product (a) and benzo alkene fluorine bacterium azoles (b) and.Comparison medicament be respectively 20%mefentrifluconazole preparation and
10% benzo alkene fluorine bacterium azoles preparation and blank clean water experiment.
Test method: each plot area is 66. 7m2, it is repeated 3 times;Investigation drug effect side after investigating before dispenser and preventing and treating
Method is: 5 points of randomization in test process area, carries out severity Scaling according to national field test relevant criterion, calculates preventive effect.
Result of the test see table:
Field efficacy result shows, as shown in Table 2, the present composition has an obvious synergistic function, compositionss anti-
Control excellent effect, prevention effect is all better than single dose kind, in agricultural application, there is using value.
Claims (6)
1. a kind of composition pesticide is it is characterised in that active component comprises mefentrifluconazole and benzo alkene fluorine bacterium
Azoles.
2. composition pesticide according to claim 1 is it is characterised in that described mefentrifluconazole and benzo
The weight of alkene fluorine bacterium azoles is than for 1:20-20:1.
3. the composition pesticide according to any one of claim 1-2 claim it is characterised in that: described pesticide combination
Thing is aided with Pesticide formulation auxiliary element and is processed into any one dosage form being suitable for agriculturally using.
4. composition pesticide according to claim 3 it is characterised in that described composition pesticide dosage form be cream, can
WP, suspending agent, aqueous emulsion, microemulsion, water dispersible granules, dispersible oil-suspending agent, dispersible oil preparation, dispersible
Agent, solvable powder, soluble granule, microcapsule suspending agent, suspension emulsion, liquor, arbitrary in oil preparation in.
5. composition pesticide according to any one of claim 1-4 claim is used for preventing and kill off the purposes of corps diseases.
6. purposes according to claim 5 is it is characterised in that described corps diseases are preferably target.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610761376.3A CN106359395A (en) | 2016-08-30 | 2016-08-30 | Bactericidal composition containing benzovindiflupyr |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610761376.3A CN106359395A (en) | 2016-08-30 | 2016-08-30 | Bactericidal composition containing benzovindiflupyr |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106359395A true CN106359395A (en) | 2017-02-01 |
Family
ID=57901179
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610761376.3A Pending CN106359395A (en) | 2016-08-30 | 2016-08-30 | Bactericidal composition containing benzovindiflupyr |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106359395A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018204435A1 (en) * | 2017-05-02 | 2018-11-08 | Dow Agrosciences Llc | Synergistic mixtures for fungal control in cereals |
| WO2019007839A1 (en) * | 2017-07-05 | 2019-01-10 | BASF Agro B.V. | Fungicidal mixtures of mefentrifluconazole |
| WO2020120204A3 (en) * | 2018-12-11 | 2020-07-23 | BASF Agro B.V. | Method to control a phythopatogenic fungi selected from septoria tritici and puccinia spp. in cereals by compositions comprising mefentrifluconazole |
| WO2020120206A3 (en) * | 2018-12-11 | 2020-07-23 | BASF Agro B.V. | Method to control a phythopatogenic fungi selected from phakopsora spp. in soybeans by compositions comprising mefentrifluconazole |
| WO2020241788A1 (en) * | 2019-05-31 | 2020-12-03 | Sumitomo Chemical Company, Limited | Liquid composition comprising mefentrifluconazole |
| WO2020241789A1 (en) * | 2019-05-31 | 2020-12-03 | Sumitomo Chemical Company, Limited | Liquid composition comprising mefentrifluconazole |
| US11033030B2 (en) | 2019-05-31 | 2021-06-15 | Sumitomo Chemical Company, Limited | Liquid composition comprising mefentrifluconazole |
| US11272707B2 (en) | 2019-05-31 | 2022-03-15 | Sumitomo Chemical Company, Limited | Liquid composition comprising mefentrifluconazole |
| US11317629B2 (en) | 2019-05-31 | 2022-05-03 | Sumitomo Chemical Company, Limited | Liquid composition comprising mefentrifluconazole |
| US12114660B2 (en) | 2014-12-30 | 2024-10-15 | Corteva Agriscience Llc | Picolinamide compounds with fungicidal activity |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103649057A (en) * | 2011-07-13 | 2014-03-19 | 巴斯夫欧洲公司 | Fungicidal substituted 2-[2-halogenalkyl-4-(phenoxy)-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds |
| CN105050406A (en) * | 2012-12-20 | 2015-11-11 | 巴斯夫农业公司 | Compositions comprising a triazole compound |
-
2016
- 2016-08-30 CN CN201610761376.3A patent/CN106359395A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103649057A (en) * | 2011-07-13 | 2014-03-19 | 巴斯夫欧洲公司 | Fungicidal substituted 2-[2-halogenalkyl-4-(phenoxy)-phenyl]-1-[1,2,4]triazol-1-yl-ethanol compounds |
| CN105050406A (en) * | 2012-12-20 | 2015-11-11 | 巴斯夫农业公司 | Compositions comprising a triazole compound |
Non-Patent Citations (1)
| Title |
|---|
| 姜宜飞等: "苯并烯氟菌唑原药高效液相色谱分析方法研究", 《农药科学与管理》 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12114660B2 (en) | 2014-12-30 | 2024-10-15 | Corteva Agriscience Llc | Picolinamide compounds with fungicidal activity |
| WO2018204435A1 (en) * | 2017-05-02 | 2018-11-08 | Dow Agrosciences Llc | Synergistic mixtures for fungal control in cereals |
| US11771085B2 (en) | 2017-05-02 | 2023-10-03 | Corteva Agriscience Llc | Synergistic mixtures for fungal control in cereals |
| WO2019007839A1 (en) * | 2017-07-05 | 2019-01-10 | BASF Agro B.V. | Fungicidal mixtures of mefentrifluconazole |
| US11477984B2 (en) | 2017-07-05 | 2022-10-25 | BASF Agro B.V. | Fungicidal mixtures of mefentrifluconazole |
| WO2020120204A3 (en) * | 2018-12-11 | 2020-07-23 | BASF Agro B.V. | Method to control a phythopatogenic fungi selected from septoria tritici and puccinia spp. in cereals by compositions comprising mefentrifluconazole |
| WO2020120206A3 (en) * | 2018-12-11 | 2020-07-23 | BASF Agro B.V. | Method to control a phythopatogenic fungi selected from phakopsora spp. in soybeans by compositions comprising mefentrifluconazole |
| WO2020241788A1 (en) * | 2019-05-31 | 2020-12-03 | Sumitomo Chemical Company, Limited | Liquid composition comprising mefentrifluconazole |
| WO2020241789A1 (en) * | 2019-05-31 | 2020-12-03 | Sumitomo Chemical Company, Limited | Liquid composition comprising mefentrifluconazole |
| US11033030B2 (en) | 2019-05-31 | 2021-06-15 | Sumitomo Chemical Company, Limited | Liquid composition comprising mefentrifluconazole |
| US11272707B2 (en) | 2019-05-31 | 2022-03-15 | Sumitomo Chemical Company, Limited | Liquid composition comprising mefentrifluconazole |
| US11317629B2 (en) | 2019-05-31 | 2022-05-03 | Sumitomo Chemical Company, Limited | Liquid composition comprising mefentrifluconazole |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106359395A (en) | Bactericidal composition containing benzovindiflupyr | |
| CN102578126B (en) | Pyraclostrobin-containing agricultural bactericidal compound composition | |
| CN102630679B (en) | Pesticide composition containing orysastrobin | |
| CN104137833A (en) | Complex biological fungicide for preventing and treating wheat scab and application thereof | |
| CN101810181A (en) | Sterilizing pesticide combination, preparation method and application thereof | |
| CN101669524B (en) | Bactericide composition with tetraconazole | |
| CN104012562B (en) | Weed control composition containing atrazine | |
| CN106900735A (en) | A kind of Seed Treatment agricultural chemicals | |
| CN104738045B (en) | A kind of Pesticidal combination containing propylene glycol alginate | |
| CN105265446A (en) | Pesticide combination containing fenaminstrobin and tetraconazole | |
| CN104206388B (en) | A kind of composition pesticide of fluorine-containing azoles bacterium aniline | |
| CN103355303A (en) | Bactericidal composition containing picoxystrobin and amino-oligosaccharin, usage and application thereof | |
| CN105794859B (en) | A kind of Pesticidal combination containing Conidiobolus thromboides and biogenic substances | |
| CN107047563A (en) | A kind of bactericidal composition for preventing and treating Zizyphus maurtiana powdery mildew | |
| CN106332889B (en) | Composition pesticide containing benzo alkene fluorine bacterium azoles | |
| CN105325417A (en) | Bactericidal composition containing mandipropamid and kasugamycin | |
| CN104872158B (en) | Composition pesticide and its application containing Zhongshengmycin and fluorine bacterium azoles | |
| CN104970031A (en) | Pesticide composition containing pyraclostrobin and chitosan | |
| CN105746523B (en) | A kind of Pesticidal combination of pyriproxyfen-containing | |
| CN104604904B (en) | A kind of containing difenodiconazole with the bactericidal composition of Mancozeb | |
| CN107467038A (en) | A kind of bactericidal composition containing isotianil and Zhongshengmycin | |
| CN102783491B (en) | Agricultural bactericide composition containing Flutolanil and difenoconazole and application thereof | |
| CN103271044B (en) | Sterilization composite containing tiadinil and thifluzamide | |
| CN102657185B (en) | Sterilization combination containing thifluzamide and tetraconazole | |
| CN105248421B (en) | A kind of composition pesticide containing Spiromesifen and bishydrazide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170201 |
|
| RJ01 | Rejection of invention patent application after publication |