CN105084940B - Crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite glazed tiles - Google Patents
Crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite glazed tiles Download PDFInfo
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- 239000000919 ceramic Substances 0.000 title claims abstract description 55
- 239000002131 composite material Substances 0.000 title claims abstract description 15
- 239000010410 layer Substances 0.000 claims abstract description 46
- 239000003595 mist Substances 0.000 claims abstract description 33
- 239000011159 matrix material Substances 0.000 claims abstract description 20
- 235000015895 biscuits Nutrition 0.000 claims abstract description 14
- 239000002344 surface layer Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 64
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 29
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 28
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 18
- 239000005995 Aluminium silicate Substances 0.000 claims description 15
- 235000012211 aluminium silicate Nutrition 0.000 claims description 15
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 15
- 239000000395 magnesium oxide Substances 0.000 claims description 14
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 12
- 238000010304 firing Methods 0.000 claims description 11
- 229940037003 alum Drugs 0.000 claims description 9
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 9
- 239000002689 soil Substances 0.000 claims description 9
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 8
- 229910021538 borax Inorganic materials 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 7
- 239000004328 sodium tetraborate Substances 0.000 claims description 7
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 7
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 6
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims description 6
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 6
- 239000000292 calcium oxide Substances 0.000 claims description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 6
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 claims description 6
- 239000010459 dolomite Substances 0.000 claims description 6
- 229910000514 dolomite Inorganic materials 0.000 claims description 6
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims description 6
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 6
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 6
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 6
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 6
- 239000010451 perlite Substances 0.000 claims description 6
- 235000019362 perlite Nutrition 0.000 claims description 6
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000010453 quartz Substances 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 6
- 229910000018 strontium carbonate Inorganic materials 0.000 claims description 6
- 230000008961 swelling Effects 0.000 claims description 6
- 239000000454 talc Substances 0.000 claims description 6
- 235000012222 talc Nutrition 0.000 claims description 6
- 229910052623 talc Inorganic materials 0.000 claims description 6
- 239000010456 wollastonite Substances 0.000 claims description 6
- 229910052882 wollastonite Inorganic materials 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 5
- 210000003298 dental enamel Anatomy 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 239000004744 fabric Substances 0.000 claims description 3
- 238000007689 inspection Methods 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 238000004806 packaging method and process Methods 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 238000010791 quenching Methods 0.000 claims description 3
- 230000000171 quenching effect Effects 0.000 claims description 3
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- 239000001923 methylcellulose Substances 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 239000002253 acid Substances 0.000 abstract description 7
- 238000010521 absorption reaction Methods 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 239000002932 luster Substances 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 239000004566 building material Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 description 9
- 239000011521 glass Substances 0.000 description 6
- 239000011449 brick Substances 0.000 description 4
- 239000002241 glass-ceramic Substances 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012372 quality testing Methods 0.000 description 3
- 239000000375 suspending agent Substances 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 229940031098 ethanolamine Drugs 0.000 description 1
- 239000010438 granite Substances 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
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- Cosmetics (AREA)
- Glass Compositions (AREA)
Abstract
The present invention discloses a kind of crystallite transparent lead-free glaze glomerocryst micro mist Ceramic Composite glazed tiles, belongs to building material technical field.The glazed tiles include the glomerocryst micro mist layer between crystallite transparent lead-free glaze surface layer, ceramic matrix layer and fritted glaze surface layer and ceramic matrix layer.The glazed tiles, using fritted glaze technology and crystallite and the glomerocryst micro mist complex technique of Western-style tile, fritted glaze are complex as a whole by glomerocryst micro mist layer with biscuit of ceramics on the basis of biscuit ware biscuit.The glazed tiles have a physical and chemical performances such as high, the wear-resisting resistant of acid and alkali-resistance, low-activity, low water absorption, intensity, glaze is unleaded, it is smooth, bright in luster, light, be not easy to peel off, ceramic segment also has the function of adsorbing, resolving harmful gas.
Description
Technical field
The invention belongs to building material technical fields, more particularly to a kind of crystallite transparent lead-free glaze-glomerocryst micro mist-ceramics
Compound glazed tiles and its production method.
Background technology
Glazed tiles are because its material is firm, bright in luster, glaze colours is smooth, always as the building object of Chinese tradition, warp
Successive dynasties development is crossed, the improvement of quality due to a variety of excellent functions, and is widely used in modern architecture.
Existing glazed tiles are formed using a variety of pug mixed sinterings, and glaze layer is generally thicker and generates and answers
Power, quality weight easily lead to the defect that product glaze cracking occurs, collapses stripping.It is not smooth enough, and pug is easy in process of production
Pollution is generated, cost and high energy consumption, the quality of product are not sufficiently stable, and glaze glossiness is inadequate, and colour generation is not abundant enough, stablizes,
It is easy to fade under climate variability area or prolonged sunlight.
Western-style tile is the ceramic tile for the traditional clay shingle in opposite China, and glaze is will never fade.Western-style tile glaze is molten
Block glaze, fritted glaze have larger firing range and color glaze choice.The industrial chemicals to be selected of preparation frit (borax,
Alkali face, red lead etc.) technical pure is should be, the purity of colorant wants high.The quality of frit directly influences glaze quality, should pay attention to burning
The links of system, improve the quality of frit, and good frit should be the transparent nature of glass.Since Western-style tile-base surface uses advanced pottery
Glaze, high temperature firing keep its color will never fade.It is not only applicable in the weather of northern China cold, and prolonged sunlight shines
It penetrates down and also keeps color constant.
Microcrystallite glass-ceramic composite brick is the architectural decoration veneer material being combined by devitrified glass and ceramic matrix
Material.Chinese patent CN200710199034.8 discloses a kind of microcrystal glass-ceramic compounded plate and its production method.The crystallite glass
Glass-ceramic clad plate is combined by devitrified glass surface layer and ceramic sandwich layer, and devitrified glass includes the component of following parts by weight：
SiO250-68 parts, Al2O33-10 parts, CaO20-38 parts, R2O(Na2O+K2O+Li2O) 3-12 parts, B2O30-3 parts, MgO0-12 parts.
Microcrystallite glass-ceramic composite brick is from initial pure color Cultivar development to high artificial granite lithotome kind, texture, pattern
And designs and varieties are still more dull, greatly improve imitative stone effect using in-glaze decoration decorative means, but because depositing
In printed network site problem, the verisimilitude that reach natural-like stone still has a certain distance.Chinese patent CN102704637A is public
A kind of devitrified glass-glomerocryst micro mist-ceramic composite brick is opened, the patent is on the basis of above-mentioned patent CN200710199034.8
Glomerocryst micro mist layer is added, solves the problems, such as that there are printed network sites in in-glaze decoration decorative brick face.
Invention content
Contain existing for defect existing for existing glazed tiles, especially glaze layer the technical problem to be solved by the present invention is to be directed to
The deficiencies of lead, matter are weighed, are easily cracked, easily collapses stripping, is rough provides a kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite coloured glaze
Glass watt, the glazed tiles are multiple using the fritted glaze technology and crystallite and glomerocryst micro mist of Western-style tile on the basis of biscuit ware biscuit
Fritted glaze is complex as a whole by glomerocryst micro mist layer with biscuit of ceramics by conjunction technology.The glazed tiles have acid and alkali-resistance, low radiation
Property, the physical and chemical performances such as high, the wear-resisting resistant of low water absorption, intensity, glaze is unleaded, it is smooth, bright in luster, light, be not easy to peel off, make pottery
Porcelain part also has the function of absorption, resolving harmful gas.
To achieve the goals above, the present invention is achieved by the following scheme：
A kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite glazed tiles, including crystallite transparent lead-free glaze surface layer and pottery
Porcelain basal body layer also has glomerocryst micro mist layer between the fritted glaze surface layer and ceramic matrix layer.
The crystallite transparent lead-free glaze surface layer by following components by weight parts array at：Kaolin 16~20%, quartz 20
~24%, potassium feldspar 18~22%, talcum 12~18%, borax 3~5%, boric acid 2~4%, line borate 2~4%, aluminium oxide 2
~4%, zinc oxide 1~3%, dolomite 1~3%, wollastonite 2~4%, barium carbonate 0~2%, strontium carbonate 0~2%, lithium carbonate
0~2%, lanthana 0~2%, zirconium oxide 0~2%.
The glomerocryst micro mist layer by following components by weight parts array at：Silica 54~58%, aluminium oxide 23~25%,
Iron oxide 0.1~1%, sodium oxide molybdena 3~5%, potassium oxide 4~8%, titanium oxide 0.1~1%, calcium oxide 4~6%, magnesia 3
~5%.
The ceramic matrix layer by following components by weight parts array at：Diatomite 15~25%, kaolin 10~20%,
Red soil 10~15%, land plaster 10~15%, swelling perlite powder 10~15%, aluminium oxide 6~10%, magnesia 6~10%,
Magnesium chloride 6~10%, alum 1~5%, triethanolamine 0~3%.
Preferably, the crystallite transparent lead-free glaze surface layer by following components by weight parts array at：Kaolin 18%, quartz
22%, potassium feldspar 20%, talcum 15%, borax 4%, boric acid 3%, line borate 3%, aluminium oxide 3%, zinc oxide 2%, dolomite
2%, wollastonite 3%, barium carbonate 1%, strontium carbonate 1%, lithium carbonate 1%, lanthana 1%, zirconium oxide 1%.
Preferably, the glomerocryst micro mist layer by following components by weight parts array at：Silica 56%, aluminium oxide 24%,
Sodium oxide molybdena 4%, potassium oxide 6%, calcium oxide 5%, magnesia 4%, iron oxide 0.5%, titanium oxide 0.5%.
Preferably, the ceramic matrix layer by following components by weight parts array at：Diatomite 20%, kaolin 15%,
Red soil 12%, land plaster 12%, swelling perlite powder 12%, magnesia 8%, magnesium chloride 8%, aluminium oxide 8%, alum 3%, three
Ethanol amine 2%.
The preparation process of the crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite glazed tiles, including following specific step
Suddenly：
(1) prepared by crystallite transparent lead-free glaze
It is uniformly mixed after each raw material is quantitatively weighed by weight, according to conventional fritted glaze preparation process, in high temperature melting
It is melted in 1350~1450 DEG C in block stove, the time is 3~4h, using water as the medium system of quenching, and suspending agent is added, and is made unleaded molten
Block glaze, by lead-free fritting enamel, glaze slip is made in ball milling in the ball mill；
(2) prepared by glomerocryst micro mist
It after each raw material is quantitatively weighed respectively by weight, is uniformly mixed, according to conventional glomerocryst micro mist preparation process, burns
System can be obtained glomerocryst micro mist；
(3) prepared by ceramic idiosome
Diatomite, kaolin, red soil are quantitatively weighed by weight, are crushed respectively, fineness is 200-250 mesh, is uniformly mixed,
The magnesia quantitatively weighed by weight, magnesium chloride, aluminium oxide, alum and triethanolamine are added, is uniformly mixed, according to conventional
Ceramic colored glaze watt biscuit preparation process, ceramic matrix is made, cloth glomerocryst micro mist material, plastic pressure forming on ceramic matrix, send to
The plain idiosome of biscuit firing roller kiln firing；
(4) glazing
(1) (3) the glaze slip of gained is imposed on the biscuit of ceramics through biscuiting, in 1150~1240 DEG C, in glaze firing roller kilns
Low fire ceramic product；
(5) prepared by finished product
To the (4) reconditioning of gained ceramic, quality inspection, packaging.
The suspending agent is methylcellulose, and addition is the 0.3% of lead-free fritting enamel quality.
The ball milling, material：Ball：Water=1:2:0.5, glaze slip fineness control 250 mesh screen residues mass ratio be 0.2~
0.4%.
Preferably, the crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite glazed tiles, three layer components press golden section
Law distributes each layer thickness proportioning：Crystallite transparent lead-free glaze layer is than glomerocryst micro mist layer, glomerocryst micro mist layer than the ratio between ceramic matrix layer
It is 0.618 or close to 0.618.
The beneficial effects of the invention are as follows：
(1) glazed tiles of the invention are fritted glaze with glaze, which is the fritted glaze of crystallite transparent lead-free, the coefficient of expansion
It is small, make glazed tiles glaze gloss, lubrication, is not easy to peel off；
(2) contain glomerocryst micro mist layer in glazed tiles of the invention, not only improve glazed tiles glaze fit, glaze is made to be not easy
It bursts apart, remove, and control the thickness of glomerocryst micro mist layer, can be used as the carrier of glazed tiles color pattern, increase the gorgeous of glazed tiles
Beautiful degree；
(3) have absorption, decomposition harmful containing materials such as diatomite, aluminium oxide in the ceramic matrix of glazed tiles of the invention
The function of gas；
(4) glazed tiles of the invention have the materializations such as acid and alkali-resistance, low-activity, low water absorption, intensity height, wear-resisting resistant
Energy.
Specific implementation mode
In conjunction with the embodiments and quality testing report further illustrates the present invention, is not construed as limiting the invention.
Embodiment 1
A kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite glazed tiles, composition include:
(1) crystallite transparent lead-free glaze layer：16 parts of kaolin, 20 parts of quartz, 18 parts of potassium feldspar, 12 parts of talcum, 3 parts of borax, boron
2 parts of acid, 2 parts of line borate, 2 parts of aluminium oxide, 1 part of zinc oxide, 1 part of dolomite, 2 parts of wollastonite, 0.5 part of barium carbonate, strontium carbonate 0.5
Part, 0.5 part of lithium carbonate, 0.5 part of lanthana, 0.5 part of zirconium oxide；
(2) glomerocryst micro mist layer：54 parts of silica, 23 parts of aluminium oxide, 0.1 part of iron oxide, 3 parts of sodium oxide molybdena, 4 parts of potassium oxide, oxygen
Change 0.1 part of titanium, 4 parts of calcium oxide, 3 parts of magnesia；
(3) ceramic matrix layer：15 parts of diatomite, 10 parts of kaolin, 10 parts of red soil, 10 parts of land plaster, swelling perlite powder 10
Part, 6 parts of aluminium oxide, 6 parts of magnesia, 6 parts of magnesium chloride, 1 part of alum, 0.5 part of triethanolamine.
Embodiment 2
A kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite glazed tiles, composition include:
(1) crystallite transparent lead-free glaze layer：20 parts of kaolin, 24 parts of quartz, 22 parts of potassium feldspar, 18 parts of talcum, 5 parts of borax, boron
Acid 4 parts, 4 parts of line borate, 4 parts of aluminium oxide, 3 parts of zinc oxide, 3 parts of dolomite, 4 parts of wollastonite, 2 parts of barium carbonate, 2 parts of strontium carbonate,
2 parts of lithium carbonate, 2 parts of lanthana, 2 parts of zirconium oxide；
(2) glomerocryst micro mist layer：58 parts of silica, 25 parts of aluminium oxide, 1 part of iron oxide, 5 parts of sodium oxide molybdena, 8 parts of potassium oxide, oxidation
1 part of titanium, 6 parts of calcium oxide, 5 parts of magnesia；
(3) ceramic matrix layer：25 parts of diatomite, 20 parts of kaolin, 15 parts of red soil, 15 parts of land plaster, swelling perlite powder 15
Part, 10 parts of aluminium oxide, 10 parts of magnesia, 10 parts of magnesium chloride, 5 parts of alum, 3 parts of triethanolamine.
Embodiment 3
A kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite glazed tiles, composition include:
(1) crystallite transparent lead-free glaze layer：18 parts of kaolin, 22 parts of quartz, 20 parts of potassium feldspar, 15 parts of talcum, 4 parts of borax, boron
Acid 3 parts, 3 parts of line borate, 3 parts of aluminium oxide, 2 parts of zinc oxide, 2 parts of dolomite, 3 parts of wollastonite, 1 part of barium carbonate, 1 part of strontium carbonate,
1 part of lithium carbonate, 1 part of lanthana, 1 part of zirconium oxide；
(2) glomerocryst micro mist layer：56 parts of silica, 24 parts of aluminium oxide, 4 parts of sodium oxide molybdena, 6 parts of potassium oxide, 5 parts of calcium oxide, oxidation
4 parts of magnesium, 0.5 part of iron oxide, 0.5 part of titanium oxide；
(3) ceramic matrix layer：20 parts of diatomite, 15 parts of kaolin, 12 parts of red soil, 12 parts of land plaster, swelling perlite powder 12
Part, 8 parts of magnesia, 8 parts of magnesium chloride, 8 parts of aluminium oxide, 3 parts of alum, 2 parts of triethanolamine.
In above-described embodiment, the preparation work of following crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite glazed tiles is pressed
Skill specifically includes the following steps：
(1) prepared by crystallite transparent lead-free glaze
It is uniformly mixed after each raw material is quantitatively weighed by weight, according to conventional fritted glaze preparation process, in high temperature melting
It is melted in 1350~1450 DEG C in block stove, the time is 3~4h, using water as the medium system of quenching, and suspending agent is added, and lead free soldering is made
Glaze, by lead-free fritting enamel, glaze slip is made in ball milling in the ball mill；
(2) prepared by glomerocryst micro mist
It after each raw material is quantitatively weighed respectively by weight, is uniformly mixed, according to conventional glomerocryst micro mist preparation process, burns
System can be obtained glomerocryst micro mist；
(3) prepared by ceramic idiosome
Diatomite, kaolin, red soil are quantitatively weighed by weight, are crushed respectively, fineness is 200-250 mesh, is uniformly mixed,
The magnesia quantitatively weighed by weight, magnesium chloride, aluminium oxide, alum and triethanolamine are added, is uniformly mixed, according to conventional
Ceramic colored glaze watt biscuit preparation process, ceramic matrix is made, cloth glomerocryst micro mist material, plastic pressure forming on ceramic matrix, send to
The plain idiosome of biscuit firing roller kiln firing；
(4) glazing
(1) (3) the glaze slip of gained is imposed on the biscuit of ceramics through biscuiting, in 1150~1240 DEG C, in glaze firing roller kilns
Low fire ceramic product；
(5) prepared by finished product
To the (4) reconditioning of gained ceramic, quality inspection, packaging.
Quality testing report
According to national JC/T765-2006《Colored glaze product》Standard and relevant criterion carry out the glazed tiles of the present invention
Product quality detects, and sampling plan is carried out, testing result is such as according to the regulation of GB/T3810.1 using the method for random sampling
Under：
According to quality testing report the results show that the glazed tiles of the present invention comply fully with relevant national standard, have
Water absorption rate is low, and glossiness is good, does not fade, and body and glaze associativity is good, thermal shock resistance, resistance to acid and alkali, emergency heat and cooling property resistance chilling, frost resistance,
Bending resistance is strong, be free of dissoluble lead the characteristics of, be suitble to China's each department extensive use.
Claims (1)
1. a kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite glazed tiles, including crystallite transparent lead-free glaze surface layer and ceramics
Base layer also has glomerocryst micro mist layer between the crystallite transparent lead-free glaze surface layer and ceramic matrix layer, it is characterised in that：It is described
Crystallite transparent lead-free glaze surface layer, glomerocryst micro mist layer, three layer component of ceramic matrix layer distribute each layer thickness by golden section law
Proportioning, i.e. crystallite transparent lead-free glaze layer are 0.618 than the ratio between ceramic matrix layer than glomerocryst micro mist layer, glomerocryst micro mist layer；
The crystallite transparent lead-free glaze surface layer by following components by weight parts array at：Kaolin 18%, quartz 22%, potassium feldspar
20%, talcum 15%, borax 4%, boric acid 3%, line borate 3%, aluminium oxide 3%, zinc oxide 2%, dolomite 2%, wollastonite
3%, barium carbonate 1%, strontium carbonate 1%, lithium carbonate 1%, lanthana 1%, zirconium oxide 1%；The glomerocryst micro mist layer is by following group
Divide and forms in parts by weight：Silica 56%, aluminium oxide 24%, sodium oxide molybdena 4%, potassium oxide 6%, calcium oxide 5%, magnesia
4%, iron oxide 0.5%, titanium oxide 0.5%；The ceramic matrix layer by following components by weight parts array at：Diatomite
20%, kaolin 15%, red soil 12%, land plaster 12%, swelling perlite powder 12%, magnesia 8%, magnesium chloride 8%, oxidation
Aluminium 8%, alum 3%, triethanolamine 2%；
Including following specific steps：
(1) prepared by crystallite transparent lead-free glaze
It is uniformly mixed, is melted in 1350~1450 DEG C in high temperature Cinker clew furnace, the time after each raw material is quantitatively weighed by weight
For 3~4h, using water as the medium system of quenching, and methylcellulose is added, addition is the 0.3% of lead-free fritting enamel quality, and nothing is made
Lead frit glaze, by lead-free fritting enamel, ball milling is made glaze slip in the ball mill, and when ball milling expects：Ball：The ratio between water quality is 1:2:0.5,
The control of glaze slip fineness is 0.2~0.4% in the mass ratio of 250 mesh screen residues；
(2) prepared by glomerocryst micro mist
It after each raw material is quantitatively weighed respectively by weight, is uniformly mixed, firing can be obtained glomerocryst micro mist；
(3) prepared by ceramic idiosome
Diatomite, kaolin, red soil are quantitatively weighed by weight, is crushed respectively, and fineness is 200-250 mesh, is uniformly mixed, then is added
Enter the magnesia quantitatively weighed by weight, magnesium chloride, aluminium oxide, alum and triethanolamine, is uniformly mixed, ceramic base is made
Body, cloth glomerocryst micro mist material, plastic pressure forming on ceramic matrix send to biscuit firing roller kiln and are burnt into plain idiosome；
(4) glazing
(1) (3) the glaze slip of gained is imposed on the biscuit of ceramics through biscuiting, in 1150~1240 DEG C, glaze firing roller kiln burning at
Ceramic；
(5) prepared by finished product
To the (4) reconditioning of gained ceramic, quality inspection, packaging.
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| CN105967523B (en) * | 2016-04-29 | 2019-01-04 | 佛山市东鹏陶瓷有限公司 | A kind of glaze and its manufacturing method |
| CN106116467B (en) * | 2016-06-22 | 2018-11-13 | 嵊州市森汇知识产权运营有限公司 | A method of preparing low fever's glazed tiles using black earth |
| CN106145894A (en) * | 2016-06-23 | 2016-11-23 | 叶国强 | A kind of preparation method of red mud low grade fever's terracotta base substrate |
| CN106892683B (en) * | 2017-03-10 | 2019-04-12 | 景德镇陶瓷大学 | A kind of preparation method and the product obtained of architectural pottery high abrasion transparent microcrystal fritted glaze and glaze layer |
| CN110818264A (en) * | 2019-12-18 | 2020-02-21 | 湖南华联瓷业股份有限公司 | High-temperature all-ceramic crack glaze and preparation method thereof |
| CN111718124A (en) * | 2020-06-11 | 2020-09-29 | 内蒙古华宸再生资源科技有限公司 | Antibacterial lead-free ceramic fritted glaze and preparation method thereof |
| CN112960906A (en) * | 2021-04-13 | 2021-06-15 | 刘永广 | Lead-free environment-friendly ceramic glaze and preparation method thereof |
| CN113788617B (en) * | 2021-09-26 | 2023-03-28 | 广东百强陶瓷有限公司 | Super-wear-resistant high-permeability diamond microcrystalline glaze and production process thereof |
| CN114988916B (en) * | 2022-07-02 | 2023-05-16 | 山东理工大学 | Composite technology of ceramic colored glaze |
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| CN1143058A (en) * | 1996-07-01 | 1997-02-19 | 张成华 | Preparing method for new type glass tile |
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| CN102701715A (en) * | 2012-05-18 | 2012-10-03 | 佛山市三水宏源陶瓷企业有限公司 | Porcelain brick with high glomerocryst micropowder proportion and correlated production process |
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| CN1143058A (en) * | 1996-07-01 | 1997-02-19 | 张成华 | Preparing method for new type glass tile |
| CN102704637A (en) * | 2012-05-18 | 2012-10-03 | 佛山市三水宏源陶瓷企业有限公司 | Glass ceramic-glomerocryst micro powder-ceramic composite brick and production method thereof |
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