CN105084940A - Microcrystalline transparent leadless glaze-polycrystalline micropowder-ceramic composite glass tile - Google Patents
Microcrystalline transparent leadless glaze-polycrystalline micropowder-ceramic composite glass tile Download PDFInfo
- Publication number
- CN105084940A CN105084940A CN201410191637.3A CN201410191637A CN105084940A CN 105084940 A CN105084940 A CN 105084940A CN 201410191637 A CN201410191637 A CN 201410191637A CN 105084940 A CN105084940 A CN 105084940A
- Authority
- CN
- China
- Prior art keywords
- glaze
- oxide
- micro mist
- ceramic
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Glass Compositions (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a microcrystalline transparent leadless glaze-polycrystalline micropowder-ceramic composite glass tile and belongs to the technical field of building materials. The glass tile comprises a microcrystalline transparent leadless glaze surface layer, a ceramic base body layer and a polycrystalline micropowder layer between the fritted glaze surface layer and the ceramic base body layer. According to the ceramic tile, based on an unglazed ceramic biscuit, the fritted glaze is integrally compounded with the ceramic biscuit through the polycrystalline micropowder layer by virtue of a fritted glaze technology of a western tile and a compound technology of microcrystalline and polycrystalline micropowder. The glass tile has the physical and chemical performances of being resistant to acid and alkali, low in radioactivity, low in water absorption, high in strength, resistant to water and stain, and the like. The glass tile is leadless on the glaze face, smooth and glossy in texture, bright in color, light in weight and not prone to peel. The ceramic part further has the functions of adsorbing and decomposing harmful gas.
Description
Technical field
The invention belongs to building material technical field, relate to a kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta and production method thereof particularly.
Background technology
Terra-cotta are because its material is firm, bright in luster, glaze colours is smooth, and always as the building object of Chinese tradition, it developed through the successive dynasties, the improvement of quality, owing to having multiple excellent function, and are widely used in modern architecture.
Existing terra-cotta are all adopt multiple pug mixed sintering to form usually, and its glaze layer is general thicker and produce stress, quality weight, easily cause product glaze paint to occur be full of cracks, collapse the defect of stripping.Smooth not, and pug easily produces pollution in process of production, cost and energy consumption high, the quality of product is stable not, and its glaze paint glossiness is inadequate, and colour generation is abundant not, stable, easily fades under solar radiation in climate variability area or for a long time.
Western-style tile is the ceramic tile of the traditional clay shingle of relative China, and glaze paint is will never fade.Western-style tile glaze is fritted glaze, and fritted glaze has larger firing range and color glaze choice.The industrial chemicals (borax, alkali face, red lead etc.) that preparation frit will be selected should be technical pure, and the purity of tinting material wants high.The quality of frit directly has influence on glaze quality, should pay attention to the links fired, and improve the quality of frit, good frit should be the transparent glassiness.Because Western-style tile tiling adopts advanced ceramic glaze, high temperature burns till and makes its color will never fade.Not only be suitable for the weather of northern China cold, and also keep color constant under long solar radiation.
Microcrystallite glass-ceramic composite brick is the architectural decoration finishing material be composited by devitrified glass and ceramic matrix.Chinese patent CN200710199034.8 discloses a kind of microcrystal glass-ceramic compounded plate and production method thereof.This microcrystal glass-ceramic compounded plate is composited by devitrified glass top layer and ceramic sandwich layer, and devitrified glass comprises the component of following parts by weight: SiO
250-68 part, Al
2o
33-10 part, CaO20-38 part, R
2o (Na
2o+K
2o+Li
2o) 3-12 part, B
2o
30-3 part, MgO0-12 part.Microcrystallite glass-ceramic composite brick is from initial pure color Cultivar development to high artificial granite lithotome kind, its texture, pattern and assortment are still more dull, in-glaze decoration decorative means is adopted to improve imitative stone effect greatly, but because there is printed network site problem, the verisimilitude that reach natural-like stone still has certain distance.Chinese patent CN102704637A discloses a kind of devitrified glass-glomerocryst micro mist-ceramic composite brick, and this patent adds glomerocryst micro mist layer on the basis of above-mentioned patent CN200710199034.8, solves in-glaze decoration decorative block face and there is printed network site problem.
Summary of the invention
Technical problem to be solved by this invention is the defect existed for existing terra-cotta, especially heavy, the easily be full of cracks of leaded, the matter that exists of glaze layer, easily stripping, the deficiency such as rough is collapsed, a kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta are provided, these terra-cotta are on the basis of biscuit ware biscuit, adopt the fritted glaze technology of Western-style tile and crystallite and glomerocryst micro mist compounding technology, fritted glaze is complex as a whole by glomerocryst micro mist layer and biscuit of ceramics.These terra-cotta have the physical and chemical performances such as acid and alkali-resistance, low-activity, low water absorption, intensity are high, wear-resisting resistant, and glaze paint is unleaded, smooth, bright in luster, light weight, incrust, and ceramic segment also has the function of absorption, resolving harmful gas.
To achieve these goals, the present invention is achieved by the following technical solutions:
A kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta, comprise crystallite transparent lead-free glaze top layer and ceramic matrix layer, also have glomerocryst micro mist layer between described fritted glaze top layer and ceramic matrix layer.
Described crystallite transparent lead-free glaze top layer is become by following components by weight parts array: kaolin 16 ~ 20%, quartz 20 ~ 24%, potassium felspar sand 18 ~ 22%, talcum 12 ~ 18%, borax 3 ~ 5%, boric acid 2 ~ 4%, lime borate 2 ~ 4%, aluminum oxide 2 ~ 4%, zinc oxide 1 ~ 3%, rhombspar 1 ~ 3%, wollastonite 2 ~ 4%, barium carbonate 0 ~ 2%, Strontium carbonate powder 0 ~ 2%, Quilonum Retard 0 ~ 2%, lanthanum trioxide 0 ~ 2%, zirconium white 0 ~ 2%.
Described glomerocryst micro mist layer is become by following components by weight parts array: silicon oxide 54 ~ 58%, aluminum oxide 23 ~ 25%, ferric oxide 0.1 ~ 1%, sodium oxide 3 ~ 5%, potassium oxide 4 ~ 8%, titanium oxide 0.1 ~ 1%, calcium oxide 4 ~ 6%, magnesium oxide 3 ~ 5%.
Described ceramic matrix layer is become by following components by weight parts array: diatomite 15 ~ 25%, kaolin 10 ~ 20%, red soil 10 ~ 15%, terra alba 10 ~ 15%, swelling perlite powder 10 ~ 15%, aluminum oxide 6 ~ 10%, magnesium oxide 6 ~ 10%, magnesium chloride 6 ~ 10%, alum 1 ~ 5%, trolamine 0 ~ 3%.
Preferably, described crystallite transparent lead-free glaze top layer is become by following components by weight parts array: kaolin 18%, quartz 22%, potassium felspar sand 20%, talcum 15%, borax 4%, boric acid 3%, lime borate 3%, aluminum oxide 3%, zinc oxide 2%, rhombspar 2%, wollastonite 3%, barium carbonate 1%, Strontium carbonate powder 1%, Quilonum Retard 1%, lanthanum trioxide 1%, zirconium white 1%.
Preferably, described glomerocryst micro mist layer is become by following components by weight parts array: silicon oxide 56%, aluminum oxide 24%, sodium oxide 4%, potassium oxide 6%, calcium oxide 5%, magnesium oxide 4%, ferric oxide 0.5%, titanium oxide 0.5%.
Preferably, described ceramic matrix layer is become by following components by weight parts array: diatomite 20%, kaolin 15%, red soil 12%, terra alba 12%, swelling perlite powder 12%, magnesium oxide 8%, magnesium chloride 8%, aluminum oxide 8%, alum 3%, trolamine 2%.
The preparation technology of described crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta, comprises following concrete steps:
(1) crystallite transparent lead-free glaze preparation
Mix after each raw material is quantitatively taken by weight, according to conventional fritted glaze preparation technology, found in 1350 ~ 1450 DEG C in high temperature Cinker clew furnace, time is 3 ~ 4h, take water as the medium system of quenching, and adding suspension agent, obtained lead-free fritting enamel, makes glaze slip by lead-free fritting enamel ball milling in ball mill;
(2) glomerocryst micro mist preparation
After each raw material is quantitatively taken by weight respectively, mix, according to conventional glomerocryst micro mist preparation technology, fire and can obtain glomerocryst micro mist;
(3) ceramic idiosome preparation
Quantitatively take diatomite, kaolin, red soil by weight, pulverize respectively, fineness is 200-250 order, mixes, then adds the magnesium oxide, magnesium chloride, aluminum oxide, alum and the trolamine that quantitatively take by weight, mix, according to conventional ceramic colored glaze watt biscuit preparation technology, make ceramic matrix, cloth glomerocryst micro mist material on ceramic matrix, plastic pressure forming, delivers to biscuit firing roller kiln and burns till plain idiosome;
(4) glazing
(1) the glaze slip of gained is imposed on (3) on the biscuit of ceramics of biscuiting, in 1150 ~ 1240 DEG C, burns till ceramic at glaze firing roller kiln;
(5) finished product preparation
By the (4) reconditioning of gained ceramic, quality inspection, pack.
Described suspension agent is methylcellulose gum, and add-on is 0.3% of lead-free fritting enamel quality.
Described ball milling, material: ball: water=1:2:0.5, it is 0.2 ~ 0.4% that glaze slip fineness controls at the mass ratio of 250 mesh screen residues.
Preferably, described crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta, three layer components distribute each layer thickness proportioning by golden section law: crystallite transparent lead-free glaze layer is 0.618 or close to 0.618 than glomerocryst micro mist layer, glomerocryst micro mist layer than the ratio of ceramic matrix layer.
The invention has the beneficial effects as follows:
(1) terra-cotta glaze of the present invention is fritted glaze, and this fritted glaze is the fritted glaze of crystallite transparent lead-free, and the coefficient of expansion is little, makes terra-cotta glaze paint gloss, lubrication, incrust;
(2) contain glomerocryst micro mist layer in terra-cotta of the present invention, not only improve terra-cotta glaze fit, glaze paint is not easily burst apart, peels off, and control the thickness of glomerocryst micro mist layer, can be used as the carrier of terra-cotta color pattern, increase the gorgeous degree of terra-cotta;
(3), containing the material such as diatomite, aluminum oxide in the ceramic matrix of terra-cotta of the present invention, there is the function of absorption, resolving harmful gas;
(4) terra-cotta of the present invention have the physical and chemical performances such as acid and alkali-resistance, low-activity, low water absorption, intensity are high, wear-resisting resistant.
Embodiment
In conjunction with the embodiments and quality examination report further the present invention is set forth, be not construed as limiting the invention.
Embodiment 1
A kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta, its composition comprises:
(1) crystallite transparent lead-free glaze layer: kaolin 16 parts, 20 parts, quartz, potassium felspar sand 18 parts, 12 parts, talcum, borax 3 parts, boric acid 2 parts, lime borate 2 parts, 2 parts, aluminum oxide, 1 part, zinc oxide, rhombspar 1 part, wollastonite 2 parts, barium carbonate 0.5 part, Strontium carbonate powder 0.5 part, Quilonum Retard 0.5 part, lanthanum trioxide 0.5 part, zirconium white 0.5 part;
(2) glomerocryst micro mist layer: silicon oxide 54 parts, 23 parts, aluminum oxide, ferric oxide 0.1 part, sodium oxide 3 parts, potassium oxide 4 parts, titanium oxide 0.1 part, 4 parts, calcium oxide, 3 parts, magnesium oxide;
(3) ceramic matrix layer: 15 parts, diatomite, kaolin 10 parts, 10 parts, red soil, terra alba 10 parts, swelling perlite powder 10 parts, 6 parts, aluminum oxide, 6 parts, magnesium oxide, 6 parts, magnesium chloride, 1 part, alum, trolamine 0.5 part.
Embodiment 2
A kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta, its composition comprises:
(1) crystallite transparent lead-free glaze layer: kaolin 20 parts, 24 parts, quartz, potassium felspar sand 22 parts, 18 parts, talcum, borax 5 parts, boric acid 4 parts, lime borate 4 parts, 4 parts, aluminum oxide, 3 parts, zinc oxide, rhombspar 3 parts, wollastonite 4 parts, barium carbonate 2 parts, Strontium carbonate powder 2 parts, Quilonum Retard 2 parts, lanthanum trioxide 2 parts, zirconium white 2 parts;
(2) glomerocryst micro mist layer: silicon oxide 58 parts, 25 parts, aluminum oxide, ferric oxide 1 part, sodium oxide 5 parts, potassium oxide 8 parts, titanium oxide 1 part, 6 parts, calcium oxide, 5 parts, magnesium oxide;
(3) ceramic matrix layer: 25 parts, diatomite, kaolin 20 parts, 15 parts, red soil, terra alba 15 parts, swelling perlite powder 15 parts, 10 parts, aluminum oxide, 10 parts, magnesium oxide, 10 parts, magnesium chloride, 5 parts, alum, trolamine 3 parts.
Embodiment 3
A kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta, its composition comprises:
(1) crystallite transparent lead-free glaze layer: kaolin 18 parts, 22 parts, quartz, potassium felspar sand 20 parts, 15 parts, talcum, borax 4 parts, boric acid 3 parts, lime borate 3 parts, 3 parts, aluminum oxide, 2 parts, zinc oxide, rhombspar 2 parts, wollastonite 3 parts, barium carbonate 1 part, Strontium carbonate powder 1 part, Quilonum Retard 1 part, lanthanum trioxide 1 part, zirconium white 1 part;
(2) glomerocryst micro mist layer: silicon oxide 56 parts, 24 parts, aluminum oxide, sodium oxide 4 parts, potassium oxide 6 parts, 5 parts, calcium oxide, 4 parts, magnesium oxide, ferric oxide 0.5 part, titanium oxide 0.5 part;
(3) ceramic matrix layer: 20 parts, diatomite, kaolin 15 parts, 12 parts, red soil, terra alba 12 parts, swelling perlite powder 12 parts, 8 parts, magnesium oxide, 8 parts, magnesium chloride, 8 parts, aluminum oxide, 3 parts, alum, trolamine 2 parts.
In above-described embodiment, all by the preparation technology of following crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta, specifically comprise the following steps:
(1) crystallite transparent lead-free glaze preparation
Mix after each raw material is quantitatively taken by weight, according to conventional fritted glaze preparation technology, found in 1350 ~ 1450 DEG C in high temperature Cinker clew furnace, time is 3 ~ 4h, take water as the medium system of quenching, and adding suspension agent, obtained lead-free fritting enamel, makes glaze slip by lead-free fritting enamel ball milling in ball mill;
(2) glomerocryst micro mist preparation
After each raw material is quantitatively taken by weight respectively, mix, according to conventional glomerocryst micro mist preparation technology, fire and can obtain glomerocryst micro mist;
(3) ceramic idiosome preparation
Quantitatively take diatomite, kaolin, red soil by weight, pulverize respectively, fineness is 200-250 order, mixes, then adds the magnesium oxide, magnesium chloride, aluminum oxide, alum and the trolamine that quantitatively take by weight, mix, according to conventional ceramic colored glaze watt biscuit preparation technology, make ceramic matrix, cloth glomerocryst micro mist material on ceramic matrix, plastic pressure forming, delivers to biscuit firing roller kiln and burns till plain idiosome;
(4) glazing
(1) the glaze slip of gained is imposed on (3) on the biscuit of ceramics of biscuiting, in 1150 ~ 1240 DEG C, burns till ceramic at glaze firing roller kiln;
(5) finished product preparation
By the (4) reconditioning of gained ceramic, quality inspection, pack.
Quality examination report
According to national JC/T765-2006 " colored glaze goods " standard and relevant criterion, carry out quality product detection to terra-cotta of the present invention, sampling plan is according to the regulation of GB/T3810.1, and adopt the method for stochastic sampling to carry out, detected result is as follows:
Result according to quality examination report shows, terra-cotta of the present invention meet relevant national standard completely, there is water-intake rate low, glossiness is good, do not fade, body and glaze associativity is good, and heat-shock resistance, resistance to acids and bases, emergency heat and cooling property resistance chilling, frost resistance, bending resistance are strong, not containing the feature of dissoluble lead, be applicable to China's each department widespread use.
Claims (7)
1. crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta, is characterized in that: comprise crystallite transparent lead-free glaze top layer and ceramic matrix layer, also have glomerocryst micro mist layer between described fritted glaze top layer and ceramic matrix layer.
2. a kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta as claimed in claim 1, it is characterized in that: three described layer components distribute each layer thickness proportioning by golden section law, namely crystallite transparent lead-free glaze layer is 0.618 or close to 0.618 than glomerocryst micro mist layer, glomerocryst micro mist layer than the ratio of ceramic matrix layer.
3. a kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta as claimed in claim 1, is characterized in that: described fritted glaze top layer is become by following components by weight parts array: kaolin 16 ~ 20%, quartz 22%, potassium felspar sand 20%, talcum 15%, borax 4%, boric acid 3%, lime borate 3%, aluminum oxide 3%, zinc oxide 2%, rhombspar 2%, wollastonite 3%, barium carbonate 1%, Strontium carbonate powder 1%, Quilonum Retard 1%, lanthanum trioxide 1%, zirconium white 1%; Described glomerocryst micro mist layer is become by following components by weight parts array: silicon oxide 54 ~ 58%, aluminum oxide 23 ~ 25%, ferric oxide 0.1 ~ 1%, sodium oxide 3 ~ 5%, potassium oxide 4 ~ 8%, titanium oxide 0.1 ~ 1%, calcium oxide 4 ~ 6%, magnesium oxide 3 ~ 5%; Described ceramic matrix layer is become by following components by weight parts array: diatomite 15 ~ 25%, kaolin 10 ~ 20%, red soil 10 ~ 15, terra alba 10 ~ 15, swelling perlite powder 10 ~ 15, aluminum oxide 6 ~ 10% magnesium oxide 6 ~ 10%, magnesium chloride 6 ~ 10%, alum 1 ~ 5%, trolamine 0 ~ 3%.
4. a kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta as claimed in claim 1, is characterized in that: described crystallite transparent lead-free glaze top layer is become by following components by weight parts array: kaolin 18%, quartz 22%, potassium felspar sand 20%, talcum 15%, borax 4%, boric acid 3%, lime borate 3%, aluminum oxide 3%, zinc oxide 2%, rhombspar 2%, wollastonite 3%, barium carbonate 1%, Strontium carbonate powder 1%, Quilonum Retard 1%, lanthanum trioxide 1%, zirconium white 1%; Described glomerocryst micro mist layer is become by following components by weight parts array: silicon oxide 56%, aluminum oxide 24%, sodium oxide 4%, potassium oxide 6%, calcium oxide 5%, magnesium oxide 4%, ferric oxide 0.5%, titanium oxide 0.5%; Described ceramic matrix layer is become by following components by weight parts array: diatomite 20%, kaolin 15%, red soil 12%, terra alba 12%, swelling perlite powder 12%, magnesium oxide 8%, magnesium chloride 8%, aluminum oxide 8%, alum 3%, trolamine 2%.
5. the preparation technology of a kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta as claimed in claim 1, is characterized in that: comprise following concrete steps:
(1) crystallite transparent lead-free glaze preparation
Mix after each raw material is quantitatively taken by weight, according to conventional fritted glaze preparation technology, found in 1350 ~ 1450 DEG C in high temperature Cinker clew furnace, time is 3 ~ 4h, take water as the medium system of quenching, and adding suspension agent, obtained lead-free fritting enamel, makes glaze slip by lead-free fritting enamel ball milling in ball mill;
(2) glomerocryst micro mist preparation
After each raw material is quantitatively taken by weight respectively, mix, according to conventional glomerocryst micro mist preparation technology, fire and can obtain glomerocryst micro mist;
(3) ceramic idiosome preparation
Quantitatively take diatomite, kaolin, red soil by weight, pulverize respectively, fineness is 200-250 order, mixes, then adds the magnesium oxide, magnesium chloride, aluminum oxide, alum and the trolamine that quantitatively take by weight, mix, according to conventional ceramic colored glaze watt biscuit preparation technology, make ceramic matrix, cloth glomerocryst micro mist material on ceramic matrix, plastic pressure forming, delivers to biscuit firing roller kiln and burns till plain idiosome;
(4) glazing
(1) the glaze slip of gained is imposed on (3) on the biscuit of ceramics of biscuiting, in 1150 ~ 1240 DEG C, burns till ceramic at glaze firing roller kiln;
(5) finished product preparation
By the (4) reconditioning of gained ceramic, quality inspection, pack.
6. the preparation technology of a kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta as claimed in claim 5, it is characterized in that: described suspension agent is methylcellulose gum, add-on is 0.3% of lead-free fritting enamel quality.
7. the preparation technology of a kind of crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite terra-cotta as claimed in claim 5, it is characterized in that: described ball milling, material: ball: water=1:2:0.5, it is 0.2 ~ 0.4% that glaze slip fineness controls at the mass ratio of 250 mesh screen residues.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410191637.3A CN105084940B (en) | 2014-05-07 | 2014-05-07 | Crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite glazed tiles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410191637.3A CN105084940B (en) | 2014-05-07 | 2014-05-07 | Crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite glazed tiles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105084940A true CN105084940A (en) | 2015-11-25 |
| CN105084940B CN105084940B (en) | 2018-09-14 |
Family
ID=54566382
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410191637.3A Active CN105084940B (en) | 2014-05-07 | 2014-05-07 | Crystallite transparent lead-free glaze-glomerocryst micro mist-Ceramic Composite glazed tiles |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105084940B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105967523A (en) * | 2016-04-29 | 2016-09-28 | 佛山市东鹏陶瓷有限公司 | Frit used for glaze, and making method thereof |
| CN106116467A (en) * | 2016-06-22 | 2016-11-16 | 徐晓 | A kind of method utilizing black earth to prepare low grade fever's glazed tiles |
| CN106145894A (en) * | 2016-06-23 | 2016-11-23 | 叶国强 | A kind of preparation method of red mud low grade fever's terracotta base substrate |
| CN106892683A (en) * | 2017-03-10 | 2017-06-27 | 景德镇陶瓷大学 | A kind of architectural pottery high abrasion transparent microcrystal fritted glaze and the preparation method and obtained product of glaze layer |
| CN110818264A (en) * | 2019-12-18 | 2020-02-21 | 湖南华联瓷业股份有限公司 | High-temperature all-ceramic crack glaze and preparation method thereof |
| CN111718124A (en) * | 2020-06-11 | 2020-09-29 | 内蒙古华宸再生资源科技有限公司 | Antibacterial lead-free ceramic fritted glaze and preparation method thereof |
| CN112960906A (en) * | 2021-04-13 | 2021-06-15 | 刘永广 | Lead-free environment-friendly ceramic glaze and preparation method thereof |
| CN113788617A (en) * | 2021-09-26 | 2021-12-14 | 广东百强陶瓷有限公司 | Super-wear-resistant high-permeability diamond microcrystalline glaze and production process thereof |
| CN114988916A (en) * | 2022-07-02 | 2022-09-02 | 山东理工大学 | Composite process of ceramic colored glaze |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1143058A (en) * | 1996-07-01 | 1997-02-19 | 张成华 | Preparing method for new type glass tile |
| CN102701715A (en) * | 2012-05-18 | 2012-10-03 | 佛山市三水宏源陶瓷企业有限公司 | Porcelain brick with high glomerocryst micropowder proportion and correlated production process |
| CN102704637A (en) * | 2012-05-18 | 2012-10-03 | 佛山市三水宏源陶瓷企业有限公司 | Glass ceramic-glomerocryst micro powder-ceramic composite brick and production method thereof |
-
2014
- 2014-05-07 CN CN201410191637.3A patent/CN105084940B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1143058A (en) * | 1996-07-01 | 1997-02-19 | 张成华 | Preparing method for new type glass tile |
| CN102701715A (en) * | 2012-05-18 | 2012-10-03 | 佛山市三水宏源陶瓷企业有限公司 | Porcelain brick with high glomerocryst micropowder proportion and correlated production process |
| CN102704637A (en) * | 2012-05-18 | 2012-10-03 | 佛山市三水宏源陶瓷企业有限公司 | Glass ceramic-glomerocryst micro powder-ceramic composite brick and production method thereof |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105967523A (en) * | 2016-04-29 | 2016-09-28 | 佛山市东鹏陶瓷有限公司 | Frit used for glaze, and making method thereof |
| CN105967523B (en) * | 2016-04-29 | 2019-01-04 | 佛山市东鹏陶瓷有限公司 | A kind of glaze and its manufacturing method |
| CN106116467A (en) * | 2016-06-22 | 2016-11-16 | 徐晓 | A kind of method utilizing black earth to prepare low grade fever's glazed tiles |
| CN106145894A (en) * | 2016-06-23 | 2016-11-23 | 叶国强 | A kind of preparation method of red mud low grade fever's terracotta base substrate |
| CN106892683A (en) * | 2017-03-10 | 2017-06-27 | 景德镇陶瓷大学 | A kind of architectural pottery high abrasion transparent microcrystal fritted glaze and the preparation method and obtained product of glaze layer |
| CN106892683B (en) * | 2017-03-10 | 2019-04-12 | 景德镇陶瓷大学 | A kind of preparation method and the product obtained of architectural pottery high abrasion transparent microcrystal fritted glaze and glaze layer |
| CN110818264A (en) * | 2019-12-18 | 2020-02-21 | 湖南华联瓷业股份有限公司 | High-temperature all-ceramic crack glaze and preparation method thereof |
| CN111718124A (en) * | 2020-06-11 | 2020-09-29 | 内蒙古华宸再生资源科技有限公司 | Antibacterial lead-free ceramic fritted glaze and preparation method thereof |
| CN112960906A (en) * | 2021-04-13 | 2021-06-15 | 刘永广 | Lead-free environment-friendly ceramic glaze and preparation method thereof |
| CN113788617A (en) * | 2021-09-26 | 2021-12-14 | 广东百强陶瓷有限公司 | Super-wear-resistant high-permeability diamond microcrystalline glaze and production process thereof |
| CN114988916A (en) * | 2022-07-02 | 2022-09-02 | 山东理工大学 | Composite process of ceramic colored glaze |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105084940B (en) | 2018-09-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105084940A (en) | Microcrystalline transparent leadless glaze-polycrystalline micropowder-ceramic composite glass tile | |
| CN102249739B (en) | Preparation method of carbon-golden metallic luster crystalline glaze | |
| WO2021218132A1 (en) | 3d dazzling ceramic tile and preparation method therefor | |
| CN104926281B (en) | A kind of preparation method of inexpensive ultrawhite ceramic tile | |
| CA2616467C (en) | Glaze composition | |
| CN106830685B (en) | A kind of glaze compositions | |
| CN106830684B (en) | Preparation method of reflective heat-insulation ceramic glazed tile | |
| CN102417343B (en) | Production method of sandstone-like porcelain exterior wall tile | |
| CN103693994A (en) | Color-changing glaze tile and production method thereof | |
| CN110092579A (en) | A kind of starry sky glaze glaze, starry sky glaze pottery and preparation method thereof | |
| CN107698235B (en) | A kind of high brightness under-glaze red porcelain and its manufacturing process | |
| CN106396638B (en) | Low-temperature light-weight white-gray gradient glaze ceramics and its production process | |
| CN106430977B (en) | A kind of pale blue matting glaze and preparation method thereof for fictile | |
| CN103693992A (en) | Color-changing glaze ceramic and production method thereof | |
| CN110818264A (en) | High-temperature all-ceramic crack glaze and preparation method thereof | |
| CN106186700B (en) | Environmentally friendly shell pearl glaze, environmental protection shell pearl glaze ceramic and preparation method thereof made from it | |
| CN108164139A (en) | Parian sheen brick overglaze, parian sheen brick and preparation method thereof | |
| CN105272153A (en) | Preparation method of blue-and-white Nixing ceramic | |
| CN105218170B (en) | A kind of high-hardness, wearable exempts to polish iron microcrystalline glass in series ceramic clad plate and preparation method thereof | |
| CN104860646B (en) | A kind of glazed tiles utilizing black earth to prepare | |
| CN111362577A (en) | A kind of bright glaze for ceramic antique brick and preparation method thereof | |
| CN101519277A (en) | Method for producing calendaring type glass-ceramic decorative board by phosphorous slag | |
| CN105330274A (en) | Ultrathin ultra-white talc constructional ceramic tile and manufacturing method thereof | |
| CN104261880B (en) | A kind of sand crystal glaze and preparation technology thereof utilizing iron mica | |
| CN112960969A (en) | Brick and manufacturing process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180725 Address after: 742400 Xi Po Town, Gansu Province, Zi Ba Village Applicant after: Hongtai Ceramics Co., Ltd. Address before: 742400 192 Cang Ping Village, west slope town, Longnan County, Gansu Province Applicant before: Jia Yaoxi |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191105 Address after: 430000 Hubei Province Wuhan Hongshan District Donghu New Technology Development Zone Laowu-Huanghe Highway 206 Huigu Space-time Building 705, 706A Patentee after: Wuhan Tuozhijia Information Technology Co., Ltd. Address before: 742400 Xi Po Town, Gansu Province, Zi Ba Village Patentee before: Hongtai Ceramics Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191210 Address after: No.1, floor 3, No.319, zhanggongshan Road, Yuhui District, Bengbu City, Anhui Province Patentee after: Bengbu guijiu Intellectual Property Service Co., Ltd Address before: 430000 Hubei Province Wuhan Hongshan District Donghu New Technology Development Zone Laowu-Huanghe Highway 206 Huigu Space-time Building 705, 706A Patentee before: Wuhan Tuozhijia Information Technology Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200323 Address after: 405200 Chongqing Liangping County Industrial Park Patentee after: CHONGQING TIANGE CERAMICS Co.,Ltd. Address before: No.1, floor 3, No.319, zhanggongshan Road, Yuhui District, Bengbu City, Anhui Province Patentee before: Bengbu guijiu Intellectual Property Service Co., Ltd |