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CN103482946A - Neutral mosaic adhesive - Google Patents

Neutral mosaic adhesive Download PDF

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Publication number
CN103482946A
CN103482946A CN201310414327.9A CN201310414327A CN103482946A CN 103482946 A CN103482946 A CN 103482946A CN 201310414327 A CN201310414327 A CN 201310414327A CN 103482946 A CN103482946 A CN 103482946A
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China
Prior art keywords
mosaic
neutral
gypsum
tackiness agent
water
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Application number
CN201310414327.9A
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Chinese (zh)
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CN103482946B (en
Inventor
方楚燕
董峰亮
邓德安
吴海明
刘少严
陈学静
阿那
梁至柔
胡程
周碧平
丁天华
陆小勇
严昌俊
万德刚
薛静
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Davco Guangzhou Building Material Co Ltd
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Davco Guangzhou Building Material Co Ltd
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Priority to CN201310414327.9A priority Critical patent/CN103482946B/en
Publication of CN103482946A publication Critical patent/CN103482946A/en
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Publication of CN103482946B publication Critical patent/CN103482946B/en
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  • Adhesives Or Adhesive Processes (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention relates to a neutral mosaic adhesive which is obtained by preparing plaster selected and used as a cementing material, quartz sand, water-retaining agents, emulsion powder with redispersibility, retarder and water-reducing agents according to a recipe. The neutral mosaic adhesive is neutral after hydration, so that the problems of oxidizing and blackening of glass mosaics and returning of alkali due to the strong alkalinity of cement hydration products when traditional cement or a cement-based adhesive is used for sticking the glass mosaics are solved. Meanwhile, as the plaster and the quartz sand with the whiteness higher than that of the white cement are adopted, the effect of improving the whiteness can be achieved, and the better decoration effect is obtained. The neutral mosaic adhesive is high in adhesive strength, prevents the hollowing and falling phenomena, and is suitable for sticking tiles and the mosaics, and particularly suitable for sticking the glass mosaics indoors.

Description

Neutral mosaic tackiness agent
Technical field
The present invention relates to a kind of tackiness agent, particularly a kind of neutral mosaic tackiness agent, belong to the matrix material technical field in building trade.
Background technology
Mosaic has another name called mosaic tile, is a kind of building decoration material that can be spliced into various patterns of sheet, is widely used in house ornamentation toilet metope, ground, the positions such as swimming pool, and the mosaic exquisiteness is small and exquisite, and pattern is changeable, and the multiple combination mode is arranged, personalized pure.The production of mosaic normally a piece is processed the mosaic material paste on base material, become one finished product, the existing material be applied on mosaic mainly contains pottery, stone material, glass (comprising hot melt glass and crystal glass), metal, timber, shell, corium, resin etc., flourish along with mosaic in recent years, the mosaic product of various materials emerges in an endless stream, and applied environment is also more and more extensive.Glass Mosaic is the mosaic of current usage quantity maximum.
The mosaic mosaic tile adopts the notched scraper of 3mm*3mm or 4mm*4mm specification will add tackiness agent that water is stirred and criticizes and scrape on basal plane when paving, be carded to again dentate stripe, mosaic is rubbed and is pressed on tackiness agent, after solidifying, select suitable spackling to carry out the joint filling processing.The paving of traditional glass Mosaic is generally to adopt cement or cement-based adhesive, and cement can produce calcium hydroxide in hydration process, and hydrated product is strong basicity.For the glass Mosaic of goldleaf, minute surface, plating, cold spray one class, because of it, without crossing high-temperature fusion, between the color layers of mosaic material and glass coating, by glue, connect mutually, once run into the easy oxidation blackening of acid and alkali substance, thus decorative effect lost.Therefore, while using the tackiness agent paving glass Mosaic of cement or cement based, the highly basic material that hydrated cementitious produces acts on glass Mosaic, not only can affect decorative effect, also can affect the glass Mosaic life-span.
The whiteness of the tackiness agent of usually making with the gelling material of common white cement is not high, therefore, while adopting this type of tackiness agent to paste bottoming, can't set off out the beautiful color of glass Mosaic and moulding.
Adopt gypsum material and the preferred quartz sand of high whiteness in formula, the adhesive material whiteness is high, and the mosaic after stickup not only keeps the beautiful true qualities of mosaic, and high whiteness also shows the top grade taste of mosaic.Someone proposes to adopt neutral glass glue to carry out the stickup of glass Mosaic, but in actual applications, the problem of using glass cement the most often to occur is that (1) easily blackening is mouldy, even use waterproof glass glue, mildew-resistant glass cement can not avoid the generation of problems fully, therefore have for a long time the place of water or immersion should not construct; (2) glass cement wants the surface of bonding base material must be for totally, and other dirt settlings (such as dust etc.) can not be arranged, otherwise glass cement will there will be the bonding not firm or phenomenon that comes off after solidifying; (3) bonding force of neutral glass glue a little less than, easily cause obscission.
Gypsum is a kind of air-setting inorganic coagulation material that calcium sulfate is main component of take, gypsum is of many uses in material of construction, gypsum also has report as the application of one of adhesive component, as the application documents of publication number CN 1141266A disclose a kind of decoration special cement, it is to form by weight ratio with white cement clinker, calcite or dry powder, dihydrate gypsum, talcum powder that this kind decorated special cement, is particularly useful for sticking glass, mosaic, wall floor tile, marble etc.This decorates special cement and is still the tackiness agent that belongs to cement based, dihydrate gypsum Main Function in its component is to play delayed coagulation, therefore still likely there is the existing existing deficiency of cement-based adhesive sticking glass mosaic when the paving of the paving for mosaic, particularly glass Mosaic.
There do not is at present a kind of tackiness agent to solve aforesaid owing to using traditional cement or cement-based adhesive to cause the problems such as glass Mosaic is oxidized, have no the report of neutral gum stick of the gypsum base of glass Mosaic special use yet.
Summary of the invention
The object of the present invention is to provide a kind of neutral mosaic tackiness agent of gypsum base that is specifically designed to glass Mosaic, this neutrality mosaic tackiness agent selects gypsum as gelling material, be equipped with quartz sand, water-holding agent, redispersible latex powder, retardant, water reducer prepares by formula, after this tackiness agent aquation, be neutral, can solve the oxidized blackening of glass Mosaic that traditional cement or cement-based adhesive cause due to the strong basicity of hydrolysis product of cement when the sticking glass mosaic, the problem of the accumulation of salt in the surface soil, simultaneously owing to adopting the whiteness gypsum higher than white cement, quartz sand, can also reach the raising whiteness, obtain bright background color, improve the purpose of mosaic decorative effect, it is high that this neutrality mosaic tackiness agent also has cohesive strength, hollowing does not appear, the phenomenon come off.
In order to address the above problem, the technical solution adopted in the present invention is as follows: a kind of neutral mosaic tackiness agent, it is a kind of neutral gum stick of gypsum base, by gypsum, quartz sand, water-holding agent, redispersible latex powder, retardant, water reducer, formed, in formula, each component concentration contains the kg number of this component in adhesive products per ton, as follows:
Gypsum 480-800
Quartz sand 180-500
Water-holding agent 0.5-5
Redispersible latex powder 5-30
Retardant 0.5-5
Water reducer 0.5-5.
The preferred ingredient proportioning is as follows, and each component concentration is the kg number containing this component in adhesive products per ton:
Gypsum 500-700
Quartz sand 280-480
Water-holding agent 1.5-4
Redispersible latex powder 12-26
Retardant 1.2-4.2
Water reducer 0.8-4.
Described gypsum is one or both in dehydrated gyp-, semi-hydrated gypsum, dihydrate gypsum, and preferably whiteness is the 85-95 degree.
Described quartz sand particle size is the 60-200 order, and preferably whiteness is the 85-90 degree.
Described water-holding agent is hydroxypropyl methyl cellulose ether or the hydroxyethyl ether cellulose that viscosity is 2500-75000mPas.
Described redispersible latex powder is ethylene-vinyl acetate copolymer or copolymer in cinnamic acrylic ester.
Described retardant is one or both in Trisodium Citrate, Sunmorl N 60S.
Described water reducer is one or both in poly carboxylic acid series water reducer, amino high efficiency water reducing agent, preferably polycarboxylate high performance water-reducing agent or amino high efficiency water reducing agent.
Neutral mosaic tackiness agent of the present invention adopts the following methods preparation: first according to proportion speed weighing gypsum, quartz sand, water-holding agent, redispersible latex powder, retardant, water reducer, hand operated mixing mixes in advance, put into again the cement mortar mixer of the planetary cement mortar mixer of JC/T681-2005 or other applicable models, stirring at low speed, stir 10-20 minute, until mix, can obtain the tackiness agent powder.
The present invention is as follows with respect to the beneficial effect of prior art:
(1) the present invention be directed to the technical problem that glass Mosaic adopts cement or cement-based adhesive to exist, select the gypsum place of cement as main gelling material: the gypsum main component is calcium sulfate, it is a kind of air-setting inorganic coagulation material of neutrality, using the main raw of gypsum as the glass Mosaic tackiness agent, when application, tackiness agent pH value is 7, be neutral, therefore, adopt this neutral tackiness agent to paste mosaic, not there will be the alkaline matter after similar traditional hydrated cementitious to cause the problems such as mosaic oxidation blackening, the accumulation of salt in the surface soil;
(2) gypsum is a kind of white powder material, the whiteness scope is at the 85-95 degree, higher than general white cement whiteness 75-85 degree, the present invention's formula be take gypsum as main volume, preferably adopt the gypsum of whiteness scope at the 85-95 degree, adopt particle diameter 60-200 order simultaneously, the quartz sand that whiteness is the 85-90 degree, its whiteness of selected gypsum and quartz sand is all higher than traditional, white cement for tackiness agent, can make by the present invention fill a prescription the preparation tackiness agent there is high whiteness, during for the stickup of mosaic, decorative effect is good, especially at glass Mosaic, metal mosaic etc. this type of will embody the construction of mosaic material of its beautiful decorative effect the time, need background color bright, adopt mosaic tackiness agent of the present invention can reach the purpose that sets off the color of mosaic material own, obtain more excellent decorative effect,
(3) traditional sticking glass mosaic material is cement or sand-cement slurry, during construction, be arbitrarily to add at the construction field (site) water to use, can cause the mosaic of fritter the situations such as bonding is not firm, come off to occur, and neutral mosaic tackiness agent of the present invention is to form by meticulous configuration, adopt the high quartz sand of selected high-quality whiteness, in conjunction with water-holding agent, retardant and water reducer, can improve cohesive strength, operable time and the set time of material, after being used for pasting mosaic, the phenomenon such as hollowing do not occur, come off.
Neutral mosaic tackiness agent of the present invention is suitable for the stickup of ceramic tile, mosaic, is particularly useful for glass Mosaic indoor
Stickup.Basic construction requirement during construction, construction process are as follows:
(1) all basal planes structurally must be firm, and drying is clean and without movement, oils, grease, paraffin and other fouling productss; The paint basal plane must expose the clean basal plane more than at least 75%;
(2) prepare neutral mosaic tackiness agent powder according to formula of the present invention and preparation method, add the clear water that accounts for powder quality 30%-35%, be stirred well to even without the caking paste by electric blender by tackiness agent and water;
(3) behind the standing 5-10 of tackiness agent minute after stirring, then stir a little 1-2 minute, can use;
(4) with suitable notched scraper, the tackiness agent rubber cement is criticized and scraped on working face, coating evenly;
(5) rub the pressure mosaic, guarantee that mosaic and tackiness agent have better stickup and hollowing does not occur under mosaic;
(6) wipe with sponge or wet cloth the adhesive material that the mosaic surface stays;
(7) neutral mosaic tackiness agent was pasted after 2 days, can arrange joint filling, and the concrete time is looked weather, execution conditions are different and appropriately adjust.
Embodiment
Below by embodiment, the present invention is described in further details, these embodiment only are used for illustrating the present invention, do not limit the scope of the invention.
embodiment 1prepare neutral mosaic tackiness agent of the present invention by following formula:
(1) press the following material of proportion speed weighing: the dehydrated gyp-500kg of whiteness 95, particle diameter is 180 orders, whiteness 85
Quartz sand 480 kg, Vltra tears 1.5 kg that viscosity is 2500mPas, ethylene-vinyl acetate copolymer 14.5 kg, Trisodium Citrate 2.5kg, high performance water reducing agent of polyocarboxy acid 1.5 kg;
(2) by the hand operated mixing mixing in advance of above-mentioned load weighted material, then put into the planetary cement mortar mixer stirring at low speed of JC/T681-2005, stir 15 minutes, until mix.
Tackiness agent powder to above-mentioned preparation carries out the performance index detection, as shown in the table:
Sequence number Interventions Requested Measure unit Assay
1 Outward appearance / Homogeneous, dry powder, without caking
2 PH value / 7.3
3 Operable time h 2
4 Presetting period min 110
5 Final setting time min 330
6 The stretching adhesive strength MPa 0.58
7 Open assembly time, 20min stretching adhesive strength MPa 0.54
embodiment 2adopt following formula preparation neutral mosaic tackiness agent of the present invention:
(1) by the following material of proportion speed weighing: quartz sand 280 kg that semi-hydrated gypsum 780 kg of whiteness 85, particle diameter are 120 orders, whiteness 85, hydroxyethyl ether cellulose 4 kg that viscosity is 5000mPas, copolymer in cinnamic acrylic ester 12 kg, Trisodium Citrate 2 kg, amino high efficiency water reducing agent 2kg;
(2) by the hand operated mixing mixing in advance of above-mentioned load weighted material, then put into cement mortar mixer, stirring at low speed, stir 10 minutes, until mix.
embodiment 3adopt following formula preparation neutral mosaic tackiness agent of the present invention:
(1) press the following material of proportion speed weighing: dehydrated gyp-650 kg of whiteness 95, particle diameter is 200 orders, whiteness 88
Quartz sand 321 kg, Vltra tears 1 kg that viscosity is 75000mPas, ethylene-vinyl acetate copolymer 26 kg, Sunmorl N 60S 1.2 kg, high performance water reducing agent of polyocarboxy acid 0.8 kg;
(2) by the hand operated mixing mixing in advance of above-mentioned load weighted material, then put into the planetary cement mortar mixer stirring at low speed of JC/T681-2005, stir 18 minutes, until mix.
embodiment 4adopt following formula preparation neutral mosaic tackiness agent of the present invention:
(1) press the following material of proportion speed weighing: dihydrate gypsum 800 kg of whiteness 85, particle diameter is 60 orders, whiteness 90
Quartz sand 180 kg, hydroxyethyl ether cellulose 2 kg that viscosity is 50000mPas, copolymer in cinnamic acrylic ester 14.4 kg, Sunmorl N 60S 1.8kg, amino high efficiency water reducing agent 1.8 kg;
(2) by the hand operated mixing mixing in advance of above-mentioned load weighted material, then put into the planetary cement mortar mixer stirring at low speed of JC/T681-2005, stir 20 minutes, until mix.
embodiment 5adopt following formula preparation neutral mosaic tackiness agent of the present invention:
(1) press the following material of proportion speed weighing: semi-hydrated gypsum 160 kg of whiteness 88,, the dehydrated gyp-320kg of whiteness 90,
Quartz sand 500 kg that particle diameter is 160 orders, whiteness 85, Vltra tears 5 kg that viscosity is 5000mPas, copolymer in cinnamic acrylic ester 6.8 kg, Trisodium Citrate 3 kg, Sunmorl N 60S 1.2 kg, high performance water reducing agent of polyocarboxy acid 4 kg;
(2) by the hand operated mixing mixing in advance of above-mentioned load weighted material, then put into cement mortar mixer, stirring at low speed, stir 14 minutes, until mix.

Claims (8)

1. a neutral mosaic tackiness agent, it is characterized in that: the neutral gum stick that is a kind of gypsum base, gypsum, quartz sand, water-holding agent, redispersible latex powder, retardant, water reducer, consist of, in formula, each component concentration contains the kg number of this component in adhesive products per ton, as follows:
Gypsum 480-800
Quartz sand 180-500
Water-holding agent 0.5-5
Redispersible latex powder 5-30
Retardant 0.5-5
Water reducer 0.5-5.
2. neutral mosaic tackiness agent according to claim 1, it is characterized in that: the neutral gum stick that is a kind of gypsum base, by gypsum, quartz sand, water-holding agent, redispersible latex powder, retardant, water reducer, formed, in formula, each component concentration contains the kg number of this component in adhesive products per ton, as follows:
Gypsum 500-700
Quartz sand 280-480
Water-holding agent 1.5-4
Redispersible latex powder 12-26
Retardant 1.2-4.2
Water reducer 0.8-4.
3. neutral mosaic tackiness agent according to claim 1 and 2, it is characterized in that: described gypsum is one or both in dehydrated gyp-, semi-hydrated gypsum, dihydrate gypsum, its whiteness is the 85-95 degree.
4. neutral mosaic tackiness agent according to claim 1 and 2, it is characterized in that: described quartz sand particle size is the 60-200 order, whiteness is the 85-90 degree.
5. neutral mosaic tackiness agent according to claim 1 and 2, it is characterized in that: described water-holding agent is hydroxypropyl methyl cellulose ether or the hydroxyethyl ether cellulose that viscosity is 2500-75000mPas.
6. neutral mosaic tackiness agent according to claim 1 and 2, it is characterized in that: described redispersible latex powder is ethylene-vinyl acetate copolymer or copolymer in cinnamic acrylic ester.
7. neutral mosaic tackiness agent according to claim 1 and 2, it is characterized in that: described retardant is one or both in Trisodium Citrate, Sunmorl N 60S.
8. neutral mosaic tackiness agent according to claim 1 and 2, it is characterized in that: described water reducer is one or both in poly carboxylic acid series water reducer, amino water reducer.
CN201310414327.9A 2013-09-12 2013-09-12 Neutral mosaic adhesive Active CN103482946B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN103482946B CN103482946B (en) 2015-04-22

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104072076A (en) * 2014-06-30 2014-10-01 孙红芳 Surface layer grinding gypsum powder
CN104086148A (en) * 2014-06-30 2014-10-08 孙红芳 Bottom plastering gypsum powder

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1955242A (en) * 2005-10-19 2007-05-02 辽宁石油化工大学 Dry Powder Colored Tile Adhesive
CN101172795A (en) * 2007-10-30 2008-05-07 南京一夫建材实业有限公司 Alpha type high-strength gypsum cementing agent
CN102838337A (en) * 2012-09-04 2012-12-26 同济大学 Desulfurized gypsum based functional mortar for coating and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1955242A (en) * 2005-10-19 2007-05-02 辽宁石油化工大学 Dry Powder Colored Tile Adhesive
CN101172795A (en) * 2007-10-30 2008-05-07 南京一夫建材实业有限公司 Alpha type high-strength gypsum cementing agent
CN102838337A (en) * 2012-09-04 2012-12-26 同济大学 Desulfurized gypsum based functional mortar for coating and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104072076A (en) * 2014-06-30 2014-10-01 孙红芳 Surface layer grinding gypsum powder
CN104086148A (en) * 2014-06-30 2014-10-08 孙红芳 Bottom plastering gypsum powder
CN104086148B (en) * 2014-06-30 2016-05-18 孙红芳 Bottom layer brushing gypsum powder

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