CN105218024A - A kind of ceramic tile bond - Google Patents
A kind of ceramic tile bond Download PDFInfo
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- CN105218024A CN105218024A CN201510627201.9A CN201510627201A CN105218024A CN 105218024 A CN105218024 A CN 105218024A CN 201510627201 A CN201510627201 A CN 201510627201A CN 105218024 A CN105218024 A CN 105218024A
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Abstract
The invention discloses a kind of ceramic tile bond, it is characterized in that, comprise the dry-mix additive of the inorganic coagulation material of 30 ~ 40 weight parts, the anionic additive of 5 ~ 10 weight parts, the filler of 5 ~ 10 weight parts, the sand of 35 ~ 60 weight parts and 2 ~ 4 weight parts.The negative ion type ceramic tile adhesive with the three-in-one function of bonding, waterproof and joint filling provided by the invention, the permanence of bonding is improve in construction, effectively avoid ceramic tile hollowing obscission, ensure stability and the Practical Project demand of stickup, and the release in use not only with good water resistance and obnoxious flavour is lower than national standard, and negative ion can also be gone out by sustained release, remove the indoor toxic and harmful such as formaldehyde, phenol, purify the air of a room, improve indoor living environment, the living space of nature environmental protection is provided.
Description
Technical field
The invention belongs to matrix material technical field in building trade, particularly relate to a kind of ceramic tile bond.
Background technology
Along with the continuous lifting of people's quality of life, the paving materials such as building house also become increasingly abundant colorful.In numerous paving material, the most frequently used no more than ceramic tile, it is with fire-resistant metal oxide and half-metal oxide, via the process of grinding, mixing, compacting, glazing, sintering, and a kind of porcelain of acid and alkali-resistance formed or the building of stone matter or finishing material, its starting material are many to be mixed by clay, quartz sand etc.
In numerous standards of ceramic tile, water-intake rate is one of major criterion affecting application aspect, and what water-intake rate was high is often used for wall brick, and water-intake rate low be generally used for floor tile, especially the ground in the space such as kitchen, toilet then needs lower water-intake rate.In national standard, the water-intake rate of porcelain brick is less than or equal to 0.5%; The water-intake rate of Shi porcelain is greater than 0.5% and is less than or equal to 3%; The water-intake rate of thin Shi matter is greater than 3% and is less than or equal to 6%; The water-intake rate of Shi matter brick is greater than 6% and is less than or equal to 10%; And the water-intake rate of pottery brick is greater than 10%, in usual industry, ceramic tile low for water-intake rate is called waterproof ceramic tile.
But in actual applications, also have a prior aspect can not be ignored, it can directly affect waterproof, stability, outward appearance and environmental protection etc., and that is exactly the matrix material of ceramic tile.The mode of traditional tile bonding many employings sand-cement slurry, but the cohesive force of this mortar is weak, poor durability, easily peel off, and adopt the mode of stirring and thick-layer construction, proportioning is unstable, affect the weather resistance of ceramic tile, waste raw material, also affect speed of application, contaminate environment, its security can not be guaranteed, and is easy to occur security incident.
Thus, ceramic tile bond arises at the historic moment, it is also called glue for tile or tile adhesives, be mainly used in the finishing material such as sticking brick, face brick, floor tile, be widely used in the facing decoration places of the buildings such as inside and outside metope, ground, bathroom, kitchen, its principal feature is simple to operate, easy construction, and water-retentivity is good; Cohesive strength is high, and conformance is good, working efficiency high; Having good water-fast, heatproof, water proof anti-seepage, freeze-thawing resistant, cold-hot acute degeneration and good ageing resistance, is a kind of matrix material of ideal replacement traditional cement mortar.Ceramic tile bond can improve the bonding strength between finishing material and base material significantly, resistant slide, have good water-fast, acid and alkali-resistance and ageing-resistant performance, the test that can stand alternation of wetting and drying and cold and heat succeed each other, thoroughly solves directly by all drawbacks that cement is pasted.
Continuous expansion along with market and the further pursuit to quality, the specification of quality of ceramic tile bond and function are also improved further, but also will meet people aesthetic while, avoid because finishing causes indoor pollution to affect the problem of HUMAN HEALTH, improve the feature of environmental protection of indoor building material, be even of value to HUMAN HEALTH etc.
Thus, how can find a kind of better ceramic tile bond, while making ceramic tile bond have bonding, waterproof and joint filling function, can also be of value to HUMAN HEALTH, be one of manufacturer's problem demanding prompt solution in field always.
Summary of the invention
In view of this, the technical problem to be solved in the present invention is to provide a kind of ceramic tile bond, i.e. a kind of negative ion type ceramic tile adhesive, and ceramic tile bond provided by the invention, while having bonding, waterproof and joint filling function, can also be of value to HUMAN HEALTH.
The invention discloses a kind of ceramic tile bond, it is characterized in that, comprising:
Preferably, described inorganic gel materials is one or more in silicate cement, aluminate cement and aluminosulfate cement.
Preferably, described anionic additive is one or more in tourmalinite, opal and astroies.
Preferably, described filler is one or more in water-ground limestone, flyash and silica powder;
Described sand is washed-out sand and/or quartz sand.
Preferably, described dry-mix additive comprises redispersable latex powder, water-retaining admixture, superplasticizer and auxiliary agent.
Preferably, the weight part that in described dry-mix, each component accounts for described ceramic tile bond is:
Preferably, described redispersable latex powder is one or more in the multipolymer of the multipolymer of vinyl acetate between to for plastic and ethene, vinylbenzene and acrylate and acrylate copolymer.
Preferably, described water-retaining admixture is hydroxypropyl methyl cellulose ether and/or ethoxyl methyl cellulose ether.
Preferably, described superplasticizer is polycarboxylate and/or trimeric cyanamide.
Preferably, described auxiliary agent comprises thixotropic lubricant and hardening accelerator;
Described thixotropic lubricant is one or more in starch ethers, modified alta-mud and neusilin;
Described hardening accelerator is one or more in calcium formiate, calcium chloride and sodium sulfate.
The invention discloses a kind of ceramic tile bond, it is characterized in that, comprise the dry-mix additive of the inorganic coagulation material of 30 ~ 40 weight parts, the anionic additive of 5 ~ 10 weight parts, the filler of 5 ~ 10 weight parts, the sand of 35 ~ 60 weight parts and 2 ~ 4 weight parts.Compared with prior art, the present invention adds the anionic additive of specified proportion at ceramic tile bond, each component formula of inorganic coagulation material and overall specified proportion, make ceramic tile bond provided by the invention when having bonding and joint filling function, also possess water resistance, and after adding anionic additive, made a kind of environment-friendly materials that can continue to produce negative ion, negative ion there is more beneficial functions, especially oxidation-resistance give prominence to.The negative ion type ceramic tile adhesive with the three-in-one function of bonding, waterproof and joint filling provided by the invention, the permanence of bonding is improve in construction, effectively avoid ceramic tile hollowing obscission, ensure stability and the Practical Project demand of stickup, and the release in use not only with good water resistance and obnoxious flavour is lower than national standard, and negative ion can also be gone out by sustained release, remove the indoor toxic and harmful such as formaldehyde, phenol, purify the air of a room, improve indoor living environment, the living space of nature environmental protection is provided.
Experimental result shows, ceramic tile bond prepared by the present invention, and the gluing former intensity that stretches can reach 1.05MPa, and thermal ageing cohesive strength can reach 0.62MPa, and hanging the stretching adhesive strength after 20min can reach 0.80MPa; Free formaldehyde is lower than 0.04g/kg, and the negative ion quantity of release can reach 2830/m
3.Ceramic tile bond provided by the invention is a kind of indoor decorating field being applicable to house, school, market, the three-in-one negative ion type material of construction of environment protection health, more can meet people for environmental protection and healthy requirement.
Embodiment
In order to understand the present invention further, below in conjunction with embodiment, the preferred embodiments of the invention are described, but should be appreciated that these describe just as further illustrating the features and advantages of the present invention instead of the restriction to patent requirements of the present invention.
The all raw materials of the present invention, be not particularly limited its source, commercially buy or prepare according to ordinary method well known to those skilled in the art.
The all raw materials of the present invention, be not particularly limited its purity, the present invention preferably adopts analytical pure.
The invention discloses a kind of ceramic tile bond, it is characterized in that, comprising:
The present invention is not particularly limited described ceramic tile, with ceramic tile well known to those skilled in the art, can be one or more in porcelain brick, Shi ceramic tile, fine stoneware tile, Shi matter brick or pottery brick, also can for there is water-proof function or not there is water-proof function, the present invention, for better to embody waterproof effect, preferably has the waterproof ceramic tile of water-proof function.
In ceramic tile bond of the present invention, the add-on of described inorganic coagulation material is preferably 30 ~ 40 weight parts, is more preferably 32 ~ 38 weight parts, most preferably is 34 ~ 36 weight parts; The concrete selection of the present invention to described inorganic coagulation material is not particularly limited, with inorganic coagulation material well known to those skilled in the art; The present invention is for improving bond effect, described inorganic coagulation material is preferably one or more the above mixtures in silicate cement, aluminate cement, aluminosulfate cement, be more preferably silicate cement or ordinary Portland cement, most preferably being strength grade must not lower than the silicate cement of P.O42.5 or P.II42.5.When the present invention is the mixture of multiple above-mentioned cement to described inorganic gel materials, its concrete blending ratio is not particularly limited, with blending ratio well known to those skilled in the art, those skilled in the art can adjust according to product requirement, service requirements and mixing requirement.The present invention is in order to reach object hard soon, can select ordinary Portland cement and, any one composite use in aluminate cement or aluminosulfate cement, also can be used alone aluminate cement or aluminosulfate cement, thus improve the quick bond effect of tackiness agent, also improve bonding hardness simultaneously.
In ceramic tile bond of the present invention, the add-on of described anionic additive is preferably 5 ~ 10 weight parts, is more preferably 6 ~ 9 weight parts, most preferably is 7 ~ 8 weight parts; The concrete selection of the present invention to described anionic additive is not particularly limited, with anionic additive well known to those skilled in the art; The present invention be ensure negative ion release performance and and binding agent between composite, described anionic additive is preferably nano-negative ion additive, is more preferably the nano-negative ion additive prepared by one or more raw materials in tourmalinite, opal and astroies; When the present invention is the mixture of multiple above-mentioned raw materials to described anionic additive, its concrete blending ratio is not particularly limited, and those skilled in the art can adjust according to product requirement, service requirements and mixing requirement.Negative ion powder of the present invention is prepared by nanotechnology by natural materials, keeps energetic and have great help to the improvement of human residential environment to human body, natural, tasteless, nontoxic and safety performance is good.
In ceramic tile bond of the present invention, the add-on of described filler is preferably 5 ~ 10 weight parts, is more preferably 6 ~ 9 weight parts, most preferably is 7 ~ 8 weight parts; The concrete selection of the present invention to described filler is not particularly limited, with well known to those skilled in the art for the filler in ceramic tile bond, filler of the present invention is preferably mineral filler, be more preferably in water-ground limestone, flyash and silica powder one or more, be more preferably water-ground limestone, flyash or silica powder, most preferably be water-ground limestone or silica powder; The fineness of described filler is preferably 100 ~ 300 orders, is more preferably 180 ~ 280 orders, most preferably is 150 ~ 250 orders; When the present invention is the mixture of multiple above-mentioned raw materials to described filler, its concrete blending ratio is not particularly limited, and those skilled in the art can adjust according to product requirement, service requirements and mixing requirement.
In ceramic tile bond of the present invention, the add-on of described sand is preferably 35 ~ 60 weight parts, is more preferably 40 ~ 55 weight parts, most preferably is 45 ~ 50 weight parts; The concrete selection of the present invention to described sand is not particularly limited, with well known to those skilled in the art for the filler in ceramic tile bond; The present invention is the intensity improving binding agent, and described sand is preferably washed-out sand and/or quartz sand, is more preferably washed-out sand or quartz sand; The fineness of described sand is preferably 20 ~ 200 orders, is more preferably 30 ~ 180 orders, most preferably is 40 ~ 150 orders; When the present invention is the mixture of washed-out sand and quartz sand to described sand, its concrete blending ratio is not particularly limited, and those skilled in the art can adjust according to product requirement, service requirements and mixing requirement.Washed-out sand or quartz sand as the aggregate of Cementitious Adhesive, can effectively be limited the cubic deformation of the gelling material such as cement when aquation, and can significantly improve the cohesive strength of Cementitious Adhesive by the present invention, increase the bending and compressive strength of tackiness agent.
In ceramic tile bond of the present invention, the add-on of described dry-mix additive is preferably 2 ~ 4 weight parts, is more preferably 2.3 ~ 3.8 weight parts, most preferably is 2.5 ~ 3.5 weight parts; The concrete selection of the present invention to described dry-mix additive is not particularly limited, with dry-mix additive well known to those skilled in the art; The present invention is the waterproof and the bonding effect that better improve binding agent, and described dry-mix additive preferably includes redispersable latex powder, water-retaining admixture, superplasticizer and auxiliary agent.
In dry-mix additive of the present invention, each component accounts for the parts by weight in described three-in-one negative ion waterproof ceramic tile bond and is: redispersable latex powder is preferably 1.5 ~ 2.5 weight parts, be more preferably 1.6 ~ 2.4 weight parts, most preferably be 1.8 ~ 2.2 weight parts; Described water-retaining admixture is preferably 0.15 ~ 0.3 weight part, is more preferably 0.17 ~ 0.28 weight part, most preferably is 0.20 ~ 0.25 weight part; Described superplasticizer is preferably 0.05 ~ 0.20 weight part, is more preferably 0.07 ~ 0.18 weight part, most preferably is 0.10 ~ 0.15 weight part; Described auxiliary agent is preferably 0.10 ~ 0.80 weight part, is more preferably 0.20 ~ 0.60 weight part, most preferably is 0.30 ~ 0.50 weight part.
The concrete composition of the present invention to described redispersable latex powder is not particularly limited, with redispersable latex powder well known to those skilled in the art, the present invention be preferably in vinyl acetate between to for plastic and ethylene copolymer, acrylate copolymer, vinylbenzene and acrylate copolymer one or more, be more preferably the multipolymer of vinyl acetate between to for plastic and ethene, acrylate copolymer, and the one in the multipolymer of vinylbenzene and acrylate; If those skilled in the art are from the viewpoint of adhesive durability, most preferably acrylate copolymer can be used; When the present invention is the mixture of above-mentioned polymkeric substance to described redispersable latex powder, its concrete blending ratio is not particularly limited, and those skilled in the art can adjust according to product requirement, service requirements and mixing requirement.The present invention using redispersable latex powder as one of component in dry-mix additive, it is a kind of high molecular polymer, the effective film forming of energy in Cementitious Adhesive, reduce Young's modulus, the rigidity of modified cement, improves the force of cohesion of mortar, increases stopping property and the water-repellancy of mortar, snappiness and the deformability of mortar can be improved simultaneously, and effectively improve application property.
The concrete composition of the present invention to described water-retaining admixture is not particularly limited, with water-retaining admixture well known to those skilled in the art, the present invention be preferably in hydroxypropyl methyl cellulose ether and ethoxyl methyl cellulose ether one or both, be more preferably hydroxypropyl methyl cellulose ether or ethoxyl methyl cellulose ether; The viscosity of described water-retaining admixture is preferably 30000 ~ 120000mPas, is more preferably 35000 ~ 11000mPas, most preferably is 40000 ~ 100000mPas; When the present invention is the mixture of above-mentioned two kinds of ether of cellulose to described water-retaining admixture, its concrete blending ratio is not particularly limited, and those skilled in the art can adjust according to product requirement, service requirements and mixing requirement.The present invention using water-retaining admixture as one of component in dry-mix additive, it can play water conservation, thickening, bleed, the effect of prolongation open hour, can effectively prevent mortar segregation layering, and can moisture be kept, the water needed for gelling gel material aquation such as cement is provided, can application property be significantly improved simultaneously.
The concrete composition of the present invention to described superplasticizer is not particularly limited, with superplasticizer well known to those skilled in the art, the present invention be preferably in polycarboxylate and trimeric cyanamide one or both, be more preferably polycarboxylate or trimeric cyanamide; When the present invention is the mixture of above-mentioned bi-material to described superplasticizer, its concrete blending ratio is not particularly limited, and those skilled in the art can adjust according to product requirement, service requirements and mixing requirement.The present invention is using superplasticizer as one of component in dry-mix additive, and it is as tensio-active agent, significantly can reduce the water consumption of mortar, reduces water cement ratio, improves degree of compactness and the intensity of mortar, improves the degree of mobilization of mortar, improve the application property of mortar.Particularly the present invention introduces a large amount of low modulus, protruded packing in adhesive formulation system, considerable influence is had to cohesive strength and pressure-proof and snap-resistent intensity, add superplasticizer in formula and reduce the object that water cement ratio can reach raising intensity, improve cohesive strength and the ultimate compression strength of bonding.
The concrete composition of the present invention to described auxiliary agent is not particularly limited, with well known to those skilled in the art for the auxiliary agent in dry-mix additive, the present invention be preferably in thixotropic lubricant and hardening accelerator one or both, be more preferably thixotropic lubricant or hardening accelerator; Described thixotropic lubricant is preferably one or more the mixture in starch ethers, modified alta-mud and neusilin, is more preferably starch ethers, modified alta-mud or neusilin, most preferably is modified alta-mud or neusilin; Described hardening accelerator is preferably one or more the mixture in calcium formiate, calcium chloride and sodium sulfate, is more preferably calcium formiate, calcium chloride or sodium sulfate, most preferably is calcium formiate or sodium sulfate; The concrete ratio of the present invention to thixotropic lubricant in described auxiliary agent and hardening accelerator is not particularly limited, and those skilled in the art can adjust according to product requirement, service requirements and mixing requirement; When the present invention is the mixture of above-mentioned different materials to described thixotropic lubricant, its concrete blending ratio is not particularly limited, and those skilled in the art can adjust according to product requirement, service requirements and mixing requirement; When the present invention is the mixture of above-mentioned different materials to described hardening accelerator, its concrete blending ratio is not particularly limited, and those skilled in the art can adjust according to product requirement, service requirements and mixing requirement.The present invention is using auxiliary agent as one of component in dry-mix additive, and described thixotropic lubricant can improve the Construction State of mortar, improves the slipping of construction, and has very strong anti-sag performance.Described hardening accelerator effectively can accelerate the aquation of cement Minerals, shortens the time of coagulation of sand-cement slurry, makes to arrive final strength in the mortar short period.
The negative ion type ceramic tile adhesive with the three-in-one function of bonding, waterproof and joint filling provided by the invention, the permanence of bonding is improve in construction, effectively avoid ceramic tile hollowing obscission, ensure stability and the Practical Project demand of stickup, and the release in use not only with good water resistance and obnoxious flavour is lower than national standard, and negative ion can also be gone out by sustained release, remove the indoor toxic and harmful such as formaldehyde, phenol, purify the air of a room, improve indoor living environment, the living space of nature environmental protection is provided.
The preparation method of the present invention to described three-in-one negative ion waterproof ceramic tile joint filling binding agent is not particularly limited, with the preparation process of tackiness agent well known to those skilled in the art, those skilled in the art can regulate voluntarily according to practical condition or product requirement, the present invention is by described inorganic coagulation material, anionic additive, filler, after sand and dry-mix additive mix according to the above ratio, obtain ceramic tile adhesive, if according to product service requirements or reach evenly mixing, also can by above-mentioned inorganic coagulation material, anionic additive, filler, after sand and dry-mix additive carry out according to the above ratio taking and mix with water, obtain ceramic tile adhesive, i.e. a kind of water-based matrix material.The additional proportion of the present invention to described water is not particularly limited, and with additional proportion well known to those skilled in the art, those skilled in the art can carry out Reasonable adjustment according to product service requirements, specification of quality or mixture homogeneity.The present invention is all not particularly limited the mode of described mixing, condition and equipment, with the mode of mixing well known to those skilled in the art, condition and equipment, the preferred hybrid mode of the present invention is for being uniformly mixed, and mixing temperature is preferably 20 ~ 30 DEG C, is more preferably 22 ~ 28 DEG C; Describedly be uniformly mixed the time and be preferably 15 ~ 30min, be more preferably 20 ~ 25min; The equipment of described mixing is preferably double-screw type dry-mix mixer.
The present invention obtains through above-mentioned steps has bonding, the negative ion type ceramic tile adhesive of waterproof and the three-in-one function of joint filling, product performance detection is carried out to its standard with reference to " ceramic wall and floor bricks tackiness agent " (JC/T547-2005), detected result shows, ceramic tile bond prepared by the present invention, the gluing former intensity that stretches can reach 1.05MPa, cohesive strength after immersion can reach 0.75Mpa, thermal ageing cohesive strength can reach 0.62MPa, early stage cohesive strength (24h) can reach 0.57MPa, slippage is minimum reaches 0.07mm, hang the stretching adhesive strength after 20min and can reach 0.80MPa, VOC content is minimum is 27g/L, and free formaldehyde is lower than 0.04g/kg, and the negative ion quantity of release can reach 2830/m
3.Ceramic tile bond provided by the invention is a kind of indoor decorating field being applicable to house, school, market, the three-in-one negative ion type material of construction of environment protection health, more can meet people for environmental protection and healthy requirement.
In order to understand the present invention further, be described negative ion type ceramic tile adhesive provided by the invention and preparation process thereof below in conjunction with embodiment, protection scope of the present invention is not limited by the following examples.
Embodiment 1
First, take by mass percentage the inorganic gel agent of 35%, 5% anionic additive, the mineral filler of 10%, the sand of 47% and 3% dry-mix additive, add a certain proportion of water.
Wherein, inorganic coagulation material is silicate cement, and anionic additive is tourmalinite, and mineral filler is fineness is 150 object silica powders, the mixture of to be 40 ~ 70 object washed-out sands and fineness be 70 ~ 140 object washed-out sands that sand is fineness;
The composition of dry-mix additive comprises: redispersable latex powder, water-retaining admixture, superplasticizer and auxiliary agent, and the mass percent of above-mentioned each component in described tackiness agent is respectively: the redispersable latex powder of 2%, the water-retaining admixture of 0.2%, 0.05% superplasticizer and 0.75% auxiliary agent.Wherein redispersable latex powder is vinyl acetate between to for plastic and ethylene copolymer, superplasticizer is the mixture of polycarboxylate and trimeric cyanamide, in auxiliary agent, thixotropic lubricant is starch ethers, in auxiliary agent, hardening accelerator is calcium formiate, and water-retaining admixture is hydroxypropyl methyl cellulose ether and the viscosity of water-retaining admixture is 40000mPas.
Then put in double-screw type dry-mix mixer by the above-mentioned each component taken, be uniformly mixed under the condition of 20 DEG C in temperature, churning time is after 15min, obtains ceramic tile adhesive.
The ceramic tile adhesive that above-mentioned steps is obtained, Performance Detection is carried out with reference to " ceramic wall and floor bricks tackiness agent " (JC/T547-2005) standard, detected result see table 1, the physical performance data of the three-in-one anion tile binding agent of table 1 prepared by the embodiment of the present invention 1 ~ 5.
Embodiment 2
First, take by mass percentage the inorganic gel agent of 30%, 10% anionic additive, the mineral filler of 5%, the sand of 51% and 4% dry-mix additive, add a certain proportion of water.
Wherein, inorganic coagulation material is aluminosulfate cement, anionic additive is mass ratio is the tourmalinite of 1:1 and opaline mixture, and mineral filler is fineness is 200 object flyash, the mixture of sand is fineness to be 40 ~ 70 object quartz sands and fineness be 70 ~ 140 object quartz sands;
The composition of dry-mix additive comprises: redispersable latex powder, water-retaining admixture, superplasticizer and auxiliary agent, and the mass percent of above-mentioned each component in described tackiness agent is respectively: the redispersable latex powder of 3.6%, the water-retaining admixture of 0.15%, 0.1% superplasticizer and 0.15% auxiliary agent.Wherein redispersable latex powder is acrylate copolymer, superplasticizer is polycarboxylate, in auxiliary agent, thixotropic lubricant is starch ethers, and in auxiliary agent, hardening accelerator is sodium sulfate, and water-retaining admixture is hydroxypropyl methyl cellulose ether and the viscosity of water-retaining admixture is 100000mPas.
Then put in double-screw type dry-mix mixer by the above-mentioned each component taken, be uniformly mixed under the condition of 30 DEG C in temperature, churning time is after 20min, obtains ceramic tile adhesive.
The ceramic tile adhesive that above-mentioned steps is obtained, Performance Detection is carried out with reference to " ceramic wall and floor bricks tackiness agent " (JC/T547-2005) standard, detected result see table 1, the physical performance data of the three-in-one anion tile binding agent of table 1 prepared by the embodiment of the present invention 1 ~ 5.
Embodiment 3
First, take by mass percentage the inorganic gel agent of 40%, 8% anionic additive, the mineral filler of 8%, the sand of 42% and 2% dry-mix additive, add a certain proportion of water.
Wherein, inorganic coagulation material is the mixture of silicate cement and aluminosulfate cement, anionic additive is mass ratio is the opal of 1:1 and the mixture of astroies, mineral filler is water-ground limestone, the mixture of sand is fineness to be 40 ~ 70 object quartz sands and fineness be 70 ~ 140 object quartz sands;
The composition of dry-mix additive comprises: redispersable latex powder, water-retaining admixture, superplasticizer and auxiliary agent, and the mass percent of above-mentioned each component in described tackiness agent is respectively: the redispersable latex powder of 1%, the water-retaining admixture of 0.25%, 0.2% superplasticizer and 0.555% auxiliary agent.Wherein redispersable latex powder is vinylbenzene and acrylate copolymer, superplasticizer is trimeric cyanamide, in auxiliary agent, thixotropic lubricant is starch ethers, and in auxiliary agent, hardening accelerator is calcium chloride, and water-retaining admixture is ethoxyl methyl cellulose ether and the viscosity of water-retaining admixture is 50000mPas.
Then put in double-screw type dry-mix mixer by the above-mentioned each component taken, be uniformly mixed under the condition of 25 DEG C in temperature, churning time is after 25min, obtains ceramic tile adhesive.
The ceramic tile adhesive that above-mentioned steps is obtained, Performance Detection is carried out with reference to " ceramic wall and floor bricks tackiness agent " (JC/T547-2005) standard, detected result see table 1, the physical performance data of the three-in-one anion tile binding agent of table 1 prepared by the embodiment of the present invention 1 ~ 5.
Embodiment 4
First, take by mass percentage the inorganic gel agent of 37%, 6% anionic additive, the mineral filler of 8%, the sand of 45.5% and 3.5% dry-mix additive, add a certain proportion of water.
Wherein, inorganic coagulation material is the mixture of silicate cement and aluminate cement, anionic additive is opal, mineral filler is mass ratio is the water-ground limestone of 1:1 and the mixture of flyash, the mixture of to be 40 ~ 70 object washed-out sands and fineness be 70 ~ 140 object washed-out sands that sand is fineness;
The composition of dry-mix additive comprises: redispersable latex powder, water-retaining admixture, superplasticizer and auxiliary agent, and the mass percent of above-mentioned each component in described tackiness agent is respectively: the redispersable latex powder of 2.3%, the water-retaining admixture of 0.3%, 0.1% superplasticizer and 0.8% auxiliary agent.Wherein redispersable latex powder is acrylate copolymer, superplasticizer is polycarboxylate, in auxiliary agent, thixotropic lubricant is the mixture of modified alta-mud and neusilin, in auxiliary agent, hardening accelerator is mass ratio is the calcium formiate of 1:1 and the mixture of calcium chloride, and water-retaining admixture is hydroxypropyl methyl cellulose ether and the viscosity of water-retaining admixture is 60000mPas.
Then put in double-screw type dry-mix mixer by the above-mentioned each component taken, be uniformly mixed under the condition of 30 DEG C in temperature, churning time is after 30min, obtains ceramic tile adhesive.
The ceramic tile adhesive that above-mentioned steps is obtained, Performance Detection is carried out with reference to " ceramic wall and floor bricks tackiness agent " (JC/T547-2005) standard, detected result see table 1, the physical performance data of the three-in-one anion tile binding agent of table 1 prepared by the embodiment of the present invention 1 ~ 5.
Embodiment 5
First, take by mass percentage the inorganic gel agent of 40%, the mineral filler of 11%, the sand of 45.5% and 3.5% dry-mix additive, add a certain proportion of water.
Wherein, inorganic coagulation material is the mixture of silicate cement and aluminate cement, anionic additive is opal, mineral filler is mass ratio is the water-ground limestone of 1:1 and the mixture of flyash, the mixture of to be 40 ~ 70 object washed-out sands and fineness be 70 ~ 140 object washed-out sands that sand is fineness;
The composition of dry-mix additive comprises: redispersable latex powder, water-retaining admixture, superplasticizer and auxiliary agent, and the mass percent of above-mentioned each component in described tackiness agent is respectively: the redispersable latex powder of 2.3%, the water-retaining admixture of 0.3%, 0.1% superplasticizer and 0.8% auxiliary agent.Wherein redispersable latex powder is acrylate copolymer, superplasticizer is polycarboxylate, in auxiliary agent, thixotropic lubricant is the mixture of modified alta-mud and neusilin, in auxiliary agent, hardening accelerator is mass ratio is the calcium formiate of 1:1 and the mixture of calcium chloride, and water-retaining admixture is hydroxypropyl methyl cellulose ether and the viscosity of water-retaining admixture is 60000mPas.
Then put in double-screw type dry-mix mixer by the above-mentioned each component taken, be uniformly mixed under the condition of 30 DEG C in temperature, churning time is after 30min, obtains ceramic tile adhesive.
The ceramic tile adhesive that above-mentioned steps is obtained, Performance Detection is carried out with reference to " ceramic wall and floor bricks tackiness agent " (JC/T547-2005) standard, detected result see table 1, the physical performance data of the three-in-one anion tile binding agent of table 1 prepared by the embodiment of the present invention 1 ~ 5.
The physical performance data of the three-in-one negative ion waterproof ceramic tile joint filling binding agent prepared by table 1 embodiment of the present invention 1 ~ 5
As known from Table 1, three-in-one negative ion waterproof ceramic tile joint filling binding agent provided by the invention, the all properties index of C1 glue for tile in JC/T547-2005 " ceramic wall and floor bricks binding agent " can not only be met, and have good green tensile cohesive strength, original with hang the cohesive strength etc. after 20min, this shows that the present invention has excellent over-all properties in bonding, waterproof and joint filling etc.And tile adhesives prepared by the present invention is in use, also there is lower VOC and free formaldehyde content, and can sustained release negative ion, play and purify air, the effect of environmental protect.In addition, negative ion material add the performance also not affecting overall ceramic tile bond.
Energy sustained release provided by the invention go out negative ion, remove the indoor toxic and harmful such as formaldehyde, phenol, purify the air of a room, improve indoor living environment, the living space of nature environmental protection is provided, being applicable to the indoor decorating field in house, school, market, is a kind of negative ion type material of construction of environment protection health.
Above a kind of ceramic tile bond provided by the present invention is described in detail.Apply a concrete example herein to set forth principle of the present invention and embodiment, the explanation of above embodiment just understands method of the present invention and core concept thereof for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improve and modify and also fall in the protection domain of the claims in the present invention.
Claims (10)
1. a ceramic tile bond, is characterized in that, comprising:
2. ceramic tile bond according to claim 1, is characterized in that, described inorganic gel materials is one or more in silicate cement, aluminate cement and aluminosulfate cement.
3. ceramic tile bond according to claim 1, is characterized in that, described anionic additive is one or more in tourmalinite, opal and astroies.
4. ceramic tile bond according to claim 1, is characterized in that, described filler is one or more in water-ground limestone, flyash and silica powder;
Described sand is washed-out sand and/or quartz sand.
5. ceramic tile bond according to claim 1, is characterized in that, described dry-mix additive comprises redispersable latex powder, water-retaining admixture, superplasticizer and auxiliary agent.
6. ceramic tile bond according to claim 5, is characterized in that, in described dry-mix, each component accounts for the weight part of described ceramic tile bond and is:
7. ceramic tile bond according to claim 5, is characterized in that, described redispersable latex powder is one or more in the multipolymer of the multipolymer of vinyl acetate between to for plastic and ethene, vinylbenzene and acrylate and acrylate copolymer.
8. ceramic tile bond according to claim 5, is characterized in that, described water-retaining admixture is hydroxypropyl methyl cellulose ether and/or ethoxyl methyl cellulose ether.
9. ceramic tile bond according to claim 5, is characterized in that, described superplasticizer is polycarboxylate and/or trimeric cyanamide.
10. ceramic tile bond according to claim 5, is characterized in that, described auxiliary agent comprises thixotropic lubricant and hardening accelerator;
Described thixotropic lubricant is one or more in starch ethers, modified alta-mud and neusilin;
Described hardening accelerator is one or more in calcium formiate, calcium chloride and sodium sulfate.
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| CN201510627201.9A CN105218024A (en) | 2015-09-28 | 2015-09-28 | A kind of ceramic tile bond |
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| CN201510627201.9A CN105218024A (en) | 2015-09-28 | 2015-09-28 | A kind of ceramic tile bond |
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| CN105753407A (en) * | 2016-03-01 | 2016-07-13 | 山东金水岸环保科技有限公司 | Ceramic tile adhesive and construction method thereof |
| CN105837125A (en) * | 2016-04-28 | 2016-08-10 | 佛山市恒学科技服务有限公司 | Efficient tile adhesive |
| CN106007549A (en) * | 2016-06-24 | 2016-10-12 | 广德县中威新型材料有限公司 | Tile adhesive with good environmental suitability |
| CN106007598A (en) * | 2016-05-27 | 2016-10-12 | 河北绿藤再生资源利用有限公司 | Anion binder |
| CN106348688A (en) * | 2016-08-26 | 2017-01-25 | 派丽(上海)管理有限公司 | Low-elasticity tile adhesive |
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| CN107572911A (en) * | 2017-08-28 | 2018-01-12 | 上海前引科技有限公司 | A kind of antibacterial and mouldproof anion tile adhesive |
| CN108947436A (en) * | 2018-07-31 | 2018-12-07 | 合肥尚涵装饰工程有限公司 | Cement base underfill composition and its application |
| CN110240880A (en) * | 2019-05-22 | 2019-09-17 | 广州和新实业有限公司 | It is a kind of to discharge nail-free glue of anion and preparation method thereof |
| CN111154408A (en) * | 2020-01-10 | 2020-05-15 | 林培双 | Preparation method of antibacterial high-strength ceramic tile glue |
| CN111470824A (en) * | 2020-04-29 | 2020-07-31 | 江西易必居新型建材有限公司 | Negative ion environment-friendly ceramic tile back glue and preparation method thereof |
| CN112125631A (en) * | 2020-09-27 | 2020-12-25 | 广东粤固建材科技有限公司 | Damp-proof ceramic tile binder and preparation method thereof |
| CN112174622A (en) * | 2020-10-10 | 2021-01-05 | 广东粤固建材科技有限公司 | High-viscosity water-based tile adhesive and preparation method thereof |
| CN113533198A (en) * | 2021-07-26 | 2021-10-22 | 天津市建筑材料科学研究院有限公司 | Method for detecting adhesive property of back adhesive of ceramic facing brick |
| CN113716912A (en) * | 2021-07-12 | 2021-11-30 | 广东碧橙建材有限公司 | Negative ion ceramic tile glue |
| CN114477927A (en) * | 2022-01-26 | 2022-05-13 | 广州市凯聚新材料有限公司 | Ceramic tile bonding mortar material with waterproof function and tool used in cooperation with ceramic tile bonding mortar material |
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| CN105753407A (en) * | 2016-03-01 | 2016-07-13 | 山东金水岸环保科技有限公司 | Ceramic tile adhesive and construction method thereof |
| CN105837125A (en) * | 2016-04-28 | 2016-08-10 | 佛山市恒学科技服务有限公司 | Efficient tile adhesive |
| CN106007598A (en) * | 2016-05-27 | 2016-10-12 | 河北绿藤再生资源利用有限公司 | Anion binder |
| CN106007549A (en) * | 2016-06-24 | 2016-10-12 | 广德县中威新型材料有限公司 | Tile adhesive with good environmental suitability |
| CN106348688B (en) * | 2016-08-26 | 2018-08-07 | 派丽(上海)管理有限公司 | A kind of low elasticity glue for tile |
| CN106348688A (en) * | 2016-08-26 | 2017-01-25 | 派丽(上海)管理有限公司 | Low-elasticity tile adhesive |
| CN106365561A (en) * | 2016-08-31 | 2017-02-01 | 郭舒洋 | Preparation method of weather-resistance tile adhesion agent for exterior wall ceramic tiles |
| CN106630826A (en) * | 2016-12-15 | 2017-05-10 | 苏州市世好建材新技术工程有限公司 | High-performance mortar for ceramic tile |
| CN107555893A (en) * | 2017-08-16 | 2018-01-09 | 河北卓达建材研究院有限公司 | A kind of anion mortar of construction wall and preparation method thereof |
| CN107572911A (en) * | 2017-08-28 | 2018-01-12 | 上海前引科技有限公司 | A kind of antibacterial and mouldproof anion tile adhesive |
| CN107540311A (en) * | 2017-09-26 | 2018-01-05 | 杭州泽通建筑节能新材料有限公司 | A kind of autoclaved aerated concrete slab splices binding agent |
| CN108947436A (en) * | 2018-07-31 | 2018-12-07 | 合肥尚涵装饰工程有限公司 | Cement base underfill composition and its application |
| CN110240880A (en) * | 2019-05-22 | 2019-09-17 | 广州和新实业有限公司 | It is a kind of to discharge nail-free glue of anion and preparation method thereof |
| CN111154408A (en) * | 2020-01-10 | 2020-05-15 | 林培双 | Preparation method of antibacterial high-strength ceramic tile glue |
| CN111470824A (en) * | 2020-04-29 | 2020-07-31 | 江西易必居新型建材有限公司 | Negative ion environment-friendly ceramic tile back glue and preparation method thereof |
| CN111470824B (en) * | 2020-04-29 | 2022-02-18 | 江西星高新材料有限公司 | Negative ion environmental protection tile adhesive and preparation method thereof |
| CN112125631A (en) * | 2020-09-27 | 2020-12-25 | 广东粤固建材科技有限公司 | Damp-proof ceramic tile binder and preparation method thereof |
| CN112174622A (en) * | 2020-10-10 | 2021-01-05 | 广东粤固建材科技有限公司 | High-viscosity water-based tile adhesive and preparation method thereof |
| CN113716912A (en) * | 2021-07-12 | 2021-11-30 | 广东碧橙建材有限公司 | Negative ion ceramic tile glue |
| CN113533198A (en) * | 2021-07-26 | 2021-10-22 | 天津市建筑材料科学研究院有限公司 | Method for detecting adhesive property of back adhesive of ceramic facing brick |
| CN114477927A (en) * | 2022-01-26 | 2022-05-13 | 广州市凯聚新材料有限公司 | Ceramic tile bonding mortar material with waterproof function and tool used in cooperation with ceramic tile bonding mortar material |
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Application publication date: 20160106 |