CN103053530B - Bactericidal composition of propamidine and fluazinam - Google Patents
Bactericidal composition of propamidine and fluazinam Download PDFInfo
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- CN103053530B CN103053530B CN201310003441.2A CN201310003441A CN103053530B CN 103053530 B CN103053530 B CN 103053530B CN 201310003441 A CN201310003441 A CN 201310003441A CN 103053530 B CN103053530 B CN 103053530B
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- propamidine
- fluazinam
- bactericidal composition
- composition
- pathogen
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- 239000005780 Fluazinam Substances 0.000 title claims abstract description 48
- UZCGKGPEKUCDTF-UHFFFAOYSA-N fluazinam Chemical compound [O-][N+](=O)C1=CC(C(F)(F)F)=C(Cl)C([N+]([O-])=O)=C1NC1=NC=C(C(F)(F)F)C=C1Cl UZCGKGPEKUCDTF-UHFFFAOYSA-N 0.000 title claims abstract description 48
- WTFXJFJYEJZMFO-UHFFFAOYSA-N propamidine Chemical group C1=CC(C(=N)N)=CC=C1OCCCOC1=CC=C(C(N)=N)C=C1 WTFXJFJYEJZMFO-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 229960003761 propamidine Drugs 0.000 title claims abstract description 48
- 239000000203 mixture Substances 0.000 title claims abstract description 39
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 21
- 241000221662 Sclerotinia Species 0.000 claims abstract description 9
- 241001465180 Botrytis Species 0.000 claims abstract description 6
- 244000052769 pathogen Species 0.000 claims abstract description 6
- 230000001717 pathogenic effect Effects 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims description 9
- 238000009472 formulation Methods 0.000 claims description 8
- 239000000375 suspending agent Substances 0.000 claims description 7
- 241001558929 Sclerotium <basidiomycota> Species 0.000 claims description 6
- 201000010099 disease Diseases 0.000 claims description 6
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 238000009736 wetting Methods 0.000 claims description 6
- 239000004480 active ingredient Substances 0.000 claims description 4
- 230000000361 pesticidal effect Effects 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 abstract description 4
- 241000221696 Sclerotinia sclerotiorum Species 0.000 abstract description 2
- 239000012752 auxiliary agent Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 7
- 239000002270 dispersing agent Substances 0.000 description 6
- 239000000080 wetting agent Substances 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 230000003449 preventive effect Effects 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 235000003228 Lactuca sativa Nutrition 0.000 description 4
- 241000227653 Lycopersicon Species 0.000 description 4
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 240000002791 Brassica napus Species 0.000 description 3
- 235000006008 Brassica napus var napus Nutrition 0.000 description 3
- 240000008415 Lactuca sativa Species 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 241000123650 Botrytis cinerea Species 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 230000002528 anti-freeze Effects 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- -1 polyoxyethylene Polymers 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- OWYSSKOUATWAAO-UHFFFAOYSA-N C1(=CC=CC=C1)C=1C(=C(C(=C(C1)O)C=C)C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound C1(=CC=CC=C1)C=1C(=C(C(=C(C1)O)C=C)C1=CC=CC=C1)C1=CC=CC=C1 OWYSSKOUATWAAO-UHFFFAOYSA-N 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 241000208822 Lactuca Species 0.000 description 1
- UDSDECJPWHXDPX-UHFFFAOYSA-N N-fluoro-4-methyl-2,6-dinitroaniline Chemical compound FNC1=C(C=C(C=C1[N+](=O)[O-])C)[N+](=O)[O-] UDSDECJPWHXDPX-UHFFFAOYSA-N 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a bactericidal composition of propamidine and fluazinam. The bactericidal composition comprises commonly used auxiliary agents, propamidine and fluazinam. Mass part ratio of propamidine and fluazinam in the composition is 5:1-1:45, and preferably 3:1-1:25. When propamidine and fluazinam are compounded, a substantial synergetic effect is provided. Effective component dose of the compounded agent is substantially reduced than that of separate use. The composition provided by the invention is suitable to be used against crop gray mold caused by botrytis pathogen and crop stalk break casued by sclerotinia pathogen.
Description
Technical field
The bactericidal composition the present invention relates to, is taking propamidine and fluazinam as active ingredient, is applicable to the crop gray mold that control causes by Botrytis pathogen, the sclerotium disease being caused by Sclerotinia pathogen.
Background technology
Propamidine, english common name propamidine, 1,3-bis-(4-amidino groups phenoxy group) propane.Propamidine is broad-spectrum germicide, has protection and therapeutic action, and the crop gray mold being caused by Botrytis pathogen, the sclerotium disease that caused by Sclerotinia pathogen are had to outstanding preventive effect.
Fluazinam, english common name fluazinam, the chloro-5-trifluoromethyl-2-of the chloro-N-(3-of chemical name 3-pyridine radicals)-α, α, α-tri-are fluoro-2,6-dinitro-p-toluidine.Fluazinam is protective fungicide, and current commercial formulation is suspending agent, and using method is mainly cauline leaf, soil spraying is processed.
Sclerotinite mainly causes all kinds of sclerotium diseases; Botrytis cinerea mainly causes all kinds of crop gray molds.
Have no at present the composite report of propamidine and fluazinam.
Summary of the invention
The object of this invention is to provide a kind of efficient, low toxicity, low-residual,, active ingredient good, lower-cost to Environmental compatibility is the bactericidal composition of propamidine and fluazinam.
The present invention is achieved through the following technical solutions: a kind of bactericidal composition, active ingredient is propamidine and fluazinam, propamidine and the fluazinam mass ratio in composition is 5:1～1:45, preferably, than being 3:1～1:25, propamidine and the fluazinam gross mass mark percentage composition in composition is 3%～90%.
The production technology that described bactericidal composition adds auxiliary agent and excipients all to know according to those skilled in the art is made suspending agent, water dispersible granules, wetting powder.
Bactericidal composition of the present invention is for preventing and treating the crop gray mold being caused by Botrytis pathogen, the sclerotium disease being caused by Sclerotinia pathogen.
Advantage of the present invention: the bactericidal composition that contains propamidine and fluazinam of the present invention, compared with single product, there is the feature of binary bactericidal composition, expand effective active scope, to by the microbial all kinds of plant stalk breaks of nuclear disk; All kinds of crop gray molds that Botrytis cinerea causes have good preventive effect, and have delayed drug-fast generation, and the lasting period is long, has reduced dosage and access times, cost-saving, easy to use, time and labour saving, and reduce the pollution to environment.
Embodiment
The present invention describes by following specific embodiment, but the invention is not restricted to following specific embodiment.In these embodiments, unless otherwise indicated, all percentage is all weight percentage.
example of formulations 1: 30% propamidine fluazinam suspending agent.
Propamidine 2%, fluazinam 28%, emulsifier 1601# 10%, wetting agent LS 5%, dispersant SOPA-270 3%, thickener bentonite 2%, stabilizing agent xanthan gum 0.5%, defoamer organosilicon 0.4%, antifreeze glycerine 5%, deionized water complements to 100%.Above-mentioned formula is pulverized in proportion in advance, then added in sand mill and grind, after high shear mixing, allotment makes 30% propamidine fluazinam suspending agent.
example of formulations 2: 20% propamidine fluazinam suspending agent.
Propamidine 6%, fluazinam 14%, emulsifier triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether 12%, wetting agent calcium dodecyl benzene sulfonate 5%, dispersant alkylphenol polyoxyethylene formaldehyde condensation products sulphate 3%, stabilizing agent gum Arabic 0.1%, antifreeze glycerine 5%, deionized water complements to 100%.Above-mentioned formula is pulverized in proportion in advance, then added in sand mill and grind, after high shear mixing, allotment makes 20% propamidine fluazinam suspending agent.
example of formulations 3: 60% propamidine fluazinam water dispersible granules.
Propamidine 5%, fluazinam 55%, wetting agent lauryl sodium sulfate 6%, dispersant lignosulfonates 4%, disintegrant urea 2%, binding agent polyethylene glycol 3%, stabilizing agent soluble starch 3%, kaolin complements to 100%.By above-mentioned formula, 60% propamidine fluazinam water dispersible granules is made and is obtained in dry pulverization process, granulation, dry, screening in proportion.
example of formulations 4: 50% propamidine fluazinam water dispersible granules.
Propamidine 3%, fluazinam 47%, wetting agent spaonin powder 6%, dispersant naphthalenesulfonic acid-formaldehyde condensate 4%, disintegrant bentonite 2%, binding agent cyclodextrin 2%, stabilizing agent soluble starch 3%, kaolin complements to 100%.By above-mentioned formula, 50% propamidine fluazinam water dispersible granules is made and is obtained in dry pulverization process, granulation, dry, screening in proportion.
example of formulations 5: 50% propamidine fluazinam wetting powder.
Propamidine 1%, fluazinam 49%, wetting agent pulls open powder 3%, dispersant lignosulfonates 6%, filler talcum powder 15%, filler kaolin complements to 100%.Above-mentioned formula is entered in blender after coarse crushing and mixed in proportion, then after air-flow crushing, make 50% propamidine fluazinam wetting powder.
example of formulations 6: 40% propamidine fluazinam wetting powder.
Propamidine 2%, fluazinam 38%, wetting agent pulls open powder 3%, dispersant dodecylphenol polyvinylether sulfonate 5%, filler white carbon 3%, kaolin complements to 100%.Above-mentioned formula is entered in blender after coarse crushing and mixed in proportion, then after air-flow crushing, make 40% propamidine fluazinam wetting powder.
biologicall test embodiment 1:the composite Toxicity Determination to sclerotinite of propamidine and fluazinam.
The composite Toxicity Determination result to sclerotinite of table 1, propamidine and fluazinam.
As shown in Table 1, propamidine of the present invention and fluazinam bactericidal composition have pair sclerotinite to have higher synergistic effect, propamidine and fluazinam 3:1,1:1,1:3,1:9,1:25 synergistic effect are obvious, and co-toxicity coefficient is greater than 140, and other proportionings all show synergistic effect in various degree.
biologicall test embodiment 2: to the field control effectiveness test of Lettuce Drop.
This is tested in March, 2012 and carries out in Feitian town, Huizhou Boluo County, and be watered 45kg by every mu and carry out even spraying, dispenser 1 time altogether, after medicine, 7 days control efficiency are in table 2.
Table 2, field control effectiveness test result to Lettuce Drop.
As can be seen from Table 2, the bactericidal composition of propamidine and fluazinam mixture has good control efficiency to Lettuce Drop, finds in test, and said composition, to lettuce safety, can reach desirable control efficiency in after medicine 7 days.
biologicall test embodiment 3:to the field control effectiveness test of graw mold of tomato.
This is tested in April, 2012 and carries out in Liang Zhuan town, Yue Dai district, Tai’an, Shandong Province, and be watered 45kg by every mu and carry out even spraying, dispenser 1 time altogether, after medicine, 7 days control efficiency are in table 3.
Table 3, field control effectiveness test result to graw mold of tomato.
As can be seen from Table 3, the bactericidal composition of propamidine and fluazinam has good control efficiency to graw mold of tomato, finds in test, and said composition, to tomato safety, can reach desirable preventive effect in after medicine 7 days.
biologicall test embodiment 4:to the field control effectiveness test of sclerotinia rot of colza.
This is tested in April, 2012 and carries out in market town, Funan County side of Anhui Province, and be watered 45kg by every mu and carry out even spraying, dispenser 1 time altogether, after medicine, 7 days control efficiency are in table 4.
Table 4, field control effectiveness test result to sclerotinia rot of colza.
As can be seen from Table 4, the composite bactericidal composition of propamidine and fluazinam has good control efficiency to sclerotinia rot of colza, finds in test, and said composition, to rape safety, can reach desirable preventive effect in after medicine 7 days.
In sum, the crop gray mold that the composite bactericidal composition of propamidine and fluazinam causes the sclerotium disease being caused by Sclerotinia pathogen, Botrytis pathogen has good preventive effect, to crop safety, environmentally friendly.Compared with single dose, reduce medication number of times, save cost.Therefore R&D and promotion of the present invention is significant.
Claims (4)
1. a bactericidal composition for propamidine and fluazinam, is characterized in that: active ingredient is propamidine and fluazinam; Propamidine and the fluazinam mass ratio in composition is 3:1～1:25.
2. the bactericidal composition of propamidine according to claim 1 and fluazinam, is characterized in that: in described bactericidal composition, also contain pesticidal preparations auxiliary element.
3. the bactericidal composition of propamidine according to claim 1 and fluazinam, is characterized in that: its formulation is suspending agent, water dispersible granules or wetting powder.
4. the application in the crop gray mold that the bactericidal composition of propamidine according to claim 1 and fluazinam is caused by Botrytis pathogen in control, the sclerotium disease being caused by Sclerotinia pathogen.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310003441.2A CN103053530B (en) | 2013-01-06 | 2013-01-06 | Bactericidal composition of propamidine and fluazinam |
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| CN201310003441.2A CN103053530B (en) | 2013-01-06 | 2013-01-06 | Bactericidal composition of propamidine and fluazinam |
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| CN103053530B true CN103053530B (en) | 2014-09-17 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103518726B (en) * | 2013-10-12 | 2015-11-18 | 京博农化科技股份有限公司 | A kind of bactericidal composition containing Boscalid and propamidine |
| CN104285956B (en) * | 2014-09-10 | 2017-11-28 | 广东中迅农科股份有限公司 | A kind of composition pesticide containing Fluoxastrobin and propamidine |
| CN104322496B (en) * | 2014-09-15 | 2017-12-12 | 广东中迅农科股份有限公司 | A kind of composition pesticide containing cyprodinil and propamidine |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1613847A (en) * | 2004-09-13 | 2005-05-11 | 西北农林科技大学无公害农药研究服务中心 | Aromatic diamidine compound with bactericidal activity and application thereof |
| WO2011076726A2 (en) * | 2009-12-23 | 2011-06-30 | Bayer Cropscience Ag | Pesticidal compound mixtures |
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2013
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1613847A (en) * | 2004-09-13 | 2005-05-11 | 西北农林科技大学无公害农药研究服务中心 | Aromatic diamidine compound with bactericidal activity and application thereof |
| WO2011076726A2 (en) * | 2009-12-23 | 2011-06-30 | Bayer Cropscience Ag | Pesticidal compound mixtures |
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