CN102919259A - Pesticide composition containing iminoctadine tris and fluazinam - Google Patents
Pesticide composition containing iminoctadine tris and fluazinam Download PDFInfo
- Publication number
- CN102919259A CN102919259A CN2012103838011A CN201210383801A CN102919259A CN 102919259 A CN102919259 A CN 102919259A CN 2012103838011 A CN2012103838011 A CN 2012103838011A CN 201210383801 A CN201210383801 A CN 201210383801A CN 102919259 A CN102919259 A CN 102919259A
- Authority
- CN
- China
- Prior art keywords
- fluazinam
- biguanides
- octyl benzene
- iminoctadine tris
- benzene sulfonates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005780 Fluazinam Substances 0.000 title claims abstract description 44
- UZCGKGPEKUCDTF-UHFFFAOYSA-N fluazinam Chemical compound [O-][N+](=O)C1=CC(C(F)(F)F)=C(Cl)C([N+]([O-])=O)=C1NC1=NC=C(C(F)(F)F)C=C1Cl UZCGKGPEKUCDTF-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000000203 mixture Substances 0.000 title claims abstract description 38
- 239000000575 pesticide Substances 0.000 title claims abstract description 22
- 239000007983 Tris buffer Substances 0.000 title abstract 7
- RONFGUROBZGJKP-UHFFFAOYSA-N iminoctadine Chemical compound NC(N)=NCCCCCCCCNCCCCCCCCN=C(N)N RONFGUROBZGJKP-UHFFFAOYSA-N 0.000 title abstract 7
- 241000233866 Fungi Species 0.000 claims abstract description 7
- 241000235349 Ascomycota Species 0.000 claims abstract description 6
- 244000052769 pathogen Species 0.000 claims abstract description 6
- 239000004615 ingredient Substances 0.000 claims abstract description 3
- 229940123208 Biguanide Drugs 0.000 claims description 48
- GVMDZMPQYYHMSV-UHFFFAOYSA-N octyl benzenesulfonate Chemical class CCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVMDZMPQYYHMSV-UHFFFAOYSA-N 0.000 claims description 47
- 150000004283 biguanides Chemical class 0.000 claims description 44
- 238000009472 formulation Methods 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 8
- 239000000375 suspending agent Substances 0.000 claims description 7
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 238000009736 wetting Methods 0.000 claims description 6
- 230000001717 pathogenic effect Effects 0.000 claims description 5
- 241000607479 Yersinia pestis Species 0.000 claims description 3
- 201000010099 disease Diseases 0.000 abstract description 6
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 6
- 230000002195 synergetic effect Effects 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 230000000474 nursing effect Effects 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 241000209094 Oryza Species 0.000 description 4
- 235000007164 Oryza sativa Nutrition 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 235000009566 rice Nutrition 0.000 description 4
- XNCOSPRUTUOJCJ-UHFFFAOYSA-N Biguanide Chemical group NC(N)=NC(N)=N XNCOSPRUTUOJCJ-UHFFFAOYSA-N 0.000 description 3
- 241000123650 Botrytis cinerea Species 0.000 description 3
- 241000221785 Erysiphales Species 0.000 description 3
- 241000209140 Triticum Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 230000000361 pesticidal effect Effects 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 244000215068 Acacia senegal Species 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000000205 acacia gum Substances 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- XDQUZFWEORJPTA-UHFFFAOYSA-N C(CCCCCCC)C1=C(C2=C(N=C(N2)S(=O)(=O)O)C=C1)C1=CC=CC=C1 Chemical class C(CCCCCCC)C1=C(C2=C(N=C(N2)S(=O)(=O)O)C=C1)C1=CC=CC=C1 XDQUZFWEORJPTA-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- UDSDECJPWHXDPX-UHFFFAOYSA-N N-fluoro-4-methyl-2,6-dinitroaniline Chemical compound FNC1=C(C=C(C=C1[N+](=O)[O-])C)[N+](=O)[O-] UDSDECJPWHXDPX-UHFFFAOYSA-N 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a pesticide composition containing iminoctadine tris and fluazinam. The weight part ratio of the iminoctadine tris to the fluazinam is (20:1)-(1:50), preferably (10:1)-(1:20); and the weight percent of the weight sum of the iminoctadine tris and the fluazinam relative to the weight of the pesticide composition is 3-80%. According to the pesticide composition containing the iminoctadine tris and the fluazinam, disclosed by the invention, a remarkable synergistic effect is achieved after compunding the iminoctadine tris and the fluazinam, the dosage of the effective ingredients of the compounded agent is remarkably smaller than the dosage of a singly used agent, and double nursing including protection and treatment can be effectively carried out on crops. The pesticide composition containing the iminoctadine tris and the fluazinam is suitable for controlling crop diseases caused by pathogens such as ascomycetes and fungi imperfecti.
Description
Technical field
The composition pesticide that the present invention relates to is take biguanides three octyl benzene sulfonates and fluazinam as active ingredient, is applicable to prevent and treat the crop pest that is caused by pathogen sac fungi, imperfect fungus.
Background technology
Biguanides three octyl benzene sulfonates, chemical name: 1,1-octyl group methylene biguanides, three octyl phenylbenzimidazole sulfonic acid salt.Biguanides three octyl benzene sulfonates are wide spectrum, low toxicity bactericide, suppress the biosynthesis of germ quasi-grease compound, and local permeability is strong, and pathogen sac fungi, imperfect fungus are had very high growth inhibitory activity.
Fluazinam, chemical name: 3-chloro-N-(3-chloro-5-trifluoromethyl-2-pyridine radicals)-and α, α, α-three fluoro-2,6-dinitro-p-toluidine.Fluazinam is protective fungicide, and Various Diseases original fungi is all had very high biologically active, and present commercial formulation is suspending agent, and using method is mainly cauline leaf, the soil spraying is processed.
The same with other bactericide, there are resistance risk in long-term single use fluazinam or biguanides three octyl benzene sulfonates.
Have no at present the composite report of biguanides three octyl benzene sulfonates and fluazinam.
Summary of the invention
The purpose of this invention is to provide a kind of efficient, low toxicity, low-residual, to Environmental compatibility is good, cost is lower, active ingredient is the composition pesticide of biguanides three octyl benzene sulfonates and fluazinam.
Technical scheme of the present invention: a kind of composition pesticide, effective ingredient is biguanides three octyl benzene sulfonate and fluazinams, the ratio of weight and number of biguanides three octyl benzene sulfonates and fluazinam is 20:1～1:50, the preferred weight portion rate is 10:1～1:20, and biguanides three octyl benzene sulfonates and the percentage by weight of fluazinam weight summation in composition pesticide are 3～80%.
Composition pesticide of the present invention can be selected known pesticidal preparations auxiliary element according to well known to a person skilled in the art method, is mixed with the Multiple Pesticides formulation.In the present invention, preferably be mixed with suspending agent, water dispersible granules and wetting powder.
The pesticidal preparations auxiliary element that uses in the composition pesticide of the present invention comprises that solvent, dispersant, stabilizing agent, emulsifier, antifreezing agent, thickener etc. and other are of value to active ingredient stablizes and bring into play drug effect in preparation known substance, all be various compositions commonly used in the pesticidal preparations or that permission is used, be not particularly limited, concrete composition and consumption require to determine by test according to prescription.
Advantage of the present invention is: biguanides three octyl benzene sulfonates and the composite composition pesticide of fluazinam; the crop pest that is caused by pathogen sac fungi, imperfect fungus there is good preventive effect; crop is provided protection, treats dual nursing; and can delay drug-fast generation, the lasting period is long, has reduced dosage and access times; save cost; easy to use, the time and labour saving, environmentally friendly.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage more short and sweet, the present invention describes with following specific embodiment, but the present invention only limits to absolutely not these examples.The following stated only is preferably embodiment of the present invention, only is used for describing the present invention, can not be interpreted as the restriction to scope of the present invention.Should be pointed out that all any modifications of making within the spirit and principles in the present invention, be equal to replacement and improvement etc., all should be included within protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Example of formulations 1: 30% biguanides, three octyl benzene sulfonate fluazinam suspending agents.
Biguanides three octyl benzene sulfonates 15%, fluazinam 15%, sodium lignin sulfonate 5%, calcium dodecyl benzene sulfonate 3%, xanthan gum 0.1%, empgen BB 5%, glycerine 5%, gum Arabic 0.1%.Deionized water complements to 100%.Above-mentioned prescription is pulverized in proportion in advance, added in the sand mill and grind, allotment makes 30% biguanides, three octyl benzene sulfonate fluazinam suspending agents after high shear mixing.
Example of formulations 2: 20% biguanides, three octyl benzene sulfonate fluazinam suspending agents.
Biguanides three octyl benzene sulfonates 8%, fluazinam 12%, sodium lignin sulfonate 5%, calcium dodecyl benzene sulfonate 3%, xanthan gum 0.1%, empgen BB 5%, glycerine 5%, gum Arabic 0.1%.Deionized water complements to 100%.Above-mentioned prescription is pulverized in proportion in advance, added in the sand mill and grind, allotment makes 20% biguanides, three octyl benzene sulfonate fluazinam suspending agents after high shear mixing.
Example of formulations 3: 60% biguanides, three octyl benzene sulfonate fluazinam water dispersible granules.
Biguanides three octyl benzene sulfonates 25%, fluazinam 35%, lauryl sodium sulfate 6%, dispersant sodium lignin sulfonate 4%, disintegrant sodium chloride 2%, binding agent polyethylene glycol 3%, stable meltable starch 3%, kaolin complements to 100%.Dry pulverization process, granulation, drying, screening preparation namely get 60% biguanides, three octyl benzene sulfonate fluazinam water dispersible granules in proportion with above-mentioned prescription.
Example of formulations 4: 50% biguanides, three octyl benzene sulfonate fluazinam water dispersible granules.
Biguanides three octyl benzene sulfonates 10%, fluazinam 40%, lauryl sodium sulfate 6%, dispersant sodium lignin sulfonate 4%, disintegrant sodium chloride 2%, binding agent polyethylene glycol 3%, stable meltable starch 3%, kaolin complements to 100%.Dry pulverization process, granulation, drying, screening preparation namely get 50% biguanides, three octyl benzene sulfonate fluazinam water dispersible granules in proportion with above-mentioned prescription.
Example of formulations 5: 50% biguanides, three octyl benzene sulfonate fluazinam wetting powders.
Biguanides three octyl benzene sulfonates 5%, fluazinam 45% pulls open powder 3%, lignosulfonates (sodium, calcium) 6%, talcum powder 15%, kaolin complements to 100%.Above-mentioned prescription entered in the blender after the coarse crushing in proportion mix, behind air-flow crushing, namely make again 50% biguanides, three octyl benzene sulfonate fluazinam wetting powders.
Example of formulations 6: 60% biguanides, three octyl benzene sulfonate fluazinam wetting powders.
Biguanides three octyl benzene sulfonates 18%, fluazinam 42% pulls open powder 3%, sodium lignin sulfonate 6%, talcum powder 15%, kaolin complements to 100%.Above-mentioned prescription entered in the blender after the coarse crushing in proportion mix, behind air-flow crushing, namely make again 60% biguanides, three octyl benzene sulfonate fluazinam wetting powders.
Biologicall test embodiment 1: biguanides three octyl benzene sulfonate fluazinams are to the Toxicity Determination of Botrytis cinerea.
Table 1, biguanides three octyl benzene sulfonate fluazinams are to the Toxicity Determination of Botrytis cinerea.
As shown in Table 1, biguanides three octyl benzene sulfonates of the present invention and the composite composition pesticide of fluazinam have pair Botrytis cinerea that higher synergistic effect is arranged, especially take be mixed weight ratio as 10:1,5:1,1:3,1:9,1:30 synergistic effect obvious, co-toxicity coefficient is greater than 140, and other proportionings all show synergistic effect in various degree.
Biologicall test embodiment 2: biguanides three octyl benzene sulfonate fluazinams are to the field control effectiveness test of rice sheath blight disease.
This is tested on March 5th, 2012 and carries out in Feitian town, Huizhou Boluo County, is watered 45kg by every mu and carries out even spraying, and dispenser is 1 time altogether, 7 days control efficiency such as tables 2 behind the medicine.
Table 2, biguanides three octyl benzene sulfonate fluazinams are to the field control effectiveness test result of rice sheath blight disease.
As can be seen from Table 2, the composite bactericidal composition of biguanides three octyl benzene sulfonate fluazinams of the present invention has preferably control efficiency to rice sheath blight disease, finds that in test said composition can reach desirable control efficiency in 7 days to rice safety behind the medicine.
Biologicall test embodiment 3: biguanides three octyl benzene sulfonate fluazinams are to the field control effectiveness test of wheat powdery mildew.
This is tested on April 20th, 2012 and carries out in market town, Funan County side, Anhui Province, is watered 45kg by every mu and carries out even spraying, and dispenser is 1 time altogether, 7 days control efficiency such as tables 3 behind the medicine.
Table 3, biguanides three octyl benzene sulfonate fluazinams are to the field control effectiveness test result of wheat powdery mildew.
As can be seen from Table 3, the composite bactericidal composition of biguanides three octyl benzene sulfonate fluazinams of the present invention has preferably control efficiency to wheat powdery mildew, finds that in test said composition can reach desirable preventive effect in 7 days to tomato safety behind the medicine.
In sum; biguanides three octyl benzene sulfonates and the composite composition pesticide of fluazinam have preferably preventive effect to the plant disease that is caused by pathogen sac fungi, imperfect fungus; crop is had protection, treats dual nursing role, to crop safety safety, environmentally friendly.Compare with single dose, reduced the medication number of times, saved cost.Therefore R﹠D and promotion of the present invention is significant.
Claims (4)
1. the composition pesticide of biguanides three octyl benzene sulfonates and fluazinam, it is characterized in that: effective ingredient is biguanides three octyl benzene sulfonate and fluazinams, the ratio of weight and number of biguanides three octyl benzene sulfonates and fluazinam is 20:1～1:50, and biguanides three octyl benzene sulfonates and the percentage by weight of fluazinam weight summation in composition pesticide are 5～80%.
2. the composition pesticide of biguanides three octyl benzene sulfonates according to claim 1 and fluazinam, it is characterized in that: the ratio of weight and number of described biguanides three octyl benzene sulfonates and fluazinam is 10:1～1:20.
3. the composition pesticide of biguanides three octyl benzene sulfonates according to claim 1 and fluazinam is characterized in that the formulation when reality is used is suspending agent, water dispersible granules or wetting powder.
According to claim 1 with the composition pesticide of 2 described biguanides three octyl benzene sulfonates and fluazinam, it is characterized in that: described composition pesticide is used for the crop pest that control is caused by pathogen sac fungi, imperfect fungus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103838011A CN102919259A (en) | 2012-10-11 | 2012-10-11 | Pesticide composition containing iminoctadine tris and fluazinam |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103838011A CN102919259A (en) | 2012-10-11 | 2012-10-11 | Pesticide composition containing iminoctadine tris and fluazinam |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102919259A true CN102919259A (en) | 2013-02-13 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012103838011A Pending CN102919259A (en) | 2012-10-11 | 2012-10-11 | Pesticide composition containing iminoctadine tris and fluazinam |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102919259A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103190447A (en) * | 2013-03-28 | 2013-07-10 | 河北省农林科学院植物保护研究所 | Sterilization composition |
| CN106689181A (en) * | 2016-12-07 | 2017-05-24 | 陕西上格之路生物科学有限公司 | Bactericidal composition containing fenpyrazamine |
| CN109511655A (en) * | 2017-09-18 | 2019-03-26 | 沈阳中化农药化工研发有限公司 | A kind of bactericidal composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85101560A (en) * | 1984-02-24 | 1987-01-24 | 大日本油墨化学工业株式会社 | Guanidine-type (fungus) fungicide for agriculture and gardening and its production process |
| JPH06220018A (en) * | 1992-10-27 | 1994-08-09 | Bayer Ag | Substituted aza(cyclo)alkane |
-
2012
- 2012-10-11 CN CN2012103838011A patent/CN102919259A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85101560A (en) * | 1984-02-24 | 1987-01-24 | 大日本油墨化学工业株式会社 | Guanidine-type (fungus) fungicide for agriculture and gardening and its production process |
| JPH06220018A (en) * | 1992-10-27 | 1994-08-09 | Bayer Ag | Substituted aza(cyclo)alkane |
Non-Patent Citations (1)
| Title |
|---|
| ANONYMOUS: "Fluazinam Compositions", 《RESEARCH DISCLOSURE》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103190447A (en) * | 2013-03-28 | 2013-07-10 | 河北省农林科学院植物保护研究所 | Sterilization composition |
| CN103190447B (en) * | 2013-03-28 | 2014-05-07 | 河北省农林科学院植物保护研究所 | a bactericidal composition |
| CN106689181A (en) * | 2016-12-07 | 2017-05-24 | 陕西上格之路生物科学有限公司 | Bactericidal composition containing fenpyrazamine |
| CN109511655A (en) * | 2017-09-18 | 2019-03-26 | 沈阳中化农药化工研发有限公司 | A kind of bactericidal composition |
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