CN103053530A - Bactericidal composition of propamidine and fluazinam - Google Patents
Bactericidal composition of propamidine and fluazinam Download PDFInfo
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- CN103053530A CN103053530A CN2013100034412A CN201310003441A CN103053530A CN 103053530 A CN103053530 A CN 103053530A CN 2013100034412 A CN2013100034412 A CN 2013100034412A CN 201310003441 A CN201310003441 A CN 201310003441A CN 103053530 A CN103053530 A CN 103053530A
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- Prior art keywords
- propamidine
- fluazinam
- bactericidal composition
- composition
- pathogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005780 Fluazinam Substances 0.000 title claims abstract description 53
- UZCGKGPEKUCDTF-UHFFFAOYSA-N fluazinam Chemical compound [O-][N+](=O)C1=CC(C(F)(F)F)=C(Cl)C([N+]([O-])=O)=C1NC1=NC=C(C(F)(F)F)C=C1Cl UZCGKGPEKUCDTF-UHFFFAOYSA-N 0.000 title claims abstract description 53
- WTFXJFJYEJZMFO-UHFFFAOYSA-N propamidine Chemical group C1=CC(C(=N)N)=CC=C1OCCCOC1=CC=C(C(N)=N)C=C1 WTFXJFJYEJZMFO-UHFFFAOYSA-N 0.000 title claims abstract description 53
- 229960003761 propamidine Drugs 0.000 title claims abstract description 53
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 24
- 241000221662 Sclerotinia Species 0.000 claims abstract description 9
- 241001465180 Botrytis Species 0.000 claims abstract description 6
- 244000052769 pathogen Species 0.000 claims abstract description 6
- 230000001717 pathogenic effect Effects 0.000 claims abstract description 6
- 238000009472 formulation Methods 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 239000000375 suspending agent Substances 0.000 claims description 7
- 241001558929 Sclerotium <basidiomycota> Species 0.000 claims description 6
- 201000010099 disease Diseases 0.000 claims description 6
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims description 6
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 238000009736 wetting Methods 0.000 claims description 6
- 239000004480 active ingredient Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- 230000003641 microbiacidal effect Effects 0.000 claims 1
- 229940124561 microbicide Drugs 0.000 claims 1
- 239000002855 microbicide agent Substances 0.000 claims 1
- 230000000361 pesticidal effect Effects 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 abstract description 4
- 241000221696 Sclerotinia sclerotiorum Species 0.000 abstract description 2
- 239000012752 auxiliary agent Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 7
- 239000002270 dispersing agent Substances 0.000 description 6
- 239000000080 wetting agent Substances 0.000 description 6
- 239000002131 composite material Substances 0.000 description 5
- 230000003449 preventive effect Effects 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 235000003228 Lactuca sativa Nutrition 0.000 description 4
- 241000227653 Lycopersicon Species 0.000 description 4
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 240000002791 Brassica napus Species 0.000 description 3
- 235000006008 Brassica napus var napus Nutrition 0.000 description 3
- 240000008415 Lactuca sativa Species 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 241000123650 Botrytis cinerea Species 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 230000002528 anti-freeze Effects 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- -1 polyoxyethylene Polymers 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- OWYSSKOUATWAAO-UHFFFAOYSA-N C1(=CC=CC=C1)C=1C(=C(C(=C(C1)O)C=C)C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound C1(=CC=CC=C1)C=1C(=C(C(=C(C1)O)C=C)C1=CC=CC=C1)C1=CC=CC=C1 OWYSSKOUATWAAO-UHFFFAOYSA-N 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 241000208822 Lactuca Species 0.000 description 1
- UDSDECJPWHXDPX-UHFFFAOYSA-N N-fluoro-4-methyl-2,6-dinitroaniline Chemical compound FNC1=C(C=C(C=C1[N+](=O)[O-])C)[N+](=O)[O-] UDSDECJPWHXDPX-UHFFFAOYSA-N 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a bactericidal composition of propamidine and fluazinam. The bactericidal composition comprises commonly used auxiliary agents, propamidine and fluazinam. Mass part ratio of propamidine and fluazinam in the composition is 5:1-1:45, and preferably 3:1-1:25. When propamidine and fluazinam are compounded, a substantial synergetic effect is provided. Effective component dose of the compounded agent is substantially reduced than that of separate use. The composition provided by the invention is suitable to be used against crop gray mold caused by botrytis pathogen and crop stalk break casued by sclerotinia pathogen.
Description
Technical field
The bactericidal composition that the present invention relates to is take propamidine and fluazinam as active ingredient, the sclerotium disease that is applicable to prevent and treat the crop gray mold that caused by the Botrytis pathogen, is caused by the Sclerotinia pathogen.
Background technology
Propamidine, english common name propamidine, 1,3-two (4-amidino groups phenoxy group) propane.Propamidine is broad-spectrum germicide, has protection and therapeutic action, and the crop gray mold that is caused by the Botrytis pathogen, the sclerotium disease that is caused by the Sclerotinia pathogen are had outstanding preventive effect.
Fluazinam, english common name fluazinam, chemical name 3-chloro-N-(3-chloro-5-trifluoromethyl-2-pyridine radicals)-α, α, α-three fluoro-2,6-dinitro-p-toluidine.Fluazinam is protective fungicide, and present commercial formulation is suspending agent, and using method is mainly cauline leaf, the soil spraying is processed.
Sclerotinite mainly causes all kinds of sclerotium diseases; Botrytis cinerea mainly causes all kinds of crop gray molds.
Have no at present the composite report of propamidine and fluazinam.
Summary of the invention
The purpose of this invention is to provide a kind of efficient, low toxicity, low-residual,, active ingredient good, lower-cost to Environmental compatibility is the bactericidal composition of propamidine and fluazinam.
The present invention is achieved through the following technical solutions: a kind of bactericidal composition, active ingredient is propamidine and fluazinam, propamidine and the fluazinam mass ratio in composition is 5:1～1:45, preferably than being 3:1～1:25, propamidine and the fluazinam gross mass mark percentage composition in composition is 3%～90%.
The production technology that described bactericidal composition adding auxiliary agent and excipients are all known according to those skilled in the art is made suspending agent, water dispersible granules, wetting powder.
The sclerotium disease that bactericidal composition of the present invention is used for crop gray mold that control causes by the Botrytis pathogen, is caused by the Sclerotinia pathogen.
Advantage of the present invention: the bactericidal composition that contains propamidine and fluazinam of the present invention, compare with single product, have the characteristics of binary bactericidal composition, enlarged the effective active scope, to by the microbial all kinds of plant stalk breaks of nuclear disk; All kinds of crop gray molds that Botrytis cinerea causes have good preventive effect, and have delayed drug-fast generation, and the lasting period is long, has reduced dosage and access times, save cost, and are easy to use, the time and labour saving, and minimizing is to the pollution of environment.
Embodiment
The present invention describes by following specific embodiment, but the invention is not restricted to following specific embodiment.In these embodiments, unless otherwise indicated, all percentages all are weight percentage.
Example of formulations 1: 30% propamidine fluazinam suspending agent.
Propamidine 2%, fluazinam 28%, emulsifier 1601# 10%, wetting agent LS 5%, dispersant SOPA-270 3%, thickener bentonite 2%, stabilizing agent xanthan gum 0.5%, defoamer organosilicon 0.4%, antifreeze glycerine 5%, deionized water complements to 100%.Above-mentioned prescription is pulverized in proportion in advance, added in the sand mill and grind, allotment makes 30% propamidine fluazinam suspending agent after high shear mixing.
Example of formulations 2: 20% propamidine fluazinam suspending agent.
Propamidine 6%, fluazinam 14%, emulsifier triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether 12%, wetting agent calcium dodecyl benzene sulfonate 5%, dispersant alkylphenol polyoxyethylene formaldehyde condensation products sulphate 3%, stabilizing agent gum Arabic 0.1%, antifreeze glycerine 5%, deionized water complements to 100%.Above-mentioned prescription is pulverized in proportion in advance, added in the sand mill and grind, allotment makes 20% propamidine fluazinam suspending agent after high shear mixing.
Example of formulations 3: 60% propamidine fluazinam water dispersible granules.
Propamidine 5%, fluazinam 55%, wetting agent lauryl sodium sulfate 6%, dispersant lignosulfonates 4%, disintegrant urea 2%, binding agent polyethylene glycol 3%, stabilizing agent soluble starch 3%, kaolin complements to 100%.Dry pulverization process, granulation, drying, screening preparation system namely get 60% propamidine fluazinam water dispersible granules in proportion with above-mentioned prescription.
Example of formulations 4: 50% propamidine fluazinam water dispersible granules.
Propamidine 3%, fluazinam 47%, wetting agent spaonin powder 6%, dispersant naphthalenesulfonic acid-formaldehyde condensate 4%, disintegrant bentonite 2%, binding agent cyclodextrin 2%, stabilizing agent soluble starch 3%, kaolin complements to 100%.Dry pulverization process, granulation, drying, screening preparation system namely get 50% propamidine fluazinam water dispersible granules in proportion with above-mentioned prescription.
Example of formulations 5: 50% propamidine fluazinam wetting powder.
Propamidine 1%, fluazinam 49%, wetting agent pull open powder 3%, dispersant lignosulfonates 6%, filler talcum powder 15%, filler kaolin complements to 100%.Above-mentioned prescription entered in the blender after the coarse crushing in proportion mix, behind air-flow crushing, namely make again 50% propamidine fluazinam wetting powder.
Example of formulations 6: 40% propamidine fluazinam wetting powder.
Propamidine 2%, fluazinam 38%, wetting agent pull open powder 3%, dispersant dodecylphenol polyvinylether sulfonate 5%, filler white carbon 3%, kaolin complements to 100%.Above-mentioned prescription entered in the blender after the coarse crushing in proportion mix, behind air-flow crushing, namely make again 40% propamidine fluazinam wetting powder.
Biologicall test embodiment 1:The composite Toxicity Determination to sclerotinite of propamidine and fluazinam.
The composite Toxicity Determination result to sclerotinite of table 1, propamidine and fluazinam.
As shown in Table 1, propamidine of the present invention and fluazinam bactericidal composition have pair sclerotinite that higher synergistic effect is arranged, propamidine and fluazinam 3:1,1:1,1:3,1:9,1:25 synergistic effect are obvious, and co-toxicity coefficient is greater than 140, and other proportionings all show synergistic effect in various degree.
Biologicall test embodiment 2: to the field control effectiveness test of Lettuce Drop.
This is tested in March, 2012 and carries out in Feitian town, Huizhou Boluo County, is watered 45kg by every mu and carries out even spraying, and dispenser is 1 time altogether, and 7 days control efficiency see Table 2 behind the medicine.
Table 2, to the field control effectiveness test result of Lettuce Drop.
As can be seen from Table 2, the bactericidal composition that propamidine and fluazinam are mixed has preferably control efficiency to Lettuce Drop, finds that in test said composition can reach desirable control efficiency in 7 days to lettuce safety behind the medicine.
Biologicall test embodiment 3:Field control effectiveness test to graw mold of tomato.
This is tested in April, 2012 and carries out in the Yue Dai Qu Liang village, Tai’an, Shandong Province town, is watered 45kg by every mu and carries out even spraying, and dispenser is 1 time altogether, and 7 days control efficiency see Table 3 behind the medicine.
Table 3, to the field control effectiveness test result of graw mold of tomato.
As can be seen from Table 3, the bactericidal composition of propamidine and fluazinam has preferably control efficiency to graw mold of tomato, finds that in test said composition can reach desirable preventive effect in 7 days to tomato safety behind the medicine.
Biologicall test embodiment 4:Field control effectiveness test to sclerotinia rot of colza.
This is tested in April, 2012 and carries out in market town, Funan County side, Anhui Province, is watered 45kg by every mu and carries out even spraying, and dispenser is 1 time altogether, and 7 days control efficiency see Table 4 behind the medicine.
Table 4, to the field control effectiveness test result of sclerotinia rot of colza.
As can be seen from Table 4, the composite bactericidal composition of propamidine and fluazinam has preferably control efficiency to sclerotinia rot of colza, finds that in test said composition can reach desirable preventive effect in 7 days to rape safety behind the medicine.
In sum, the composite bactericidal composition of propamidine and fluazinam has preferably preventive effect to the sclerotium disease that is caused by the Sclerotinia pathogen, the crop gray mold that the Botrytis pathogen causes, and is to crop safety, environmentally friendly.Compare with single dose, reduced the medication number of times, saved cost.Therefore R﹠D and promotion of the present invention is significant.
Claims (7)
1. the bactericidal composition of a propamidine and fluazinam, it is characterized in that: active ingredient is propamidine and fluazinam.
2. the bactericidal composition of propamidine according to claim 1 and fluazinam, it is characterized in that: propamidine and the fluazinam mass ratio in composition is 5:1～1:45.
3. the bactericidal composition of propamidine according to claim 2 and fluazinam, it is characterized in that: propamidine and the fluazinam mass ratio in composition is 3:1～1:25.
4. the bactericidal composition of propamidine according to claim 1 and fluazinam is characterized in that, propamidine and the fluazinam gross mass mark percentage composition in composition is 3%～90%.
5. the bactericidal composition of propamidine according to claim 1 and fluazinam is characterized in that: also contain the pesticidal preparations auxiliary element in the described bactericidal composition, be fit to the upper formulation of using of agricultural so that microbicide compositions is made.
6. the bactericidal composition of propamidine according to claim 1 and fluazinam, it is characterized in that: its formulation is suspending agent, water dispersible granules, wetting powder.
7. the bactericidal composition of propamidine according to claim 1 and fluazinam is characterized in that: the sclerotium disease that is used for crop gray mold that control causes by the Botrytis pathogen, is caused by the Sclerotinia pathogen.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310003441.2A CN103053530B (en) | 2013-01-06 | 2013-01-06 | Bactericidal composition of propamidine and fluazinam |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310003441.2A CN103053530B (en) | 2013-01-06 | 2013-01-06 | Bactericidal composition of propamidine and fluazinam |
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| Publication Number | Publication Date |
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| CN103053530A true CN103053530A (en) | 2013-04-24 |
| CN103053530B CN103053530B (en) | 2014-09-17 |
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| CN201310003441.2A Active CN103053530B (en) | 2013-01-06 | 2013-01-06 | Bactericidal composition of propamidine and fluazinam |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103518726A (en) * | 2013-10-12 | 2014-01-22 | 京博农化科技股份有限公司 | Sterilizing composition containing boscalid and propamidine |
| CN104285956A (en) * | 2014-09-10 | 2015-01-21 | 广东中迅农科股份有限公司 | Pesticide composition containing azoxystrobin and propamidine |
| CN104322496A (en) * | 2014-09-15 | 2015-02-04 | 广东中迅农科股份有限公司 | Pesticide composition containing cyprodinil and propamidine |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1613847A (en) * | 2004-09-13 | 2005-05-11 | 西北农林科技大学无公害农药研究服务中心 | Aromatic diamidine compound with bactericidal activity and application thereof |
| WO2011076726A2 (en) * | 2009-12-23 | 2011-06-30 | Bayer Cropscience Ag | Pesticidal compound mixtures |
-
2013
- 2013-01-06 CN CN201310003441.2A patent/CN103053530B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1613847A (en) * | 2004-09-13 | 2005-05-11 | 西北农林科技大学无公害农药研究服务中心 | Aromatic diamidine compound with bactericidal activity and application thereof |
| WO2011076726A2 (en) * | 2009-12-23 | 2011-06-30 | Bayer Cropscience Ag | Pesticidal compound mixtures |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103518726A (en) * | 2013-10-12 | 2014-01-22 | 京博农化科技股份有限公司 | Sterilizing composition containing boscalid and propamidine |
| CN103518726B (en) * | 2013-10-12 | 2015-11-18 | 京博农化科技股份有限公司 | A kind of bactericidal composition containing Boscalid and propamidine |
| CN104285956A (en) * | 2014-09-10 | 2015-01-21 | 广东中迅农科股份有限公司 | Pesticide composition containing azoxystrobin and propamidine |
| CN104285956B (en) * | 2014-09-10 | 2017-11-28 | 广东中迅农科股份有限公司 | A kind of composition pesticide containing Fluoxastrobin and propamidine |
| CN104322496A (en) * | 2014-09-15 | 2015-02-04 | 广东中迅农科股份有限公司 | Pesticide composition containing cyprodinil and propamidine |
| CN104322496B (en) * | 2014-09-15 | 2017-12-12 | 广东中迅农科股份有限公司 | A kind of composition pesticide containing cyprodinil and propamidine |
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| Publication number | Publication date |
|---|---|
| CN103053530B (en) | 2014-09-17 |
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