CN102850848B - UV gravure RFID printing ink and preparation method thereof - Google Patents
UV gravure RFID printing ink and preparation method thereof Download PDFInfo
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- CN102850848B CN102850848B CN201210075860.2A CN201210075860A CN102850848B CN 102850848 B CN102850848 B CN 102850848B CN 201210075860 A CN201210075860 A CN 201210075860A CN 102850848 B CN102850848 B CN 102850848B
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- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- 239000003208 petroleum Substances 0.000 claims abstract description 13
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000049 pigment Substances 0.000 claims abstract description 11
- 239000002270 dispersing agent Substances 0.000 claims abstract description 9
- 239000000178 monomer Substances 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims description 18
- 229920000058 polyacrylate Polymers 0.000 claims description 14
- 150000002148 esters Chemical class 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 10
- LYXOWKPVTCPORE-UHFFFAOYSA-N phenyl-(4-phenylphenyl)methanone Chemical compound C=1C=C(C=2C=CC=CC=2)C=CC=1C(=O)C1=CC=CC=C1 LYXOWKPVTCPORE-UHFFFAOYSA-N 0.000 claims description 9
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 9
- JIGUICYYOYEXFS-UHFFFAOYSA-N 3-tert-butylbenzene-1,2-diol Chemical compound CC(C)(C)C1=CC=CC(O)=C1O JIGUICYYOYEXFS-UHFFFAOYSA-N 0.000 claims description 8
- 239000013032 Hydrocarbon resin Substances 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 8
- 229920006270 hydrocarbon resin Polymers 0.000 claims description 8
- 229920002521 macromolecule Polymers 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- -1 chloride acrylic ester Chemical class 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 5
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims description 4
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 4
- WXPWZZHELZEVPO-UHFFFAOYSA-N (4-methylphenyl)-phenylmethanone Chemical compound C1=CC(C)=CC=C1C(=O)C1=CC=CC=C1 WXPWZZHELZEVPO-UHFFFAOYSA-N 0.000 claims description 3
- PSCIFRQCZMVELI-UHFFFAOYSA-N 1,3-bis(2-phenylphenyl)propan-2-one Chemical compound C=1C=CC=C(C=2C=CC=CC=2)C=1CC(=O)CC1=CC=CC=C1C1=CC=CC=C1 PSCIFRQCZMVELI-UHFFFAOYSA-N 0.000 claims description 2
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 2
- BTJPUDCSZVCXFQ-UHFFFAOYSA-N 2,4-diethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC(CC)=C3SC2=C1 BTJPUDCSZVCXFQ-UHFFFAOYSA-N 0.000 claims description 2
- OPLCSTZDXXUYDU-UHFFFAOYSA-N 2,4-dimethyl-6-tert-butylphenol Chemical compound CC1=CC(C)=C(O)C(C(C)(C)C)=C1 OPLCSTZDXXUYDU-UHFFFAOYSA-N 0.000 claims description 2
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 claims description 2
- NQOGBCBPDVTBFM-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol;prop-2-enoic acid Chemical compound OC(=O)C=C.CC(O)COC(C)COC(C)CO NQOGBCBPDVTBFM-UHFFFAOYSA-N 0.000 claims description 2
- XRCRJFOGPCJKPF-UHFFFAOYSA-N 2-butylbenzene-1,4-diol Chemical compound CCCCC1=CC(O)=CC=C1O XRCRJFOGPCJKPF-UHFFFAOYSA-N 0.000 claims description 2
- UROMEJXLYLGHIE-UHFFFAOYSA-N 2-ethoxyethyl 2-ethoxyprop-2-eneperoxoate Chemical compound CCOCCOOC(=O)C(=C)OCC UROMEJXLYLGHIE-UHFFFAOYSA-N 0.000 claims description 2
- SAPGBCWOQLHKKZ-UHFFFAOYSA-N 6-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCOC(=O)C(C)=C SAPGBCWOQLHKKZ-UHFFFAOYSA-N 0.000 claims description 2
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 claims description 2
- ZMDDERVSCYEKPQ-UHFFFAOYSA-N Ethyl (mesitylcarbonyl)phenylphosphinate Chemical compound C=1C=CC=CC=1P(=O)(OCC)C(=O)C1=C(C)C=C(C)C=C1C ZMDDERVSCYEKPQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005062 Polybutadiene Substances 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- SSOONFBDIYMPEU-UHFFFAOYSA-N [3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propyl] prop-2-enoate Chemical compound OCC(CO)(CO)COCC(CO)(CO)COC(=O)C=C SSOONFBDIYMPEU-UHFFFAOYSA-N 0.000 claims description 2
- 230000002378 acidificating effect Effects 0.000 claims description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
- 159000000013 aluminium salts Chemical class 0.000 claims description 2
- 229910000329 aluminium sulfate Inorganic materials 0.000 claims description 2
- NJVHCUNZAMFQNA-UHFFFAOYSA-N azane;n-hydroxy-n-phenylnitrous amide Chemical compound N.O=NN(O)C1=CC=CC=C1 NJVHCUNZAMFQNA-UHFFFAOYSA-N 0.000 claims description 2
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 2
- 239000001055 blue pigment Substances 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 2
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical class COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 claims description 2
- YLHXLHGIAMFFBU-UHFFFAOYSA-N methyl phenylglyoxalate Chemical compound COC(=O)C(=O)C1=CC=CC=C1 YLHXLHGIAMFFBU-UHFFFAOYSA-N 0.000 claims description 2
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 claims description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 claims description 2
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims 2
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 17
- 239000002253 acid Substances 0.000 abstract description 15
- 238000005530 etching Methods 0.000 abstract description 15
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 1
- 239000012467 final product Substances 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 12
- 239000002002 slurry Substances 0.000 description 12
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 7
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 7
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 7
- 239000003513 alkali Substances 0.000 description 5
- 238000007711 solidification Methods 0.000 description 4
- 230000008023 solidification Effects 0.000 description 4
- 239000002585 base Substances 0.000 description 3
- 235000021384 green leafy vegetables Nutrition 0.000 description 3
- 229920006271 aliphatic hydrocarbon resin Polymers 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 229920006026 co-polymeric resin Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 150000002430 hydrocarbons Chemical group 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000003505 terpenes Chemical class 0.000 description 2
- 235000007586 terpenes Nutrition 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002761 deinking Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000176 photostabilization Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses UV gravure RFID printing ink and a preparation method thereof; the UV gravure RFID printing ink comprises, by weight:10-30 parts of petroleum resin, 10-30 parts of acrylic acid prepolymer, 0.1-1 part of a polymerization inhibitor, 5-12 parts of a photoinitiator, 5-10 parts of pigment, 1-5 parts of a dispersant, and 20-50 parts of acrylic acid monomers. The UV gravure RFID printing ink of the invention has the following beneficial effects: the printing ink is suitable for gravure press and flexo-graphic machines, is instantly dried by an ultraviolet lamp, which greatly increases the working efficiency. After dried, the printing ink can resist strong acid etching; the concentration of the etching acid can be adjusted at will; the etching solution temperature can be increased; the etching time can be increased; and thus processing of various RFID labels can be met. After drying and etching, the printing ink is easy to be washed by alkalis, and a 3% NaOH solution can remove the ink within 5-20 seconds. The line surface is effectively maintained to be clean and free of printing ink residues, and thus the final product quality is ensured.
Description
Technical field
The present invention relates to UV curable ink composition and method and gravure process, mainly a kind of UV gravure RFID ink and preparation method thereof.
Background technology
RFID, be a kind of contactless automatic identification technology, it automatically identifies target object by radiofrequency signal and obtains related data, and the work of identification need not manual intervention, can work in various severe environment.RFID technique identifiable design high-speed moving object also can identify multiple label simultaneously.
Current RFID ink has common gravure ink and UV silk-screen ink.Common gravure ink flow leveling is good, after printing longitudinal lines and cross-wise lines straight, there will not be sawtooth, print speed is fast, and acid resistance is good, without dew point after etching, easy alkali cleaning; But containing a large amount of solvent in gravure ink, belong to hazardous substance, domestic do not have the external import of need of production, delivery date is unstable, discharges a large amount of organic volatile contaminate environment.And UV silk-screen ink, can not printed with fine lines, acidproof etch differential, weak base takes off performance of ink difference, and print speed is slow, cannot meet RFID label tag in enormous quantities and produce.
Application number be 200810000593.6 Chinese invention patent to have employed in molecule at least containing a phenolic hydroxyl group and not carboxylic strong lye soluble resin, can alkaline-resisting etching and being dissolved by alkali lye after solving ink solidification, this alkali lye is highly basic.In actually operating, due to highly basic also soluble metal substrate, the higher production of scrap rate is more difficult, and this invention is for circuit card printing.
Summary of the invention
In order to solve print speed slowly, the etching of not resistance to strong acid, weak base takes off the problem that poor, the UV gravure ink of ink easily precipitates, the invention provides a kind of high speed printing, excellent, the resistance to strong acid etching of flow leveling, black UV gravure RFID ink composite can be taken off by week-base water.
Another object of the present invention is to provide that a kind of dispersion effect is good, the preparation method of the UV gravure RFID ink of administration measure.
The present invention solves the technical scheme that its technical problem adopts: this UV gravure RFID ink, with mass ratio range, comprise 10 ~ 30 parts of hydrocarbon resins, 10 ~ 30 acrylic polymers, 0.1 ~ 1 part of stopper, 5 ~ 12 parts of light triggers, 5 ~ 10 parts of pigment, 1 ~ 5 part of dispersion agent, 20 ~ 50 parts of Acrylic Acid Monomers.
The softening temperature of described hydrocarbon resin is 100 DEG C ~ 150 DEG C, and hydrocarbon resin is that one or more in C9 petroleum resin, C5 petroleum resin, the blended petroleum resin of C9/C5, DCPD petroleum resin, terpine resin, acrylic acid modified petroleum resin, hydrogenated petroleum resin, vinylbenzene/olefin copolymer, vinylbenzene/alpha-methyl styrene/olefin copolymer, polybutadiene oligomer are used in combination.This resinoid is owing to only containing hydrocarbon chain segment structure, and hydrolytic resistance is good, and acid-proof alkaline is good, can have very outstanding acidproof etching performance after making ink solidification.
Described acrylic polymer is polyfunctional group methacrylic ester, and the many curing speeds of functional group are fast, the hard acid resistance of film forming is good, but too much can cause loss of adhesion at material surface of ink, therefore selects the methacrylic ester of 3 ~ 5 functional groups.The ink being applicable to intaglio printing press printing has low viscous feature, adopt No. 4 and examine engler's cup between 12 ~ 20 seconds, therefore described acrylic polymer viscosity is between 1000 ~ 5000mPa.S/25 DEG C under 25 DEG C of conditions.Can be taken off ink by the NaOH alkali lye of 3% after ink solidification, therefore described acrylic polymer has carboxylic-acid functional group, and prepolymer acid number is between 50 ~ 400.Described acrylic polymer be polyester acrylate, carboxy(l)polyester acrylate, polyester chloride acrylic ester, epoxy acrylate, urethane acrylate one or more are used in combination.
Described stopper is without special restriction, conventional such as has: 2-Tert. Butyl Hydroquinone, 2,5-di-tert-butyl hydroquinone, tert-butyl catechol, toluhydroquinone, tertiary butyl para benzoquinone, the 6-tertiary butyl-2,4-xylenol, MEHQ, N-nitroso-N-phenylhydroxylamine ammonium salt, three (N-nitroso-group-N-Phenylhydroxylamine) aluminium salt etc.Stopper cited above can be used alone or mixture as two kinds of materials uses.
Described light trigger is 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-[4-(2-hydroxyl-oxethyl) phenyl]-1-acetone, 2, 4, 6-trimethylbenzoy-dipheny phosphine oxide, 2-hydroxy-2-methyl-1-phenyl-acetone, 2, 4, 6-trimethylbenzoyl phenyl phosphinic acid ethyl ester, 4-(dimethylamino)-phenylformic acid-(2-ethyl) own ester, methyl benzoylformate, 4-(dimethylamino)-phenylformic acid-(2-ethyl) own ester, 2, 4-diethyl thioxanthone, 4-phenyl benzophenone, o-benzoyl yl benzoic acid methyl esters, EDMAB, 2, 2-dimethoxy-1, 2-phenylbenzyl ketone, two kinds of 4-methyl benzophenone or the use of two or more mixtures.Benzophenone initiator causes effective, Stability Analysis of Structures, therefore 4-methyl benzophenone and 4-phenyl benzophenone are as preferably.
Described pigment is conventional phthalocyanine blue pigment, phthalocyanine green pigment.Comprise the one of B-15, B-15:1, B-15:2, B-15:3, B-15:4, B-15:6, G-7, G-36.Phthalocyanine pigment is bright in colour, the chemical stability that tinting strength is high, excellent, and good photostabilization, has the features such as high temperature nondiscoloration, acidproof etching performance after raising ink solidification.
Described dispersion agent is macromolecule dispersing agent, and this type of dispersion agent can accelerate the moistening of pigment particles, has good mobility when increasing the solid content of dispersion system.Reduce millbase granularity, increase mill efficiency and quantum of output.Show high color saturation and tinctorial strength, make pigment reach maximum tinting strength.Ink viscosity is steady in a long-term, can not produce hard sedimentation caking.
Described Acrylic Acid Monomer is β-propyloic acrylic ester, acidic functionality methacrylic ester, methylacryoyloxyethyl phthalic ester, tripropylene glycol acrylate, 1,6-hexylene glycol two propylene, HDDMA, two-trimethylolpropane tetra-acrylate, Viscoat 295, triethoxy Viscoat 295, tripropylene glycol and two kinds of acrylate, dipentaerythritol acrylate, ethoxy ethoxy ethoxy acrylate.Its common feature is that viscosity is low, substantially at 10 ~ 500mPa.S/25 DEG C, effectively reduces the overall viscosity of ink, realizes high speed printing on intaglio printing press.Acrylic Acid Monomer containing specific groups, has good sticking power on the metal material, and can be dissolved in buck, realizes buck and takes off ink.
Described UV gravure RFID ink obtains by following methods:
First hydrocarbon resin 10 ~ 30 parts, 0.1 ~ 1 part of stopper and Acrylic Acid Monomer 10 ~ 30 parts are devoted in stainless steel cauldron and mix, slowly be heated to 100 DEG C ~ 150 DEG C, stir until dissolve completely under the speed of 100-500rpm/min, be incubated 30 minutes, cool to that 60 DEG C ~ 80 DEG C degree add the acrylic polymer of 10 ~ 30 parts again, 0.1 ~ 1 part of stopper, 5 ~ 12 parts of light triggers, 5 ~ 10 parts of pigment, 1 ~ 5 part of dispersion agent stir and obtain mixed pulp.
Secondly mixed pulp is pumped into pearl ink machine, adopt zirconium pearl to mill, detect finess degree with fineness scraper plate and reach less than 5 μm, after qualified, obtain work in-process.
Finally work in-process are heated to 40 DEG C ~ 80 DEG C, add 10 ~ 40 parts of Acrylic Acid Monomers, fully stir 20 ~ 50 minutes at high speeds.
UV gravure RFID ink of the present invention has following beneficial effect:
1, this ink is applicable to intaglio printing press and flexible printing press, and adopts ultraviolet lamp wink-dry, increases work efficiency greatly.
2, strong acid can be resisted after ink setting to etch, can arbitrarily regulate etching acid concentration, increase etching solution temperature, increase etching period, meet the processing of all kinds of different RFID label tag.
3, easily alkali cleaning after ink setting etching, can by deinking in the NaOH solution 5 ~ 20 seconds of 3%.Effectively reach circuit surface clean without ink residue, ensure end product quality.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with citing, the present invention is further elaborated.Should be appreciated that citing described herein only in order to explain the present invention, be not intended to limit the present invention.
The preparation of the dark blue ink of embodiment 1 UV gravure RFID
By 10 parts of C9 oil hydrocarbon resins, 0.1 part of stopper ST-1 and 15 part of tripropylene glycol crylic acid ester mixture, be warmed to 140 DEG C of dissolvings.Add the special EB168 acrylic polymer of 15 parts of cyanogen, 0.2 part of tert-butyl catechol, 4 parts of 4-phenyl benzophenones, 4 parts of 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 10 parts of B-15:3 phthalocyanine blues, 2 parts of macromolecule dispersing agent BYK-163 again, 1000rpm/min stirs 30 minutes.Slurry is squeezed into pearl ink machine, is warmed to 60 DEG C and mills, fully mill after slurry fineness is less than 5 μm, to add 20 parts of β-propyloic acrylic esters, 20 part of 1,6-hexylene glycol two propylene stirs and can obtain the blue ink of UV gravure RFID.
The preparation of the light blue ink of embodiment 2 UV gravure RFID
By 10 parts of C5/C9 copolymer resinses, 0.1 part of stopper ST-1 and 15 part of tripropylene glycol crylic acid ester mixture, be warmed to 140 DEG C of dissolvings.Add the special EB168 acrylic polymer of 15 parts of cyanogen, 0.2 part of tert-butyl catechol, 4 parts of 4-phenyl benzophenones, 4 parts of 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 3 parts of B-15:3 phthalocyanine blues, 2 parts of macromolecule dispersing agent BYK-163 again, 1000rpm/min stirs 30 minutes.Slurry is squeezed into pearl ink machine, is warmed to 60 DEG C and mills, fully mill after slurry fineness is less than 5 μm, to add 23 parts of β-propyloic acrylic esters, 24 part of 1,6-hexylene glycol two propylene stirs and can obtain the blue ink of UV gravure RFID.
The preparation of the blue ink of embodiment 3 UV gravure RFID
By 10 parts of terpene modified C5 resins of C5,0.1 part of stopper ST-1 and 15 part of tripropylene glycol crylic acid ester mixture, be warmed to 140 DEG C of dissolvings.Add the special EB168 acrylic polymer of 15 parts of cyanogen, 0.2 part of tert-butyl catechol, 4 parts of 4-phenyl benzophenones, 4 parts of 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 6 parts of B-15:3 phthalocyanine blues, 2 parts of macromolecule dispersing agent BYK-163 again, 1000rpm/min stirs 30 minutes.Slurry is squeezed into pearl ink machine, is warmed to 60 DEG C and mills, fully mill after slurry fineness is less than 5 μm, to add 22 parts of β-propyloic acrylic esters, 22 part of 1,6-hexylene glycol two propylene stirs and can obtain the blue ink of UV gravure RFID.
The preparation of the dark green ink of embodiment 4 UV gravure RFID
By 10 parts of C9 hydrocarbon oil resins, 0.1 part of stopper ST-1 and 15 part of tripropylene glycol crylic acid ester mixture, be warmed to 140 DEG C of dissolvings.Add the special EB168 acrylic polymer of 15 parts of cyanogen, 0.2 part of tert-butyl catechol, 4 parts of 4-phenyl benzophenones, 4 parts of 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 10 parts of G-7 phthalocyanine greens, 2 parts of macromolecule dispersing agent BYK-168 again, 1000rpm/min stirs 30 minutes.Slurry is squeezed into pearl ink machine, is warmed to 60 DEG C and mills, fully mill after slurry fineness is less than 5 μm, add 20 parts of β-propyloic acrylic esters, 20 part of 1,6-hexylene glycol two propylene stirs and can obtain UV gravure RFID green ink.
The preparation of the light green ink of embodiment 5 UV gravure RFID
By 10 parts of C5/C9 copolymer resinses, 0.1 part of stopper ST-1 and 15 part of tripropylene glycol crylic acid ester mixture, be warmed to 140 DEG C of dissolvings.Add the special EB168 acrylic polymer of 15 parts of cyanogen, 0.2 part of tert-butyl catechol, 4 parts of 4-phenyl benzophenones, 4 parts of 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 3 parts of G-7 phthalocyanine greens, 2 parts of macromolecule dispersing agent BYK-168 again, 1000rpm/min stirs 30 minutes.Slurry is squeezed into pearl ink machine, is warmed to 60 DEG C and mills, fully mill after slurry fineness is less than 5 μm, add 23 parts of β-propyloic acrylic esters, 24 part of 1,6-hexylene glycol two propylene stirs and can obtain UV gravure RFID green ink.
The preparation of the light green ink of embodiment 6 UV gravure RFID
By 10 parts of terpene modified C5 resins of C5,0.1 part of stopper ST-1 and 15 part of tripropylene glycol crylic acid ester mixture, be warmed to 140 DEG C of dissolvings.Add the special EB168 acrylic polymer of 15 parts of cyanogen, 0.2 part of tert-butyl catechol, 4 parts of 4-phenyl benzophenones, 4 parts of 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 6 parts of G-7 phthalocyanine greens, 2 parts of macromolecule dispersing agent BYK-168 again, 1000rpm/min stirs 30 minutes.Slurry is squeezed into pearl ink machine, is warmed to 60 DEG C and mills, fully mill after slurry fineness is less than 5 μm, add 22 parts of β-propyloic acrylic esters, 22 part of 1,6-hexylene glycol two propylene stirs and can obtain UV gravure RFID green ink.
Be understandable that, for a person skilled in the art, technical scheme of the present invention and inventive concept be equal to and replace or change the protection domain that all should belong to the claim appended by the present invention.
Claims (9)
1. a preparation method for UV gravure RFID ink, is characterized in that: comprise the following steps:
1) first hydrocarbon resin 10 ~ 30 parts, 0.1 ~ 1 part of stopper and Acrylic Acid Monomer 20 ~ 50 parts are devoted in stainless steel cauldron and mix, slowly be heated to 100 DEG C ~ 150 DEG C, stir until dissolve completely under the speed of 100-500rpm/min, be incubated 30 minutes, cool to that 60 DEG C ~ 80 DEG C degree add the acrylic polymer of 10 ~ 30 parts again, 0.1 ~ 1 part of stopper, 5 ~ 12 parts of light triggers, 5 ~ 10 parts of pigment, 1 ~ 5 part of dispersion agent stir and obtain mixed pulp;
2) secondly mixed pulp is pumped into pearl ink machine, adopt zirconium pearl to mill, detect finess degree with fineness scraper plate and reach less than 5 μm, after qualified, obtain work in-process;
3) finally work in-process are heated to 40 DEG C ~ 80 DEG C, add 20 ~ 40 parts of Acrylic Acid Monomers, fully stir 20 ~ 50 minutes at high speeds.
2. the preparation method of UV gravure RFID ink according to claim 1, it is characterized in that: the softening temperature of described hydrocarbon resin is 100 DEG C ~ 150 DEG C, hydrocarbon resin is that one or more in C9 petroleum resin, C5 petroleum resin, the blended petroleum resin of C9/C5, DCPD petroleum resin, terpine resin, acrylic acid modified petroleum resin, hydrogenated petroleum resin, vinylbenzene/olefin copolymer, vinylbenzene/alpha-methyl styrene/olefin copolymer, polybutadiene oligomer are used in combination.
3. the preparation method of UV gravure RFID ink according to claim 1, is characterized in that: described acrylic polymer be polyester acrylate, carboxy(l)polyester acrylate, polyester chloride acrylic ester, epoxy acrylate, urethane acrylate one or more are used in combination.
4. the preparation method of UV gravure RFID ink according to claim 1, it is characterized in that: described stopper is 2-Tert. Butyl Hydroquinone, 2,5-di-tert-butyl hydroquinone, tert-butyl catechol, toluhydroquinone, tertiary butyl para benzoquinone, the 6-tertiary butyl-2,4-xylenol, MEHQ, N-nitroso-N-phenylhydroxylamine ammonium salt, three (N-nitroso-group-N-Phenylhydroxylamine) aluminium salt one or more are used in combination.
5. the preparation method of UV gravure RFID ink according to claim 1, it is characterized in that: described light trigger is 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 1-hydroxycyclohexyl phenyl ketone, 2-hydroxy-2-methyl-1-[4-(2-hydroxyl-oxethyl) phenyl]-1-acetone, 2, 4, 6-trimethylbenzoy-dipheny phosphine oxide, 2-hydroxy-2-methyl-1-phenyl-acetone, 2, 4, 6-trimethylbenzoyl phenyl phosphinic acid ethyl ester, 4-(dimethylamino)-phenylformic acid-(2-ethyl) own ester, methyl benzoylformate, 4-(dimethylamino)-phenylformic acid-(2-ethyl) own ester, 2, 4-diethyl thioxanthone, 4-phenyl benzophenone, o-benzoyl yl benzoic acid methyl esters, EDMAB, 2, 2-dimethoxy-1, 2-phenylbenzyl ketone, one or more of 4-methyl benzophenone are used in combination.
6. the preparation method of UV gravure RFID ink according to claim 1, is characterized in that: described pigment is pigment dyestuff.
7. the preparation method of UV gravure RFID ink according to claim 6, is characterized in that: described pigment dyestuff is the one of phthalocyanine blue pigment or phthalocyanine green.
8. the preparation method of UV gravure RFID ink according to claim 1, is characterized in that: described dispersion agent is macromolecule dispersing agent.
9. the preparation method of UV gravure RFID ink according to claim 1, it is characterized in that: described Acrylic Acid Monomer is β-propyloic acrylic ester, acidic functionality methacrylic ester, methylacryoyloxyethyl phthalic ester, tripropylene glycol acrylate, 1, 6-hexanediyl ester, 1, 6-hexanediol dimethacrylate, two-trimethylolpropane tetra-acrylate, Viscoat 295, triethoxy Viscoat 295, tripropylene glycol diacrylate, dipentaerythritol acrylate, one or more of ethoxy ethoxy ethoxy acrylate are used in combination.
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| CN103275537B (en) * | 2013-05-30 | 2015-06-24 | 苏州艾特斯环保材料有限公司 | Heatproof and rustproof coating containing DCCP alicyclic petroleum resin |
| CN103666061B (en) * | 2013-11-25 | 2016-03-23 | 铜陵方正塑业科技有限公司 | Anticorrosive ink of a kind of liquid photosensitive and preparation method thereof |
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| CN108485450B (en) * | 2018-04-12 | 2020-07-31 | 江西龙正科技发展有限公司 | Polyacrylic acid coating for wood and preparation method thereof |
| CN108912831A (en) * | 2018-07-17 | 2018-11-30 | 昆明理工大学 | A kind of environment-friendly water-based gravure ink and preparation method thereof |
| CN110774791B (en) * | 2019-10-10 | 2021-05-11 | 恩利克（浙江）智能装备有限公司 | Method for manufacturing conducting wire pattern of nano silver wire transparent conducting film by gravure transfer printing method |
| CN114316671A (en) * | 2022-02-11 | 2022-04-12 | 江苏可信电子材料有限公司 | High-flexibility white hole plugging ink and preparation method thereof |
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| US6322620B1 (en) * | 2000-11-16 | 2001-11-27 | National Starch And Chemical Investment Holding Corporation | Conductive ink composition |
| CN101197462A (en) * | 2006-12-07 | 2008-06-11 | 上海英内电子标签有限公司 | Production method for RFID etching aluminum antenna |
| CN101284928A (en) * | 2007-04-10 | 2008-10-15 | 国家淀粉及化学投资控股公司 | Electrically conductive UV-curable ink |
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