CN101665641A - Ultraviolet curing embossed printing ink - Google Patents
Ultraviolet curing embossed printing ink Download PDFInfo
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- CN101665641A CN101665641A CN200910190383A CN200910190383A CN101665641A CN 101665641 A CN101665641 A CN 101665641A CN 200910190383 A CN200910190383 A CN 200910190383A CN 200910190383 A CN200910190383 A CN 200910190383A CN 101665641 A CN101665641 A CN 101665641A
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- China
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- printing ink
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- ultraviolet curing
- embossed printing
- ink according
- Prior art date
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- Pending
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- 238000007639 printing Methods 0.000 title claims abstract description 24
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 9
- 239000000178 monomer Substances 0.000 claims abstract description 9
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 8
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 8
- 239000000049 pigment Substances 0.000 claims abstract description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
- YFPJFKYCVYXDJK-UHFFFAOYSA-N Diphenylphosphine oxide Chemical compound C=1C=CC=CC=1[P+](=O)C1=CC=CC=C1 YFPJFKYCVYXDJK-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- -1 Acrylic ester Chemical class 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims description 5
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- KTALPKYXQZGAEG-UHFFFAOYSA-N 2-propan-2-ylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(C(C)C)=CC=C3SC2=C1 KTALPKYXQZGAEG-UHFFFAOYSA-N 0.000 claims description 4
- 239000004258 Ethoxyquin Substances 0.000 claims description 4
- 125000005396 acrylic acid ester group Chemical group 0.000 claims description 4
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical group C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 4
- 239000006229 carbon black Substances 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 4
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 claims description 4
- 229940093500 ethoxyquin Drugs 0.000 claims description 4
- 235000019285 ethoxyquin Nutrition 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- AXDJCCTWPBKUKL-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-imino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]aniline;hydron;chloride Chemical compound Cl.C1=CC(=N)C(C)=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 AXDJCCTWPBKUKL-UHFFFAOYSA-N 0.000 claims description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 claims description 2
- VFZKVQVQOMDJEG-UHFFFAOYSA-N 2-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(=O)C=C VFZKVQVQOMDJEG-UHFFFAOYSA-N 0.000 claims description 2
- SSOONFBDIYMPEU-UHFFFAOYSA-N [3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propyl] prop-2-enoate Chemical compound OCC(CO)(CO)COCC(CO)(CO)COC(=O)C=C SSOONFBDIYMPEU-UHFFFAOYSA-N 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052737 gold Inorganic materials 0.000 abstract description 3
- 239000010931 gold Substances 0.000 abstract description 3
- 229910052709 silver Inorganic materials 0.000 abstract description 3
- 239000004332 silver Substances 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 2
- 238000007650 screen-printing Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 10
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 7
- 229940042596 viscoat Drugs 0.000 description 4
- 235000010215 titanium dioxide Nutrition 0.000 description 3
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical class C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000011087 paperboard Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 1
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical class C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 1
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to a high molecular polymer, relating to an ultraviolet curing embossed ink which comprises the following substances in parts by weight: 50-70 parts of acrylic resin, 10-30 partsof acrylate monomer, 5-12 parts of photoinitiator, 1-8 parts of pigment and 0.5-5 parts of auxiliary agent. The ink can be printed on gold and silver card paper, a PVC or a dumb film for one time bya mode of screen printing; and the colourful embossed effect can be formed by only one time of printing.
Description
Technical field
The present invention relates to high molecular polymer, particularly a kind of ultraviolet curing embossed printing ink.
Background technology
Ultraviolet curing embossed printing ink is a kind of screen printing ink, the irradiation of the ultraviolet lamp of process specific wavelength forms type effect lucuriant in design, this printing ink can be widely used in high-grade packing aspect, can be formulated into the bright-coloured embossed printing ink of shades of colour according to customer requirement, its curing speed and sticking power are all good.
Existing ultraviolet curing embossed printing ink all needs repeatedly to print and could form the type effect, the easy like this register trouble expense material consuming time that occurs.
Summary of the invention
A kind of UV curable ink that the objective of the invention is to deduct a percentage, this printing ink only needs one-step print, and ultraviolet light polymerization just can form type effect lucuriant in design.
The objective of the invention is to be achieved through the following technical solutions:
A kind of ultraviolet curing embossed printing ink is characterized in that, is made up of the material of following weight part proportioning:
Acrylic resin 50-70 part
Acrylic ester monomer 10-30 part
Light trigger 5-12 part
Pigment 1-8 part
Auxiliary agent 0.5-5 part
Described acrylic resin is the mixture or the pure acrylic acid ester resin of epoxy acrylate and urethane acrylate.
Described acrylic ester monomer is two or three a monomeric mixture in 1,6 one hexanediyl ester, propylene glycol diacrylate, tripropylene glycol two acrylic acid fat, Viscoat 295, ethoxyquin Viscoat 295, glycerol propoxylate triacrylate, the dipentaerythritol acrylate.
Described light trigger is 1-hydroxy-cyclohexyl phenyl ketone, 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 2; at least two kinds mixture in 4,6 one trimethylbenzoyls, one diphenyl phosphine oxide, the 2-isopropyl thioxanthone.
Described pigment is carbon black or titanium dioxide or fuchsin or bright red or golden red or phthalocyanine blue etc.
Described auxiliary agent is defoamer, flow agent and dispersion agent.The defoamer that defoamer, flow agent, dispersion agent, the BYK company that being fit to auxiliary agent of the present invention has Tego company to produce produces, flow agent, dispersion agent etc.
The UV-light that the high mercury lamp of ultraviolet light polymerization product utilization sends and quick initiated polymerization has the energy of saving, is beneficial to characteristics such as environmental protection, economy and high-performance.The present invention is to be the main body component with acrylic resin and acrylic monomer, light trigger is at specific wavelength---under the UV-irradiation, produce living radical through cracking or hydrogen transference, living radical causes unsaturated two being good in acrylate monomer and the acrylic resin, thereby make two strong become single strong make acrylic resin and the crosslinked generation solid superpolymers of Acrylic Acid Monomer, superpolymer and pigment wherein, it is membranaceous attached on the base material that auxiliary agents etc. are, form ink film, this printing ink thing is imprinted on the base material by the screen painting mode, through the uviolizing after fixing of specific wavelength, have type effect lucuriant in design simultaneously.
Being fit to base material of the present invention can be the mute film of gold and silver paperboard PVC card, BOPP.
Ultraviolet curing embossed printing ink of the present invention can prepare by following method:
A part of acrylate resin is added after dispersion agent, pigment stir, after three to five times fineness of three-roll grinder grinding reach below the 15um, add residual acrylic acid ester resin, acrylate monomer, light trigger, auxiliary agent again and be heated to 50 ℃ and stir, obtain ultraviolet curing embossed printing ink.
Printing ink provided by the invention can once be imprinted on it on gold and silver paperboard, PVC or the mute film by the screen painting mode, and it only needs one-step print just can form type effect lucuriant in design.
Embodiment
The present invention is described in further detail below by specific embodiment.Used proportioning raw materials all is a mass parts among the embodiment.
Embodiment 1
50 parts of epoxy acrylate 620-100
20 parts of urethane acrylate 6145-100
10 parts of ethoxyquin Viscoat 295s
5 parts of dipentaerythritol acrylates
2,4,6 one trimethylbenzoyls, one diphenyl phosphine oxide is 2 parts
1 part of 2-isopropyl thioxanthone
5 parts of 2-methyl-2-(4-morpholinyl)-1-[4-(4-(methylthio group) phenyl)-1-acetone
1 part of Tego UV680
1 part of Foamex N
3,510 0.3 parts of BYK
3 parts of carbon black MA-100
2 parts of Aerosil200
With 10 parts of 620-100 and 1 part of TegoUV680; 3 parts of carbon black MA-100 add and disperse cylinder; after stirring; grind three to five times with three-roll grinder; the fineness of mixture reaches below the 10um; add residue 620-100 and 20 parts of 6145-100 again; 10 parts of ethoxyquin Viscoat 295s; 5 parts of dipentaerythritol acrylates; 2 part 2; 4; 6 one trimethylbenzoyls, one diphenyl phosphine oxide; 1 part of 2-isopropyl thioxanthone; 5 parts of 2-methyl-2-(4-morpholinyl-1-[4-(methylthio group) phenyl]-1 part of Foamex N of 1-acetone; 0.3 part BYK3510; Aerosil200 is heated to 50 ℃ for 2 parts and stirs, and can obtain ultraviolet light polymerization black embossed printing ink.
Embodiment 2
Epoxy acrylate 6215-100 40
Urethane acrylate 611A-85 25
Glycerol propoxylate triacrylate 10
1-hydroxy cyclohexyl phenylketone 3
2,4,6 one trimethylbenzoyls, one diphenyl phosphine oxide 3
BYK?111 1
Foamex?N 1
BYK?3510 0.3
Titanium dioxide 15
Aerosil200 2
20 parts of 6215-100 and 111,15 parts of titanium dioxides of 1 part of BYK are added the dispersion cylinder; after stirring; grind three to five times with three-roll grinder; the mixture fineness reaches below the 10um; add 20 parts of 6215-100,25 parts of 611A-85,10 parts of glycerol propoxylate triacrylates, 3 parts of 1-hydroxy-cyclohexyl phenyl ketones again; 3 part 2,4,6 one trimethylbenzoyls, one diphenyl phosphine oxide; 1 part of Foamex N; 0.3 part BYK3510,2 parts of Aerosil200 are heated to 50 ℃ and stir, and can obtain ultraviolet light polymerization white embossed printing ink.
Embodiment 3
Epoxy acrylate 621-100 45
Urethane acrylate 6112-100 20
Trimethylolpropane triacrylate 10
Tripropylene glycol diacrylate 10
2,4,6 one trimethylbenzoyls, one diphenyl phosphine oxide 3
1-hydroxy-cyclohexyl phenyl ketone 5
Tego?UV681 1
Foamex?N 1
BYK3510 0.3
Fuchsin 3
Aerosil200 2
With 10 parts of 621-100 and 1 part of Tego UV680; 3 parts of fuchsins add and disperse cylinder; after stirring; grind three to five times with three-roll grinder; the mixture fineness reaches below the 10um; add 35 parts of 621-100 again; 20 parts of 6112-100; 10 parts of Viscoat 295s; 10 parts of tripropylene glycol diacrylates; 3 part 2; 4; 6 one trimethylbenzoyls, one diphenyl phosphine oxide; 5 parts of 1-hydroxy-cyclohexyl phenyl ketones; 1 part of Foamex N; 0.3 part BYK3510; 2 parts of Aerosil200 are heated to 50 ℃ and stir, and can obtain the red embossed printing ink of ultraviolet light polymerization.
Embodiment 4
Pure acrylic acid ester 6530B-40 70
Viscoat 295 14
2,4,6 one trimethylbenzoyls, one diphenyl phosphine oxide 4
2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone 5
Tego?UV680 1
Foamex?N 1
BYK?3510 0.3
Phthalocyanine blue 3
Aerosil200 2
20 parts of 6530B-40 and 1 part of Tego UV680,3 parts of phthalocyanine blues are added the dispersion cylinder; after stirring; grind three to five times with three-roll grinder; the mixture fineness reaches below the 10um; add 50 parts of 6530B-40,14 parts of Viscoat 295s, 4 part 2 again; 4; 6 one trimethylbenzoyls, one diphenyl phosphine oxide, 5 parts of 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 1 part of Foamex N, 0.3 part of BYK3510,2 parts of Aerosil200 is heated to 50 ℃ and stirs, and can obtain the blue embossed printing ink of ultraviolet light polymerization.
Claims (6)
1, a kind of ultraviolet curing embossed printing ink is characterized in that, is made up of the material of following weight part proportioning:
Acrylic resin 50-70 part
Acrylic ester monomer 10-30 part
Light trigger 5-12 part
Pigment 1-8 part
Auxiliary agent 0.5-5 part.
2, ultraviolet curing embossed printing ink according to claim 1 is characterized in that, described acrylic resin is the mixture or the pure acrylic acid ester resin of epoxy acrylate and urethane acrylate.
3, ultraviolet curing embossed printing ink according to claim 1, it is characterized in that described acrylic ester monomer is two or three a monomeric mixture in 1.6 1 hexanediyl esters, propylene glycol diacrylate, tripropylene glycol two acrylic acid fat, Viscoat 295, ethoxyquin Viscoat 295, glycerol propoxylate triacrylate, the dipentaerythritol acrylate.
4, ultraviolet curing embossed printing ink according to claim 1; it is characterized in that; described light trigger is 1-hydroxy-cyclohexyl phenyl ketone, 2-methyl-2-(4-morpholinyl)-1-[4-(methylthio group) phenyl]-1-acetone, 2; at least two kinds mixture in 4,6 one trimethylbenzoyls, one diphenyl phosphine oxide, the 2-isopropyl thioxanthone.
5, ultraviolet curing embossed printing ink according to claim 1 is characterized in that, described pigment is carbon black or titanium dioxide or bright red or golden letter of fuchsin or phthalocyanine blue.
6, ultraviolet curing embossed printing ink according to claim 1 is characterized in that, described auxiliary agent is defoamer, flow agent and dispersion agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910190383A CN101665641A (en) | 2009-09-25 | 2009-09-25 | Ultraviolet curing embossed printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910190383A CN101665641A (en) | 2009-09-25 | 2009-09-25 | Ultraviolet curing embossed printing ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101665641A true CN101665641A (en) | 2010-03-10 |
Family
ID=41802430
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910190383A Pending CN101665641A (en) | 2009-09-25 | 2009-09-25 | Ultraviolet curing embossed printing ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101665641A (en) |
Cited By (22)
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| CN102585608A (en) * | 2012-03-31 | 2012-07-18 | 武汉大学 | Method for manufacturing local grating by using UV (Ultraviolet) ink |
| CN102702848A (en) * | 2012-06-05 | 2012-10-03 | 无锡金桥精细油墨有限公司 | Low-halogen rotation UV (Ultraviolet) environment-friendly ink and preparation method thereof |
| CN103160204A (en) * | 2011-12-15 | 2013-06-19 | 北京天坛股份有限公司 | Preparation method of light-curing polyurethane modified carpentry paint |
| CN103602258A (en) * | 2013-12-06 | 2014-02-26 | 东周化学工业（昆山）有限公司 | Ultraviolet-curing finish coat adhesive |
| CN103666031A (en) * | 2013-11-23 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Printing ink for ultraviolet light curing intaglio printing and preparation method of printing ink |
| CN103666063A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Ultraviolet light curing silk-screen printing ink and preparation method thereof |
| CN103666035A (en) * | 2013-11-23 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV curing printing ink for screen printing and preparation method thereof |
| CN103666039A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Ultraviolet-curable printing ink for package printing and preparation method thereof |
| CN103666033A (en) * | 2013-11-23 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Novel UV (ultraviolet) curing silk-screen printing pearly-luster ink and preparation method thereof |
| CN103666036A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | Scratching-resistant antifouling UV cured printing ink and preparation method thereof |
| CN103709906A (en) * | 2014-01-15 | 2014-04-09 | 东周化学工业（昆山）有限公司 | White ultraviolet curing finishing coat |
| US8846778B2 (en) | 2008-12-22 | 2014-09-30 | Canadian Bank Note Company, Limited | Method and composition for printing tactile marks and security document formed therefrom |
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| CN108102457A (en) * | 2017-12-29 | 2018-06-01 | 江苏乘鹰新材料股份有限公司 | UV embossed printing ink compositions and preparation method thereof |
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| CN111205700A (en) * | 2020-02-28 | 2020-05-29 | 上海超彩油墨有限公司 | Tin printing screen printing ink based on UV curing |
| CN114075393A (en) * | 2020-08-19 | 2022-02-22 | 深圳正峰印刷有限公司 | Three-dimensional printing wear-resistant ink and printing method thereof |
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Cited By (30)
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