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CN102620878B - Capacitive micromachining ultrasonic sensor and preparation and application methods thereof - Google Patents

Capacitive micromachining ultrasonic sensor and preparation and application methods thereof Download PDF

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CN102620878B
CN102620878B CN201210068766.4A CN201210068766A CN102620878B CN 102620878 B CN102620878 B CN 102620878B CN 201210068766 A CN201210068766 A CN 201210068766A CN 102620878 B CN102620878 B CN 102620878B
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silicon dioxide
silicon
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CN102620878A (en
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赵立波
李支康
蒋庄德
赵玉龙
苑国英
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Zhejiang Hongzhen Intelligent Chip Co ltd
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Xian Jiaotong University
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Abstract

本发明提供了一种电容式微加工超声传感器及其制备与应用方法,其整体结构自上而下依次为:单晶硅振动薄膜、二氧化硅支柱,以及单晶硅基座,其中,所述二氧化硅支柱中间的部分为空腔,所述单晶硅振动薄膜的中间部分经硼离子重掺杂形成上电极,所述单晶硅基座的中间部分经硼离子重掺杂形成下电极,上电极和下电极的横向尺寸小于或等于空腔的横向尺寸且大于空腔横向尺寸的一半。本发明传感器结构简单、加工难度小、适用于批量生产;本发明的振动薄膜中无力敏电阻及电路的集成,薄膜厚度和质量均可进一步减小,从而实现更高灵敏度和更小量程压力的测量;本发明采用共振频率的偏移来测量压力的变化,因而输入与输出量之间保持着更好的线性关系。The present invention provides a capacitive micromachining ultrasonic sensor and its preparation and application method. Its overall structure is as follows from top to bottom: a single crystal silicon vibration film, a silicon dioxide pillar, and a single crystal silicon base, wherein the The middle part of the silicon dioxide pillar is a cavity, the middle part of the monocrystalline silicon vibrating film is heavily doped with boron ions to form an upper electrode, and the middle part of the single crystal silicon base is heavily doped with boron ions to form a lower electrode , the lateral dimension of the upper electrode and the lower electrode is less than or equal to the lateral dimension of the cavity and greater than half of the lateral dimension of the cavity. The sensor of the present invention has simple structure, low processing difficulty, and is suitable for mass production; the vibrating film of the present invention has no integration of force sensitive resistors and circuits, and the thickness and quality of the film can be further reduced, thereby achieving higher sensitivity and smaller range pressure. Measurement; the present invention uses the shift of resonance frequency to measure the change of pressure, thus maintaining a better linear relationship between input and output.

Description

一种电容式微加工超声传感器及其制备与应用方法A capacitive micro-machined ultrasonic sensor and its preparation and application method

技术领域technical field

本发明属于MEMS技术领域,涉及一种电容式微加工超声传感器及其制备与应用方法。The invention belongs to the technical field of MEMS, and relates to a capacitive micro-processing ultrasonic sensor and its preparation and application method.

背景技术Background technique

超微低压传感器主要用于微小压力的测量,其在工业控制、环保设备、医疗设备、航空航天以及军事武器等领域均有迫切的需求和广泛的应用,因而对该类传感器的研究具有极其重要的实用价值。Ultra-micro low-pressure sensors are mainly used for the measurement of tiny pressures. They have urgent needs and wide applications in the fields of industrial control, environmental protection equipment, medical equipment, aerospace and military weapons, so the research on this type of sensors is extremely important. practical value.

目前,基于MEMS((Micro Electro-Mechanical Systems,微型机械电子系统)技术的硅微微压传感器在压力传感器领域已占统治地位,并得到商业化的广泛应用。硅微微压传感器按其工作原理,主要可分为以下三种:压阻式、电容式以及谐振式。压阻式微压传感器主要利用硅的压阻效应,通过电压变化来测量压力大小。虽然其输出与输入具有良好的线性关系,但硅薄膜中力敏电阻的温度敏感性要求传感器必须实行温度补偿,增加测量的复杂性,同时硅膜中惠斯登电桥的集成致使其薄膜厚度难以在保证测量精度的条件下进一步减小,进而难以进一步降低量程,提高灵敏度。电容式硅微压力传感器利用电容极距变化将压力变化转化为电容的变化,有着温度稳定性好、灵敏度高、功耗低、进一步微型化变得相对简单等一系列优点,但其输出与输入的线性度较差。谐振式硅微压力传感器是利用谐振梁的固有频率随施加轴向力的改变而改变来实现压力测量的,虽然其测量精度、稳定性和分辨力都优于以上两种,但结构复杂,加工难度较大。目前,硅微微压力传感器的量程主要在1000Pa左右,最小的可达300Pa。由于上述结构自身的限制,致使其难以进一步实现更低量程与更高灵敏度的超低微压测量。因而本文欲将一种基于MEMS技术更具有结构和性能优势的CMUT(Capactive Micromachined Ultrasonic Transducer,电容式微加工超声传感器)用于超微压力测量。CMUT是MEMS技术的重要研究方向之一,它具有良好的机电特性、更小的薄膜质量、更高的共振频率(可达几十MHz)和品质因子(可达几百)等特点,这为进一步实现更高灵敏度和更小量程压力的测量提供可能;其结构简单、易加工、易阵列、易集成等特点为低成本、短周期、高效化批量生产以及复杂电路集成提供诸多优势。目前,CMUT主要用于超声成像、生化物质检测等方面,在超低微压测量领域的研究还未见相关报道。At present, silicon micro-pressure sensors based on MEMS (Micro Electro-Mechanical Systems) technology have dominated the field of pressure sensors and have been widely used commercially. According to their working principles, silicon micro-pressure sensors mainly It can be divided into the following three types: piezoresistive, capacitive and resonant. The piezoresistive micro-pressure sensor mainly uses the piezoresistive effect of silicon to measure the pressure through voltage changes. Although its output has a good linear relationship with the input, but The temperature sensitivity of the force sensitive resistor in the silicon film requires that the sensor must implement temperature compensation, which increases the complexity of the measurement. At the same time, the integration of the Wheatstone bridge in the silicon film makes it difficult to further reduce the film thickness under the condition of ensuring the measurement accuracy. It is difficult to further reduce the range and improve the sensitivity. The capacitive silicon micro pressure sensor uses the change of the capacitance pole distance to convert the pressure change into the capacitance change, which has good temperature stability, high sensitivity, low power consumption, and relatively simple further miniaturization. A series of advantages, but the linearity of its output and input is poor.The resonant silicon micro pressure sensor uses the natural frequency of the resonant beam to change with the change of the applied axial force to achieve pressure measurement, although its measurement accuracy and stability and resolution are better than the above two, but the structure is complex and difficult to process. At present, the range of silicon micro pressure sensors is mainly around 1000Pa, and the smallest can reach 300Pa. Due to the limitations of the above structure itself, it is difficult to further realize Ultra-low micro-pressure measurement with lower range and higher sensitivity. Therefore, this paper intends to use a CMUT (Capactive Micromachined Ultrasonic Transducer, capacitive micromachined ultrasonic sensor) based on MEMS technology with more structural and performance advantages for ultra-micro pressure measurement. CMUT It is one of the important research directions of MEMS technology. It has the characteristics of good electromechanical properties, smaller film quality, higher resonance frequency (up to dozens of MHz) and quality factor (up to hundreds of) and so on. It is possible to achieve higher sensitivity and smaller range pressure measurement; its simple structure, easy processing, easy array, easy integration and other characteristics provide many advantages for low cost, short cycle, high-efficiency mass production and complex circuit integration. At present, CMUT It is mainly used in ultrasonic imaging, detection of biochemical substances, etc., and there are no relevant reports in the field of ultra-low and micro-pressure measurement.

发明内容Contents of the invention

本发明所要解决的技术问题是提供一种电容式微加工超声传感器及其制备与应用方法,将电容式微加工超声传感器应用于微小压力测量,以解决目前超低微压测量领域的难题,实现灵敏度高于150Hz/Pa和量程低于300Pa的超低微压测量。The technical problem to be solved by the present invention is to provide a capacitive micro-machined ultrasonic sensor and its preparation and application method. The capacitive micro-machined ultrasonic sensor is applied to micro-pressure measurement to solve the current problems in the field of ultra-low micro-pressure measurement, and to achieve a sensitivity higher than 150Hz/Pa and ultra-low micro-pressure measurement with a range below 300Pa.

为解决以上技术问题,本发明采用以下技术方案:In order to solve the above technical problems, the present invention adopts the following technical solutions:

一种电容式微加工超声传感器,其整体结构自上而下依次为:单晶硅振动薄膜、二氧化硅支柱,以及单晶硅基座,其中,所述二氧化硅支柱中间的部分为空腔,所述单晶硅振动薄膜的中间部分经硼离子重掺杂形成上电极,所述单晶硅基座的中间部分经硼离子重掺杂形成下电极,上电极和下电极的横向尺寸小于或等于空腔的横向尺寸且大于空腔横向尺寸的一半。A capacitive micro-machined ultrasonic sensor, its overall structure from top to bottom is: a single crystal silicon vibration film, a silicon dioxide pillar, and a single crystal silicon base, wherein the middle part of the silicon dioxide pillar is a cavity , the middle part of the monocrystalline silicon vibrating film is heavily doped with boron ions to form an upper electrode, the middle part of the single crystal silicon base is heavily doped with boron ions to form a lower electrode, and the lateral dimensions of the upper electrode and the lower electrode are less than Or equal to the transverse dimension of the cavity and greater than half of the transverse dimension of the cavity.

作为本发明的优选实施例,所述单晶硅振动薄膜的厚度为0.06~0.12um;As a preferred embodiment of the present invention, the thickness of the single crystal silicon vibrating film is 0.06-0.12um;

作为本发明的优选实施例,所述单晶硅振动薄膜的有效振动薄膜横向尺寸为5μm~15μm,所述有效振动薄膜为空腔以上的振动薄膜部分;As a preferred embodiment of the present invention, the lateral size of the effective vibration film of the single crystal silicon vibration film is 5 μm to 15 μm, and the effective vibration film is the part of the vibration film above the cavity;

作为本发明的优选实施例,所述空腔的横向尺寸与有效振动薄膜的横向尺寸相等,为5~15μm,空腔高度与二氧化硅支柱相等,为0.08~0.15μm;As a preferred embodiment of the present invention, the lateral dimension of the cavity is equal to that of the effective vibrating film, which is 5-15 μm, and the height of the cavity is equal to the silica pillar, which is 0.08-0.15 μm;

作为本发明的优选实施例,所述上电极和下电极的电阻率小于10-3Ω·cm。As a preferred embodiment of the present invention, the resistivity of the upper electrode and the lower electrode is less than 10 −3 Ω·cm.

一种电容式微加工超声传感器的制备方法,包括以下步骤:A method for preparing a capacitive micromachined ultrasonic sensor, comprising the following steps:

(1)取<111>晶向单晶硅,采用局部离子注入技术在单晶硅中部注入硼离子,使其电阻率小于10-3Ω·cm,其中,重掺杂单晶硅部分形成下电极,其余部分为CMUT基座;(1) Take <111> crystal silicon, and use local ion implantation technology to implant boron ions in the middle of the single crystal silicon, so that the resistivity is less than 10 -3 Ω·cm. Among them, the heavily doped single crystal silicon part forms the lower electrodes, and the rest are CMUT bases;

(2)采用等离子体增强化学气相沉积此处是否需要该技术的英文缩写:PECVD技术在CMUT基座上沉积二氧化硅层,然后光刻该二氧化硅层,形成空腔图形窗口,接着用缓冲刻蚀液刻蚀掉暴露于图形窗口中二氧化硅层,剩余的二氧化硅层形成二氧化硅支柱,最后采用化学机械抛光CMP技术对二氧化硅支柱的上表面进行抛光,形成第一部分;(2) Plasma-enhanced chemical vapor deposition Is the English abbreviation of this technology needed here: PECVD technology deposits a silicon dioxide layer on the CMUT base, and then photolithographically etches the silicon dioxide layer to form a cavity pattern window, and then uses The buffer etching solution etches away the silicon dioxide layer exposed in the graphics window, and the remaining silicon dioxide layer forms the silicon dioxide pillar. Finally, the upper surface of the silicon dioxide pillar is polished by chemical mechanical polishing CMP technology to form the first part ;

(3)取SOI晶片,采用干法氧化技术将SOI晶片的顶部单晶硅薄片的上表面进行干法氧化形成二氧化硅层,其中氧化形成的二氧化硅层的厚度与生成二氧化硅层时所消耗的单晶硅薄片厚度之比为1:0.44,未被氧化的部分称为单晶硅层;(3) Take the SOI wafer, dry oxidize the upper surface of the top monocrystalline silicon slice of the SOI wafer by dry oxidation technology to form a silicon dioxide layer, and the thickness of the silicon dioxide layer formed by oxidation is the same as that of the silicon dioxide layer formed The ratio of the thickness of the monocrystalline silicon flakes consumed during the process is 1:0.44, and the unoxidized part is called the monocrystalline silicon layer;

(4)用缓冲刻蚀液将步骤(3)形成的二氧化硅层刻蚀掉,露出未被氧化的单晶硅层,然后,在单晶硅层的中部采用局部离子注入技术重掺杂硼离子,使其电阻率小于10-3Ω·cm,其中,重掺杂单晶硅部分形成上电极,最后对单晶硅层的上表面进行化学机械抛光,形成第二部分;(4) Etch the silicon dioxide layer formed in step (3) with a buffer etchant to expose the unoxidized single crystal silicon layer, and then use local ion implantation technology to heavily dope the middle of the single crystal silicon layer Boron ions to make the resistivity less than 10 -3 Ω·cm, wherein the heavily doped single crystal silicon part forms the upper electrode, and finally chemical mechanical polishing is performed on the upper surface of the single crystal silicon layer to form the second part;

(5)在真空环境下,将步骤(2)得到的第一部分和步骤(4)得到的第二部分进行阳极键合,其中,第一部分的二氧化硅支柱的上表面与第二部分的顶部未被氧化单晶硅层的上表面进行键合;因为SOI晶片有底部衬底硅、埋层二氧化硅和顶部单晶硅薄片之分,此处只说是第二部分单晶硅层是否无法区分衬底单晶硅和顶部单晶硅层。(5) In a vacuum environment, the first part obtained in step (2) and the second part obtained in step (4) are anodically bonded, wherein the upper surface of the silicon dioxide pillar of the first part is connected to the top of the second part The upper surface of the unoxidized single crystal silicon layer is bonded; because the SOI wafer is divided into the bottom substrate silicon, the buried silicon dioxide and the top single crystal silicon slice, here only the second part of the single crystal silicon layer is It is not possible to distinguish between the substrate monocrystalline silicon and the top monocrystalline silicon layer.

(6)将步骤(5)得到的器件采用湿法刻蚀自上而下依次去除SOI晶片的衬底单晶硅和80%的埋层二氧化硅,然后再用缓冲刻蚀液刻蚀剩余20%的埋层二氧化硅。(6) The device obtained in step (5) is wet-etched from top to bottom to remove the substrate monocrystalline silicon and 80% of the buried silicon dioxide of the SOI wafer, and then etch the remaining silicon dioxide with a buffer etching solution. 20% buried silicon dioxide.

一种电容式微加工超声传感器的应用方法,所述电容式微加工超声传感器用于实现灵敏度高于150Hz/Pa和量程低于300Pa的超低微压测量,具体方法为:通过仿真分析和实验手段共同确定CMUT的最佳工作点,即偏置直流电压,同时确定固有谐振频率以及该频率点的交流信号,交流信号的电压幅值与偏置电压之和应小于CMUT塌陷电压,以耦合系数最大为原则;在所确定的偏置直流电压和谐振频率交流信号激励下,CMUT发生谐振,将其置于微小压力环境中,由于压力作用在CMUT振动薄膜上,改变CMUT振动状态,失去谐振,此时调节交流信号频率,使CMUT再次发生谐振,记录该谐振频率,计算固有谐振频率与该压力作用下的谐振频率差Δf,再由压力和频移之间的函数关系P=Δf/k,即可求得所测压力值,实现压力测量。An application method of a capacitive micro-machined ultrasonic sensor, the capacitive micro-machined ultrasonic sensor is used to achieve ultra-low micro-pressure measurement with a sensitivity higher than 150 Hz/Pa and a range lower than 300 Pa, the specific method is: jointly determine through simulation analysis and experimental means The best operating point of the CMUT is the bias DC voltage. At the same time, determine the natural resonant frequency and the AC signal at this frequency point. The sum of the voltage amplitude of the AC signal and the bias voltage should be less than the collapse voltage of the CMUT. The principle is to maximize the coupling coefficient ; Under the excitation of the determined bias DC voltage and the AC signal of the resonant frequency, the CMUT resonates, and it is placed in a micro-pressure environment. Because the pressure acts on the CMUT vibration film, the vibration state of the CMUT is changed and the resonance is lost. At this time, the adjustment The frequency of the AC signal causes the CMUT to resonate again, record the resonant frequency, calculate the difference Δf between the natural resonant frequency and the resonant frequency under the pressure, and then use the functional relationship between pressure and frequency shift P=Δf/k to obtain Get the measured pressure value to realize pressure measurement.

本发明基于CMUT的超低微压传感器及其制备方法至少具有以下优点:The CMUT-based ultra-low micro-pressure sensor and preparation method thereof of the present invention have at least the following advantages:

(1)相对于压阻式微压传感器,本发明CMUT振动薄膜中无力敏电阻及电路的集成,薄膜厚度和质量均可以进一步减小,从而可以实现更高灵敏度和更小量程压力的测量。(1) Compared with the piezoresistive micro-pressure sensor, the CMUT vibrating film of the present invention has no integration of force-sensing resistors and circuits, and the thickness and quality of the film can be further reduced, so that the measurement of higher sensitivity and smaller range pressure can be realized.

(2)相对于电容式微压传感器,本发明采用共振频率的偏移来测量压力的变化,因而输入与输出量之间保持着更好的线性关系。(2) Compared with the capacitive micro-pressure sensor, the present invention uses the shift of the resonant frequency to measure the change of the pressure, thus maintaining a better linear relationship between the input and output.

(3)相对于谐振式微压力传感器,本发明结构简单,加工难度小,适于批量生产,易于集成。(3) Compared with the resonant micro-pressure sensor, the present invention has a simple structure, less difficulty in processing, is suitable for mass production, and is easy to integrate.

(4)由于本发明CMUT结构只由单晶硅和二氧化硅两种测量材料组成,而这两种材料膨胀系数相同,因而结构适用于高温环境,其热膨胀系数非常相近(其中二氧化硅热膨胀系数为2.3×10-6/℃,单晶硅为2.6×10-6/℃),因此该结构还可用于高温环境中微小压力的测量。(4) Since the CMUT structure of the present invention is only composed of two measurement materials, single crystal silicon and silicon dioxide, and the expansion coefficients of these two materials are the same, the structure is suitable for high temperature environments, and its thermal expansion coefficients are very similar (wherein the thermal expansion of silicon dioxide The coefficient is 2.3×10 -6 /℃, single crystal silicon is 2.6×10 -6 /℃), so this structure can also be used for the measurement of micro pressure in high temperature environment.

附图说明Description of drawings

图1为本发明基于CMUT的超低微压传感器的结构示意图;Fig. 1 is the structural representation of the ultra-low pressure sensor based on CMUT of the present invention;

图2为本发明传感器的制备工艺流程图。Fig. 2 is a flow chart of the preparation process of the sensor of the present invention.

具体实施方式Detailed ways

下面结合附图对本发明一种电容式微加工超声传感器及其制备与应用方法做详细描述:A capacitive micromachining ultrasonic sensor of the present invention and its preparation and application method are described in detail below in conjunction with the accompanying drawings:

请参阅附图1,本发明一种电容式微加工超声传感器的整体结构自上而下依次为:单晶硅振动薄膜1、二氧化硅支柱2、空腔6以及单晶硅基座3。其中,单晶硅振动薄膜1中部经硼离子重掺杂区域形成上电极4,也即振动薄膜1同时用作CMUT上电极,上电极4与振动薄膜1为一体化结构;单晶硅基座3中部经硼离子重掺杂区域形成CMUT下电极5,也即单晶硅基座3同时用作下电极,下电极5与基座3为一体化结构。Please refer to accompanying drawing 1, the overall structure of a capacitive micromachined ultrasonic sensor of the present invention is as follows from top to bottom: single crystal silicon diaphragm 1, silicon dioxide pillar 2, cavity 6 and single crystal silicon base 3. Among them, the upper electrode 4 is formed in the middle part of the monocrystalline silicon vibration film 1 through the heavily doped region of boron ions, that is, the vibration film 1 is also used as the upper electrode of the CMUT, and the upper electrode 4 and the vibration film 1 are an integrated structure; the single crystal silicon base The middle part of the CMUT is heavily doped with boron ions to form the lower electrode 5 of the CMUT, that is, the monocrystalline silicon base 3 is also used as the lower electrode, and the lower electrode 5 and the base 3 are of an integrated structure.

所述单晶硅振动薄膜1除用于CMUT振动薄膜外,还用于上电极。一方面薄膜厚度应尽量小,以减小薄膜质量,进而提高CMUT的灵敏度,实现更小量程压力测量;另一方面,厚度太小将增加串联电阻,影响上电极4的导电性能;因此薄膜厚度范围应为0.06~0.12um。另外,根据薄膜振动频率的理论计算公式可知,要获得高的共振频率,应尽量减小表面半径,因此本发明中振动薄膜1的有效振动薄膜横向尺寸范围为5μm~15μm,有效振动薄膜区域即为振动薄膜1的空腔6以上或未与二氧化硅支柱2键合的薄膜部分。上电极4的横向尺寸应小于或等于空腔6横向尺寸,但应等于或大于其横向尺寸一半,以减小寄生电容,增大耦合系数为设计原则。The single crystal silicon vibration film 1 is not only used for the CMUT vibration film, but also used for the upper electrode. On the one hand, the thickness of the film should be as small as possible to reduce the mass of the film, thereby improving the sensitivity of the CMUT and realizing a smaller range of pressure measurement; on the other hand, too small a thickness will increase the series resistance and affect the conductivity of the upper electrode 4; Should be 0.06 ~ 0.12um. In addition, according to the theoretical calculation formula of the vibration frequency of the membrane, it can be known that to obtain a high resonance frequency, the surface radius should be reduced as much as possible. Therefore, the effective vibration membrane lateral dimension of the vibration membrane 1 in the present invention ranges from 5 μm to 15 μm, and the effective vibration membrane area is It is above the cavity 6 of the vibration film 1 or the part of the film that is not bonded to the silicon dioxide support 2 . The lateral size of the upper electrode 4 should be smaller than or equal to the lateral size of the cavity 6, but should be equal to or larger than half of the lateral size, so as to reduce the parasitic capacitance and increase the coupling coefficient as the design principle.

所述空腔6为圆形或多边形,其横向尺寸与有效振动薄膜横向尺寸相同,其尺寸范围为5μm~15μm,高度与二氧化硅支柱2的高度相同。The cavity 6 is circular or polygonal, its lateral dimension is the same as that of the effective vibrating film, its size ranges from 5 μm to 15 μm, and its height is the same as that of the silicon dioxide pillar 2 .

所述二氧化硅支柱2的高度尽量小,以减小空腔高度,增大耦合系数,进而提高灵敏度,其高度范围为0.08~0.15μm。The height of the silicon dioxide pillar 2 is as small as possible to reduce the cavity height, increase the coupling coefficient, and further improve the sensitivity, and the height range is 0.08-0.15 μm.

所述单晶硅基座3除用作整个CMUT结构的底座外,其中部经硼离子重掺杂后还用作下电极5,下电极5与单晶硅基座3为一体化结构。下电极5的横向尺寸应小于或等于空腔6横向尺寸,但应等于或大于其横向尺寸一半,以减小寄生电容,增大耦合系数为设计原则。The monocrystalline silicon base 3 is not only used as the base of the entire CMUT structure, but also serves as the lower electrode 5 after the middle part is heavily doped with boron ions. The lower electrode 5 and the single crystal silicon base 3 are an integrated structure. The lateral size of the lower electrode 5 should be smaller than or equal to the lateral size of the cavity 6, but should be equal to or larger than half of the lateral size, so as to reduce the parasitic capacitance and increase the coupling coefficient as the design principle.

所述上电极4及下电极5经硼离子重掺杂后电阻率应小于10-4Ω·cm,以减小串联电阻,降低功耗。After the upper electrode 4 and the lower electrode 5 are heavily doped with boron ions, the resistivity should be less than 10 −4 Ω·cm, so as to reduce series resistance and reduce power consumption.

所述上电极4、下电极5以及空腔6形状相同,同轴且关于中心轴对称。The upper electrode 4 , the lower electrode 5 and the cavity 6 have the same shape, are coaxial and symmetrical about the central axis.

所述振动薄膜1、单晶硅基座3的材料为单晶硅,支柱2的材料为二氧化硅,这两种材料线性热膨胀系数非常接近,因而该结构满足高温环境中微小压力测量的要求。The material of the vibrating membrane 1 and the monocrystalline silicon base 3 is monocrystalline silicon, and the material of the pillar 2 is silicon dioxide. The linear thermal expansion coefficients of these two materials are very close, so this structure meets the requirements of micro pressure measurement in high temperature environment .

本发明传感器,其主要结构参数如下:Sensor of the present invention, its main structural parameters are as follows:

空腔高度:0.08~0.15μmCavity height: 0.08~0.15μm

振动薄膜厚度:0.06~0.12umThickness of vibration film: 0.06~0.12um

有效振动薄膜横向尺寸:5μm~15μm。Effective vibrating film lateral size: 5μm ~ 15μm.

下面结合附图2,对本发明一种电容式微加工超声传感器的制备工艺流程进行详细描述:Below in conjunction with accompanying drawing 2, the preparation technological process of a kind of capacitive micromachining ultrasonic sensor of the present invention is described in detail:

(1)取<111>晶向单晶硅,并采用局部离子注入技术在单晶硅中部注入硼离子,使其电阻率小于10-3Ω·cm,其中重掺杂单晶硅部分形成下电极5,下电极5同时与其余未掺杂单晶硅一起形成CMUT基座3;取SOI晶片,顶部单晶硅薄片厚度为150nm。(1) Take <111> crystal silicon, and use local ion implantation technology to implant boron ions in the middle of the single crystal silicon, so that the resistivity is less than 10 -3 Ω·cm, and the heavily doped single crystal silicon part forms the lower The electrode 5 and the bottom electrode 5 form the CMUT base 3 together with the rest of the undoped single crystal silicon; take the SOI wafer, and the thickness of the top single crystal silicon slice is 150nm.

(2)采用等离子体增强化学气相沉积(Plasma Enhanced Chemical VaporDeposition,简称PECVD)技术在CMUT基座3上沉积二氧化硅层,严格控制二氧化硅层的厚度,以精确控制由二氧化硅形成的空腔支柱的高度,进而精确控制整个结构空腔的高度;采用干法氧化技术将SOI晶片顶部单晶硅薄片8上表面进行干法氧化形成二氧化硅层,SOI晶片顶部单晶硅薄片8中未被氧化的单晶硅层形成单晶硅层10,其中氧化形成的二氧化硅层的厚度与生成二氧化硅层时所消耗的单晶硅薄片厚度之比为1:0.44。(2) A silicon dioxide layer is deposited on the CMUT base 3 by using plasma enhanced chemical vapor deposition (Plasma Enhanced Chemical Vapor Deposition, PECVD for short), and the thickness of the silicon dioxide layer is strictly controlled to precisely control the formation of silicon dioxide. The height of the cavity pillars, and then accurately control the height of the entire structural cavity; dry oxidation technology is used to dry the upper surface of the single crystal silicon slice 8 on the top of the SOI wafer to form a silicon dioxide layer, and the single crystal silicon slice 8 on the top of the SOI wafer The single crystal silicon layer 10 is formed from the unoxidized single crystal silicon layer, wherein the ratio of the thickness of the silicon dioxide layer formed by oxidation to the thickness of the single crystal silicon flakes consumed when forming the silicon dioxide layer is 1:0.44.

(3)光刻CMUT基座3上层的二氧化硅层形成空腔图形窗口,采用20:1的缓冲刻蚀液以最短的时间完全刻蚀掉暴露于图形窗口中二氧化硅层,剩余的二氧化硅层则形成二氧化硅支柱2;同时用20:1的缓冲刻蚀液以最短的时间刻蚀掉右侧SOI晶片上的二氧化硅层,露出单晶硅层10的上表面。(3) The silicon dioxide layer on the upper layer of the CMUT base 3 is photolithographically formed to form a cavity pattern window, and the silicon dioxide layer exposed to the pattern window is completely etched away in the shortest time with a 20:1 buffer etching solution, and the remaining The silicon dioxide layer forms the silicon dioxide pillars 2; at the same time, the silicon dioxide layer on the right SOI wafer is etched away in the shortest time with a 20:1 buffer etchant, exposing the upper surface of the single crystal silicon layer 10.

(4)采用化学机械抛光技术对左侧二氧化硅支柱2的上表面进行抛光;在右侧单晶硅层10的中部采用局部离子注入技术重掺杂硼离子,使其电阻率小于10-3Ω·cm,其中重掺杂单晶硅部分形成上电极4,上电极4同时与其余未掺杂单晶硅一起形成CMUT振动薄膜1,然后再对薄膜1的上表面进行化学机械抛光。(4) The upper surface of the silicon dioxide pillar 2 on the left is polished using chemical mechanical polishing technology; the middle part of the monocrystalline silicon layer 10 on the right is heavily doped with boron ions using local ion implantation technology to make the resistivity less than 10 − 3 Ω·cm, in which the heavily doped single crystal silicon part forms the upper electrode 4, and the upper electrode 4 forms the CMUT vibration film 1 together with the rest of the undoped single crystal silicon, and then the upper surface of the film 1 is chemically mechanically polished.

(5)在真空环境下,将左侧二氧化硅支柱2的上表面与右侧振动薄膜1的上表面进行阳极键合,其中SOI晶片在上,基座3在下。(5) In a vacuum environment, perform anodic bonding on the upper surface of the silicon dioxide pillar 2 on the left side and the upper surface of the vibrating membrane 1 on the right side, wherein the SOI wafer is on top and the base 3 is on the bottom.

(6)采用湿法刻蚀自上而下依次去除SOI的衬底单晶硅和80%的埋层二氧化硅,然后再用20:1的缓冲刻蚀液以最短的时间刻蚀剩余20%埋层二氧化硅,以保证振动薄膜1的表面平滑度。(6) Use wet etching to remove the SOI substrate monocrystalline silicon and 80% of the buried silicon dioxide from top to bottom, and then use a 20:1 buffer etchant to etch the remaining 20% in the shortest time. % buried silicon dioxide to ensure the surface smoothness of the vibrating membrane 1.

本发明一种电容式微加工超声传感器,应用于压力测量领域,其工作原理为:在工作电压(偏置直流电压)作用下,CMUT薄膜因受到静电引力而发生变形,向基底靠拢,此时再施加一定频率的交流信号,CMUT薄膜将产生与信号频率相同的强迫振动,改变交流信号的频率,当该输入频率等于CMUT结构自身固有频率时,CMUT将发生共振。在无压力作用时CMUT的共振频率为结构自身的固有频率,当有压力作用其薄膜上时,CMUT的共振频率将会发生相应的偏移,不同的压力对应着不同频率偏移,在一定范围内压力和频移保持着良好的线性关系:Δf=kP或P=Δf/k。其中Δf为加压后CMUT的共振频率f相对于固有共振频率f0的频移,即Δf=f0-f,其单位为Hz;k为传感器灵敏度,单位为Hz/Pa;P为被测压力值,单位为Pa。因此通过CMUT共振频率的变化即可计算出对应的压力值。The present invention is a capacitive micro-machined ultrasonic sensor, which is used in the field of pressure measurement. Its working principle is: under the action of working voltage (bias DC voltage), the CMUT film is deformed due to electrostatic attraction and moves closer to the substrate. When an AC signal of a certain frequency is applied, the CMUT film will generate forced vibrations with the same frequency as the signal, changing the frequency of the AC signal. When the input frequency is equal to the natural frequency of the CMUT structure itself, the CMUT will resonate. When there is no pressure, the resonance frequency of the CMUT is the natural frequency of the structure itself. When there is pressure on the film, the resonance frequency of the CMUT will shift accordingly. Different pressures correspond to different frequency shifts. In a certain range Internal pressure and frequency shift maintain a good linear relationship: Δf=kP or P=Δf/k. Among them, Δf is the frequency shift of the resonant frequency f of the CMUT after pressurization relative to the natural resonant frequency f 0 , that is, Δf=f 0 -f, and its unit is Hz; k is the sensor sensitivity, and the unit is Hz/Pa; P is the measured Pressure value, the unit is Pa. Therefore, the corresponding pressure value can be calculated by changing the resonance frequency of the CMUT.

本发明一种电容式微加工超声传感器应用于压力测量领域时,其具体应用方法为:通过仿真分析和实验手段共同确定CMUT的最佳工作点,即偏置直流电压(一般为塌陷电压的80%~90%),同时确定固有谐振频率以及该频率点的交流信号,交流信号的电压幅值与偏置电压之和应小于CMUT塌陷电压,以耦合系数最大为原则。在所确定偏置直流电压和谐振频率交流信号激励下,CMUT发生谐振,将其置于微小压力环境中,由于压力作用在CMUT振动薄膜上,改变CMUT振动状态,失去谐振,此时调节交流信号频率,使CMUT再次发生谐振,记录该谐振频率,计算固有谐振频率与该压力作用下的谐振频率差Δf,再由压力和频移之间的函数关系P=Δf/k,即可求得所测压力值,实现压力测量。When a capacitive micromachining ultrasonic sensor of the present invention is applied to the field of pressure measurement, its specific application method is: jointly determine the optimal operating point of the CMUT through simulation analysis and experimental means, that is, the bias DC voltage (generally 80% of the collapse voltage ~90%), and at the same time determine the natural resonance frequency and the AC signal at this frequency point, the sum of the voltage amplitude of the AC signal and the bias voltage should be less than the CMUT collapse voltage, and the principle is to maximize the coupling coefficient. Under the excitation of the determined bias DC voltage and the AC signal of the resonant frequency, the CMUT resonates, and it is placed in a micro-pressure environment. Because the pressure acts on the CMUT vibration film, the vibration state of the CMUT is changed and the resonance is lost. At this time, the AC signal is adjusted. Frequency, so that the CMUT resonates again, record the resonant frequency, calculate the difference Δf between the natural resonant frequency and the resonant frequency under the pressure, and then use the functional relationship P=Δf/k between the pressure and the frequency shift to obtain the obtained Measure the pressure value to realize the pressure measurement.

本发明不限于以上所述实施方式,在条件和技术允许条件下,单晶硅振动薄膜1还可不采用SOI晶片通过氧化工艺减薄顶部单晶硅薄片厚度的方法,直接选用顶部单晶硅薄片符合振动薄膜1厚度要求的SOI晶片;其次振动薄膜1的材料还可选用多晶硅,以提高薄膜机械性能和减小厚度、质量为原则。空腔6及上电极4、下电极5的形状除以上所述形状外以及相关结构尺寸可根据实际应用情况灵活选取,以增大有效电容、提高耦合系数与灵敏度为设计原则。在应用于高温环境时,由于重掺杂单晶硅的导电性能根据温度而变化,因而应根据不同的温度情况,采用适宜的工作电压,以保证传感器对微小压力的准确测量。另外,本结构中上电极4与下电极5之间无电隔绝层,因此要在后续测量电路设置相应的过流保护电路,防止薄膜发生塌陷后对结构自身以及其他相关设备的损坏。The present invention is not limited to the above-described embodiments. Under conditions and technology permitting conditions, the monocrystalline silicon vibration film 1 can not use the method of thinning the thickness of the top monocrystalline silicon slice through the oxidation process of the SOI wafer, and directly select the top single crystal silicon slice. An SOI wafer that meets the thickness requirements of the vibrating membrane 1; secondly, the material of the vibrating membrane 1 can also be polysilicon, in order to improve the mechanical properties of the membrane and reduce the thickness and quality. The shape of the cavity 6, the upper electrode 4, and the lower electrode 5 can be flexibly selected according to the actual application in addition to the above-mentioned shapes, and the design principles are to increase the effective capacitance, improve the coupling coefficient and sensitivity. When used in a high-temperature environment, since the conductivity of heavily doped single crystal silicon changes according to temperature, an appropriate working voltage should be used according to different temperature conditions to ensure accurate measurement of small pressure by the sensor. In addition, there is no electrical isolation layer between the upper electrode 4 and the lower electrode 5 in this structure, so a corresponding overcurrent protection circuit should be installed in the subsequent measurement circuit to prevent damage to the structure itself and other related equipment after the film collapses.

本发明一种基于CMUT的超微压力传感器的主要性能指标如下:The main performance index of a kind of ultramicro pressure sensor based on CMUT of the present invention is as follows:

测量范围:0~100PaMeasuring range: 0~100Pa

测量精度:优于2%FSMeasurement accuracy: better than 2%FS

灵敏度:180Hz/PaSensitivity: 180Hz/Pa

工作温度:-50~300℃Working temperature: -50~300℃

以上所述仅为本发明的一种实施方式,不是全部或唯一的实施方式,本领域普通技术人员通过阅读本发明说明书而对本发明技术方案采取的任何等效的变换,均为本发明的权利要求所涵盖。The above is only one embodiment of the present invention, not all or the only embodiment. Any equivalent transformation of the technical solution of the present invention adopted by those of ordinary skill in the art by reading the description of the present invention is the right of the present invention. covered by the requirements.

Claims (7)

1.一种电容式微加工超声传感器,其特征在于:其整体结构自上而下依次为:单晶硅振动薄膜(1)、二氧化硅支柱(2),以及单晶硅基座(3),其中,所述二氧化硅支柱(2)中间的部分为空腔(6),所述单晶硅振动薄膜(1)的中间部分经硼离子重掺杂形成上电极,所述单晶硅基座(3)的中间部分经硼离子重掺杂形成下电极,上电极和下电极的横向尺寸小于或等于空腔(6)的横向尺寸且大于空腔(6)横向尺寸的一半。1. A capacitive micro-machined ultrasonic sensor, characterized in that: its overall structure from top to bottom is: monocrystalline silicon vibration film (1), silicon dioxide pillar (2), and monocrystalline silicon base (3) , wherein the middle part of the silicon dioxide pillar (2) is a cavity (6), the middle part of the single crystal silicon vibrating film (1) is heavily doped with boron ions to form an upper electrode, and the single crystal silicon The middle part of the base (3) is heavily doped with boron ions to form a lower electrode, and the lateral size of the upper electrode and the lower electrode is less than or equal to the lateral size of the cavity (6) and greater than half of the lateral size of the cavity (6). 2.如权利要求1所述的一种电容式微加工超声传感器,其特征在于:所述单晶硅振动薄膜(1)的厚度为0.06~0.12um。2. A capacitive micro-machined ultrasonic sensor according to claim 1, characterized in that: the thickness of the single crystal silicon diaphragm (1) is 0.06-0.12um. 3.如权利要求1所述的一种电容式微加工超声传感器,其特征在于:所述单晶硅振动薄膜(1)的有效振动薄膜横向尺寸为5μm~15μm,所述有效振动薄膜为空腔(6)以上的振动薄膜部分。3. A capacitive micro-machined ultrasonic sensor according to claim 1, characterized in that: the effective vibration film lateral size of the single crystal silicon vibration film (1) is 5 μm to 15 μm, and the effective vibration film is a cavity (6) Above the diaphragm part. 4.如权利要求3所述的一种电容式微加工超声传感器,其特征在于:所述空腔(6)的横向尺寸与有效振动薄膜的横向尺寸相等,为5~15μm,空腔(6)高度与二氧化硅支柱(2)相等,为0.08~0.15μm。4. A capacitive micro-machined ultrasonic sensor according to claim 3, characterized in that: the transverse dimension of the cavity (6) is equal to the transverse dimension of the effective vibrating film, which is 5-15 μm, and the cavity (6) The height is equal to that of the silica pillar (2), and is 0.08-0.15 μm. 5.如权利要求1所述的一种电容式微加工超声传感器,其特征在于:所述上电极和下电极的电阻率小于10-3Ω·cm。5. A capacitive micromachined ultrasonic sensor according to claim 1, characterized in that: the resistivity of the upper electrode and the lower electrode is less than 10 -3 Ω·cm. 6.一种电容式微加工超声传感器的制备方法,其特征在于:包括以下步骤:(1)取<111>晶向单晶硅,采用局部离子注入技术在单晶硅中部注入硼离子,使其电阻率小于10-3Ω·cm,其中,重掺杂单晶硅部分形成下电极(5),其余部分为CMUT基座(3);6. A method for preparing a capacitive micromachining ultrasonic sensor, which is characterized in that it comprises the following steps: (1) Take <111> oriented monocrystalline silicon, and implant boron ions in the middle of the monocrystalline silicon by using local ion implantation technology to make it The resistivity is less than 10 -3 Ω·cm, wherein the heavily doped single crystal silicon part forms the lower electrode (5), and the rest is the CMUT base (3); (2)采用等离子体增强化学气相沉积技术在CMUT基座(3)上沉积二氧化硅层,然后光刻该二氧化硅层,形成空腔图形窗口,接着用缓冲刻蚀液刻蚀掉暴露于图形窗口中二氧化硅层,剩余的二氧化硅层形成二氧化硅支柱(2),最后采用化学机械抛光技术对二氧化硅支柱(2)的上表面进行抛光,形成第一部分;(2) Deposit a silicon dioxide layer on the CMUT base (3) by using plasma-enhanced chemical vapor deposition technology, and then photoetch the silicon dioxide layer to form a cavity pattern window, and then etch away the exposed A silicon dioxide layer is formed in the graphics window, and the remaining silicon dioxide layer forms a silicon dioxide pillar (2), and finally the upper surface of the silicon dioxide pillar (2) is polished by chemical mechanical polishing technology to form the first part; (3)取SOI晶片,采用干法氧化技术将SOI晶片的顶部单晶硅薄片的上表面进行干法氧化形成二氧化硅层,其中氧化形成的二氧化硅层的厚度与生成二氧化硅层时所消耗的单晶硅薄片厚度之比为1:0.44,未被氧化的部分称为单晶硅层;(3) Take the SOI wafer, dry oxidize the upper surface of the top monocrystalline silicon slice of the SOI wafer by dry oxidation technology to form a silicon dioxide layer, and the thickness of the silicon dioxide layer formed by oxidation is the same as that of the silicon dioxide layer formed The ratio of the thickness of the monocrystalline silicon flakes consumed during the process is 1:0.44, and the unoxidized part is called the monocrystalline silicon layer; (4)用缓冲刻蚀液将步骤(3)形成的二氧化硅层刻蚀掉,露出未被氧化的单晶硅层,然后,在单晶硅层的中部采用局部离子注入技术重掺杂硼离子,使其电阻率小于10-3Ω·cm,其中,重掺杂单晶硅部分形成上电极(4),最后对单晶硅层的上表面进行化学机械抛光,形成第二部分;(4) Etch the silicon dioxide layer formed in step (3) with a buffer etchant to expose the unoxidized single crystal silicon layer, and then use local ion implantation technology to heavily dope the middle of the single crystal silicon layer Boron ions to make the resistivity less than 10 -3 Ω·cm, wherein the heavily doped single crystal silicon part forms the upper electrode (4), and finally chemical mechanical polishing is performed on the upper surface of the single crystal silicon layer to form the second part; (5)在真空环境下,将步骤(2)得到的第一部分和步骤(4)得到的第二部分进行阳极键合,其中,第一部分的二氧化硅支柱(2)的上表面与第二部分的单晶硅层的上表面进行键合;(5) In a vacuum environment, the first part obtained in step (2) and the second part obtained in step (4) are anodically bonded, wherein the upper surface of the silicon dioxide pillar (2) of the first part is connected to the second part The upper surface of part of the monocrystalline silicon layer is bonded; (6)将步骤(5)得到的器件采用湿法刻蚀自上而下依次去除SOI晶片的衬底单晶硅和80%的埋层二氧化硅,然后再用缓冲刻蚀液刻蚀剩余20%的埋层二氧化硅。(6) Remove the substrate monocrystalline silicon and 80% of the buried layer silicon dioxide of the SOI wafer by wet etching from top to bottom, and then etch the remaining silicon dioxide with buffer etching solution. 20% buried silicon dioxide. 7.一种电容式微加工超声传感器的应用方法,其特征在于:所述电容式微加工超声传感器用于实现灵敏度高于150Hz/Pa和量程低于300Pa的超低微压测量,具体方法为:通过仿真分析和实验手段共同确定CMUT的最佳工作点,即偏置直流电压,同时确定固有谐振频率以及该频率点的交流信号,交流信号的电压幅值与偏置电压之和应小于CMUT塌陷电压,以耦合系数最大为原则;在所确定的偏置直流电压和谐振频率交流信号激励下,CMUT发生谐振,将其置于微小压力环境中,由于压力作用在CMUT振动薄膜上,改变CMUT振动状态,失去谐振,此时调节交流信号频率,使CMUT再次发生谐振,记录该谐振频率,计算固有谐振频率与该压力作用下的谐振频率差Δf,再由压力和频移之间的函数关系P=Δf/k,即可求得所测压力值,实现压力测量。7. An application method of a capacitive micro-processed ultrasonic sensor, characterized in that: the capacitive micro-processed ultrasonic sensor is used to realize ultra-low micro-pressure measurement with a sensitivity higher than 150Hz/Pa and a range lower than 300Pa, the specific method is: through simulation Analytical and experimental means jointly determine the optimal operating point of the CMUT, that is, the bias DC voltage, and at the same time determine the natural resonant frequency and the AC signal at this frequency point. The sum of the voltage amplitude of the AC signal and the bias voltage should be less than the CMUT collapse voltage. The principle is to maximize the coupling coefficient; under the excitation of the determined bias DC voltage and the AC signal of the resonant frequency, the CMUT resonates, and it is placed in a micro-pressure environment. Since the pressure acts on the CMUT vibration film, the vibration state of the CMUT is changed. When the resonance is lost, adjust the frequency of the AC signal to make the CMUT resonate again, record the resonance frequency, calculate the difference Δf between the natural resonance frequency and the resonance frequency under the pressure, and then use the functional relationship between pressure and frequency shift P=Δf /k, the measured pressure value can be obtained to realize pressure measurement.
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