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CN102559019B - Agate-imitating spray coating material - Google Patents

Agate-imitating spray coating material Download PDF

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Publication number
CN102559019B
CN102559019B CN201110449385.6A CN201110449385A CN102559019B CN 102559019 B CN102559019 B CN 102559019B CN 201110449385 A CN201110449385 A CN 201110449385A CN 102559019 B CN102559019 B CN 102559019B
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Prior art keywords
coating
powder coating
agate
water
fineness
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CN201110449385.6A
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CN102559019A (en
Inventor
张亦彬
潘雨沛
赵鑫
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Haining Economic Development Industrial Park Development And Construction Co Ltd
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Individual
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Abstract

The invention relates to a new spray coating material and a preparation method of the spray coating material. The spray coating material can endow a surface layer with agate luster and texture and is fully elegant when used on the surface layer to be spray-coated. The spray coating material can be used as an inner wall paint, or directly spray-coated on the outer layer of sanitary wares; the use method of the spray coating material is identical to that of common paint; and the spray coating material has the characteristics of delicate coating, convenience for operation, corrosion resistance and the like.

Description

Imitative agate material spray material
Technical field
The present invention relates to building decoration field, especially relate to a kind of imitative agate material spray material and preparation method thereof.
Background technology
Agate is a kind of valuable stone material, and its quality is lubricious, and material is hard, and glossiness is good, always by the ornament as a kind of top grade.But agate is only limitted to make accessory, and jewellery, involve great expense, and cannot popularize use.
Along with people live the raising gradually of degree, the domestic environment of people to oneself is also more and more paid attention to.Various household art work emerges in an endless stream.Only with regard to coating, kind is just very abundant.The sorting technique of coating is a lot, usually has following several sorting technique:
(1) water-borne coatings, solvent reducible coatings, powder coating, high solid coating etc. can be divided into by the form of coating;
(2) brush coating, sprayed coating, roll coat enamel, dip-coating paint, electrophoretic paint etc. can be divided into by constructional method;
(3) priming paint, floating coating (surfacer), finish paint, finishing paint etc. can be divided into by working procedure;
(4) decorative paint, protective system, electrically conducting coating, rust proof paint, high-temperature resistant coating, thermo-paint, thermal insulating coating, frie retardant coating, waterproof paint etc. can be divided into by function
(5) building coating, can lacquer, car paint, aircraft coating, appliance finishes, woodwork coating, bridge coating, plastic paint, paper coating etc. can be divided into by purposes.
(6) home paint can be divided into interior wall coating, exterior coating, wood lacquer, metal paint, floor paint.
(7) divide (antifouling paste, insullac, electric conduction paint, heat-resisting varnish etc.) by paint film property
(8) divide (alkyd, epoxy, chlorinated rubber, vinylformic acid, urethane, ethene etc.) by filmogen
Summary of the invention
Technical problem solved by the invention is to provide a kind of new spray material and preparation method thereof.Spray material of the present invention is used in the aspect that need spray, and aspect can be made to obtain gloss and the texture of agate, very elegant in appearance.It as a kind of interior wall coating, or can be painted on sanitary ware skin, and using method is identical with common coating, has coating fineness, easy to operate, the feature such as corrosion-resistant.
Imitative agate material spray material of the present invention, the raw material primarily of following weight part is made:
Adjacent benzene-type unsaturated polyester resin: 18 ~ 22;
Metaphenylene unsaturated polyester resin: 6 ~ 10;
Benzoyl peroxide: 1 ~ 4;
Tributyl phosphate: 0.03 ~ 0.07;
Quartz sand: 25 ~ 35;
Aluminium powder: 10 ~ 14;
Tung oil: 0.2 ~ 0.4;
Calcium carbonate: 3.0 ~ 4.5;
Glycerol: 1.5 ~ 3.0;
Talcum powder: 4 ~ 8.
Imitative agate material spray material of the present invention, the raw material preferably primarily of following weight part is made:
Adjacent benzene-type unsaturated polyester resin: 20;
Metaphenylene unsaturated polyester resin: 8;
Benzoyl peroxide: 2;
Tributyl phosphate: 0.05;
Quartz sand: 30;
Aluminium powder: 12;
Tung oil: 0.3;
Calcium carbonate: 4.0;
Glycerol: 2.0;
Talcum powder: 6.
Imitative agate material spray material of the present invention, also comprises appropriate pigment in wherein said raw material.According to customer need, appropriate various known coatings pigment can be added, to enrich the color variety of coating.
The preparation method of imitative agate material spray material of the present invention, is fully uniformly mixed every raw material, makes powder coating.
The using method of imitative agate material spray material of the present invention, first takes powder coating 1 weight part, then adds the water allotment of 4 weight parts; During allotment, first infiltrate powder coating with a part of cold water of total Water, moisten even after, then remainder cool water heating to boiling, pour in moistening powder coating, rapid stirring, make colloid wherein fully dissolve dispersion, brushing of constructing after cooling.Adopt spray gun spraying effect better.
Raw material used in the present invention is:
Unsaturated polyester resin: the unsaturated linear polyester resin that unsaturated dibasic acid and dibasic alcohol chemical combination generate.Containing double bond in its molecular backbone chain.Be generally thick liquid.Crosslinking reaction can be there is with vinyl monomer under the effect of initiator or heat and form occurring matrix type vibrin.Conventional unsaturated dibasic acid is MALEIC ANHYDRIDE, and dibasic alcohol is ethylene glycol, and vinyl monomer is vinylbenzene etc.Be mainly used in glass reinforced plastic processed and coating, also for glue mud and molding powder etc.But namely become clear yellow viscous liquid after oxidation, outer appearnce is like rapeseed oil.Property more tough and tensile, ageing-resistant, smooth finish and the transparency good.Be this product main binder, select adjacent benzene-type to do matrix resin, metaphenylene makes surface resin layer.
Quartz sand: also known as silica flour.Refer to containing the more river sand, extra large sand, mountain sand etc. of silicon-dioxide.Except main component silicon-dioxide, also containing the impurity such as ferric oxide, mica.Be used as stopping composition in this product, select powdery.Fineness controls between 200 ~ 350 orders.
Aluminium powder: also known as aluminium hydrate powder, is commonly called as silver powder.Have the metal color of silver color, quality is light, and buoyancy is large, strong covering power, good stability, and the performance of reflection light and heat is good.Be used in this product improving intensity and shock-resistance, and any surface finish can be made attractive in appearance, select industrial goods.Fineness controls between 200 ~ 350 orders.
Tung oil: the oil of being squeezed out by the seeds of a tung oil tree.Oil colours is yellowish-brown, relative density 0.925 ~ 0.945 (15/15 DEG C), 2 ~ 3 DEG C, zero pour, iodine number 160 ~ 170.Be a kind of epochmaking siccative oil, main component is the glyceryl ester of eleostearic acid, and containing a small amount of oleic acid and linoleic glyceryl ester.Oil film is dry rapidly, does not firmly glue, can water-fast, alkaline-resisting, fast light and atmospheric corrosion resistance.It is the good raw material manufacturing paint.For the solubility promoter of this spray material.
Calcium carbonate: white crystals or powder, density 2.5 ~ 2.6 gram per centimeter 3be water-ground limestone.Meet acid and can release carbonic acid gas, pole is insoluble in water, and the easy moisture absorption of water breakthrough, has slight alkalinity.The density of water-ground limestone is large, and easily precipitate, the consumption thus in coating is not easily excessive, can use together with the filler of other suspensions.The density of light calcium carbonate is little, and particle is thin, tinting strength and opacifying power good.Additive is used as in this spray material.Light calcium carbonate should be adopted.Fineness controls more than 300 orders.
Tributyl phosphate: have another name called phosphate n-butyl.Colorless and odorless liquid.Proportion 0.976, boiling point 289 DEG C, fusing point less than-80 DEG C.Slightly water-soluble, be dissolved in organic solvent.As the softening agent of plastics and the extraction agent etc. of rare metal, be also used as heat exchange medium.Defoamer is used as in this spray material.
Glycerol: be commonly called as glycerine, the thick liquid that no color or smell is pleasantly sweet.Density 1.26 gram per centimeter 3, boiling point 290 DEG C, fusing point 17.9 DEG C.Can be miscible with any ratio with water, the freezing point of water can be reduced, have great water absorbability, slightly be dissolved in ethanol and ether, be insoluble to chloroform.Be used as softening agent in this product.
Talcum powder: white, nattierblue or faint yellow oblique system, Cheng Liufang or rhombus platelike crystal, normal slabbing, flakey or compact mass aggregate.There is vitreous luster, have soapy feeling, dead-soft, chemical property torpescence.Density 2.7 ~ 2.8 gram per centimeter 3, hardness 1.Have many uses.Be used as in this coating stopping composition and levelling, satiny dose, fineness requirement reaches more than 300 orders.
Benzoyl peroxide: have another name called benzoyl peroxide, dibenzoyl peroxide.Colourless or white crystalline powder.Slightly smell, fusing point 103 ~ 106 DEG C, is slightly soluble in water, is slightly dissolved in ethanol, is dissolved in ether, acetone, chloroform and benzene.Dry product extremely unstable, easy firing, can explode when clashing into, being heated or rubbing.Burn when adding sulfuric acid.The water of 25% ~ 30% should be injected during storage.Initiator is used as in this coating.
Pigment: add in right amount.
Water: appropriate, tap water.
Spray material of the present invention is used in the aspect that need spray, and aspect can be made to obtain gloss and the texture of agate, very elegant in appearance.It as a kind of interior wall coating, or can be painted on sanitary ware skin, and using method is identical with common coating, has coating fineness, easy to operate, the feature such as corrosion-resistant.There is good promotion prospect and economic worth.
Embodiment
For further illustrating the present invention, illustrate with the following Examples:
Embodiment 1:
A kind of imitative agate material spray material, the raw material primarily of following weight part is made:
Adjacent benzene-type unsaturated polyester resin: 18;
Metaphenylene unsaturated polyester resin: 10;
Benzoyl peroxide: 1;
Tributyl phosphate: 0.07;
Quartz sand: 25;
Aluminium powder: 14;
Tung oil: 0.2;
Calcium carbonate: 4.5;
Glycerol: 1.5;
Talcum powder: 8.
Above-mentioned every raw material is fully uniformly mixed, makes powder coating.
The using method of above-mentioned imitative agate material spray material, first takes powder coating 1 weight part, then adds the water allotment of 4 weight parts; During allotment, first infiltrate powder coating with a part of cold water of total Water, moisten even after, then remainder cool water heating to boiling, pour in moistening powder coating, rapid stirring, make colloid wherein fully dissolve dispersion, brushing of constructing after cooling.Adopt spray gun spraying effect better.
Embodiment 2:
A kind of imitative agate material spray material, the raw material primarily of following weight part is made:
Adjacent benzene-type unsaturated polyester resin: 22;
Metaphenylene unsaturated polyester resin: 6;
Benzoyl peroxide: 4;
Tributyl phosphate: 0.03;
Quartz sand: 35;
Aluminium powder: 10;
Tung oil: 0.4;
Calcium carbonate: 3.0;
Glycerol: 3.0;
Talcum powder: 4.
Above-mentioned every raw material is fully uniformly mixed, makes powder coating.
The using method of above-mentioned imitative agate material spray material, first takes powder coating 1 weight part, then adds the water allotment of 4 weight parts; During allotment, first infiltrate powder coating with a part of cold water of total Water, moisten even after, then remainder cool water heating to boiling, pour in moistening powder coating, rapid stirring, make colloid wherein fully dissolve dispersion, brushing of constructing after cooling.Adopt spray gun spraying effect better.
Embodiment 3:
A kind of imitative agate material spray material, the raw material primarily of following weight part is made:
Adjacent benzene-type unsaturated polyester resin: 20;
Metaphenylene unsaturated polyester resin: 8;
Benzoyl peroxide: 2;
Tributyl phosphate: 0.05;
Quartz sand: 30;
Aluminium powder: 12;
Tung oil: 0.3;
Light calcium carbonate: 4.0;
Glycerol: 2.0;
Talcum powder: 6;
Pigment: 0.1.
Above-mentioned every raw material is fully uniformly mixed, makes powder coating.
The using method of above-mentioned imitative agate material spray material, first takes powder coating 1 weight part, then adds the water allotment of 4 weight parts; During allotment, first infiltrate powder coating with a part of cold water of total Water, moisten even after, then remainder cool water heating to boiling, pour in moistening powder coating, rapid stirring, make colloid wherein fully dissolve dispersion, brushing of constructing after cooling.Adopt spray gun spraying effect better.
The coating that above-described embodiment obtains through spray gun spraying, makes inner wall surface present gloss and the quality of similar agate material, has good decorative effect in inner wall surface.The present invention implements this coating in 15 family volunteer families, and the family of 100% all thinks and which gives good decorative effect, and coatingsurface has the slickness and brightness that are similar to agate surface, and sense of touch also has certain imitative agate effect.This coating also can be used on the articles for use such as furniture, sanitary equipment, can obtain similar effect.
Above-described embodiment is only be described the preferred embodiment of the present invention; not scope of the present invention is limited; under not departing from the present invention and designing the prerequisite of spirit; the various distortion that the common engineering technical personnel in this area make technical scheme of the present invention and improvement, all should fall in protection domain that claims of the present invention determine.

Claims (6)

1. an imitative agate material spray material, is characterized in that: the raw material primarily of following weight part is made:
The fineness of wherein said quartz sand controls between 200 ~ 350 orders, and the fineness of described aluminium powder controls between 200 ~ 350 orders, and the fineness of described calcium carbonate controls more than 300 orders, and talcous fineness is more than 300 orders.
2. imitative agate material spray material according to claim 1, is characterized in that: the raw material primarily of following weight part is made:
3. imitative agate material spray material according to claim 1 and 2, is characterized in that: also comprise appropriate pigment in described raw material.
4. the preparation method of the imitative agate material spray material described in claim 1 or 2, is characterized in that: be fully uniformly mixed by every raw material, make powder coating.
5. the powder coating for preparing of preparation method according to claim 4.
6. the using method of powdered material according to claim 5, is characterized in that: first take powder coating 1 weight part, then adds the water allotment of 4 weight parts; During allotment, first infiltrate powder coating with a part of cold water of total Water, moisten even after, then remainder cool water heating to boiling, pour in moistening powder coating, rapid stirring, make colloid wherein fully dissolve dispersion, brushing of constructing after cooling.
CN201110449385.6A 2011-12-29 2011-12-29 Agate-imitating spray coating material Active CN102559019B (en)

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Application Number Priority Date Filing Date Title
CN201110449385.6A CN102559019B (en) 2011-12-29 2011-12-29 Agate-imitating spray coating material

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CN102559019A CN102559019A (en) 2012-07-11
CN102559019B true CN102559019B (en) 2015-02-11

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103483993B (en) * 2013-09-03 2016-02-10 蚌埠市鸿安精密机械有限公司 A kind of low-temperature curable powder coating
CN103509384A (en) * 2013-09-04 2014-01-15 安徽祈艾特电子科技有限公司 Pearlescent powder paint

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1075725A (en) * 1993-03-18 1993-09-01 赵琢玉 Reinforced ultra-thin man-made serialized board, its production method, and combined furniture made of the serialized board
CN1079136A (en) * 1993-05-27 1993-12-08 方庆仁 Technique for making composite artificial agate bathtub

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1075725A (en) * 1993-03-18 1993-09-01 赵琢玉 Reinforced ultra-thin man-made serialized board, its production method, and combined furniture made of the serialized board
CN1079136A (en) * 1993-05-27 1993-12-08 方庆仁 Technique for making composite artificial agate bathtub

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Address before: 226500, Jiangsu, Rugao moved by the town, moved through the village of twenty-four groups

Patentee before: Rugao Fu Steel Machinery Fittings Co., Ltd.