CN104151949B - A kind of multi-colour spraying plastic paint - Google Patents
A kind of multi-colour spraying plastic paint Download PDFInfo
- Publication number
- CN104151949B CN104151949B CN201410409888.4A CN201410409888A CN104151949B CN 104151949 B CN104151949 B CN 104151949B CN 201410409888 A CN201410409888 A CN 201410409888A CN 104151949 B CN104151949 B CN 104151949B
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- plastic paint
- spraying plastic
- colour spraying
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- 239000003973 paint Substances 0.000 title claims abstract description 25
- 239000004033 plastic Substances 0.000 title claims abstract description 20
- 238000005507 spraying Methods 0.000 title claims abstract description 18
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 33
- -1 Polytetramethylene Polymers 0.000 claims abstract description 17
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004793 Polystyrene Substances 0.000 claims abstract description 11
- 239000012948 isocyanate Substances 0.000 claims abstract description 11
- 229920002223 polystyrene Polymers 0.000 claims abstract description 11
- WHNBDXQTMPYBAT-UHFFFAOYSA-N 2-butyloxirane Chemical compound CCCCC1CO1 WHNBDXQTMPYBAT-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000010425 asbestos Substances 0.000 claims abstract description 10
- 235000019362 perlite Nutrition 0.000 claims abstract description 10
- 229910052895 riebeckite Inorganic materials 0.000 claims abstract description 10
- 229920002545 silicone oil Polymers 0.000 claims abstract description 10
- 239000012965 benzophenone Substances 0.000 claims abstract description 9
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000049 pigment Substances 0.000 claims abstract description 8
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- ARXVXVOLXMVYIT-UHFFFAOYSA-N 3-methylbutyl 2-(dimethylamino)benzoate Chemical compound CC(C)CCOC(=O)C1=CC=CC=C1N(C)C ARXVXVOLXMVYIT-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 239000011490 mineral wool Substances 0.000 claims abstract description 6
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 6
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004014 plasticizer Substances 0.000 claims abstract description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 12
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 5
- 210000002268 wool Anatomy 0.000 claims description 5
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical class COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 150000002513 isocyanates Chemical class 0.000 claims 1
- 239000003513 alkali Substances 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 6
- 239000010451 perlite Substances 0.000 abstract description 6
- 238000005187 foaming Methods 0.000 abstract description 5
- 229920006395 saturated elastomer Polymers 0.000 abstract description 5
- 238000005201 scrubbing Methods 0.000 abstract description 5
- 239000007787 solid Substances 0.000 abstract description 5
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 15
- 238000000576 coating method Methods 0.000 description 15
- 238000005422 blasting Methods 0.000 description 6
- 238000010792 warming Methods 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- 238000000498 ball milling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 101150075120 DBP10 gene Chemical group 0.000 description 1
- 101150060208 DBP9 gene Chemical group 0.000 description 1
- 101000830410 Homo sapiens Probable ATP-dependent RNA helicase DDX49 Chemical group 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 102100024765 Probable ATP-dependent RNA helicase DDX49 Human genes 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000008366 benzophenones Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- XKYICAQFSCFURC-UHFFFAOYSA-N isoamyl formate Chemical class CC(C)CCOC=O XKYICAQFSCFURC-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical group 0.000 description 1
- 230000001795 light effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000006223 plastic coating Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
A kind of multi-colour spraying plastic paint, its raw materials by weight portion proportioning is as follows: 100 parts of polystyrene; Toluene di-isocyanate(TDI) 1-10 part; Methyl-silicone oil 15-25 part; Butyl ethylene oxide 20-40 part; Asbestos 10-20 part; Polytetramethylene ether diol 5-15 part; Deionized water 80-90 part; 1-Methoxy-2-propyl acetate 15-35 part; Pigment 10-20 part; P methoxy phenol 15-25 part; Mineral wool 10-30 part; Benzophenone 20-30 part; Plasticizer 8-10 part; Dimethylaminobenzoic acid isopentyl ester 25-35 part; Perlite 30-40 part; Titanium dioxide 20-40 part; Product adhesive force 100%, film scrubbing resistance 1000-3000 time is not show-through; Non-foaming soak 20-40d in 20 DEG C of water after, dry linting not, rate of drying is fast, does solid work 6-8h, the saturated aqua calcis 10-30d of alkali resistance; Film pliability is good, can the not division of history into periods of widespread production replace current material.
Description
Technical field
The application belongs to paint field, relates in particular to a kind of multi-colour spraying plastic paint.
Background technology
Coating, in China, tradition name is called paint. So-called coating is be coated in protected or filledThe body surface of decorations, and can form with coated article the continuous film of firm attachment, normally with treeFat or oil or emulsion are main, add or do not add pigment, filler, add corresponding additive,With organic solvent or the formulated thick liquid of asbestos. What China's coating circle was more authoritative " is coated withMaterial technique " book is like this definition: " coating is a kind of material, and this material can be with notSame construction technology is coated in object surface, forms and adheres to firmly, has some strength, continuousSolid film. The film common name film forming like this, claims again paint film or coating. " paint finishingCan and form the material of complete and tough and tensile diaphragm with the fine bonding of matrix material in body surface,Be called coating. Coating and paint are identical concepts. Paint is people's custom titles used for a long time,Introduce after China, just utilize in building trade always. The effect of coating may be summarized to be threeAspect: protective effect, decoration function, specific function effect. The general composition of coating: compriseFilm forming matter, color stuffing, solvent, auxiliary agent.
Coating refers to the general name that is applied to body surface and can form the material of tough and tensile diaphragm, buildsBuilding coating is an important class in coating, in China, generally will be used for building plastic-blasting,Exterior wall, ceiling, ground, the coating of toilet is called building coating. Plastic-blasting is by plastic powdersBe sprayed on a kind of surface treatment method on part. The plastic-blasting electrostatic powder that namely we often saySpray-coating.
So-called multi-colour spraying plastic paint is made up of inconsistent two phase constituents, and wherein one disperses to be situated between mutuallyMatter is continuous phase, and another is decentralized photo mutually, when application, by disposable spray finishing, just can obtainLuxurious, attractive in appearance, colorful pattern. Plastic-blasting is to utilize electrostatic generator to make plastic powders charged,Be adsorbed on the surface of iron plate or other products, then, through the baking of 180～220 DEG C, make powderFusing is attached on the surface of metal or other object, and plastic-blasting product is used for the casing of indoor use,Paint film presents zero diopter or dumb light effect. Plastic-blasting powder mainly contains acrylic clear powder, polyester powder etc.And universal along with humanity concept, and the formation of novel harmonious society, design a kind of resistance to water,The multi-colour spraying plastic paint of scrub resistance and alkali resistance excellence is very important.
Summary of the invention
The technical problem solving:
The application, for above-mentioned technical problem, provides a kind of multi-colour spraying plastic paint, solves existing manyColor spray plastic coating resistance to water and scrub resistance be poor, dry slowly, the technical problem such as alkali corrosion resistance not.
Technical scheme:
A kind of multi-colour spraying plastic paint, the raw materials by weight portion proportioning of described multi-colour spraying plastic paint asUnder: 100 parts of polystyrene; Toluene di-isocyanate(TDI) 1-10 part; Methyl-silicone oil 15-25 part;Butyl ethylene oxide 20-40 part; Asbestos 10-20 part; Polytetramethylene ether diol 5-15 part;Deionized water 80-90 part; 1-Methoxy-2-propyl acetate 15-35 part; Pigment 10-20 part; RightMetoxyphenol 15-25 part; Mineral wool 10-30 part; Benzophenone 20-30 part; Plasticizer8-10 part; Dimethylaminobenzoic acid isopentyl ester 25-35 part; Perlite 30-40 part; DioxyChange titanium 20-40 part.
As a preferred technical solution of the present invention: the raw material of described multi-colour spraying plastic paint is by heavyAmount umber proportioning is as follows: 100 parts of polystyrene; 5 parts of toluene di-isocyanate(TDI)s; Methyl-silicone oil20 parts; 30 parts of butyl ethylene oxides; 15 parts, asbestos; 10 parts of polytetramethylene ether diols;85 parts of deionized waters; 25 parts of 1-Methoxy-2-propyl acetates; 15 parts of pigment; To methoxybenzene20 parts, phenol; 20 parts of mineral wools; 25 parts of benzophenone; 9 parts, plasticizer; Dimethylaminobenzene30 parts of isoamyl formates; 35 parts of perlites; 30 parts of titanium dioxide.
As a preferred technical solution of the present invention: described pigment adopts iron oxide red, oxidationCologne earth or iron oxide black.
As a preferred technical solution of the present invention: described plasticizer adopts DBP.
Beneficial effect:
A kind of multi-colour spraying plastic paint of the present invention adopts above technical scheme and prior art phaseRatio, has following technique effect: 1, product adhesive force 100%, film scrubbing resistance 1000-3000Inferior not show-through; 2, non-foaming soak 20-40d in 20 DEG C of water after, dry linting not, dry speedDegree is fast, does solid work 6-8h, the saturated aqua calcis 10-30d of alkali resistance; 3, film pliabilityGood, can the not division of history into periods of widespread production replace current material.
Detailed description of the invention
Embodiment 1:
A kind of multi-colour spraying plastic paint, its raw materials by weight portion proportioning is as follows: polystyrene 100Part; 1 part of toluene di-isocyanate(TDI); 15 parts of methyl-silicone oils; 20 parts of butyl ethylene oxides; StoneCotton 10 parts; 5 parts of polytetramethylene ether diols; 80 parts of deionized waters; Propylene glycol monomethyl ether acetic acid15 parts of esters; 10 parts of iron oxide reds; 15 parts of p methoxy phenols; 10 parts of mineral wools; Hexichol20 parts of ketones; DBP8 part; 25 parts of dimethylaminobenzoic acid isopentyl ester; 30 parts of perlites;20 parts of titanium dioxide.
By polystyrene, methyl-silicone oil, butyl ethylene oxide, asbestos and polytetramethylene ether twoAlcohol adds in deionized water, be heated to 40 DEG C stir 3h, add 1-Methoxy-2-propyl acetate,P methoxy phenol, mineral wool, benzophenone, perlite and DBP, be warming up to 50 DEG C with ballGrinding machine ball milling 10min, adds toluene di-isocyanate(TDI) and surplus stock, is warming up to 60 DEG C of stirringsAfter 10h, both obtained finished product.
Film scrubbing resistance 1000 times is not show-through; Non-foaming soak 20d in 20 DEG C of water after, noDry linting, does solid work 8h, the saturated aqua calcis 10d of alkali resistance.
Embodiment 2:
A kind of multi-colour spraying plastic paint, its raw materials by weight portion proportioning is as follows: polystyrene 100Part; 10 parts of toluene di-isocyanate(TDI)s; 25 parts of methyl-silicone oils; 40 parts of butyl ethylene oxides;20 parts, asbestos; 15 parts of polytetramethylene ether diols; 90 parts of deionized waters; Propylene glycol monomethyl ether35 parts of acetates; 20 parts of iron oxide browns; 25 parts of p methoxy phenols; 30 parts of mineral wools;30 parts of benzophenone; DBP10 part; 35 parts of dimethylaminobenzoic acid isopentyl ester; Perlite 40Part; 40 parts of titanium dioxide.
By polystyrene, methyl-silicone oil, butyl ethylene oxide, asbestos and polytetramethylene ether twoAlcohol adds in deionized water, be heated to 40 DEG C stir 3h, add 1-Methoxy-2-propyl acetate,P methoxy phenol, mineral wool, benzophenone, perlite and DBP, be warming up to 50 DEG C with ballGrinding machine ball milling 10min, adds toluene di-isocyanate(TDI) and surplus stock, is warming up to 60 DEG C of stirringsAfter 10h, both obtained finished product.
Film scrubbing resistance 2000 times is not show-through; Non-foaming soak 30d in 20 DEG C of water after, noDry linting, does solid work 7h, the saturated aqua calcis 20d of alkali resistance.
Embodiment 3:
A kind of multi-colour spraying plastic paint, its raw materials by weight portion proportioning is as follows: polystyrene 100Part; 5 parts of toluene di-isocyanate(TDI)s; 20 parts of methyl-silicone oils; 30 parts of butyl ethylene oxides; StoneCotton 15 parts; 10 parts of polytetramethylene ether diols; 85 parts of deionized waters; Propylene glycol monomethyl ether vinegar25 parts of acid esters; 15 parts of iron oxide blacks; 20 parts of p methoxy phenols; 20 parts of mineral wools; Two25 parts of Benzophenones; DBP9 part; 30 parts of dimethylaminobenzoic acid isopentyl ester; 35 parts of perlites;30 parts of titanium dioxide.
By polystyrene, methyl-silicone oil, butyl ethylene oxide, asbestos and polytetramethylene ether twoAlcohol adds in deionized water, be heated to 40 DEG C stir 3h, add 1-Methoxy-2-propyl acetate,P methoxy phenol, mineral wool, benzophenone, perlite and DBP, be warming up to 50 DEG C with ballGrinding machine ball milling 10min, adds toluene di-isocyanate(TDI) and surplus stock, is warming up to 60 DEG C of stirringsAfter 10h, both obtained finished product.
Film scrubbing resistance 3000 times is not show-through; Non-foaming soak 40d in 20 DEG C of water after, noDry linting, does solid work 6h, the saturated aqua calcis 30d of alkali resistance.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, instead of restriction, because ofThis any change in implication and the scope suitable with claims of the present invention, all shouldThink to be included in the scope of claims.
Claims (2)
1. a multi-colour spraying plastic paint, the raw material that it is characterized in that described multi-colour spraying plastic paint byParts by weight proportioning is as follows: 100 parts of polystyrene; Toluene di-isocyanate(TDI) 1-10 part; FirstBase silicone oil 15-25 part; Butyl ethylene oxide 20-40 part; Asbestos 10-20 part; Poly-four methylenesBase ether glycol 5-15 part; Deionized water 80-90 part; 1-Methoxy-2-propyl acetate 15-35 part;Pigment 10-20 part; P methoxy phenol 15-25 part; Mineral wool 10-30 part; Benzophenone20-30 part; Plasticizer 8-10 part; Dimethylaminobenzoic acid isopentyl ester 25-35 part; PearlRock 30-40 part; Titanium dioxide 20-40 part;
Described pigment adopts iron oxide red, iron oxide brown or iron oxide black;
Described plasticizer adopts DBP.
2. a kind of multi-colour spraying plastic paint according to claim 1, described in it is characterized in thatThe raw materials by weight portion proportioning of multi-colour spraying plastic paint is as follows: 100 parts of polystyrene; Toluene two5 parts of isocyanates; 20 parts of methyl-silicone oils; 30 parts of butyl ethylene oxides; 15 parts, asbestos;10 parts of polytetramethylene ether diols; 85 parts of deionized waters; 25 parts of 1-Methoxy-2-propyl acetates;15 parts of pigment; 20 parts of p methoxy phenols; 20 parts of mineral wools; 25 parts of benzophenone; IncreaseMould 9 parts of agent; 30 parts of dimethylaminobenzoic acid isopentyl ester; 35 parts of perlites; Titanium dioxide30 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410409888.4A CN104151949B (en) | 2014-08-20 | 2014-08-20 | A kind of multi-colour spraying plastic paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410409888.4A CN104151949B (en) | 2014-08-20 | 2014-08-20 | A kind of multi-colour spraying plastic paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104151949A CN104151949A (en) | 2014-11-19 |
| CN104151949B true CN104151949B (en) | 2016-05-18 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410409888.4A Expired - Fee Related CN104151949B (en) | 2014-08-20 | 2014-08-20 | A kind of multi-colour spraying plastic paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104151949B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113292889A (en) * | 2021-05-27 | 2021-08-24 | 临海市国盛泰工艺品股份有限公司 | Efficient plastic coating for green furniture and plastic spraying process thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD210896A1 (en) * | 1982-10-18 | 1984-06-27 | Lacke Und Farben Veb K | PROCESS FOR PRODUCING DECORATIVE SURFACES |
| CN1094738A (en) * | 1993-03-16 | 1994-11-09 | 李清洲 | A kind of thermal insulation, Multi-colour spraying plastic paint manufacturing process and prescription |
| CN1102193A (en) * | 1993-11-01 | 1995-05-03 | 韩晓根 | Multi-colour paint for internal wall |
| CN1233636A (en) * | 1998-04-27 | 1999-11-03 | 陈民英 | Multi-purpose color water-proof coating made of poly styrene wastes |
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2014
- 2014-08-20 CN CN201410409888.4A patent/CN104151949B/en not_active Expired - Fee Related
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| CN104151949A (en) | 2014-11-19 |
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