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CN104151983B - A kind of dual-water-phase colour pattern paint - Google Patents

A kind of dual-water-phase colour pattern paint Download PDF

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Publication number
CN104151983B
CN104151983B CN201410409867.2A CN201410409867A CN104151983B CN 104151983 B CN104151983 B CN 104151983B CN 201410409867 A CN201410409867 A CN 201410409867A CN 104151983 B CN104151983 B CN 104151983B
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parts
water
dual
colour pattern
diacrylate
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CN104151983A (en
Inventor
费金华
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Hebei Chenyang Industry and Trade Group Co Ltd
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Wujiang Huacheng Composite Technology Co Ltd
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Abstract

A kind of dual-water-phase colour pattern paint, its raw materials by weight portion proportioning is as follows: acrylonitrile butadient styrene 100 parts;Dimethoxyphenylacetophenone 1 10 parts;5 15 parts of sodium sulfate;Tetramethylol methane tetraacrylate 10 20 parts;Butanediol monobutyl ether 15 25 parts;Urethane acrylate 20 30 parts;Deionized water 80 90 parts;Benzophenone 25 35 parts;Pigment 5 15 parts;Tripropylene glycol diacrylate 5 25 parts;Carboxymethyl cellulose 15 35 parts;Hexamethylene diisocyanate 10 30 parts;Plasticizer 6 10 parts;N, N dimethylethanolamine 30 40 parts;Hydroxyethyl cellulose 35 45 parts;Tri (propylene glycol) diacrylate 20 40 parts;Product solid content 25 30%, film scrubbing resistance 3,500 4500 times;Bin stability 6 10 months, non-foaming after soaking 20 40d in 20 DEG C of water, not dry linting;Surface drying 0.1 0.5h, does solid work 6 8h, alkali resistance saturated aqua calcis 10 20d, can be with the widespread production not division of history into periods for current material.

Description

A kind of dual-water-phase colour pattern paint
Technical field
The application belongs to paint field, particularly relates to a kind of dual-water-phase colour pattern paint.
Background technology
Coating, at the entitled paint of Chinese tradition.So-called coating is to be coated in be protected or filled The body surface of decorations, and can be with the continuous film of coated article formation firm attachment, it is common that with tree Fat or oil or emulsion are main, add or without pigment, filler, add corresponding additive, With the formulated thick liquid of organic solvent or butanediol monobutyl ether.China's coating circle compares power " coating process " book of prestige is defined such that " coating is a kind of material, this material Can be coated in object surface by different construction technologies, formation adheres to firmly, has the most by force Degree, continuous print solid film.The film common name film so formed, also known as paint film or coating." be coated with Material is covered with paint, lacquer, colour wash, etc. and can very well be bondd with matrix material in body surface and form complete and tough and tensile protecting film Material, referred to as coating.Coating and paint are the identicals concept.Paint is that people are used for a long time Custom title, after introducing China, utilizes in building trade the most always.The effect of coating is permissible It is summarised as three aspects: protective effect, decoration function, specific function effect.Coating general Composition: comprise film forming matter, color stuffing, solvent, auxiliary agent.
Coating refers to be applied to body surface and can form the general name of the material of tough and tensile protecting film, builds Building coating is an important class in coating, in China, typically will be used for inner wall of building, Exterior wall, ceiling, ground, the coating of toilet is referred to as building coating.Acrylonitrile-butadiene- Styrol copolymer, is called for short ABS.ABS is a kind of intensity height, good toughness, is easily processed into Thermoplastics type's Polymer Materials ' Structure of type.ABS resin is acrylonitrile, 1,3-butadiene, benzene The terpolymer of ethylene.Can act normally in the environment of-25 DEG C~60 DEG C, and have very Good mouldability, the product surface processed is bright and clean, it is easy to dyes and electroplates.And can be with many Plant resin compounding and become blend.
So-called dual-water-phase colour pattern paint is made up of two incompatible phase constituents, a wherein phase Disperse medium is continuous phase, and another phase is dispersion phase, during application, by disposable spray finishing, just Available luxurious, attractive in appearance, colorful pattern.Acrylonitrile-butadiene-styrene copolymer, be A kind of intensity height, good toughness, thermoplastics type's Polymer Materials ' Structure easily processed into type.And with The universal of humanity concept, and the composition of novel harmonious society, a kind of resistance to water of design, resistance to The dual-water-phase colour pattern paint of scrubbing character and alkali resistance excellence is very important.
Summary of the invention
Solve the technical problem that:
The application is for above-mentioned technical problem, it is provided that a kind of dual-water-phase colour pattern paint, solves Existing dual-water-phase colour pattern paint resistance to water and scrub resistance is poor, be dried slowly, not alkali corrosion resistance Etc. technical problem.
Technical scheme:
A kind of dual-water-phase colour pattern paint, the raw material of described dual-water-phase colour pattern paint is by weight Amount number proportioning is as follows: acrylonitrile-butadiene-styrene copolymer 100 parts;Dimethoxy benzene Benzoylformaldoxime 1-10 part;Sodium sulfate 5-15 part;Tetramethylol methane tetraacrylate 10-20 part; Butanediol monobutyl ether 15-25 part;Urethane acrylate 20-30 part;Deionized water 80-90 Part;Benzophenone 25-35 part;Pigment 5-15 part;Tripropylene glycol diacrylate 5-25 part; Carboxymethyl cellulose 15-35 part;Hexamethylene diisocyanate 10-30 part;Plasticizer 6-10 Part;N, N-dimethylethanolamine 30-40 part;Hydroxyethyl cellulose 35-45 part;Two contractings 3 third Omega-diol diacrylate 20-40 part.
As a preferred technical solution of the present invention: described dual-water-phase colour pattern paint former Expect that proportioning is as follows by weight: acrylonitrile-butadiene-styrene copolymer 100 parts;Diformazan Phenyl 1-Phenylethanone. 5 parts;10 parts of sodium sulfate;Tetramethylol methane tetraacrylate 15 parts;Fourth Glycol monobutyl ether 20 parts;Urethane acrylate 25 parts;Deionized water 85 parts;Hexichol first Ketone 30 parts;Pigment 10 parts;Tripropylene glycol diacrylate 15 parts;Carboxymethyl cellulose 25 Part;Hexamethylene diisocyanate 20 parts;Plasticizer 8 parts;N, N-dimethylethanolamine 35 Part;Hydroxyethyl cellulose 40 parts;Tri (propylene glycol) diacrylate 30 parts.
As a preferred technical solution of the present invention: described pigment uses iron oxide red, oxidation Iron oxide yellow or iron oxide brown.
As a preferred technical solution of the present invention: described plasticizer uses DBP.
Beneficial effect:
A kind of dual-water-phase colour pattern paint of the present invention uses above technical scheme with existing Technology is compared, and has following technical effect that 1, product solid content 25-30%, film scrubbing resistance 3500-4500 time;2, bin stability 6-10 month, 20 DEG C of water soaks 20-40d The most non-foaming, not dry linting;3, surface drying 0.1-0.5h, does solid work 6-8h, the saturated hydrogen-oxygen of alkali resistance Change calcium solution 10-20d, can be with the widespread production not division of history into periods for current material.
Detailed description of the invention
Embodiment 1:
A kind of dual-water-phase colour pattern paint, its raw materials by weight portion proportioning is as follows: acrylonitrile -BS 100 parts;Dimethoxyphenylacetophenone 1 part;Sodium sulfate 5 Part;Tetramethylol methane tetraacrylate 10 parts;Butanediol monobutyl ether 15 parts;Polyurethane acroleic acid Ester 20 parts;Deionized water 80 parts;Benzophenone 25 parts;Iron oxide brown 5 parts;3 the third two Alcohol diacrylate 5 parts;Carboxymethyl cellulose 15 parts;Hexamethylene diisocyanate 10 parts; DBP6 part;N, N-dimethylethanolamine 30 parts;Hydroxyethyl cellulose 35 parts;Two contractings 3 third Omega-diol diacrylate 20 parts.
By acrylonitrile-butadiene-styrene copolymer, sodium sulfate, tetramethylol methane tetraacrylate, Butanediol monobutyl ether and urethane acrylate add in deionized water, are heated to 40 DEG C of stirrings 3h, adds benzophenone, tripropylene glycol diacrylate, carboxymethyl cellulose, hexa-methylene Diisocyanate, hydroxyethyl cellulose and DBP, be warming up to 50 DEG C with ball mill ball milling 10min, Add dimethoxyphenylacetophenone and surplus stock, both obtained after being warming up to 60 DEG C of stirring 10h Finished product.
Product solid content 25%, film scrubbing resistance 3500 times;Bin stability 6 months, 20 DEG C of water soak non-foaming after 20d, not dry linting;Surface drying 0.5h, does solid work 8h, alkali resistance Saturated aqua calcis 10d.
Embodiment 2:
A kind of dual-water-phase colour pattern paint, its raw materials by weight portion proportioning is as follows: acrylonitrile -BS 100 parts;Dimethoxyphenylacetophenone 10 parts;Sodium sulfate 15 parts;Tetramethylol methane tetraacrylate 20 parts;Butanediol monobutyl ether 25 parts;Polyurethane third Olefin(e) acid ester 30 parts;Deionized water 90 parts;Benzophenone 35 parts;Iron oxide yellow 15 parts;Three Propylene glycol diacrylate 25 parts;Carboxymethyl cellulose 35 parts;Hexamethylene diisocyanate 30 parts;DBP10 part;N, N-dimethylethanolamine 40 parts;Hydroxyethyl cellulose 45 parts;Two Contracting tripropylene glycol diacrylate 40 parts.
By acrylonitrile-butadiene-styrene copolymer, sodium sulfate, tetramethylol methane tetraacrylate, Butanediol monobutyl ether and urethane acrylate add in deionized water, are heated to 40 DEG C of stirrings 3h, adds benzophenone, tripropylene glycol diacrylate, carboxymethyl cellulose, hexa-methylene Diisocyanate, hydroxyethyl cellulose and DBP, be warming up to 50 DEG C with ball mill ball milling 10min, Add dimethoxyphenylacetophenone and surplus stock, both obtained after being warming up to 60 DEG C of stirring 10h Finished product.
Product solid content 28%, film scrubbing resistance 4000 times;Bin stability 8 months, 20 DEG C of water soak non-foaming after 30d, not dry linting;Surface drying 0.3h, does solid work 7h, alkali resistance Saturated aqua calcis 15d.
Embodiment 3:
A kind of dual-water-phase colour pattern paint, its raw materials by weight portion proportioning is as follows: acrylonitrile -BS 100 parts;Dimethoxyphenylacetophenone 5 parts;Sodium sulfate 10 parts;Tetramethylol methane tetraacrylate 15 parts;Butanediol monobutyl ether 20 parts;Polyurethane third Olefin(e) acid ester 25 parts;Deionized water 85 parts;Benzophenone 30 parts;Iron oxide red 10 parts;Three Propylene glycol diacrylate 15 parts;Carboxymethyl cellulose 25 parts;Hexamethylene diisocyanate 20 parts;DBP8 part;N, N-dimethylethanolamine 35 parts;Hydroxyethyl cellulose 40 parts;Two Contracting tripropylene glycol diacrylate 30 parts.
By acrylonitrile-butadiene-styrene copolymer, sodium sulfate, tetramethylol methane tetraacrylate, Butanediol monobutyl ether and urethane acrylate add in deionized water, are heated to 40 DEG C of stirrings 3h, adds benzophenone, tripropylene glycol diacrylate, carboxymethyl cellulose, hexa-methylene Diisocyanate, hydroxyethyl cellulose and DBP, be warming up to 50 DEG C with ball mill ball milling 10min, Add dimethoxyphenylacetophenone and surplus stock, both obtained after being warming up to 60 DEG C of stirring 10h Finished product.
Product solid content 30%, film scrubbing resistance 4500 times;Bin stability 10 months, 20 DEG C of water soak non-foaming after 40d, not dry linting;Surface drying 0.1h, does solid work 6h, alkali resistance Saturated aqua calcis 20d.
Compositions all components in above example all can be commercially available.
Above-described embodiment is only intended to be illustrated present disclosure rather than limit, because of This any change in the implication suitable with claims of the present invention and scope, all should It is considered to be included within the scope of the claims.

Claims (1)

1. a dual-water-phase colour pattern paint, it is characterised in that described dual-water-phase colour pattern The raw materials by weight portion proportioning of coating is as follows: acrylonitrile-butadiene-styrene copolymer 100 Part;Dimethoxyphenylacetophenone 5 parts;10 parts of sodium sulfate;Tetramethylol methane tetraacrylate 15 parts;Butanediol monobutyl ether 20 parts;Urethane acrylate 25 parts;Deionized water 85 parts; Benzophenone 30 parts;Pigment 10 parts;Tripropylene glycol diacrylate 15 parts;Carboxymethyl is fine Dimension element 25 parts;Hexamethylene diisocyanate 20 parts;Plasticizer 8 parts;N, N-dimethyl second Hydramine 35 parts;Hydroxyethyl cellulose 40 parts;Tri (propylene glycol) diacrylate 30 parts;
Described pigment uses iron oxide red, iron oxide yellow or iron oxide brown;
Described plasticizer uses DBP.
CN201410409867.2A 2014-08-20 2014-08-20 A kind of dual-water-phase colour pattern paint Active CN104151983B (en)

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CN104151983A CN104151983A (en) 2014-11-19
CN104151983B true CN104151983B (en) 2016-09-21

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1103092A (en) * 1993-11-26 1995-05-31 中国矿业大学 Water-in-water type multi-colour figure paint
CN1109901A (en) * 1994-05-25 1995-10-11 湘潭市南方高新技术研究所 Dual-water-phase colour pattern paint
CN1117509A (en) * 1994-08-24 1996-02-28 苏州市建筑科学研究所 Water-in-water type multi-color decorative pattern paint
JP4520111B2 (en) * 2002-08-02 2010-08-04 エスケー化研株式会社 Multi-color paint composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1103092A (en) * 1993-11-26 1995-05-31 中国矿业大学 Water-in-water type multi-colour figure paint
CN1109901A (en) * 1994-05-25 1995-10-11 湘潭市南方高新技术研究所 Dual-water-phase colour pattern paint
CN1117509A (en) * 1994-08-24 1996-02-28 苏州市建筑科学研究所 Water-in-water type multi-color decorative pattern paint
JP4520111B2 (en) * 2002-08-02 2010-08-04 エスケー化研株式会社 Multi-color paint composition

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Inventor after: Liu Shanjiang

Inventor after: Liu Zhanchuan

Inventor after: Mei Shaofeng

Inventor after: Hu Zhongyuan

Inventor before: Fei Jinhua

TR01 Transfer of patent right

Effective date of registration: 20171221

Address after: 071000 Hebei city of Baoding province Xushui Chenyang Street No. 1

Patentee after: Hebei Chenyang IndustrialL&trade Group Co., Ltd.

Address before: Wujiang District of Suzhou City, Jiangsu province 215200 Song Ling Zhen Wu highway

Patentee before: Wujiang Huacheng Composite Technology Co., Ltd.

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Effective date of registration: 20200929

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