CN104356798A - Intumescent flame-retardant coating for glass door and preparing method of coating - Google Patents
Intumescent flame-retardant coating for glass door and preparing method of coating Download PDFInfo
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- CN104356798A CN104356798A CN201410538764.6A CN201410538764A CN104356798A CN 104356798 A CN104356798 A CN 104356798A CN 201410538764 A CN201410538764 A CN 201410538764A CN 104356798 A CN104356798 A CN 104356798A
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- parts
- coating
- waterborne
- water
- silane coupling
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- 238000000576 coating method Methods 0.000 title claims abstract description 21
- 239000011521 glass Substances 0.000 title claims abstract description 21
- 239000011248 coating agent Substances 0.000 title claims abstract description 19
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 239000003063 flame retardant Substances 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 13
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 13
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 10
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 claims abstract description 7
- ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 2-phenyl-1h-imidazole Chemical compound C1=CNC(C=2C=CC=CC=2)=N1 ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004593 Epoxy Substances 0.000 claims abstract description 7
- 241001122767 Theaceae Species 0.000 claims abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000853 adhesive Substances 0.000 claims abstract description 7
- 230000001070 adhesive effect Effects 0.000 claims abstract description 7
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 claims abstract description 7
- 229940063655 aluminum stearate Drugs 0.000 claims abstract description 7
- 229910052810 boron oxide Inorganic materials 0.000 claims abstract description 7
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 7
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000003822 epoxy resin Substances 0.000 claims abstract description 7
- 239000002502 liposome Substances 0.000 claims abstract description 7
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims abstract description 7
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 7
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 7
- 150000008442 polyphenolic compounds Chemical class 0.000 claims abstract description 7
- 235000013824 polyphenols Nutrition 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000011347 resin Substances 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 7
- -1 polysiloxane Polymers 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 18
- 239000012752 auxiliary agent Substances 0.000 claims description 14
- 239000012153 distilled water Substances 0.000 claims description 12
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 9
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 9
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052599 brucite Inorganic materials 0.000 claims description 7
- 230000036541 health Effects 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- IBDVWXAVKPRHCU-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCOC(=O)C(C)=C IBDVWXAVKPRHCU-UHFFFAOYSA-N 0.000 claims description 6
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 claims description 6
- DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 claims description 6
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 6
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 6
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 6
- 229940043232 butyl acetate Drugs 0.000 claims description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 229960002887 deanol Drugs 0.000 claims description 6
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 6
- 239000012972 dimethylethanolamine Substances 0.000 claims description 6
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 6
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 6
- 150000002460 imidazoles Chemical class 0.000 claims description 6
- 239000004816 latex Substances 0.000 claims description 6
- 229920000126 latex Polymers 0.000 claims description 6
- 239000005543 nano-size silicon particle Substances 0.000 claims description 6
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 6
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 6
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000004807 desolvation Methods 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 6
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 230000003373 anti-fouling effect Effects 0.000 abstract description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000010451 perlite Substances 0.000 abstract 1
- 235000019362 perlite Nutrition 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 6
- 230000032683 aging Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000027555 hydrotropism Effects 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
- C09D5/185—Intumescent paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an intumescent flame-retardant coating for a glass door. The coating is characterized by being prepared from raw materials in parts by weight as follows: 30-34 parts of waterborne hydroxyl acrylic resin, 7-9 parts of a waterborne coalescing agent, 0.5-1.0 part of aluminum stearate, 13-15 parts of waterborne epoxy resin, 9-13 parts of a waterborne pure acrylic emulsion, 0.3-0.5 parts of polysiloxane resin, 1-2 parts of epoxy butyl oleate, 1-2 parts expanded perlite, 2-3 parts of artinite, 1-2 parts of polyethylene glycol monooleate, 3-4 parts of sodium tripolyphosphate, 2-3 parts of imidazole such as 2-phenylimidazole and the like, 0.3-0.4 parts of a leveling agent BYK-310, 1-2 parts of pigment, 0.5-1.0 part of nano silica, 2-3 parts of tea polyphenol liposome, 0.5-1.0 part of a silane coupling agent KH792, 2-3 parts of triethylene glycol butyl ether, 1-2 parts of boron oxide, 1-2 parts of a polyacrylate adhesive and 13-16 parts of deionized water. The coating is very good in flame retardant effect, non-toxic, smokeless, free from pollution, high in coating hardness after cured, good in wear resistance, excellent in corrosion resistance, stain resistance and antifouling property and suitable for glass in various places.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of expandable flame retardant type glass door coating and preparation method thereof.
Background technology
Indoor and outdoor, between space and space boundary has been linked up in the appearance of glass, allows Home Fashion & Design Shanghai there occurs revolutionary leap.And the Technology of present coating imparts the more artistry of glass and functional.Although existing glass paint can meet the demand of people to a certain extent, but the glass paint that market is sold mostly is oil paint, its filmogen is mainly from petroleum chemicals, and its solvent also adopts organic solvent more, usually containing toxic substances such as formaldehyde, free TDI and dimethylbenzene, these materials constantly come out in glass paint production process and use procedure, not only cause environmental pollution, and damage HUMAN HEALTH; Compared with traditional solvent based coating, water-borne coatings has that price is low, use safety, saving resource and the energy, reduce the advantage such as environmental pollution and public hazards, because becoming the Main way of current development coatings industry, so glass paint is developed by solvent-borne type hydrotropisms, it is the inexorable trend adapting to environment protection requirement development, and along with the continuous expansion of Application Areas, more and more higher requirement is proposed to glass paint functional performance, the requirement having surmounted traditional decoration far away and beautified.
Acrylic resin paint has good gloss retention, tint retention, quick-drying and erosion resistance, along with the enhancing of people's environmental consciousness and the constantly sound of law, acrylic resin paint also hydrotropisms's paint development gradually, water-borne acrylic resin because of transparent color and luster, protect that light tint retention is good, glossiness is good, good heat resistance, corrosion-resistant and stain resistance good, the advantage such as cheap is widely used.The present invention, by the waterborne film-forming auxiliary agent added, is applied to family decoration glass door, has film forming properties excellent, ageing-resistant, strong adhesion, corrosion-resistant, stain resistance and good etc. the feature of didirtresistance.
Summary of the invention
The object of this invention is to provide a kind of expandable flame retardant type glass door coating and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of expandable flame retardant type glass door coating, be made up of the raw material of following weight part: water based acrylic resin 30-34, waterborne film-forming auxiliary agent 7-9, aluminum stearate 0.5-1.0, aqueous epoxy resins 13-15, water-based pure acrylic latex 9-13, polyorganosiloxane resin 0.3-0.5, epoxy health butyl oleate 1-2, pearlstone 1-2, fine brucite 2-3, polyoxyethylene oleic acid ester 1-2, tripoly phosphate sodium STPP 3-4, the imidazoles 2-3 such as 2-phenylimidazole, flow agent BYK-3100.3-0.4, pigment 1-2, nano silicon 0.5-1.0, tea polyphenol liposomes 2-3, silane coupling agent KH7920.5-1.0, triethylene glycol butyl ether 2-3, boron oxide 1-2, polyacrylate adhesives 1-2, deionized water 13-16,
Described waterborne film-forming auxiliary agent is made up of the raw material of following weight part: the different monooctyl ester 1-2 of 3-thiohydracrylic acid, methyl methacrylate 13-16, butyl acrylate 22-25, Propylene glycol monoacrylate 12-15, methacrylic acid 8-11, benzoyl peroxide 1-3, Diisopropyl azodicarboxylate 0.5-1.0, butylacetate 18-22, AAEM 4-6, dimethylethanolamine 3-4, polyborosiloxane 2-3, nm-class rutile-type TiO 2 3-5, silane coupling agent KH5601-2, dehydrated alcohol 10-15, distilled water 100-150, nm-class rutile-type TiO 2, polyborosiloxane and dehydrated alcohol are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add silane coupling agent KH560 be heated to backflow, isothermal reaction 1-2 hour, filters and uses distilled water wash three dry for standby.By methyl methacrylate, butyl acrylate, Propylene glycol monoacrylate, the benzoyl peroxide mixing formation monomer mixed solution of methacrylic acid and 10-30% is for subsequent use, butylacetate is heated to 120-140 ° of C, add the monomer mixture solution of 10-20%, above-mentioned material for subsequent use, the different monooctyl ester of 3-thiohydracrylic acid and Diisopropyl azodicarboxylate, insulation reaction 45 minutes, slowly drip remaining mixed monomer solution and benzoyl peroxide again, guarantee to drip in 1.5 hours to terminate, constant temperature keeps adding dimethylethanolamine and distilled water after 2-3 hour, the azeotrope of heating desolvation and distilled water, add AAEM mixing and stirring again and can obtain waterborne film-forming auxiliary agent.
A kind of expandable flame retardant type glass door coating of the present invention, be made up of following concrete steps:
(1) deionized water, polyorganosiloxane resin, flow agent BYK-310, tea polyphenol liposomes mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds triethylene glycol butyl ether, epoxy health butyl oleate, aluminum stearate stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds the imidazoles such as water based acrylic resin, waterborne film-forming auxiliary agent, aqueous epoxy resins, water-based pure acrylic latex, 2-phenylimidazole, polyacrylate adhesives stirs 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds silane coupling agent KH792, pigment, nano silicon, fine brucite, pearlstone, tripoly phosphate sodium STPP, boron oxide stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
Advantage of the present invention is: it is excellent that the present invention has film forming properties by the waterborne film-forming auxiliary agent added, ageing-resistant, strong adhesion, corrosion-resistant, stain resistance and good etc. the effect of didirtresistance, fine brucite has good flame retardant effect, nontoxic, smokeless, pollution-free, can play the reinforced effects of filler simultaneously, reduce costs, pearlstone also has good heat insulation, fp effect.
Coating of the present invention has good flame retardant effect, and nontoxic, smokeless, pollution-free, and after solidification, hardness of film is high, and wear resistance is good, and erosion resistance, stain resistance and antifouling property are excellent, and the glass being applicable to numerous place is used.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of expandable flame retardant type glass door coating, be made up of the raw material of following weight part (kilogram): water based acrylic resin 32, waterborne film-forming auxiliary agent 8, aluminum stearate 0.6, aqueous epoxy resins 14, water-based pure acrylic latex 12, polyorganosiloxane resin 0.4, epoxy health butyl oleate 1, pearlstone 1, fine brucite 3, polyoxyethylene oleic acid ester 1, tripoly phosphate sodium STPP 3, the imidazoles 2 such as 2-phenylimidazole, flow agent BYK-3100.3, pigment 1, nano silicon 0.6, tea polyphenol liposomes 2, silane coupling agent KH7920.8, triethylene glycol butyl ether 3, boron oxide 1, polyacrylate adhesives 1, deionized water 16,
Described waterborne film-forming auxiliary agent is made up of the raw material of following weight part (kilogram): the different monooctyl ester 1 of 3-thiohydracrylic acid, methyl methacrylate 14, butyl acrylate 24, Propylene glycol monoacrylate 13, methacrylic acid 10, benzoyl peroxide 2, Diisopropyl azodicarboxylate 0.7, butylacetate 20, AAEM 5, dimethylethanolamine 3, polyborosiloxane 3, nm-class rutile-type TiO 24, silane coupling agent KH5601.5, dehydrated alcohol 15, distilled water 110; Nm-class rutile-type TiO 2, polyborosiloxane and dehydrated alcohol are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add silane coupling agent KH560 be heated to backflow, isothermal reaction 1-2 hour, filters and uses distilled water wash three dry for standby.By methyl methacrylate, butyl acrylate, Propylene glycol monoacrylate, the benzoyl peroxide mixing formation monomer mixed solution of methacrylic acid and 10-30% is for subsequent use, butylacetate is heated to 120-140 ° of C, add the monomer mixture solution of 10-20%, above-mentioned material for subsequent use, the different monooctyl ester of 3-thiohydracrylic acid and Diisopropyl azodicarboxylate, insulation reaction 45 minutes, slowly drip remaining mixed monomer solution and benzoyl peroxide again, guarantee to drip in 1.5 hours to terminate, constant temperature keeps adding dimethylethanolamine and distilled water after 2-3 hour, the azeotrope of heating desolvation and distilled water, add AAEM mixing and stirring again and can obtain waterborne film-forming auxiliary agent.
A kind of expandable flame retardant type glass door coating of the present invention, be made up of following concrete steps:
(1) deionized water, polyorganosiloxane resin, flow agent BYK-310, tea polyphenol liposomes mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds triethylene glycol butyl ether, epoxy health butyl oleate, aluminum stearate stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds the imidazoles such as water based acrylic resin, waterborne film-forming auxiliary agent, aqueous epoxy resins, water-based pure acrylic latex, 2-phenylimidazole, polyacrylate adhesives stirs 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds silane coupling agent KH792, pigment, nano silicon, fine brucite, pearlstone, tripoly phosphate sodium STPP, boron oxide stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
After paint solidification of the present invention, hardness of paint film is 2H, and sticking power experiment is 1 grade, wear resistance experiment (0.5g/r)/mg:5.5, shock resistance is tested: 50cm, water tolerance experiment (500h): without exception, resistance to boiling water experiment (100 ° of C >=12h): not loss of gloss, non-foaming, allows slightly to change, can restore, alcohol resistance experiment (soaked in absolute ethyl alcohol 24h): without exception, salt fog resistance experiment (12h): unchanged, artificial ageing resistance is tested: 750h is non-foaming, do not peel off, flawless.
Claims (2)
1. an expandable flame retardant type glass door coating, it is characterized in that, be made up of the raw material of following weight part: water based acrylic resin 30-34, waterborne film-forming auxiliary agent 7-9, aluminum stearate 0.5-1.0, aqueous epoxy resins 13-15, water-based pure acrylic latex 9-13, polyorganosiloxane resin 0.3-0.5, epoxy health butyl oleate 1-2, pearlstone 1-2, fine brucite 2-3, polyoxyethylene oleic acid ester 1-2, tripoly phosphate sodium STPP 3-4, the imidazoles 2-3 such as 2-phenylimidazole, flow agent BYK-3100.3-0.4, pigment 1-2, nano silicon 0.5-1.0, tea polyphenol liposomes 2-3, silane coupling agent KH7920.5-1.0, triethylene glycol butyl ether 2-3, boron oxide 1-2, polyacrylate adhesives 1-2, deionized water 13-16,
Described waterborne film-forming auxiliary agent is made up of the raw material of following weight part: the different monooctyl ester 1-2 of 3-thiohydracrylic acid, methyl methacrylate 13-16, butyl acrylate 22-25, Propylene glycol monoacrylate 12-15, methacrylic acid 8-11, benzoyl peroxide 1-3, Diisopropyl azodicarboxylate 0.5-1.0, butylacetate 18-22, AAEM 4-6, dimethylethanolamine 3-4, polyborosiloxane 2-3, nm-class rutile-type TiO 2 3-5, silane coupling agent KH5601-2, dehydrated alcohol 10-15, distilled water 100-150, nm-class rutile-type TiO 2, polyborosiloxane and dehydrated alcohol are added in round-bottomed flask fully to stir and ultrasonic vibration 10-20min by preparation method, and slowly add silane coupling agent KH560 be heated to backflow, isothermal reaction 1-2 hour, filters and uses distilled water wash three dry for standby,
By methyl methacrylate, butyl acrylate, Propylene glycol monoacrylate, the benzoyl peroxide mixing formation monomer mixed solution of methacrylic acid and 10-30% is for subsequent use, butylacetate is heated to 120-140 ° of C, add the monomer mixture solution of 10-20%, above-mentioned material for subsequent use, the different monooctyl ester of 3-thiohydracrylic acid and Diisopropyl azodicarboxylate, insulation reaction 45 minutes, slowly drip remaining mixed monomer solution and benzoyl peroxide again, guarantee to drip in 1.5 hours to terminate, constant temperature keeps adding dimethylethanolamine and distilled water after 2-3 hour, the azeotrope of heating desolvation and distilled water, add AAEM mixing and stirring again and can obtain waterborne film-forming auxiliary agent.
2. a kind of expandable flame retardant type glass door coating according to claim 1, is characterized in that, be made up of following concrete steps:
(1) deionized water, polyorganosiloxane resin, flow agent BYK-310, tea polyphenol liposomes mixing are added in Scattered Kettle, to stir 3-5 minute under the condition of 600-800 rev/min;
(2) rotating speed is adjusted to 900-1000 rev/min, in Scattered Kettle, adds triethylene glycol butyl ether, epoxy health butyl oleate, aluminum stearate stirring 6-8 minute;
(3) rotating speed is adjusted to 1400-1600 rev/min, adds the imidazoles such as water based acrylic resin, waterborne film-forming auxiliary agent, aqueous epoxy resins, water-based pure acrylic latex, 2-phenylimidazole, polyacrylate adhesives stirs 15-25 minute;
(4) rotating speed is adjusted to 1000-1200 rev/min, adds silane coupling agent KH792, pigment, nano silicon, fine brucite, pearlstone, tripoly phosphate sodium STPP, boron oxide stirring 20-30 minute successively;
(5) be added in sand mill and carry out grinding distribution by the material after dispersion, after filtering, fineness is less than 20 μm and packs.
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