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CN1075725A - Reinforced ultra-thin man-made serialized board, its production method, and combined furniture made of the serialized board - Google Patents

Reinforced ultra-thin man-made serialized board, its production method, and combined furniture made of the serialized board Download PDF

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CN1075725A
CN1075725A CN 93102733 CN93102733A CN1075725A CN 1075725 A CN1075725 A CN 1075725A CN 93102733 CN93102733 CN 93102733 CN 93102733 A CN93102733 A CN 93102733A CN 1075725 A CN1075725 A CN 1075725A
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赵琢玉
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Abstract

The invention uses resin and other chemical raw materials, produces various specifications of artificial jade boards, artificial agate boards, artificial amber boards, artificial ceramic boards and artificial transparent marble boards through scientific proportioning and compression molding, and reinforces aluminum alloy fittings on the boards to manufacture various high-grade combined furniture according to requirements. The seriation plate is light, thin, bright, clean, changeable in color and luster, not easy to break, good in toughness and pressure resistance, and wide in application range, and can be used for manufacturing combined furniture, kitchen utensils and sanitary wares which are convenient, elegant and portable to combine.

Description

本发明涉及一种强化超薄型人造玉板、人造翡翠板、人造玛瑙板、人造琥珀板、人造陶瓷板、人造大理石板及其生产方法和用该系列化板制作的组合家具。The invention relates to a strengthened ultra-thin artificial jade board, artificial emerald board, artificial agate board, artificial amber board, artificial ceramic board, artificial marble board, production method thereof and combined furniture made of the serialized boards.

随着人们生活水平的提高,高档豪华型家具逐步进入人们的生活,如大理石面写字台,餐桌以及聚酯组合家具,虽然美观、气派,但美中不足的是大理石比较沉重,聚酯板材较厚、制作家具成本高,而且缺乏韧性、不耐压,容易变形,影响使用寿命。With the improvement of people's living standards, high-end luxury furniture gradually enters people's lives, such as marble-faced writing desks, dining tables and polyester combination furniture. The cost of furniture is high, and it lacks toughness, is not pressure-resistant, and is easy to deform, which affects the service life.

本发明的目的是提供一种轻而薄、光洁明亮、色泽多变、韧性和耐压性能良好的强化超薄型人造系列化板材。The object of the present invention is to provide a reinforced ultra-thin man-made serial plate material which is light and thin, clean and bright, changeable in color, good in toughness and pressure resistance.

本发明的另一目的是提供一种工艺简单、成本低廉的超薄型人造系列化板的生产方法。Another object of the present invention is to provide a production method of an ultra-thin artificial serialized board with simple process and low cost.

本发明的另一目的是提供一种作用超薄型人造系列化板制作的组合方便、高雅美观、轻便的高档组合家具。Another object of the present invention is to provide a high-grade modular furniture that is easy to assemble, elegant and beautiful, and light and made of ultra-thin artificial serialized boards.

本发明是这样实现的:强化超薄型人造系列化板,主要以甲基丙烯酸甲丁脂或不饱和聚酯树脂等脂类化工原料及无机化工原料等组成,其特征是在脂类化工原料中添加碳化硅纤维,制成人造系列化板,其组成为:The present invention is realized in this way: the strengthened ultra-thin man-made serialized board is mainly composed of lipid chemical raw materials such as methyl butyl methacrylate or unsaturated polyester resin and inorganic chemical raw materials, and is characterized in that the lipid chemical raw materials Adding silicon carbide fiber to make man-made series board, its composition is:

(1)强化超薄型人造玉板(以1000克为单位),不饱和聚酯树脂800克-850克、碳化硅纤维150-200克;(1) Reinforced ultra-thin artificial jade plate (in units of 1000 grams), 800-850 grams of unsaturated polyester resin, 150-200 grams of silicon carbide fiber;

(2)强化超薄型人造翡翠板(以1000克为单位),不饱和聚酯树脂800-850克、碳化硅纤维150-200,色素1-2克;(2) Reinforced ultra-thin artificial jade plate (in units of 1000 grams), 800-850 grams of unsaturated polyester resin, 150-200 grams of silicon carbide fiber, and 1-2 grams of pigment;

(3)强化超薄型人造玛瑙板(以1000克为单位),不饱和聚酯树脂800-850克、碳化硅纤维150-200克;(3) Reinforced ultra-thin artificial agate board (in units of 1000 grams), 800-850 grams of unsaturated polyester resin, 150-200 grams of silicon carbide fiber;

(4)强化超薄型人造琥珀板(以1000克为单位),甲基丙烯酸甲丁脂700-800克、碳化硅纤维150-200克、三氯甲烷50-100克、硬化剂6-10克;(4) Reinforced ultra-thin artificial amber board (in units of 1000 grams), 700-800 grams of methyl butyl methacrylate, 150-200 grams of silicon carbide fiber, 50-100 grams of chloroform, and 6-10 grams of hardener gram;

(5)强化超薄型人造陶瓷板(以3000克为单位),石膏900-1000克、碳化硅纤维150-200克、仿瓷涂料900-1000克、水900-1000克;(5) Reinforced ultra-thin artificial ceramic plate (in units of 3000 grams), 900-1000 grams of gypsum, 150-200 grams of silicon carbide fiber, 900-1000 grams of imitation porcelain paint, and 900-1000 grams of water;

(6)强化超薄型人造透明大理石板,分为表层和芯层两种材料配比,表层(以4000克为单位),不饱和聚酯树脂900-1000克、碳化硅纤维150-200克、高纯度粉沫状碳酸钙900-1000克、粒子状碳酸钙900-1000克、石英砂500-700克;芯层(以3000克为单位),不饱和聚酯树脂800-1000克、碳化硅纤维150-200克、硬化剂6-10克、高纯度粉沫状碳酸钙900-1000克、粒子状碳酸钙900-1000克。(6) Reinforced ultra-thin artificial transparent marble slabs are divided into surface layer and core layer. The surface layer (in units of 4000 grams), unsaturated polyester resin 900-1000 grams, silicon carbide fiber 150-200 grams , high-purity powdered calcium carbonate 900-1000 grams, granular calcium carbonate 900-1000 grams, quartz sand 500-700 grams; core layer (in units of 3000 grams), unsaturated polyester resin 800-1000 grams, carbonized 150-200 grams of silicon fiber, 6-10 grams of hardener, 900-1000 grams of high-purity powdered calcium carbonate, and 900-1000 grams of granular calcium carbonate.

强化超薄型人造系列化板的生产方法,包括配制溶液、模铸成型、干燥固化、脱模等步骤,其特征是在配制溶液工序时按比例在脂类化工原料中添加碳化硅纤维混合后,另添加无机化工原料;在模铸成型工序时先在带有排气孔的模具内表面涂抹表层材料混合液,然后注入芯材混合液,再在芯材混合液表面涂抹表层材料混合液。The production method of reinforced ultra-thin man-made serialized board includes the steps of preparing solution, molding, drying and curing, and demolding. , and add inorganic chemical raw materials; in the molding process, first apply the surface material mixture on the inner surface of the mold with vent holes, then inject the core material mixture, and then apply the surface material mixture on the surface of the core material mixture.

用强化超薄型人造系列化板制作的组合家具,其特征在于系列化板的周边加压铝合金边框、并安装有合页、吸盘支撑块、脚轮等。The combined furniture made of strengthened ultra-thin man-made serialized panels is characterized in that the serialized panels are surrounded by pressurized aluminum alloy frames, and are equipped with hinges, suction cup support blocks, casters, etc.

下面结合本发明的实施例及附图对本发明作进一步说明:Below in conjunction with the embodiments of the present invention and accompanying drawing, the present invention will be further described:

图1  为本发明的组合柜示意图;Fig. 1 is the combined cabinet schematic diagram of the present invention;

图2  为本发明的写字台示意图;Fig. 2 is desk schematic diagram of the present invention;

图3  为本发明的会议桌示意图。Fig. 3 is the conference table schematic diagram of the present invention.

首先详述强化超薄型人造系列化板的组成及生产方法。Firstly, the composition and production method of the strengthened ultra-thin man-made serialized board are described in detail.

(1)强化超薄型人造玉板是由型号“199”(也可以用“306”或“307”)不饱和聚酯树脂溶液、碳化硅纤维(也可以用尼龙丝或聚乙烯细丝)组成的。将“199”不饱和聚酯树脂溶液850克中添加碳化硅纤维(直径0.25mm、长3-5mm)150克混合均匀后倒入带有排气孔的板模中,待自然干燥固化(一般需20-30小时)后脱模。(1) The reinforced ultra-thin artificial jade plate is made of unsaturated polyester resin solution of model "199" ("306" or "307" can also be used), silicon carbide fiber (nylon filament or polyethylene filament can also be used) consist of. Add 150 grams of silicon carbide fiber (diameter 0.25 mm, length 3-5 mm) to 850 grams of "199" unsaturated polyester resin solution, mix evenly, pour it into a plate mold with vent holes, and wait for natural drying and curing (generally It takes 20-30 hours) to demould.

(2)强化超薄型人造玛瑙板是由“115-A玛瑙型不饱和聚酯树脂”溶液、碳化硅纤维(也可用尼龙丝或聚乙烯丝)组成的。其配比和生产方法与人造玉板相同。(2) The reinforced ultra-thin artificial agate board is composed of "115-A agate type unsaturated polyester resin" solution and silicon carbide fiber (nylon or polyethylene wire can also be used). Its ratio and production method are the same as artificial jade board.

(3)强化超薄型人造翡翠板是由型号“195”或“196”不饱和聚酯树脂溶液、碳化硅纤维(也可以用尼龙丝或聚乙烯丝)等组成的。将“195”不饱和聚酯树脂溶液848克中添加碳化硅纤维(直径0.25mm、长3-5mm)150克、绿色素2克混合均匀后倒入带有排气孔的板模内,待自然干燥固化(一般需20-30小时)后脱模。(3) Reinforced ultra-thin artificial emerald board is composed of unsaturated polyester resin solution of type "195" or "196", silicon carbide fiber (nylon wire or polyethylene wire can also be used), etc. Add 150 grams of silicon carbide fiber (diameter 0.25 mm, length 3-5 mm) and 2 grams of green pigment to 848 grams of "195" unsaturated polyester resin solution, mix well, and pour it into a plate mold with vent holes. After natural drying and curing (generally 20-30 hours), demould.

(4)强化超薄型人造琥珀板是由甲基丙烯酸甲丁酯、碳化硅纤维(也可以用尼龙丝或聚乙烯丝)、三氯甲烷等组成的。制备时将粒状或粉状甲基丙烯酸甲丁脂740克、碳化硅纤维(直径0.25mm、长3-5mm)150克混合后,加入三氯甲烷100克(能将甲基丙烯酸甲丁脂溶解成蛋清样),硬化剂10克制成混合液倒入板模内,在模壁上有很多排气孔,待三氯甲烷蒸发后,让其自然干燥固化(一般需30小时左右)后脱模。(4) The reinforced ultra-thin artificial amber board is composed of methyl butyl methacrylate, silicon carbide fiber (nylon wire or polyethylene wire can also be used), chloroform, etc. When preparing, mix 740 grams of granular or powdered methyl butyl methacrylate and 150 grams of silicon carbide fiber (0.25 mm in diameter, 3-5 mm in length), and then add 100 grams of chloroform (which can dissolve methyl butyl methacrylate) Egg white sample), 10 grams of hardener to make a mixed solution and pour it into the plate mold. There are many vent holes on the mold wall. After the chloroform evaporates, let it dry and solidify naturally (generally takes about 30 hours) and then remove it. mold.

(5)强化超薄型人造陶瓷板是由石膏、碳化硅纤维(也可以用尼龙丝或聚乙烯丝)、“888”型号仿瓷涂料等组成的。将石膏粉800克、碳化硅纤维(直径0.25mm、长3-5mm)200克混合,再将仿瓷涂料1000克用1000克的水调稀后与含有碳化硅纤维的石膏粉混合均匀后倒入板模中,待硬化后,将表面涂抹两层“888”仿瓷涂料,自然干燥固化(一般需30小时左右)后脱模。(5) Reinforced ultra-thin artificial ceramic board is composed of gypsum, silicon carbide fiber (nylon or polyethylene wire can also be used), "888" imitation porcelain paint, etc. Mix 800 grams of gypsum powder and 200 grams of silicon carbide fiber (diameter 0.25 mm, length 3-5 mm), then dilute 1,000 grams of imitation porcelain paint with 1,000 grams of water, mix evenly with gypsum powder containing silicon carbide fiber, and pour Put it into the formwork, and after hardening, apply two layers of "888" imitation porcelain paint on the surface, let it dry and solidify naturally (generally takes about 30 hours), and then demould.

(6)强化超薄型人造透明大理石板、分为表层和芯层两种材料配比。表层是由不饱和聚酯树脂溶液、碳化硅纤维(也可以用白色尼龙丝或聚乙烯丝)、聚酯系色涂料、硬化剂、70微米粒子状碳酸钙、70微米粉沫状碳酸钙、石英砂组成的。首先将不饱和聚酯树脂溶液1000克、碳化硅纤维(直径0.25mm、长3-5mm)200克混合均匀,另添加聚酯树脂白色涂料80克、硬化剂20克、高纯度粉沫状碳酸钙1000克、粒子状碳酸钙1000克、石英砂700克,边加入边搅拌均匀,制备成一种粘稠的混合液,滤去杂质备用。芯层是由不饱和聚酯树脂溶液、碳化硅纤维、硬化剂、70微米粒子状碳酸钙、70微米粉沫状碳酸钙组成的。将不饱和聚酯树脂溶液800克、碳化硅纤维(直径0.25mm、长3-5mm)190克混合,另添加硬化剂10克、粉沫状碳酸钙1000克、粒子状碳酸钙1000克,均匀混合搅拌成混合液。在制备大理石板时,将表层材料混合液用毛刷均匀涂抹在模具的内表面,涂层厚度为1mm,放置2小时,在室温下达到凝胶状态。然后将芯材混合液注入模中,在室温下放置3小时,待干燥固化后即可脱模。如果要求上下面都透明光亮,在芯材进模固化时,再在芯材表面涂一层表层混合液,待干燥固化出模即可。(6) Strengthen the ultra-thin artificial transparent marble slab, which is divided into two material ratios: the surface layer and the core layer. The surface layer is made of unsaturated polyester resin solution, silicon carbide fiber (white nylon wire or polyethylene wire can also be used), polyester color coating, hardener, 70 micron granular calcium carbonate, 70 micron powdered calcium carbonate, Made of quartz sand. First, mix 1000 grams of unsaturated polyester resin solution, 200 grams of silicon carbide fiber (diameter 0.25mm, length 3-5mm) and mix evenly, then add 80 grams of polyester resin white paint, 20 grams of hardener, high-purity powder carbonic acid 1000 grams of calcium, 1000 grams of granular calcium carbonate, and 700 grams of quartz sand were added and stirred evenly to prepare a viscous mixed solution, which was filtered to remove impurities for later use. The core layer is composed of unsaturated polyester resin solution, silicon carbide fiber, hardener, 70-micron granular calcium carbonate, and 70-micron powdered calcium carbonate. Mix 800 grams of unsaturated polyester resin solution, 190 grams of silicon carbide fiber (diameter 0.25 mm, length 3-5 mm), add 10 grams of hardener, 1000 grams of powdered calcium carbonate, and 1000 grams of granular calcium carbonate, and mix them evenly. Stir to form a mixture. When preparing the marble slab, apply the surface material mixture evenly on the inner surface of the mold with a brush, the thickness of the coating is 1mm, leave it for 2 hours, and reach the gel state at room temperature. Then inject the core material mixture into the mold, leave it at room temperature for 3 hours, and release the mold after drying and curing. If the top and bottom are required to be transparent and bright, when the core material enters the mold and solidifies, apply a layer of surface layer mixture on the surface of the core material, and leave the mold after drying and curing.

接着详述用强化超薄型人造系列化板制作的组合家具。组合家具所需的各种规格的型板材,经包压铝合金边框4后,安装合页2、吸盘支撑块6、脚轮5等,按一定规格和需求组合成一种高档化家具。如图1、图2、图3所示的组合柜,写字台、会议桌。图1的组合柜所用的组合板1是经包压铝合金边框4的超薄型人造玉板,它与柜门3及后板通过合页2、吸盘支撑块6、脚轮5巧妙地组合为一个整体,成为高档豪华的组合家具。同样可以组合成餐桌、床头柜、文件柜等。人造玛瑙板光洁明亮、不易破碎,还可以制成各种厨室用具及卫生洁具,如洗碗池,洗澡盆等。由于添加了色素和涂料,因而色泽多变,画上各种色彩图案可作屏风、装饰用品及工艺品等。Then describe in detail the combined furniture made of reinforced ultra-thin man-made serialized boards. The profiled plates of various specifications required by the combined furniture are assembled into a high-grade furniture according to certain specifications and requirements after the aluminum alloy frame 4 is wrapped, and the hinges 2, suction cup support blocks 6, casters 5, etc. are installed. Combination cabinets, writing desks, conference tables as shown in Figure 1, Figure 2, and Figure 3. The composite panel 1 used in the composite cabinet of Fig. 1 is an ultra-thin artificial jade panel with a pressed aluminum alloy frame 4, which is skillfully combined with the cabinet door 3 and the rear panel through hinges 2, suction cup support blocks 6, and casters 5. As a whole, it becomes a high-end and luxurious combined furniture. It can also be combined into a dining table, bedside table, filing cabinet, etc. The artificial agate board is bright and clean, not easy to break, and can also be made into various kitchen utensils and sanitary ware, such as sinks, bath tubs, etc. Due to the addition of pigments and paints, the color is changeable, and various color patterns can be painted for screens, decorative items and handicrafts.

本发明的优点在于人造系列化板中加入强化材料碳化硅纤维或尼龙丝、聚乙烯丝等,因而提高了板材的韧性和抗压强度,不易破碎,同时减轻了重量和厚度、可薄至5mm以下,比普通聚酯板轻50%以上。因而成本也大大降低,使用范围进一步扩大,过去人们不敢问津的人造玉、人造玛瑙、人造翡翠、人造琥珀等逐步进入人们的生活。The advantage of the present invention is that reinforcing materials such as silicon carbide fiber, nylon wire, polyethylene wire, etc. are added to the artificial serialized board, thereby improving the toughness and compressive strength of the board, making it not easy to break, and reducing the weight and thickness at the same time, and can be as thin as 5mm Below, more than 50% lighter than ordinary polyester board. Therefore, the cost is also greatly reduced, and the scope of use is further expanded. Artificial jade, artificial agate, artificial emerald, artificial amber, etc. that people did not dare to pay attention to in the past have gradually entered people's lives.

Claims (3)

1、一种强化超薄型人造系列化板,主要以甲基丙烯酸甲丁脂或不饱和聚酯树脂等脂类化工原料及无机化工原料等组成,其特征是在脂类化工原料中添加碳化硅纤维,制成人造系列化板,其组成为:1. A reinforced ultra-thin man-made serial board, mainly composed of lipid chemical raw materials such as methyl butyl methacrylate or unsaturated polyester resin and inorganic chemical raw materials, and is characterized in that carbonization is added to the lipid chemical raw materials Silicon fiber, made of man-made series board, its composition is: (1)强化超薄型人造玉板(以1000克为单位),不饱和聚酯树脂800克-850克、碳化硅纤维150-200克;(1) Reinforced ultra-thin artificial jade plate (in units of 1000 grams), 800-850 grams of unsaturated polyester resin, 150-200 grams of silicon carbide fiber; (2)强化超薄型人造翡翠板(以1000克为单位),不饱和聚酯树脂800-850克、碳化硅纤维150-200克,色素1-2克;(2) Reinforced ultra-thin artificial emerald board (in units of 1000 grams), 800-850 grams of unsaturated polyester resin, 150-200 grams of silicon carbide fiber, and 1-2 grams of pigment; (3)强化超薄型人造玛瑙板(以1000克为单位),不饱和聚酯树脂800-850克、碳化硅纤维150-200克;(3) Reinforced ultra-thin artificial agate board (in units of 1000 grams), 800-850 grams of unsaturated polyester resin, 150-200 grams of silicon carbide fiber; (4)强化超薄型人造琥珀板(以1000克为单位),甲基丙烯酸甲丁脂700-800克、碳化硅纤维150-200克、三氯甲烷50-100克、硬化剂6-10克;(4) Reinforced ultra-thin artificial amber board (in units of 1000 grams), 700-800 grams of methyl butyl methacrylate, 150-200 grams of silicon carbide fiber, 50-100 grams of chloroform, and 6-10 grams of hardener gram; (5)强化超薄型人造陶瓷板(以3000克为单位),石膏900-1000克、碳化硅纤维150-200克、仿瓷涂料900-1000克、水900-1000克;(5) Reinforced ultra-thin artificial ceramic plate (in units of 3000 grams), 900-1000 grams of gypsum, 150-200 grams of silicon carbide fiber, 900-1000 grams of imitation porcelain paint, and 900-1000 grams of water; (6)强化超薄型人造透明大理石板,分为表层和芯层两种材料配比,表层(以4000克为单位),不饱和聚酯树脂900-1000克、碳化硅纤维150-200克、聚酯树脂涂料50-100克、硬化剂10-20克、高纯度粉沫状碳酸钙900-1000克、粒子状碳酸钙900-1000克、石英砂500-700克;芯层(以3000克为单位),不饱和聚酯树脂800-1000克、碳化硅纤维150-200克、硬化剂6-10克、高纯度粉沫状碳酸钙900-1000克、粒子状碳酸钙900-1000克。(6) Reinforced ultra-thin artificial transparent marble slabs are divided into surface layer and core layer. The surface layer (in units of 4000 grams), unsaturated polyester resin 900-1000 grams, silicon carbide fiber 150-200 grams , 50-100 grams of polyester resin coating, 10-20 grams of hardener, 900-1000 grams of high-purity powdered calcium carbonate, 900-1000 grams of granular calcium carbonate, 500-700 grams of quartz sand; the core layer (with 3000 gram unit), unsaturated polyester resin 800-1000 grams, silicon carbide fiber 150-200 grams, hardener 6-10 grams, high-purity powder calcium carbonate 900-1000 grams, granular calcium carbonate 900-1000 grams . 2、一种如权利要求1所组成的系列化板的生产方法,包括配制溶液、模铸成型、干燥固化、脱模等步骤,其特征是在配制溶液工序时按比例在脂类化工原料中添加碳化硅纤维混合后,另添加无机化工原料;在模铸成型工序时先在带有排气孔的模具内表面涂抹表层材料混合液,然后注入芯材混合液,再在芯材混合液表面涂抹表层材料混合液。2. A method for producing a serialized plate as claimed in claim 1, comprising the steps of preparing a solution, molding, drying and solidifying, and demoulding, and is characterized in that it is added in proportion to the lipid chemical raw materials during the solution preparation process. After adding silicon carbide fiber and mixing, add inorganic chemical raw materials; in the molding process, first smear the surface material mixture on the inner surface of the mold with vent holes, then inject the core material mixture, and then apply the core material mixture on the surface of the core material mixture. Apply the surface material mixture. 3、一种用权利要求1组成的系列化板制作的组合家具,其特征在于系列化板的周边加压铝合金边框(4)、并安装有合页(2)、吸盘支撑块(6)、脚轮(5)等。3. A combined furniture made of the serialized panels according to claim 1, characterized in that the aluminum alloy frames (4) are pressurized around the serialized panels, and hinges (2) and suction cup support blocks (6) are installed , casters (5) and so on.
CN 93102733 1993-03-18 1993-03-18 Reinforced ultra-thin man-made serialized board, its production method, and combined furniture made of the serialized board Pending CN1075725A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101845119A (en) * 2010-05-25 2010-09-29 宁波华缘玻璃钢电器制造有限公司 Polyester molding compound with imitative agate decorative patterns and preparation method thereof
CN102559019A (en) * 2011-12-29 2012-07-11 文杰 Agate-imitating spray coating material
CN103880396A (en) * 2014-02-16 2014-06-25 由伟 High-tenacity artificial jade and preparation method thereof
CN104674927A (en) * 2013-11-28 2015-06-03 唐代全 Closestool and wash basin barely feel cold in winter

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101845119A (en) * 2010-05-25 2010-09-29 宁波华缘玻璃钢电器制造有限公司 Polyester molding compound with imitative agate decorative patterns and preparation method thereof
CN101845119B (en) * 2010-05-25 2011-10-19 宁波华缘玻璃钢电器制造有限公司 Polyester molding compound with imitative agate decorative patterns and preparation method thereof
CN102559019A (en) * 2011-12-29 2012-07-11 文杰 Agate-imitating spray coating material
CN102559019B (en) * 2011-12-29 2015-02-11 张亦彬 Agate-imitating spray coating material
CN104674927A (en) * 2013-11-28 2015-06-03 唐代全 Closestool and wash basin barely feel cold in winter
CN103880396A (en) * 2014-02-16 2014-06-25 由伟 High-tenacity artificial jade and preparation method thereof

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