CN102302029A - Compounded pesticide - Google Patents
Compounded pesticide Download PDFInfo
- Publication number
- CN102302029A CN102302029A CN201110202747A CN201110202747A CN102302029A CN 102302029 A CN102302029 A CN 102302029A CN 201110202747 A CN201110202747 A CN 201110202747A CN 201110202747 A CN201110202747 A CN 201110202747A CN 102302029 A CN102302029 A CN 102302029A
- Authority
- CN
- China
- Prior art keywords
- metaflumizone
- prescription
- rynaxypyr
- pesticide
- effect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000575 pesticide Substances 0.000 title claims abstract description 19
- 239000005914 Metaflumizone Substances 0.000 claims abstract description 29
- MIFOMMKAVSCNKQ-HWIUFGAZSA-N Metaflumizone Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)N\N=C(C=1C=C(C=CC=1)C(F)(F)F)\CC1=CC=C(C#N)C=C1 MIFOMMKAVSCNKQ-HWIUFGAZSA-N 0.000 claims abstract description 29
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000000375 suspending agent Substances 0.000 claims description 8
- 239000004562 water dispersible granule Substances 0.000 claims description 6
- 230000000361 pesticidal effect Effects 0.000 claims description 3
- KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 241000500437 Plutella xylostella Species 0.000 abstract description 17
- 230000000694 effects Effects 0.000 abstract description 11
- 231100000053 low toxicity Toxicity 0.000 abstract description 4
- 239000005886 Chlorantraniliprole Substances 0.000 abstract description 2
- 230000002688 persistence Effects 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 18
- 239000003814 drug Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- 241000238631 Hexapoda Species 0.000 description 9
- 231100000225 lethality Toxicity 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 230000032696 parturition Effects 0.000 description 7
- 230000000749 insecticidal effect Effects 0.000 description 6
- 230000002195 synergetic effect Effects 0.000 description 6
- 241000500441 Plutellidae Species 0.000 description 5
- 241000607479 Yersinia pestis Species 0.000 description 5
- 239000004480 active ingredient Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 230000010534 mechanism of action Effects 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 230000002633 protecting effect Effects 0.000 description 5
- 235000013305 food Nutrition 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 241000254173 Coleoptera Species 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 235000011299 Brassica oleracea var botrytis Nutrition 0.000 description 2
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 2
- 240000003259 Brassica oleracea var. botrytis Species 0.000 description 2
- 241000255777 Lepidoptera Species 0.000 description 2
- 206010034133 Pathogen resistance Diseases 0.000 description 2
- 108010052164 Sodium Channels Proteins 0.000 description 2
- 102000018674 Sodium Channels Human genes 0.000 description 2
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 241001290610 Abildgaardia Species 0.000 description 1
- 241000590412 Agromyzidae Species 0.000 description 1
- 241000254127 Bemisia tabaci Species 0.000 description 1
- 244000178993 Brassica juncea Species 0.000 description 1
- 235000005855 Brassica juncea var. subintegrifolia Nutrition 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000017647 Brassica oleracea var italica Nutrition 0.000 description 1
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 1
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 1
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 1
- 241001674939 Caulanthus Species 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- 241001124134 Chrysomelidae Species 0.000 description 1
- 241000931705 Cicada Species 0.000 description 1
- 241000338702 Cupido minimus Species 0.000 description 1
- 241000256602 Isoptera Species 0.000 description 1
- 241001582888 Lobus Species 0.000 description 1
- 241000256259 Noctuidae Species 0.000 description 1
- 241000819999 Nymphes Species 0.000 description 1
- 241000255893 Pyralidae Species 0.000 description 1
- 244000088415 Raphanus sativus Species 0.000 description 1
- 235000006140 Raphanus sativus var sativus Nutrition 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 210000003050 axon Anatomy 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- -1 ction Species 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 150000007659 semicarbazones Chemical class 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a compounded pesticide, wherein the compounded pesticide comprises 1-20% of chlorantraniliprole and 1-30% of metaflumizone. The compounded pesticide has the advantages of high efficiency, low toxicity, long persistence, high quick action, very good preventing and treating effect on plutella xylostella and uneasiness for generating pesticide damage; meanwhile, the generation of resistance to the pesticide is slowed down and the pollution to the environment is reduced.
Description
Technical field
The invention belongs to pesticide field, relate in particular to the compounded pesticides of a kind of Rynaxypyr and metaflumizone.
Background technology
Rynaxypyr (Chlorantraniliprole); It is a kind of brand-new low toxicity efficient pesticides of du pont company exploitation; The Rynaxypyr high-efficiency broad spectrum; Lepidopterous Noctuidae, Pyralidae, moth fruit moth section, tortricid, miller section, diamond-back moth section, Gelechidae, Gracilariidae etc. all there is excellent control effect; Can also control the coleoptera Culculionidae; Chrysomelidae, diptera Agromyzidae, multiple non-lepidoptera pest such as Bemisia tabaci.According to preliminary on probation, very good really to lepidopterous insect effect, the control time is very long.
Metaflumizone (metaflumizone) is a kind of brand-new compound that BASF Aktiengesellschaft and Japanese agricultural chemicals company develop jointly, and belongs to the semicarbazones insecticides.The mechanism of action of metaflumizone is unique, and itself has insecticidal activity, does not need bioactivation, does not have cross resistance with existing each insecticides.Metaflumizone can be prevented and treated larva, the adult of lepidoptera pest and some coleoptera effectively, can also be used to prevent and treat insects such as ant, termite, fly class, cicada dung beetle.Metaflumizone is a kind of insecticide of brand-new mechanism of action, and on the acceptor attached to sodium-ion channel, it is current to hinder sodium ion, does not have cross resistance with the compound of chrysanthemum ester class or other kinds.This medicine mainly is to get food through insect to get into and stomach toxicity to take place in its body kill off the insect pests, and action of contace poison is less, no systemic action.This medicine all has the better prevention effect for target pest, the larva in each length of time; This medicine gets into polypide behind the insect's food-taking; Through the sodium-ion channel on the mechanism of action blocking-up insect neuron axon film of uniqueness; Make sodium ion can not pass through axolemma; And then inhibition nerve impulse makes excessive the loosening, benumb of polypide; Behind the several hrs, insect promptly stops to get food, and is dead in one to three day.
Because agricultural pests causes very big loss to crops production every year; Consider the agricultural chemicals of long-term use single variety; Impel insect to produce resistance easily; Environment is caused bigger pollution; Field trial shows; The existing medicament another kind of mixed pesticide different with mechanism of action; Can not only postpone resistance produces; Can also improve drug effect and residual period, reduce usage amount, reduce cost; Therefore we carry out composite with Rynaxypyr and metaflumizone; Improve insecticidal effect, enlarge insecticidal spectrum, reduce environmental pollution simultaneously.
Summary of the invention
The purpose of this invention is to provide a kind of high-efficiency low-toxicity, lasting effect is long, quick-acting is high, insecticidal spectrum is wide, the Pesticidal combination of environmental protection.Be specifically related to the pesticidal preparations that Rynaxypyr and metaflumizone are basis.
Above-mentioned compounded pesticides contains Rynaxypyr 1%-20%, metaflumizone 1%-30%.
Utilize the described compounded pesticides of foregoing invention, be equipped with the known auxiliary agent of those skilled in that art, can process formulation of the present invention with those skilled in that art's known method, its formulation that can process is suspending agent, water dispersible granules.
Advantage that the present invention has and beneficial effect: 1. high-efficiency low-toxicity; 2. quick-acting, hold to imitate and take into account; 3. noresidue, nuisanceless, environmentally safe; 4. use compound formulation, two kinds of active ingredients also have synergistic effect, and consumption reduces during all than single use, thereby have improved the insecticidal effect of active ingredient, have increased safety, have reduced environmental pollution.
Embodiment
Following instantiation is in order to further explain the present invention, but the present invention absolutely not only is limited to following these embodiment.Percentage all is weight percentage in the prescription, and employed former medicine and auxiliary agent are other producers and buy.
Formulation examples is following:
1, the preparation of suspending agent
According to the prescription requirement, be medium with water, will grind in the adding sand mills such as active ingredient, wetting agent, dispersant, thickener, defoamer, the back adds emulsification in the high-shear emulsifying still, makes suspending agent.
Prescription one (10% suspending agent)
Prescription two (20% suspending agents)
Prescription three (16% suspending agents)
2, the preparation of water dispersible granules
Active ingredient, wetting agent, dispersant, adhesive, filler etc. are fully mixed in the ratio of prescription, after ultrafine crusher is pulverized, add an amount of purified water, make water dispersible granules through kneading, granulation, drying, screening.
Prescription four (25% water dispersible granules)
Prescription five (20% water dispersible granules)
Diamond-back moth (Plutella xylostella) belongs to Lepidoptera diamond-back moth section, another name: little blue or green worm, pointed at both ends.The worldwide insect that migrates, crucifers such as main harm wild cabbage, purple cabbage, broccoli, a kind of sedge dish, leaf mustard, cauliflower, Chinese cabbage, rape, radish.The harm characteristics: first instar larvae is only got food mesophyll, stays epidermis, on the dish leaf, forms transparent one by one spot, and blank, 3～4 instar larvaes can be eaten into the dish leaf hole and incise, and full leaf is eaten and reticulated when serious.Often concentrate lobus cardiacus to cause harm in seedling stage, the influence bag heart.In the strain of reserving seed for planting, endanger tender stem, young pod and seed.Rynaxypyr and metaflumizone are two kinds of compositions that insecticidal activity is very high, according to their the effect characteristics and mechanism of action, the object of indoor biometrics are decided to be diamond-back moth.
The method of indoor biometrics is: adopt capillary trace drop method, capillary trace dropper volume is 1.0 μ L.With micro-dropper with soup by a drop in the back side of diamondback moth larvae, each concentration is handled about 30 larva, the culture dish that it is 9cm that per 5 larvas are put into a diameter, the built-in a small amount of feed of ware supplies to get food, in addition with 30 larvas of acetone drop as contrast.Larva after treatment still is placed in the receptacle, checks lethality behind the 48h.Data are handled with the SPSS software statistics.Obtain toxicity regression formula, the lethal concentration of 50, correlation coefficient etc., and obtain co-toxicity coefficient with the abundant method of Sun Yun.
The co-toxicity of mixture preparation adopts the abundant co-toxicity coefficient method representation of Sun Yun:
The theoretical toxicity index A=∑ of mixture preparation (toxicity index of certain medicine * percentage of this pharmaceutically active ingredient in mixture).
C was synergistic effect greater than 120 o'clock, less than 80 o'clock be antagonism, be addition during 80-120.
The different proportionings of table 1 are to the toxicity test result of diamond-back moth
Table 28% Rynaxypyr is tested the test of giving birth to of diamond-back moth
| Dosage (mg/L) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 5 | 100 | 18 | 18 | 18 |
| 10 | 100 | 29 | 29 | 29 |
| 20 | 100 | 37 | 37 | 37 |
| 40 | 100 | 52 | 52 | 52 |
| 50 | 100 | 68 | 68 | 68 |
| CK | 100 | 0 |
Table 320% metaflumizone is tested the test of giving birth to of diamond-back moth
| Dosage (mg/L) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 5 | 100 | 22 | 22 | 22 |
| 10 | 100 | 26 | 26 | 26 |
| 20 | 100 | 39 | 39 | 39 |
| 40 | 100 | 50 | 50 | 50 |
| 50 | 100 | 66 | 66 | 66 |
| CK | 100 | 0 |
The test of giving birth to of a pair of diamond-back moth of table 4 prescription is tested
| Dosage (mg/L) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 5 | 100 | 33 | 33 | 33 |
| 10 | 100 | 55 | 55 | 55 |
| 20 | 100 | 61 | 61 | 61 |
| 40 | 100 | 70 | 70 | 70 |
| 50 | 100 | 80 | 80 | 80 |
| CK | 100 | 0 |
The test of giving birth to of two pairs of diamond-back moths of table 5 prescription is tested
| Dosage (mg/L) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 5 | 100 | 28 | 28 | 28 |
| 10 | 100 | 49 | 49 | 49 |
| 20 | 100 | 60 | 60 | 60 |
| 40 | 100 | 72 | 72 | 72 |
| 50 | 100 | 86 | 86 | 86 |
| CK | 100 | 0 |
The test of giving birth to of three pairs of diamond-back moths of table 6 prescription is tested
| Dosage (mg/L) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 5 | 100 | 32 | 32 | 32 |
| 10 | 100 | 49 | 49 | 49 |
| 20 | 100 | 69 | 69 | 69 |
| 40 | 100 | 83 | 83 | 83 |
| 50 | 100 | 90 | 90 | 90 |
| CK | 100 | 0 |
The test of giving birth to of four pairs of diamond-back moths of table 7 prescription is tested
| Dosage (mg/L) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 5 | 100 | 36 | 36 | 36 |
| 10 | 100 | 67 | 67 | 67 |
| 20 | 100 | 81 | 81 | 81 |
| 40 | 100 | 92 | 92 | 92 |
| 50 | 100 | 98 | 98 | 98 |
| CK | 100 | 0 |
The test of giving birth to of five pairs of diamond-back moths of table 8 prescription is tested
| Dosage (mg/L) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 5 | 100 | 33 | 33 | 33 |
| 10 | 100 | 50 | 50 | 50 |
| 20 | 100 | 70 | 70 | 70 |
| 40 | 100 | 82 | 82 | 82 |
| 50 | 100 | 92 | 92 | 92 |
| CK | 100 | 0 |
It is bright to analyze above-mentioned tables of data, and when Rynaxypyr and metaflumizone different proportion were composite, the co-toxicity coefficient of prescription had obvious synergistic effect all greater than 120.It is one the most obvious with prescription four synergistic effect wherein to fill a prescription, and its co-toxicity coefficient is for being respectively 150.28 and 141.89.
Through the indoor biometrics test, select the field trial that the bigger prescription of CTC one, prescription four and the less prescription three of CTC are prevented and treated diamond-back moth, confirm the effect of prescription control diamond-back moth; Simultaneously through with the effect comparison of Rynaxypyr, the agent of metaflumizone list, verify the synergistic effect after composite.Concrete test method, data are following:
Test the test of pesticide effectiveness that one: 10% Rynaxypyr metaflumizone SC, 25% Rynaxypyr metaflumizone WDG, 16% Rynaxypyr metaflumizone SC do the field control diamond-back moth, use 8% Rynaxypyr SC and 15% metaflumizone SC simultaneously as contrast.The test place is Shouguang City, Weifang Prefecture, Shandong Province, and the time is on April 19th, 2011, test totally four processing, and each handles three repetitions, sub-district randomized arrangement, sub-district area 100m
2, the planting habit of all sub-districts all planting habit with local is identical, and is record dispenser same day and all synoptic data thereafter, specific as follows:
Table 9 duration of test meteorological data
The investigation standard is: 7d gets killed strain 50 strains at random behind the medicine in each sub-district, and the life or death number of bat dish method metering nymph calculates lethality; 150 clumps of parallel sampling method samplings are adopted in 15d, the every sub-district of 25d behind the medicine, investigate withered calculation, calculate withered heart rate and seedling protecting effect at last.Specifically data (data are the mean value of three repetitions) are as follows:
The effect table of table 1010% Rynaxypyr metaflumizone SC and other chemical control diamond-back moths
Annotate: data are the mean value that repeats for 3 times in the table, and letter is all Duncan testing differentia remarkable time mutually: in April, 2011 place: Shouguang, Shandong
Can find out from above data; Under the situation of using same dose; 25d behind medicine; The control rate of 10% Rynaxypyr metaflumizone SC, 25% Rynaxypyr metaflumizone WDG reaches 84.45% and 83.12% respectively; Effect when being higher than 8% Rynaxypyr SC and 15% metaflumizone SC use far away, difference is extremely remarkable.Simultaneously, 16% Rynaxypyr metaflumizone SC 25d after medication, its control efficiency to diamond-back moth on the vegetables has also reached 79.62%, and the preventive effect when only using a kind of single agent is significantly improved.Simultaneously, above-mentioned field trial also match (CTC is big more, and synergistic effect is big more) with the indoor biometrics test for data.
Find out that thus prescription one is best with the control efficiency of prescription four, but the two difference is not remarkable.Because suspending agent is the novel formulation that recent years, country promoted, it has more added water base phase constituent, thus friendly more to environment, consider product cost simultaneously, think that prescription one is even more ideal.
10% Rynaxypyr metaflumizone SC (prescription one) is carried out further test, filtered out the optium concentration of control diamond-back moth.Experimental scheme 10g/ mu, 12g/ mu, 14g/ mu and 4 concentration tonsures of 16g/ mu are also done contrast with the effect of 15% metaflumizone (10g/ mu), 8% Rynaxypyr (10g/ mu); Test method and investigation method are the same, and specifically data (mean values of three repetitions) are as follows:
Table 11 prescription one different amounts control diamond-back moth effect table
Annotate: data are the mean value that repeats for 3 times in the table, and letter is all Duncan testing differentia remarkable time mutually: in April, 2011 place: Shouguang, Shandong
Can find out from the result of the above-mentioned test of pesticide effectiveness; Increase along with the prescription dosage; Drug effect also increases to some extent; 10% Rynaxypyr metaflumizone SC consumption is a 14g/ mu; The seedling protecting effect of 25d is 86.77% behind the medicine, and apparently higher than 15% metaflumizone SC and 8% Rynaxypyr SC, difference is extremely remarkable; Simultaneously, seedling protecting effect is higher than 10g/ mu and 12g/ mu; When the mu consumption was 16g/ mu, 25 days seedling protecting effect is 87.01% after medication, and was not remarkable with the seedling protecting effect difference of mu consumption 14g.Therefore, under the prerequisite of considering the mu cost, should advocate mu usage amount is 14g/ mu.
Claims (3)
1. a compounded pesticides is characterized in that, said Pesticidal combination active component is made up of Rynaxypyr and metaflumizone.
2. compounded pesticides according to claim 1 is characterized in that, chloride worm benzamide 1%～20%, metaflumizone 1%～30%.
3. compounded pesticides according to claim 2 is characterized in that said compounded pesticides can be made into suspending agent, water dispersible granules.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110202747A CN102302029A (en) | 2011-07-19 | 2011-07-19 | Compounded pesticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110202747A CN102302029A (en) | 2011-07-19 | 2011-07-19 | Compounded pesticide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102302029A true CN102302029A (en) | 2012-01-04 |
Family
ID=45376027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110202747A Pending CN102302029A (en) | 2011-07-19 | 2011-07-19 | Compounded pesticide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102302029A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104026143A (en) * | 2013-03-07 | 2014-09-10 | 沈阳科创化学品有限公司 | Binary pesticide composition and its use |
| CN105613544A (en) * | 2014-10-28 | 2016-06-01 | 陕西美邦农药有限公司 | ZJ3757-containng insecticidal composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
| US20100130561A1 (en) * | 2007-04-17 | 2010-05-27 | Bayer Cropscience Ag | Controlling pests by combining insecticides and transgenic plants by applying directly to leaves and roots |
-
2011
- 2011-07-19 CN CN201110202747A patent/CN102302029A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101014247A (en) * | 2004-07-01 | 2007-08-08 | 杜邦公司 | Synergistic mixtures of anthranilamide invertebrate pest control agents |
| US20100130561A1 (en) * | 2007-04-17 | 2010-05-27 | Bayer Cropscience Ag | Controlling pests by combining insecticides and transgenic plants by applying directly to leaves and roots |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104026143A (en) * | 2013-03-07 | 2014-09-10 | 沈阳科创化学品有限公司 | Binary pesticide composition and its use |
| CN104026143B (en) * | 2013-03-07 | 2016-03-23 | 沈阳科创化学品有限公司 | Binary pesticide composition and uses thereof |
| CN105613544A (en) * | 2014-10-28 | 2016-06-01 | 陕西美邦农药有限公司 | ZJ3757-containng insecticidal composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102302022A (en) | Insecticidal composition | |
| CN102308805A (en) | Compound pesticide | |
| CN101803605B (en) | Insecticidal composition of butene-fipronil and spinosad | |
| CN102986707A (en) | Complex insecticide | |
| CN102742593A (en) | Insecticidal composition for control of athetis lepigone | |
| CN102007909B (en) | Spinosad-containing pesticidal composition | |
| CN102318620A (en) | Insecticidal composition | |
| CN103947646A (en) | Insecticidal composition | |
| CN102428932B (en) | Insecticidal composition | |
| CN102302029A (en) | Compounded pesticide | |
| CN102308812B (en) | Insecticidal composition | |
| CN102657216A (en) | Use of pesticide mixed preparation containing chlorpyrifos and high-efficiency cypermethrin in control of Athetis lepigone Moschler | |
| CN102657193A (en) | Complex insecticide | |
| CN102599170A (en) | Insecticidal composition | |
| CN102318609A (en) | Insecticidal composition | |
| CN102326577A (en) | Pesticide composition | |
| CN102308815A (en) | Pesticide composition | |
| Ghale | Efficiency of seed disinfection and foliar spray with Imidacloprid and Cypermethrin for control of flea beetles in canola | |
| CN102613211B (en) | Compound insecticide | |
| CN104285951A (en) | Compound insecticide | |
| CN102067846B (en) | Buprofezin-containing pesticide composition | |
| CN103651386A (en) | Insecticidal composition containing chlorfenapyr | |
| CN102805099A (en) | Insect disinfestation composition | |
| CN102657170A (en) | Pesticide composition | |
| CN102428926A (en) | Mixed insecticide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120104 |