CN104026143B - Binary pesticide composition and uses thereof - Google Patents
Binary pesticide composition and uses thereof Download PDFInfo
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- CN104026143B CN104026143B CN201310073053.1A CN201310073053A CN104026143B CN 104026143 B CN104026143 B CN 104026143B CN 201310073053 A CN201310073053 A CN 201310073053A CN 104026143 B CN104026143 B CN 104026143B
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- chlorantraniliprole
- pesticide composition
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- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
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- 239000000428 dust Substances 0.000 description 1
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- 238000005516 engineering process Methods 0.000 description 1
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- 150000002170 ethers Chemical class 0.000 description 1
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- 230000009969 flowable effect Effects 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
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- 235000011187 glycerol Nutrition 0.000 description 1
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- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 125000004591 piperonyl group Chemical group C(C1=CC=2OCOC2C=C1)* 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 229910001487 potassium perchlorate Inorganic materials 0.000 description 1
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- 238000003672 processing method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
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- 235000009566 rice Nutrition 0.000 description 1
- 235000021003 saturated fats Nutrition 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229940104261 taurate Drugs 0.000 description 1
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to field of pesticides, relate to a kind of binary pesticide composition and uses thereof.Active component one is four chlorantraniliproles, and active component two is semicarbazone compounds; Described four chlorantraniliprole structural formulas are as follows:
Description
Technical field
The invention belongs to field of pesticides, relate to a kind of binary pesticide composition and uses thereof.
Background technology
The agricultural chemicals of insecticide to be a kind of subject be insect, is mainly used in the medicine preventing and treating pest and urban health insect. use that history is long-range, consumption is large, wide in variety.In protection various crops and urban afforestation etc., there is obvious effect.
Chinese invention patent CN101333213A discloses a kind of 1-substituted pyridyl-pyrazol acid amide compounds and controls the purposes of insect pest and disease, wherein compound 1.25(tetra-chlorantraniliprole) can be used for preventing and treating various pests, especially to lepidoptera pest, there is outstanding control efficiency.
Pesticidal composition is that two or more pestsides synthesis form, and effectively can solve pest pesticide resistance distinct issues.Insecticide containing single-activity component, control of insect uses continuously, easily makes insect develop immunity to drugs.Selection index system mechanism is different, without the insecticide of two kinds of active components of cross resistance, mixture becomes by a certain percentage, can improve control efficiency, reduces the amount of application of the agricultural chemicals in unit are, reduces pesticide cost, while can delay the generation of pest resistance to insecticide.
Although disclose four chlorantraniliproles or its homologue and other Mixture Use of Insecticides in prior art general can produce additional advantage and effect, the technical scheme of the binary pesticide composition containing four chlorantraniliproles has no concrete open.
Summary of the invention
The object of the invention is the demand meeting agricultural and pest control aspect, urban health field day by day improves insecticide effect and kind is constantly updated, and provides a kind of binary pesticide composition and uses thereof.
For achieving the above object, the technical solution used in the present invention is:
A kind of binary pesticide composition, active component one is four chlorantraniliproles, and active component two is semicarbazone compounds; Described four chlorantraniliprole structural formulas are as follows:
Described semicarbazone compounds is metaflumizone, and wherein, the ratio of weight and number between two kinds of active components is 1:99-99:1.
Further, the ratio of weight and number between two kinds of active components is 1:20-20:1.
Composition can be made into missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder or oil-suspending agent.
In composition active component percentage by weight between 0.5%-95%.
Say further, in composition active component percentage by weight between 1%-85%.
The application of binary pesticide composition is characterized in that: described composition can be used as the insecticide controlling agriculture and forestry injurious insect or urban health insect.
Described composition imposes on the medium of insect or its growth needing to control with effective dose; Apply the effective dose that dosage is per hectare 10 grams-500 grams.
Say further, apply the effective dose that dosage is per hectare 15 grams-100 grams.
Tool of the present invention has the following advantages:
One is that composition of the present invention shows obvious synergistic effect in certain ratio range, improves the control efficiency of this compound to insect.
Two is using dosages that said composition reduces compound in the application, thus reduces use cost, reduces environmental pollution.
Three is that the mechanism of action of each active ingredient in said composition is different, there is not the problem of cross resistance, can delay the generation of pest resistance to insecticide with its pest control, and improve the control efficiency of antagonism population.
Embodiment
A kind of binary pesticide composition, active component one is four chlorantraniliproles, and structural formula is as follows:
Active component two is selected from metaflumizone; Demonstrate binary pesticide composition of the present invention through indoor biological determination of activity and there is good synergistic effect.Active component two in composition is metaflumizones.
Composition of the present invention can provide in dosage form.Make missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder, oil-suspending agent etc. as required.In composition, the percentage by weight cumulative amount of active component is between 0.5%-95%, and preferred cumulative amount is between 1%-85%.In composition of the present invention, the content of active component depends on amount of application when being used alone, and also depends on mixed ratio and synergistic effect degree.The optimum range of active component content is different according to the preparation type of composition.
The preparation of composite preparation of the present invention can be prepared by the processing method of routine, after mixing with liquid-carrier (solvent) or solid carrier by active substance, add one or more auxiliary agents as emulsifier, dispersant, wetting agent, adhesive, stabilizing agent and defoamer etc.Containing at least one carrier and at least one surfactant in usual composition.In all cases, should guarantee that present composition active component is uniformly distributed.
The active component of missible oil usually containing 10-75%, 2-20% emulsifier, other additive such as stabilizing agent, bleeding agent, the corrosion inhibitor etc. of 0-20%, and solvent (if desired also containing cosolvent).
Suspending agent needs sand milling usually, to obtain stable non-deposited flowable product.Usually containing 5-50% active component in suspending agent, 5-15% dispersant, 0.1-10% wetting agent, 4-10% antifreezing agent, other additive of 0-10% is as defoamer, preservative, stabilizing agent, bleeding agent and thickener, and liquid-carrier surplus.
(aqueous dispersion) granula makes 10-100 international standard sieve mesh (1.676-0.152mm) particle usually, can by extruding, dipping or Spray granulation method preparation, usually (aqueous dispersion) granule contains the active component of 0.5-80% and auxiliary agent such as dispersant, wetting agent, disintegrant and the adhesive of 5-20%, and inert carrier surplus.
The active component of wetting powder usually containing 10-85%, except solid inert carrier, the dispersant usually containing 3-10%, can also contain wetting agent and (or) other additive of 0-10%, such as bleeding agent or stabilizing agent.
Aqueous emulsion is that former medicine, organic solvent, emulsifier mixing are formed oil phase, water, antifreezing agent is mixed, becomes transparent and homogeneous liquid.With high-shear emulsion machine high speed shear oil phase, slowly aqueous phase is added oil phase, usual active component 1-60%, surfactant 5-20%, antifreezing agent 2-10%, water surplus simultaneously.
Microemulsion is mixed former medicine, organic solvent, surfactant, water, becomes transparent and homogeneous aqueous phase.Usual active component 1-50%, surfactant 10-40%, antifreezing agent 2-10%, water surplus.
Soluble liquid is mixed active component, organic solvent, surfactant, becomes transparent and homogeneous liquid.Usual active component 1-50%, surfactant 6-20%, organic solvent surplus.
Oil-suspending agent is by having active component, surfactant, oil based vehicle to add sand milling in sand mill, until particle diameter is qualified, and usual active component 2-60%, surfactant 6-20%, oil based vehicle surplus.
Moisture dispersion liquid and emulsion (composition that missible oil as of the present invention in dilute with water, wetting powder or concentrate obtain) are also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have dense thick paste-like consistency.
The preparation of composite preparation of the present invention can adopt known (liquid or solid) carrier of those skilled in the art and various auxiliary agent.Such as include but not limited to following all kinds of material.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc., as one or more in toluene, dimethylbenzene, acetone, cyclohexanone, dimethylbenzene, benzene, cyclohexane, isopropyl alcohol, ethylene glycol, sorbierite, methyl alcohol, ethanol, butanols, dimethyl formamide, naphthalane, machine oil, benzinum etc.
Suitable solid carrier comprises clay that is natural or synthesis and silicate, and the solid carrier being applicable to pulvis comprises the mineral matter (as microdispersed silicic acid or aluminium oxide) ground of the rock dust of natural formation, chalk, quartz, clay, imvite, silica, diatomite, float stone, gypsum, talcum, bentonite, kaolin, potter's clay and synthesis.The particulate vector be applicable to comprises the broken synthesis particle made with natural rock such as calcite, marble, float stone, sepiolite and dolomite of classification and by the powder of organic matter and inorganic matter.
Suitable cosolvent is one or more in methyl alcohol, phenol, isoamyl alcohol, dimethyl sulfoxide (DMSO), ethyl acetate, butanone, dimethyl formamide etc.
Suitable emulsifier can be ethoxylated castor oil, polyoxyethylene (n
20) phenethyl phenol ether through reaction oleate, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, agriculture breast 0201B, agriculture breast 0203B, agriculture breast T-20, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast 36#, agriculture breast 600#, agriculture breast 1601#, agriculture breast 2201#, agriculture breast OX-8686, agriculture breast 1601#, agriculture breast NP-15, agriculture breast OX-2681 etc.
Suitable dispersant can be sodium lignin sulfonate, calcium lignosulfonate, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, methyl naphthalene sulfonate formaldehyde condensate, methanonaphthalene sodium sulfonate, oleic acid methylaminoethyl sodium sulfonate, epoxidized polyether, to tertbutyl ether, piperonyl butoxide, alkyl amide taurate, dibutyl naphthalenesulfonic acid formaldehyde condensation products, alkylphenol-polyethenoxy based phosphates, methylcellulose etc.
Suitable wetting agent can be sodium sulphate, sldium lauryl sulfate, methanonaphthalene sodium sulfonate, neopelex, calcium dodecyl benzene sulfonate, Negel aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether etc.
Suitable thickener can be synthesis (as carbonyl methylol, polyvinyl alcohol, polyvinyl acetate) or natural water-soluble polymer (as xanthans, gelatin, gum Arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, polyethylene glycol, phenolic resins, shellac, carboxymethyl cellulose and sodium alginate etc.), adds in preparation with powder, particle or latex form.
Suitable defoamer is bubble enemy, silicone, C8-10 fatty alcohol, phosphoric acid ester, C10-20 saturated fat acids (as capric acid) and acid amides etc.
Suitable oxidant is: potassium chlorate, sodium chlorate, potassium perchlorate, sodium nitrate, potassium nitrate, potassium permanganate etc.
Suitable adhesive can be polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, carboxymethyl cellulose and sodium alginate etc.
Aerosol can be made during for preventing and treating city insect, need to add propellant wherein, also bait formulation composition be can make, except containing except active component, also the foodstuff of insect's food-taking, optional attractant and optional wetting agent are suitable for containing one or more.
Composition of the present invention is suitable for the multiple important agriculture and forestry injurious insect of control or urban health insect, as mythimna separata, beet armyworm, cotton bollworm, cutworm, tomato moth, apple skin worm, rice leaf roller, corn borer, striped rice borer, diamond-back moth, cabbage caterpillar, fall webworm, tent caterpillar, gypsymoth, Asiatic migratory locust, soil insect, leaf miner, liriomyza bryoniae, class Diabrotica etc., city insect is as termite, blattaria, ant, fly class, mosquito class etc.For fruit tree as apple, pears, citrus, lichee etc., Cereal is as wheat, paddy rice etc., and beans is as soybean, Kidney bean etc., and cotton, vegetables are as wild cabbage, cauliflower, Chinese cabbage, rape, tomato, capsicum etc., and flowers.During for preventing and treating city insect, may be used for family, various public place, office space etc.Therefore, the present composition can control agriculture and forestry injurious insect or urban health insect.
Following specific embodiment is for further describing the present invention, but the present invention is only limitted to absolutely not these examples.In embodiment, each component percentages or proportioning are all by weight.Active component in each formula calculates with effective content.
Formulation Example
The preparation of embodiment 1,10% 4 chlorantraniliprole metaflumizone missible oil
By recipe requirements, count by weight, by 5 part of four chlorantraniliprole, 5 parts of metaflumizones, 6 parts of agriculture breast 0201B, 4 parts of agriculture breast 0203B, 1.5 parts of agriculture breast 1601#, 5 parts of methyl alcohol, 73.5 parts of dimethylbenzene, mix, use hot bath heating for dissolving if desired, namely obtain 10% 4 chlorantraniliprole metaflumizone missible oil.
The preparation of embodiment 2,30% 4 chlorantraniliprole metaflumizone wetting powder
By recipe requirements, count by weight, by 5 part of four chlorantraniliprole, 25 parts of metaflumizones, 2 parts of lauryl sodium sulfate, 4 parts of calcium lignosulfonates, 8 parts of condensation compound of methyl naphthalene sulfonic acid and formaldehyde, 6 parts of White Carbon blacks, 2 parts of detergent LS, 48 parts of precipitated calcium carbonates, abundant mixing, after ultra-fine pulverizer disintegrating, namely obtain 30% 4 chlorantraniliprole metaflumizone wetting powder.
The preparation of embodiment 3,10% 4 chlorantraniliprole metaflumizone aqueous emulsion
By recipe requirements, count by weight, by 5 part of four chlorantraniliprole, 5 parts of metaflumizones, 10 parts of agriculture breast 2201#, 4.5 parts of alkylaryl polyoxyethylene poly-oxygen propylene aethers, 2.5 parts of piperonyl butoxides, 10 parts of cyclohexanone, 5 parts of glycerine, be added together, make to be dissolved into homogeneous oil phase.Under high velocity agitation, 58 parts of water, join oil phase, form 10% 4 chlorantraniliprole metaflumizone aqueous emulsion of favorable dispersibility.
The preparation of embodiment 4,15% 4 chlorantraniliprole metaflumizone aqueous emulsion
By recipe requirements, count by weight, by 12.5 part of four chlorantraniliprole, 2.5 parts of metaflumizones, 8.5 parts of agriculture breast 507#, 3.5 parts of agriculture breast OX-8686,3 parts of agriculture breast 1601#, 8 parts of dimethyl formamides, 0.5 part of tetradecanol, 5 parts of ethylene glycol, be added together, make to be dissolved into homogeneous oil phase.Under high velocity agitation, add 56.5 parts of water, join oil phase, form 15% 4 chlorantraniliprole metaflumizone aqueous emulsion of favorable dispersibility.
The preparation of embodiment 5,30% 4 chlorantraniliprole metaflumizone water-dispersible granules
By recipe requirements; count by weight; by 25 part of four chlorantraniliprole, 5 parts of metaflumizones, 8 parts of naphthalenesulfonic acid-formaldehyde condensates, 4 parts of methyl naphthalene sulfonate formaldehyde condensates, 6 parts of N-methyl-oleoyl-sodium taurocholates, 10 parts of sodium sulphate, 42 parts of kaolin; carry out co-grinding; add water again after mediating, add in the comminutor that certain specification screen cloth is housed and carry out granulation.And then drying, screening (by screen cloth scope) namely obtain 30% 4 chlorantraniliprole metaflumizone water-dispersible granules.
The preparation of embodiment 6,20% 4 chlorantraniliprole metaflumizone suspending agent
By recipe requirements, count by weight, by 10 part of four chlorantraniliprole, 10 parts of metaflumizones, 3 parts of methyl naphthalene sulfonate formaldehyde condensates, 3 parts of sodium lignin sulfonates, 6 parts of agriculture breast 0201B, 0.3 part of xanthans, 0.6 part of white carbon, 5 parts of ethylene glycol, 62.1 parts of water, add in sand milling still, carry out porphyrize, make 20% 4 chlorantraniliprole metaflumizone suspending agent.
The preparation of embodiment 7,9% 4 chlorantraniliprole metaflumizone soluble concentrate
By recipe requirements, count by weight, by 7.5 part of four chlorantraniliprole, 1.5 parts of metaflumizones, 15 parts of agriculture breast 2201#, 2 parts of agriculture breast T-20,8 parts of agriculture breast NP-15,12 parts of dimethyl formamides, 8 parts of methyl alcohol, 46 parts of methyl alcohol, mix, use hot bath heating for dissolving if desired, 9% 4 chlorantraniliprole metaflumizone soluble concentrate can be obtained.
The preparation of embodiment 8,20% 4 chlorantraniliprole metaflumizone microemulsion
By recipe requirements, count by weight, by 10 part of four chlorantraniliprole, 10 parts of metaflumizones, 5 parts of triphenyl vinyl phenol polyoxyethylene (n
20) ether phosphoric acid triethanolamine salt, 8 parts of agricultures breast 36#, 10 parts of agriculture breast OX-2681,20 parts of cyclohexanone are added together, make to be dissolved into homogeneous oil phase.Add 29 parts of water again, 5 parts of ethylene glycol are mixed, become homogeneous aqueous phase.Under high velocity agitation, aqueous phase joined oil phase or oil phase is joined aqueous phase, forming 20% 4 chlorantraniliprole metaflumizone microemulsion of favorable dispersibility.The preparation of embodiment 9,30% 4 chlorantraniliprole metaflumizone oil-suspending agent
By recipe requirements, count by weight, by 27 part of four chlorantraniliprole, 3 parts of metaflumizones, 3 parts of agriculture breast S-80,2 parts of agriculture breast T-20,6 parts of agriculture breast 0201B, 3 parts of agriculture breast 500#, 2 parts of white carbons, 54 parts of methylated soya oil, add in sand milling still, carry out porphyrize, make 30% 4 chlorantraniliprole metaflumizone oil-suspending agent.
Indoor biological determination of activity
Embodiment 10 4 chlorantraniliprole and metaflumizone used in combination to corn borer toxicity determination test
For examination object: corn borer (Ostriniafurnacalis), 3 instar larvaes, the sensitive strain of indoor feeding.
Test condition: temperature: 24-26 DEG C, humidity: RH60%, illumination: L:D=14:10
Test medication liquid making method: active component four chlorantraniliprole, the metaflumizone that accurately take insecticide of the present invention with electronic analytical balance respectively, then former medicine is added proper amount of acetone to dissolve, after dissolving completely, desired concn mother liquor is mixed with the water containing 0.1% Tween 80, in the ratio in insecticide of the present invention between two kinds of active components, above-mentioned mother liquor is hybridly prepared into mixed solution by a certain percentage, is diluted to the serial liquid of tool finite concentration gradient by experimental scheme dosage respectively.
Test method: adopt artificial feed culture plate method, 24 well culture plates of selection standard cleaning, every hole adds 1ml artificial feed, after cooled and solidified, adds 0.05ml liquid with continuous sampler to each hole of culture plate, then puts shady and cool place nature and dries in the shade.Select in the examination worm access culture plate of neat and consistent, 1, every hole, often processes repetition 4 times.Be placed in observation ward by the examination worm after process, routine observation examination worm response situation, 72h " Invest, Then Investigate " is dead, borer population of living.
With Abbott formulae discovery corrected mortality, appliance computer program obtains each the virulence regression equation formula, the LC that use with for examination single dose and variant proportioning
50value and 95% confidence limit, by Sun Yunpei (SunY-P) method, obtain the co-toxicity coefficient that each proportioning is mixed, evaluate.If co-toxicity coefficient is summation action close to 100, be synergistic effect apparently higher than 100, be starkly lower than 100 for antagonism.
Result of the test is in table 1.As can be seen from the table, each proportioning is mixed all shows synergistic effect to corn borer for trying for four chlorantraniliproles and metaflumizone.
Table 1: four chlorantraniliprole metaflumizones are to the indoor joint toxicity measuring result of corn borer
embodiment 11 4 chlorantraniliprole and metaflumizone used in combination to beet armyworm toxicity determination test
For examination object: beet armyworm (Spodopteraexigua), 3 instar larvaes, the sensitive strain of indoor feeding.
Test condition: temperature: 24-26 DEG C, humidity: RH60%, illumination: L:D=14:10
Drug solution preparation method is with embodiment 10.Test method: adopt infusion process to process, the cabbage leaves of greenhouse culture is fetched, make diameter 2cm leaf dish, leaf dish is flooded 5s respectively in above-described embodiment liquid or contrast liquid, dry in the shade after taking-up, put into the 9cm culture dish being lined with filter paper, select in the examination worm access culture dish of neat and consistent, often process repetition 4 times.Be placed in observation ward by the examination worm after process, routine observation examination worm response situation, 72h " Invest, Then Investigate " is dead, borer population of living.Contrast liquid is respectively four chlorantraniliproles, metaflumizone.
Calculation Estimation method is with embodiment 10.
Result of the test is in table 2.As can be seen from the table, each proportioning is mixed all shows synergistic effect to beet armyworm for trying for four chlorantraniliproles and metaflumizone.
Table 2: four chlorantraniliprole metaflumizones are to the indoor joint toxicity measuring result of beet armyworm
Claims (7)
1. a binary pesticide composition, is characterized in that: active component one is four chlorantraniliproles, and active component two is semicarbazone compounds; Described four chlorantraniliprole structural formulas are as follows:
Described semicarbazone compounds is metaflumizone, wherein,
Ratio of weight and number between two kinds of active components is 20:1.
2. according to binary pesticide composition according to claim 1, it is characterized in that: composition can be made into missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble liquid, wetting powder or oil-suspending agent.
3. according to binary pesticide composition according to claim 2, it is characterized in that: in composition, the percentage by weight of active component is between 0.5%-95%.
4. according to binary pesticide composition according to claim 3, it is characterized in that: in composition, the percentage by weight of active component is between 1%-85%.
5. a binary pesticide composition according to claim 1 is for controlling the application of agriculture and forestry injurious insect or urban health pests insecticide.
6. by application according to claim 5, it is characterized in that: described composition imposes on the insect of needs control or the medium of its growth with effective dose; Apply the effective dose that dosage is per hectare 10 grams-500 grams.
7. by application according to claim 6, it is characterized in that: apply the effective dose that dosage is per hectare 15 grams-100 grams.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310073053.1A CN104026143B (en) | 2013-03-07 | 2013-03-07 | Binary pesticide composition and uses thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310073053.1A CN104026143B (en) | 2013-03-07 | 2013-03-07 | Binary pesticide composition and uses thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN104026143A CN104026143A (en) | 2014-09-10 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103858910A (en) * | 2013-12-19 | 2014-06-18 | 北京燕化永乐生物科技股份有限公司 | Insecticide composition containing metaflumizone |
| CN104012558B (en) * | 2014-05-14 | 2016-03-16 | 青岛瀚生生物科技股份有限公司 | Containing the compounded pesticides of metaflumizone and four chlorantraniliproles |
| CN105532698B (en) * | 2014-11-03 | 2017-11-10 | 中化农化有限公司 | Composition and its application containing four chlorantraniliproles and process for preparation of benzoylurea compounds |
| CN104585198B (en) * | 2014-12-28 | 2016-08-24 | 江苏天容集团股份有限公司 | Containing four chlorantraniliprole Pesticidal combinations |
| CN104814022A (en) * | 2015-05-02 | 2015-08-05 | 广东中迅农科股份有限公司 | Insecticidal composition containing tetrachlorantraniliprole and lufenuron |
| TW202128016A (en) * | 2019-12-19 | 2021-08-01 | 美商富曼西公司 | Diamide suspension concentrate compositions |
| CN111567545A (en) * | 2020-06-01 | 2020-08-25 | 沈阳化工研究院（南通）化工科技发展有限公司 | Composition containing tetrachloro-zoon amide and metaflumizone and application thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102302029A (en) * | 2011-07-19 | 2012-01-04 | 北京燕化永乐农药有限公司 | Compounded pesticide |
| CN103918685A (en) * | 2013-01-11 | 2014-07-16 | 陕西汤普森生物科技有限公司 | Insect disinfestation composition containing tetrachlorantraniliprole |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102302029A (en) * | 2011-07-19 | 2012-01-04 | 北京燕化永乐农药有限公司 | Compounded pesticide |
| CN103918685A (en) * | 2013-01-11 | 2014-07-16 | 陕西汤普森生物科技有限公司 | Insect disinfestation composition containing tetrachlorantraniliprole |
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