CN102302022A - Insecticidal composition - Google Patents
Insecticidal composition Download PDFInfo
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- CN102302022A CN102302022A CN201110202725A CN201110202725A CN102302022A CN 102302022 A CN102302022 A CN 102302022A CN 201110202725 A CN201110202725 A CN 201110202725A CN 201110202725 A CN201110202725 A CN 201110202725A CN 102302022 A CN102302022 A CN 102302022A
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- Prior art keywords
- fipronil
- butene
- rynaxypyr
- effect
- borer
- Prior art date
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- 239000000203 mixture Substances 0.000 title abstract description 11
- 230000000749 insecticidal effect Effects 0.000 title abstract description 10
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000004480 active ingredient Substances 0.000 claims abstract description 4
- HVQHXBNMBZJPLK-UHFFFAOYSA-N 1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-5-[(2-methylprop-2-en-1-yl)amino]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound CC(=C)CNC1=C([S+]([O-])C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl HVQHXBNMBZJPLK-UHFFFAOYSA-N 0.000 claims description 29
- 230000000361 pesticidal effect Effects 0.000 claims description 8
- 239000000375 suspending agent Substances 0.000 claims description 5
- 239000004562 water dispersible granule Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 1
- 241000426497 Chilo suppressalis Species 0.000 abstract description 27
- 239000000575 pesticide Substances 0.000 abstract description 7
- 238000001228 spectrum Methods 0.000 abstract description 4
- 239000005886 Chlorantraniliprole Substances 0.000 abstract description 2
- 239000005899 Fipronil Substances 0.000 abstract description 2
- 229940013764 fipronil Drugs 0.000 abstract description 2
- 230000003405 preventing effect Effects 0.000 abstract description 2
- -1 butylene fipronil Chemical compound 0.000 abstract 1
- 230000001276 controlling effect Effects 0.000 abstract 1
- 230000003111 delayed effect Effects 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 24
- 230000000694 effects Effects 0.000 description 16
- 238000000034 method Methods 0.000 description 11
- 239000003814 drug Substances 0.000 description 10
- 231100000225 lethality Toxicity 0.000 description 9
- 230000032696 parturition Effects 0.000 description 7
- 230000002195 synergetic effect Effects 0.000 description 7
- 241000238631 Hexapoda Species 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 241000209094 Oryza Species 0.000 description 4
- 235000007164 Oryza sativa Nutrition 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 230000000857 drug effect Effects 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000002917 insecticide Substances 0.000 description 4
- 238000011835 investigation Methods 0.000 description 4
- 230000002045 lasting effect Effects 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- 235000009566 rice Nutrition 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 3
- 230000010534 mechanism of action Effects 0.000 description 3
- 230000002633 protecting effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241000426499 Chilo Species 0.000 description 2
- 241000254173 Coleoptera Species 0.000 description 2
- 241000255777 Lepidoptera Species 0.000 description 2
- 241000500437 Plutella xylostella Species 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 description 1
- OEDUIFSDODUDRK-UHFFFAOYSA-N 5-phenyl-1h-pyrazole Chemical compound N1N=CC=C1C1=CC=CC=C1 OEDUIFSDODUDRK-UHFFFAOYSA-N 0.000 description 1
- 241000590412 Agromyzidae Species 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 241000254127 Bemisia tabaci Species 0.000 description 1
- 241000665051 Chilo sacchariphagus indicus Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241001124134 Chrysomelidae Species 0.000 description 1
- 241001414720 Cicadellidae Species 0.000 description 1
- 241001498622 Cixius wagneri Species 0.000 description 1
- 241000008892 Cnaphalocrocis patnalis Species 0.000 description 1
- 241001237160 Kallima inachus Species 0.000 description 1
- 241000256259 Noctuidae Species 0.000 description 1
- 241000907661 Pieris rapae Species 0.000 description 1
- 241000255893 Pyralidae Species 0.000 description 1
- 241001161749 Stenchaetothrips biformis Species 0.000 description 1
- 229940124277 aminobutyric acid Drugs 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an insecticidal composition, which comprises two active ingredients consisting of butylene fipronil and chlorantraniliprole. According to the insecticidal composition provided by the invention, the insecticidal spectrum is enlarged; the efficacy duration is long; the preventing and controlling effect on rice Chilo suppressalis is good; the resistance to pesticide is delayed while reducing the use amount, the pollution on the environment is reduced, and the pesticide damage is difficult to generate.
Description
Technical field the invention belongs to pesticide field, relates in particular to the Pesticidal combination of butene-fipronil and Rynaxypyr.
Background technology butene-fipronil (fipronil) belongs to a kind of Phenylpyrazole insecticides; Insecticidal spectrum is wide; Is main to insect with stomach poison function; Have concurrently and tag and certain systemic function; Its mechanism of action is to hinder the chloride metabolism of insect γ～aminobutyric acid control; Therefore important pests such as aphid, leafhopper, plant hopper, lepidopterous larvae, fly class and coleoptera there is very high insecticidal activity, crop is not had poisoning.During foliage spray, water rice hopper, rice-stem borer, paddy rice paddy stem borer, rice leaf roller, diamond-back moth, imported cabbageworm, rice thrips etc. are all had high-level preventive effect, and the lasting period is long.
Rynaxypyr (Chlorantraniliprole); It is a kind of brand-new low toxicity efficient pesticides of du pont company exploitation; The Rynaxypyr high-efficiency broad spectrum; Lepidopterous Noctuidae, Pyralidae, moth fruit moth section, tortricid, miller section, diamond-back moth section, Gelechidae, Gracilariidae etc. all there is excellent control effect; Can also control the coleoptera Culculionidae; Chrysomelidae, diptera Agromyzidae, multiple non-lepidoptera pest such as Bemisia tabaci.According to preliminary on probation, very good really to lepidopterous insect effect, the control time is very long.
Because agricultural pests causes very big loss to crops production every year; Consider the agricultural chemicals of long-term use single variety; Impel insect to produce resistance easily, environment is caused bigger pollution, field trial shows; The existing medicament another kind of mixed pesticide different with mechanism of action; Can not only postpone resistance and produce, can also improve drug effect and residual period, reduce usage amount; Reduce cost, so we are with butene-fipronil and the composite expansion insecticidal spectrum of Rynaxypyr.Not only can effectively prevent and treat most of insect, reduce environmental pollution, also improve drug effect and lasting period.The synergistic complex of agricultural chemicals is the effective ways that enlarge the pesticide control spectrum and improve drug effect.
Summary of the invention the purpose of this invention is to provide that a kind of insecticidal activity is efficient, lasting effect is long, the Pesticidal combination of the high and low poison of quick-acting, environmental protection.Concrete relate to butene-fipronil and Rynaxypyr is the pesticidal preparations of basis.
Above-mentioned Pesticidal combination contains butene-fipronil 0.5%～30%, Rynaxypyr 1%～20%.
Utilize the described insecticides of the invention described above, be equipped with the known auxiliary agent of those skilled in that art, can process formulation of the present invention with those skilled in that art's known method.Its formulation that can process is suspending agent (SC), water dispersible granules (WDG).
Advantage that the present invention has and beneficial effect: 1. the desinsection scope is wide, to the Lepidoptera super-high-efficient; 2. the lasting period is long; 3. low toxicity,
Noresidue, nuisanceless, environmentally safe; 4. use compound formulation, two kinds of insecticides also have synergistic effect, and the consumption of two kinds of insecticides reduces during all than single use, thereby has improved insecticidal effect, has increased safety, has reduced environmental pollution.
Embodiment
Following instantiation is in order to further explain the present invention, but the present invention absolutely not only is limited to following these embodiment.Percentage all is weight percentage in the prescription, and employed former medicine and auxiliary agent are other producers and buy.
Formulation examples is following:
Prescription 1 (5% suspending agent)
Each component sum is 100%.
Instance 2 (9% suspending agent)
Each component sum is 100%.
Instance 3 (10% water dispersible granules)
Each component sum is 100%.
Instance 4 (15% suspending agent)
Each component sum is 100%.
Instance 5 (20% water dispersible granules)
Each component sum is 100%.
Rice-stem borer (Chilo suppressalis) popular name borer, borer, moth stalk worm etc. are the formidable opponents of paddy rice.Larva moth food stem stalk causes the withered heart, and striped rice borer has the strain of commentaries on classics harm habit, and a Chilo spp larvae can endanger many strains paddy rice, causes dead leaf sheath, the withered heart.If untimely control, the field a lot of withered heart seedlings occur through regular meeting, and part field piece is not is not prevented and treated striped rice borer because of nursery period, and field withered heart seedling ratio is up to 30% now, and part location, field withered heart seedling ratio surpasses 50%, causes very big loss.Butene-fipronil, Rynaxypyr are two kinds of compositions that insecticidal activity is very high, according to their the effect characteristics and mechanism of action, the object of indoor biometrics are decided to be rice-stem borer.
The method of indoor biometrics is: adopt capillary trace drop method, capillary trace dropper volume is 1.0 μ L.With micro-dropper soup is pursued a drop in the back side of striped rice borer 6 instar larvaes; Each concentration is handled about 30 larva; The culture dish that it is 9cm that per 5 larvas are put into a diameter, the built-in a small amount of feed of ware supplies to get food, in addition with 30 larvas of acetone drop as contrast.Larva after treatment still is placed in the receptacle, checks lethality behind the 48h.Data are handled with the SPSS software statistics.Obtain toxicity regression formula, the lethal concentration of 50, correlation coefficient etc., and obtain co-toxicity coefficient with the abundant method of Sun Yun.
The co-toxicity of mixture preparation adopts the abundant co-toxicity coefficient method representation of Sun Yun:
The theoretical toxicity index A=∑ of mixture preparation (toxicity index of certain medicine * percentage of this pharmaceutically active ingredient in mixture).
C was synergistic effect greater than 120 o'clock, less than 80 o'clock be antagonism, 80～120 o'clock is addition.
The different proportionings of table 1 are to the toxicity test result of striped rice borer
Table 2 butene-fipronil is tested the test of giving birth to of striped rice borer
| Dosage (mg/L) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 5 | 100 | 20 | 20.00 | 20.00 |
| 10 | 100 | 31 | 31.00 | 31.00 |
| 20 | 100 | 40 | 40.00 | 40.00 |
| 40 | 100 | 53 | 53.00 | 53.00 |
| 50 | 100 | 60 | 60.00 | 60.00 |
| CK | 100 | 0 |
Table 3 Rynaxypyr is tested the test of giving birth to of striped rice borer
| Dosage (mg/L) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 5 | 100 | 25 | 25.00 | 25.00 |
| 10 | 100 | 33 | 33.00 | 33.00 |
| 20 | 100 | 48 | 48.00 | 48.00 |
| 40 | 100 | 58 | 58.00 | 58.00 |
| 50 | 100 | 66 | 66.00 | 66.00 |
| CK | 100 | 0 |
The test of giving birth to of 1 pair of striped rice borer of table 4 prescription is tested
| Dosage (mg/L) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 5 | 100 | 22 | 22.00 | 20.00 |
| 10 | 100 | 42 | 42.00 | 36.00 |
| 20 | 100 | 50 | 50.00 | 60.00 |
| 40 | 100 | 58 | 58.00 | 78.00 |
| 50 | 100 | 71 | 71.00％ | 86.00 |
| CK | 100 | 0 |
The test of giving birth to of 2 pairs of striped rice borer of table 5 prescription is tested
| Dosage (mg/L) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 5 | 100 | 28 | 28.00 | 28.00 |
| 10 | 100 | 40 | 40.00 | 40.00 |
| 20 | 100 | 67 | 67.00 | 67.00 |
| 40 | 100 | 83 | 83.00 | 83.00 |
| 50 | 100 | 91 | 91.00 | 91.00 |
| CK | 100 | 0 |
The test of giving birth to of 3 pairs of striped rice borer of table 6 prescription is tested
| Dosage (mg/L) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 5 | 100 | 33 | 33.00 | 33.00 |
| 10 | 100 | 45 | 45.00 | 45.00 |
| 20 | 100 | 58 | 58.00 | 58.00 |
| 40 | 100 | 69 | 69.00 | 69.00 |
| 50 | 100 | 88 | 88.00 | 88.00 |
| CK | 100 | 0 |
The test of giving birth to of 4 pairs of striped rice borer of table 7 prescription is tested
| Dosage (mg/L) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 5 | 100 | 35 | 35.00 | 35.00 |
| 10 | 100 | 56 | 56.00 | 56.00 |
| 20 | 100 | 64 | 64.00 | 64.00 |
| 40 | 100 | 84 | 84.00 | 84.00 |
| 50 | 100 | 95 | 95.00 | 95.00 |
| CK | 100 | 0 |
The test of giving birth to of 5 pairs of striped rice borer of table 8 prescription is tested
| Dosage (mg/L) | The examination borer population | Death toll | Lethality (%) | Corrected mortality (%) |
| 5 | 100 | 41 | 41.00 | 41.00 |
| 10 | 100 | 52 | 52.00 | 52.00 |
| 20 | 100 | 60 | 60.00 | 60.00 |
| 40 | 100 | 87 | 87.00 | 87.00 |
| 50 | 100 | 97 | 97.00 | 97.00 |
| CK | 100 | 0 |
It is bright to analyze above-mentioned tables of data, and when butene-fipronil and Rynaxypyr different proportion were composite, the co-toxicity coefficient of prescription all had obvious synergistic effect all greater than 120.It is 4 maximum with prescription 5 co-toxicity coefficients wherein to fill a prescription, and is respectively 170.95 and 166.89.
Through the indoor biometrics test, select the field trial that the bigger prescription of CTC 4, prescription 5 and the less prescription 1 of CTC are prevented and treated rice-stem borer, confirm the effect of prescription control rice-stem borer; Simultaneously through with the effect comparison of butene-fipronil, the agent of Rynaxypyr list, verify the synergistic effect after composite.Concrete test method and data are following:
Test the field control effectiveness test that one: 15% butene-fipronil Rynaxypyr SC, 10% butene-fipronil SC, 5% Rynaxypyr SC do the control striped rice borer.The test place is that Hanchuan City Liu of Xiaogan Prefecture, Hubei Province is at a distance from the town; Time is on July 11st, 2010; Test totally four processing; Each handles three repetitions; The sub-district randomized arrangement, sub-district area 67m2, the planting habit of all sub-districts all planting habit with local is identical; Record dispenser same day and all synoptic data thereafter, specific as follows:
Table 9 duration of test meteorological data
The investigation standard is: 7d gets killed strain 100 strains at random behind the medicine in each sub-district, and the life or death number of Chilo spp larvae is looked in stripping, calculates lethality; 150 clumps of parallel sampling method samplings are adopted in 15d, the every sub-district of 25d behind the medicine, investigate withered calculation, calculate withered heart rate and seedling protecting effect at last.Specifically data (data are the mean value of three repetitions) are as follows:
The effect table of table 1015% butene-fipronil Rynaxypyr SC and other chemical control striped rice borer
Annotate: data are the mean value that repeats for 3 times in the table, and letter is all Duncan testing differentia remarkable time mutually: in July, 2010 place: the Hubei Xiaogan
Can find out from above data; Under the situation of identical using dosage; 15% butene-fipronil Rynaxypyr SC 25d control rate behind medicine can reach 90.8%, the effect when preventive effect is higher than 10% butene-fipronil SC and 5% Rynaxypyr SC list agent use far away, and difference is extremely remarkable.
Test two: test method, investigation method and meteorological data are the same, and concrete test data is following:
The effect table of table 1120% butene-fipronil Rynaxypyr and other chemical control striped rice borer
Annotate: data are the mean value that repeats for 3 times in the table, and letter is all Duncan testing differentia remarkable time mutually: in July, 2010 place: the Hubei Xiaogan
Can find out from above data; Under the situation of identical using dosage; 20% butene-fipronil Rynaxypyr SC 25d control rate behind medicine can reach 91.6%, the effect when preventive effect is higher than 15% butene-fipronil SC and 5% Rynaxypyr SC list agent use far away, and difference is extremely remarkable.
Test three: test method, investigation method and meteorological data are the same, and concrete test data is following:
The effect table of table 125% butene-fipronil Rynaxypyr and other chemical control striped rice borer
Annotate: data are the mean value that repeats for 3 times in the table, and letter is all Duncan testing differentia remarkable time mutually: in July, 2010 place: the Hubei Xiaogan
Can find out from above data; Under the situation of identical using dosage; 5% butene-fipronil butene-fipronil 25d control rate behind medicine can reach 80.1%, the effect when preventive effect is higher than 2% butene-fipronil SC and 5% Rynaxypyr SC list agent use far away, and difference is extremely remarkable.
Through above-mentioned three field control effectiveness tests; The effect that can find out prescription 4, prescription 5 control rice-stem borers is best; This also matches with the result of indoor biometrics, and (CTC is big more; Synergistic effect is big more); But the two difference is not remarkable; As considering the factor of pesticide cost again, prescription 4 is best, the most economical proportionings of effect; Also verified simultaneously butene-fipronil and Rynaxypyr by different proportion when composite, the control efficiency of rice-stem borer all has been better than the effect of butene-fipronil and Rynaxypyr list agent use, certain synergistic effect has been arranged.
Through above-mentioned three field control effectiveness tests, can confirm to fill a prescription 4 for preventing and treating the more suitable prescription of rice-stem borer, 15% butene-fipronil Rynaxypyr SC (prescription 4) has been carried out further test, filter out the optium concentration of control striped rice borer.Experimental scheme 6g/ mu, 7g/ mu, 8g/ mu and 4 concentration tonsures of 9g/ mu are also done contrast with the effect of 10% butene-fipronil SC (8g/ mu), 5% Rynaxypyr SC (8g/ mu); Test method and investigation method are the same, and specifically data (mean values of three repetitions) are as follows:
Table 13 prescription 4 different amounts control striped rice borer effect table
Annotate: data are the mean value that repeats for 3 times in the table, and letter is all Duncan testing differentia remarkable time mutually: in July, 2010 place: the Hubei Xiaogan
Can find out that from above-mentioned data along with the increase of prescription dosage, drug effect also increases to some extent; 15% butene-fipronil Rynaxypyr SC consumption is a 8g/ mu; The seedling protecting effect of 25d is 91.6% behind the medicine, and apparently higher than 10% butene-fipronil SC and 5% Rynaxypyr SC, difference is extremely remarkable; When consumption was 9g/ mu, 25 days seedling protecting effect and 8g/ mu was roughly the same after medication, and difference is not remarkable.Therefore, under the prerequisite of considering the mu cost, should advocate mu usage amount is 9g/ mu.
Claims (3)
1. Pesticidal combination is characterized in that, active ingredient is made up of butene-fipronil and Rynaxypyr.
2. Pesticidal combination according to claim 1 is characterized in that, it by 0.5%～30% butene-fipronil and 1%～20% Rynaxypyr, adds an amount of auxiliary agent and carrier by weight percentage, is mixed into suspending agent, water dispersible granules.
3. Pesticidal combination according to claim 1 is characterized in that, the mass percentage content of active ingredient in preparation is between 1.5%-50%.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103109823A (en) * | 2013-01-17 | 2013-05-22 | 湖南农大海特农化有限公司 | Butene-fipronil and chlorantraniliprole pesticide composition |
| CN103651439A (en) * | 2013-12-19 | 2014-03-26 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition |
| CN103960262A (en) * | 2014-05-22 | 2014-08-06 | 北京燕化永乐生物科技股份有限公司 | Pesticide composition |
| CN104855399A (en) * | 2015-05-02 | 2015-08-26 | 广东中迅农科股份有限公司 | Insecticidal combination containing butene-fipronil and fluorine benzene worm amide |
| WO2016115476A1 (en) * | 2015-01-16 | 2016-07-21 | Valent Biosciences Corporation | Bacillus thuringiensis subsp.kurstaki and bacillus thuringiensis subsp. aizawai combination formulations |
| CN106857642A (en) * | 2016-12-31 | 2017-06-20 | 新昌县云河虫害防治技术开发有限公司 | Prevent and treat insecticides of bamboo shoots insect and application thereof |
| CN109757495A (en) * | 2019-03-07 | 2019-05-17 | 湖南速博生物技术有限公司 | Composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide |
| WO2024157264A1 (en) * | 2023-01-27 | 2024-08-02 | Adama Makhteshim Ltd. | Plant health / plant vigor improving mixture of insecticides |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103109823A (en) * | 2013-01-17 | 2013-05-22 | 湖南农大海特农化有限公司 | Butene-fipronil and chlorantraniliprole pesticide composition |
| CN103651439A (en) * | 2013-12-19 | 2014-03-26 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition |
| CN103960262A (en) * | 2014-05-22 | 2014-08-06 | 北京燕化永乐生物科技股份有限公司 | Pesticide composition |
| WO2016115476A1 (en) * | 2015-01-16 | 2016-07-21 | Valent Biosciences Corporation | Bacillus thuringiensis subsp.kurstaki and bacillus thuringiensis subsp. aizawai combination formulations |
| CN104855399A (en) * | 2015-05-02 | 2015-08-26 | 广东中迅农科股份有限公司 | Insecticidal combination containing butene-fipronil and fluorine benzene worm amide |
| CN104855399B (en) * | 2015-05-02 | 2018-06-19 | 广东中迅农科股份有限公司 | A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide |
| CN106857642A (en) * | 2016-12-31 | 2017-06-20 | 新昌县云河虫害防治技术开发有限公司 | Prevent and treat insecticides of bamboo shoots insect and application thereof |
| CN109757495A (en) * | 2019-03-07 | 2019-05-17 | 湖南速博生物技术有限公司 | Composition pesticide containing butene-fipronil and bromine worm fluorobenzene bisamide |
| WO2024157264A1 (en) * | 2023-01-27 | 2024-08-02 | Adama Makhteshim Ltd. | Plant health / plant vigor improving mixture of insecticides |
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