CN101798246B - Water-soluble fertilizer by complexing humic acid with plurality of nutrient elements and preparation method thereof - Google Patents
Water-soluble fertilizer by complexing humic acid with plurality of nutrient elements and preparation method thereof Download PDFInfo
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 50
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 239000004021 humic acid Substances 0.000 title claims abstract description 38
- 235000015097 nutrients Nutrition 0.000 title claims abstract description 18
- 230000000536 complexating effect Effects 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims abstract description 44
- 229910001950 potassium oxide Inorganic materials 0.000 claims abstract description 43
- 150000001875 compounds Chemical class 0.000 claims abstract description 36
- 239000011573 trace mineral Substances 0.000 claims abstract description 36
- 235000013619 trace mineral Nutrition 0.000 claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000843 powder Substances 0.000 claims abstract description 27
- 239000002994 raw material Substances 0.000 claims abstract description 23
- 239000011591 potassium Substances 0.000 claims abstract description 21
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 21
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000654 additive Substances 0.000 claims abstract description 19
- 239000005648 plant growth regulator Substances 0.000 claims abstract description 19
- 235000016709 nutrition Nutrition 0.000 claims abstract description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 68
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 40
- REZQBEBOWJAQKS-UHFFFAOYSA-N triacontan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO REZQBEBOWJAQKS-UHFFFAOYSA-N 0.000 claims description 36
- 229910052742 iron Inorganic materials 0.000 claims description 34
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 32
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 32
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 32
- 229910052802 copper Inorganic materials 0.000 claims description 32
- 239000010949 copper Substances 0.000 claims description 32
- 229910052748 manganese Inorganic materials 0.000 claims description 32
- 239000011572 manganese Substances 0.000 claims description 32
- 239000011701 zinc Substances 0.000 claims description 32
- 229910052725 zinc Inorganic materials 0.000 claims description 32
- 239000011734 sodium Substances 0.000 claims description 30
- 238000010668 complexation reaction Methods 0.000 claims description 26
- 239000007787 solid Substances 0.000 claims description 25
- 229920001296 polysiloxane Polymers 0.000 claims description 22
- 229910052757 nitrogen Inorganic materials 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 20
- CJUUXVFWKYRHAR-UHFFFAOYSA-M 1-Naphthaleneacetic acid sodium salt Chemical compound [Na+].C1=CC=C2C(CC(=O)[O-])=CC=CC2=C1 CJUUXVFWKYRHAR-UHFFFAOYSA-M 0.000 claims description 18
- 229930191978 Gibberellin Natural products 0.000 claims description 18
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 claims description 18
- 239000003448 gibberellin Substances 0.000 claims description 18
- 238000007689 inspection Methods 0.000 claims description 18
- VMZBTPALYWVSGZ-UHFFFAOYSA-M potassium;2-nitrophenolate Chemical compound [K+].[O-]C1=CC=CC=C1[N+]([O-])=O VMZBTPALYWVSGZ-UHFFFAOYSA-M 0.000 claims description 18
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 17
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 17
- 239000004094 surface-active agent Substances 0.000 claims description 17
- LMSDCGXQALIMLM-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;iron Chemical compound [Fe].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O LMSDCGXQALIMLM-UHFFFAOYSA-N 0.000 claims description 16
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 16
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 16
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 16
- 239000012378 ammonium molybdate tetrahydrate Substances 0.000 claims description 16
- FIXLYHHVMHXSCP-UHFFFAOYSA-H azane;dihydroxy(dioxo)molybdenum;trioxomolybdenum;tetrahydrate Chemical compound N.N.N.N.N.N.O.O.O.O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O.O[Mo](O)(=O)=O FIXLYHHVMHXSCP-UHFFFAOYSA-H 0.000 claims description 16
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 16
- 239000004327 boric acid Substances 0.000 claims description 16
- 229910052796 boron Inorganic materials 0.000 claims description 16
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 claims description 16
- 239000004202 carbamide Substances 0.000 claims description 16
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 claims description 16
- 229910052750 molybdenum Inorganic materials 0.000 claims description 16
- 239000011733 molybdenum Substances 0.000 claims description 16
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 16
- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 16
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims description 16
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims description 16
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 16
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 16
- 235000011151 potassium sulphates Nutrition 0.000 claims description 16
- 239000012535 impurity Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 10
- 239000004255 Butylated hydroxyanisole Substances 0.000 claims description 9
- 229940043253 butylated hydroxyanisole Drugs 0.000 claims description 9
- 235000019282 butylated hydroxyanisole Nutrition 0.000 claims description 9
- 238000001914 filtration Methods 0.000 claims description 8
- 238000001694 spray drying Methods 0.000 claims description 8
- -1 that is Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical group C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims 1
- 229940043264 dodecyl sulfate Drugs 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 abstract description 9
- 238000005516 engineering process Methods 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 30
- 230000004720 fertilization Effects 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 8
- 229920013822 aminosilicone Polymers 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 235000013399 edible fruits Nutrition 0.000 description 4
- 238000003973 irrigation Methods 0.000 description 4
- 230000002262 irrigation Effects 0.000 description 4
- 239000012265 solid product Substances 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 235000012041 food component Nutrition 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 235000021073 macronutrients Nutrition 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000013589 supplement Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000003042 antagnostic effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000003630 growth substance Substances 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000013543 active substance Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 235000015872 dietary supplement Nutrition 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- 230000005089 fruit drop Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000015816 nutrient absorption Nutrition 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
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- Fertilizers (AREA)
Abstract
本发明属于农业技术领域，具体涉及腐植酸络合多种营养元素水溶肥料及其制备方法，它按原料重量份数络合后构成水溶肥料，其原料组份是：含腐植酸量≥50%和含氧化钾量≥10%、水不溶物≤2%的腐植酸钾粉8份，水42-46份，大量元素化合物33-38份，微量元素化合物10份，助剂1.3-1.5份，植物生长调节剂1.8-2.5份。它的制备方法分六个步骤完成，该水溶肥料具有营养成分较全、作物吸收利用率较高及针对性较强的特点。The invention belongs to the field of agricultural technology, and specifically relates to a water-soluble fertilizer complexed with various nutritional elements by humic acid and a preparation method thereof. The water-soluble fertilizer is formed after complexing according to the weight of raw materials, and the raw material components are: humic acid content ≥ 50% And 8 parts of potassium humate powder containing potassium oxide ≥ 10%, water insoluble matter ≤ 2%, 42-46 parts of water, 33-38 parts of macroelement compounds, 10 parts of trace element compounds, 1.3-1.5 parts of additives, Plant growth regulator 1.8-2.5 parts. Its preparation method is completed in six steps, and the water-soluble fertilizer has the characteristics of complete nutrient components, high absorption and utilization rate of crops and strong pertinence.
Description
技术领域 technical field
本发明属于农业技术领域，具体涉及的是腐植酸络合多种营养元素水溶肥料及其制备方法。 The invention belongs to the technical field of agriculture, and in particular relates to a water-soluble fertilizer complexed with multiple nutritional elements by humic acid and a preparation method thereof.
背景技术 Background technique
结合灌溉供给植物所需的营养物质，称为灌溉施肥。使用喷施的方式通过叶片、茎干、果实供给植物所需的营养物质，称为叶面施肥。水溶肥料：经水溶解或稀释，用于灌溉施肥、叶面施肥、无土栽培、浸种蘸根等用途的液体或固体肥料称为水溶肥料（水溶肥料定义为农业部NY1106-2006标准，即《含腐植酸水溶肥料》标准3.1水溶肥料定义）。 Combining irrigation to supply the nutrients needed by plants is called fertigation. The way of spraying is used to supply the nutrients needed by plants through leaves, stems and fruits, which is called foliar fertilization. Water-soluble fertilizers: liquid or solid fertilizers that are dissolved or diluted in water and used for irrigation and fertilization, foliar fertilization, soilless cultivation, soaking seeds and roots, etc. are called water-soluble fertilizers (water-soluble fertilizers are defined as the Ministry of Agriculture NY1106-2006 standard, namely " Humic acid-containing water-soluble fertilizer "standard 3.1 definition of water-soluble fertilizer).
随着科技发展，高产、优质、低成本是现代农业的主要目标，要求一切农业技术措施（包括施肥）经济易行。实践证明，以叶面施肥为主要途径的水溶肥料，具有肥效迅速、肥料利用率高、用肥量少、针对性强等特点。以腐植酸等有机质为载体，添加多种助剂，添加多种营养元素的新型有机水溶肥料，具有养分吸收快、肥料利用率高、操作方便、避免某些元素被土壤固定等特点，在农业生产实践上得到迅速推广和应用，成为农业生产中提高产量和品质的一项重要技术措施。 With the development of science and technology, high yield, high quality and low cost are the main goals of modern agriculture, requiring all agricultural technical measures (including fertilization) to be economically feasible. Practice has proved that water-soluble fertilizers with foliar fertilization as the main method have the characteristics of rapid fertilizer efficiency, high fertilizer utilization rate, less fertilizer use, and strong pertinence. A new type of organic water-soluble fertilizer that uses organic matter such as humic acid as a carrier, adds various additives, and adds various nutrients. It has the characteristics of fast nutrient absorption, high fertilizer utilization rate, convenient operation, and avoids certain elements from being fixed by the soil. It is widely used in agriculture. It has been rapidly popularized and applied in production practice, and has become an important technical measure to improve yield and quality in agricultural production.
目前，市场提供的含腐植酸水溶肥料，主要是依据农业部NY1106-2006标准（即《含腐植酸水溶肥料》标准）生产的，使用时虽然也能起到一定效果，但存在营养成分不全及作物吸收利用率低的缺点，所以研究开发具有活性的高效、经济、环保、多元素、多功能的水溶肥料，是其发展方向。 At present, the humic acid-containing water-soluble fertilizers provided by the market are mainly produced according to the NY1106-2006 standard of the Ministry of Agriculture (that is, the "humic acid-containing water-soluble fertilizer" standard). The disadvantage of low crop absorption and utilization rate, so research and development of active, efficient, economical, environmentally friendly, multi-element, multi-functional water-soluble fertilizers is the development direction.
发明内容 Contents of the invention
本发明的目的是提供腐植酸络合多种营养元素水溶肥料及其制备方法，该水溶肥料具有营养成分较全、作物吸收利用率较高及针对性较强的特点。 The object of the present invention is to provide humic acid complexed multi-nutrient water-soluble fertilizer and its preparation method. The water-soluble fertilizer has the characteristics of relatively complete nutritional components, high crop absorption and utilization rate and strong pertinence.
本发明的技术方案是提供一种腐植酸络合多种营养元素水溶肥料，它按原料重量份数络合后构成水溶肥料，其原料组份是：含腐植酸量≥50%和含氧化钾量≥10%、水不溶物≤2%的腐植酸钾粉8份，水42-46份，大量元素化合物33-38份，微量元素化合物10份，助剂1.3-1.5份，植物生长调节剂1.8-2.5份。 The technical solution of the present invention is to provide a kind of humic acid complexed multi-nutrient water-soluble fertilizer, which forms water-soluble fertilizer after complexing according to the weight of raw materials, and its raw material components are: humic acid content ≥ 50% and potassium oxide Potassium humate powder with content ≥10% and water-insoluble matter ≤2% 8 parts, water 42-46 parts, macroelement compound 33-38 parts, trace element compound 10 parts, additive 1.3-1.5 parts, plant growth regulator 1.8-2.5 servings.
所述的大量元素化合物33-38份：含氮量≥46%的尿素 7-29份，含氧化钾量≥51%的硫酸钾 1-22份，含五氧化二磷量≥51%和含氧化钾量≥34%的磷酸二氢钾6-25份。 33-38 parts of the macroelement compound: 7-29 parts of urea with a nitrogen content ≥ 46%, 1-22 parts of potassium sulfate with a potassium oxide content ≥ 51%, phosphorus pentoxide content ≥ 51% and 6-25 parts of potassium dihydrogen phosphate with potassium oxide content ≥ 34%.
所述的微量元素化合物10份是含铁量≥12%的络合铁Fe-EDTA为3份，含锌量≥14%的络合锌Na2ZnEDTA为2.5份，含锰量≥12%的络合锰MnEDTA为2份，含铜量≥13%的络合铜Na2CuEDTA为1份，含硼量≥17%的硼酸1份，含钼量≥52%的四水钼酸铵0.5份。 The 10 parts of the trace element compound are 3 parts of complex iron Fe-EDTA with iron content ≥ 12%, 2.5 parts of complex zinc Na 2 ZnEDTA with zinc content ≥ 14%, and 2.5 parts with manganese content ≥ 12%. 2 parts of complex manganese MnEDTA, 1 part of complex copper Na2CuEDTA with copper content ≥ 13%, 1 part of boric acid with boron content ≥ 17%, 0.5 part of ammonium molybdate tetrahydrate with molybdenum content ≥ 52% .
所述的助剂1.3-1.5份是丁基羟基茴香醚0.3-0.5份，有机硅表面活性剂0.4-0.6份，十二烷基硫酸钠0.4-0.6份。 The 1.3-1.5 parts of the auxiliary agents are 0.3-0.5 parts of butyl hydroxyanisole, 0.4-0.6 parts of organic silicon surfactant, and 0.4-0.6 parts of sodium lauryl sulfate.
所述的植物生长调节剂1.8-2.5份是三十烷醇0.4-0.6份，复硝酚钾0.4-0.6份，赤霉素0.4-0.6份，萘乙酸钠0.5-0.7份。 The 1.8-2.5 part of the plant growth regulator is 0.4-0.6 part of triacontanol, 0.4-0.6 part of potassium nitrophenolate, 0.4-0.6 part of gibberellin and 0.5-0.7 part of sodium naphthalene acetate.
腐植酸络合多种营养元素水溶肥料，它按原料重量份数络合后构成水溶肥料，其原料组份是： Humic acid complexes a variety of nutrient elements water-soluble fertilizer, which forms a water-soluble fertilizer after complexing according to the weight of raw materials, and its raw material components are:
1）含腐植酸量≥50%和含氧化钾量≥10%、水不溶物≤2%的腐植酸钾粉8份； 1) 8 parts of potassium humate powder containing humic acid ≥ 50%, potassium oxide ≥ 10%, water insoluble ≤ 2%;
2）大量元素化合物，合计38份：含氮量≥46%的尿素 8份，含氧化钾量≥51%的硫酸钾 22份，含五氧化二磷量≥51%和含氧化钾量≥34%的磷酸二氢钾 8份； 2) A large number of elemental compounds, a total of 38 parts: 8 parts of urea with nitrogen content ≥ 46%, 22 parts of potassium sulfate with potassium oxide content ≥ 51%, phosphorus pentoxide content ≥ 51% and potassium oxide content ≥ 34 % potassium dihydrogen phosphate 8 parts;
3）微量元素化合物，合计10份：含铁量≥12%的络合铁Fe-EDTA为3份，含锌量≥14%的络合锌Na2ZnEDTA为2.5份，含锰量≥12%的络合锰MnEDTA为2份，含铜量≥13%的络合铜Na2CuEDTA为1份，含硼量≥17%的硼酸1份，含钼量≥52%的四水钼酸铵0.5份； 3) Trace element compounds, 10 parts in total: 3 parts of complex iron Fe-EDTA with iron content ≥ 12%, 2.5 parts of complex zinc Na 2 ZnEDTA with zinc content ≥ 14%, manganese content ≥ 12% 2 parts of complexed manganese MnEDTA, 1 part of complexed copper Na 2 CuEDTA with copper content ≥ 13%, 1 part of boric acid with boron content ≥ 17%, 0.5 parts of ammonium molybdate tetrahydrate with molybdenum content ≥ 52% share;
4）助剂，合计1.3份：丁基羟基茴香醚0.3份，有机硅表面活性剂0.5份，十二烷基硫酸钠0.5份； 4) Additives, 1.3 parts in total: 0.3 parts of butylated hydroxyanisole, 0.5 parts of silicone surfactant, 0.5 parts of sodium lauryl sulfate;
5）植物生长调节剂，合计1.8份：三十烷醇0.5份，复硝酚钾0.4份，赤霉素0.4份，萘乙酸钠0.5份； 5) Plant growth regulator, 1.8 parts in total: 0.5 part of triacontanol, 0.4 part of potassium nitrophenolate, 0.4 part of gibberellin, and 0.5 part of sodium naphthalene acetate;
6）水42份。 6) 42 parts of water.
腐植酸络合多种营养元素水溶肥料，它按原料重量份数络合后构成水溶肥料，其原料组份是： Humic acid complexes a variety of nutrient elements water-soluble fertilizer, which forms a water-soluble fertilizer after complexing according to the weight of raw materials, and its raw material components are:
1）含腐植酸量≥50%和含氧化钾量≥10%、水不溶物≤2%的腐植酸钾粉8份； 1) 8 parts of potassium humate powder containing humic acid ≥ 50%, potassium oxide ≥ 10%, water insoluble ≤ 2%;
2）大量元素化合物，合计36份：含氮量≥46%的尿素 29份，含氧化钾量≥51%的硫酸钾 1份，含五氧化二磷量≥51%和含氧化钾量≥34%的磷酸二氢钾6份； 2) A large number of elemental compounds, 36 parts in total: 29 parts of urea with nitrogen content ≥ 46%, 1 part of potassium sulfate with potassium oxide content ≥ 51%, phosphorus pentoxide content ≥ 51% and potassium oxide content ≥ 34 6 parts of potassium dihydrogen phosphate;
3）微量元素化合物，合计10份：含铁量≥12%的络合铁Fe-EDTA为3份，含锌量≥14%的络合锌Na2ZnEDTA为2.5份，含锰量≥12%的络合锰MnEDTA为2份，含铜量≥13%的络合铜Na2CuEDTA为1份，含硼量≥17%的硼酸1份，含钼量≥52%的四水钼酸铵0.5份； 3) Trace element compounds, 10 parts in total: 3 parts of complex iron Fe-EDTA with iron content ≥ 12%, 2.5 parts of complex zinc Na 2 ZnEDTA with zinc content ≥ 14%, manganese content ≥ 12% 2 parts of complexed manganese MnEDTA, 1 part of complexed copper Na 2 CuEDTA with copper content ≥ 13%, 1 part of boric acid with boron content ≥ 17%, 0.5 parts of ammonium molybdate tetrahydrate with molybdenum content ≥ 52% share;
4）助剂，合计1.4份：丁基羟基茴香醚0.4份，有机硅表面活性剂0.4份，十二烷基硫酸钠0.6份； 4) Additives, 1.4 parts in total: 0.4 parts of butylated hydroxyanisole, 0.4 parts of silicone surfactant, 0.6 parts of sodium lauryl sulfate;
5）植物生长调节剂，合计2份：三十烷醇0.4份，复硝酚钾0.5份，赤霉素0.5份，萘乙酸钠0.6份。 5) Plant growth regulator, 2 parts in total: 0.4 part of triacontanol, 0.5 part of potassium nitrophenolate, 0.5 part of gibberellin, and 0.6 part of sodium naphthalene acetate.
6）水44份。 6) 44 parts of water.
腐植酸络合多种营养元素水溶肥料，它按原料重量份数络合后构成水溶肥料，其原料组份是： Humic acid complexes a variety of nutrient elements water-soluble fertilizer, which forms a water-soluble fertilizer after complexing according to the weight of raw materials, and its raw material components are:
1）含腐植酸量≥50%和含氧化钾量≥10%、水不溶物≤2%的腐植酸钾粉8份； 1) 8 parts of potassium humate powder containing humic acid ≥ 50%, potassium oxide ≥ 10%, water insoluble ≤ 2%;
2）大量元素化合物，合计33份：含氮量≥46%的尿素 7份，含氧化钾量≥51%的硫酸钾 1份，含五氧化二磷量≥51%和含氧化钾量≥34%的磷酸二氢钾25份； 2) A large number of elemental compounds, a total of 33 parts: 7 parts of urea with nitrogen content ≥ 46%, 1 part of potassium sulfate with potassium oxide content ≥ 51%, phosphorus pentoxide content ≥ 51% and potassium oxide content ≥ 34 % potassium dihydrogen phosphate 25 parts;
3）微量元素化合物，合计10份：含铁量≥12%的络合铁Fe-EDTA为3份，含锌量≥14%的络合锌Na2ZnEDTA为2.5份，含锰量≥12%的络合锰MnEDTA为2份，含铜量≥13%的络合铜Na2CuEDTA为1份，含硼量≥17%的硼酸1份，含钼量≥52%的四水钼酸铵0.5份； 3) Trace element compounds, 10 parts in total: 3 parts of complex iron Fe-EDTA with iron content ≥ 12%, 2.5 parts of complex zinc Na 2 ZnEDTA with zinc content ≥ 14%, manganese content ≥ 12% 2 parts of complexed manganese MnEDTA, 1 part of complexed copper Na 2 CuEDTA with copper content ≥ 13%, 1 part of boric acid with boron content ≥ 17%, 0.5 parts of ammonium molybdate tetrahydrate with molybdenum content ≥ 52% share;
4）助剂，合计1.5份：丁基羟基茴香醚0.5份，有机硅表面活性剂 0.6份，十二烷基硫酸钠0.4份； 4) Additives, 1.5 parts in total: 0.5 parts of butylated hydroxyanisole, 0.6 parts of silicone surfactant, 0.4 parts of sodium lauryl sulfate;
5）植物生长调节剂，合计2.5份：三十烷醇0.6份，复硝酚钾0.6份，赤霉素0.6份，萘乙酸钠0.7份； 5) Plant growth regulator, 2.5 parts in total: 0.6 part of triacontanol, 0.6 part of potassium nitrophenolate, 0.6 part of gibberellin, 0.7 part of sodium naphthalene acetate;
6）水46份。 6) 46 parts of water.
腐植酸络合多种营养元素水溶肥料的制备方法，按原料重量份数螯合后构成水溶肥料，其制备步骤如下： A method for preparing a water-soluble fertilizer complexed with humic acid and various nutritional elements. The water-soluble fertilizer is formed after chelating according to the weight of raw materials. The preparation steps are as follows:
1）络合反应一：在加温反应釜中，将42-46份的水和8份的腐植酸钾粉混合,加温到50℃～60℃之间并不断搅拌,将固体溶解；再加入微量元素化合物共10份，即含铁量≥12%的络合铁Fe-EDTA为3份，含锌量≥14%的络合锌Na2ZnEDTA为2.5份，含锰量≥12%的络合锰MnEDTA为2份，含铜量≥13%的络合铜Na2CuEDTA为1份，含硼量≥17%的硼酸1份，含钼量≥52%的四水钼酸铵0.5份；保持温度50℃～60℃之间并不断搅拌，反应0.5小时； 1) Complexation reaction 1: In a heating reactor, mix 42-46 parts of water and 8 parts of potassium humate powder, heat to 50℃～60℃ and keep stirring to dissolve the solid; Add a total of 10 parts of trace element compounds, that is, 3 parts of complex iron Fe-EDTA with iron content ≥ 12%, 2.5 parts of complex zinc Na 2 ZnEDTA with zinc content ≥ 14%, and 2.5 parts of 2 parts of complexed manganese MnEDTA, 1 part of complexed copper Na2CuEDTA with copper content ≥ 13%, 1 part of boric acid with boron content ≥ 17%, 0.5 part of ammonium molybdate tetrahydrate with molybdenum content ≥ 52% ; Keep the temperature between 50°C and 60°C and keep stirring, and react for 0.5 hours;
2）络合反应二：将上步所得溶液，依次分别加入大量元素化合物共33-38份，即含氮量≥46%的尿素 7-29份，含氧化钾量≥51%的硫酸钾1-22份，含五氧化二磷量≥51%和含氧化钾量≥34%的磷酸二氢钾6-25份；再加入助剂共1.3-1.5份，即丁基羟基茴香醚0.3-0.5份，有机硅表面活性剂0.4-0.6份，十二烷基硫酸钠0.4-0.6份；保持温度50℃～60℃之间，不断搅拌，反应2小时； 2) Complexation reaction 2: Add 33-38 parts of a large number of elemental compounds to the solution obtained in the previous step, that is, 7-29 parts of urea with a nitrogen content ≥ 46%, and potassium sulfate 1 with a potassium oxide content ≥ 51%. -22 parts, 6-25 parts of potassium dihydrogen phosphate containing phosphorus pentoxide ≥ 51% and potassium oxide ≥ 34%; add a total of 1.3-1.5 parts of additives, that is, butylated hydroxyanisole 0.3-0.5 Parts, 0.4-0.6 parts of silicone surfactant, 0.4-0.6 parts of sodium lauryl sulfate; keep the temperature between 50°C and 60°C, keep stirring, and react for 2 hours;
3）络合反应三：将上步所得溶液，依次加入植物生长调节剂共1.8-2.5份，即三十烷醇0.4-0.6份，复硝酚钾0.4-0.6份，赤霉素0.4-0.6份，萘乙酸钠0.5-0.7份；保持温度40℃～50℃之间，不断搅拌，反应1小时； 3) Complexation reaction 3: Add 1.8-2.5 parts of the plant growth regulator to the solution obtained in the previous step, namely, 0.4-0.6 parts of triacontanol, 0.4-0.6 parts of potassium nitrophenolate, and 0.4-0.6 parts of gibberellin Parts, 0.5-0.7 parts of sodium naphthalene acetate; keep the temperature between 40°C and 50°C, keep stirring, and react for 1 hour;
4）过滤除杂：将上步所得溶液通过过滤器过滤，去除杂质； 4) Filtration to remove impurities: filter the solution obtained in the previous step through a filter to remove impurities;
5）喷雾干燥成固体：将上步所得溶液经过干燥塔喷雾干燥成固体粉末或小颗粒； 5) Spray drying into solid: the solution obtained in the previous step is spray-dried into solid powder or small particles through a drying tower;
6）质检：将上步所得固体粉末或小颗粒进行质检，质检合格，即为产品。 6) Quality inspection: The solid powder or small particles obtained in the previous step are subjected to quality inspection, and if the quality inspection is passed, it is the product.
本发明的有益效果： Beneficial effects of the present invention:
（1）本发明产品是以腐植酸为载体，添加多种助剂，添加大量元素及微量元素的新型有机水溶肥料，具有养分吸收快、肥料利用率高、操作方便、避免某些元素被土壤固定等特点，对环境安全友好。生长调节剂三十烷醇对作物有增加产量和改善品质等作用，复硝酚钾促进元素的运转传送，赤霉素促进植物再生组织对元素的吸收比率，萘乙酸钠促进植物生长旺盛；有机硅表面活性剂大大降低了喷雾时溶液的表面张力，十二烷基硫酸钠使叶片润湿作用增强。这些都使营养元素更易植物吸收利用。 (1) The product of the present invention is a new type of organic water-soluble fertilizer that uses humic acid as a carrier, adds a variety of additives, and adds a large number of elements and trace elements. Fixed and other features, safe and friendly to the environment. The growth regulator triacontanol can increase the yield and improve the quality of crops. Potassium nitrophenolate promotes the operation and transmission of elements, gibberellin promotes the absorption rate of elements by plant regeneration tissues, and sodium naphthalene acetate promotes vigorous plant growth; organic The silicon surfactant greatly reduces the surface tension of the solution during spraying, and the sodium lauryl sulfate enhances leaf wetting. These make the nutrients easier for plants to absorb and utilize.
（2）本发明产品通过腐植酸的络合，使元素之间没有拮抗作用，也解决了铁、锰易氧化，植物不易吸收的问题，使各元素相互促进吸收，协同增效。本发明产品用于叶面施肥和灌溉施肥，比传统土壤施肥吸收利用率大幅度提高。 (2) The complexation of humic acid in the product of the present invention makes there be no antagonistic effect between elements, and also solves the problems that iron and manganese are easy to oxidize and plants are not easy to absorb, so that each element can promote mutual absorption and synergistic effect. The product of the invention is used for foliage fertilization and irrigation fertilization, and the absorption and utilization rate of the traditional soil fertilization is greatly improved.
本发明产品和农业部NY1106-2006标准（即《含腐植酸水溶肥料》标准）——大量元素Ⅱ型相比较，在其它技术指标都符合该标准前提下，大量元素含量大幅度提高；另外本发明产品比标准指标另外多包含了微量元素2.0%，可以同时补充大量元素和微量元素，节省人工，综合使用成本降低。 Compared with the NY1106-2006 standard of the Ministry of Agriculture (that is, the standard of "water-soluble fertilizer containing humic acid") - macroelement type II, the product of the present invention has greatly increased the content of macroelements on the premise that other technical indicators meet this standard; The invented product contains 2.0% more trace elements than the standard index, which can supplement both macronutrients and trace elements at the same time, saving labor and reducing the comprehensive use cost.
（3）本发明产品营养成分较全，大量元素和微量元素同补；尤其分别强化补充氮、磷、钾，针对性强，可满足植物不同生长时期对不同营养元素的需求，所以综合使用成本较低。 (3) The nutritional components of the product of the present invention are relatively complete, and macroelements and trace elements are supplemented at the same time; especially nitrogen, phosphorus, and potassium are supplemented separately, which is highly targeted and can meet the needs of different nutrient elements in different growth periods of plants, so the comprehensive use cost lower.
具体实施方式 Detailed ways
本发明的腐植酸络合多种营养元素水溶肥料，按腐殖酸添加营养元素类型，将产品分为：高钾微量元素型、高氮微量元素型、高磷微量元素型，每种产品都为固体产品。 The humic acid complexed multi-nutrient water-soluble fertilizer of the present invention can be divided into high-potassium trace element type, high-nitrogen trace element type, and high-phosphorus trace element type according to the type of nutrient element added by humic acid. for solid products.
实施例1：腐植酸络合多种营养元素水溶肥料（高钾微量元素型） Example 1: Humic acid complexed with multiple nutrients water-soluble fertilizer (high potassium trace element type)
1、产品技术指标（固体产品） 1. Product technical index (solid product)
2、产品组成成分(下列组分均为产品重量份数，每份单位为千克) 2. Composition of the product (the following components are parts by weight of the product, and the unit of each part is kilogram)
（1）腐植酸钾粉（含腐植酸量≥50%，含氧化钾量≥10%，水不溶物≤2%）8份。 (1) Potassium humate powder (containing humic acid ≥ 50%, potassium oxide ≥ 10%, water insoluble ≤ 2%) 8 parts.
（2）大量元素化合物（合计38份）：尿素（含氮量≥46%）8份，硫酸钾（含氧化钾量≥51%）22份，磷酸二氢钾（含五氧化二磷量≥51%、含氧化钾量≥34%）8份。 (2) Macroelement compounds (38 parts in total): 8 parts of urea (nitrogen content ≥ 46%), potassium sulfate (potassium oxide content ≥ 51%) 22 parts, potassium dihydrogen phosphate (phosphorus pentoxide content ≥ 51%, potassium oxide content ≥ 34%) 8 parts.
（3）微量元素化合物（共10份）：络合铁Fe-EDTA（含铁量≥12%）3份，络合锌Na2ZnEDTA（含锌量≥14%）2.5份，络合锰MnEDTA（含锰量≥12%）2份，络合铜Na2CuEDTA（含铜量≥13%）1份，硼酸(含硼量≥17%)1份，四水钼酸铵(含钼量≥52%)0.5份。 (3) Trace element compounds (10 parts in total): 3 parts of complexed iron Fe-EDTA (iron content ≥ 12%), 2.5 parts of complexed zinc Na 2 ZnEDTA (with zinc content ≥ 14%), complexed manganese MnEDTA (manganese content ≥ 12%) 2 parts, complex copper Na 2 CuEDTA (copper content ≥ 13%) 1 part, boric acid (boron content ≥ 17%) 1 part, ammonium molybdate tetrahydrate (molybdenum content ≥ 52%) 0.5 parts.
（4）助剂（合计1.3份）：丁基羟基茴香醚0.3份，有机硅表面活性剂（氨基改性聚硅氧烷，简称氨基硅油）0.5份，十二烷基硫酸钠0.5份。 (4) Auxiliary (1.3 parts in total): 0.3 part of butyl hydroxyanisole, 0.5 part of silicone surfactant (amino-modified polysiloxane, amino silicone oil for short), 0.5 part of sodium lauryl sulfate.
（5）植物生长调节剂（合计1.8份）：三十烷醇0.5份，复硝酚钾0.4份，赤霉素0.4份，萘乙酸钠0.5份。 (5) Plant growth regulator (1.8 parts in total): 0.5 part of triacontanol, 0.4 part of potassium nitrophenolate, 0.4 part of gibberellin, and 0.5 part of sodium naphthalene acetate.
（6）水42份。 (6) 42 parts of water.
3、生产工艺简图 3. Schematic diagram of the production process
（1）络合反应一 →（2）络合反应二 →（3）络合反应三 →（4）过滤除杂 →（5）喷雾干燥成固体 →（6）质检→产品。 (1) Complexation reaction one → (2) Complexation reaction two → (3) Complexation reaction three → (4) Filtration and removal of impurities → (5) Spray drying into solid → (6) Quality inspection → product.
4、生产工艺描述： 4. Description of production process:
（1）络合反应一：在加温反应釜中，将42份的水和8份的腐植酸钾粉混合,加温到50℃～60℃之间并不断搅拌,将固体溶解；再加入微量元素化合物共10份，即络合铁Fe-EDTA（含铁量≥12%）3份，络合锌Na2ZnEDTA（含锌量≥14%）2.5份，络合锰MnEDTA（含锰量≥12%）2份，络合铜Na2CuEDTA（含铜量≥13%）1份，硼酸(含硼≥17%)1份，四水钼酸铵(含钼量≥52%)0.5份；保持温度50℃～60℃之间并不断搅拌，反应0.5小时。 (1) Complexation reaction 1: In a heating reactor, mix 42 parts of water and 8 parts of potassium humate powder, heat to 50℃～60℃ and keep stirring to dissolve the solid; then add A total of 10 parts of trace element compounds, namely complex iron Fe-EDTA (iron content ≥ 12%) 3 parts, complex zinc Na 2 ZnEDTA (zinc content ≥ 14%) 2.5 parts, complex manganese MnEDTA (manganese content ≥12%) 2 parts, complex copper Na 2 CuEDTA (copper content ≥13%) 1 part, boric acid (boron content ≥17%) 1 part, ammonium molybdate tetrahydrate (molybdenum content ≥52%) 0.5 part ; Keep the temperature between 50°C and 60°C and keep stirring, and react for 0.5 hours.
（2）络合反应二：将上步所得溶液，依次分别加入大量元素化合物共38份，即尿素（含氮量≥46%）8份，硫酸钾（含氧化钾量≥51%）22份，磷酸二氢钾（含五氧化二磷量≥51%、含氧化钾量≥34%）8份；再加入助剂共1.3份，即丁基羟基茴香醚0.3份，有机硅表面活性剂（氨基改性聚硅氧烷，简称氨基硅油）0.5份，十二烷基硫酸钠0.5份；保持温度50℃～60℃之间，不断搅拌，反应2小时。 (2) Complexation reaction 2: Add 38 parts of a large number of element compounds to the solution obtained in the previous step, namely 8 parts of urea (nitrogen content ≥ 46%), and 22 parts of potassium sulfate (potassium oxide content ≥ 51%) , potassium dihydrogen phosphate (containing phosphorus pentoxide ≥ 51%, potassium oxide ≥ 34%) 8 parts; then add a total of 1.3 parts of additives, namely 0.3 parts of butyl hydroxyanisole, silicone surfactant ( Amino-modified polysiloxane (amino silicone oil for short) 0.5 part, sodium lauryl sulfate 0.5 part; keep the temperature between 50°C and 60°C, keep stirring, and react for 2 hours.
（3）络合反应三：将上步所得溶液，依次加入植物生长调节剂共1.8份，即三十烷醇0.5份，复硝酚钾0.4份，赤霉素0.4份，萘乙酸钠0.5份；保持温度40℃～50℃之间，不断搅拌，反应1小时。 (3) Complexation reaction 3: Add 1.8 parts of plant growth regulator to the solution obtained in the previous step, namely 0.5 part of triacontanol, 0.4 part of potassium nitrophenolate, 0.4 part of gibberellin, and 0.5 part of sodium naphthalene acetate ; Keep the temperature between 40°C and 50°C, keep stirring, and react for 1 hour.
（4）过滤除杂：将上步所得溶液通过过滤器过滤，去除杂质。 (4) Filtration to remove impurities: filter the solution obtained in the previous step through a filter to remove impurities.
（5）喷雾干燥成固体：将上步所得溶液经过干燥塔喷雾干燥成固体粉末或小颗粒。 (5) Spray drying into solid: the solution obtained in the previous step is spray dried into solid powder or small particles through a drying tower.
（6）质检：将上步所得固体粉末或小颗粒进行质检，质检合格，即为产品。 (6) Quality inspection: The solid powder or small particles obtained in the previous step are subjected to quality inspection, and if the quality inspection is passed, it is the product.
实施例2：腐植酸络合多种营养元素水溶肥料（高氮微量元素型） Example 2: Humic acid complexed with multiple nutrients water-soluble fertilizer (high nitrogen trace element type)
1、产品技术指标（固体产品） 1. Product technical index (solid product)
2、产品组成成分(下列组分均为产品重量份数，每份单位为千克) 2. Composition of the product (the following components are parts by weight of the product, and the unit of each part is kilogram)
（1）腐植酸钾粉（含腐植酸量≥50%，含氧化钾量≥10%，水不溶物≤2%）8份。 (1) Potassium humate powder (containing humic acid ≥ 50%, potassium oxide ≥ 10%, water insoluble ≤ 2%) 8 parts.
（2）大量元素化合物（合计36份）：尿素（含氮量≥46%）29份，硫酸钾（含氧化钾量≥51%）1份，磷酸二氢钾（含五氧化二磷量≥51%、含氧化钾量≥34%）6份。 (2) Macroelement compounds (36 parts in total): 29 parts of urea (nitrogen content ≥ 46%), potassium sulfate (potassium oxide content ≥ 51%) 1 part, potassium dihydrogen phosphate (phosphorus pentoxide content ≥ 51%, containing potassium oxide ≥ 34%) 6 parts.
（3）微量元素化合物（合计10份）：络合铁Fe-EDTA（含铁量≥12%）3份，络合锌Na2ZnEDTA（含锌量≥14%）2.5份，络合锰MnEDTA（含锰量≥12%）2份，络合铜Na2CuEDTA（含铜量≥13%）1份，硼酸(含硼量≥17%)1份，四水钼酸铵(含钼量≥52%)0.5份。 (3) Trace element compounds (10 parts in total): 3 parts of complexed iron Fe-EDTA (iron content ≥ 12%), 2.5 parts of complexed zinc Na 2 ZnEDTA (with zinc content ≥ 14%), complexed manganese MnEDTA (manganese content ≥ 12%) 2 parts, complex copper Na 2 CuEDTA (copper content ≥ 13%) 1 part, boric acid (boron content ≥ 17%) 1 part, ammonium molybdate tetrahydrate (molybdenum content ≥ 52%) 0.5 parts.
（4）助剂（合计1.4份）：丁基羟基茴香醚0.4份，有机硅表面活性剂（氨基改性聚硅氧烷，简称氨基硅油）0.4份，十二烷基硫酸钠0.6份。 (4) Additives (1.4 parts in total): 0.4 parts of butyl hydroxyanisole, 0.4 parts of silicone surfactant (amino-modified polysiloxane, amino silicone oil for short), 0.6 parts of sodium lauryl sulfate.
（5）植物生长调节剂（合计2份）：三十烷醇0.4份，复硝酚钾0.5份，赤霉素0.5份，萘乙酸钠0.6份。 (5) Plant growth regulator (2 parts in total): 0.4 part of triacontanol, 0.5 part of potassium nitrophenolate, 0.5 part of gibberellin, and 0.6 part of sodium naphthalene acetate.
（6）水44份。 (6) 44 parts of water.
3、生产工艺简图 3. Schematic diagram of the production process
（1）络合反应一 →（2）络合反应二 →（3）络合反应三 →（4）过滤除杂 →（5）喷雾干燥成固体 →（6）质检→产品。 (1) Complexation reaction one → (2) Complexation reaction two → (3) Complexation reaction three → (4) Filtration and removal of impurities → (5) Spray drying into solid → (6) Quality inspection → product.
4、生产工艺描述： 4. Description of production process:
（1）络合反应一：在加温反应釜中，将44份的水和8份的腐植酸钾粉混合,加温到50℃～60℃之间并不断搅拌,将固体溶解；再加入微量元素化合物共10份，即络合铁Fe-EDTA（含铁量≥12%）3份，络合锌Na2ZnEDTA（含锌量≥14%）2.5份，络合锰MnEDTA（含锰量≥12%）2份，络合铜Na2CuEDTA（含铜量≥13%）1份，硼酸(含硼量≥17%)1份，四水钼酸铵(含钼量≥52%)0.5份；保持温度50℃～60℃之间并不断搅拌，反应0.5小时。 (1) Complexation reaction 1: In a heating reactor, mix 44 parts of water and 8 parts of potassium humate powder, heat to 50℃～60℃ and keep stirring to dissolve the solid; then add A total of 10 parts of trace element compounds, namely complex iron Fe-EDTA (iron content ≥ 12%) 3 parts, complex zinc Na 2 ZnEDTA (zinc content ≥ 14%) 2.5 parts, complex manganese MnEDTA (manganese content ≥12%) 2 parts, complex copper Na 2 CuEDTA (copper content ≥13%) 1 part, boric acid (boron content ≥17%) 1 part, ammonium molybdate tetrahydrate (molybdenum content ≥52%) 0.5 parts; keep the temperature between 50°C and 60°C and keep stirring, and react for 0.5 hours.
（2）络合反应二：将上步所得溶液，依次分别加入大量元素化合物共36份，即尿素（含氮量≥46%）29份，硫酸钾（含氧化钾量≥51%）1份，磷酸二氢钾（含五氧化二磷量≥51%、含氧化钾量≥34%）6份；再加入助剂共1.4份，即丁基羟基茴香醚0.4份，有机硅表面活性剂（氨基改性聚硅氧烷，简称氨基硅油）0.4份，十二烷基硫酸钠0.6份；保持温度50℃～60℃之间，不断搅拌，反应2小时。 (2) Complexation reaction 2: Add 36 parts of a large number of element compounds to the solution obtained in the previous step, namely 29 parts of urea (nitrogen content ≥ 46%), and 1 part of potassium sulfate (potassium oxide content ≥ 51%) , potassium dihydrogen phosphate (containing phosphorus pentoxide ≥ 51%, potassium oxide ≥ 34%) 6 parts; then add a total of 1.4 parts of additives, namely 0.4 parts of butyl hydroxyanisole, silicone surfactant ( Amino-modified polysiloxane, referred to as amino silicone oil) 0.4 parts, sodium lauryl sulfate 0.6 parts; keep the temperature between 50°C and 60°C, keep stirring, and react for 2 hours.
（3）络合反应三：将上步所得溶液，依次加入植物生长调节剂共2份，即三十烷醇0.4份，复硝酚钾0.5份，赤霉素0.5份，萘乙酸钠0.6份；保持温度40℃～50℃之间，不断搅拌，反应1小时。 (3) Complexation reaction 3: Add 2 parts of the plant growth regulator to the solution obtained in the previous step, namely 0.4 part of triacontanol, 0.5 part of potassium nitrophenolate, 0.5 part of gibberellin, and 0.6 part of sodium naphthalene acetate ; Keep the temperature between 40°C and 50°C, keep stirring, and react for 1 hour.
（4）过滤除杂：将上步所得溶液通过过滤器过滤，去除杂质。 (4) Filtration to remove impurities: filter the solution obtained in the previous step through a filter to remove impurities.
（5）喷雾干燥成固体：将上步所得溶液经过干燥塔喷雾干燥成固体粉末或小颗粒。 (5) Spray drying into solid: the solution obtained in the previous step is spray dried into solid powder or small particles through a drying tower.
（6）质检：将上步所得固体粉末或小颗粒进行质检，质检合格，即为产品。 (6) Quality inspection: The solid powder or small particles obtained in the previous step are subjected to quality inspection, and if the quality inspection is passed, it is the product.
实施例3：腐植酸络合多种营养元素水溶肥料（高磷微量元素型） Example 3: Humic acid complexed with multiple nutrients water-soluble fertilizer (high phosphorus trace element type)
1、产品技术指标（固体产品） 1. Product technical index (solid product)
2、产品组成成分(下列组分均为产品重量份数，每份单位为千克) 2. Composition of the product (the following components are parts by weight of the product, and the unit of each part is kilogram)
（1）腐植酸钾粉（含腐植酸量≥50%，含氧化钾量≥10%，水不溶物≤2%）8份。 (1) Potassium humate powder (containing humic acid ≥ 50%, potassium oxide ≥ 10%, water insoluble ≤ 2%) 8 parts.
（2）大量元素化合物（合计33份）：尿素（含氮量≥46%）7份，硫酸钾（含氧化钾量≥51%）1份，磷酸二氢钾（含五氧化二磷量≥51%、含氧化钾量≥34%）25份。 (2) Macroelement compounds (33 parts in total): 7 parts of urea (nitrogen content ≥ 46%), potassium sulfate (potassium oxide content ≥ 51%) 1 part, potassium dihydrogen phosphate (phosphorus pentoxide content ≥ 51%, containing potassium oxide ≥ 34%) 25 parts.
（3）微量元素化合物（合计10份）：络合铁Fe-EDTA（含铁量≥12%）3份，络合锌Na2ZnEDTA（含锌量≥14%）2.5份，络合锰MnEDTA（含锰量≥12%）2份，络合铜Na2CuEDTA（含铜量≥13%）1份，硼酸(含硼量≥17%)1份，四水钼酸铵(含钼量≥52%)0.5份。 (3) Trace element compounds (10 parts in total): 3 parts of complexed iron Fe-EDTA (iron content ≥ 12%), 2.5 parts of complexed zinc Na 2 ZnEDTA (with zinc content ≥ 14%), complexed manganese MnEDTA (manganese content ≥ 12%) 2 parts, complex copper Na 2 CuEDTA (copper content ≥ 13%) 1 part, boric acid (boron content ≥ 17%) 1 part, ammonium molybdate tetrahydrate (molybdenum content ≥ 52%) 0.5 parts.
（4）助剂（合计1.5份）：丁基羟基茴香醚0.5份，有机硅表面活性剂（氨基改性聚硅氧烷，简称氨基硅油）0.6份，十二烷基硫酸钠0.4份。 (4) Additives (1.5 parts in total): 0.5 part of butyl hydroxyanisole, 0.6 part of silicone surfactant (amino-modified polysiloxane, amino silicone oil for short), 0.4 part of sodium lauryl sulfate.
（5）植物生长调节剂（合计2.5份）：三十烷醇0.6份，复硝酚钾0.6份，赤霉素0.6份，萘乙酸钠0.7份。 (5) Plant growth regulator (2.5 parts in total): 0.6 part of triacontanol, 0.6 part of potassium nitrophenolate, 0.6 part of gibberellin, and 0.7 part of sodium naphthalene acetate.
（6）水46份。 (6) 46 parts of water.
3、生产工艺简图 3. Schematic diagram of the production process
（1）络合反应一 →（2）络合反应二 →（3）络合反应三 →（4）过滤除杂 →（5）喷雾干燥成固体 →（6）质检→产品。 (1) Complexation reaction one → (2) Complexation reaction two → (3) Complexation reaction three → (4) Filtration and removal of impurities → (5) Spray drying into solid → (6) Quality inspection → product.
4、生产工艺描述： 4. Description of production process:
（1）络合反应一：在加温反应釜中，将46份的水和8份的腐植酸钾粉混合,加温到50℃～60℃之间并不断搅拌,将固体溶解；再加入微量元素化合物共10份，即络合铁Fe-EDTA（含铁量≥12%）3份，络合锌Na2ZnEDTA（含锌量≥14%）2.5份，络合锰MnEDTA（含锰量≥12%）2份，络合铜Na2CuEDTA（含铜量≥13%）1份，硼酸(含硼量≥17%)1份，四水钼酸铵(含钼量≥52%)0.5份；保持温度50℃～60℃之间并不断搅拌，反应0.5小时。 (1) Complexation reaction 1: In a heating reactor, mix 46 parts of water and 8 parts of potassium humate powder, heat to 50℃～60℃ and keep stirring to dissolve the solid; then add A total of 10 parts of trace element compounds, namely complex iron Fe-EDTA (iron content ≥ 12%) 3 parts, complex zinc Na 2 ZnEDTA (zinc content ≥ 14%) 2.5 parts, complex manganese MnEDTA (manganese content ≥12%) 2 parts, complex copper Na 2 CuEDTA (copper content ≥13%) 1 part, boric acid (boron content ≥17%) 1 part, ammonium molybdate tetrahydrate (molybdenum content ≥52%) 0.5 parts; keep the temperature between 50°C and 60°C and keep stirring, and react for 0.5 hours.
（2）络合反应二：将上步所得溶液，依次分别加入大量元素化合物共33份，即尿素（含氮量≥46%）7份，硫酸钾（含氧化钾量≥51%）1份，磷酸二氢钾（含五氧化二磷量≥51%、含氧化钾量≥34%）25份；再加入助剂1.5份，即丁基羟基茴香醚0.5份，有机硅表面活性剂（氨基改性聚硅氧烷，简称氨基硅油）0.6份，十二烷基硫酸钠0.4份；保持温度50℃～60℃之间，不断搅拌，反应2小时。 (2) Complexation reaction 2: Add 33 parts of a large number of element compounds to the solution obtained in the previous step, namely, 7 parts of urea (nitrogen content ≥ 46%), and 1 part of potassium sulfate (potassium oxide content ≥ 51%) , potassium dihydrogen phosphate (containing phosphorus pentoxide ≥ 51%, potassium oxide ≥ 34%) 25 parts; then add 1.5 parts of additives, namely 0.5 parts of butylated hydroxyanisole, silicone surfactant (amino Modified polysiloxane, referred to as amino silicone oil) 0.6 parts, sodium lauryl sulfate 0.4 parts; keep the temperature between 50°C and 60°C, keep stirring, and react for 2 hours.
（3）络合反应三：将上步所得溶液，依次分别加入植物生长调节剂共2.5份，即三十烷醇0.6份，复硝酚钾0.6份，赤霉素0.6份，萘乙酸钠0.7份；保持温度40℃～50℃之间，不断搅拌，反应1小时。 (3) Complexation reaction 3: Add 2.5 parts of the plant growth regulator to the solution obtained in the previous step, namely, 0.6 part of triacontanol, 0.6 part of potassium nitrophenolate, 0.6 part of gibberellin, and 0.7 part of sodium naphthalene acetate. parts; keep the temperature between 40°C and 50°C, keep stirring, and react for 1 hour.
（4）过滤除杂：将上步所得溶液通过过滤器过滤，去除杂质。 (4) Filtration to remove impurities: filter the solution obtained in the previous step through a filter to remove impurities.
（5）喷雾干燥成固体：将上步所得溶液经过干燥塔喷雾干燥成固体粉末或小颗粒。 (5) Spray drying into solid: the solution obtained in the previous step is spray dried into solid powder or small particles through a drying tower.
（6）质检：将上步所得固体粉末或小颗粒进行质检，质检合格，即为产品。 (6) Quality inspection: The solid powder or small particles obtained in the previous step are subjected to quality inspection, and if the quality inspection is passed, it is the product.
5、本发明技术带来的有益效果： 5. Beneficial effects brought by the technology of the present invention:
（1）本发明产品是以腐植酸为载体，添加多种助剂，添加大量元素及微量元素的新型有机水溶肥料，具有养分吸收快、肥料利用率高、操作方便、避免某些元素被土壤固定等特点，对环境安全友好。生长调节剂三十烷醇对作物有增加产量和改善品质等作用，复硝酚钾促进元素的运转传送，赤霉素促进植物再生组织对元素的吸收比率，萘乙酸钠促进植物生物旺盛；表面活性剂有机硅大大降低了喷雾时溶液的表面张力，十二烷基硫酸钠使叶片润湿作用增强。这些都使营养元素更易被植物吸收利用。 (1) The product of the present invention is a new type of organic water-soluble fertilizer that uses humic acid as a carrier, adds a variety of additives, and adds a large number of elements and trace elements. Fixed and other features, safe and friendly to the environment. The growth regulator triacontanol can increase the yield and improve the quality of crops. Potassium nitrophenolate can promote the operation and transmission of elements, gibberellin can promote the absorption rate of elements by plant regeneration tissues, and sodium naphthalene acetate can promote the vigorous growth of plant organisms; The active agent silicone greatly reduces the surface tension of the solution when spraying, and sodium lauryl sulfate enhances leaf wetting. All of these make the nutrients more easily absorbed and utilized by plants.
（2）本发明产品通过腐植酸的络合，使元素之间没有拮抗作用，也解决了铁、锰易氧化，植物不易吸收的问题，使各元素相互促进吸收，协同增效。本发明产品用于叶面施肥或灌溉施肥，比传统土壤施肥吸收利用率大幅度提高。 (2) The complexation of humic acid in the product of the present invention makes there be no antagonistic effect between elements, and also solves the problems that iron and manganese are easy to oxidize and plants are not easy to absorb, so that each element can promote mutual absorption and synergistic effect. The product of the invention is used for foliar fertilization or irrigation fertilization, and the absorption and utilization rate of the traditional soil fertilization is greatly improved.
本发明产品和农业部NY1106-2006标准（即《含腐植酸水溶肥料》标准）——大量元素Ⅱ型相比较，在其它技术指标都符合该标准前提下，大量元素含量大幅度提高；另外本发明产品比标准指标另外多包含了的微量元素2.0%，可以同时补充大量元素和微量元素，节省人工，综合使用成本降低。 Compared with the NY1106-2006 standard of the Ministry of Agriculture (that is, the standard of "water-soluble fertilizer containing humic acid") - macroelement type II, the product of the present invention has greatly increased the content of macroelements on the premise that other technical indicators meet this standard; The invention product contains 2.0% more trace elements than the standard index, which can supplement both macronutrients and trace elements at the same time, saving labor and reducing the overall cost of use.
（3）本发明产品营养成分较全，大量元素和微量元素同补，尤其分别强化补充氮、磷、钾，针对性强，可满足植物不同生长时期对不同营养元素的需求，所以综合使用成本较低。 (3) The product of the present invention has relatively complete nutritional components, and supplements both macronutrients and trace elements, especially nitrogen, phosphorus, and potassium, which are highly targeted and can meet the needs of plants for different nutritional elements in different growth periods, so the comprehensive use cost lower.
用法用量：本发明产品叶面施肥时，高钾微量元素型加水稀释500倍、高氮微量元素型加水稀释600倍、高磷微量元素型稀释1000倍。经多点试验：本发明产品用于果实膨大期、成熟期，施用于果树、蔬菜、大田作物，使果实个大均匀，表面光洁，固形物增加，生长后期落果减少，商品等级明显提高，增产15～25%。 Usage and dosage: when fertilizing the leaves of the product of the present invention, the high-potassium trace element type is diluted 500 times with water, the high-nitrogen trace element type is diluted 600 times with water, and the high-phosphorus trace element type is diluted 1000 times. After multi-point tests: the product of the present invention is used in the fruit expansion stage and maturity stage, and is applied to fruit trees, vegetables, and field crops, so that the fruit size is uniform, the surface is smooth, the solid content is increased, the fruit drop in the late growth period is reduced, the commodity grade is obviously improved, and the production is increased. 15-25%.
以上实施例中原料成份比是优选后的原料成份比，本发明不仅限于此原料配比。 The raw material composition ratio in the above embodiment is the optimized raw material composition ratio, and the present invention is not limited to this raw material composition ratio.
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| CN106431528A (en) * | 2016-09-28 | 2017-02-22 | 林晓山 | Methods for producing fulvic acid salt, fulvic acid water-soluble fertilizers and aquatic nutrient solution from alcohol waste liquid from waste molasses |
| CN108503451A (en) * | 2018-06-21 | 2018-09-07 | 上海永通生态工程股份有限公司 | A kind of biological medicine fertilizer and preparation method thereof |
| CN109206235A (en) * | 2018-10-27 | 2019-01-15 | 山西惠亿农生物科技有限公司 | A kind of humic acid Macroelement water-soluble fertilizer and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2206340A (en) * | 1987-06-25 | 1989-01-05 | Perlite Gmbh | Composition for soil improvement |
| CN1451637A (en) * | 2002-04-12 | 2003-10-29 | 李裕 | Drought-resistant and saline-alkali-resistant phosphate fertilizer |
| CN101096326A (en) * | 2006-06-28 | 2008-01-02 | 吴嫦华 | Organic silicon leaf fertilizer and preparation method thereof |
-
2010
- 2010-03-16 CN CN2010101252548A patent/CN101798246B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2206340A (en) * | 1987-06-25 | 1989-01-05 | Perlite Gmbh | Composition for soil improvement |
| CN1451637A (en) * | 2002-04-12 | 2003-10-29 | 李裕 | Drought-resistant and saline-alkali-resistant phosphate fertilizer |
| CN101096326A (en) * | 2006-06-28 | 2008-01-02 | 吴嫦华 | Organic silicon leaf fertilizer and preparation method thereof |
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| CN101798246A (en) | 2010-08-11 |
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