CN101134689A - Complete-element high-concentration water-soluble long-acting compound fertilizer and method for manufacturing same - Google Patents
Complete-element high-concentration water-soluble long-acting compound fertilizer and method for manufacturing same Download PDFInfo
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- CN101134689A CN101134689A CNA2006100305166A CN200610030516A CN101134689A CN 101134689 A CN101134689 A CN 101134689A CN A2006100305166 A CNA2006100305166 A CN A2006100305166A CN 200610030516 A CN200610030516 A CN 200610030516A CN 101134689 A CN101134689 A CN 101134689A
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 62
- 150000001875 compounds Chemical class 0.000 title claims description 30
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- 238000000034 method Methods 0.000 title description 7
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 19
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003112 inhibitor Substances 0.000 claims abstract description 10
- 239000011573 trace mineral Substances 0.000 claims abstract description 9
- 235000013619 trace mineral Nutrition 0.000 claims abstract description 9
- 239000002131 composite material Substances 0.000 claims abstract 6
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 26
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 19
- 239000011575 calcium Substances 0.000 claims description 18
- 229910052757 nitrogen Inorganic materials 0.000 claims description 16
- 229910052698 phosphorus Inorganic materials 0.000 claims description 16
- 239000011777 magnesium Substances 0.000 claims description 15
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 13
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 13
- 239000012466 permeate Substances 0.000 claims description 13
- 229910052700 potassium Inorganic materials 0.000 claims description 13
- 238000005303 weighing Methods 0.000 claims description 13
- 229910052802 copper Inorganic materials 0.000 claims description 12
- 239000010949 copper Substances 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 12
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 12
- 239000011701 zinc Substances 0.000 claims description 12
- 229910052725 zinc Inorganic materials 0.000 claims description 12
- 229910052796 boron Inorganic materials 0.000 claims description 11
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 10
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 10
- 239000011574 phosphorus Substances 0.000 claims description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 9
- 229940090496 Urease inhibitor Drugs 0.000 claims description 9
- 229910052750 molybdenum Inorganic materials 0.000 claims description 9
- 239000011591 potassium Substances 0.000 claims description 9
- 239000000047 product Substances 0.000 claims description 9
- 239000002601 urease inhibitor Substances 0.000 claims description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 7
- 241000196324 Embryophyta Species 0.000 claims description 6
- 210000003608 fece Anatomy 0.000 claims description 6
- 239000010871 livestock manure Substances 0.000 claims description 6
- MFUVDXOKPBAHMC-UHFFFAOYSA-N magnesium;dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MFUVDXOKPBAHMC-UHFFFAOYSA-N 0.000 claims description 6
- 239000004323 potassium nitrate Substances 0.000 claims description 6
- 235000010333 potassium nitrate Nutrition 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 5
- 239000013543 active substance Substances 0.000 claims description 5
- 239000011572 manganese Substances 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- 229910021538 borax Inorganic materials 0.000 claims description 4
- 239000004202 carbamide Substances 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 4
- 229910000396 dipotassium phosphate Inorganic materials 0.000 claims description 4
- 235000019797 dipotassium phosphate Nutrition 0.000 claims description 4
- 238000005516 engineering process Methods 0.000 claims description 4
- 239000000618 nitrogen fertilizer Substances 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 239000004328 sodium tetraborate Substances 0.000 claims description 4
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 3
- 235000007688 Lycopersicon esculentum Nutrition 0.000 claims description 3
- 240000003768 Solanum lycopersicum Species 0.000 claims description 3
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 3
- NGLMYMJASOJOJY-UHFFFAOYSA-O azanium;calcium;nitrate Chemical compound [NH4+].[Ca].[O-][N+]([O-])=O NGLMYMJASOJOJY-UHFFFAOYSA-O 0.000 claims description 3
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 244000144730 Amygdalus persica Species 0.000 claims description 2
- 235000017060 Arachis glabrata Nutrition 0.000 claims description 2
- 244000105624 Arachis hypogaea Species 0.000 claims description 2
- 235000010777 Arachis hypogaea Nutrition 0.000 claims description 2
- 235000018262 Arachis monticola Nutrition 0.000 claims description 2
- 235000000832 Ayote Nutrition 0.000 claims description 2
- 241000167854 Bourreria succulenta Species 0.000 claims description 2
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 claims description 2
- 240000008384 Capsicum annuum var. annuum Species 0.000 claims description 2
- 244000241235 Citrullus lanatus Species 0.000 claims description 2
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 claims description 2
- 244000241257 Cucumis melo Species 0.000 claims description 2
- 235000009847 Cucumis melo var cantalupensis Nutrition 0.000 claims description 2
- 240000008067 Cucumis sativus Species 0.000 claims description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 claims description 2
- 240000004244 Cucurbita moschata Species 0.000 claims description 2
- 235000009854 Cucurbita moschata Nutrition 0.000 claims description 2
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 claims description 2
- 239000005696 Diammonium phosphate Substances 0.000 claims description 2
- 240000001008 Dimocarpus longan Species 0.000 claims description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- 244000061508 Eriobotrya japonica Species 0.000 claims description 2
- 235000009008 Eriobotrya japonica Nutrition 0.000 claims description 2
- 235000000235 Euphoria longan Nutrition 0.000 claims description 2
- 240000005561 Musa balbisiana Species 0.000 claims description 2
- 235000018290 Musa x paradisiaca Nutrition 0.000 claims description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 2
- 244000061176 Nicotiana tabacum Species 0.000 claims description 2
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 2
- 235000006040 Prunus persica var persica Nutrition 0.000 claims description 2
- 244000061458 Solanum melongena Species 0.000 claims description 2
- 235000002597 Solanum melongena Nutrition 0.000 claims description 2
- 244000061456 Solanum tuberosum Species 0.000 claims description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 claims description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 claims description 2
- 240000006365 Vitis vinifera Species 0.000 claims description 2
- 235000014787 Vitis vinifera Nutrition 0.000 claims description 2
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 235000019693 cherries Nutrition 0.000 claims description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 2
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 2
- 239000003814 drug Substances 0.000 claims description 2
- 235000012907 honey Nutrition 0.000 claims description 2
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 2
- 239000006012 monoammonium phosphate Substances 0.000 claims description 2
- 235000020232 peanut Nutrition 0.000 claims description 2
- 239000002686 phosphate fertilizer Substances 0.000 claims description 2
- 229940072033 potash Drugs 0.000 claims description 2
- 235000007686 potassium Nutrition 0.000 claims description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 2
- 235000015320 potassium carbonate Nutrition 0.000 claims description 2
- 235000015136 pumpkin Nutrition 0.000 claims description 2
- 239000003352 sequestering agent Substances 0.000 claims description 2
- RWVGQQGBQSJDQV-UHFFFAOYSA-M sodium;3-[[4-[(e)-[4-(4-ethoxyanilino)phenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]-2-methylcyclohexa-2,5-dien-1-ylidene]methyl]-n-ethyl-3-methylanilino]methyl]benzenesulfonate Chemical compound [Na+].C1=CC(OCC)=CC=C1NC1=CC=C(C(=C2C(=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=2C(=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=C1 RWVGQQGBQSJDQV-UHFFFAOYSA-M 0.000 claims description 2
- 239000012747 synergistic agent Substances 0.000 claims description 2
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 5
- 239000002689 soil Substances 0.000 abstract description 3
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 235000021049 nutrient content Nutrition 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 235000015097 nutrients Nutrition 0.000 description 7
- WZLMXYBCAZZIRQ-UHFFFAOYSA-N [N].[P].[K] Chemical compound [N].[P].[K] WZLMXYBCAZZIRQ-UHFFFAOYSA-N 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- 235000016709 nutrition Nutrition 0.000 description 4
- 230000035764 nutrition Effects 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- 241000108664 Nitrobacteria Species 0.000 description 2
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- -1 fully stir Substances 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 235000010149 Brassica rapa subsp chinensis Nutrition 0.000 description 1
- 235000000536 Brassica rapa subsp pekinensis Nutrition 0.000 description 1
- 241000499436 Brassica rapa subsp. pekinensis Species 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- VSNHCAURESNICA-UHFFFAOYSA-N Hydroxyurea Chemical compound NC(=O)NO VSNHCAURESNICA-UHFFFAOYSA-N 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 description 1
- 229940061634 magnesium sulfate heptahydrate Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000009919 sequestration Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 238000003900 soil pollution Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
Landscapes
- Fertilizers (AREA)
Abstract
The present invention discloses one series of all-component high concentration water soluble composite fertilizers containing macro elements and trace elements essential for crops and its production process. The composite fertilizers are produced through recipe design, addition of Ca, Mg and other elements, addition of chelated trace elements, penetrant, nitrification inhibitor and other effective components. The composite fertilizers are high quality chemical fertilizers with raised nutrient contents, long acting period, capacity of promoting the absorption of crop, low production cost, capacity of improving soil structure and natural environment, and other advantages.
Description
Technical field
The serial compound manure that the present invention relates to use on the agroforestry especially can be applied to the complete-element high-concentration water-soluble long-acting compound fertilizer of multiple kinds of crops and landscape flower.
Background technology
Fertilizer has become the important foundation of modern agricultural development as the grain of supplying with the plant desired nutritional.At present, become main flow, and also have and add trace element in the part fertilizer based on the ternary compounded granular fertilizer of N, P, K, or multiple functional elements.This class fertilizer is because comprehensive nutrition is compared with common straight fertilizer, and its fertilizer efficiency increases.Yet, have compound manure now owing to wherein contain insoluble composition, and, can not effectively be absorbed by crop owing to easily form antagonistic action between the trace element; Meanwhile, because the nitrogen element in the compound manure under the effect of nitrobacteria and urase, a series of side reactions takes place in soil, cause nitrogen loss and soil pollution.
Summary of the invention
The purpose of this invention is to provide complete-element high-concentration water-soluble long-acting compound fertilizer and manufacture method thereof that a class contains various nutrient elements, has high utilization rate.
Technical scheme foundation of the present invention:
1, according to the characteristics of growth and development of plants, the water soluble nutrient of full unit is provided, wherein contain macroelement N, P, K, moderate-element Ca, Mg, S, micro-Cu, Fe, Mn, Mo, Zn, Co, B are to satisfy demand of plant growth.
2, the citric acid that has intelligent pH regulator function by employing, the pH value of regulating fertilizer, satisfying edaphic condition, and nutrients such as realization citric acid and calcium, magnesium carry out the low temperature chelating, prevent nutrients such as calcium, magnesium and are fixed.Meanwhile,, guarantee that water-soluble calcium and phosphorus coexist, break the taboo that calcium in the water soluble fertilizer, magnesium and phosphorus can not compatibilities, guaranteed the equilibrium of nutrition by the effect of citric acid.
3, all trace elements except that B, Mo all adopt chelated microelements, can guarantee crop to trace elements absorbed, effectively prevent trace element and phosphorus generation antagonism.
4, in above-mentioned fertilizer, add chemical assistant with utmost point low surface tension, utilize strong wet performance, super ductibility energy and the strong pore perviousness and the anti-rain drop erosion performance of this auxiliary agent, can promote the rapid absorption of nutrient, improve the utilising efficiency of fertilizer leaf dressing on the blade face.
5, in above-mentioned fertilizer, add quinhydrones (HQ), avoid the urea nitrigen in the fertilizer to be converted into ammonium nitrogen fast with the effect of inhibition urase; Add dicyandiamide (DCD), avoid the ammonium nitrogen in the fertilizer under the effect of nitrobacteria, to form gaseous nitrogen with inhibition nitrification.Interact by HQ and DCD, improve the service efficiency of nitrogenous fertilizer.
6, add the tensio-active agent of an amount of good dispersion property in above-mentioned fertilizer, make material particles loose, nutrient is even, and no caking phenomenon takes place.
Complete-element high-concentration water-soluble long-acting compound fertilizer of the present invention is applicable to the chemical fertilizer of farm crop and plant, comprises following component:
(1) contains the mixture or the compound of water-soluble inorganic nitrogen, phosphorus and potassium;
(2) contain water-soluble calcium, magnesium elements and other inorganics;
(3) contain the inorganic salt of water-soluble copper, iron, manganese, zinc, cobalt chelated microelements and molybdenum, boron;
(4) contain and sprawl permeate agent, nitrification inhibitor, urease inhibitor and anti-hard caking agent.
Further, above-mentioned complete-element high-concentration water-soluble long-acting compound fertilizer is to select for use said components to process by following constituent content scope:
(1) in this water-soluble long-acting compound fertilizer, macroelement N, P
2O
5, K
2O content summation is 28-75 weight %.
(2) in this water-soluble long-acting compound fertilizer, moderate-element Ca, Mg content summation are 0-11 weight %.
(3) in this water-soluble long-acting compound fertilizer, the content summation of micro-Cu, Fe, Mn, Mo, Zn, Co, B is 0.02-0.10 weight %.
(4) in this water-soluble long-acting compound fertilizer, sprawl permeate agent content and be about 0.05-1 weight %; The 0-5 weight % of nitrification inhibitor (DCD) content total nitrogen; Urease inhibitor (HQ) content accounts for the 0-5.0 weight % of total nitrogen; Anti-hard caking agent content is 0-1.0%.
Manufacture method of the present invention
1, raw material: in the above-mentioned complete-element high-concentration water-soluble long-acting compound fertilizer, nitrogen is from urea, agricultural ammonium nitrate, agricultural saltpetre; Phosphorus derives from monoammonium phosphate, diammonium phosphate, potassium primary phosphate, potassium hydrogen phosphate; Potassium derives from potassium primary phosphate, potassium hydrogen phosphate, agricultural saltpetre; Calcium source is in calcium ammonium nitrate, nitrocalcite; Magnesium derives from magnesium sulfate heptahydrate, magnesium nitrate hexahydrate; Boron derives from boric acid, borax; Molybdenum derives from Sodium Molybdate Dihydrate; The inner complex of copper, iron, manganese, zinc, cobalt is processed by one or both sequestrants among EDTA, the DTPA, adopts the process for sequestration on the textbook to be prepared; Sprawl permeate agent and derive from silicone based tensio-active agent, be preferably the silicone based tensio-active agent that contains the trisiloxane ethoxylate structure, comprise the not Keep away from rain that Shanghai Wintong Chemicals Co., Ltd. produces
TMThe fertile synergistic agent of superfine product medicine; Nitrification inhibitor derives from dicyandiamide (DCD); Urease inhibitor derives from quinhydrones (HQ); Anti-hard caking agent derives from commercially available water miscible compound manure anti-hard caking agent.
2, manufacturing process: at first take by weighing each component raw material, crushing screening by above proportioning.
(1) elder generation with after containing the deionized water dissolving of a certain amount of citric acid, mixes stand-by with nitrogenous fertilizer nitrification inhibitor, urease inhibitor and anti-hard caking agent;
(2) take by weighing a certain amount of trace element, sprawl permeate agent and calcium, magnesium fertilizer mix after, stand-by;
(3) take by weighing a certain amount of phosphate fertilizer and potash fertilizer, mix, add step 2) mixture that obtains, mix, add the mixture that step 1) obtains again, carry out thorough mixing again, promptly obtain product of the present invention.
Above-mentioned complete-element high-concentration water-soluble long-acting compound fertilizer can be applied on following farm crop and the plant respectively: flowers, lawn, gardens, nursery stock, tobacco, tealeaves, green pepper, eggplant, cucumber, pumpkin, muskmelon, watermelon, lichee, longan, loquat, banana, grape, cherry, honey peach, peanut, potato, tomato etc.
The advantage of complete-element high-concentration water-soluble long-acting compound fertilizer of the present invention is:
1, nutrient is complete, instant effect.
2, be full water-soluble fertilizer, applicable to multiple fertilization mode, wide application.
3, nitrogenous fertilizer extension of validity has improved fertilizer utilization ratio.
4, the taboo that calcium and phosphorus in the water soluble fertilizer can not compatibilities has been broken in water-soluble calcium and phosphorus coexistence, has guaranteed the equilibrium of nutrition.
5, fertilizer is with strong points, and prescription satisfies equilibrium relationship between soil, crop, the fertilizer, satisfies crop each breeding time of the demand to various nutritive elements.
6, increase yield significantly uses this product can make fruit volume increase 20-30%, vegetables volume increase 25-35%, and flower characteristic obviously promotes.
7, preparation technology is simple, adopts the mechanical stirring method can produce various dedicated fertilizers.
Embodiment:
Below in conjunction with embodiment the present invention is encyclopaedized it.
Embodiment 1:
According to the present invention, the weight face proportion by subtraction of the complete-element high-concentration water-soluble fertilizer general formulation of each element and binder component preparation is:
N 20％ P
2O
5 20％ K
2O 20％ Ca 0％
Mg 0.07％ B 0.009％ Cu 0.02％ Fe 0.1％
Mn 0.05％ Mo 0.002％ Zn 0.02％ Co 0.0005％
DCD 0.0006% HQ 0.005% sprawls permeate agent 0.05%
Anti-hard caking agent 0.5%
The preparation method of above-mentioned general formulation is as follows:
With 100Kg fertilizer is example.
1) takes by weighing 0.6g DCD, 5g HQ and 0.5kg anti-hard caking agent and be dissolved in a certain amount of deionized water that contains citric acid, fully stir, make its dissolving; Take by weighing 22kg urea, 43.48kg saltpetre again, above-mentioned solution is sprayed at the nitrate surface that weighs up equably with the form of spraying, mix, stand-by.
2) take by weighing 0.08kg borax, 0.045kg Sodium orthomolybdate, 0.01kg and sprawl permeate agent, 0.2kg chelated copper, 1.0kg chelated iron, 0.5kg Chelated Manganese, 0.2kg chelating cobalt, 0.005 chelating zinc, fully stir, mix, stand-by.
3) take by weighing the 32.79kg primary ammonium phosphate, add step 2 again) mixture that obtains, fully stir, mix, add step 1) gained mixture again.Fully stir, behind the mixing, get product.
This routine formula fertilizer is applicable to that various crops are in the fertilising of different steps.
Effect behind this routine chemical fertilizer application (comparing) with the common nitrogen phosphorus potassium summation 60% of no chelated microelements
1) Chinese cabbage
| Project | Output ton/mu | Product proterties and quality (kg) | |||
| Chlorophyll content (mg/g -1) | Vitamin C content (mg/ (100g) -1) | Soluble sugar amount (g/kg -1) | Nitrate nitrogen content (mg/kg -1) | ||
| This fertilizer | 1.90 | 0.95 | 77.7 | 4.55 | 206.3 |
| Common nitrogen phosphorus potassium total content 60% | 1.43 | 0.84 | 71.3 | 3.71 | 242.9 |
Embodiment 2:
According to the present invention, the weight face proportion by subtraction of the complete-element high-concentration water-soluble fertilizer calcium magnesium prescription of each element and binder component preparation is:
N 15％ P
2O 55％ K
2O 15％ Ca 5％
Mg 2％ B 0.009％ Cu 0.02％ Fe 0.1％
Mn 0.05％ Mo 0.002％ Zn 0.02％ Co 0.0005％
DCD 0.0008% HQ 0.01% sprawls permeate agent 0.06%
Anti-hard caking agent 0.5%
The preparation method of above-mentioned prescription is as follows:
1) takes by weighing 0.8g DCD, 10g HQ and 0.5kg anti-hard caking agent and be dissolved in a certain amount of deionized water that contains citric acid, fully stir, make its dissolving; Take by weighing 7.2kg ammonium nitrate, 32.93kg saltpetre again, above-mentioned solution is sprayed at the nitrate surface that weighs up equably with the form of spraying, mix, stand-by.
2) take by weighing 26.3kg calcium ammonium nitrate, 20kg exsiccant magnesium nitrate hexahydrate, 0.08kg borax, 0.045kg Sodium orthomolybdate, 0.01kg and sprawl permeate agent, 0.2kg chelated copper, 1.0kg chelated iron, 0.5kg Chelated Manganese, 0.2kg chelating cobalt, 0.005kg chelating zinc, fully stir, mix, stand-by.
3) take by weighing the 11.4kg Ureaphil, add step 2) mixture that obtains, fully stir, mix, add step 1) gained mixture again.Fully behind stirring, the mixing, get product.
This routine formula fertilizer is applicable to the various fertilisings that the crop of calcium magnesium demand is arranged.
Effect behind this routine chemical fertilizer application (comparing) with the common nitrogen phosphorus potassium summation 35% of no chelated microelements
(1) tomato
| Project | Output ton/mu | The product proterties | Fruit type, quality comprehensive evaluation | |||
| The leaf look | Plant height/cm | Maximum width of blade degree/cm | Stem is thick/cm | |||
| This fertilizer | 15.0 | Dark green | 510 | 9.2 | 2.0 | Fruit shape is straight, and color and luster is beautiful |
| Common nitrogen phosphorus potassium total content 35% | 11.2 | Green | 421 | 8.70 | 1.0 | Malformed fruit is arranged, tarnish, mouthfeel is acid |
The foregoing description is that foregoing of the present invention is described further, but this should be interpreted as that the scope of the above-mentioned theme of the present invention only limits to above-mentioned example.All technology that realizes based on foregoing all belong to category of the present invention.
Claims (7)
1. complete-element high-concentration water-soluble long-acting compound fertilizer comprises following component:
(1) contains the mixture or the compound of water-soluble inorganic nitrogen, phosphorus and potassium;
(2) contain water-soluble calcium, magnesium elements and other inorganics;
(3) contain the inorganic salt of water-soluble copper, iron, manganese, zinc, cobalt chelated microelements and boron, molybdenum element;
(4) contain and sprawl permeate agent, nitrification inhibitor, urease inhibitor and anti-hard caking agent.
2. according to the described in other words complete-element high-concentration water-soluble long-acting compound fertilizer of claim 1, it is characterized in that being mixed into the following compound manure of content by following component:
(1) contains the mixture or the compound of water-soluble inorganic nitrogen, phosphorus and potassium; In water-soluble long-acting compound fertilizer, macroelement N, P
2O
5, K
2O content summation is 28-75 weight %.
(2) contain water-soluble calcium, magnesium elements and other inorganics; In water-soluble long-acting composite fertilizer, moderate-element Ca, Mg content summation are 0-11 weight %.
(3) contain the inorganic salt of water-soluble copper, iron, manganese, zinc, cobalt chelated microelements and boron, molybdenum element; In water-soluble long-acting composite fertilizer, the content summation of micro-Cu, Fe, Mn, Mo, Zn, Co, B is 0.02-1.0 weight %.
(4) contain and sprawl permeate agent, nitrification inhibitor, urease inhibitor and anti-hard caking agent; In water soluble composite fertilizer, sprawl permeate agent content and be about 0.05-1.0 weight %; Nitrification inhibitor (DCD) accounts for the 0-5.0% of total nitrogen; Urease inhibitor (HQ) accounts for the 0-5.0% of total nitrogen; Anti-hard caking agent content is about 0-1.0%.
3. according to claim 1,2 described complete-element high-concentration water-soluble long-acting compound fertilizers, it is characterized in that described nitrogen is from urea, agricultural saltpetre, ammonium nitrate; Phosphorus derives from monoammonium phosphate, diammonium phosphate, potassium primary phosphate, potassium hydrogen phosphate; Potassium derives from potassium primary phosphate, potassium hydrogen phosphate, agricultural saltpetre; Calcium source is in calcium ammonium nitrate; Magnesium derives from magnesium nitrate hexahydrate; Boron derives from boric acid or borax; Molybdenum derives from Sodium Molybdate Dihydrate; Sprawl permeate agent and derive from silicone based tensio-active agent, be preferably the silicone based tensio-active agent that contains the trisiloxane ethoxylate structure, comprise the fertile synergistic agent of not Keep away from rain TM superfine product medicine that Shanghai Wintong Chemicals Co., Ltd. produces; Nitrification inhibitor derives from dicyandiamide (DCD); Urease inhibitor derives from quinhydrones (HQ); Anti-hard caking agent derives from commercially available water miscible compound manure anti-hard caking agent.
4. complete-element high-concentration water-soluble long-acting compound fertilizer according to claim 1 is characterized in that, the inner complex of described copper, iron, manganese, zinc, cobalt is processed by one or both sequestrants among EDTA, the DTPA.
5. claim 1,2 arbitrary described complete-element high-concentration water-soluble long-acting compound fertilizer preparation technologies may further comprise the steps:
(1) elder generation with after containing a certain amount of deionized water dissolving of citric acid, mixes stand-by with nitrogenous fertilizer nitrification inhibitor, urease inhibitor and anti-hard caking agent;
(2) take by weighing a certain amount of trace element and sprawl permeate agent and mix afterwards stand-by with calcium, magnesium fertilizer;
(3) take by weighing a certain amount of phosphate fertilizer and potash fertilizer, mix, add step 2) mixture that obtains, mix, add the mixture that step 1) obtains again, carry out thorough mixing again, promptly obtain product of the present invention.
6. claim 1,2 arbitrary described complete-element high-concentration water-soluble long-acting compound fertilizers are applied on the following farm crop:
Flowers, lawn, gardens, nursery stock, tobacco, tealeaves, green pepper, eggplant, cucumber, pumpkin, muskmelon, watermelon, lichee, longan, loquat, banana, grape, cherry, honey peach, peanut, potato, tomato etc.
Claim 1,2 described complete-element high-concentration water-soluble long-acting compound fertilizers can be in the farm crop of establishing in large scale or the application on the plant.
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