CN101671201A - Under-glaze and in-glaze picture pattern decorating method of magnesia porcelain - Google Patents
Under-glaze and in-glaze picture pattern decorating method of magnesia porcelain Download PDFInfo
- Publication number
- CN101671201A CN101671201A CN200810212260A CN200810212260A CN101671201A CN 101671201 A CN101671201 A CN 101671201A CN 200810212260 A CN200810212260 A CN 200810212260A CN 200810212260 A CN200810212260 A CN 200810212260A CN 101671201 A CN101671201 A CN 101671201A
- Authority
- CN
- China
- Prior art keywords
- porcelain
- glaze
- picture pattern
- magnesia
- picture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 229910052573 porcelain Inorganic materials 0.000 title claims abstract description 54
- 239000000395 magnesium oxide Substances 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title abstract description 18
- 239000000049 pigment Substances 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000011248 coating agent Substances 0.000 claims abstract description 6
- 238000000576 coating method Methods 0.000 claims abstract description 6
- 239000003292 glue Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 244000269722 Thea sinensis Species 0.000 claims abstract description 4
- 235000006468 Thea sinensis Nutrition 0.000 claims abstract description 4
- 235000020279 black tea Nutrition 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 210000003298 dental enamel Anatomy 0.000 claims description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 238000001354 calcination Methods 0.000 claims description 10
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 5
- 239000000292 calcium oxide Substances 0.000 claims description 5
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 5
- 239000000919 ceramic Substances 0.000 claims description 5
- 239000003086 colorant Substances 0.000 claims description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 5
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 5
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 5
- 229960001866 silicon dioxide Drugs 0.000 claims description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 5
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 4
- 240000000111 Saccharum officinarum Species 0.000 claims description 3
- 235000007201 Saccharum officinarum Nutrition 0.000 claims description 3
- 239000003973 paint Substances 0.000 claims description 3
- 239000007858 starting material Substances 0.000 claims description 3
- 235000000346 sugar Nutrition 0.000 claims description 3
- 150000008163 sugars Chemical class 0.000 claims description 3
- 238000007639 printing Methods 0.000 abstract description 4
- 229910052793 cadmium Inorganic materials 0.000 abstract description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract description 3
- 238000000227 grinding Methods 0.000 abstract 2
- 238000010422 painting Methods 0.000 abstract 2
- 239000002699 waste material Substances 0.000 abstract 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 abstract 1
- 229930006000 Sucrose Natural products 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 229960004793 sucrose Drugs 0.000 abstract 1
- 230000002950 deficient Effects 0.000 description 5
- 238000010586 diagram Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000015895 biscuits Nutrition 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Images
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- Glass Compositions (AREA)
Abstract
The invention relates to an under-glaze and in-glaze picture pattern decorating method of a magnesia porcelain, which comprises the following steps of: adding 2 percent of crushed magnesia waste porcelain in a basic pigment, mixing the mixture with a glue and grinding the mixture, and printing, hand painting or adhering a decorated layer of a picture pattern on an internal blank of the porcelain;coating a porcelain glaze layer on the internal blank of the porcelain, wherein after being made and calcined, the pattern can appear on a bottom layer under the porcelain glaze; or after adding the magnesia waste porcelain in the basic pigment, boiling 3kg of water, adding 20g of black tea and 100g of cane sugar, stirring the mixture for over 1.5h, grinding the stirred water and raw materials forover 150h, coating the porcelain glaze on the bottom of the decorating picture pattern, and printing or hand painting the picture pattern of the pigment. The under-glaze and in-glaze picture patterndecorating method of the magnesia porcelain has the advantages of improving the quality of the picture decorating method of the original magnesia porcelain, preventing lead and cadmium which are dissolved out from the surface of the porcelain from exceeding the standard, avoiding damages to human bodies, preventing the picture pattern layer from being damaged, along with clear patterns and brightcolors.
Description
Technical field
The present invention relates to a kind of pattern decorative method of magnesia porcelain, relate in particular under a kind of magnesia porcelain glaze with glaze in the trailing of picture pattern.
Background technology
The picture of magnesia porcelain is decorated and is adopted the way (being decorative method on the glaze) of decorating on the porcelain glaze usually at present, the enamel picture that adopts this method to make is very easy to cause the wearing and tearing of local coat of colo(u)r after slight the cutting of process drawn or rubbed, also can follow simultaneously the phenomenon that plumbous cadmium stripping exceeds standard takes place, to such an extent as to so prior art exist that the efficient of very big this kind of defective production method is lower, quality product is relatively poor, durable inadequately; If adopt magnesia porcelain glaze picture pattern decorative method down, very easy the coming off of position enamel glass coating of porcelain surface enamel decorative picture in calcination process then makes that the quality of product reduces greatly, product scrap rate and fraction defective rising; Adopt the figuration of picture in the magnesia porcelain glaze in addition, the quality product that such method processes is stable equally inadequately, and enamel decorative picture position enamel glass coating in calcination process in porcelain surface is very easy to be destroyed by pigment, thereby causes that the enamel surface has that pin hole, picture pattern color layers easily come off, product scrap rate and the higher defective of fraction defective.
Summary of the invention
The objective of the invention is at above-mentioned defective, provide under a kind of magnesia porcelain glaze with glaze in the trailing of picture pattern, relatively poor to overcome because of the quality product that adopts general method to cause to produce, inadequately durable, human body is existed the deficiency that certain healthy hidden danger, picture pattern layer are damaged easily or come off.
For achieving the above object, the present invention is by the following technical solutions:
A kind of magnesia porcelain glaze down with glaze in the trailing of picture pattern, the trailing of picture pattern under the glaze wherein may further comprise the steps:
(1) the ceramic glaze pigment powder that preparation is finished applies the siccative Gu and fills a prescription clearly, doses the magnesia useless porcelain of the disintegrated that is equivalent to the total proportioning 2% of pigment in basic colorant;
(2) adopt glue to be in harmonious proportion and levigate, with picture pattern printed decorative layer, Freehandhand-drawing or stick in the porcelain on the idiosome;
(3) in china clay, add 75% silicon-dioxide, 7.5%~8% aluminum oxide, 2%~2.5% calcium oxide, 2.8%~3% magnesium oxide, 7.5%~8% potassium oxide and mixture and other micro substance of sodium oxide, thereby be mixed with enamel layer;
(4) enamel layer is set in porcelain on the idiosome, after making calcining, various picture patterns keep bright-coloured and can be reflected in the bottom under the porcelain glaze.
The trailing of picture pattern in the described glaze, can carry out above-mentioned steps (1) afterwards, adding 20g black tea and 100 gram sugarcane white sugars stirrings one and a half hours over the 3kg poach, the water that has stirred is ground more than 150 hours with starting material again, enamel is coated in the bottom of the decorative picture pattern of wanting, republishes or the picture pattern of Freehandhand-drawing paint.
Beneficial effect of the present invention is: improved the class of the picture trailing of original magnesia porcelain, make plumbous cadmium can stripping porcelain surface do not exceed standard, harmless, can keep safety, health, be applicable in the daily life for a long time; When the porcelain surface is subjected to mild wear, can keeps the picture pattern layer not suffer damage, thereby can keep the picture pattern of porcelain clear, beautiful in colour; Improved production efficiency, improved product quality, prolonged work-ing life of porcelain product.
Description of drawings
With reference to the accompanying drawings the present invention is described in further detail below.
Fig. 1 is the synoptic diagram that embodiments of the invention 1 and embodiment 2 all adopt picture pattern decorative method under the magnesia enamel;
Fig. 2 is the synoptic diagram that embodiments of the invention 3 adopt picture pattern decorative method in the magnesia enamel.
Among the figure:
1, idiosome in the porcelain; 2, enamel layer; 3, picture pattern ornament layer; 4, china clay skin.
Embodiment
Embodiment 1
As shown in Figure 1, the trailing of picture pattern under the described magnesia porcelain glaze of the embodiment of the invention may further comprise the steps:
(1) the ceramic glaze pigment powder that preparation is finished applies the siccative Gu and fills a prescription clearly, doses the magnesia useless porcelain of the disintegrated that is equivalent to the total proportioning 2% of pigment in basic colorant;
(2) adopt glue to be in harmonious proportion and levigate, with 3 printings of picture pattern ornament layer, Freehandhand-drawing or stick in the porcelain on the idiosome 1;
(3) in china clay, add 75% silicon-dioxide, 8% aluminum oxide, 2% calcium oxide, 3% magnesium oxide, 8% potassium oxide and mixture and other micro substance of sodium oxide, thereby be mixed with enamel layer 2;
(4) enamel layer 2 is set in porcelain on the idiosome 1, after making calcining, various picture patterns keep bright-coloured and can be reflected in the bottom under the porcelain glaze.
As shown in Figure 1, the trailing of picture pattern under the described magnesia porcelain glaze of the embodiment of the invention may further comprise the steps:
(1) in china clay, adds 75% silicon-dioxide, 7.5% aluminum oxide, 2.5% calcium oxide, 3% magnesium oxide, 8% the potassium oxide and mixture and other micro substance of sodium oxide, thereby be mixed with enamel layer 2 and be arranged on the interior idiosome 1 of porcelain;
(2) the ceramic glaze pigment powder that preparation is finished applies the siccative Gu and fills a prescription clearly, doses the magnesia useless porcelain of the disintegrated that is equivalent to the total proportioning 2% of pigment in basic colorant;
(3) adopt glue to be in harmonious proportion and levigate, with 3 printings of picture pattern ornament layer, Freehandhand-drawing or stick in the porcelain on the idiosome 1, after making calcining, various picture patterns keep bright-coloured and can be reflected in the bottom under the porcelain glaze.
As shown in Figure 2, the trailing of picture pattern in the described magnesia porcelain glaze of the embodiment of the invention may further comprise the steps:
(1) in china clay, adds 75% silicon-dioxide, 8% aluminum oxide, 2.5% calcium oxide, 3% magnesium oxide, 7.5% potassium oxide and mixture and other micro substance of sodium oxide, thereby be mixed with enamel layer 2, again base substrate in the product 1 formed the white biscuit device through the glazing calcining;
(2) the ceramic glaze pigment powder that preparation is finished applies the siccative Gu and fills a prescription clearly, in basic colorant, dose the magnesia useless porcelain of the disintegrated that is equivalent to the total proportioning 2% of pigment, adding 20g black tea and 100 gram sugarcane white sugars stirrings one and a half hours over the 3kg poach, the water that has stirred is ground more than 150 hours with starting material again, adjust pigment with this ratio;
(3) enamel is coated in the bottom of the decorative picture pattern of wanting, republishes or the picture pattern of Freehandhand-drawing paint, then various pigment picture patterns can be fused in the enamel glass coating after calcining.
Above-described embodiment; be more preferably several embodiments of the present invention, the common color that those skilled in the art is carried out around present technique method core procedure in the technical solution of the present invention scope, the variation aspect the quality and replacement all should be included in protection scope of the present invention.
Claims (3)
1, a kind of magnesia porcelain glaze down with glaze in the trailing of picture pattern, it is characterized in that,
May further comprise the steps:
(1) the ceramic glaze pigment powder that preparation is finished applies the siccative Gu and fills a prescription clearly, doses the magnesia useless porcelain of the disintegrated that is equivalent to the total proportioning 2% of pigment in basic colorant;
(2) adopt glue to be in harmonious proportion and levigate, with picture pattern printed decorative layer, Freehandhand-drawing or stick in the porcelain on the idiosome;
(3) in china clay, add 75% silicon-dioxide, 7.5%~8% aluminum oxide, 2%~2.5% calcium oxide, 2.8%~3% magnesium oxide, 7.5%~8% potassium oxide and mixture and other micro substance of sodium oxide, thereby be mixed with enamel layer;
(4) enamel layer is set in porcelain on the idiosome, after making calcining, various picture patterns keep bright-coloured and can be reflected in the bottom under the porcelain glaze.
2, magnesia porcelain glaze according to claim 1 down with glaze in the trailing of picture pattern, it is characterized in that: can dispose enamel layer earlier and be arranged in the porcelain on the idiosome, adopt glue that pigment is in harmonious proportion again and levigate, with picture pattern printed decorative layer, Freehandhand-drawing or after sticking in the porcelain on the idiosome again through making calcining.
3, magnesia porcelain glaze according to claim 1 down with glaze in the trailing of picture pattern, it is characterized in that: can finish step (1) afterwards, adding 20g black tea and 100 gram sugarcane white sugars stirrings one and a half hours over the 3kg poach, the water that has stirred is ground more than 150 hours with starting material again, enamel is coated in the bottom of waiting to decorate picture pattern, republish or Freehandhand-drawing paint pattern, then various pigment picture patterns can be fused in the enamel glass coating after calcining.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN200810212260A CN101671201A (en) | 2008-09-08 | 2008-09-08 | Under-glaze and in-glaze picture pattern decorating method of magnesia porcelain |
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CN200810212260A CN101671201A (en) | 2008-09-08 | 2008-09-08 | Under-glaze and in-glaze picture pattern decorating method of magnesia porcelain |
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CN200810212260A Pending CN101671201A (en) | 2008-09-08 | 2008-09-08 | Under-glaze and in-glaze picture pattern decorating method of magnesia porcelain |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106587921A (en) * | 2016-12-15 | 2017-04-26 | 湖南新辉陶瓷有限责任公司 | Improved magnesia porcelain |
CN107053884A (en) * | 2016-12-09 | 2017-08-18 | 重庆昊晟玻璃股份有限公司 | The decal method that preventing heavy metal is separated out |
CN112457059A (en) * | 2020-12-07 | 2021-03-09 | 余志刚 | Pigment for painting and calligraphy on underglaze and in-glaze color bottom and application method thereof |
-
2008
- 2008-09-08 CN CN200810212260A patent/CN101671201A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107053884A (en) * | 2016-12-09 | 2017-08-18 | 重庆昊晟玻璃股份有限公司 | The decal method that preventing heavy metal is separated out |
CN107053884B (en) * | 2016-12-09 | 2018-11-30 | 重庆昊晟玻璃股份有限公司 | The decal method that preventing heavy metal is precipitated |
CN106587921A (en) * | 2016-12-15 | 2017-04-26 | 湖南新辉陶瓷有限责任公司 | Improved magnesia porcelain |
CN112457059A (en) * | 2020-12-07 | 2021-03-09 | 余志刚 | Pigment for painting and calligraphy on underglaze and in-glaze color bottom and application method thereof |
CN112457059B (en) * | 2020-12-07 | 2023-04-28 | 余志刚 | Pigment for painting and calligraphy under glaze and on color bottom in glaze and application method thereof |
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Application publication date: 20100317 |