CN105753465B

CN105753465B - A kind of preparation method of super flat mirror face art mural of porcelain and its obtained product

Info

Publication number: CN105753465B
Application number: CN201610043338.4A
Authority: CN
Inventors: 伍剑峰
Original assignee: Individual
Current assignee: Individual
Priority date: 2016-01-24
Filing date: 2016-01-24
Publication date: 2017-12-29
Anticipated expiration: 2036-01-24
Also published as: CN105753465A

Abstract

The present invention relates to a kind of preparation method of the super flat mirror face art mural of porcelain, comprise the following steps：Blank is prepared into adobe by roll-forming, applies cosmetic soil layer and transparent suboptical glaze layer in adobe after drying, then kiln-firing is into ceramic tile；Zirconium white ground glaze layer is printed in ceramic tile surface by silk-screen printing technique, painted decoration is carried out after high temperature drying, pattern is then printed on painted decoration layer and fixes glaze layer and throws brilliant dry powder layer, then kiln-firing is into artistic ceramic tile；Decorated on artistic ceramic tile using craft of gilding or schreinering, then the super flat mirror face art mural product of porcelain is made by edging, glossing.The present invention is by using ceramic ink jet printing technology and traditional silk-screen printing and hand painting technique, stable performance, superior in quality porcelain mural painting have been prepared through twice firing, product quality is exquisite, picture is abundant, exquisite in texture, can be widely applied to airport, station, house, office building finishing in, have broad application prospects.

Description

A kind of preparation method of super flat mirror face art mural of porcelain and its obtained product

Technical field

The invention belongs to inorganic non-metallic material（Ceramics）Field, and in particular to a kind of super flat mirror face art mural of porcelain Preparation method and its obtained product.

Background technology

At present, in the market art porcelain plate painter's skill is numerous and diverse, such as UV paint pictures（The product is not environmentally）, also with powder enamel （The five colours）, based on blue and white with copper red colors series of products, subject matter is mostly scenery with hills and waters, such as：The high-grade ceramic board pictures such as snow scenes, birds and flowers, personage, base By technique great master, manual drawing, mostly original product, every secondary picture creative time cycle are grown in person on this, and quantity is very limited, and And it is expensive, more more than tens thousand of members.

Low and middle-grade ceramic board pictures are mostly that general skilled worker copies the works formed by hand, lack value of art appreciation mostly, often Though width works are inexpensive, it also is difficult to enter commonly other life；Using silk-screen printing or the porcelain plate of decal paper technique productions Product, it is cheap, but lack individuality, picture lacks artistic effect, and water absorption rate of existing market porcelain plate itself is high, and brick is unstable Fixed, time length is easy to crack.In summary, the preparation method of mural painting can not meet consumer demand in the market, sternly The development prospect of art mural is hindered again.

The content of the invention

The technical problem to be solved in the present invention is to provide a kind of porcelain, technique is simple, stable performance, cost of material are low The preparation method of honest and clean, good decorating effect the super flat mirror face art mural of porcelain and its obtained product

To solve above technical problem, the technical scheme is that：A kind of making of the super flat mirror face art mural of porcelain Method, it is characterised in that comprise the following steps：

Step 1：It is standby to prepare blank, cosmetic soil, transparent suboptical glaze, zirconium white ground-coat enamel, pattern fixation glaze, the brilliant dry powder of throwing；

Step 2：Blank is prepared into adobe by roll-forming, first applies cosmetic soil layer in adobe after drying, then apply Transparent suboptical glaze layer, then enter kiln through 120~150 minutes, ceramic tile is fired at 1180~1200 DEG C；

Step 3：Zirconium white ground glaze layer is printed in ceramic tile surface made from step 2 by silk-screen printing technique, done through high temperature Painted decoration is carried out after dry, pattern is then printed on painted decoration layer and fixes glaze layer, then fixes to print in glaze layer in pattern and throws Brilliant dry powder layer, then enter kiln through 75~110 minutes, artistic ceramic tile is fired at 1020~1100 DEG C；

Step 4：Decorated, then passed through using craft of gilding or schreinering on artistic ceramic tile made from step 3 The super flat mirror face art mural product of porcelain is made in edging, glossing.

The percentage by weight of blank and the cosmetic soil formula forms：

Blank：It is black mud 15~20%, calcined kaolin 10~20%, potassium albite 40~50%, high temperature sand 10~20%, magnesia Soil 1~3%；

Cosmetic soil：Potassium albite 20~30%, quartz 20~30%, calcined kaolin 5~10%, burning talcum 15~20%, chlorine Change aluminium 1~5%, frit one 5~10%, air knife soil 5~8%.

The transparent suboptical glaze, zirconium white ground-coat enamel, the percentage by weight composition of pattern fixation glaze formula are：

Transparent suboptical glaze：Potassium albite 20~30%, quartz 15~20%, talcum 10~15%, calcined kaolin 10~15%, Aluminum oxide 3~6%, zinc oxide 1~4%, calcite 10~15%, frit one 10~20%, kaolin 5~8%, air knife soil 5~8%；

Zirconium white ground-coat enamel：Creamy white frit 60~70%, zirconium silicate 10~15%, calcined kaolin 5~10%, aluminum oxide 5~10%, Burn talcum 8~10%, additional ethylene glycol 10~20%, print cream 60~80%；

Pattern fixes glaze：Frit 2 20~40%, dry powder one 30~40%, dry powder 2 30~40%, additional ethylene glycol 10~ 25%th, cream 80~100% is printed.

The percentage by weight for throwing brilliant dry powder, which forms, is：Dry powder one 30%, dry powder 2 70%.

In the step 2 cosmetic the thickness of the layer be 0.2~0.25mm, the thickness of transparent suboptical glaze be 0.25~ 0.3mm, adobe water absorption rate are 1~3%, ceramic tile glacing flatness is 0.2~0.3mm.

The logical mesh number that zirconium white ground glaze layer is printed in the step 3 is 80~120 mesh, thickness 0.55mm；Print pattern The logical mesh number of fixed glaze layer is 80~120 mesh, thickness 0.8mm；The logical mesh number that brilliant dry powder layer is thrown in printing is 40 mesh, thickness For 1.6~1.8mm.

The frit one is the KT-1411 Creamy white frits of Guangdong Sanshui Dahong Glaze Making Co., Ltd.'s sale, frit two is KZ-867 Creamy white frits, the dry powder one of Guangdong Sanshui Dahong Glaze Making Co., Ltd.'s sale are Foshan Sihui City dragon dollar ceramics LC-759 dry granulars, the dry powder two of raw material Co., Ltd sale are sold for dragon dollar ceramic raw material Co., Ltd of Foshan Sihui City LC-750 dry granulars.

The print cream is by cellulose CMC, glycerine, ethylene glycol, water by weight percentage 0.5:1.5:3:5 ratio coordinate and Into.

The painted decoration process includes one or more decorating methods in screen printing, inkjet printing, hand painting Combination, pigment used in the screen printing, inkjet printing is that inorganic pigment and stamp-pad ink and ointment mix, wherein inorganic face Material, stamp-pad ink, the weight ratio of ointment are 3:5:2, pigment used in the hand painting is that inorganic pigment mixes with frankincense oil and camphorated oil Conjunction forms, and wherein inorganic pigment, frankincense oil, the weight ratio of camphorated oil are 7:1:2.

Product made from above-mentioned preparation method, it is characterised in that：The size of the product be 600 × 600mm or 800 × 800mm or 1000 × 1000mm, glossiness are 100~105, and the depth of parallelism, the error of perpendicularity are no more than 0.3mm, the physics of product Performance parameter is：Frost resistance：- 4~4 DEG C, 80 circulations, flawless is without peeling；Heat endurance：It is small to be heated to 180 DEG C of insulations half Shi Hou, then put into 25 DEG C of water and do not split three times；Chemical resistance：Ammonium chloride 100g/L：GA levels, potassium hydroxide 30g/L：GLA Level, the V/V of hydrochloric acid 18%：GHA levels；Stain resistance：Iron oxide red：4 grades, the tincture of iodine：5 grades, olive oil：5 grades；Radioactivity：Shone in Ra, Th, K Index 0.7, outer photograph index 0.8.

The present invention use natural mineral raw and industrial pure material, by double-firing process prepared stable performance, The super flat mirror face art mural of superior in quality porcelain, meanwhile, with reference to international newest ceramic ink jet printing technology and traditional silk Wire mark brush and hand painting technique, famous calligraphy and painting of all times being fabricated to super flat mirror face art mural, the product quality is exquisite, Picture enriches, and pattern is provided simultaneously with light-weight environment-friendly, non-discolouring, the characteristics of never degenerating, can meet the modern times rich in texture and anima The level of consumption of people and the demand appreciated artistic product, and meet the industry policy of national energy-saving emission reduction, as long as having The place of wall can decorate the product, therefore have vast potential for future development.

Embodiment

Implementation column one：

A kind of super flat mirror face art mural of porcelain, it is characterised in that comprise the following steps：

Step 1：Blank, cosmetic soil, transparent suboptical glaze, zirconium white ground-coat enamel, pattern is prepared to fix glaze, throw brilliant dry powder；

The preparation process of wherein blank is：Black mud 16%, calcined kaolin 13%, potassium sodium length are weighed by formulation weight percentage Stone 50%, high temperature sand 19%, magnesium soil 2%, ball milling is carried out after above raw material is mixed, Ball-milling Time is 15 hours, and ball milling slurry is thin 250 mesh sieves to be spent, are tailed over less than 3%, the powder that water content is 7% is made by spray tower in the 30L/ seconds, by slurry in mud speed rate, It is strict to control grain composition, 5% is less than below 20 mesh, 20~40 mesh are more than the mesh of 25~45%, 40~60 mesh 45~65%, 100 small In 5% powder, the powder that has been granulated store 48 hours it is standby；

The preparation process of wherein cosmetic soil is：Potassium albite 23%, quartz 30%, calcining height are weighed by formulation weight percentage Ridge soil 10%, talcum 20%, aluminium chloride 3%, frit one 6%, air knife soil 8% are burnt, it is standby that ball grinder grinding is entered after above raw material is mixed With the fineness of grinding was 325 mesh sieves, was tailed over as less than 0.8%, proportion is 1.8 grams/cm3, flow velocity is the 30L/ seconds；

The preparation process of wherein transparent suboptical glaze is：Potassium albite 20%, quartz 10% are weighed by formulation weight percentage, are slided Stone 12%, calcined kaolin 15%, aluminum oxide 3%, zinc oxide 4%, calcite 13%, frit one 10%, kaolin 8%, air knife soil 5%, Will above raw material mix after enter and grind standby in ball mill, the fineness of grinding was 325 mesh sieves, was tailed over as less than 0.8%, than Weight is 1.8 grams/cm3, and flow velocity is the 30L/ seconds；

The preparation process of wherein zirconium white ground-coat enamel is：Creamy white frit 60%, zirconium silicate 15% are weighed by formulation weight percentage, are forged Burn kaolin 8%, aluminum oxide 8%, burn talcum 9%, additional ethylene glycol 10%, print cream 60%, enter ball mill after above raw material is mixed Middle grinding is standby, and the fineness of grinding was 325 mesh sieves, was tailed over as less than 0.8%, proportion is 1.6 grams/cm3, flow velocity 30L/ Second；

Wherein pattern fix glaze preparation process be：By formulation weight percentage weigh frit 2 20%, dry powder one 40%, Dry powder 2 40%, additional ethylene glycol 10%, print cream 80%, will above raw material mix after enter ball mill in grind it is standby, grinding it is thin It was 325 mesh sieves to spend, and was tailed over as 0；

The preparation process for wherein throwing brilliant dry powder is：Dry powder one 30% is weighed by formulation weight percentage, dry powder 2 70% mixes It is uniformly standby；

Step 2：Blank powder is distinguished into punching press 600 × 600mm adobes, stamping pressure by 3200 tons of roll squeezers 300bar/ cm3, first spoon 0.2mm cosmetic soil layer after 180 DEG C are dried in adobe, then spoon 0.25mm transparent suboptical Glaze layer, then enter kiln through 120 minutes, the ceramic tile that glacing flatness is below 0.3mm is fired at 1180 DEG C；

Step 3：Lead to net with 80~120 purposes and the zirconium white bottom that print thickness is 0.55mm is carried out on the ceramic tile after burning till Glaze layer, 100 DEG C of drying are carried out after printing, then lead to net with 80 purposes and pattern printing is carried out on zirconium white ground glaze layer, subsequently into Dried in 100 DEG C of baking oven, then led to 80 purposes after net prints on silk-screen printing pattern and fix glaze layer for 0.8mm patterns, Lead to net with 40 purposes again and fix the throwing crystalline substance dry powder layer that print thickness in glaze layer is 1.6mm in pattern, then enter kiln through 75 minutes, 1020 DEG C are fired into artistic ceramic tile；

Step 4：Decorated made from step 3 on artistic ceramic tile using craft of gilding, then passing through edging, buffer The super flat mirror face art mural product of porcelain that glossiness is 100 is made in skill.

Pigment used in pattern printing is that inorganic pigment mixes with stamp-pad ink and ointment, wherein inorganic pigment, stamp-pad ink, The weight ratio of ointment is 3:5:2.

Implementation column two：

The preparation process of wherein blank is：Black mud 18%, calcined kaolin 20%, potassium sodium length are weighed by formulation weight percentage Stone 41%, high temperature sand 18%, magnesium soil 3%, ball milling is carried out after above raw material is mixed, Ball-milling Time is 15 hours, and ball milling slurry is thin 250 mesh sieves to be spent, are tailed over less than 3%, the powder that water content is 7% is made by spray tower in the 40L/ seconds, by slurry in mud speed rate, It is strict to control grain composition, 5% is less than below 20 mesh, 20~40 mesh are more than the mesh of 25~45%, 40~60 mesh 45~65%, 100 small In 5% powder, the powder that has been granulated store 48 hours it is standby；

The preparation process of wherein cosmetic soil is：Potassium albite 30%, quartz 23%, calcining height are weighed by formulation weight percentage Ridge soil 8%, talcum 17%, aluminium chloride 5%, frit one 9%, air knife soil 8% are burnt, it is standby that ball grinder grinding is entered after above raw material is mixed With the fineness of grinding was 325 mesh sieves, was tailed over as less than 0.8%, proportion is 1.8 grams/cm3, flow velocity is the 40L/ seconds；

The preparation process of wherein transparent suboptical glaze is：Potassium albite 18%, quartz 12% are weighed by formulation weight percentage, are slided Stone 13%, calcined kaolin 13%, aluminum oxide 4%, zinc oxide 2%, calcite 14%, frit one 12%, kaolin 6%, air knife soil 6%, Will above raw material mix after enter and grind standby in ball mill, the fineness of grinding was 325 mesh sieves, was tailed over as less than 0.8%, than Weight is 1.8 grams/cm3, and flow velocity is the 40L/ seconds；

The preparation process of wherein zirconium white ground-coat enamel is：Creamy white frit 60%, zirconium silicate 15% are weighed by formulation weight percentage, are forged Burn kaolin 8%, aluminum oxide 8%, burn talcum 9%, additional ethylene glycol 10%, print cream 60%, enter ball mill after above raw material is mixed Middle grinding is standby, and the fineness of grinding was 325 mesh sieves, was tailed over as less than 0.8%, proportion is 1.6 grams/cm3, flow velocity 40L/ Second；

Step 2：Blank powder is distinguished into punching press 1000 × 1000mm adobes, stamping pressure by 3200 tons of roll squeezers 300bar/ cm3, first spoon 0.22mm cosmetic soil layer after 190 DEG C are dried in adobe, then spoon 0.27mm transparent Asia Light glaze layer, then enter kiln through 130 minutes, the ceramic tile that glacing flatness is below 0.3mm is fired at 1190 DEG C；

Step 3：Lead to net with 100 purposes and the zirconium white ground glaze layer that print thickness is 0.55mm carried out on the ceramic tile after burning till, 100 DEG C of drying are carried out after printing, then leads to net with 100 purposes and inkjet printing pattern is carried out on zirconium white ground glaze layer, subsequently into Dried in 100 DEG C of baking oven, then led to 100 purposes after net prints on inkjet printing pattern and fix glaze layer for 0.8mm patterns, Lead to net with 40 purposes again and fix the throwing crystalline substance dry powder layer that print thickness in glaze layer is 1.7mm in pattern, then enter kiln through 90 minutes, 1060 DEG C are fired into artistic ceramic tile；

Step 4：Decorated made from step 3 on artistic ceramic tile using schreinering, then passing through edging, buffer The super flat mirror face art mural product of porcelain that glossiness is 102 is made in skill.

Pigment used in the inkjet printing be inorganic pigment mixed with stamp-pad ink and ointment, wherein inorganic pigment, stamp-pad ink, The weight ratio of ointment is 3:5:2.

Implementation column three：

The preparation process of wherein blank is：Black mud 20%, calcined kaolin 18%, potassium sodium length are weighed by formulation weight percentage Stone 46%, high temperature sand 13%, magnesium soil 3%, ball milling is carried out after above raw material is mixed, Ball-milling Time is 15 hours, and ball milling slurry is thin 250 mesh sieves to be spent, are tailed over less than 3%, the powder that water content is 6% is made by spray tower in the 50L/ seconds, by slurry in mud speed rate, It is strict to control grain composition, 5% is less than below 20 mesh, 20~40 mesh are more than the mesh of 25~45%, 40~60 mesh 45~65%, 100 small In 5% powder, the powder that has been granulated store 48 hours it is standby；

The preparation process of wherein cosmetic soil is：Potassium albite 26%, quartz 27%, calcining height are weighed by formulation weight percentage Ridge soil 7%, talcum 19%, aluminium chloride 5%, frit one 10%, air knife soil 6% are burnt, it is standby that ball grinder grinding is entered after above raw material is mixed With the fineness of grinding was 325 mesh sieves, was tailed over as less than 0.8%, proportion is 1.8 grams/cm3, flow velocity is the 50L/ seconds；

The preparation process of wherein transparent suboptical glaze is：Potassium albite 18%, quartz 12% are weighed by formulation weight percentage, are slided Stone 13%, calcined kaolin 13%, aluminum oxide 4%, zinc oxide 2%, calcite 14%, frit one 12%, kaolin 6%, air knife soil 6%, Will above raw material mix after enter and grind standby in ball mill, the fineness of grinding was 325 mesh sieves, was tailed over as less than 0.8%, than Weight is 1.8 grams/cm3, and flow velocity is the 50L/ seconds；

The preparation process of wherein zirconium white ground-coat enamel is：Creamy white frit 60%, zirconium silicate 15% are weighed by formulation weight percentage, are forged Burn kaolin 8%, aluminum oxide 8%, burn talcum 9%, additional ethylene glycol 10%, print cream 60%, enter ball mill after above raw material is mixed Middle grinding is standby, and the fineness of grinding was 325 mesh sieves, was tailed over as less than 0.8%, proportion is 1.6 grams/cm3, flow velocity 50L/ Second；

Wherein pattern fix glaze preparation process be：By formulation weight percentage weigh frit 2 40%, dry powder one 30%, Dry powder 2 30%, additional ethylene glycol 25%, print cream 100%, will above raw material mix after enter ball mill in grind it is standby, grinding Fineness was 325 mesh sieves, was tailed over as 0；

Step 2：Blank powder is distinguished into punching press 800 × 800mm adobes, stamping pressure by 3200 tons of roll squeezers 300bar/ cm3, first spoon 0.25mm cosmetic soil layer after 200 DEG C are dried in adobe, then spoon 0.3mm transparent suboptical Glaze layer, then enter kiln through 150 minutes, the ceramic tile that glacing flatness is below 0.3mm is fired at 1200 DEG C；

Step 3：Lead to net with 120 purposes and the zirconium white ground glaze layer that print thickness is 0.55mm carried out on the ceramic tile after burning till, 100 DEG C of drying are carried out after printing, then leads to net with 120 purposes and painted decoration is carried out on zirconium white ground glaze layer, subsequently into 100 DEG C Baking oven in dry, then led to 120 purposes after net prints in painted decoration and fix glaze layer for 0.8mm patterns, then with 40 mesh Logical net pattern fix glaze layer on print thickness be 1.8mm throwing crystalline substance dry powder layer, then enter kiln through 110 minutes, at 1100 DEG C It is fired into artistic ceramic tile；

Step 4：Decorated made from step 3 on artistic ceramic tile using craft of gilding, then passing through edging, buffer The super flat mirror face art mural product of porcelain that glossiness is 105 is made in skill.

Painted decoration is that inkjet printing adds hand painting, and pigment used in inkjet printing is that inorganic pigment mixes with stamp-pad ink and print cream Conjunction forms, and wherein inorganic pigment, stamp-pad ink, the weight ratio of print cream are 3:5:2；

Pigment used in hand painting is that inorganic pigment mixes with frankincense oil and camphorated oil, wherein inorganic pigment, frankincense Oil, the weight ratio of camphorated oil are 7:1:2.

Embodiment 1~3 be made product physical function parameter be：Frost resistance：- 4~4 DEG C, 80 circulations, flawless is without stripping Fall；Heat endurance：After being heated to 180 DEG C of insulation half an hour, then put into 25 DEG C of water and do not split three times；Chemical resistance：Chlorination Ammonium 100g/L：GA levels, potassium hydroxide 30g/L：GLA levels, the V/V of hydrochloric acid 18%：GHA levels；Stain resistance：Iron oxide red：4 grades, the tincture of iodine：5 Level, olive oil：5 grades；Radioactivity：Ra, Th, K are interior to be shone index 0.7, is outer according to index 0.8.

600 × 600mm made from above-described embodiment or 800 × 800mm or 1000 × 1000mm super flat mirror face skill of porcelain Art mural painting product, any place is suitable for by free splicing, combination, the decoration of environment uses.

Claims

1. a kind of preparation method of the super flat mirror face art mural of porcelain, it is characterised in that comprise the following steps：

Step 2：Blank is prepared into adobe by roll-forming, first applies cosmetic soil layer in adobe after drying, then apply transparent Matt glaze layer, then enter kiln through 120~150 minutes, ceramic tile is fired at 1180~1200 DEG C；

Step 3：Zirconium white ground glaze layer is printed in ceramic tile surface made from step 2 by silk-screen printing technique, after high temperature drying Painted decoration is carried out, pattern fixation glaze layer is then printed on painted decoration layer, then fix printing in glaze layer in pattern and throw brilliant do Bisque, then enter kiln through 75~110 minutes, artistic ceramic tile is fired at 1020~1100 DEG C；

Step 4：Decorated made from step 3 on artistic ceramic tile using craft of gilding or schreinering, then by edging, The super flat mirror face art mural product of porcelain is made in glossing.

2. preparation method according to claim 1, it is characterised in that：The percentage by weight of blank and the cosmetic soil formula Form and be：

Blank：Black mud 15~20%, calcined kaolin 10~20%, potassium albite 40~50%, high temperature sand 10~20%, magnesium soil 1 ~3%；

Cosmetic soil：Potassium albite 20~30%, quartz 20~30%, calcined kaolin 5~10%, burning talcum 15~20%, aluminium chloride 1 ~5%, frit one 5~10%, air knife soil 5~8%.

3. preparation method according to claim 1, it is characterised in that：Cosmetic the thickness of the layer is 0.2 in the step 2 ~0.25mm, the thickness of transparent suboptical glaze are 0.25~0.3mm, adobe water absorption rate is 1~3%, ceramic tile glacing flatness be 0.2~ 0.3mm。

4. preparation method according to claim 1, it is characterised in that：The painted decoration process includes screen printing, spray One or more decorating methods combination in ink printing, hand painting, pigment used in the screen printing, inkjet printing are inorganic Pigment mixes with stamp-pad ink and ointment, and wherein inorganic pigment, stamp-pad ink, the weight ratio of ointment are 3:5:2, the hand painting institute It is that inorganic pigment mixes with frankincense oil and camphorated oil with pigment, wherein inorganic pigment, frankincense oil, the weight ratio of camphorated oil are 7:1:2。