CN106045577B - Medium temperature snowflake glaze ceramic and its production method - Google Patents
Medium temperature snowflake glaze ceramic and its production method Download PDFInfo
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- CN106045577B CN106045577B CN201610373925.XA CN201610373925A CN106045577B CN 106045577 B CN106045577 B CN 106045577B CN 201610373925 A CN201610373925 A CN 201610373925A CN 106045577 B CN106045577 B CN 106045577B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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Abstract
The present invention relates to ceramic fabrication technique field, be specifically related to a kind of medium temperature snowflake glaze ceramic and its production method.This kind of medium temperature snowflake glaze ceramic, the bottom glaze set gradually outward including green body, by green body, snowflake glaze layer, the component of the snowflake glaze layer includes ceramic whiteware particle, feldspar, cullet, quartz, opacifiers, kaolin, barium carbonate, aluminium oxide.The medium temperature snowflake glaze ceramic prepared using the above method, snowflower particle can be changed according to the specification of ceramic, and even particle distribution, three-dimensional sense are strong；Glaze passes through the cooperation of bottom glaze and snowflake glaze, it can be achieved that bottom glaze is arranged in pairs or groups with the polychrome of snowflake glaze, combined；Snowflake glaze introduces ceramic whiteware particle as raw material, it can be achieved that the recycling of waste material, reduction raw material production cost is low, and furthermore this kind of medium temperature snowflake glaze ceramic simple production process, medium temperature firing, energy conservation and environmental protection, have positive social and economic benefit.
Description
Technical field
The present invention relates to ceramic fabrication technique field, be specifically related to a kind of medium temperature snowflake glaze ceramic and its production
Method.
Background technique
Snowflake glaze is a kind of ceramic surface decoration glaze, and effect is to generate uniform raised particle in ceramic surface,
It in the natural simpleness of ceramic surface generation, is smooth to the touch, visual effect beautiful and generous, is widely used in all kinds of decorative ceramics
On product.In order to improve the quality of snowflake glaze, application publication number is that CN104150966A discloses a kind of snowflake glaze decoration day
Preparation method and its product obtained with ceramics, the formula of blank are talcum, feldspar, talcum powder, quartz, primary and secondary section；
Glaze includes unglazed glaze and high white glaze material, and unglazed glaze is formed using feldspar, quartz, burning talcum, kaolin, zinc oxide,
High white glaze material is using feldspar, quartz, burning talcum, kaolin, barium carbonate composition；Blank and glaze preparation, molding, drying, repaired biscuit,
Applied inside and outside moisturizing, green body mat glaze, grand feu, natural cooling, apply high white glaze outside carcass, medium temperature glaze firing obtains product.
There are many problems in production for existing snowflake glaze porcelain, first is that snowflower particle is as glaze adheres to and makes pottery
On porcelain billet body, therefore distribution of particles is uneven, three-dimensional sense is not strong, and the average grain diameter of raised particle is 1.5-2mm, raised particle without
Method changes with the size of ceramic；Second is that snowflower particle is identical with glaze background color, glaze lacks variation；Third is that institute
The cost of material of use is high, firing temperature is at 1300-1320 DEG C, needs that firing temperature is high, leads to that the production cost increases, energy consumption
Greatly.
Summary of the invention
In order to solve the deficiencies in the prior art, the present invention provides a kind of medium temperature snowflake glaze ceramic and its production side
Method.
To achieve the above object, the present invention provides medium temperature snowflake glaze ceramics, which is characterized in that including green body, by
Bottom glaze that green body is set gradually outward, snowflake glaze layer, the component of the snowflake glaze layer are as follows: 20-30 parts of ceramic whiteware particle, long
15-20 parts of stone, 10-20 parts of cullet, 10-20 parts of quartz, 5-10 parts of opacifiers, 5-10 parts of kaolin, 1-5 parts of barium carbonate, oxygen
Change aluminium 1-5 parts.
Optimization, the partial size for the ceramic whiteware particle that gives up is 1-10mm.
Optimization, the component of snowflake glaze layer is as follows: 23 parts of ceramic whiteware particle, 20 parts of feldspar, 19 parts of cullet, quartz 14 parts,
6 parts of opacifiers, 10 parts of kaolin, 3 parts of barium carbonate, 5 parts of aluminium oxide.
Optimization, the component of snowflake glaze layer is as follows: 30 parts of ceramic whiteware particle, 18 parts of feldspar, 16 parts of cullet, quartz 18 parts,
10 parts of opacifiers, 6 parts of kaolin, 1 part of barium carbonate, 1 part of aluminium oxide.
Optimization, the component of snowflake glaze layer is as follows: 26 parts of ceramic whiteware particle, 19 parts of feldspar, 13 parts of cullet, quartz 15 parts,
7 parts of opacifiers, 8 parts of kaolin, 4 parts of barium carbonate, 4 parts of aluminium oxide.
A kind of production method with medium temperature snowflake glaze ceramic, preparation have described in claim 1-5 any one
Low temperature snowflake glaze ceramic, the specific steps are as follows:
Step 1, the ceramic whiteware waste material during Production of Ceramics is collected, the ceramic whiteware waste material of collection, crushing, sieving obtain white
Porcelain particle；
Step 2, by material rate, feldspar, cullet, quartz, opacifiers, kaolin, barium carbonate, aluminium oxide are mixed also
There is wet ball mill, glaze slip is made；
Step 3, ceramic whiteware particle made from step 1 is mixed with the glaze slip that step 2 obtains；
Step 4, the concentration most 50-60 Baume degrees of low temperature snowflake glaze is adjusted；
Step 5, after ceramic body has made, biscuiting is put into kiln into biscuit；
Step 6, bottom glaze and snowflake glaze are successively applied on biscuit of ceramics；
Step 7, the ceramic body after glazing is put into kiln, is formed by a firing, firing temperature is 1100-1200 DEG C.
Further, in step 1, the partial size of ceramic whiteware particle is 1mm-10mm.
Further, in step 2, when wet ball mill expects: ball: the ratio of water is 1:0.8:1.2.
Further, step 6 moderate snow fancy glaze, which uses, pours glaze or painting glaze mode glazing.
Further, bottom glaze is colored glaze layer.
By the above-mentioned description of this invention it is found that medium temperature snowflake glaze ceramic provided by the invention, snowflower particle can root
It is changed according to the specification of ceramic, even particle distribution, three-dimensional sense are strong；Glaze is matched by bottom glaze and snowflake glaze
It closes, it can be achieved that bottom glaze is arranged in pairs or groups with the polychrome of snowflake glaze, combined；Snowflake glaze introduces ceramic whiteware particle as raw material, can
Realize waste material recycling, reduce raw material production cost it is low, furthermore this kind of medium temperature snowflake glaze ceramic simple production process,
Medium temperature firing, energy conservation and environmental protection, have positive social and economic benefit.
Specific embodiment
Below by way of specific embodiment, the invention will be further described.
The present invention provides medium temperature snowflake glaze ceramic, the bottom glaze that is set gradually outward including green body, by green body,
The component of snowflake glaze layer, the snowflake glaze layer is as follows: 20-30 parts of ceramic whiteware particle, 15-20 parts of feldspar, 10-20 parts of cullet, stone
10-20 parts of English, 5-10 parts of opacifiers, 5-10 parts of kaolin, 1-5 parts of barium carbonate, 1-5 parts of aluminium oxide.
Specific embodiment one:
Medium temperature snowflake glaze ceramic, the bottom glaze set gradually outward including green body, by green body, snowflake glaze layer；
Ground glaze layer position black glaze layer；
The component of snowflake glaze layer is as follows: 23 parts of ceramic whiteware particle, 20 parts of feldspar, 19 parts of cullet, quartzy 14 parts, opacifiers 6
Part, 10 parts of kaolin, 3 parts of barium carbonate, 5 parts of aluminium oxide.
The glazing effect of the medium temperature snowflake glaze ceramic of the present embodiment has the background color of black, and snowflake glaze uses and pours glaze side
Formula glazing, white is uniform-distribution on black background color thinks the general concave-convex particle of snowflake, forms strong color contrast.
Specific embodiment two:
Medium temperature snowflake glaze ceramic, the bottom glaze set gradually outward including green body, by green body, snowflake glaze layer；
Ground glaze layer position white enamel；
The component of snowflake glaze layer is as follows: 30 parts of ceramic whiteware particle, 18 parts of feldspar, 16 parts of cullet, quartzy 18 parts, opacifiers 10
Part, 6 parts of kaolin, 1 part of barium carbonate, 1 part of aluminium oxide.
The glazing effect of the medium temperature snowflake glaze ceramic of the present embodiment has the background color of white, and snowflake glaze uses and pours glaze side
Formula glazing is uniform-distribution with the concave-convex particle as the snowflake of white, white-based color and White snowflake particle phase on white-based color
Mutually fusion.
Specific embodiment three:
Medium temperature snowflake glaze ceramic, the bottom glaze set gradually outward including green body, by green body, snowflake glaze layer；
Ground glaze layer position cyan glaze；
The component of snowflake glaze layer is as follows: 26 parts of ceramic whiteware particle, 19 parts of feldspar, 13 parts of cullet, quartzy 15 parts, opacifiers 7
Part, 8 parts of kaolin, 4 parts of barium carbonate, 4 parts of aluminium oxide.
The glazing effect of the medium temperature snowflake glaze ceramic of the present embodiment has the background color of cyan, and snowflake glaze is using painting glaze side
Formula glazing is dispersed with the snowflake bumps particle of white in the form of sheets on cyan background color, forms the speckle of white, and artistic effect is strong.
Production method with medium temperature snowflake glaze ceramic, prepares described in any one of specific embodiment one to three
The ceramic of low temperature snowflake glaze, the specific steps are as follows:
Step 1, the ceramic whiteware waste material during Production of Ceramics is collected, the ceramic whiteware waste material of collection, crushing, sieving obtain white
Porcelain particle, the partial size of ceramic whiteware particle are followed by ceramic size for 1mm-10mm and are changed；
Step 2, by material rate, feldspar, cullet, quartz, opacifiers, kaolin, barium carbonate, aluminium oxide are mixed also
There is wet ball mill, be made glaze slip, when wet ball mill expects: ball: the ratio of water is 1:0.8:1.2；
Step 3, ceramic whiteware particle made from step 1 is mixed with the glaze slip that step 2 obtains；
Step 4, the concentration most 50-60 Baume degrees of low temperature snowflake glaze is adjusted；
Step 5, after ceramic body has made, biscuiting is put into kiln into biscuit；
Step 6, bottom glaze and snowflake glaze are successively applied on biscuit of ceramics, wherein bottom glaze can pour glaze, leaching glaze
Or the mode glazing of glaze spraying, the glazing by the way of pouring glaze or painting glaze of snowflake glaze, bottom glaze are colored glaze layer；
Step 7, the ceramic body after glazing is put into kiln, is formed by a firing, firing temperature is 1100-1200 DEG C.
Above-mentioned medium temperature snowflake glaze ceramic, snowflower particle can be changed according to the specification of ceramic, distribution of particles
Uniformly, three-dimensional sense is strong；Glaze is by the cooperation of bottom glaze and snowflake glaze, it can be achieved that the polychrome of bottom glaze and snowflake glaze
Collocation, combination；Snowflake glaze introduces ceramic whiteware particle as raw material, it can be achieved that the recycling of waste material, reduces raw material and be produced into
This is low, and furthermore this kind of medium temperature snowflake glaze ceramic simple production process, medium temperature firing, energy conservation and environmental protection, have positive society
And economic benefit.
It above are only a specific embodiment of the invention, but the design concept of the present invention is not limited to this, all utilizations
This design makes a non-material change to the present invention, and should all belong to behavior that violates the scope of protection of the present invention.
Claims (8)
1. a kind of production method with medium temperature snowflake glaze ceramic, it is characterised in that: the medium temperature snowflake glaze ceramic,
The bottom glaze that sets gradually outward including green body, by green body, snowflake glaze layer, the component of the snowflake glaze layer are as follows: ceramic whiteware
Grain 20-30 parts, 15-20 parts of feldspar, 10-20 parts of cullet, 10-20 parts of quartz, 5-10 parts of opacifiers, 5-10 parts of kaolin, carbon
Sour barium 1-5 parts, 1-5 parts of aluminium oxide, specific step is as follows for the production method with medium temperature snowflake glaze ceramic:
Step 1, the ceramic whiteware waste material during Production of Ceramics is collected, by the ceramic whiteware waste material of collection, crushing, sieving, obtains ceramic whiteware
Grain；
Step 2, by material rate, feldspar, cullet, quartz, opacifiers, kaolin, barium carbonate, aluminium oxide are mixed also wet
Glaze slip is made in ball milling；
Step 3, ceramic whiteware particle made from step 1 is mixed with the glaze slip that step 2 obtains；
Step 4, the concentration most 50-60 Baume degrees of low temperature snowflake glaze is adjusted；
Step 5, after ceramic body has made, biscuiting is put into kiln into biscuit；
Step 6, bottom glaze and snowflake glaze are successively applied on biscuit of ceramics；
Step 7, the ceramic body after glazing is put into kiln, is formed by a firing, firing temperature is 1100-1200 DEG C.
2. the production method of medium temperature snowflake glaze ceramic according to claim 1, which is characterized in that the group of snowflake glaze layer
Divide as follows: 23 parts of ceramic whiteware particle, 20 parts of feldspar, 19 parts of cullet, quartzy 14 parts, 6 parts of opacifiers, 10 parts of kaolin, barium carbonate 3
Part, 5 parts of aluminium oxide.
3. the production method of medium temperature snowflake glaze ceramic according to claim 1, which is characterized in that the snowflake glaze layer
Component it is as follows: 30 parts of ceramic whiteware particle, 18 parts of feldspar, 16 parts of cullet, quartzy 18 parts, 10 parts of opacifiers, 6 parts of kaolin, carbon
1 part of sour barium, 1 part of aluminium oxide.
4. the production method of medium temperature snowflake glaze ceramic according to claim 1, which is characterized in that the snowflake glaze layer
Component it is as follows: 26 parts of ceramic whiteware particle, 19 parts of feldspar, 13 parts of cullet, quartzy 15 parts, 7 parts of opacifiers, 8 parts of kaolin, carbonic acid
4 parts of barium, 4 parts of aluminium oxide.
5. the production method of medium temperature snowflake glaze ceramic according to claim 1, it is characterised in that: in the step 1,
The partial size of ceramic whiteware particle is 1mm-10mm.
6. the production method of medium temperature snowflake glaze ceramic according to claim 1, it is characterised in that: in the step 2,
Expect when wet ball mill: ball: the ratio of water is 1:0.8:1.2.
7. the production method of medium temperature snowflake glaze ceramic according to claim 1, it is characterised in that: in the step 6
Snowflake glaze, which uses, pours glaze or painting glaze mode glazing.
8. the production method of medium temperature snowflake glaze ceramic according to claim 1 is it is characterized by: the bottom glaze is
Colored glaze layer.
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| CN106746669A (en) * | 2016-12-28 | 2017-05-31 | 湖南陶润会文化传播有限公司 | Plus the single-layer back of grain answers glaze and preparation method thereof |
| CN108947488B (en) * | 2018-09-17 | 2019-09-24 | 泉州市陶瓷科学技术研究所 | Snow-white porcelain in Dehua and preparation method thereof |
| CN110423142A (en) * | 2019-09-06 | 2019-11-08 | 济源市坤彤陶瓷科技开发有限公司 | A kind of silver figure glaze ceramic process |
| CN111116171A (en) * | 2019-12-31 | 2020-05-08 | 泉州阳光创艺陶瓷股份有限公司 | Antibacterial and mildew-proof ceramic artwork and preparation method thereof |
| CN111499194A (en) * | 2020-04-23 | 2020-08-07 | 潮州市智信新材料科技有限公司 | Preparation method of pearlescent colorful refractive antibacterial ceramic product |
| CN111646821B (en) * | 2020-07-07 | 2023-12-19 | 江西服装学院 | Convex carving ceramic and coloring manufacturing method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101691309A (en) * | 2009-10-16 | 2010-04-07 | 醴陵联合陶瓷制品有限公司 | Preparation method of high-temperature high white ceramic glaze |
| CN103102175A (en) * | 2013-01-22 | 2013-05-15 | 广东尚高科技有限公司 | Self-cleaning glaze and application thereof as well as ceramic sanitary ware |
| CN104150966A (en) * | 2014-08-11 | 2014-11-19 | 景德镇市精业陶瓷有限公司 | Preparation method of snowflake enamel decorative domestic ceramic and manufactured product thereof |
| CN105315015A (en) * | 2014-12-04 | 2016-02-10 | 四川白塔新联兴陶瓷集团有限责任公司 | Preparation method for architectural decoration flambe art ceramic tile |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3034015B2 (en) * | 1990-11-19 | 2000-04-17 | 宮脇グレイズ工業株式会社 | Manufacturing method of ceramic products using colored glaze |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101691309A (en) * | 2009-10-16 | 2010-04-07 | 醴陵联合陶瓷制品有限公司 | Preparation method of high-temperature high white ceramic glaze |
| CN103102175A (en) * | 2013-01-22 | 2013-05-15 | 广东尚高科技有限公司 | Self-cleaning glaze and application thereof as well as ceramic sanitary ware |
| CN104150966A (en) * | 2014-08-11 | 2014-11-19 | 景德镇市精业陶瓷有限公司 | Preparation method of snowflake enamel decorative domestic ceramic and manufactured product thereof |
| CN105315015A (en) * | 2014-12-04 | 2016-02-10 | 四川白塔新联兴陶瓷集团有限责任公司 | Preparation method for architectural decoration flambe art ceramic tile |
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