CN106045577A - Medium-temperature snowflake glaze ceramic and manufacturing method thereof - Google Patents
Medium-temperature snowflake glaze ceramic and manufacturing method thereof Download PDFInfo
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- CN106045577A CN106045577A CN201610373925.XA CN201610373925A CN106045577A CN 106045577 A CN106045577 A CN 106045577A CN 201610373925 A CN201610373925 A CN 201610373925A CN 106045577 A CN106045577 A CN 106045577A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 88
- 241000533950 Leucojum Species 0.000 title claims abstract description 84
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 22
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 18
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 18
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000010453 quartz Substances 0.000 claims abstract description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002245 particle Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 13
- 239000002699 waste material Substances 0.000 claims abstract description 10
- 238000010304 firing Methods 0.000 claims abstract description 9
- 239000008187 granular material Substances 0.000 claims description 31
- 229910052925 anhydrite Inorganic materials 0.000 claims description 17
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 17
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 16
- 239000006063 cullet Substances 0.000 claims description 15
- 239000003605 opacifier Substances 0.000 claims description 15
- 239000000758 substrate Substances 0.000 claims description 14
- 235000015895 biscuits Nutrition 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 239000003643 water by type Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 238000000498 ball milling Methods 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 6
- 238000009826 distribution Methods 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 4
- 238000004064 recycling Methods 0.000 abstract description 3
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000010433 feldspar Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 5
- 235000015256 Chionanthus virginicus Nutrition 0.000 description 4
- 241000234283 Galanthus nivalis Species 0.000 description 4
- 229910052573 porcelain Inorganic materials 0.000 description 4
- 235000012222 talc Nutrition 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- PLXMOAALOJOTIY-FPTXNFDTSA-N Aesculin Natural products OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H]1Oc2cc3C=CC(=O)Oc3cc2O PLXMOAALOJOTIY-FPTXNFDTSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Road Paving Structures (AREA)
Abstract
The invention relates to the technical field of ceramic manufacturing, in particular to a medium-temperature snowflake glaze ceramic and a manufacturing method thereof. The medium-temperature snowflake glaze ceramic comprises a body, a bottom layer glaze and a snowflake glazing layer, wherein the bottom layer glaze and the snowflake glazing layer are sequentially arranged outwards from the body. The snowflake glazing layer is prepared from white ceramic particles, feldspar, waste glass, quartz, an opacifying agent, kaolin, barium carbonate and alumina. According to the medium-temperature snowflake glaze ceramic prepared through the method, snowflake particles can change according to the specifications of the ceramic and are uniform in distribution and high in three-dimensional sense; by means of cooperation of the bottom layer glaze and snowflake glaze of the glazing face, multi-color matching and combining of the bottom layer glaze and the snowflake glaze can be achieved; the white ceramic particles are introduced into the snowflake glaze to serve as a raw material, recycling of the waste can be achieved, and the production cost of the raw material is reduced; in addition, production technology of the medium-temperature snowflake glaze ceramic is simple, medium-temperature firing is carried out, energy is saved, the environment is protected, and social and economic benefits are achieved.
Description
Technical field
The present invention relates to ceramic fabrication technique field, be specifically related to a kind of middle temperature snowflake glaze ceramic and making
Method.
Background technology
Snowflake glaze is a kind of ceramic surface decoration glaze, and its effect is to produce uniform protruding granule at ceramic surface,
Ceramic surface produce natural simpleness, be smooth to the touch, visual effect elegant in appearance, be widely used in all kinds of ornamental pottery
On product.In order to improve the quality of snowflake glaze, application publication number is that CN104150966A discloses a kind of snowflake glaze decoration day
With preparation method and the prepared product thereof of pottery, the formula of its blank is Talcum, Anhydrite, Pulvis Talci, quartz, primary and secondary joint;
Glaze includes unglazed glaze and high white glaze material, and it is unglazed, and glaze uses Anhydrite, quartz, burning Talcum, Kaolin, zinc oxide composition,
High white glaze material uses Anhydrite, quartz, burning Talcum, Kaolin, brium carbonate composition;Prepared by blank and glaze, molding, be dried, repaired biscuit,
Execute inside and outside moisturizing, base substrate and execute high white glaze outside mat glaze, grand feu, natural cooling, carcass, intermediate glaze burns and obtains goods.
There is many problems in existing snowflake glaze porcelain, one is that snowflower particle is as glaze attachment and pottery when making
On porcelain base substrate, therefore distribution of particles is uneven, third dimension is strong, and the mean diameter of protruding granule is 1.5-2mm, protruding granule without
Method changes along with the size of ceramic;Two is that snowflower particle is identical with glaze background color, and glaze lacks change;Three is institute
The cost of material height of employing, firing temperature, at 1300-1320 DEG C, need firing temperature height, cause production cost increase, energy resource consumption
Greatly.
Summary of the invention
In order to solve the deficiencies in the prior art, the invention provides a kind of middle temperature snowflake glaze ceramic and making side
Method.
For achieving the above object, the invention provides middle temperature snowflake glaze ceramic, it is characterised in that include base substrate, by
Bottom glaze that base substrate outwards sets gradually, snowflake glaze layer, the component of described snowflake glaze layer is as follows: ceramic whiteware granule 20-30 part, length
Stone 15-20 part, cullet 10-20 part, quartz 10-20 part, opacifiers 5-10 part, Kaolin 5-10 part, brium carbonate 1-5 part, oxygen
Change aluminum 1-5 part.
Optimizing, the particle diameter of useless ceramic whiteware granule is 1-10mm.
Optimize, the component of snowflake glaze layer is as follows: ceramic whiteware granule 23 parts, Anhydrite 20 parts, cullet 19 parts, quartz 14 parts,
Opacifiers 6 parts, Kaolin 10 parts, brium carbonate 3 parts, aluminium oxide 5 parts.
Optimize, the component of snowflake glaze layer is as follows: ceramic whiteware granule 30 parts, Anhydrite 18 parts, cullet 16 parts, quartz 18 parts,
Opacifiers 10 parts, Kaolin 6 parts, brium carbonate 1 part, aluminium oxide 1 part.
Optimize, the component of snowflake glaze layer is as follows: ceramic whiteware granule 26 parts, Anhydrite 19 parts, cullet 13 parts, quartz 15 parts,
Opacifiers 7 parts, Kaolin 8 parts, brium carbonate 4 parts, aluminium oxide 4 parts.
A kind of manufacture method with middle temperature snowflake glaze ceramic, preparation has described in claim 1-5 any one
The ceramic of low temperature snowflake glaze, specifically comprise the following steps that
Step 1, collects the ceramic whiteware waste material during Production of Ceramics, by the ceramic whiteware waste material of collection, pulverizes, sieves, it is thus achieved that be white
Porcelain granule;
Step 2, by material rate, by Anhydrite, cullet, quartz, opacifiers, Kaolin, brium carbonate, aluminium oxide mixing also
There is wet ball mill, make glaze slip;
Step 3, mixes the glaze slip that the ceramic whiteware granule that step 1 prepares obtains with step 2;
Step 4, the concentration most 50-60 Baume degrees of regulation low temperature snowflake glaze;
Step 5, after ceramic body has made, puts into biscuiting in kiln and becomes biscuit;
Step 6, executes bottom glaze and snowflake glaze on biscuit of ceramics successively;
Step 7, puts in kiln by the ceramic body after glazing, forms by a firing, and firing temperature is 1100-1200 DEG C.
Further, in step 1, the particle diameter of ceramic whiteware granule is 1mm-10mm.
Further, in step 2, expect during wet ball mill: ball: the ratio of water is 1:0.8:1.2.
Further, step 6 moderate snow fancy glaze uses and waters glaze or be coated with glaze mode glazing.
Further, bottom glaze is coloured glaze layer.
From the above-mentioned description of this invention, the middle temperature snowflake glaze ceramic that the present invention provides, snowflower particle can root
Being changed according to the specification of ceramic, even particle distribution, third dimension are strong;Glaze is joined by bottom glaze and snowflake glaze
Close, the polychrome collocation of bottom glaze and snowflake glaze, combination can be realized;Snowflake glaze introduces ceramic whiteware granule as raw material, can
Realize the recycling of waste material, reduce raw material production low cost, in addition this kind of middle temperature snowflake glaze ceramic production technology simply,
Middle temperature is burnt till, energy-conserving and environment-protective, has positive Social and economic benef@.
Detailed description of the invention
Below by way of detailed description of the invention, the invention will be further described.
The invention provides middle temperature snowflake glaze ceramic, the bottom glaze including base substrate, outwards set gradually by base substrate,
Snowflake glaze layer, the component of described snowflake glaze layer is as follows: ceramic whiteware granule 20-30 part, Anhydrite 15-20 part, cullet 10-20 part, stone
English 10-20 part, opacifiers 5-10 part, Kaolin 5-10 part, brium carbonate 1-5 part, aluminium oxide 1-5 part.
Specific embodiment one:
Middle temperature snowflake glaze ceramic, the bottom glaze including base substrate, outwards set gradually by base substrate, snowflake glaze layer;
Ground glaze layer position black glaze layer;
The component of snowflake glaze layer is as follows: ceramic whiteware granule 23 parts, Anhydrite 20 parts, cullet 19 parts, quartz 14 parts, opacifiers 6
Part, Kaolin 10 parts, brium carbonate 3 parts, aluminium oxide 5 parts.
The glazing effect of the middle temperature snowflake glaze ceramic of the present embodiment has the background color of black, and snowflake glaze uses and waters glaze side
Formula glazing, be uniform-distribution with white on black background color thinks the concavo-convex granule that snowflake is general, forms strong color contrast.
Specific embodiment two:
Middle temperature snowflake glaze ceramic, the bottom glaze including base substrate, outwards set gradually by base substrate, snowflake glaze layer;
Ground glaze layer position white enamel;
The component of snowflake glaze layer is as follows: ceramic whiteware granule 30 parts, Anhydrite 18 parts, cullet 16 parts, quartz 18 parts, opacifiers 10
Part, Kaolin 6 parts, brium carbonate 1 part, aluminium oxide 1 part.
The glazing effect of the middle temperature snowflake glaze ceramic of the present embodiment has the background color of white, and snowflake glaze uses and waters glaze side
Formula glazing, is uniform-distribution with the concavo-convex granule as snowflake of white, white-based color and White snowflake granule phase on white-based color
Merge mutually.
Specific embodiment three:
Middle temperature snowflake glaze ceramic, the bottom glaze including base substrate, outwards set gradually by base substrate, snowflake glaze layer;
Ground glaze layer position cyan glaze;
The component of snowflake glaze layer is as follows: ceramic whiteware granule 26 parts, Anhydrite 19 parts, cullet 13 parts, quartz 15 parts, opacifiers 7
Part, Kaolin 8 parts, brium carbonate 4 parts, aluminium oxide 4 parts.
The glazing effect of the middle temperature snowflake glaze ceramic of the present embodiment has the background color of cyan, and snowflake glaze uses and is coated with glaze side
Formula glazing, is dispersed with the concavo-convex granule of snowflake of white on cyan background color in the form of sheets, forms the speckle of white, and artistic effect is strong.
There is the manufacture method of middle temperature snowflake glaze ceramic, prepare in specific embodiment one to three described in any one
The ceramic of low temperature snowflake glaze, specifically comprises the following steps that
Step 1, collects the ceramic whiteware waste material during Production of Ceramics, by the ceramic whiteware waste material of collection, pulverizes, sieves, it is thus achieved that be white
Porcelain granule, the particle diameter of ceramic whiteware granule is that 1mm-10mm followed by ceramic size and is changed;
Step 2, by material rate, by Anhydrite, cullet, quartz, opacifiers, Kaolin, brium carbonate, aluminium oxide mixing also
There is wet ball mill, make glaze slip, expect during wet ball mill: ball: the ratio of water is 1:0.8:1.2;
Step 3, mixes the glaze slip that the ceramic whiteware granule that step 1 prepares obtains with step 2;
Step 4, the concentration most 50-60 Baume degrees of regulation low temperature snowflake glaze;
Step 5, after ceramic body has made, puts into biscuiting in kiln and becomes biscuit;
Step 6, executes bottom glaze and snowflake glaze on biscuit of ceramics successively, and wherein bottom glaze can water glaze, leaching glaze
Or the mode glazing of glaze spraying, snowflake glaze uses and waters glaze or be coated with the mode glazing of glaze, and bottom glaze is coloured glaze layer;
Step 7, puts in kiln by the ceramic body after glazing, forms by a firing, and firing temperature is 1100-1200 DEG C.
Above-mentioned middle temperature snowflake glaze ceramic, snowflower particle can be changed according to the specification of ceramic, distribution of particles
Uniformly, third dimension is strong;Glaze passes through bottom glaze and the cooperation of snowflake glaze, can realize the polychrome of bottom glaze and snowflake glaze
Collocation, combination;Snowflake glaze introduces ceramic whiteware granule as raw material, can realize the recycling of waste material, reduces raw material production and becomes
This is the lowest, in addition this kind of middle temperature snowflake glaze ceramic production technology temperature simple, middle burn till, energy-conserving and environment-protective, there is positive society
And economic benefit.
Above are only the individual detailed description of the invention of the present invention, but the design concept of the present invention is not limited thereto, all utilizations
This design carries out the change of unsubstantiality to the present invention, all should belong to the behavior invading scope.
Claims (10)
- Middle temperature snowflake glaze ceramic, it is characterised in that the bottom glaze that include base substrate, outwards set gradually by base substrate, snow Fancy glaze layer, the component of described snowflake glaze layer is as follows: ceramic whiteware granule 20-30 part, Anhydrite 15-20 part, cullet 10-20 part, quartz 10-20 part, opacifiers 5-10 part, Kaolin 5-10 part, brium carbonate 1-5 part, aluminium oxide 1-5 part.
- Middle temperature snowflake glaze ceramic the most according to claim 1, it is characterised in that the particle diameter of described useless ceramic whiteware granule is 1-10mm。
- Middle temperature snowflake glaze ceramic the most according to claim 1 and 2, it is characterised in that the component of snowflake glaze layer is as follows: Ceramic whiteware granule 23 parts, Anhydrite 20 parts, cullet 19 parts, 14 parts of quartz, opacifiers 6 parts, Kaolin 10 parts, brium carbonate 3 parts, oxidation 5 parts of aluminum.
- Middle temperature snowflake glaze ceramic the most according to claim 1 and 2, it is characterised in that the component of described snowflake glaze layer As follows: ceramic whiteware granule 30 parts, Anhydrite 18 parts, cullet 16 parts, 18 parts of quartz, opacifiers 10 parts, Kaolin 6 parts, brium carbonate 1 Part, aluminium oxide 1 part.
- Middle temperature snowflake glaze ceramic the most according to claim 1 and 2, it is characterised in that the component of described snowflake glaze layer As follows: ceramic whiteware granule 26 parts, Anhydrite 19 parts, cullet 13 parts, quartz 15 parts, opacifiers 7 parts, Kaolin 8 parts, brium carbonate 4 parts, Aluminium oxide 4 parts.
- 6. having a manufacture method for middle temperature snowflake glaze ceramic, preparation has described in claim 1-5 any one The ceramic of low temperature snowflake glaze, specifically comprises the following steps thatStep 1, collects the ceramic whiteware waste material during Production of Ceramics, by the ceramic whiteware waste material of collection, pulverizes, sieves, it is thus achieved that ceramic whiteware Grain;Step 2, by material rate, mixes the wettest by Anhydrite, cullet, quartz, opacifiers, Kaolin, brium carbonate, aluminium oxide Ball milling, makes glaze slip;Step 3, mixes the glaze slip that the ceramic whiteware granule that step 1 prepares obtains with step 2;Step 4, the concentration most 50-60 Baume degrees of regulation low temperature snowflake glaze;Step 5, after ceramic body has made, puts into biscuiting in kiln and becomes biscuit;Step 6, executes bottom glaze and snowflake glaze on biscuit of ceramics successively;Step 7, puts in kiln by the ceramic body after glazing, forms by a firing, and firing temperature is 1100-1200 DEG C.
- The manufacture method of middle temperature snowflake glaze ceramic the most according to claim 6, it is characterised in that: in described step 1, The particle diameter of ceramic whiteware granule is 1mm-10mm.
- The manufacture method of middle temperature snowflake glaze ceramic the most according to claim 6, it is characterised in that: in described step 2, Expect during wet ball mill: ball: the ratio of water is 1:0.8:1.2.
- The manufacture method of middle temperature snowflake glaze ceramic the most according to claim 6, it is characterised in that: in described step 6 Snowflake glaze uses and waters glaze or be coated with glaze mode glazing..
- The manufacture method of middle temperature snowflake glaze ceramic the most according to claim 6 is characterized in that: described bottom glaze is Coloured glaze layer.
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Cited By (6)
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CN106746669A (en) * | 2016-12-28 | 2017-05-31 | 湖南陶润会文化传播有限公司 | Plus the single-layer back of grain answers glaze and preparation method thereof |
CN108947488A (en) * | 2018-09-17 | 2018-12-07 | 泉州市陶瓷科学技术研究所 | Snow-white porcelain in Dehua and preparation method thereof |
CN110423142A (en) * | 2019-09-06 | 2019-11-08 | 济源市坤彤陶瓷科技开发有限公司 | A kind of silver figure glaze ceramic process |
CN111116171A (en) * | 2019-12-31 | 2020-05-08 | 泉州阳光创艺陶瓷股份有限公司 | Antibacterial and mildew-proof ceramic artwork and preparation method thereof |
CN111499194A (en) * | 2020-04-23 | 2020-08-07 | 潮州市智信新材料科技有限公司 | Preparation method of pearlescent colorful refractive antibacterial ceramic product |
CN111646821A (en) * | 2020-07-07 | 2020-09-11 | 江西服装学院 | Embossed ceramic and coloring manufacturing method thereof |
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CN106746669A (en) * | 2016-12-28 | 2017-05-31 | 湖南陶润会文化传播有限公司 | Plus the single-layer back of grain answers glaze and preparation method thereof |
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CN111646821A (en) * | 2020-07-07 | 2020-09-11 | 江西服装学院 | Embossed ceramic and coloring manufacturing method thereof |
CN111646821B (en) * | 2020-07-07 | 2023-12-19 | 江西服装学院 | Convex carving ceramic and coloring manufacturing method thereof |
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