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CN106045577A - Medium-temperature snowflake glaze ceramic and manufacturing method thereof - Google Patents

Medium-temperature snowflake glaze ceramic and manufacturing method thereof Download PDF

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Publication number
CN106045577A
CN106045577A CN201610373925.XA CN201610373925A CN106045577A CN 106045577 A CN106045577 A CN 106045577A CN 201610373925 A CN201610373925 A CN 201610373925A CN 106045577 A CN106045577 A CN 106045577A
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Prior art keywords
glaze
ceramic
snowflake
parts
granule
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Granted
Application number
CN201610373925.XA
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Chinese (zh)
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CN106045577B (en
Inventor
毛录贵
郑金鼎
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Quanzhou Sunshine Creative Ceramics Co Ltd
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Quanzhou Sunshine Creative Ceramics Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Road Paving Structures (AREA)

Abstract

The invention relates to the technical field of ceramic manufacturing, in particular to a medium-temperature snowflake glaze ceramic and a manufacturing method thereof. The medium-temperature snowflake glaze ceramic comprises a body, a bottom layer glaze and a snowflake glazing layer, wherein the bottom layer glaze and the snowflake glazing layer are sequentially arranged outwards from the body. The snowflake glazing layer is prepared from white ceramic particles, feldspar, waste glass, quartz, an opacifying agent, kaolin, barium carbonate and alumina. According to the medium-temperature snowflake glaze ceramic prepared through the method, snowflake particles can change according to the specifications of the ceramic and are uniform in distribution and high in three-dimensional sense; by means of cooperation of the bottom layer glaze and snowflake glaze of the glazing face, multi-color matching and combining of the bottom layer glaze and the snowflake glaze can be achieved; the white ceramic particles are introduced into the snowflake glaze to serve as a raw material, recycling of the waste can be achieved, and the production cost of the raw material is reduced; in addition, production technology of the medium-temperature snowflake glaze ceramic is simple, medium-temperature firing is carried out, energy is saved, the environment is protected, and social and economic benefits are achieved.

Description

Middle temperature snowflake glaze ceramic and manufacture method
Technical field
The present invention relates to ceramic fabrication technique field, be specifically related to a kind of middle temperature snowflake glaze ceramic and making Method.
Background technology
Snowflake glaze is a kind of ceramic surface decoration glaze, and its effect is to produce uniform protruding granule at ceramic surface, Ceramic surface produce natural simpleness, be smooth to the touch, visual effect elegant in appearance, be widely used in all kinds of ornamental pottery On product.In order to improve the quality of snowflake glaze, application publication number is that CN104150966A discloses a kind of snowflake glaze decoration day With preparation method and the prepared product thereof of pottery, the formula of its blank is Talcum, Anhydrite, Pulvis Talci, quartz, primary and secondary joint; Glaze includes unglazed glaze and high white glaze material, and it is unglazed, and glaze uses Anhydrite, quartz, burning Talcum, Kaolin, zinc oxide composition, High white glaze material uses Anhydrite, quartz, burning Talcum, Kaolin, brium carbonate composition;Prepared by blank and glaze, molding, be dried, repaired biscuit, Execute inside and outside moisturizing, base substrate and execute high white glaze outside mat glaze, grand feu, natural cooling, carcass, intermediate glaze burns and obtains goods.
There is many problems in existing snowflake glaze porcelain, one is that snowflower particle is as glaze attachment and pottery when making On porcelain base substrate, therefore distribution of particles is uneven, third dimension is strong, and the mean diameter of protruding granule is 1.5-2mm, protruding granule without Method changes along with the size of ceramic;Two is that snowflower particle is identical with glaze background color, and glaze lacks change;Three is institute The cost of material height of employing, firing temperature, at 1300-1320 DEG C, need firing temperature height, cause production cost increase, energy resource consumption Greatly.
Summary of the invention
In order to solve the deficiencies in the prior art, the invention provides a kind of middle temperature snowflake glaze ceramic and making side Method.
For achieving the above object, the invention provides middle temperature snowflake glaze ceramic, it is characterised in that include base substrate, by Bottom glaze that base substrate outwards sets gradually, snowflake glaze layer, the component of described snowflake glaze layer is as follows: ceramic whiteware granule 20-30 part, length Stone 15-20 part, cullet 10-20 part, quartz 10-20 part, opacifiers 5-10 part, Kaolin 5-10 part, brium carbonate 1-5 part, oxygen Change aluminum 1-5 part.
Optimizing, the particle diameter of useless ceramic whiteware granule is 1-10mm.
Optimize, the component of snowflake glaze layer is as follows: ceramic whiteware granule 23 parts, Anhydrite 20 parts, cullet 19 parts, quartz 14 parts, Opacifiers 6 parts, Kaolin 10 parts, brium carbonate 3 parts, aluminium oxide 5 parts.
Optimize, the component of snowflake glaze layer is as follows: ceramic whiteware granule 30 parts, Anhydrite 18 parts, cullet 16 parts, quartz 18 parts, Opacifiers 10 parts, Kaolin 6 parts, brium carbonate 1 part, aluminium oxide 1 part.
Optimize, the component of snowflake glaze layer is as follows: ceramic whiteware granule 26 parts, Anhydrite 19 parts, cullet 13 parts, quartz 15 parts, Opacifiers 7 parts, Kaolin 8 parts, brium carbonate 4 parts, aluminium oxide 4 parts.
A kind of manufacture method with middle temperature snowflake glaze ceramic, preparation has described in claim 1-5 any one The ceramic of low temperature snowflake glaze, specifically comprise the following steps that
Step 1, collects the ceramic whiteware waste material during Production of Ceramics, by the ceramic whiteware waste material of collection, pulverizes, sieves, it is thus achieved that be white Porcelain granule;
Step 2, by material rate, by Anhydrite, cullet, quartz, opacifiers, Kaolin, brium carbonate, aluminium oxide mixing also There is wet ball mill, make glaze slip;
Step 3, mixes the glaze slip that the ceramic whiteware granule that step 1 prepares obtains with step 2;
Step 4, the concentration most 50-60 Baume degrees of regulation low temperature snowflake glaze;
Step 5, after ceramic body has made, puts into biscuiting in kiln and becomes biscuit;
Step 6, executes bottom glaze and snowflake glaze on biscuit of ceramics successively;
Step 7, puts in kiln by the ceramic body after glazing, forms by a firing, and firing temperature is 1100-1200 DEG C.
Further, in step 1, the particle diameter of ceramic whiteware granule is 1mm-10mm.
Further, in step 2, expect during wet ball mill: ball: the ratio of water is 1:0.8:1.2.
Further, step 6 moderate snow fancy glaze uses and waters glaze or be coated with glaze mode glazing.
Further, bottom glaze is coloured glaze layer.
From the above-mentioned description of this invention, the middle temperature snowflake glaze ceramic that the present invention provides, snowflower particle can root Being changed according to the specification of ceramic, even particle distribution, third dimension are strong;Glaze is joined by bottom glaze and snowflake glaze Close, the polychrome collocation of bottom glaze and snowflake glaze, combination can be realized;Snowflake glaze introduces ceramic whiteware granule as raw material, can Realize the recycling of waste material, reduce raw material production low cost, in addition this kind of middle temperature snowflake glaze ceramic production technology simply, Middle temperature is burnt till, energy-conserving and environment-protective, has positive Social and economic benef@.
Detailed description of the invention
Below by way of detailed description of the invention, the invention will be further described.
The invention provides middle temperature snowflake glaze ceramic, the bottom glaze including base substrate, outwards set gradually by base substrate, Snowflake glaze layer, the component of described snowflake glaze layer is as follows: ceramic whiteware granule 20-30 part, Anhydrite 15-20 part, cullet 10-20 part, stone English 10-20 part, opacifiers 5-10 part, Kaolin 5-10 part, brium carbonate 1-5 part, aluminium oxide 1-5 part.
Specific embodiment one:
Middle temperature snowflake glaze ceramic, the bottom glaze including base substrate, outwards set gradually by base substrate, snowflake glaze layer;
Ground glaze layer position black glaze layer;
The component of snowflake glaze layer is as follows: ceramic whiteware granule 23 parts, Anhydrite 20 parts, cullet 19 parts, quartz 14 parts, opacifiers 6 Part, Kaolin 10 parts, brium carbonate 3 parts, aluminium oxide 5 parts.
The glazing effect of the middle temperature snowflake glaze ceramic of the present embodiment has the background color of black, and snowflake glaze uses and waters glaze side Formula glazing, be uniform-distribution with white on black background color thinks the concavo-convex granule that snowflake is general, forms strong color contrast.
Specific embodiment two:
Middle temperature snowflake glaze ceramic, the bottom glaze including base substrate, outwards set gradually by base substrate, snowflake glaze layer;
Ground glaze layer position white enamel;
The component of snowflake glaze layer is as follows: ceramic whiteware granule 30 parts, Anhydrite 18 parts, cullet 16 parts, quartz 18 parts, opacifiers 10 Part, Kaolin 6 parts, brium carbonate 1 part, aluminium oxide 1 part.
The glazing effect of the middle temperature snowflake glaze ceramic of the present embodiment has the background color of white, and snowflake glaze uses and waters glaze side Formula glazing, is uniform-distribution with the concavo-convex granule as snowflake of white, white-based color and White snowflake granule phase on white-based color Merge mutually.
Specific embodiment three:
Middle temperature snowflake glaze ceramic, the bottom glaze including base substrate, outwards set gradually by base substrate, snowflake glaze layer;
Ground glaze layer position cyan glaze;
The component of snowflake glaze layer is as follows: ceramic whiteware granule 26 parts, Anhydrite 19 parts, cullet 13 parts, quartz 15 parts, opacifiers 7 Part, Kaolin 8 parts, brium carbonate 4 parts, aluminium oxide 4 parts.
The glazing effect of the middle temperature snowflake glaze ceramic of the present embodiment has the background color of cyan, and snowflake glaze uses and is coated with glaze side Formula glazing, is dispersed with the concavo-convex granule of snowflake of white on cyan background color in the form of sheets, forms the speckle of white, and artistic effect is strong.
There is the manufacture method of middle temperature snowflake glaze ceramic, prepare in specific embodiment one to three described in any one The ceramic of low temperature snowflake glaze, specifically comprises the following steps that
Step 1, collects the ceramic whiteware waste material during Production of Ceramics, by the ceramic whiteware waste material of collection, pulverizes, sieves, it is thus achieved that be white Porcelain granule, the particle diameter of ceramic whiteware granule is that 1mm-10mm followed by ceramic size and is changed;
Step 2, by material rate, by Anhydrite, cullet, quartz, opacifiers, Kaolin, brium carbonate, aluminium oxide mixing also There is wet ball mill, make glaze slip, expect during wet ball mill: ball: the ratio of water is 1:0.8:1.2;
Step 3, mixes the glaze slip that the ceramic whiteware granule that step 1 prepares obtains with step 2;
Step 4, the concentration most 50-60 Baume degrees of regulation low temperature snowflake glaze;
Step 5, after ceramic body has made, puts into biscuiting in kiln and becomes biscuit;
Step 6, executes bottom glaze and snowflake glaze on biscuit of ceramics successively, and wherein bottom glaze can water glaze, leaching glaze Or the mode glazing of glaze spraying, snowflake glaze uses and waters glaze or be coated with the mode glazing of glaze, and bottom glaze is coloured glaze layer;
Step 7, puts in kiln by the ceramic body after glazing, forms by a firing, and firing temperature is 1100-1200 DEG C.
Above-mentioned middle temperature snowflake glaze ceramic, snowflower particle can be changed according to the specification of ceramic, distribution of particles Uniformly, third dimension is strong;Glaze passes through bottom glaze and the cooperation of snowflake glaze, can realize the polychrome of bottom glaze and snowflake glaze Collocation, combination;Snowflake glaze introduces ceramic whiteware granule as raw material, can realize the recycling of waste material, reduces raw material production and becomes This is the lowest, in addition this kind of middle temperature snowflake glaze ceramic production technology temperature simple, middle burn till, energy-conserving and environment-protective, there is positive society And economic benefit.
Above are only the individual detailed description of the invention of the present invention, but the design concept of the present invention is not limited thereto, all utilizations This design carries out the change of unsubstantiality to the present invention, all should belong to the behavior invading scope.

Claims (10)

  1. Middle temperature snowflake glaze ceramic, it is characterised in that the bottom glaze that include base substrate, outwards set gradually by base substrate, snow Fancy glaze layer, the component of described snowflake glaze layer is as follows: ceramic whiteware granule 20-30 part, Anhydrite 15-20 part, cullet 10-20 part, quartz 10-20 part, opacifiers 5-10 part, Kaolin 5-10 part, brium carbonate 1-5 part, aluminium oxide 1-5 part.
  2. Middle temperature snowflake glaze ceramic the most according to claim 1, it is characterised in that the particle diameter of described useless ceramic whiteware granule is 1-10mm。
  3. Middle temperature snowflake glaze ceramic the most according to claim 1 and 2, it is characterised in that the component of snowflake glaze layer is as follows: Ceramic whiteware granule 23 parts, Anhydrite 20 parts, cullet 19 parts, 14 parts of quartz, opacifiers 6 parts, Kaolin 10 parts, brium carbonate 3 parts, oxidation 5 parts of aluminum.
  4. Middle temperature snowflake glaze ceramic the most according to claim 1 and 2, it is characterised in that the component of described snowflake glaze layer As follows: ceramic whiteware granule 30 parts, Anhydrite 18 parts, cullet 16 parts, 18 parts of quartz, opacifiers 10 parts, Kaolin 6 parts, brium carbonate 1 Part, aluminium oxide 1 part.
  5. Middle temperature snowflake glaze ceramic the most according to claim 1 and 2, it is characterised in that the component of described snowflake glaze layer As follows: ceramic whiteware granule 26 parts, Anhydrite 19 parts, cullet 13 parts, quartz 15 parts, opacifiers 7 parts, Kaolin 8 parts, brium carbonate 4 parts, Aluminium oxide 4 parts.
  6. 6. having a manufacture method for middle temperature snowflake glaze ceramic, preparation has described in claim 1-5 any one The ceramic of low temperature snowflake glaze, specifically comprises the following steps that
    Step 1, collects the ceramic whiteware waste material during Production of Ceramics, by the ceramic whiteware waste material of collection, pulverizes, sieves, it is thus achieved that ceramic whiteware Grain;
    Step 2, by material rate, mixes the wettest by Anhydrite, cullet, quartz, opacifiers, Kaolin, brium carbonate, aluminium oxide Ball milling, makes glaze slip;
    Step 3, mixes the glaze slip that the ceramic whiteware granule that step 1 prepares obtains with step 2;
    Step 4, the concentration most 50-60 Baume degrees of regulation low temperature snowflake glaze;
    Step 5, after ceramic body has made, puts into biscuiting in kiln and becomes biscuit;
    Step 6, executes bottom glaze and snowflake glaze on biscuit of ceramics successively;
    Step 7, puts in kiln by the ceramic body after glazing, forms by a firing, and firing temperature is 1100-1200 DEG C.
  7. The manufacture method of middle temperature snowflake glaze ceramic the most according to claim 6, it is characterised in that: in described step 1, The particle diameter of ceramic whiteware granule is 1mm-10mm.
  8. The manufacture method of middle temperature snowflake glaze ceramic the most according to claim 6, it is characterised in that: in described step 2, Expect during wet ball mill: ball: the ratio of water is 1:0.8:1.2.
  9. The manufacture method of middle temperature snowflake glaze ceramic the most according to claim 6, it is characterised in that: in described step 6 Snowflake glaze uses and waters glaze or be coated with glaze mode glazing..
  10. The manufacture method of middle temperature snowflake glaze ceramic the most according to claim 6 is characterized in that: described bottom glaze is Coloured glaze layer.
CN201610373925.XA 2016-05-30 2016-05-30 Medium temperature snowflake glaze ceramic and its production method Expired - Fee Related CN106045577B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106746669A (en) * 2016-12-28 2017-05-31 湖南陶润会文化传播有限公司 Plus the single-layer back of grain answers glaze and preparation method thereof
CN108947488A (en) * 2018-09-17 2018-12-07 泉州市陶瓷科学技术研究所 Snow-white porcelain in Dehua and preparation method thereof
CN110423142A (en) * 2019-09-06 2019-11-08 济源市坤彤陶瓷科技开发有限公司 A kind of silver figure glaze ceramic process
CN111116171A (en) * 2019-12-31 2020-05-08 泉州阳光创艺陶瓷股份有限公司 Antibacterial and mildew-proof ceramic artwork and preparation method thereof
CN111499194A (en) * 2020-04-23 2020-08-07 潮州市智信新材料科技有限公司 Preparation method of pearlescent colorful refractive antibacterial ceramic product
CN111646821A (en) * 2020-07-07 2020-09-11 江西服装学院 Embossed ceramic and coloring manufacturing method thereof

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CN103102175A (en) * 2013-01-22 2013-05-15 广东尚高科技有限公司 Self-cleaning glaze and application thereof as well as ceramic sanitary ware
CN104150966A (en) * 2014-08-11 2014-11-19 景德镇市精业陶瓷有限公司 Preparation method of snowflake enamel decorative domestic ceramic and manufactured product thereof
CN105315015A (en) * 2014-12-04 2016-02-10 四川白塔新联兴陶瓷集团有限责任公司 Preparation method for architectural decoration flambe art ceramic tile

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106746669A (en) * 2016-12-28 2017-05-31 湖南陶润会文化传播有限公司 Plus the single-layer back of grain answers glaze and preparation method thereof
CN108947488A (en) * 2018-09-17 2018-12-07 泉州市陶瓷科学技术研究所 Snow-white porcelain in Dehua and preparation method thereof
CN110423142A (en) * 2019-09-06 2019-11-08 济源市坤彤陶瓷科技开发有限公司 A kind of silver figure glaze ceramic process
CN111116171A (en) * 2019-12-31 2020-05-08 泉州阳光创艺陶瓷股份有限公司 Antibacterial and mildew-proof ceramic artwork and preparation method thereof
CN111499194A (en) * 2020-04-23 2020-08-07 潮州市智信新材料科技有限公司 Preparation method of pearlescent colorful refractive antibacterial ceramic product
CN111646821A (en) * 2020-07-07 2020-09-11 江西服装学院 Embossed ceramic and coloring manufacturing method thereof
CN111646821B (en) * 2020-07-07 2023-12-19 江西服装学院 Convex carving ceramic and coloring manufacturing method thereof

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