CN109456035B - Ceramic tile with bright and matte effect and preparation method thereof - Google Patents
Ceramic tile with bright and matte effect and preparation method thereof Download PDFInfo
- Publication number
- CN109456035B CN109456035B CN201811514663.XA CN201811514663A CN109456035B CN 109456035 B CN109456035 B CN 109456035B CN 201811514663 A CN201811514663 A CN 201811514663A CN 109456035 B CN109456035 B CN 109456035B
- Authority
- CN
- China
- Prior art keywords
- bright
- matte
- ceramic
- layer
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 98
- 230000000694 effects Effects 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000003292 glue Substances 0.000 claims abstract description 44
- 238000007639 printing Methods 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 17
- 238000001035 drying Methods 0.000 claims abstract description 12
- 238000007641 inkjet printing Methods 0.000 claims abstract description 8
- 238000005245 sintering Methods 0.000 claims abstract description 7
- 238000005507 spraying Methods 0.000 claims abstract description 6
- 230000007480 spreading Effects 0.000 claims abstract description 6
- 238000003892 spreading Methods 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims description 31
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 239000004830 Super Glue Substances 0.000 claims description 5
- FGBJXOREULPLGL-UHFFFAOYSA-N ethyl cyanoacrylate Chemical compound CCOC(=O)C(=C)C#N FGBJXOREULPLGL-UHFFFAOYSA-N 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims 2
- 238000010304 firing Methods 0.000 claims 1
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 230000006872 improvement Effects 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 229910052681 coesite Inorganic materials 0.000 description 4
- 229910052593 corundum Inorganic materials 0.000 description 4
- 229910052906 cristobalite Inorganic materials 0.000 description 4
- 238000005034 decoration Methods 0.000 description 4
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 229910052682 stishovite Inorganic materials 0.000 description 4
- 229910052905 tridymite Inorganic materials 0.000 description 4
- 229910001845 yogo sapphire Inorganic materials 0.000 description 4
- 230000008569 process Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000003682 vanadium compounds Chemical class 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 208000003464 asthenopia Diseases 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Finishing Walls (AREA)
Abstract
The invention discloses a preparation method of a ceramic tile with a bright and matte effect, which comprises the following process steps: 1) spreading a cover glaze on the ceramic tile green body to obtain a cover glaze layer; 2) printing decorative pattern textures on the surface glaze layer by ink jet printing, and drying to obtain a decorative pattern texture layer; 3) printing the low-temperature ceramic glue with the pattern texture on the decorative pattern texture layer in an ink-jet manner to obtain a low-temperature ceramic glue layer; 4) spraying bright matte dry grain glaze on the low-temperature ceramic glue layer, and drying to obtain a bright matte dry grain layer; 5) and sintering at high temperature to obtain the finished product. According to the invention, through the synergistic effect of the low-temperature ceramic glue and the bright and matte dry grain glaze, the fault tolerance rate of the decorative pattern texture and the glue pattern texture is high, the effect of combining brightness and matte on the decorative pattern texture layer is realized, and the effect of combining brightness and matte on the bright and matte dry grain layer on the surface of the ceramic tile is also realized, so that the controllability of the brightness and matte effect of the whole ceramic tile is strong, and the definition of the decorative pattern is good. The invention also discloses a ceramic tile with a bright and matte effect, which is prepared by the method.
Description
Technical Field
The invention relates to the field of architectural ceramics, in particular to a ceramic tile with a bright and matte effect.
Background
The building ceramic tile is an unavailable ceramic decorative material in the current home decoration, and has a plurality of varieties, such as polished tiles, glazed tiles, antique tiles, ceramic tiles and the like. The introduction of the ink-jet printing technology greatly enriches the colors and designs on the surface of the ceramic tile, and enables the glazed tile to be popular in the market at any time, but the introduction of the ink-jet printing technology makes the homogenization of the decorative effect on the surface of the ceramic tile more severe, so that the visual fatigue is easily caused, and personalized decorative products such as ink-jet bleeding products, sinking glaze, full-body tiles and the like gradually appear. On the other hand, ceramic tiles with bright, matte or bright and matte decoration effects are also produced.
The traditional process of the ceramic tile with the bright and matte effect only combines bright and matte dry particles, and only realizes the combination of the bright and matte on the surface of the ceramic tile, namely, the effect of combining the bright and matte on the glaze surface can be realized. The sinking glaze can also realize the effect of combining the brightness and the matte, the basic process is to print the sinking functional ink on the ceramic tile by ink jet, the sinking functional ink contains a vanadium compound, on one hand, the sinking functional ink can reduce the surface tension and the viscosity of the glaze, on the other hand, under the high temperature environment, the vanadium compound can be decomposed to generate gas to continuously break through the glaze surface to form local sinking so as to realize the brightness effect of the sinking area. However, the bright and matte decoration effects obtained by the above methods have the disadvantages of poor definition of the decoration pattern and poor controllability of the bright and matte effects.
Disclosure of Invention
The invention aims to provide a method for preparing ceramic tiles with bright and matte effects, aiming at the defects of the prior art.
The technical scheme adopted by the invention is as follows: a preparation method of a ceramic tile with a bright and matte effect comprises the following process steps:
1) spreading a cover glaze on the ceramic tile green body to obtain a cover glaze layer;
2) printing decorative pattern textures on the surface glaze layer by ink jet printing, and drying to obtain a decorative pattern texture layer;
3) printing the low-temperature ceramic glue with the pattern texture on the decorative pattern texture layer in an ink-jet manner to obtain a low-temperature ceramic glue layer;
4) spraying bright matte dry grain glaze on the low-temperature ceramic glue layer, and drying to obtain a bright matte dry grain layer;
5) and sintering at high temperature to obtain the finished product.
Specifically, the pattern texture of the low-temperature ceramic glue layer can be overlapped with the pattern texture of the decorative pattern texture layer, and can also be used as a supplement of the pattern texture of the decorative pattern texture layer, so that the width of the bright effect of the low-temperature ceramic glue layer is controllable, the width of the low-temperature ceramic glue layer is changed along with the width of the low-temperature ceramic glue layer, and the low-temperature ceramic glue layer can be wide or narrow, and can be wide to patterns and thin to line parts.
As a further improvement of the scheme, the low-temperature ceramic glue in the step 3) is composed of α -ethyl cyanoacrylate adhesive and inorganic ceramic fluxing agent, and the solid content of the low-temperature ceramic glue is 5-15%.
In the invention, due to the existence of the low-temperature ceramic glue, when the bright matte dry grains in the bright matte dry grain glaze are adhered to the layer of low-temperature ceramic glue, the interface of the dry grains is melted under the action of the inorganic ceramic fluxing agent but the dry grains cannot be completely melted, so that the bright and glossy effect of partial melting of the dry grains can be generated at the interface, and the decorative pattern grains which are not covered by the low-temperature ceramic glue layer are the glossy effect, thereby realizing the bright and matte combined artistic effect of the decorative pattern grains on the glaze layer.
As a further improvement of the above scheme, the chemical composition of the inorganic ceramic fluxing agent is 50% SiO24% of Al2O332% of B2O33% of Li2O, 13% of Na2O, 6% of K2O and 3% CaO. In particular, the definition of the chemical components of the inorganic ceramic fluxing agent is beneficial to further improving the melting effect of the interface of the low-temperature ceramic glue and the bright matte dry-particle glaze.
As a further improvement of the scheme, the melting temperature of the low-temperature ceramic glue in the step 3) is 900-1100 ℃.
As a further improvement of the scheme, in the step 4), the bright matte dry-particle glaze is prepared by mixing bright matte dry particles and ceramic printing oil according to a mass ratio of 1: (1-1.2).
As a further improvement of the scheme, the grain diameter of the bright and matte dry grains is within the range of 100-200 meshes, and the pattern grain definition of the decorative pattern grain layer under the bright and matte effect is favorably improved.
As a further improvement of the scheme, the bright and matte dry particles are prepared by mixing bright and matte dry particles in a mass ratio of 1: (1-1.5).
As a further improvement of the scheme, the temperature of the high-temperature sintering in the step 5) is 1200-1250 ℃.
The invention also aims to provide a ceramic tile with a bright and matte effect, which is prepared by the preparation method.
The invention has the beneficial effects that: according to the invention, through the synergistic effect of the low-temperature ceramic glue and the bright and matte dry grain glaze, the fault tolerance rate of the decorative pattern texture and the glue pattern texture is high, the effect of combining brightness and matte on the decorative pattern texture layer is realized, and the effect of combining brightness and matte on the bright and matte dry grain layer on the surface of the ceramic tile is also realized, so that the controllability of the brightness and matte effect of the whole ceramic tile is strong, and the definition of the decorative pattern is good.
Detailed Description
The present invention is specifically described below with reference to examples in order to facilitate understanding of the present invention by those skilled in the art. It should be particularly noted that the examples are given solely for the purpose of illustration and are not to be construed as limitations on the scope of the invention, as non-essential improvements and modifications to the invention may occur to those skilled in the art, which fall within the scope of the invention as defined by the appended claims. Meanwhile, the raw materials mentioned below are not specified in detail and are all commercial products; the process steps or preparation methods not mentioned in detail are all process steps or preparation methods known to the person skilled in the art.
Example 1
A preparation method of a ceramic tile with a bright and matte effect comprises the following process steps:
1) spreading a cover glaze on the ceramic tile green body to obtain a cover glaze layer;
2) printing decorative pattern textures on the surface glaze layer by ink jet printing, and drying to obtain a decorative pattern texture layer;
3) printing low-temperature ceramic glue with pattern textures and with the melting temperature of 900-1100 ℃ on the decorative pattern texture layer in an ink-jet mode to obtain a low-temperature ceramic glue layer;
4) taking the bright dry particles and the matte dry particles with the particle size range of 100-150 meshes, mixing the bright dry particles and the matte dry particles according to the mass ratio of 1:1, and then adding ceramic printing oil, wherein the mass ratio of the ceramic printing oil to the bright matte dry particles is 1:1, so as to obtain bright matte dry particle glaze;
5) spraying bright matte dry grain glaze on the low-temperature ceramic glue layer, and drying to obtain a bright matte dry grain layer;
6) sintering at 1200 ℃ to obtain the finished product of the example 1.
The low-temperature ceramic glue consists of α -ethyl cyanoacrylate adhesive and inorganic ceramic fluxing agent, the solid content of the low-temperature ceramic glue is 5%, and the chemical composition of the inorganic ceramic fluxing agent is 50% of SiO24% of Al2O332% of B2O33% of Li2O, 13% of Na2O, 6% of K2O and 3% CaO.
Example 2
A preparation method of a ceramic tile with a bright and matte effect comprises the following process steps:
1) spreading a cover glaze on the ceramic tile green body to obtain a cover glaze layer;
2) printing decorative pattern textures on the surface glaze layer by ink jet printing, and drying to obtain a decorative pattern texture layer;
3) printing low-temperature ceramic glue with pattern textures and with the melting temperature of 1050-1100 ℃ on the decorative pattern texture layer in an ink-jet mode to obtain a low-temperature ceramic glue layer;
4) taking the bright dry particles and the matte dry particles with the particle size range of 150-200 meshes, mixing the bright dry particles and the matte dry particles according to the mass ratio of 1:1.5, and then adding ceramic printing oil, wherein the mass ratio of the ceramic printing oil to the bright matte dry particles is 1:1.2, so as to obtain bright matte dry particle glaze;
5) spraying bright matte dry grain glaze on the low-temperature ceramic glue layer, and drying to obtain a bright matte dry grain layer;
6) and sintering at 1250 ℃ to obtain the finished product of the example 2.
The low-temperature ceramic glue consists of α -ethyl cyanoacrylate adhesive and inorganic ceramic fluxing agent, the solid content of the glue is 15%, and the chemical composition of the inorganic ceramic fluxing agent is 50% of SiO24% of Al2O332% of B2O33% of Li2O, 13% of Na2O, 6% of K2O and 3% CaO.
Example 3
A preparation method of a ceramic tile with a bright and matte effect comprises the following process steps:
1) spreading a cover glaze on the ceramic tile green body to obtain a cover glaze layer;
2) printing decorative pattern textures on the surface glaze layer by ink jet printing, and drying to obtain a decorative pattern texture layer;
3) printing low-temperature ceramic glue with pattern textures on the decorative pattern texture layer in an ink-jet mode, wherein the melting temperature of the low-temperature ceramic glue is 950-1100 ℃, and a low-temperature ceramic glue layer is obtained;
4) taking bright dry particles and matte dry particles with the particle size range of 100-200 meshes, mixing the bright dry particles and the matte dry particles according to the mass ratio of 1:1.2, and then adding ceramic printing oil, wherein the mass ratio of the ceramic printing oil to the bright matte dry particles is 1:1.1, so as to obtain bright matte dry particle glaze;
5) spraying bright matte dry grain glaze on the low-temperature ceramic glue layer, and drying to obtain a bright matte dry grain layer;
6) and sintering at 1230 ℃ to obtain the finished product of the example 3.
The low-temperature ceramic glue consists of α -ethyl cyanoacrylate adhesive and inorganic ceramic fluxing agent, the solid content of the low-temperature ceramic glue is 10%, and the chemical composition of the inorganic ceramic fluxing agent is 50% of SiO24% of Al2O332% of B2O33% of Li2O, 13% of Na2O, 6% of K2O and 3% CaO.
The above embodiments are preferred embodiments of the present invention, and all similar processes and equivalent variations to those of the present invention should fall within the scope of the present invention.
Claims (7)
1. A preparation method of a ceramic tile with a bright and matte effect is characterized by comprising the following process steps:
1) spreading a cover glaze on the ceramic tile green body to obtain a cover glaze layer;
2) printing decorative pattern textures on the surface glaze layer by ink jet printing, and drying to obtain a decorative pattern texture layer;
3) printing the low-temperature ceramic glue with the pattern texture on the decorative pattern texture layer in an ink-jet manner to obtain a low-temperature ceramic glue layer;
4) spraying bright matte dry grain glaze on the low-temperature ceramic glue layer, and drying to obtain a bright matte dry grain layer;
5) firing at high temperature to obtain a finished product;
the low-temperature ceramic glue in the step 3) consists of α -ethyl cyanoacrylate adhesive and inorganic ceramic fluxing agent, and the solid content of the low-temperature ceramic glue is 5-15%.
2. The method for preparing ceramic tiles with bright and matte effects as claimed in claim 1, wherein: the melting temperature of the low-temperature ceramic glue in the step 3) is 900-1100 ℃.
3. The method for preparing ceramic tiles with bright and matte effects as claimed in claim 1, wherein: the bright matte dry grain glaze in the step 4) is prepared from bright matte dry grains and ceramic printing oil according to the mass ratio of 1: (1-1.2).
4. A method for producing ceramic tiles with a glossy and matte effect as claimed in claim 3, characterized in that: the particle size of the bright and matte dry particles is within the range of 100-200 meshes.
5. A method for producing ceramic tiles with a glossy and matte effect as claimed in claim 3, characterized in that: the bright and matte dry particles are prepared from bright and matte dry particles according to the mass ratio of 1: (1-1.5).
6. The method for preparing ceramic tiles with bright and matte effects as claimed in claim 1, wherein: the temperature of the high-temperature sintering in the step 5) is 1200-1250 ℃.
7. A ceramic tile with a bright and matte effect, which is prepared by the preparation method of any one of claims 1 to 6.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811514663.XA CN109456035B (en) | 2018-12-11 | 2018-12-11 | Ceramic tile with bright and matte effect and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811514663.XA CN109456035B (en) | 2018-12-11 | 2018-12-11 | Ceramic tile with bright and matte effect and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109456035A CN109456035A (en) | 2019-03-12 |
| CN109456035B true CN109456035B (en) | 2020-06-16 |
Family
ID=65613054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811514663.XA Active CN109456035B (en) | 2018-12-11 | 2018-12-11 | Ceramic tile with bright and matte effect and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109456035B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110128172B (en) * | 2019-04-28 | 2022-02-08 | 东莞市唯美陶瓷工业园有限公司 | Method for improving surface moisture retention performance of ceramic tile green body and ceramic tile prepared by method |
| CN110357428A (en) * | 2019-08-09 | 2019-10-22 | 东莞市唯美陶瓷工业园有限公司 | A kind of preparation method and Ceramic Tiles of the controllable Ceramic Tiles of glaze glossiness |
| CN110668846A (en) * | 2019-10-11 | 2020-01-10 | 山东狮王陶瓷有限公司 | Preparation process of matte wear-resistant dry particle brick |
| CN111499201A (en) * | 2020-06-17 | 2020-08-07 | 佛山东华盛昌新材料有限公司 | Low-temperature eutectic ink, preparation method thereof and preparation method of ceramic tile thereof |
| CN118755310B (en) * | 2024-08-21 | 2024-11-08 | 新明珠集团股份有限公司 | Digital ink composition, ceramic tile with mold effect and preparation method of ceramic tile |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2797086Y (en) * | 2005-06-27 | 2006-07-19 | 汕头市东田转印有限公司 | Glass product having bright dumb decorative picture and writing on surface |
| CN106542812B (en) * | 2016-09-26 | 2019-06-04 | 广东协进陶瓷有限公司 | A kind of magic glazed tile and its production method |
| CN107673749A (en) * | 2017-08-16 | 2018-02-09 | 广东博华陶瓷有限公司 | A kind of production technology of ceramics modelled after an antique |
| CN108424111B (en) * | 2018-01-25 | 2021-07-06 | 广东金牌陶瓷有限公司 | Bright dry-particle polished ceramic large plate and preparation method thereof |
| CN108394008A (en) * | 2018-03-23 | 2018-08-14 | 广东萨米特陶瓷有限公司 | Big plate of ceramics of anhydrous glaze line full digital code jet printing technique and preparation method thereof |
| CN108587320A (en) * | 2018-05-11 | 2018-09-28 | 广西欧神诺陶瓷有限公司 | A kind of function glue applied to inkjet printing, ornamental porcelain brick and preparation method thereof |
-
2018
- 2018-12-11 CN CN201811514663.XA patent/CN109456035B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN109456035A (en) | 2019-03-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109456035B (en) | Ceramic tile with bright and matte effect and preparation method thereof | |
| CN108675637B (en) | Whole body antiskid ceramic tile and manufacturing method thereof | |
| US11001534B2 (en) | Semi-transparent ceramic sheet decorated with ink light-absorbance and preparation method thereof | |
| CN109553299B (en) | Whole-body porcelain tile combining ink-jet effect and preparation method thereof | |
| WO2020177248A1 (en) | Ink-jet dry-grain decorative ceramic tile and manufacturing method thereof | |
| CN106518170B (en) | Fancy infiltration method for ceramic tile | |
| CN110746203A (en) | Ceramic product with mold effect texture manufactured by digital process and manufacturing method thereof | |
| CN108484114B (en) | Glazed ceramic tile with high-content polishing waste and preparation method thereof | |
| CN110845252B (en) | Special blank large-particle combined digital cloth archaized brick and preparation method thereof | |
| CN114163225B (en) | Preparation method of ceramic tile with super matte effect | |
| CN107759090B (en) | Glaze material with effect of imitating black gold sand marble and application thereof | |
| CN113845307B (en) | High-simulation digital mold ceramic tile and preparation method thereof | |
| CN113716967A (en) | Ceramic tile with flashing effect and preparation method thereof | |
| CN103833420B (en) | A kind of ancient black color glaze manufacture method and formula thereof | |
| CN110790507B (en) | Ground glaze and preparation method thereof, black ink-jet ceramic tile and manufacturing method thereof | |
| CN110282876B (en) | Colored dry particle frit, colored dry particle frit decorated ceramic tile and preparation method thereof | |
| CN104892034B (en) | It is a kind of that there are ceramics of group glaze effect and preparation method thereof | |
| CN110903080B (en) | Special blank large particle combined digital cloth ink-jet infiltration polished brick and preparation method thereof | |
| CN106699146A (en) | Semi-polished ceramic glazed tile having fluorescent effect and manufacturing method thereof | |
| CN105753465B (en) | A kind of preparation method of super flat mirror face art mural of porcelain and its obtained product | |
| CN107417114A (en) | Luminescence generated by light cover-coat enamel, luminescent microcrystal Ceramic Tiles and preparation method thereof | |
| CN108892540A (en) | A kind of preparation method of the Ceramic Tiles with sagging effect | |
| CN106830686A (en) | It is a kind of burn till after have concavo-convex texture candy glaze and Imitation Rock Porcelain Tiles preparation method | |
| CN104944925A (en) | Preparation process of underglaze red nixing pottery | |
| CN114804928A (en) | Preparation method of one-time sintered gold-plated dry grain glazed rock plate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20231229 Address after: 333000 Jingdezhen Ceramic Industrial Park, Fuliang County, Jingdezhen City, Jiangxi Province Patentee after: JINGDEZHEN OUSHENNUO CERAMIC CO.,LTD. Address before: 528000 fan Lake Industrial Park, Leping Town, Sanshui District, Foshan, Guangdong Patentee before: FOSHAN OCEANO CERAMICS Co.,Ltd. |