CN100487070C - Solvent-free expansion type fire-proof epoxy coating and its preparation method - Google Patents
Solvent-free expansion type fire-proof epoxy coating and its preparation method Download PDFInfo
- Publication number
- CN100487070C CN100487070C CNB2006100910483A CN200610091048A CN100487070C CN 100487070 C CN100487070 C CN 100487070C CN B2006100910483 A CNB2006100910483 A CN B2006100910483A CN 200610091048 A CN200610091048 A CN 200610091048A CN 100487070 C CN100487070 C CN 100487070C
- Authority
- CN
- China
- Prior art keywords
- fire
- agent
- parts
- proof paint
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses the inflatable fire-resisting paint, comprising A and B. The A comprises epoxide resin, modified resin, catalyst, foamable agent, fire retarding agent, fluxing agent, color filler and smog inhibiting agent, and the B comprises color filler, curing agent and auxiliary agent. The fire-resisting paint has the advantages of good heat-insulating property, adhesion force and intensity. The coating has good water resistance, acid- alkali resistance, corrosion resistance and tenacity, and is not easy to drop. The paint can be used in rolled steel and aluminum products, especially the fireproof situation of oil factories.
Description
Technical field
The present invention relates to expanding fire-proof paint, be suitable for indoor, outdoor steel, aluminium and other materials and avoid Mierocrystalline cellulose and hydrocarbon polymer flame and flame, blast, the effect of maintenance materials within a certain period of time.Than conventional expanded type frie retardant coating, the present invention more is applicable to offshore oil platform, oil field, refinery and petrochemical plant etc.
Background technology
Frie retardant coating generally is divided into expanded polystyrene veneer and non-expansion type two classes from fire prevention mechanism.Volume change did not take place in coating basically when the non-expansion type frie retardant coating was subjected to fire, and the coating thermal conductivity is low, retardation heat pass speed to protected base material.Frie retardant coating itself is non-combustible, and base material is played barrier and prevents the thermal radiation effect, has avoided the direct attack base material of flame and high temperature.Some component chance fire in the coating reacts to each other and generates non-flammable gases is thermo-negative reaction, has also consumed a large amount of heat.But the flameproof effect that this class coating wants to reach good must be coated with very thickly, and needs fire retardants such as interpolation is halogen-containing in a large number, nitrogen, phosphorus, produces a large amount of toxic gases.The non-expansion type fireproof paint coating is thicker, and affected by environment bigger, water tolerance is relatively poor, and poor adhesive force is easily peeled off from base material.
The expanding fire-proof paint expanded by heating of filming exactly forms cellular charring layer, flame heat regulating is isolated and reduces or slows down transmission to ground, and coating decomposites non-flammable gas when high temperature simultaneously, and is isolated and diluted air; The a series of physics and the chemical reaction of coating generation when meeting fire have absorbed a large amount of heats in addition, thereby play effect fire-retardant and that delay the flame expansion, spread, for people provide more attack time.
Behind the conventional expanded type frie retardant coating expanded by heating, the porous foam defence layer that produces, than former thick coating tens even hundred times, and the thermal conductivity ratio of the back foam layer that expands low at least order of magnitude of coating before not expanding, be coated with to such an extent that very thinly just can reach good flameproof effect.Its shortcoming is that most of expanding fire-proof paints are film forming matter with the acrylic resin, chemical resistance, water tolerance, poor solvent resistance, and fire retardant easily moves from coating, makes coating lose original fire-proof function.Therefore, this expansion type frie retardant coating is unsuitable for being applied in the open air.
Fire generally is divided into Mierocrystalline cellulose fire and hydro carbons fire.Be rich in fire that the fuel (as oils, chemical) of hydrogen and carbon produces hydrocarbon fire.The hydro carbons fire generally heats up faster than the Mierocrystalline cellulose fire, flame is more fierce.This point (see figure 1) as can be seen from the curve of BS476 standard the 20th part.
In hydro carbons fire experiment, the validity that is designed for the conventional frie retardant coating of Mierocrystalline cellulose fire only reach in the hydro carbons fire about 60%.It should be noted that when hydrocarbon fire takes place, usually be attended by blast and take place.Expanding fire-proof paint must can both remain intact and stick on the base material in blast process and after the blast generation.The expanding fire-proof paint that the present invention relates to can not only provide protection at the plain fire of violent natural fiber, particularly has excellent protection function at blast and hydro carbons fire.
Summary of the invention
Expanding fire-proof paint of the present invention is made up of A component and B component, and the prescription of A, B component is as follows:
The component parts by weight
The A component
Resins, epoxy 10-30
Modified resin 5-20
Catalyzer 5-20
Char-forming agent 10-35
Whipping agent 5-20
Fire retardant 15-40
Fusing assistant 5-15
Color stuffing 10-25
Smog inhibitor 2-15
The B component
Color stuffing 10-25
Solidifying agent 10-50
Auxiliary agent 2-15
In the above-mentioned prescription, resin has great effect to the performance of expanding fire-proof paint, and it and other component compatibility had both guaranteed that coating had various use propertieies under normal operation, can have excellent expanded foamed effect again under flame calcination or high temperature action.The present invention considers requirements such as resin should satisfy low viscosity, high crosslink density, bonding force is strong, erosion resistance is strong, water resisting property is strong, good weatherability when being chosen to film.
The good fluidity of Resins, epoxy has bonding force strong, the characteristic that pliability and toughness are excellent, physical strength is high.In epoxy resin structural, contain aliphatic hydroxyl, ether and as lively as a cricket epoxy group(ing).The polarity of hydroxyl and ether height makes the Resins, epoxy molecular energy produce electromagnetic attraction at critical surface, and the formation chemical bond and epoxide group can react with the radical of dielectric surface is so the bonding force of Resins, epoxy is strong especially.It all has good cementability to most of material such as timber, metal, glass, plastics, rubber, leather, pottery, fiber etc.Resins, epoxy after the curing has good chemical resistance, thermotolerance, acid and alkali-resistance and excellent electric insulating, thereby has good sticking power, non-corrosibility and physical strength with the frie retardant coating that it is prepared.Because the Resins, epoxy frie retardant coating has splendid closure, so its fire resistance is subjected to the influence of time and environment less.Particularly the Resins, epoxy frie retardant coating can both remain intact and stick on the base material in blast process and after the blast generation, more is applicable to offshore oil platform, oil field, refinery and petrochemical plant etc. than conventional expanded type frie retardant coating.
The present invention is main membrane-forming agent with Resins, epoxy, mainly consider resin viscosity, neat coal amout, have or not ignition-proof element, package stability etc.The Resins, epoxy that preferred viscosities of the present invention is little, the amount of being fuming is few, neat coal amout is big, contain ignition-proof element is made base-material.
Resins, epoxy of the present invention, be selected from following one or more: bisphenol A type epoxy resin, bisphenol f type epoxy resin, TDE-85 Resins, epoxy, glycolylurea epoxide resin, glycidyl amine type epoxy resin, polybutadiene epoxy resin, hydrogenated bisphenol A epoxy resin.
The present invention to the selection of modified resin based on following consideration: an important requirement of expanding fire-proof paint is that coating has good snappiness and sticking power.For this reason, modified resin should satisfy:
A. not during presence of fire coating can protect base material to avoid the direct impact of external object, and coating self can not separated with base material;
B. the rapid variation of the variation of weather, especially envrionment temperature can not cause coating cracking or break away from base material;
C. good snappiness and sticking power still can be combined closely coating with base material under the effect of explosion wave;
D. after coating was met the fire expansion, expanding layer can not break away from from base material yet.
Though Resins, epoxy has the advantages that bonding force is strong, hardness is big, but it is very big to solidify back paint film fragility, so add following one or more modified resin in the prescription above-mentioned Resins, epoxy is carried out modification: urethane, furane resin, aminoresin, Bisphenol F type resin, vinyl ester resins, acrylic resin, resol, Synolac, HCPE, chlorinated polyether resin, epoxy soybean oil, hydrogenated castor oil, polyvinyl butyral, chlorinated rubber, carboxybutyl rubber, coal tar wet goods.
The adding of modified resin, not only the snappiness that improves paint film is had very great help, and in these resins resinamines and chlorine-containing resins particularly highly-chlorinated polyethylene, chlorinated rubber, chlorinated polyether resin the over-all properties of coating is greatly improved, resol is then significantly helpful to the ultimate production of the compactness of charring layer and carbide.
The present invention selects for use mainly based on following consideration solidifying agent:
A. solidifying agent viscosity is low, curing speed fast, the coating usage period is long;
Effective cross-linking density height, chemical proofing and the physical and mechanical property of filming after b. solidifying are good;
C. the good weatherability of solidifying agent;
D. the curing system of solidifying agent and curing catalyst formation is nontoxic, does not produce low molecular contaminants during curing.
Described solidifying agent comprises: your ketone diamines of polyamide-based, liquid anhydrides, ketimine compound, diaminodiphenyl-methane, m-xylene diamine, the different fluorine of modification, aliphatic polyamine, diketone acrylamide affixture, thio-alcohol.
Also can add following flexible thing in the curing agent component and improve its performance: epoxy soybean oil, hydrogenated castor oil, urethanum-acrylate copolymer etc.
Catalyzer is one of crucial composition of expanding fire-proof paint, it promotes and improves the thermal decomposition process of coating, the amount of the flammable tar that produces when minimizing or the thermolysis of prevention organism, aldehyde, ketone etc. promotes the generation of non-flammable gases to reach the formation of at high temperature stable three-dimensional structure charring layer.As long as can be under proper temperature (it is generally acknowledged 150-250 ℃), the material that the composition that decomposites can dewater to the material of hydroxyl all can be as catalyzer.Optionally material has: primary ammonium phosphate, urea phosphate, ammonium polyphosphate, polyphosphoric acid amine potassium, Potassium tripolyphosphate, melamine phosphate, the two trimeric cyanamides of phosphoric acid, melamine pyrophosphate, organophosphate, borate (ester) and derivative, sulphonate and derivative etc.
The preferred ammonium polyphosphate of the present invention, melamine phosphate or its mixture as catalyst.
General commercially available ammonium polyphosphate (polymerization degree is many 20-30), its solubleness was 62% when its solubleness was 8.2%, 60 ℃ in the time of 25 ℃.To contain the weather resistance of ammonium polyphosphate frie retardant coating under wet, thermal environment in order improving, must to reduce the water-soluble of ammonium polyphosphate.
The present invention preferably carries out surface treatment to ammonium polyphosphate, with exotic materials to polyphosphoric acid by the surface wrap up, the available material has: silane coupling agent, titanate coupling agent, methyl-silicone oil, dimethyl silicone oil, containing hydrogen silicone oil, Zinic stearas, aminoresin, Resins, epoxy, resol etc.
Surface treated ammonium polyphosphate is compared with the ammonium polyphosphate of not handling: water-soluble obvious reduction, obviously improve with the consistency of resin, dispersiveness obviously improves.
The present invention most preferably adopts silicone oil series that ammonium polyphosphate is carried out making catalyzer after the surface treatment.
Char-forming agent is the basic substance that coating at high temperature forms the foam carburization zone of nonflammable three-D space structure, and the foam charring layer is played skeleton function.Char-forming agent will be complementary with catalyzer on decomposition temperature.The validity of char-forming agent depends on the content of hydroxyl and carbon atom in the molecule, and the quantity of hydroxyl is big, and the dehydrated speed of char-forming agent is very fast relatively.But the wetting ability height of char-forming agent itself, so also the quantity of non-hydroxyl is high more good more.Carbon content height, molecule are big, and be favourable to the intensity and the compactness of the charring layer of final formation.The kind of char-forming agent has a lot, as starch, Mierocrystalline cellulose and derivative, sucrose, sorbyl alcohol, tetramethylolmethane and derivative, Resins, epoxy, resol etc.
It is main char-forming agent that the present invention adopts tetramethylolmethane and the derivative that wetting ability is low, thermostability is high.As tetramethylolmethane, Dipentaerythritol, tripentaerythritol etc.
Whipping agent discharges non-flammable gases in certain temperature---hydrogen halide, ammonia, nitrogen and compound thereof, water vapor.Whipping agent commonly used has: the phosphoric acid salt of Dyhard RU 100, trimeric cyanamide, clorafin, urea, trimeric cyanamide and borate etc.The phosphoric acid salt of described trimeric cyanamide comprises melamine phosphate, melamine pyrophosphate.
In order to prolong foamed time, make the height of charring layer better, it is whipping agent that system of the present invention adopts trimeric cyanamide and clorafin, also can adopt melamine salt/ester (as melamine phosphate) and clorafin is whipping agent.
Fire retardant is the key component of frie retardant coating, and the fire resistance of frie retardant coating is had great influence.Selected fire retardant must cooperatively interact with base-material and other composition of fireproof system, makes even, the fine and close thermofin of the expanded foamed formation of coating when being subjected to fire.
Described fire retardant comprises organic fire-retardant and inorganic combustion inhibitor.
Described organic fire-retardant comprises: 1, and two (the dibromo norcamphyl two carbimides) ethane of 2-, the tetrabromophthalate dimethyl ester, two (2, the 3-dibromopropyl) ethers of tetrabromo-bisphenol, decabromodiphynly oxide, decabromodiphenyl, Dowspray 9, clorafin, DCRP (1,2,3,4,7,8,9,10,13,13,14,14-12 chloro-1,4,4a, 5,6,6a, 7,10,10a, 11,12,12a-ten dihydros-1,4,7,10-dimethano-hexichol cyclooctane), Hai Te (HET) acid and acid anhydrides thereof, hexachlorocyclopentadiene, tetrachlorophthalic tetrachlorophthalic anhydrid, phosphoric acid ester and Halogen derivative thereof, phosphonic acid ester, phosphorous acid ester, phosphorus oxide, phosphorus-containing polyol and phosphorous-nitrogen compounds, trimeric cyanamide and salt thereof, chlorine-containing flame retardant.
Chlorine-containing flame retardant comprises: sovprene, chlorinated polyvinyl chloride, chlorosulfonated polyethylene, tricresyl phosphate (chloroethene) ester, tricresyl phosphate (dichloro third) ester, tricresyl phosphate (chlorine third) ester, pentachloro-hard acid methyl esters, cyclic aliphatic hydrocarbon chlorine-containing flame retardant and anhydride acid chloride.
Described phosphate flame retardant comprises: Tritolyl Phosphate, triphenylphosphate, tricresyl phosphate isopropyl benzene ester, tributyl phosphate, trioctyl phosphate, tolyl diphenyl phosphoester, three (1-oxo-1-phospha-2,6,7-trioxa-l-phosphabicyclo [2,2,2] octane-4-methylene radical) phosphoric acid ester (Trimer) and 1-oxygen-4-methylol-2,6,7-trioxa-1-phospha dicyclo [2,2,2] octane (PEPA);
Described inorganic combustion inhibitor comprises: micro encapsulation red phosphorus and master batch thereof, aluminium hydroxide, magnesium hydroxide, aluminum oxide, polyphosphoric acid amine (APP), antimonous oxide, colloidal antimony pentoxide, zinc borate, zinc oxide.
The fire retardant that the present invention uses always comprises: two (2, the 3-dibromopropyl) ethers of tetrabromo-bisphenol, decabromodiphynly oxide, clorafin (42,50,60,70), phosphoric acid ester and Halogen derivative thereof, phosphonic acid ester, phosphorous acid ester, aluminium hydroxide, magnesium hydroxide, aluminum oxide, antimonous oxide, colloidal antimony pentoxide, zinc borate, zinc oxide etc.
The present invention adopts the composite method of multiple fire retardant, with performance cooperative flame retardant effect.Preferably phosphoric acid ester and Halogen derivative thereof, clorafin, aluminium hydroxide, magnesium hydroxide are as fire retardant.Halogen organic phosphate flame-retardant function is higher, also has the plastifying effect, is plasticising type fire retardant.
Both are the packing type fire retardant aluminium hydroxide, magnesium hydroxide, Halogen, nontoxic, press down cigarette, by a minute heat of desorption, generate water vapour and diluting effect and bring into play flame-retarded efficiency.The initial decomposition temperature of aluminium hydroxide is about 205 ℃, and magnesium hydroxide can reach 320 ℃.Both decomposition temperature differences can reach the effect that gradient is divided heat of desorption.
Described phosphonate fire retardant effect is very good, owing to have the C-P key in the phosphonic acid ester molecule, so its stability is fine, extraordinary water tolerance, solvent resistance is arranged.The Pyrovatex of external Ciba-Geigy company development is a N-methylol Propionamides methylphosphonate, and the Antiblaze19 of Mobil company development is phosphonic acid ester in the ring.The domestic phosphonic acid ester that synthesizes has: N, N-Ursol D base (2-hydroxyl) dibenzyl phosphonic acids tetra-ethyl ester, dimethyl methyl phosphonate (DMMP).Wherein DMMP is a kind of additive flame retardant that develops in recent years.DMMP is to be raw material with the phosphonous acid trimethyl, under catalyst action isomerization reaction takes place, and makes through molecular transposition.The outstanding feature of DMMP be phosphorus content up to 25%, flame retardant effect is very good, addition just can be brought into play same effect for a half of fire retardant commonly used.
Fusing assistant is the another kind of important material that adds among the present invention.Be heated at coating under the condition of charcoal, material phosphorous or siliceous in this type of fusing assistant and the coating reacts, and forms a kind of softish or liquid material.The gas that one or more composition thermolysiss in this coating system discharge expands this material.This type of fusing assistant comprises hydration boric acid, zinc borate, boron oxide, Sodium Tetraborate, potassium borate, ammonium borate or boric acid ester.
Described boric acid ester is butyl borate and boric acid phenylester.
For expanding fire-proof paint, if expanding layer is loose, high more its fire endurance that foams is poor more, and the intensity that therefore increases expanding layer is one of key that improves the frie retardant coating fire endurance.Suitably improve the ratio of filler in prescription, help improving the intensity of expanding layer, anti-hydro carbons fire and gaseous detonation are played important effect.When selecting color stuffing, select tinting strength height, hot reflection coefficient height, thermal conductivity are low, can play skeleton function to charring layer mineral dye, filler as far as possible.
The inventor is by a large amount of tests, find that some powders and fibrous material can be used as filling, supporting material, the preferred titanium dioxide of the present invention, aluminum oxide, light calcium carbonate, wollastonite, slag wool, high territory, silica powder, process white, rock wool, cenosphere, glass wool and various fire-resistant cotton filling, the supporting material done.
Toxic gas such as carbon monoxide and hydrogen halide is murderous first reason in the fire.In order to reduce the generating capacity of toxic smog, the present invention has also added smog inhibitor specially, and smog inhibitor commonly used has: aluminium hydroxide, magnesium hydroxide, aluminum oxide, lime carbonate, zinc borate, key acid zinc, expansible black lead etc.For the purpose of the present invention, preferred expansible black lead and magnesium hydroxide.
Auxiliary agent of the present invention comprises reactive thinner, toughner, curing catalyst, dispersion agent, flow agent and defoamer.
Described reactive thinner is a kind of low molecule, low viscosity, can participates in the film forming epoxide of crosslinking curing.Reactive thinner not only can reduce execution of coating viscosity, and is one of film forming matter, and it is the important materials that promotes coating solid part, reduces coating application viscosity.But excessive reactive thinner can influence film performance.The consumption of single functionality reactive thinner is no more than 15% of content of epoxy resin, and the consumption of difunctionality or three-functionality-degree reactive thinner can reach the 20%-25% of content of epoxy resin.Selectable reactive thinner has: alicyclic diepoxide (epoxy 269, epoxy 206, epoxy 201, epoxy 221), butanols, isooctyl alcohol, phenol, alkylphenol, trihydroxymethylpropanyltri diglycidyl ether, n-butyl glycidyl ether, glycidyl allyl ether, methyl propenoic acid glycidyl ether, poly-ethanol glycidyl ether, butanediol diglycidyl ether, cresylglycidylether, glycerol epoxy resin.
Described toughner comprises: turps, furfuryl alcohol, coumarone-indene based polymer, coal tar, epoxidation cardanol, polypropylene glycol diglycidyl ether, epoxy soybean oil, hydrogenated castor oil, thiorubber etc.Preferred coumarone-indene based polymer of this patent and epoxy soybean oil are as toughner.
Expanding fire-proof paint preparation method of the present invention: each raw material in the A component is added in the material-compound tank together, stir, it is qualified to be ground to fineness with three-roll grinder, is uniformly dispersed with homogenizer.The preparation method of B component is identical with the A component.
A, B two components are pressed the mixed of 2:1-4:1 and are used.Can adopt the method for spraying, brushing, blade coating to construct.Expanding fire-proof paint of the present invention can spread indoors, steel, aluminium and the other materials surface of open air, has outstanding fire resistance.
Solvent-free expansion type fire-proof epoxy coating of the present invention has that fire insulation performance is good, bonding force is good, intensity is high, can stand high low temperature round-robin influence, the water tolerance of coating, resistance to acids and bases, salt tolerant corrodibility are good, snappiness is good, difficult drop-off, shelf-stable, characteristics such as easy construction, be particularly suitable for indoor, outdoor steel, aluminium and other materials and avoid Mierocrystalline cellulose fire and hydro carbons fire and flame and blast, in 25 years, do not influence flameproof effect, look many work-ing life than conventional expanded type frie retardant coating.
Embodiment
Following examples are used for further specifying the present invention.
Embodiment 1
A component: extracting epoxy resin E-51,21 parts, 7.5 parts of bisphenol f type epoxy resins, 5.5 parts of hydrogenated castor oils, 4 parts of butanediol diglycidyl ethers, 8.5 parts of ammonium polyphosphates, 13.2 parts of tetramethylolmethanes, 5.6 parts of clorafins, 18 parts of Calucium Silicate powder, 10 parts of boron oxides, 3 parts of titanium whites, 15.3 parts in aluminium hydroxide, 2 parts of auxiliary agents;
B component: 18 parts of polyamide resins, 17.5 parts in lime carbonate, 8 parts of magnesium hydroxides, 3 parts of hydrogenated castor oils;
A, B two components are pressed the mixed of 2.4:1 and are used.
Embodiment 2
A component: extracting epoxy resin E-54,28 parts, 9.5 parts in aminoresin, 10.5 parts of 3.2 parts of polypropylene glycols of epoxy soybean oil, ammonium polyphosphate 8.5, tetramethylolmethane 13.5, Secondary ammonium phosphate 10.4,7.5 parts of Calucium Silicate powder, 8.5 parts of potassium borates, 2 parts of titanium dioxide, 30.5 parts in aluminum oxide, auxiliary agent 2;
B component: 20 parts of polyamide resins, 15 parts in diatomite, 3 parts of hydrogenated castor oils;
A, B two components are pressed the mixed of 3.5:1 and are used.
Embodiment 3
A component: extracting epoxy resin E-51,26 parts, 9.9 parts of acrylic resins, 10.5 parts of polypropylene glycols, 14.5 parts of ammonium polyphosphates, 8.5 parts of tetramethylolmethanes, 8 parts of trimeric cyanamides, 11 parts of Secondary ammonium phosphates, 7 parts of butyl borates, 17 parts in lime carbonate, 1.6 parts of titanium dioxide, 20 parts in aluminium hydroxide, 3 parts of auxiliary agents;
B component: 20 parts of polyamide resins, 11 parts of magnesium hydroxides, 3.6 parts of alkylphenols, auxiliary agent 1;
A, B two components are pressed the mixed of 3.8:1 and are used.
Embodiment 4
A component: extracting epoxy resin E-51,25 parts, 7.5 parts of acrylic resins, 6.8 parts of polypropylene glycols, 16 parts of ammonium polyphosphates, 12 parts of tetramethylolmethanes, 6.8 parts of trimeric cyanamides, 8.5 parts of Secondary ammonium phosphates, 15 parts in lime carbonate, 8.5 parts of zinc borates, 4.5 parts of titanium dioxide, 18 parts of magnesium hydroxides, 3 parts of auxiliary agents;
B component: 32 parts of polyamide resins, 7.9 parts in aluminum oxide, 5 parts of hydrogenated castor oils, 15 parts in aluminium hydroxide, 1 part of auxiliary agent;
A, B two components are pressed the mixed of 2.2:1 and are used.
Embodiment 5
A component: extracting epoxy resin E-51,22 parts, 7.5 parts of Bisphenol F type resins, 4.5 parts of polypropylene glycols, 9.5 parts of ammonium polyphosphates, 11.9 parts of tetramethylolmethanes, 5.2 parts of trimeric cyanamides, 6.8 parts of Secondary ammonium phosphates, 15 parts in lime carbonate, 8 parts of hydration boric acid, 5 parts of titanium dioxide, 6.5 parts of mica powders, 25.4 parts of magnesium hydroxides, 3 parts of auxiliary agents;
B component: 20 parts of polyamide resins, 12.5 parts in aluminium hydroxide, 3 parts of hydrogenated castor oils, 1 part of auxiliary agent;
A, B two components are pressed the mixed of 3.6:1 and are used.
Embodiment 6
A component: extracting epoxy resin E-54,28 parts, 9 parts of Bisphenol F type resins, 8 parts in turps, 15.5 parts of ammonium polyphosphates, 8 parts of tetramethylolmethanes, 8 parts of melamine phosphates, 6.6 parts of clorafins, 8.1 parts of Secondary ammonium phosphates, 15 parts of talcum powder, 12.5 parts of magnesium hydroxides, 5 parts of titanium dioxide, 23.5 parts of potassium borates, 3 parts of auxiliary agents;
B component: 32 parts of polyamide resins, 21.5 parts in aluminium hydroxide, 2 parts of auxiliary agents;
A, B two components are pressed the mixed of 2.7:1 and are used.
Embodiment 7
A component: extracting epoxy resin E-51,22 parts, 7.5 parts of Bisphenol F type resins, 12.5 parts of Tritolyl Phosphates, 8.3 parts in methyl propenoic acid glycidyl ether, 7.5 parts of ammonium polyphosphates, 13.5 parts of tetramethylolmethanes, 8 parts of trimeric cyanamides, 15 parts of Secondary ammonium phosphates, 8 parts of hydration boric acid, 11 parts in lime carbonate, 2 parts of titanium dioxide, 18 parts of magnesium hydroxides, 8.8 parts of expansible black leads, 2 parts of auxiliary agents;
B component: 20 parts of polyamide resins, 18 parts in aluminum oxide, 11 parts in aluminium hydroxide, 1 part of auxiliary agent;
A, B two components are pressed the mixed of 2.8:1 and are used.
Claims (14)
1. an expanding fire-proof paint is characterized in that, is made up of A component and B component, and the prescription of A, B component is as follows:
The component parts by weight
The A component
Resins, epoxy 10-30
Modified resin 5-20
Catalyzer 5-20
Char-forming agent 10-35
Whipping agent 5-20
Fire retardant 15-40
Fusing assistant 5-15
Color stuffing 10-25
Smog inhibitor 2-15
The B component
Color stuffing 10-25
Solidifying agent 10-50
Auxiliary agent 2-15
Described Resins, epoxy, be selected from following one or more: bisphenol A type epoxy resin, bisphenol f type epoxy resin, TDE-85 Resins, epoxy, glycolylurea epoxide resin, glycidyl amine type epoxy resin, polybutadiene epoxy resin, hydrogenated bisphenol A epoxy resin;
Described modified resin be selected from following one or more: urethane, furane resin, aminoresin, Bisphenol F type resin, vinyl ester resins, acrylic resin, resol, Synolac, HCPE, chlorinated polyether resin, epoxy soybean oil, hydrogenated castor oil, polyvinyl butyral, chlorinated rubber, carboxybutyl rubber, aldehyde ketone resin, coal tar;
The usage ratio of described A, B component is 2 ~ 4:1.
2. according to the expanding fire-proof paint of claim 1, it is characterized in that, described solidifying agent be selected from following one or more: your ketone diamines of polyamide-based, liquid anhydrides, ketimine compound, diaminodiphenyl-methane, m-xylene diamine, the different fluorine of modification, aliphatic polyamine, diketone acrylamide affixture, thio-alcohol.
3. according to the expanding fire-proof paint of claim 2, it is characterized in that, in described solidifying agent, add one or more flexible materials to its modification: epoxy soybean oil, hydrogenated castor oil, urethanum-acrylate copolymer.
4. according to the expanding fire-proof paint of claim 1, it is characterized in that, described catalyzer be selected from following one or more: the two trimeric cyanamides of primary ammonium phosphate, urea phosphate, ammonium polyphosphate, ammonium polyphosphate potassium, Potassium tripolyphosphate, melamine phosphate, phosphoric acid, melamine pyrophosphate, organophosphate, borate or ester and derivative, sulphonate and derivative.
5. according to the expanding fire-proof paint of claim 4, it is characterized in that, with one or more of following material described catalyzer is carried out surface treatment: silane coupling agent, titanate coupling agent, methyl-silicone oil, dimethyl silicone oil, containing hydrogen silicone oil, Zinic stearas, aminoresin, Resins, epoxy, resol.
6. according to the expanding fire-proof paint of claim 5, it is characterized in that, adopt silicone oil series that ammonium polyphosphate is carried out making catalyzer after the surface treatment.
7. according to the expanding fire-proof paint of claim 1, it is characterized in that, described char-forming agent be selected from following one or more: starch, Mierocrystalline cellulose and derivative, sucrose, sorbyl alcohol, tetramethylolmethane and derivative, Resins, epoxy, resol, aldehyde ketone resin.
8. according to the expanding fire-proof paint of claim 1, it is characterized in that, described whipping agent be selected from following one or more: the phosphoric acid salt of Dyhard RU 100, trimeric cyanamide, clorafin, urea, trimeric cyanamide and borate.
9. according to the expanding fire-proof paint of claim 1, it is characterized in that, described fire retardant be selected from following one or more: two (2, the 3-dibromopropyl) ethers of tetrabromo-bisphenol, decabromodiphynly oxide, clorafin, phosphoric acid ester and Halogen derivative thereof, phosphonic acid ester, phosphorous acid ester, aluminium hydroxide, magnesium hydroxide, aluminum oxide, antimonous oxide, colloidal antimony pentoxide, zinc borate, zinc oxide.
10. according to the expanding fire-proof paint of claim 1, it is characterized in that, described fusing assistant be selected from following one or more: hydration boric acid, zinc borate, boron oxide, Sodium Tetraborate, potassium borate, ammonium borate or boric acid ester.
11. expanding fire-proof paint according to claim 1, it is characterized in that, described color stuffing be selected from following one or more: titanium dioxide, aluminum oxide, light calcium carbonate, wollastonite, slag wool, high territory, silica powder, process white, rock wool, cenosphere, glass wool and various fire-resistant cotton.
12. the expanding fire-proof paint according to claim 1 is characterized in that, described smog inhibitor be selected from following one or more: aluminium hydroxide, magnesium hydroxide, aluminum oxide, lime carbonate, zinc borate, key acid zinc, expansible black lead.
13. the expanding fire-proof paint according to claim 1 is characterized in that, described auxiliary agent comprises: reactive thinner, toughner, curing catalyst, dispersion agent, flow agent and defoamer.
14. expanding fire-proof paint according to claim 13, it is characterized in that, described reactive thinner be selected from following one or more: alicyclic diepoxide, butanols, isooctyl alcohol, phenol, alkylphenol, trihydroxymethylpropanyltri diglycidyl ether, n-butyl glycidyl ether, glycidyl allyl ether, methyl propenoic acid glycidyl ether, poly-ethanol glycidyl ether, butanediol diglycidyl ether, cresylglycidylether, glycerol epoxy resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100910483A CN100487070C (en) | 2006-07-12 | 2006-07-12 | Solvent-free expansion type fire-proof epoxy coating and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100910483A CN100487070C (en) | 2006-07-12 | 2006-07-12 | Solvent-free expansion type fire-proof epoxy coating and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1876740A CN1876740A (en) | 2006-12-13 |
| CN100487070C true CN100487070C (en) | 2009-05-13 |
Family
ID=37509304
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100910483A Active CN100487070C (en) | 2006-07-12 | 2006-07-12 | Solvent-free expansion type fire-proof epoxy coating and its preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100487070C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103971897A (en) * | 2014-04-18 | 2014-08-06 | 陆霞芸 | Novel R-type iron core used for nuclear power station |
| CN105238222A (en) * | 2015-11-13 | 2016-01-13 | 海洋化工研究院有限公司 | Environment-friendly epoxy intumescent fire-retardant coating and preparing method thereof |
Families Citing this family (150)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006056403B4 (en) * | 2006-11-29 | 2010-08-19 | Hilti Aktiengesellschaft | Intumescent multi-component epoxy resin coating for fire protection and its use |
| CN101407597B (en) * | 2007-10-12 | 2011-09-14 | 上海化工研究院 | Halogen-free flame-retardant photo-curing epoxy resin composition |
| CN101712840B (en) * | 2008-10-07 | 2012-03-21 | 北京理工大学 | Ultrathin water-based epoxy resin expandable fireproof paint and preparation method thereof |
| CN101709188B (en) * | 2009-11-10 | 2011-09-14 | 无锡市虎皇漆业有限公司 | Vibration-damping heat-insulation paint and preparation method thereof |
| CN102061119A (en) * | 2009-11-16 | 2011-05-18 | 中国京冶工程技术有限公司 | Solvent-free epoxy resin fire-resistant coating for ultrathin steel structure |
| CN101760112B (en) * | 2010-03-01 | 2011-10-05 | 李乾元 | low carbon paint |
| CN102372993A (en) * | 2010-08-25 | 2012-03-14 | 苏州美亚美建筑涂料有限公司 | Zinc oxide- epoxy resin solar heat reflection coating color-changing coating |
| CN102020910A (en) * | 2010-12-24 | 2011-04-20 | 公安部四川消防研究所 | Hydrocarbon fire resistant ultrathin expanded fireproof coating and preparation method thereof |
| CN102093593B (en) * | 2010-12-30 | 2012-10-10 | 中国人民解放军国防科学技术大学 | Resin-based composite material additive type flame retardant, flame-retarding composite material and preparation methods thereof |
| US8512814B2 (en) * | 2011-02-14 | 2013-08-20 | Blue Angel Paint and Coatings, Ltd. | Coating material for achieving sound dampening and method for the same |
| CN102675992B (en) * | 2011-03-07 | 2014-07-16 | 嘉宝莉化工集团股份有限公司 | Expanded type aqueous facing fireproof coating and preparation method thereof |
| CN102219438B (en) * | 2011-03-21 | 2012-12-05 | 山西省交通科学研究院 | Flame-retardant double-component adhesive used for color antiskid pavement layer of tunnel |
| CN102732156A (en) * | 2011-04-01 | 2012-10-17 | 上海贝泓新材料科技有限公司 | Outdoor special-purpose intumescent coating and its manufacturing method |
| CN102226052A (en) * | 2011-06-07 | 2011-10-26 | 天津派尔尼尔科技发展有限公司 | Special fireproof paint for hard polyurethane foam (PUF) thermal insulation material and preparation method thereof |
| CN102875968B (en) * | 2011-07-11 | 2016-05-11 | 滁州格美特科技有限公司 | A kind of flame-retardant reinforced epoxy plastics sheet material and preparation method thereof |
| CN102337076A (en) * | 2011-07-13 | 2012-02-01 | 大连美宸特科技有限公司 | Liquid rubber spray coating containing phosphotriester |
| KR101573230B1 (en) * | 2011-10-24 | 2015-12-02 | 주식회사 케이씨씨 | Solvent-free epoxy fire resistive paint composition having improved gas toxicity on fire |
| EP2791144B1 (en) * | 2011-12-16 | 2016-02-24 | 3M Innovative Properties Company of 3M Center | Mercapto-containing bisanhydrohexitol derivatives and uses thereof |
| CN102634316A (en) * | 2012-05-14 | 2012-08-15 | 山西省交通科学研究院 | Moisture-activated epoxy resin composition |
| CN102746773B (en) * | 2012-06-28 | 2014-07-09 | 兰州理工大学 | Bromine carbon alkyd resin transparent fireproof paint and its preparation method |
| CN102731968B (en) * | 2012-07-24 | 2013-08-21 | 广州市博汇新材料科技有限公司 | Low-smoke flame-retardant epoxy-resin-containing composition and preparation method thereof |
| CN102766391A (en) * | 2012-08-17 | 2012-11-07 | 东莞市大兴化工有限公司 | A water-based halogen-free ultra-thin intumescent steel structure fireproof coating and its preparation method |
| CN102850902A (en) * | 2012-08-30 | 2013-01-02 | 苏州市德莱尔建材科技有限公司 | Corrosion-resistant fireproof coating |
| CN103666190B (en) * | 2012-09-03 | 2016-10-26 | 徐寿柏 | A kind of aqueous river seagoing vessel priming paint and preparation method thereof |
| CN102875851B (en) * | 2012-09-12 | 2015-05-20 | 山东长星集团有限公司 | Environment-friendly flame retardant |
| CN102898930A (en) * | 2012-09-21 | 2013-01-30 | 信和新材料股份有限公司 | Hydrocarbon flame resistant intumescent coating and preparation method thereof |
| CN102911420B (en) * | 2012-10-25 | 2014-08-06 | 上海韬鸿化工科技有限公司 | Composite environment-friendly retardant used for low density polyethylene (LDPE) and LDPE flame retardant plastic |
| CN102898786B (en) * | 2012-11-02 | 2014-05-28 | 天津盛远达科技有限公司 | Epoxy molding compound for packaging tantalum capacitor and manufacturing method for epoxy molding compound |
| CN103031041A (en) * | 2013-01-16 | 2013-04-10 | 中昊北方涂料工业研究设计院有限公司 | High-solid epoxy expansion type fireproof and heat insulation coating and preparation method thereof |
| CN103937282A (en) * | 2013-01-21 | 2014-07-23 | 青岛海诺中天节能科技有限公司 | Flame retardant |
| CN103173101A (en) * | 2013-02-26 | 2013-06-26 | 安徽明珠颜料科技有限公司 | Salt spray resistant anticorrosive paint |
| CN103173102A (en) * | 2013-02-26 | 2013-06-26 | 安徽明珠颜料科技有限公司 | Anticorrosive coating containing rron oxide red |
| CN103242735B (en) * | 2013-04-15 | 2015-07-15 | 重庆三峡油漆股份有限公司 | Super-thickness film epoxy double-component anticorrosive paint |
| CN103224746B (en) * | 2013-04-17 | 2015-07-15 | 长安大学 | Anti-staining epoxy fire-retardant coating and preparation method thereof |
| CN103275588B (en) * | 2013-05-24 | 2016-02-03 | 苏州市德莱尔建材科技有限公司 | A kind of Furan resin fireproof paint for wood material |
| CN103289517B (en) * | 2013-06-04 | 2015-08-05 | 苏州艾特斯环保材料有限公司 | A kind of waterproof heat resistant coating containing o-cresol formaldehyde epoxy resin |
| CN103265870B (en) * | 2013-06-14 | 2015-09-09 | 沈阳飞机工业（集团）有限公司 | With the expanded polystyrene veneer high temperature resistant heat insulation coating that epoxy resin is main membrane-forming agent |
| ES2632254T3 (en) | 2013-07-16 | 2017-09-12 | Akzo Nobel Coatings International B.V. | Intumescent coating composition |
| BR112016000471B1 (en) * | 2013-07-16 | 2022-06-28 | Akzo Nobel Coatings International B.V. | LIQUID INTUMESCENT COATING COMPOSITION CURABLE AT AMBIENT TEMPERATURE, SUBSTRATE, AND FIRE PROTECTION METHOD |
| CN103483927A (en) * | 2013-08-22 | 2014-01-01 | 欧美龙（南通）重防腐涂料有限公司 | Acrylic resin fire retardant paint |
| CN103483928A (en) * | 2013-09-09 | 2014-01-01 | 无为县大江橡塑制品有限公司 | High epoxy resin rubber paint |
| CN104513584B (en) * | 2013-09-27 | 2017-03-15 | 中国石油天然气集团公司 | A kind of modified epoxy connection coating and manufacture method |
| CN103483973A (en) * | 2013-10-09 | 2014-01-01 | 信和新材料股份有限公司 | Explosion-proof and fireproof anti-collision coating for oil tank |
| CN103589267A (en) * | 2013-10-17 | 2014-02-19 | 安徽顺驰电缆有限公司 | Fireproof coating |
| CN103788814B (en) * | 2013-10-21 | 2016-01-06 | 溧阳市浙大产学研服务中心有限公司 | A kind of technique of steel building being carried out to flame-proof finishing |
| CN103571304B (en) * | 2013-10-21 | 2016-08-17 | 宿州典跃新型建筑材料有限公司 | A kind of flame retardant epoxy floor coatings |
| CN103709803A (en) * | 2013-12-07 | 2014-04-09 | 铜陵新九鼎铜文化产业有限公司 | Fireproof and wear resistant epoxy resin paint for copper sculptures |
| CN103709899A (en) * | 2013-12-20 | 2014-04-09 | 中国海洋石油总公司 | Fire retardant coating for steel structure surface of nuclear power plant |
| CN103696247B (en) * | 2013-12-31 | 2015-12-02 | 江苏中新资源集团有限公司 | For not sticky grey coating and preparation method thereof of textiles |
| CN103788830A (en) * | 2014-01-20 | 2014-05-14 | 南通华新环保设备工程有限公司 | Acid and alkali resistant coating for stirring equipment and preparation method thereof |
| CN104056413B (en) * | 2014-06-22 | 2016-08-31 | 山东史达夫工控科技有限公司 | Kaolin network gel foam mud fire-prevention extinguishing agent |
| CN104056380B (en) * | 2014-06-22 | 2016-12-21 | 青岛玉兰祥商务服务有限公司 | Shale network gel foam mud fire-prevention extinguishing agent |
| CN104056414B (en) * | 2014-06-22 | 2016-08-24 | 许盛英 | Attapulgite network gel foam mud fire-prevention extinguishing agent |
| CN104056402B (en) * | 2014-06-22 | 2016-12-21 | 青岛玉兰祥商务服务有限公司 | Boron mud network gel foam mud fire-prevention extinguishing agent |
| CN104056384B (en) * | 2014-06-22 | 2016-08-24 | 许盛英 | Meerschaum network gel foam mud fire-prevention extinguishing agent |
| CN104056391B (en) * | 2014-06-22 | 2017-04-12 | 永春县达埔文雅家庭农场 | Rectorite mesh gel foam mud fire prevention and extinguishing agent |
| CN104056381B (en) * | 2014-06-22 | 2017-04-12 | 福建永信香业有限公司 | Cement mesh gel foam mud fire prevention and extinguishing agent |
| CN104056382B (en) * | 2014-06-22 | 2016-12-21 | 青岛玉兰祥商务服务有限公司 | Asbestos netted gel foam preventing slurry extinguishing chemical |
| CN104056401B (en) * | 2014-06-22 | 2016-12-14 | 重庆市路迪机械厂 | Talcum network gel foam mud fire-prevention extinguishing agent |
| CN104056397B (en) * | 2014-06-22 | 2016-12-14 | 重庆市巴南区前进机械厂 | Muscovitum network gel foam mud fire-prevention extinguishing agent |
| CN104056392B (en) * | 2014-06-22 | 2016-12-21 | 青岛玉兰祥商务服务有限公司 | Water-granulated slag network gel foam mud fire-prevention extinguishing agent |
| CN104056395B (en) * | 2014-06-22 | 2016-12-21 | 青岛玉兰祥商务服务有限公司 | Calcium carbonate network gel foam mud fire-prevention extinguishing agent |
| CN104056408B (en) * | 2014-06-22 | 2017-04-12 | 福建永春李和元食品有限公司 | Lime mesh gel foam mud fire prevention and extinguishing agent |
| CN104056387B (en) * | 2014-06-22 | 2017-04-12 | 永春县一都财华山羊养殖专业合作社 | Bauxite mesh gel foam mud fire prevention and extinguishing agent |
| CN104056400B (en) * | 2014-06-22 | 2016-12-21 | 青岛玉兰祥商务服务有限公司 | Ardealite network gel foam mud fire-prevention extinguishing agent |
| CN104056398B (en) * | 2014-06-22 | 2016-12-21 | 青岛玉兰祥商务服务有限公司 | Flint clay network gel foam mud fire-prevention extinguishing agent |
| CN104056385B (en) * | 2014-06-22 | 2016-12-21 | 青岛玉兰祥商务服务有限公司 | Vermiculitum network gel foam mud fire-prevention extinguishing agent |
| CN104056406B (en) * | 2014-06-22 | 2016-12-21 | 青岛玉兰祥商务服务有限公司 | Perlite network gel foam mud fire-prevention extinguishing agent |
| CN104056386B (en) * | 2014-06-22 | 2016-11-23 | 重庆市巴南区前进机械厂 | Graphite network gel foam preventing slurry extinguishing chemical |
| CN104083843B (en) * | 2014-06-23 | 2017-04-19 | 许庆华 | Gypsum reticular gel foam mud fire prevention and extinguishing agent |
| CN104056421B (en) * | 2014-06-23 | 2017-02-08 | 广西华科达科技发展有限公司 | Chlorite-illite mixed layer clay meshy gel foamed mud fire prevention and extinguishing agent |
| CN104119767A (en) * | 2014-06-25 | 2014-10-29 | 蚌埠凯盛工程技术有限公司 | Yellowing-resistant flame-retardant powder coating |
| CN104109448A (en) * | 2014-07-21 | 2014-10-22 | 天津金海兴业科技有限公司 | Novel nanometer magnesium hydroxide flame retardant coating |
| FR3025522B1 (en) * | 2014-09-09 | 2018-03-16 | Saint Gobain Adfors | FLAME RETARDANT COMPOSITION FOR TEXTILE SUBSTRATE. |
| CN104293091A (en) * | 2014-09-16 | 2015-01-21 | 天长市银狐漆业有限公司 | Flame-retardant insulating paint capable of increasing hardness of paint film and preparation method thereof |
| CN104194551A (en) * | 2014-09-28 | 2014-12-10 | 芜湖县双宝建材有限公司 | Impact-resistant flame retardant coating |
| CN104449221A (en) * | 2014-11-24 | 2015-03-25 | 天长市开林化工有限公司 | High-adhesion flame-retardant corrosion-resistant paint |
| CN104449220A (en) * | 2014-11-24 | 2015-03-25 | 天长市开林化工有限公司 | Epoxy resin modified paint with high solidification speed |
| CN104449217A (en) * | 2014-11-24 | 2015-03-25 | 天长市开林化工有限公司 | High-strength abrasion-resistant impact-resistant flame retardant coating |
| CN104761159A (en) * | 2015-04-07 | 2015-07-08 | 江苏铁锚玻璃股份有限公司 | High-transmittance grouting type fireproof glass |
| CN104860604A (en) * | 2015-04-23 | 2015-08-26 | 铜陵祥云消防科技有限责任公司 | Anti-corrosion anti-permeability fire-retardant coating |
| CN104845465A (en) * | 2015-04-23 | 2015-08-19 | 铜陵祥云消防科技有限责任公司 | Safe pollution-free fireproof coating |
| EP3085744A1 (en) * | 2015-04-24 | 2016-10-26 | PPG Coatings Europe B.V. | An intumescent coating composition |
| CN104817935A (en) * | 2015-04-27 | 2015-08-05 | 苏州市鼎立包装有限公司 | Waterproof coating for surface of packaging wood case and preparation method of waterproof coating |
| CN104987795A (en) * | 2015-07-06 | 2015-10-21 | 王舒怡 | Flame-retardant thermal insulation paint used for curtain walls and preparation method of flame-retardant thermal insulation paint |
| CN105131788B (en) * | 2015-09-21 | 2017-05-31 | 盐城市昶桦户外用品股份有限公司 | A kind of outdoor tent support bar and production technology |
| CN105199593A (en) * | 2015-11-02 | 2015-12-30 | 淄博夸克医药技术有限公司 | Modified polyurethane fireproof coating with wear resistance |
| KR101729075B1 (en) * | 2015-11-12 | 2017-04-21 | 주식회사 케이씨씨 | Fire resistant intumescent coating composition |
| CN105238221A (en) * | 2015-11-13 | 2016-01-13 | 海洋化工研究院有限公司 | Flexible epoxy intumescence fire-retardant coating and preparation method thereof |
| CN105255320A (en) * | 2015-11-20 | 2016-01-20 | 常熟市至翔建筑装饰工程有限公司 | House decorating coating |
| CN105368166A (en) * | 2015-11-27 | 2016-03-02 | 沈阳顺风新城建筑材料有限公司 | Expansion-type chlorinated rubber fire retardant coating and preparation method thereof |
| CN105462385B (en) * | 2015-11-27 | 2018-04-13 | 湖南省英越船舶配套工程有限责任公司 | A kind of yacht environmentally friendly topping paint and preparation method thereof |
| CN105440882B (en) * | 2015-11-30 | 2017-08-15 | 中国航空工业集团公司北京航空材料研究院 | A kind of nano modification anticorrosion resistance to erosion coating and preparation method |
| CN105462177B (en) * | 2016-01-07 | 2018-02-06 | 广东美特家家居用品有限公司 | A kind of heat-resistant fireproof bamboo-plastic composite material and preparation method thereof |
| CN105694566A (en) * | 2016-03-08 | 2016-06-22 | 杨超 | Fire-retardant coating for ultrathin steel structure |
| CN105670449A (en) * | 2016-03-16 | 2016-06-15 | 安徽海德石油化工有限公司 | High-sulphur and high-acid crude oil distillation column inner wall anticorrosive paint |
| CN105810332A (en) * | 2016-05-19 | 2016-07-27 | 合肥庭索环保材料有限公司 | Cable filler for antifreeze fire-resistant cable |
| CN106046422A (en) * | 2016-07-21 | 2016-10-26 | 肖金源 | Incombustible fire-resistant treating agent |
| CN106398458A (en) * | 2016-07-26 | 2017-02-15 | 苏州明轩地坪涂料有限公司 | Fireproof coating |
| CN106280953A (en) * | 2016-08-27 | 2017-01-04 | 安徽省金盾涂料有限责任公司 | A kind of inflaming-retarding antifouling polyurethane coating |
| CN106279771B (en) * | 2016-08-30 | 2019-01-01 | 浙江旭森非卤消烟阻燃剂有限公司 | A kind of preparation method of ammonium polyphosphate flame retardant microcapsule coated with epoxy resin |
| CN106367084A (en) * | 2016-08-30 | 2017-02-01 | 黄海涛 | Fire retardant |
| CN106634110A (en) * | 2016-12-06 | 2017-05-10 | 苏州洛特兰新材料科技有限公司 | Fireproof and anti-corrosion wall body heat insulation and thermal isolation paint material |
| CN106700422A (en) * | 2016-12-22 | 2017-05-24 | 苏州缔绿电子科技有限公司 | Anticorrosion and fireproofing thermal insulation composite material and preparation method thereof |
| CN107286771B (en) * | 2017-06-27 | 2019-12-13 | 公安部四川消防研究所 | Aluminum alloy fireproof coating and preparation method thereof |
| CN107384131A (en) * | 2017-08-21 | 2017-11-24 | 金华联创塑粉科技有限公司 | A kind of high abrasion anticorrosive coating and preparation method thereof |
| CN107502248A (en) * | 2017-09-13 | 2017-12-22 | 太仓天润新材料科技有限公司 | A kind of electronic material suitable for high integration Electronic Assemblies |
| CN108102440A (en) * | 2017-12-06 | 2018-06-01 | 安徽金达节能材料发展有限公司 | A kind of aluminum alloy doors and windows coating |
| CN108264823A (en) * | 2018-02-25 | 2018-07-10 | 李嘉顺 | A kind of solvent-free thick coated type epoxy resin fireproof coating and preparation method thereof |
| CN108559359B (en) * | 2018-04-25 | 2020-07-31 | 中南林业科技大学 | A kind of phase change endothermic, intumescent flame retardant steel structure fireproof coating and preparation method thereof |
| CN108795134A (en) * | 2018-06-11 | 2018-11-13 | 中国海洋石油集团有限公司 | A kind of solvent-free fireproof coating |
| CN108912953A (en) * | 2018-06-12 | 2018-11-30 | 常州大学 | A kind of steel construction corrosion resistant fireproof coating and preparation method thereof |
| CN108912609B (en) * | 2018-07-02 | 2021-01-08 | 广东航科新材料有限公司 | Epoxy resin composite material and preparation method thereof |
| CN110776779A (en) * | 2018-07-29 | 2020-02-11 | 安徽省临泉县万隆塑料包装有限公司 | Ink composition and preparation method thereof |
| CN109467878B (en) * | 2018-09-11 | 2021-05-04 | 太仓市金锚新材料科技有限公司 | Light multi-effect expansion type fireproof sealing material |
| CN109217198A (en) * | 2018-09-11 | 2019-01-15 | 太仓市金锚新材料科技有限公司 | Device is run through on a kind of Shipbuilding pipe road |
| CN109519087A (en) * | 2018-12-14 | 2019-03-26 | 广西祖昌门业有限公司 | Kitchen door special |
| CN110105800A (en) * | 2019-05-09 | 2019-08-09 | 海洋化工研究院有限公司 | A kind of fire-proof and thermal-insulation coating and preparation method thereof |
| CN110105863B (en) * | 2019-05-09 | 2020-11-03 | 海洋化工研究院有限公司 | Heat-resistant primer and preparation method thereof |
| CN110272676B (en) * | 2019-06-17 | 2021-07-23 | 襄阳市百盾防护涂层材料有限公司 | Flame-retardant composite ceramic anticorrosive wear-resistant coating material |
| CN110256925B (en) * | 2019-07-03 | 2021-07-30 | 安徽工业大学 | Intumescent high-performance fire-retardant and flame-retardant coating and preparation method thereof |
| CN110317459B (en) * | 2019-07-04 | 2021-09-21 | 安徽星鑫化工科技有限公司 | Chlorinated paraffin ultraviolet absorbent |
| CN110511650B (en) * | 2019-08-23 | 2021-03-02 | 常州市碳索新材料科技有限公司 | High-voltage insulating flame-retardant powder coating and preparation method thereof |
| CN110511635A (en) * | 2019-08-30 | 2019-11-29 | 丹东安盾涂料有限公司 | One kind exempting from grid thicker fire-resistant coating for steel structure and preparation method thereof |
| CN110628305A (en) * | 2019-09-16 | 2019-12-31 | 苏州热工研究院有限公司 | Flame retardant thermal insulation coating suitable for nuclear power irradiation environment and preparation method thereof |
| CN110591502A (en) * | 2019-09-19 | 2019-12-20 | 石家庄市油漆厂 | Two-component intumescent fire-retardant coating and preparation method thereof |
| CN110951354B (en) * | 2019-10-24 | 2022-01-11 | 江苏兰陵高分子材料有限公司 | Epoxy resin-based intumescent steel structure fireproof coating for non-mechanical construction and preparation method thereof |
| CN110903738B (en) * | 2019-12-03 | 2021-07-13 | 中国海洋石油集团有限公司 | Flexible solvent-free epoxy fireproof coating and preparation method thereof |
| CN111076030B (en) * | 2019-12-20 | 2022-05-24 | 苏州热工研究院有限公司 | A kind of corrosion control method under thermal insulation layer |
| CN111253791A (en) * | 2020-01-16 | 2020-06-09 | 江苏庞捷实业发展有限公司 | Novel railway vehicle fireproof coating |
| CN111675968A (en) * | 2020-03-24 | 2020-09-18 | 山东华韵新材料有限公司 | Flame-retardant paint for fireproof, non-combustible and high-corrosion-resistance color-coated plate and preparation method thereof |
| EP3922685A1 (en) * | 2020-06-11 | 2021-12-15 | Jotun A/S | Coatings |
| CN111621980A (en) * | 2020-06-15 | 2020-09-04 | 南京淳达科技发展有限公司 | Composite auxiliary agent for polyolefin fiber material and preparation method thereof |
| CN111572140A (en) * | 2020-06-18 | 2020-08-25 | 苏州法思特新材料有限公司 | Fireproof and fireproof structure |
| CN111827519A (en) * | 2020-06-29 | 2020-10-27 | 北新集团建材股份有限公司 | Fireproof composite wall and installation method |
| CN112143329A (en) * | 2020-08-19 | 2020-12-29 | 应急管理部四川消防研究所 | A new type of epoxy aluminum alloy fireproof decorative coating and preparation method thereof |
| CN111978819B (en) * | 2020-08-19 | 2021-11-19 | 应急管理部四川消防研究所 | Epoxy aluminum alloy fireproof decorative coating and preparation method thereof |
| CN114539886B (en) * | 2020-11-26 | 2023-03-21 | 海洋化工研究院有限公司 | Fireproof coating for ships and marine facilities, preparation method and fireproof separation structure |
| CN113321959B (en) * | 2021-04-26 | 2022-01-21 | 北京慕成防火绝热特种材料有限公司 | Epoxy expansion type steel structure fireproof paint for spraying fire scene |
| CN114149645B (en) * | 2021-11-25 | 2023-06-09 | 浙江亚厦装饰股份有限公司 | Fireproof PVC plate for partition wall and manufacturing method thereof |
| CN114686093A (en) * | 2022-02-23 | 2022-07-01 | 国网安徽省电力有限公司电力科学研究院 | Polyurethane anticorrosive paint for electric fire-fighting equipment and preparation method and application thereof |
| CN116925618B (en) * | 2022-03-30 | 2024-08-09 | 吉林省汇生科技有限责任公司 | Intumescent epoxy fireproof coating and preparation method and application thereof |
| CN115029029B (en) * | 2022-04-13 | 2023-12-26 | 海洋化工研究院有限公司 | Low-smoke flame-retardant water-based epoxy fireproof paint and preparation method and application thereof |
| CN114798361A (en) * | 2022-05-11 | 2022-07-29 | 航天材料及工艺研究所 | Reusable flame-retardant ablation-resistant stealth compatible composite coating and preparation method thereof |
| CN115384162B (en) * | 2022-07-12 | 2024-03-29 | 北京慕成防火绝热特种材料有限公司 | Multi-layer expansion type shape-following fire-resistant heat insulation structure |
| CN116162401A (en) * | 2022-11-02 | 2023-05-26 | 大使涂料(安徽)有限公司 | A kind of fluorine-containing ferrophosphorous coating and preparation method thereof |
| CN115851083B (en) * | 2022-12-17 | 2023-11-10 | 鹤山市君子兰涂料有限公司 | Electrostatic spraying flame-retardant UV (ultraviolet) finish paint and preparation process thereof |
| CN116004082A (en) * | 2022-12-30 | 2023-04-25 | 李�瑞 | A light solvent-free epoxy intumescent fireproof coating for automotive power battery packs and energy storage equipment and its preparation method |
| CN116790175A (en) * | 2023-02-17 | 2023-09-22 | 江西恒大高新技术股份有限公司 | Interior wall sound insulation coating and preparation method thereof |
| CN118165610A (en) * | 2024-03-06 | 2024-06-11 | 宁波峰梅化学科技有限公司 | Mechanically sprayable ceramic solvent-free fireproof coating and preparation method and application thereof |
-
2006
- 2006-07-12 CN CNB2006100910483A patent/CN100487070C/en active Active
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103971897A (en) * | 2014-04-18 | 2014-08-06 | 陆霞芸 | Novel R-type iron core used for nuclear power station |
| CN103971897B (en) * | 2014-04-18 | 2016-06-15 | 奉化市飞天人精密模具设计有限公司 | Used in nuclear power station R sections core |
| CN105238222A (en) * | 2015-11-13 | 2016-01-13 | 海洋化工研究院有限公司 | Environment-friendly epoxy intumescent fire-retardant coating and preparing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1876740A (en) | 2006-12-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100487070C (en) | Solvent-free expansion type fire-proof epoxy coating and its preparation method | |
| CN102559022B (en) | Polyurea expanding type fireproof paint as well as preparation method and application thereof | |
| CN1164701C (en) | Expanding fire-proof paint | |
| Ma et al. | A lava-inspired micro/nano-structured ceramifiable organic-inorganic hybrid fire-extinguishing coating | |
| CN102702962A (en) | Expansion type fire-retardant coating | |
| US6960388B2 (en) | Electrical distribution system components with fire resistant insulative coating | |
| CN105238222A (en) | Environment-friendly epoxy intumescent fire-retardant coating and preparing method thereof | |
| CN101935386B (en) | Fireproof, waterproof, insulating and decorative integrated composite polyurethane material and preparation method thereof | |
| CN104774509A (en) | Fireproof paint | |
| CN102174223A (en) | Flame-retardant foamed polyethylene material and preparation method thereof | |
| Kaur et al. | The role of bentonite clay on improvement in char adhesion of intumescent fire-retardant coating with steel substrate | |
| KR20090116042A (en) | Foaming fireproof paint composition and method for imparting fire resistance to buildings using the same | |
| CN106085220A (en) | A kind of preparation method and applications of organic silicon flame-retardant fireproof coating | |
| CN105820375A (en) | Composite flame retardant | |
| CN103408891A (en) | High-molecular flame-retardant foam material and preparation method thereof | |
| CN101891949A (en) | Halogen free flame retardant liquid and method for preparing flame retardant sponge using same | |
| CN109504232A (en) | A kind of epoxy intumescent fire retardant paint enhanced by a variety of carbon-based materials | |
| Ou et al. | Solvent-free intumescent fire protection epoxy coatings with excellent smoke suppression, toxicity reduction, and durability enabled by a micro/nano-structured P/N/Si-containing flame retardant | |
| CN116004082A (en) | A light solvent-free epoxy intumescent fireproof coating for automotive power battery packs and energy storage equipment and its preparation method | |
| CN105754239A (en) | Preparation method of ceramic composite modified resin coated EPS foam flame-retardant thermal-insulation material | |
| Bourbigot | Intumescence‐based flame retardant | |
| US8066807B2 (en) | Fire-resistant and insulating additives for building materials, their methods of production and uses thereof | |
| CN104341956A (en) | Fire retardant coating | |
| Catarina et al. | Development of acrylic‐based powder coatings with incorporation of montmorillonite clays | |
| CN102993905B (en) | A kind of fireproofing flame-resistant protective system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: MARINE CHEMICAL RESEARCH INSTITUTE Free format text: FORMER NAME: RESEARCH INST OF OCEAN CHEMISTRY |
|
| CP01 | Change in the name or title of a patent holder |
Address after: 266071 Shandong Province, Qingdao city Jinhu Road No. 4 Patentee after: Marine Chemical Research Institute Address before: 266071 Shandong Province, Qingdao city Jinhu Road No. 4 Patentee before: Research Inst of Ocean Chemistry |