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CN103571304B - A kind of flame retardant epoxy floor coatings - Google Patents

A kind of flame retardant epoxy floor coatings Download PDF

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Publication number
CN103571304B
CN103571304B CN201310496511.2A CN201310496511A CN103571304B CN 103571304 B CN103571304 B CN 103571304B CN 201310496511 A CN201310496511 A CN 201310496511A CN 103571304 B CN103571304 B CN 103571304B
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China
Prior art keywords
byk
toner
flame retardant
floor coatings
host
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CN201310496511.2A
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CN103571304A (en
Inventor
郭君建
汝宗林
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Suzhou Dian Yue New Building Materials Co Ltd
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Suzhou Dian Yue New Building Materials Co Ltd
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Priority to CN201310496511.2A priority Critical patent/CN103571304B/en
Publication of CN103571304A publication Critical patent/CN103571304A/en
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Abstract

The present invention relates to a kind of flame retardant epoxy floor coatings.Flame retardant epoxy floor coatings is made up of according to the ratio mixing match of weight ratio 100:20 100:30 host and firming agent, wherein said host is made up of the raw material of following weight: epoxy resin 40 70%, diluent 2 10%, fire retardant 30 50%, dispersant 0.01 2%, defoamer 0.01 2%, levelling agent 0.01 2%, toner 1 5%, firming agent forms: polyetheramine 30 90%, property amine 10 70%, accelerator 1 10%.This flame retardant epoxy floor coatings prepares the product being different from the market of fire-retardant terrace, can reach UL94V0 fire-protection rating, and after product construction, appearance looks elegant is generous, and easy construction, it is easy to operation, low volatilization or non-volatile.

Description

A kind of flame retardant epoxy floor coatings
Technical field
The present invention relates to a kind of building chemical coating, be specifically related to a kind of flame retardant epoxy floor coatings.
Background technology
Epoxy flooring coating is a kind of high intensity, floor wear-resistant, attractive in appearance, has seamless, quality The advantages such as solid, resistance to chemical reagents is good, and anticorrosion is waterproof, dust-proof, easy maintenance, and maintenance cost is cheap. Design kinds of schemes can be required according to different purposes, as 0.3--0.5mm epoxy thin coating floor, 0.6--0.8mm epoxy thickness be coated with terrace, epoxy self-leveling ground thick for 1-5mm, anti-skid wearable application, Mortar type application, antistatic, corrosion-proof coating etc..
Epoxy flooring coating is from the outset for functional terrace: such as anticorrosion, wear-resisting, anti-skidding, develops into General general industry terrace;Except having functional requirement, also there is ornamental effect.In work On the basis of the acquisition of industry terrace is wide variety of, along with improving constantly of people's living standard, in family Decoration is able to popularization and application.Epoxy industry ground slab has become one of China's industry with the fastest developing speed, Cause the attention of everybody.It can realize factorial praluction as cement products, and prospect is more considerable.
Floor paint is when normally using, general it is emphasised that wearability and pressure-proof and impact resistance energy, also has portion Divide and require to produce into the different requirements such as anticorrosion type, have the customer requirement floor paint of only a few to have heatproof Performance or fire resistance, if any food factory because having baking box etc. or Electronics Factory to heat or part Factory has baking vanish requirement, general heat resistance to require to reach more than 100 degree, according to this situation, and can To use the floor paint that the good heat-resisting quantity of pliability is strong to produce.Require that the places such as high place such as amusement and recreation are wanted Ask floor paint to have certain resistance to cigarette end to burn performance because cigarette end when glowing extreme temperatures plus shadows such as tar Ring, often produce the problems such as Huang of burning.
Epoxy flooring coating in the market not only volatilizees pungent abnormal smells from the patient also non-refractory, therefore produces Environmental protection the most attractive in appearance but also resistance to high epoxy flooring coating are extremely urgent.
Summary of the invention
The purpose of present invention is to solve above-mentioned the deficiencies in the prior art, it is provided that one can reach After the construction of UL94V0 fire-protection rating, product, appearance looks elegant is generous, easy construction, volatilization easily operated, low Or non-volatile coating.
The present invention is realized by techniques below means:
A kind of flame retardant epoxy floor coatings, it is characterised in that by host and firming agent according to weight ratio The ratio mixing match composition of 100:20 100:30, wherein,
Described host is made up of the raw material of following weight: epoxy resin 40-70 part, diluent 2-10 part, fire retardant 30-50 part, dispersant 0.01-2 part, defoamer 0.01-2 part, levelling agent 0.01-2 part and toner 1-5 part;
Described firming agent is made up of the raw material of following weight: polyetheramine 30-90 part, modified amine 10-70 part and accelerator 1-10 part.
In described host, the selection of various dispensings is as follows:
Epoxy resin is selected from E-51, one or more in E-44, E-20;
Diluent is selected from AGE, BGE, benzyl alcohol, dimethylbenzene, isobutanol, one or more in butanone;
Fire retardant is selected from aluminium hydroxide, magnesium hydroxide, antimony oxide, tetrabromobisphenol A, poly-described phosphorus Acid ammonium, MAP, Diammonium phosphate (DAP), ammonium chloride, boric acid, TCPP, TDCPP, IPPP, DMMP, phosphorus Triphenyl phosphate ester, one or more in TDE;
Dispersant is selected from polyether modified siloxane, and BYK-111, BYK-110, in polydimethylsiloxane One or more;
Defoamer is selected from polyether modified siloxane, dimethyl siloxane, in BYK-A530, BYK-525 Kind or more than;
Levelling agent is selected from polyether modified siloxane, and polydimethylsiloxane, in BYK-315, BYK-320 One or more;
Toner is selected from corresponding inorganic toner or organic toner;
In described firming agent, the selection of various dispensings is as follows:
Polyetheramine is selected from D-230, the one in D-400, T-403;
Modified amine is modified selected from IPDA, the one in MXDA modification;
Accelerator is selected from DMP-30, K-54, benzyl dimethylamine, the one in triethylamine
Beneficial effects of the present invention: the flame retardant epoxy floor coatings of the present invention is different from product on the market, Can reach UL94V0 fire-protection rating, after product construction, appearance looks elegant is generous, and easy construction, easily In operation, low volatilization or non-volatile.
Detailed description of the invention
Embodiment 1
By weight:
By mixing cured according to the ratio of weight ratio 100:20 to host and firming agent, make thick 3 mm wides 13 millimeters, 3, the sample of long 125 millimeters, samples vertical is placed, and installs;Sample is made the when of installation The blue flame at relatively low distance combustion tube top, one end 3/8 " being 3/4 height " is placed on sample lower end Centre, burn 10 seconds, then remove flame 8 seconds and extinguish, i.e. can be made into flame retardant epoxy terrace Coating.
Embodiment 2
By weight:
By mixing cured according to the ratio (weight ratio) of 100:30 to host and firming agent, make thick 3 millis Rice is wide 13 millimeters, 3, the sample of long 125 millimeters, and samples vertical is placed, and installs;The when of installation The blue flame making the relatively low distance combustion tube top 3/8, one end " being 3/4 height " of sample is placed on sample The centre of lower end, burns 10 seconds, then removes flame and extinguishes for 5 seconds, i.e. can be made into fire-retardant ring Oxygen floor coatings.
Embodiment 3
By weight:
By mixing cured according to the ratio (weight ratio) of 100:25 to host and firming agent, make thick 3 millis Rice is wide 13 millimeters, 3, the sample of long 125 millimeters, and samples vertical is placed, and installs;The when of installation The blue flame making the relatively low distance combustion tube top 3/8, one end " being 3/4 height " of sample is placed on sample The centre of lower end, burns 10 seconds, then removes flame and extinguishes for 3 seconds, i.e. can be made into fire-retardant ring Oxygen floor coatings.
Embodiment 4
By weight:
By mixing cured according to the ratio (weight ratio) of 100:20 to host and firming agent, make thick 3 millis Rice is wide 13 millimeters, 3, the sample of long 125 millimeters, and samples vertical is placed, and installs;The when of installation The blue flame making the relatively low distance combustion tube top 3/8, one end " being 3/4 height " of sample is placed on sample The centre of lower end, burns 10 seconds, then removes flame and extinguishes for 6 seconds, i.e. can be made into fire-retardant ring Oxygen floor coatings.
Embodiment 5
By weight:
By mixing cured according to the ratio (weight ratio) of 100:20 to host and firming agent, make thick 3 millis Rice is wide 13 millimeters, 3, the sample of long 125 millimeters, and samples vertical is placed, and installs;The when of installation The blue flame making the relatively low distance combustion tube top 3/8, one end " being 3/4 height " of sample is placed on sample The centre of lower end, burns 10 seconds, then removes flame and extinguishes for 7 seconds, i.e. can be made into fire-retardant ring Oxygen floor coatings.
The embodiment of the present invention, through test, all obtains splendid coating performance, and its test result is average such as Under:

Claims (1)

1. a flame retardant epoxy floor coatings, it is characterised in that be made up of according to the ratio mixing match of weight ratio 100:20 100:30 host and firming agent, wherein,
Described host is made up of the raw material of following weight: epoxy resin 40-70 part, diluent 2-10 part, fire retardant 30-50 part, dispersant 0.01-2 part, defoamer 0.01-2 part, levelling agent 0.01-2 part and toner 1-5 part;
Described firming agent is made up of the raw material of following weight: polyetheramine 30-90 part, modified amine 10-70 part and accelerator 1-10 part,
Described epoxy resin is selected from E-51, one or more in E-44, E-20,
Described diluent is selected from AGE, BGE, benzyl alcohol, dimethylbenzene, isobutanol, one or more in butanone,
Described fire retardant is selected from aluminium hydroxide, magnesium hydroxide, antimony oxide, tetrabromobisphenol A, APP, MAP, Diammonium phosphate (DAP), ammonium chloride, boric acid, TCPP, TDCPP, IPPP, DMMP, triphenyl phosphate, one or more in TDE,
Described dispersant is selected from polyether modified siloxane, BYK-111, BYK-110, one or more in polydimethylsiloxane,
Described defoamer is selected from polyether modified siloxane, dimethyl siloxane, one or more in BYK-A530, BYK-525,
Described levelling agent is selected from polyether modified siloxane, polydimethylsiloxane, one or more in BYK-315, BYK-320,
Described toner is selected from corresponding inorganic toner or organic toner,
In described firming agent, various components are as follows:
Described polyetheramine be selected from D-230, the one in D-400, T-403,
Described modified amine is modified selected from IPDA, the one in MXDA modification,
Described accelerator is selected from DMP-30, K-54, benzyl dimethylamine, the one in triethylamine.
CN201310496511.2A 2013-10-21 2013-10-21 A kind of flame retardant epoxy floor coatings Active CN103571304B (en)

Priority Applications (1)

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Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104017459A (en) * 2014-05-05 2014-09-03 哈尔滨理工大学 Epoxy floor coating with desulfurized gypsum as filler
CN104263201B (en) * 2014-10-16 2017-04-12 公安部四川消防研究所 Transparent intumescent flame-retardant epoxy resin fireproof coating and preparation method thereof
CN104673052A (en) * 2015-02-10 2015-06-03 天津可喜涂料有限公司 Waterborne non-combustible epoxy topcoat
CN104910657A (en) * 2015-06-18 2015-09-16 郭小曼 Fireproof coating for floor
CN105110700A (en) * 2015-08-14 2015-12-02 太仓安托建筑材料有限公司 High-temperature-resistant environmental-friendly building material
CN105907145A (en) * 2016-06-14 2016-08-31 苏州科淼新材料有限公司 Epoxy fireproof terrace paint
CN106047080A (en) * 2016-07-27 2016-10-26 陈红旗 Solvent type epoxy resin floor paint preparation formula
CN106118384A (en) * 2016-08-11 2016-11-16 桂林市晟博科技服务有限公司 Environment friendly corrosion protection heat-resisting paint and preparation method thereof
WO2018109766A1 (en) 2016-12-14 2018-06-21 Bromine Compounds Ltd. Antimony free flame-retarded epoxy compositions
CN107288300A (en) * 2017-06-20 2017-10-24 合肥慧林建材有限公司 A kind of wood floor brick and preparation method thereof
CN108707391A (en) * 2018-05-31 2018-10-26 长春智享优创科技咨询有限公司 Highly effective flame-retardant epoxy resin composite coating and preparation method thereof
CN109401527A (en) * 2018-08-06 2019-03-01 河南中机华远机械工程有限公司 A kind of thermal protection coating and its coating method
CN111925719B (en) * 2020-08-19 2021-11-23 润奥(上海)环保科技有限公司 Fireproof floor coating and preparation method thereof
CN113004640B (en) * 2021-04-09 2022-12-06 广州雷诺丽特塑料有限公司 PVC film and preparation method thereof
CN113913035A (en) * 2021-08-24 2022-01-11 杭州盛得佳实业有限公司 Inorganic floor reinforcing paint and production process thereof

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CN102443342A (en) * 2011-10-18 2012-05-09 中科院广州化学有限公司 Epoxy floor coating containing epoxy polyether organic silicon hybrid and preparation method thereof
CN102863866A (en) * 2012-08-30 2013-01-09 苏州明轩地坪涂料有限公司 Solvent type epoxy varnish for floors

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CN102443342A (en) * 2011-10-18 2012-05-09 中科院广州化学有限公司 Epoxy floor coating containing epoxy polyether organic silicon hybrid and preparation method thereof
CN102863866A (en) * 2012-08-30 2013-01-09 苏州明轩地坪涂料有限公司 Solvent type epoxy varnish for floors

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Denomination of invention: A flame retardant epoxy floor coating

Granted publication date: 20160817

Pledgee: Xiaoxian finance Company limited by guarantee

Pledgor: SUZHOU DIANYUE NEW BUILDING MATERIAL CO.,LTD.

Registration number: Y2024980038105