CN101760112B - low carbon paint - Google Patents
low carbon paint Download PDFInfo
- Publication number
- CN101760112B CN101760112B CN2010101190908A CN201010119090A CN101760112B CN 101760112 B CN101760112 B CN 101760112B CN 2010101190908 A CN2010101190908 A CN 2010101190908A CN 201010119090 A CN201010119090 A CN 201010119090A CN 101760112 B CN101760112 B CN 101760112B
- Authority
- CN
- China
- Prior art keywords
- parts
- epoxy resin
- low
- bisphenol
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 12
- 239000003973 paint Substances 0.000 title abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000004922 lacquer Substances 0.000 claims description 10
- 239000011259 mixed solution Substances 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 10
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 abstract description 6
- 239000004721 Polyphenylene oxide Substances 0.000 abstract description 5
- 239000003822 epoxy resin Substances 0.000 abstract description 5
- 229920000647 polyepoxide Polymers 0.000 abstract description 5
- 229920000570 polyether Polymers 0.000 abstract description 5
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 4
- RCHKEJKUUXXBSM-UHFFFAOYSA-N n-benzyl-2-(3-formylindol-1-yl)acetamide Chemical compound C12=CC=CC=C2C(C=O)=CN1CC(=O)NCC1=CC=CC=C1 RCHKEJKUUXXBSM-UHFFFAOYSA-N 0.000 abstract description 4
- -1 polysiloxane Polymers 0.000 abstract description 4
- 229920001296 polysiloxane Polymers 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 231100000053 low toxicity Toxicity 0.000 abstract description 2
- 239000004841 bisphenol A epoxy resin Substances 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 239000013530 defoamer Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 8
- 239000012855 volatile organic compound Substances 0.000 description 6
- 229920001807 Urea-formaldehyde Polymers 0.000 description 4
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 4
- 238000009472 formulation Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 235000018185 Betula X alpestris Nutrition 0.000 description 1
- 235000018212 Betula X uliginosa Nutrition 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The low-carbon paint comprises the following components in parts by weight: 90-95 parts of bisphenol A epoxy resin, 3-5 parts of aldehyde resin, 3-5 parts of propylene glycol methyl ether acetate, 2-3 parts of nano alumina, 0.3-0.5 part of polysiloxane defoamer and 0.1-0.2 part of polyether modified siloxane solvent; the compounding formula ratio is as follows: the ratio of the mixed liquid to the polyether amine curing agent is 100: 30. The invention has excellent chemical resistance, high glossiness, ultralow VOC, high elasticity and wear resistance, environmental protection and low toxicity. The invention fully utilizes the advantages of epoxy resin and aldehyde resin, forms an elastic paint film by utilizing the reaction of bisphenol A epoxy resin and polyetheramine, fully exerts the high gloss performance of the aldehyde resin, and ensures that the paint film achieves high gloss and high elasticity, and simultaneously, only a small amount of environment-friendly solvent propylene glycol monomethyl ether acetate is added in the formula for 3-5 percent, so that the VOC content is reduced to 50 mg and is far less than 600 mg of the national standard. Really realizes low carbon and environmental protection.
Description
Technical field
The present invention relates to a kind of house decoration paint that is used for, furniture is manufactured applied surperficial varnish, the compound method of especially a kind of surface paint.
Background technology
Use family at present, the woodwork coating in the furniture production wherein contains a large amount of volatile organic compounds VOC basically based on solvent based coating, contaminate environment, and the infringement painter, it is healthy to influence the human consumer.Now there is VOC content height in the lacquer of the oiliness wood lacquer on the market, contains the free TDI height, and smell is big, admittedly contain lowly, wear resistance is low, and shock resistance is poor.
Summary of the invention
The objective of the invention is: a kind of low-carbon (LC) lacquer is provided, and it can improve the elasticity of oiliness wood lacquer effectively, and hardness, fullness ratio, feel, the wear resistance of water resisting property, chemical resistant properties, raising paint film also realizes Ultra-low carbon.
A kind of low-carbon (LC) lacquer, the weight part proportioning of its prescription:
The compounded formula proportioning:
Above-mentioned mixed solution: polyetheramine solidifying agent=100: 30.
The present invention compared with prior art has following characteristics:
Has excellent anti-chemical, high glossiness, ultralow VOC, snappiness and wear resistance, environmental protection low toxicity.Because this patent has made full use of the advantage of Resins, epoxy and urea formaldehyde, utilize the reaction formation of bisphenol A epoxide resin and polyetheramine to have the elasticity paint film, and give full play to the high gloss performance of urea formaldehyde, it is high-elastic to make paint film reach high light, simultaneously, only add a little environmental protection level solvent 1-Methoxy-2-propyl acetate 3-5% in the prescription, make VOC content be reduced to 50 milligrams, be far smaller than 600 milligrams of GBs.The real low-carbon environment-friendly of realizing.
Embodiment
Embodiment 1
A kind of weight part proportioning of prescription of low-carbon (LC) lacquer:
Composite formulation ratio:
Above-mentioned mixed solution: polyetheramine solidifying agent=100: 30
Take by weighing raw material in proportion, solid aldehyde resin 3 grams are added in the reactor, with totally-enclosed pipeline 1-Methoxy-2-propyl acetate 3 grams are joined in the reactor then, less than 20 μ m, successively with pipeline input bisphenol A epoxide resin 90 grams, nano aluminium oxide 2 restrains high speed dispersion 20-30min then to fineness, polysiloxane defoamers 0.3 gram, polyether modified siloxane solvating agent 0.1 gram, middling speed stirred 10-15 minute, promptly made finished product.
Composite: as to get polyetheramine solidifying agent 100 grams, be input in the reactor packing with pipeline.
The present invention mixes the mixed solution of bisphenol A epoxide resin, urea formaldehyde, 1-Methoxy-2-propyl acetate, nano aluminium oxide, polysiloxane defoamers and polyether modified siloxane solvating agent in use with the polyetheramine solidifying agent.
Through experimental test: standard glossiness 〉=90, actual measurement 105;
Operative norm hardness 〉=HB surveys and is 3H;
Operative norm wear resistance≤0.05, actual measurement 0.0001;
Operative norm VOC surveys 35 smaller or equal to 600.
Embodiment 2
A kind of formulation ratio of low-carbon (LC) lacquer: (weight part)
Embodiment 3
A kind of formulation ratio of low-carbon (LC) lacquer:
Bisphenol A epoxide resin model R-140 Mitsui company produces
Urea formaldehyde model A-81 Germany BASF AG produces
Chemical plant, 1-Methoxy-2-propyl acetate model PMA China Yueyang produces
Nano aluminium oxide model VK-L20T Hangzhou ten thousand scape novel material companies produce
Polysiloxane defoamers model AC-300 Taiwan three birch companies produce
Polyether modified siloxane solvating agent model BRK333 Germany BRK company produces
Polyetheramine solidifying agent model D-230 U.S. HUNSTMAN company produces.
Claims (1)
1. a low-carbon (LC) coats with lacquer, and it is characterized in that: the weight part proportioning of prescription:
The compounded formula proportioning:
Above-mentioned mixed solution: polyetheramine solidifying agent=100: 30.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101190908A CN101760112B (en) | 2010-03-01 | 2010-03-01 | low carbon paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101190908A CN101760112B (en) | 2010-03-01 | 2010-03-01 | low carbon paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101760112A CN101760112A (en) | 2010-06-30 |
| CN101760112B true CN101760112B (en) | 2011-10-05 |
Family
ID=42491495
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010101190908A Active CN101760112B (en) | 2010-03-01 | 2010-03-01 | low carbon paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101760112B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102863877B (en) * | 2012-10-17 | 2014-12-24 | 北京碧海舟腐蚀防护工业股份有限公司 | Anticorrosive coating, preparation method and applications of anticorrosive coating |
| CN104356353A (en) * | 2014-11-19 | 2015-02-18 | 广东华兹卜化学工业有限公司 | A kind of aqueous PU curing agent and preparation method thereof |
| CN109401510B (en) * | 2018-11-30 | 2021-01-12 | 肇庆千江高新材料科技股份公司 | Modified acrylic coating and preparation method thereof, and glossiness adjusting method and application thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100365048C (en) * | 2003-05-15 | 2008-01-30 | 长兴化学工业股份有限公司 | Resin composition with high dielectric constant and its usage |
| MY159538A (en) * | 2005-11-10 | 2017-01-13 | Ppg Bv | Epoxy based coatings |
| CN100487070C (en) * | 2006-07-12 | 2009-05-13 | 海洋化工研究院 | Solvent-free expansion type fire-proof epoxy coating and its preparation method |
| CN101328301A (en) * | 2008-07-18 | 2008-12-24 | 曾灿旺 | Liquid thermosetting resin composition and method for manufacturing printed circuit board by using same |
-
2010
- 2010-03-01 CN CN2010101190908A patent/CN101760112B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN101760112A (en) | 2010-06-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: FOSHAN SHUNDE YACHENG CHEMICAL CO., LTD. Free format text: FORMER OWNER: LI QIANYUAN Effective date: 20130123 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 528429 ZHONGSHAN, GUANGDONG PROVINCE TO: 528325 FOSHAN, GUANGDONG PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20130123 Address after: 528325, No. eight, No. 5, science and technology zone, Xing Tan Town Industrial Park, Shunde District, Guangdong, Foshan Patentee after: Shunde Foshan Ya Cheng Chemical Co., Ltd. Address before: 528429, Zhongshan City, Guangdong Province Huang Town Xinfeng Industrial Zone Zhongshan City Ya Cheng Chemical Co., Ltd. Patentee before: Li Qianyuan |