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CN100435657C - Method of improving comprehensive performance of vegetable paper - Google Patents

Method of improving comprehensive performance of vegetable paper Download PDF

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Publication number
CN100435657C
CN100435657C CNB2006100410406A CN200610041040A CN100435657C CN 100435657 C CN100435657 C CN 100435657C CN B2006100410406 A CNB2006100410406 A CN B2006100410406A CN 200610041040 A CN200610041040 A CN 200610041040A CN 100435657 C CN100435657 C CN 100435657C
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vegetable
paper
drying
vegetable paper
reducing agent
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CN1887112A (en
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孙金才
张慜
钟齐丰
李方
范柳萍
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NINGBO HAITONG FOOD TECHNOLOGY Co Ltd
Jiangnan University
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HAITONG FOOD GROUP CO Ltd
Jiangnan University
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Abstract

The method of improving comprehensive performance of vegetable paper belongs to the field of fruit and vegetable food producing technology and is for mainly production of edible packing paper and paper type vegetable product. The vegetable paper producing process includes the steps of: sorting vegetable material, peeling, washing, slicing, scalding to deactivate enzyme, color protecting, mixing with moisture reducing agent and forming agent, pulping, deairing, forming, hot blast drying, microwave drying or infrared drying to water content of 20-30 %, peeling, cutting, further drying to water content of 10-20 %, and nitrogen filling or vacuum packing of the product. Owing to the moisture reducing agent and forming agent, the vegetable paper has good taste, relatively high tensile strength and breaking strength and may be eaten and used as the food packing material.

Description

一种提高蔬菜纸综合性能的方法 A Method for Improving the Comprehensive Performance of Vegetable Paper

技术领域 technical field

一种提高蔬菜纸综合性能的方法,属于果蔬食品加工技术领域。A method for improving the comprehensive performance of vegetable paper belongs to the technical field of fruit and vegetable food processing.

背景技术 Background technique

蔬菜中含有丰富的维生素和纤维素。维生素是人体生长和新陈代谢所必需的微量有机物,纤维素中的膳食纤维具有促进肠胃蠕动,防止便秘和保持大肠健康的功效。同时,蔬菜中丰富的纤维素也可以作为造纸的原料。食品包装通常使用塑料包装,由于塑料难以自然降解,一些发达国家已部分限制塑料包装的使用。因此,可自然降解的食品包装材料已成为世界各国研究的热点。以蔬菜纤维为原料的可食用包装纸可满足这一要求。通常蔬菜纸的加工是在蔬菜浆中加入蔗糖、盐进行调味,然后加入一些辅料,干燥后形成口感松脆的休闲方便食品。这类蔬菜纸通常需要再次复水,直接食用的品种较少。还有的是在蔬菜浆中加入黏结剂后形成柔韧的可食用食品包装材料,但这类产品通常纸感较好,但口感较差。为了改善蔬菜纸的适口性,一般是在蔬菜中渗透或添加一些富含羟基的碳水化合物,利用其良好的吸水性来调节蔬菜纸水分含量使蔬菜纸具有良好的适口性。但由于大量糖类物质的加入会影响蔬菜纸风味,因此此法仅用于少数特殊用途的蔬菜纸产品。一些黏结剂本身是多糖类物质,其丰富的羧基使其具有较高的吸水性,既能束缚游离水又能在纤维间起架桥作用,增强纤维间的结合,提高蔬菜纸的强度。Vegetables are rich in vitamins and cellulose. Vitamins are trace organic substances necessary for human growth and metabolism. Dietary fiber in cellulose can promote gastrointestinal motility, prevent constipation and maintain the health of the large intestine. At the same time, the rich cellulose in vegetables can also be used as a raw material for papermaking. Plastic packaging is usually used for food packaging, and some developed countries have partially restricted the use of plastic packaging because plastics are difficult to degrade naturally. Therefore, naturally degradable food packaging materials have become a research hotspot all over the world. Edible wrapping paper based on vegetable fiber can meet this requirement. Usually, the processing of vegetable paper is to add sucrose and salt to the vegetable pulp for seasoning, and then add some auxiliary materials to form a crispy leisure convenience food after drying. This kind of vegetable paper usually needs to be rehydrated again, and there are fewer varieties for direct consumption. There is also a flexible edible food packaging material that is formed by adding a binder to the vegetable pulp, but this type of product usually has a better paper feel, but the taste is poor. In order to improve the palatability of vegetable paper, it is generally to infiltrate or add some hydroxyl-rich carbohydrates in vegetables, and use its good water absorption to adjust the moisture content of vegetable paper to make vegetable paper have good palatability. However, since the addition of a large amount of sugar substances will affect the flavor of vegetable paper, this method is only used for a few special-purpose vegetable paper products. Some binders themselves are polysaccharides, and their rich carboxyl groups make them have high water absorption, which can not only bind free water but also act as a bridge between fibers, strengthen the bonding between fibers, and improve the strength of vegetable paper.

专利CN1528184A以番茄压榨后的滤渣为原料,经过调节水分,添加成型剂和均质处理,物料辊压成型,真空干燥,得到成品。其成型剂包括单一或混合的琼脂、明胶、瓜尔胶、羧甲基纤维素钠和海藻酸钠。在30-60℃干燥,控制水分使成品中水分含量为6%-10%。这种加工方法的不足之处在于:1)终产品没有调节水分活度,因此终产品没有达到安全水分含量,难以长时间贮藏;2)没有比较完备的防腐抑菌措施,作为包装纸时容易发生腐烂变质;3)水分含量较低,产品干燥、坚韧,适口性差。日本专利JP2002-45143A通过将蔬菜在海藻糖溶液中渗透,置换掉蔬菜中的水分,然后将蔬菜破碎铺成膜状并干燥成型。它能够良好保持蔬菜纸的机能并具有良好的适口性,但其应用范围较窄,主要是用作日本传统食品中海苔的代替品。Patent CN1528184A uses the filter residue after tomato pressing as raw material, after adjusting the water content, adding molding agent and homogenizing treatment, the material is rolled into shape, and vacuum dried to obtain the finished product. Its forming agents include single or mixed agar, gelatin, guar gum, sodium carboxymethylcellulose and sodium alginate. Dry at 30-60°C, and control moisture so that the moisture content in the finished product is 6%-10%. The disadvantages of this processing method are: 1) the final product does not adjust the water activity, so the final product does not reach a safe moisture content, and it is difficult to store for a long time; Rot and deterioration occur; 3) the moisture content is low, the product is dry, tough and poor in palatability. The Japanese patent JP2002-45143A replaces the moisture in the vegetables by infiltrating the vegetables in the trehalose solution, and then breaks the vegetables into a film and drys them into shapes. It can well maintain the function of vegetable paper and has good palatability, but its application range is narrow, mainly used as a substitute for nori in traditional Japanese food.

发明内容 Contents of the invention

本发明目的是提供一种提高蔬菜纸综合性能的方法,用于可食用包装纸和纸型蔬菜的生产。The purpose of the invention is to provide a method for improving the comprehensive performance of vegetable paper, which is used for the production of edible wrapping paper and paper-shaped vegetables.

技术解决方案:本发明提供了一种提高蔬菜纸综合性能的方法,其主要过程为先将蔬菜原料进行选取、洗涤、切片、漂烫灭酶熟化(5~10min)、护色等预处理后,沥干至表面无明显水珠,与降水分活度剂及成型剂混合,打浆(3~5min),脱气,平铺在模具中成型,然后热风干燥(60~80℃,3-4h)、或微波干燥(60-80℃,1700W,5-10分钟)或远红外干燥(70~75℃,2.5~3.0h)至水分含量为20~30%,揭片切分并继续干燥(40~60℃)直至水分含量为10%~20%。产品用充氮或抽真空包装。本发明由于使用了降水分活度剂可以使蔬菜纸的水分含量为10%~20%,水分活度为0.55~0.70,蔬菜纸具有良好适口性的同时也能保证在较长时间(6-12个月)内品质不会明显劣化,而成型剂的使用进一步提高了蔬菜纸的强度和柔韧性,使蔬菜纸的厚度为0.1mm~1mm,拉伸强度为0.6~0.9kN/m,耐折度为95~110次,使蔬菜纸既可以食用也能作为包装纸使用。Technical solution: The present invention provides a method for improving the comprehensive performance of vegetable paper, the main process of which is to select, wash, slice, blanch, deenzyme and ripen (5-10min), color-protecting and other pretreatments of vegetable raw materials , drain until there are no obvious drops of water on the surface, mix with water activity reducing agent and forming agent, beat (3-5min), degas, lay flat in the mold to form, and then dry with hot air (60-80°C, 3-4h ), or microwave drying (60-80°C, 1700W, 5-10 minutes) or far-infrared drying (70-75°C, 2.5-3.0h) until the moisture content is 20-30%, peel off the slices and continue drying ( 40-60°C) until the moisture content is 10%-20%. The product is packed with nitrogen or vacuum. Because the present invention uses the water activity reducing agent, the water content of the vegetable paper can be 10% to 20%, and the water activity is 0.55 to 0.70. The vegetable paper has good palatability and can also ensure that the vegetable paper can be used for a long time (6-20%). The quality will not deteriorate significantly within 12 months), and the use of forming agent further improves the strength and flexibility of the vegetable paper, so that the thickness of the vegetable paper is 0.1mm-1mm, the tensile strength is 0.6-0.9kN/m, and the durability The folding degree is 95-110 times, which makes the vegetable paper not only edible but also used as wrapping paper.

在本发明中添加的降水分活度剂是食盐、蔗糖、葡萄糖、乳糖、果葡糖浆、海藻糖的单独或组合使用,添加量是果蔬湿重的5%~15%。CMC-Na、海藻酸钠和琼脂在本发明中用做成型剂,可以单独或组合使用,添加量是果蔬湿重的0.1%~0.5%。The water activity reducing agent added in the present invention is salt, sucrose, glucose, lactose, fructose syrup, trehalose used alone or in combination, and the added amount is 5% to 15% of the wet weight of fruits and vegetables. CMC-Na, sodium alginate and agar are used as forming agents in the present invention, and can be used alone or in combination, and the addition amount is 0.1% to 0.5% of the wet weight of fruits and vegetables.

蔗糖、葡萄糖、乳糖、果葡糖浆、海藻糖是比较常见的单糖和双糖,能够通过渗透作用进入蔬菜细胞,其-OH与蔬菜细胞内或胞间的游离水结合,降低蔬菜纸的水分活度。食盐也具有良好的渗透性,在水中可以离解成Na+和Cl-,以库仑力与极性的水分子结合使蔬菜纸的水分活度值降低。Sucrose, glucose, lactose, fructose syrup, and trehalose are relatively common monosaccharides and disaccharides, which can enter vegetable cells through osmosis, and their -OH combines with free water in or between vegetable cells to reduce the moisture content of vegetable paper activity. Table salt also has good permeability. It can dissociate into Na + and Cl - in water, and combine with polar water molecules by Coulomb force to reduce the water activity value of vegetable paper.

通常蔬菜纸的水分含量在7%~10%之间,为获得良好的口感一般采取的方式是添加谷物辅料,使蔬菜纸口感松脆,但如此一来就降低了蔬菜纸的机械性能,使包装条件也受到一定的限制。通过调节蔬菜纸的水分活度,同时结合真空包装或充氮包装的方法,使蔬菜纸具有中间水分食品柔韧、坚固、干燥的特点,又有一定的安全性,可以长期贮藏。Usually the moisture content of vegetable paper is between 7% and 10%. In order to obtain a good taste, the general method is to add grain auxiliary materials to make the vegetable paper crispy, but this will reduce the mechanical properties of the vegetable paper. Packaging conditions are also subject to certain restrictions. By adjusting the water activity of the vegetable paper, combined with vacuum packaging or nitrogen-filled packaging, the vegetable paper has the characteristics of flexibility, firmness and dryness of intermediate moisture foods, and has certain safety, which can be stored for a long time.

蔬菜纸的强度主要是由蔬菜纤维间的结合力所决定的。纤维的结合力中以氢键的结合力最大,是最主要的结合力。CMC-Na、海藻酸钠和琼脂都是多糖类生物高分子,分子结构中含有较多的羧基,亲水性强,可以使相距较远不易形成氢键结合的纤维靠纤维-胶体-纤维间的氢键连接起来,增强了纤维间的结合,从而提高蔬菜纸的机械性能。The strength of vegetable paper is mainly determined by the bonding force between vegetable fibers. Among the binding forces of fibers, hydrogen bonds have the largest binding force and are the most important binding force. CMC-Na, sodium alginate, and agar are all polysaccharide biopolymers, with more carboxyl groups in their molecular structure and strong hydrophilicity, which can make fibers that are far apart and difficult to form hydrogen bonds rely on fiber-colloid-fiber The hydrogen bonds between fibers are connected to strengthen the bonding between fibers, thereby improving the mechanical properties of vegetable paper.

本发明的有益效果:Beneficial effects of the present invention:

与低水分含量的蔬菜纸加工的背景技术相比,本发明的优点为:1)在提高蔬菜纸水分含量的同时又能使水分活度保持在安全水平,提高了蔬菜纸的适口性和安全性;2)提高了产品的机械性能,扩大了蔬菜纸的应用范围;3)干燥所需时间短温度低,可以减少蔬菜中热敏性物质的损失,提高蔬菜纸的营养价值;4)降低了对产品包装及运输条件的限制,减少了产品在运输过程中的损失。Compared with the background technology of vegetable paper processing with low moisture content, the advantages of the present invention are: 1) While increasing the moisture content of vegetable paper, the water activity can be kept at a safe level, improving the palatability and safety of vegetable paper 2) It improves the mechanical properties of the product and expands the application range of vegetable paper; 3) The drying time is short and the temperature is low, which can reduce the loss of heat-sensitive substances in vegetables and improve the nutritional value of vegetable paper; The limitation of product packaging and transportation conditions reduces the loss of products during transportation.

与添加胶体的蔬菜包装纸加工的技术背景相比,本发明使包装用蔬菜纸具有可食用性,充分利用蔬菜纤维本身的特性,提高了蔬菜纸的价值,扩大了蔬菜纸的适用范围。Compared with the technical background of colloid-added vegetable wrapping paper processing, the invention makes the wrapping vegetable paper edible, makes full use of the characteristics of vegetable fiber itself, improves the value of the vegetable paper, and expands the application range of the vegetable paper.

具体实施方式 Detailed ways

实施例1:以甘蓝为原料的蔬菜纸生产Embodiment 1: take cabbage as the vegetable paper production of raw material

挑选新鲜甘蓝250g,清洗干净后切割成5cm×5cm方块,以1∶20的比例在pH=7~8水中热烫5min,热烫温度为96±2℃。在清水中漂洗去表面碱液,置于1500ml的浓度为200mg/L氯化锌溶液中冷浸5min,然后在清水中漂洗干净。沥干表面水分,加入13g葡萄糖和2.5g食盐在室温下处理1h。处理结束后,置于打浆机中,加入300mL水以及0.25g CMC-Na,打浆时间为4min,打浆机转速为15000-10000转/分。将浆料放入真空干燥箱中,在真空度为0.09MPa时脱气5min。浆料按4400g/m2的量均匀平铺在模具中,在80℃下热风干燥1.5h,然后在60℃下继续热风干燥2h,揭片,切割成各种规格的长方形、圆形等形状,并继续干燥直至表面触摸无湿感(约15-30min)。取出冷却至室温后,分级并按各种规格进行真空包装和贮藏。获得的蔬菜纸厚度为0.1mm,拉伸强度为0.9kN/m,耐折度为95次,蔬菜纸的水分含量为10%,水分活度为0.55。Select 250g of fresh cabbage, clean it, cut it into 5cm×5cm cubes, and blanch it in pH=7-8 water at a ratio of 1:20 for 5min at a blanching temperature of 96±2°C. Rinse in clean water to remove surface lye, place in 1500ml of zinc chloride solution with a concentration of 200mg/L for 5 minutes, and then rinse in clean water. Drain the surface water, add 13g of glucose and 2.5g of salt to treat at room temperature for 1h. After the treatment, put it in a beater, add 300mL of water and 0.25g of CMC-Na, the beating time is 4min, and the speed of the beater is 15000-10000 rpm. Put the slurry into a vacuum drying oven, and degas it for 5 minutes at a vacuum degree of 0.09MPa. Spread the slurry evenly in the mold at an amount of 4400g/ m2 , dry with hot air at 80°C for 1.5h, then continue to dry with hot air at 60°C for 2h, peel off the sheet, and cut into rectangles, circles and other shapes of various specifications , and continue to dry until the surface does not feel wet to the touch (about 15-30min). After taking it out and cooling to room temperature, it is graded and vacuum-packed and stored according to various specifications. The obtained vegetable paper has a thickness of 0.1mm, a tensile strength of 0.9kN/m, a folding endurance of 95 times, a moisture content of 10%, and a water activity of 0.55.

实施例2:以热风干燥(AD)菜芯为原料的蔬菜纸生产Embodiment 2: take hot-air drying (AD) vegetable core as the vegetable paper production of raw material

称取50gAD菜芯,在pH=7~8的1000ml复水液中复水7mm,复水温度为96±2℃。在清水中漂洗去表面碱液,置于1500ml的浓度为200mg/L乙酸锌溶液中冷浸5min,然后在清水中漂洗干净。沥干表面水分,加入10g果葡糖浆和2.0g食盐在室温下腌制1h。腌制结束后,置于打浆机中,加入300mL水以及0.20g海藻酸钠,打浆时间为5min,机转速为10000-15000转/分。将浆料放入真空干燥箱中,在真空度为0.09MPa时脱气5min。浆料按4246g/m2的量均匀平铺在模具中,在80℃下热风干燥1.5h,然后在60℃下继续热风干燥2h,揭片,切割成各种规格的长方形、圆形等形状,并继续干燥直至表面触摸无湿感(约15-30min)。取出冷却至室温后,分级并按各种规格进行真空包装和贮藏。获得的蔬菜纸厚度为0.5mm,拉伸强度为0.75kN/m,耐折度为105次,蔬菜纸的水分含量为15%,水分活度为0.62。Weigh 50g AD cabbage core, rehydrate 7mm in 1000ml rehydration solution with pH=7-8, and the rehydration temperature is 96±2°C. Rinse in clean water to remove surface lye, place in 1500ml of 200mg/L zinc acetate solution for cold immersion for 5min, and then rinse in clean water. Drain the surface water, add 10g fructose syrup and 2.0g salt and marinate at room temperature for 1h. After pickling, put it in a beater, add 300mL of water and 0.20g of sodium alginate, beat for 5 minutes, and the speed of the machine is 10000-15000 rpm. Put the slurry into a vacuum drying oven, and degas it for 5 minutes at a vacuum degree of 0.09MPa. Spread the slurry evenly in the mold at an amount of 4246g/ m2 , dry with hot air at 80°C for 1.5h, then continue to dry with hot air at 60°C for 2h, peel off the sheet, and cut into rectangles, circles and other shapes of various specifications , and continue to dry until the surface does not feel wet to the touch (about 15-30min). After taking it out and cooling to room temperature, it is graded and vacuum-packed and stored according to various specifications. The obtained vegetable paper has a thickness of 0.5mm, a tensile strength of 0.75kN/m, a folding endurance of 105 times, a moisture content of 15%, and a water activity of 0.62.

实施例3:以甘蓝汁加工下脚料甘蓝渣为原料的蔬菜纸的生产Embodiment 3: the production of the vegetable paper that is raw material with cabbage juice processing leftover cabbage slag

称取500g甘蓝渣,在2500mL的30%蔗糖+1%食盐溶液中100℃煮3min,捞出冷却至室温,置于打浆机中,加入800mL水以及0.5g海藻酸钠(已溶于水),打浆时间为4min,机转速为10000-15000转/分。将浆料放入真空干燥箱中,在真空度为0.09MPa时脱气5min。浆料按4500g/m2的量均匀平铺在模具中,远红外干燥(70~75℃)2.5h,揭片,切割成各种规格的长方形、圆形等形状,并继续干燥直至表面触摸无湿感(约10~15min)。取出冷却至室温后,分级并按各种规格进行真空包装和贮藏。获得的蔬菜纸厚度为1mm,拉伸强度为0.6kN/m,耐折度为110次,蔬菜纸的水分含量为20%,水分活度为0.70。Weigh 500g of cabbage pomace, cook in 2500mL of 30% sucrose + 1% salt solution at 100°C for 3min, remove and cool to room temperature, put in a beater, add 800mL of water and 0.5g of sodium alginate (dissolved in water) , the beating time is 4min, and the machine speed is 10000-15000 rpm. Put the slurry into a vacuum drying oven, and degas it for 5 minutes at a vacuum degree of 0.09MPa. Spread the slurry evenly in the mold at an amount of 4500g/ m2 , dry in the far infrared (70-75°C) for 2.5 hours, peel off the sheet, cut into rectangles, circles and other shapes of various specifications, and continue to dry until the surface touches No wet feeling (about 10-15 minutes). After taking it out and cooling to room temperature, it is graded and vacuum-packed and stored according to various specifications. The obtained vegetable paper has a thickness of 1mm, a tensile strength of 0.6kN/m, a folding endurance of 110 times, a moisture content of 20%, and a water activity of 0.70.

Claims (2)

1.一种提高蔬菜纸综合性能的方法,先将蔬菜原料进行选取、洗涤、切片、漂烫灭酶、护色预处理后,其特征是预处理后的蔬菜与适量降水分活度剂及成型剂混合,打浆,脱气,成型,进行热风干燥、或微波干燥、或远红外干燥至水分含量为20%~30%,揭片切分并继续干燥,直至水分含量为10%~20%,产品蔬菜纸用充氮或抽真空包装;1. A method for improving the comprehensive performance of vegetable paper. First, vegetable raw materials are selected, washed, sliced, blanched to eliminate enzymes, and color-protected after pretreatment. It is characterized in that the pretreated vegetables are mixed with an appropriate amount of water activity reducing agent and Forming agent mixing, beating, degassing, molding, hot air drying, or microwave drying, or far infrared drying to a moisture content of 20% to 30%, peeling off the slices and continuing to dry until the moisture content is 10% to 20% , the product vegetable paper is packed with nitrogen or vacuum; 所述的降水分活度剂为食盐、蔗糖、葡萄糖、乳糖、果葡糖浆、海藻糖的单一或混合组份,添加的量为蔬菜原料湿计质量的5%~15%;The water activity reducing agent is a single or mixed component of salt, sucrose, glucose, lactose, fructose syrup, and trehalose, and the added amount is 5% to 15% of the wet weight of the vegetable raw material; 所述的成型剂为羧甲基纤维素钠、海藻酸钠、琼脂的单一或混合组份,添加的量为蔬菜原料湿计质量的0.1%~0.5%。The forming agent is a single or mixed component of sodium carboxymethyl cellulose, sodium alginate and agar, and the added amount is 0.1% to 0.5% of the wet weight of vegetable raw materials. 2.根据权利要求1所述的方法,其特征是热风干燥:60~80℃,3~4小时;或微波干燥:60~80℃,1700W,5~10分钟;或远红外干燥:70~75℃,干燥时间为2.5~3.0h。2. The method according to claim 1, characterized in that hot air drying: 60-80°C, 3-4 hours; or microwave drying: 60-80°C, 1700W, 5-10 minutes; or far-infrared drying: 70- 75°C, the drying time is 2.5~3.0h.
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