CN102071591B - Method for preparing edible, preservative and antibacterial paper - Google Patents
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Abstract
Description
技术领域 technical field
本发明涉及一种保鲜抗菌纸的制备方法,特别是涉及一种可食保鲜抗菌纸的制备方法。The invention relates to a preparation method of fresh-keeping antibacterial paper, in particular to a preparation method of edible fresh-keeping antibacterial paper.
背景技术 Background technique
人类感染细菌的途径之一就是通过人口的食物,而食品包装材料一般是与食品直接接触的,食物丰富的营养成分在高温的包装内部环境下就成为微生物滋生繁殖的营养源。具有抗菌保鲜功能的食品包装材料的研制就显得非常重要。目前,抗菌材料的种类繁多,大体上包括抗菌塑料、抗菌纤维和织物、抗菌陶瓷和抗菌金属。抗菌材料的制作一般是将抗菌剂以适当的方式添加到基材中或涂覆在基材表面,因此可以说,抗菌材料的优劣最终取决于抗菌剂的研制。虽然抗菌剂的品种繁多,应用较广,但日常使用的消毒剂只能产生短期效应,且有害人体健康,因此新型抗菌材料的开发从未停止。对抗菌剂的要求不仅要无毒无害和长效性外,同时具有健康功能也是一个重要的发展趋势。One of the ways for humans to infect bacteria is through the food of the population, and food packaging materials are generally in direct contact with food, and the rich nutrients in food become the source of nutrients for the growth and reproduction of microorganisms in the high-temperature packaging internal environment. It is very important to develop food packaging materials with antibacterial and fresh-keeping functions. At present, there are many kinds of antibacterial materials, which generally include antibacterial plastics, antibacterial fibers and fabrics, antibacterial ceramics and antibacterial metals. The production of antibacterial materials generally involves adding antibacterial agents to the substrate or coating the surface of the substrate in an appropriate manner. Therefore, it can be said that the quality of antibacterial materials ultimately depends on the development of antibacterial agents. Although there are many kinds of antibacterial agents and they are widely used, the disinfectants used in daily life can only produce short-term effects and are harmful to human health. Therefore, the development of new antibacterial materials has never stopped. The requirements for antibacterial agents are not only non-toxic, harmless and long-lasting, but also have health functions, which is also an important development trend.
抗菌包装物对于食品保质、防止外来污染非常有用。抗菌材料分为有机抗菌材料、无机抗菌材料和天然抗菌材料。有机抗菌材料对环境和人体有害且作用寿命短,使用温度低于300℃,无机抗菌剂克服了上述缺点。应用抗菌材料可防止霉毒等微生物对果蔬的侵害,获得较好的保鲜效果。Antimicrobial packaging is very useful for food preservation and protection from external contamination. Antibacterial materials are divided into organic antibacterial materials, inorganic antibacterial materials and natural antibacterial materials. Organic antibacterial materials are harmful to the environment and human body and have a short service life, and the operating temperature is lower than 300°C. Inorganic antibacterial agents overcome the above shortcomings. The application of antibacterial materials can prevent microorganisms such as mildew from invading fruits and vegetables, and obtain a better fresh-keeping effect.
作为食品包装材料,抗菌剂的选用一定要对人体无害,应避免使用具有急性毒性、慢性毒性、气味较大、刺激皮肤等类的抗菌剂。由此看来,有机抗菌剂的使用就具有很大的局限性,而无机抗菌剂和天然抗菌剂则因其安全性而成为应用的热点。As food packaging materials, the selection of antibacterial agents must be harmless to the human body, and the use of antibacterial agents with acute toxicity, chronic toxicity, strong odor, and skin irritation should be avoided. From this point of view, the use of organic antibacterial agents has great limitations, while inorganic antibacterial agents and natural antibacterial agents have become the focus of application because of their safety.
以天然原材料作为抗菌剂,主要有壳聚糖、山梨酸等,目前研究颇多的是壳聚糖。壳聚糖是甲壳素的脱乙酰产物,是一种聚氨基葡萄糖。壳聚糖具有良好的成膜性,通透性和抗菌性。其抗菌机理一般认为是由两步来完成的:首先,在酸性条件下,壳聚糖分子中的-NH2与细菌细胞壁所含的硅酸、磷酸脂等解离出的阴离子结合,使细菌的自由活动受阻,从而阻碍细菌的大量繁殖。然后,壳聚糖进一步低分子化,通过细胞进入细菌的细胞内,使遗传因子从DNA到RNA的转变过程受阻,造成细菌无法繁殖。该天然抗菌剂来源丰富,也可单独用来涂膜包装,应用前景广阔。Natural raw materials are used as antibacterial agents, mainly chitosan, sorbic acid, etc., and chitosan is currently being studied a lot. Chitosan is the deacetylation product of chitin and is a kind of polyglucosamine. Chitosan has good film-forming properties, permeability and antibacterial properties. Its antibacterial mechanism is generally considered to be completed by two steps: first, under acidic conditions, -NH2 in the chitosan molecule combines with the anions dissociated from the silicic acid and phospholipids contained in the bacterial cell wall, making the bacteria The free movement of the bacteria is hindered, thereby hindering the massive reproduction of bacteria. Then, chitosan is further low-molecularized, and enters the cells of bacteria through cells, hindering the transformation process of genetic factors from DNA to RNA, resulting in the inability of bacteria to reproduce. The natural antibacterial agent is rich in sources, and can also be used alone for coating film packaging, with broad application prospects.
猕猴桃果实含有丰富的营养成分。其可溶性固形物含量为14%-20%;含有17种氨基酸,其中包括除色氨酸外的人体必需的7种氨基酸,每100克果肉含钙27mg,磷26mg、镁12mg、钾144mg、铁1.2mg,硒0.28mg;其它成分有胡萝卜素、叶绿素;柠檬酸、奎尼酸和苹果酸是猕猴桃中的主要酸;同时含有大量的糖类,主要是葡萄糖、果糖、蔗糖及多糖和糖醛酸类;此外,猕猴桃还含有膳食纤维和不饱和脂肪酸;猕猴桃维生素C含量特别高,每100克果实含量最高可达420mg。Kiwi fruit is rich in nutrients. Its soluble solid content is 14%-20%; it contains 17 kinds of amino acids, including 7 kinds of amino acids necessary for the human body except tryptophan, and every 100 grams of pulp contains 27mg of calcium, 26mg of phosphorus, 12mg of magnesium, 144mg of potassium, iron 1.2mg, selenium 0.28mg; other ingredients include carotene and chlorophyll; citric acid, quinic acid and malic acid are the main acids in kiwifruit; it also contains a lot of sugars, mainly glucose, fructose, sucrose, polysaccharides and uronic acid In addition, kiwi fruit also contains dietary fiber and unsaturated fatty acids; kiwi fruit vitamin C content is particularly high, with a maximum content of 420 mg per 100 grams of fruit.
发明内容 Contents of the invention
本发明的目的是提供一种可食保鲜抗菌纸的制备方法,以这种方法制备的可食包装纸质地细腻、颜色深绿、具有猕猴桃的特殊清新芳香气味,对细菌具有一定的抑制作用,并可延长被包装食品的货架期,可作为休闲食品,以及方便食品、快餐食品、糕点、调味品等食品的内外包装。The purpose of the present invention is to provide a preparation method of edible fresh-keeping antibacterial paper. The edible wrapping paper prepared by this method is fine in texture, dark green in color, has the special fresh and fragrant smell of kiwi fruit, and has a certain inhibitory effect on bacteria. , and can prolong the shelf life of the packaged food, and can be used as the inner and outer packaging of snack food, convenience food, fast food, pastry, condiment and other foods.
为实现上述目的,本发明采用如下技术方案:一种可食保鲜抗菌纸的制备方法,其特征在于,其特征在于,选用新鲜、无变质猕猴桃,用清水洗净后,去除猕猴桃籽,沥干,95~100℃沸水中烫漂5~8min后打浆8~10min;浆液中加入3~6%(w/v)卡拉胶,1~3%(v/v)甘油,混合均匀后加入0.4~0.6%(w/v)壳聚糖,压模成型后得到可食保鲜抗菌纸。In order to achieve the above object, the present invention adopts the following technical scheme: a preparation method of edible fresh-keeping antibacterial paper, which is characterized in that fresh, non-deteriorated kiwi fruit is selected, and after being washed with clear water, the kiwi fruit seeds are removed and drained. , blanching in boiling water at 95-100°C for 5-8 minutes and then beating for 8-10 minutes; add 3-6% (w/v) carrageenan and 1-3% (v/v) glycerin to the slurry, mix well and add 0.4- 0.6% (w/v) chitosan, obtained edible fresh-keeping antibacterial paper after compression molding.
选用新鲜、无变质猕猴桃,用清水洗净后,去除猕猴桃籽,沥干,95~100℃沸水中烫漂5~8min后打浆8~10min。Choose fresh, non-deteriorated kiwi fruit, wash it with water, remove the kiwi fruit seeds, drain, blanch in boiling water at 95-100°C for 5-8 minutes, and then beat for 8-10 minutes.
猕猴桃浆液中加入3~6%(w/v)卡拉胶。3-6% (w/v) carrageenan is added to the kiwi pulp.
加入卡拉胶的猕猴桃浆液中加入1~3%(v/v)甘油。1-3% (v/v) glycerol is added to the kiwi fruit slurry added with carrageenan.
混合均匀后加入0.4~0.6%(w/v)壳聚糖,压模成型。After mixing uniformly, 0.4-0.6% (w/v) chitosan is added, and molded.
具体实施方式 Detailed ways
实施例1:选用新鲜、无变质猕猴桃,用清水洗净后,去除猕猴桃籽,沥干,95℃沸水中烫漂8min后打浆10min;浆液中加入4%(w/v)卡拉胶,1%(v/v)甘油,混合均匀后加入0.5%(w/v)壳聚糖,压模成型后得到可食保鲜抗菌纸。Embodiment 1: Select fresh, non-deteriorated kiwi fruit, after washing with clear water, remove the kiwi fruit seeds, drain, blanch in boiling water at 95°C for 8 minutes, and beat for 10 minutes; add 4% (w/v) carrageenan in the slurry, 1% (v/v) glycerin, after mixing evenly, add 0.5% (w/v) chitosan, obtain edible fresh-keeping antibacterial paper after compression molding.
实施例2:选用新鲜、无变质猕猴桃,用清水洗净后,去除猕猴桃籽,沥干,100℃沸水中烫漂7min后打浆9min;浆液中加入6%(w/v)卡拉胶,3%(v/v)甘油,混合均匀后加入0.6%(w/v)壳聚糖,压模成型后得到可食保鲜抗菌纸。Embodiment 2: select fresh, non-deteriorated kiwi fruit, after washing with clear water, remove the kiwi fruit seeds, drain, blanch in boiling water at 100°C for 7 minutes and then beating for 9 minutes; add 6% (w/v) carrageenan in the slurry, 3% (v/v) glycerin, after mixing evenly, add 0.6% (w/v) chitosan, obtain edible fresh-keeping antibacterial paper after compression molding.
实施例3:选用新鲜、无变质猕猴桃,用清水洗净后,去除猕猴桃籽,沥干,100℃沸水中烫漂6min后打浆8min;浆液中加入5%(w/v)卡拉胶,2%(v/v)甘油,混合均匀后加入0.4%(w/v)壳聚糖,压模成型后得到可食保鲜抗菌纸。Embodiment 3: select fresh, non-deteriorated kiwi fruit, after washing with clear water, remove the kiwi fruit seeds, drain, and beat for 8 minutes after blanching in boiling water at 100°C for 6 minutes; add 5% (w/v) carrageenan in the slurry, 2% (v/v) glycerin, after mixing evenly, add 0.4% (w/v) chitosan, obtain edible fresh-keeping antibacterial paper after compression molding.
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CN107200861A (en) * | 2017-06-21 | 2017-09-26 | 芜湖蓝天工程塑胶有限公司 | Composite antibacterial chitosan derivative fresh-keeping box and preparation method thereof |
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