CA1174818A - Process of producing high tenacity, high modulus crystalline thermoplastic article, and novel product fibers - Google Patents
Process of producing high tenacity, high modulus crystalline thermoplastic article, and novel product fibersInfo
- Publication number
- CA1174818A CA1174818A CA000401450A CA401450A CA1174818A CA 1174818 A CA1174818 A CA 1174818A CA 000401450 A CA000401450 A CA 000401450A CA 401450 A CA401450 A CA 401450A CA 1174818 A CA1174818 A CA 1174818A
- Authority
- CA
- Canada
- Prior art keywords
- solvent
- gel
- fiber
- denier
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 266
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 19
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims description 68
- 230000008569 process Effects 0.000 title claims description 46
- 239000002904 solvent Substances 0.000 claims abstract description 123
- -1 polyethylene Polymers 0.000 claims abstract description 92
- 239000004698 Polyethylene Substances 0.000 claims abstract description 59
- 229920000573 polyethylene Polymers 0.000 claims abstract description 54
- 229920000642 polymer Polymers 0.000 claims description 73
- 239000004743 Polypropylene Substances 0.000 claims description 24
- 238000002844 melting Methods 0.000 claims description 23
- 230000008018 melting Effects 0.000 claims description 23
- 229920001155 polypropylene Polymers 0.000 claims description 22
- 238000009835 boiling Methods 0.000 claims description 16
- 238000001035 drying Methods 0.000 claims description 15
- 238000001816 cooling Methods 0.000 claims description 13
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 10
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 150000002430 hydrocarbons Chemical group 0.000 claims description 7
- 239000011148 porous material Substances 0.000 claims description 7
- 229920006324 polyoxymethylene Polymers 0.000 claims description 6
- 238000011144 upstream manufacturing Methods 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 229930040373 Paraformaldehyde Natural products 0.000 claims description 4
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 2
- 229920000306 polymethylpentene Polymers 0.000 claims 2
- 108010025899 gelatin film Proteins 0.000 claims 1
- 239000000499 gel Substances 0.000 abstract description 139
- 239000000243 solution Substances 0.000 description 49
- 238000009987 spinning Methods 0.000 description 30
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 28
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 24
- 238000010791 quenching Methods 0.000 description 24
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 23
- 239000005662 Paraffin oil Substances 0.000 description 20
- 238000002156 mixing Methods 0.000 description 15
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- 239000000463 material Substances 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000007787 solid Substances 0.000 description 8
- 238000000605 extraction Methods 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 238000000638 solvent extraction Methods 0.000 description 6
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 5
- 239000000470 constituent Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 230000000875 corresponding effect Effects 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 230000002459 sustained effect Effects 0.000 description 4
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 4
- 238000013019 agitation Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000000543 intermediate Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241001274660 Modulus Species 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000002939 deleterious effect Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 238000007619 statistical method Methods 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- JHUUPUMBZGWODW-UHFFFAOYSA-N 3,6-dihydro-1,2-dioxine Chemical compound C1OOCC=C1 JHUUPUMBZGWODW-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- CYJRNFFLTBEQSQ-UHFFFAOYSA-N 8-(3-methyl-1-benzothiophen-5-yl)-N-(4-methylsulfonylpyridin-3-yl)quinoxalin-6-amine Chemical compound CS(=O)(=O)C1=C(C=NC=C1)NC=1C=C2N=CC=NC2=C(C=1)C=1C=CC2=C(C(=CS2)C)C=1 CYJRNFFLTBEQSQ-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- DEZRYPDIMOWBDS-UHFFFAOYSA-N dcm dichloromethane Chemical compound ClCCl.ClCCl DEZRYPDIMOWBDS-UHFFFAOYSA-N 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- USPLDBATMHXKKD-UHFFFAOYSA-N dichloromethane;pentane Chemical compound ClCCl.CCCCC USPLDBATMHXKKD-UHFFFAOYSA-N 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000012417 linear regression Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 231100000817 safety factor Toxicity 0.000 description 1
- 238000000646 scanning calorimetry Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 239000011240 wet gel Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
- D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US25926681A | 1981-04-30 | 1981-04-30 | |
US259,266 | 1981-04-30 | ||
US35902082A | 1982-03-19 | 1982-03-19 | |
US06/359,019 US4413110A (en) | 1981-04-30 | 1982-03-19 | High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore |
US359,019 | 1982-03-19 | ||
US359,020 | 1989-05-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1174818A true CA1174818A (en) | 1984-09-25 |
Family
ID=27401217
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000401450A Expired CA1174818A (en) | 1981-04-30 | 1982-04-22 | Process of producing high tenacity, high modulus crystalline thermoplastic article, and novel product fibers |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0064167B1 (es) |
JP (2) | JPS585228A (es) |
KR (1) | KR860000202B1 (es) |
AU (2) | AU549453B2 (es) |
CA (1) | CA1174818A (es) |
DE (1) | DE3267521D1 (es) |
ES (1) | ES513190A0 (es) |
Families Citing this family (81)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU549453B2 (en) * | 1981-04-30 | 1986-01-30 | Allied Corporation | High tenacity, high modulus, cyrstalline thermoplastic fibres |
US4543286A (en) * | 1982-03-19 | 1985-09-24 | Allied Corporation | Composite containing coated extended chain polyolefin fibers |
US4501856A (en) † | 1982-03-19 | 1985-02-26 | Allied Corporation | Composite containing polyolefin fiber and polyolefin polymer matrix |
US4599267A (en) * | 1982-09-30 | 1986-07-08 | Allied Corporation | High strength and modulus polyvinyl alcohol fibers and method of their preparation |
US4455273A (en) * | 1982-09-30 | 1984-06-19 | Allied Corporation | Producing modified high performance polyolefin fiber |
US4584347A (en) * | 1982-09-30 | 1986-04-22 | Allied Corporation | Modified polyolefin fiber |
JPS59187614A (ja) * | 1983-04-07 | 1984-10-24 | Mitsui Petrochem Ind Ltd | 超高分子量ポリエチレン延伸物の製造法 |
EP0115192B2 (en) * | 1982-12-28 | 1992-07-22 | Mitsui Petrochemical Industries, Ltd. | Process for producing stretched filaments of ultrahigh-molecular-weight polyethylene |
US5135804A (en) * | 1983-02-18 | 1992-08-04 | Allied-Signal Inc. | Network of polyethylene fibers |
DE3480796D1 (de) * | 1983-02-18 | 1990-01-25 | Allied Signal Inc | Verfestigung von polyaethylenfasernetzwerken. |
JPS59216912A (ja) * | 1983-05-20 | 1984-12-07 | Toyobo Co Ltd | 高強度・高弾性率ポリエチレン繊維の製造方法 |
JPS59227420A (ja) * | 1983-06-10 | 1984-12-20 | Mitsui Petrochem Ind Ltd | 超高分子量ポリオレフイン二軸延伸フイルム及びその製造方法 |
KR870001129B1 (ko) * | 1983-08-15 | 1987-06-09 | 도오요오 보오세끼 가부시끼가이샤 | 고강력, 고 모듈러스(modulus) 섬유 또는 필름 및 그 제조방법 |
JPS6045630A (ja) * | 1983-08-23 | 1985-03-12 | 東洋紡績株式会社 | ゲルフアイバ−の延伸方法 |
JPS6052613A (ja) * | 1983-08-30 | 1985-03-25 | Toyobo Co Ltd | 高強力、高弾性率ポリエチレン繊維 |
JPS59216914A (ja) * | 1983-10-22 | 1984-12-07 | Toyobo Co Ltd | 超高強力ポリエチレン繊維の製造方法 |
JPS59216913A (ja) * | 1983-10-22 | 1984-12-07 | Toyobo Co Ltd | 高強度・高弾性率ポリエチレン繊維 |
NL8304263A (nl) * | 1983-12-10 | 1985-07-01 | Stamicarbon | Werkwijze voor het bereiden van polyacrylonitrilfilamenten met hoge treksterkte en modulus. |
JPS60138507A (ja) * | 1983-12-27 | 1985-07-23 | Toyobo Co Ltd | ポリエチレン抗張力線 |
JPS60164421A (ja) * | 1984-02-07 | 1985-08-27 | 東洋紡績株式会社 | 新規な釣糸 |
JPS60173114A (ja) * | 1984-02-16 | 1985-09-06 | Toyobo Co Ltd | ゲル状成形体の処理方法 |
JPS60189420A (ja) * | 1984-03-09 | 1985-09-26 | Mitsui Petrochem Ind Ltd | 超高分子量ポリエチレンの延伸物の製造方法 |
JPS60190330A (ja) * | 1984-03-12 | 1985-09-27 | Mitsui Petrochem Ind Ltd | 超高分子量ポリエチレン延伸物の製造法 |
JPS60210425A (ja) * | 1984-04-04 | 1985-10-22 | Mitsui Petrochem Ind Ltd | ポリエチレン延伸物の製造方法 |
JPS60242035A (ja) * | 1984-04-27 | 1985-12-02 | Toa Nenryo Kogyo Kk | ポリエチレン微多孔膜の製造方法 |
JPS60239509A (ja) * | 1984-05-04 | 1985-11-28 | Toray Ind Inc | 高強度高モジユラスポリオレフイン系繊維の製造方法 |
JPH062841B2 (ja) * | 1984-05-31 | 1994-01-12 | 三菱化成株式会社 | 多孔化透過性ポリエチレンフイルム |
JPS6147809A (ja) * | 1984-08-06 | 1986-03-08 | Toray Ind Inc | 高強度高モジユラスポリオレフイン系繊維の製造方法 |
NL8402964A (nl) * | 1984-09-28 | 1986-04-16 | Stamicarbon | Werkwijze voor het bereiden van polyalkeenfilms met hoge treksterkte en hoge modulus. |
DE3577110D1 (de) * | 1984-09-28 | 1990-05-17 | Stamicarbon | Verfahren zur kontinuierlichen herstellung von homogenen loesungen von hochmolekularen polymeren. |
NL8402963A (nl) * | 1984-09-28 | 1986-04-16 | Stamicarbon | Werkwijze voor het bereiden van dunne films van hoogmolekulaire polyalkenen. |
US4663101A (en) * | 1985-01-11 | 1987-05-05 | Allied Corporation | Shaped polyethylene articles of intermediate molecular weight and high modulus |
US4623574A (en) * | 1985-01-14 | 1986-11-18 | Allied Corporation | Ballistic-resistant composite article |
JPH06102847B2 (ja) * | 1985-05-31 | 1994-12-14 | 三井石油化学工業株式会社 | プラスチツクワイヤ−及びその製造方法 |
DE3682241D1 (de) * | 1985-02-15 | 1991-12-05 | Toray Industries | Polyaethylen-multifilament-garn. |
NL8500477A (nl) * | 1985-02-20 | 1986-09-16 | Stamicarbon | Werkwijze voor het bereiden van polyolefine gelvoorwerpen, alsmede voor het hieruit bereiden van voorwerpen met hoge treksterkte en modulus. |
DE3676211D1 (de) * | 1985-02-25 | 1991-01-31 | Tonen Corp | Mikroporoese membran aus einem alpha-olefinpolymer mit ultrahoch-molekulargewicht. |
JPS61215708A (ja) * | 1985-03-19 | 1986-09-25 | Toray Ind Inc | マルチフイラメントヤ−ンの製造方法 |
JPH06102846B2 (ja) * | 1985-05-01 | 1994-12-14 | 三井石油化学工業株式会社 | 超高分子量ポリエチレン延伸物の製造方法 |
EP0205960B1 (en) * | 1985-06-17 | 1990-10-24 | AlliedSignal Inc. | Very low creep, ultra high moduls, low shrink, high tenacity polyolefin fiber having good strength retention at high temperatures and method to produce such fiber |
JPS623728A (ja) * | 1985-07-01 | 1987-01-09 | 旭化成株式会社 | 釣糸 |
US5032338A (en) * | 1985-08-19 | 1991-07-16 | Allied-Signal Inc. | Method to prepare high strength ultrahigh molecular weight polyolefin articles by dissolving particles and shaping the solution |
EP0212133B2 (en) * | 1985-08-19 | 1999-09-22 | AlliedSignal Inc. | Method to prepare high strength ultrahigh molecular weight polyolefin articles by dissolving particles and shaping the solution |
NL8502298A (nl) * | 1985-08-21 | 1987-03-16 | Stamicarbon | Werkwijze voor het vervaardigen van polyethyleenvoorwerpen met hoge treksterkte en modulus. |
EP0223291B1 (en) * | 1985-11-07 | 1991-07-31 | Akzo N.V. | Reinforcing element of synthetic material for use in reinforced concrete, more particularly prestressed concrete, reinforced concrete provided with such reinforcing elements, and processes of manufacturing reinforcing elements, and reinforced and prestressed concrete |
US4870136A (en) * | 1985-11-30 | 1989-09-26 | Mitsui Pertrochemical Industries, Ltd. | Molecular oriented, silane-crosslinked ultra-high-molecular-weight polyethylene molded article and process for preparation thereof |
JPS62141110A (ja) * | 1985-12-11 | 1987-06-24 | Canon Inc | ゲル繊維の製造方法 |
JPS62184110A (ja) * | 1986-02-06 | 1987-08-12 | Toray Ind Inc | 新規なポリエチレンフイラメント |
JPS63175111A (ja) * | 1987-01-09 | 1988-07-19 | Toyobo Co Ltd | 架橋された高強力,高弾性率ポリエチレン繊維 |
JPS63273651A (ja) * | 1987-04-30 | 1988-11-10 | Toa Nenryo Kogyo Kk | 超高分子量ポリエチレン微多孔膜の製造方法 |
JPS63288264A (ja) * | 1987-05-18 | 1988-11-25 | 三井化学株式会社 | フイラメント等の処理槽 |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE556923A (es) * | 1956-12-08 | |||
NL177759B (nl) * | 1979-06-27 | 1985-06-17 | Stamicarbon | Werkwijze ter vervaardiging van een polyetheendraad, en de aldus verkregen polyetheendraad. |
NL177840C (nl) * | 1979-02-08 | 1989-10-16 | Stamicarbon | Werkwijze voor het vervaardigen van een polyetheendraad. |
AU549453B2 (en) * | 1981-04-30 | 1986-01-30 | Allied Corporation | High tenacity, high modulus, cyrstalline thermoplastic fibres |
-
1982
- 1982-04-01 AU AU82254/82A patent/AU549453B2/en not_active Ceased
- 1982-04-07 EP EP82102964A patent/EP0064167B1/en not_active Expired
- 1982-04-07 DE DE8282102964T patent/DE3267521D1/de not_active Expired
- 1982-04-22 CA CA000401450A patent/CA1174818A/en not_active Expired
- 1982-04-29 KR KR8201890A patent/KR860000202B1/ko active
- 1982-04-30 JP JP57073297A patent/JPS585228A/ja active Pending
- 1982-05-22 ES ES513190A patent/ES513190A0/es active Granted
-
1985
- 1985-11-21 AU AU50242/85A patent/AU581702B2/en not_active Ceased
-
1992
- 1992-04-15 JP JP4095529A patent/JP2582985B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
KR860000202B1 (ko) | 1986-03-03 |
AU8225482A (en) | 1982-11-04 |
JP2582985B2 (ja) | 1997-02-19 |
KR830010224A (ko) | 1983-12-26 |
DE3267521D1 (en) | 1986-01-02 |
EP0064167B1 (en) | 1985-11-21 |
AU5024285A (en) | 1986-06-12 |
JPH05106107A (ja) | 1993-04-27 |
ES8306775A1 (es) | 1983-06-16 |
AU581702B2 (en) | 1989-03-02 |
ES513190A0 (es) | 1983-06-16 |
EP0064167A1 (en) | 1982-11-10 |
JPS585228A (ja) | 1983-01-12 |
AU549453B2 (en) | 1986-01-30 |
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