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BRPI0915369B8 - processo para enriquecimento do gás síntese em hidrogênio e uso de um catalisador contendo os óxidos de zinco e alumínio - Google Patents

processo para enriquecimento do gás síntese em hidrogênio e uso de um catalisador contendo os óxidos de zinco e alumínio Download PDF

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Publication number
BRPI0915369B8
BRPI0915369B8 BRPI0915369A BRPI0915369A BRPI0915369B8 BR PI0915369 B8 BRPI0915369 B8 BR PI0915369B8 BR PI0915369 A BRPI0915369 A BR PI0915369A BR PI0915369 A BRPI0915369 A BR PI0915369A BR PI0915369 B8 BRPI0915369 B8 BR PI0915369B8
Authority
BR
Brazil
Prior art keywords
synthesis gas
catalyst containing
containing zinc
aluminum oxides
hydrogen synthesis
Prior art date
Application number
BRPI0915369A
Other languages
English (en)
Inventor
Christian Schiødt Niels
Original Assignee
Haldor Topsoe As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haldor Topsoe As filed Critical Haldor Topsoe As
Publication of BRPI0915369A2 publication Critical patent/BRPI0915369A2/pt
Publication of BRPI0915369B1 publication Critical patent/BRPI0915369B1/pt
Publication of BRPI0915369B8 publication Critical patent/BRPI0915369B8/pt

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C01B2203/041—In-situ membrane purification during hydrogen production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1076—Copper or zinc-based catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1094—Promotors or activators
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

processo para enriquecimento do gás de síntese em hidrogênio e uso de um catalisador contendo os óxidos de zinco e alumínio processo para enriquecer um gás de síntese em hidrogênio pela conversão de monóxido de carbono e vapor de água em um catalisador contendo os óxidos de zinco e alumínio, com um ou mais promotores.
BRPI0915369A 2008-07-03 2009-06-15 processo para enriquecimento do gás síntese em hidrogênio e uso de um catalisador contendo os óxidos de zinco e alumínio BRPI0915369B8 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DKPA200800935 2008-07-03
DKPA200800935 2008-07-03
PCT/EP2009/004288 WO2010000387A1 (en) 2008-07-03 2009-06-15 Process for operating hts reactor

Publications (3)

Publication Number Publication Date
BRPI0915369A2 BRPI0915369A2 (pt) 2015-11-03
BRPI0915369B1 BRPI0915369B1 (pt) 2019-09-24
BRPI0915369B8 true BRPI0915369B8 (pt) 2020-02-04

Family

ID=40983342

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0915369A BRPI0915369B8 (pt) 2008-07-03 2009-06-15 processo para enriquecimento do gás síntese em hidrogênio e uso de um catalisador contendo os óxidos de zinco e alumínio

Country Status (12)

Country Link
US (1) US8404156B2 (pt)
EP (2) EP2300359B1 (pt)
KR (1) KR101529906B1 (pt)
CN (1) CN102083745B (pt)
BR (1) BRPI0915369B8 (pt)
CA (1) CA2729736C (pt)
ES (2) ES2549382T3 (pt)
MX (1) MX2010014351A (pt)
PL (2) PL2924002T3 (pt)
RU (1) RU2516546C2 (pt)
WO (1) WO2010000387A1 (pt)
ZA (1) ZA201009233B (pt)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2008313C2 (en) 2012-02-17 2013-09-02 Stichting Energie Water gas shift process.
GB201501952D0 (en) * 2015-02-05 2015-03-25 Johnson Matthey Plc Process
GB201519139D0 (en) 2015-10-29 2015-12-16 Johnson Matthey Plc Process
MX394205B (es) 2015-10-29 2025-03-21 Johnson Matthey Plc Catalizador de desplazamiento de gas de agua.
GB201519133D0 (en) 2015-10-29 2015-12-16 Johnson Matthey Plc Process
CA3010549C (en) * 2016-02-02 2023-01-17 Haldor Topsoe A/S Atr based ammonia process and plant
GB201603298D0 (en) 2016-02-25 2016-04-13 Johnson Matthey Plc Process
AR107702A1 (es) * 2016-02-29 2018-05-23 Haldor Topsoe As Renovación con baja cantidad de vapor / carbono
US11027984B2 (en) * 2017-03-07 2021-06-08 Haldor Topsoe A/S Urea process with controlled excess of CO2 and/or NH3
CA3069493A1 (en) 2017-07-13 2019-01-17 Haldor Topsoe A/S Method and catalysts for the production of ammonia synthesis gas
CN108435182B (zh) * 2017-08-16 2021-01-15 西安向阳航天材料股份有限公司 一种铜系低温变换催化剂的制备方法
PL235786B1 (pl) * 2017-09-29 2020-10-19 Grupa Azoty Spolka Akcyjna Promotowany katalizator cynkowy parowej konwersji tlenku węgla i sposób jego otrzymywania
PL234182B1 (pl) * 2017-09-29 2020-01-31 Inst Nowych Syntez Chemicznych Promotowany katalizator cynkowy parowej konwersji tlenku węgla i sposób jego otrzymywania
DK181937B1 (en) 2020-10-08 2025-04-04 Petroleo Brasileiro Sa Petrobras Methods for preparing high temperature water gas shifting catalyst, catalyst and process for reducing carbon monoxide
WO2022112310A1 (en) 2020-11-24 2022-06-02 Topsoe A/S Improved water gas shift catalyst
US20240002223A1 (en) 2020-11-24 2024-01-04 Topsoe A/S Method of starting-up a water gas shift reactor
US20240002224A1 (en) 2020-11-24 2024-01-04 Topsoe A/S Process For Producing Hydrogen From CO-rich Gases
CN116981513A (zh) * 2020-12-09 2023-10-31 巴西石油公司 通过高温水煤气变换制备催化剂的方法和降低一氧化碳含量的方法
US20240116756A1 (en) 2022-10-06 2024-04-11 Air Products And Chemicals, Inc. Process and System for Water-Gas Shift Conversion of Synthesis Gas with High CO Concentration

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2567866B1 (fr) * 1984-07-20 1987-01-02 Shell Int Research Procede de preparation d'un gaz riche en hydrogene
GB8817480D0 (en) 1988-07-22 1988-08-24 Ici Plc Hydrogen
DE68905891T2 (de) * 1988-07-22 1993-10-14 Ici Plc Erzeugung von Wasserstoff welche Kohlenmonoxidkonvertierung mittels Wasserdampf umfasst.
GB9225372D0 (en) * 1992-12-04 1993-01-27 British Petroleum Co Plc Oxide compositions
EP1149799B1 (en) * 2000-04-27 2003-10-08 Haldor Topsoe A/S Process for the production of a hydrogen rich gas
GB0121680D0 (en) * 2001-09-08 2001-10-31 Ici Plc Catalysts
US6627572B1 (en) * 2002-03-22 2003-09-30 Sud-Chemie Inc. Water gas shift catalyst
US20040105804A1 (en) * 2002-11-29 2004-06-03 Industrial Technology Research Institute Catalyst for water-gas shift reaction and method for converting carbon monoxide and water to hydrogen and carbon dioxide
ATE548324T1 (de) * 2003-02-05 2012-03-15 Haldor Topsoe As Verfahren zur aufbereitung von synthesegas
JP2004321924A (ja) * 2003-04-24 2004-11-18 Toyota Central Res & Dev Lab Inc 水性ガスシフト反応用触媒

Also Published As

Publication number Publication date
CN102083745B (zh) 2014-04-02
CA2729736A1 (en) 2010-01-07
PL2924002T3 (pl) 2019-09-30
US8404156B2 (en) 2013-03-26
RU2516546C2 (ru) 2014-05-20
KR20110039422A (ko) 2011-04-18
PL2300359T3 (pl) 2016-01-29
EP2924002A1 (en) 2015-09-30
RU2011103674A (ru) 2012-08-10
EP2300359A1 (en) 2011-03-30
AU2009266113A1 (en) 2010-01-07
CA2729736C (en) 2015-09-15
MX2010014351A (es) 2011-05-03
BRPI0915369A2 (pt) 2015-11-03
CN102083745A (zh) 2011-06-01
WO2010000387A1 (en) 2010-01-07
KR101529906B1 (ko) 2015-06-18
EP2300359B1 (en) 2015-08-26
BRPI0915369B1 (pt) 2019-09-24
ES2549382T3 (es) 2015-10-27
EP2924002B1 (en) 2019-04-24
US20110101279A1 (en) 2011-05-05
ES2728916T3 (es) 2019-10-29
ZA201009233B (en) 2012-04-25

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