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ATE324943T1 - Chirale phosphine, deren komplexe mit übergangsmetallen und deren verwendung in asymmetrischen synthesereaktionen - Google Patents

Chirale phosphine, deren komplexe mit übergangsmetallen und deren verwendung in asymmetrischen synthesereaktionen

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Publication number
ATE324943T1
ATE324943T1 AT00965136T AT00965136T ATE324943T1 AT E324943 T1 ATE324943 T1 AT E324943T1 AT 00965136 T AT00965136 T AT 00965136T AT 00965136 T AT00965136 T AT 00965136T AT E324943 T1 ATE324943 T1 AT E324943T1
Authority
AT
Austria
Prior art keywords
chiral
ligands
phosphins
complexes
asymmetric
Prior art date
Application number
AT00965136T
Other languages
English (en)
Inventor
Xumu Zhang
Original Assignee
Penn State Res Found
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Penn State Res Found filed Critical Penn State Res Found
Application granted granted Critical
Publication of ATE324943T1 publication Critical patent/ATE324943T1/de

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    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
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    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
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    • B01J31/1625Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
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AT00965136T 1999-09-20 2000-09-19 Chirale phosphine, deren komplexe mit übergangsmetallen und deren verwendung in asymmetrischen synthesereaktionen ATE324943T1 (de)

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Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2812638B1 (fr) 2000-08-03 2003-04-25 Ppg Sipsy Utilisation de diphosphines chirales comme ligands optiquement actifs pour la preparation de complexes diphosphino-metalliques, les complexes ainsi obtenus et les procedes de catalyse asymetrique les mettant en oeuvre
US6350819B1 (en) 2000-10-27 2002-02-26 Union Carbide Chemicals & Plastics Technology Corporation Dendritic macromolecules for metal-ligand catalyzed processes
AU2002342362A1 (en) * 2001-11-15 2003-05-26 Sasol Technology (Pty) Ltd Preparation of derivatives of a group 5a element
JP4176022B2 (ja) 2002-03-11 2008-11-05 独立行政法人科学技術振興機構 実用的キラルジルコニウム触媒
JP4148702B2 (ja) 2002-06-04 2008-09-10 高砂香料工業株式会社 新規なジホスフィン化合物、その製造中間体、該化合物を配位子とする遷移金属錯体並びに該錯体を含む不斉水素化触媒
JP4218261B2 (ja) * 2002-06-11 2009-02-04 ダイキン工業株式会社 ポンプユニット
GB0228018D0 (en) * 2002-11-30 2003-01-08 Lucite Int Uk Ltd Carbonylation of ester
WO2004024322A2 (en) * 2002-09-12 2004-03-25 Lucite International Uk Limited A catalyst system comprising a 1,2-bis-(phosphinoalkyl) ferrocene ligand
WO2004084834A2 (en) * 2003-03-24 2004-10-07 The University Of North Carolina At Chapel Hill Chiral porous metal phosphonates for heterogeneous asymmetric catalysis
US6878838B2 (en) 2003-03-24 2005-04-12 The University Of North Carolina At Chapel Hill Chiral porous metal phosphonates for heterogeneous asymmetric catalysis
EP1636243B1 (de) 2003-06-13 2013-11-06 Boehringer Ingelheim International GmbH Chirale liganden zur anwendung in asymmetrischen synthesen
JP2007516197A (ja) 2003-07-03 2007-06-21 ルーサイト インターナショナル ユーケー リミテッド エチレン性不飽和化合物のヒドロホルミル化方法
US7094725B2 (en) * 2003-07-11 2006-08-22 The Hong Kong Polytechnic University Biphenyldiphosphine compounds
DE10342672A1 (de) 2003-09-16 2005-04-21 Bayer Chemicals Ag Chirale Phosphane zur Verwendung in asymmetrischen Synthesen
GB0403592D0 (en) 2004-02-18 2004-03-24 Lucite Int Uk Ltd A catalyst system
EP1737471A4 (de) * 2004-04-20 2010-08-25 Rnd Pharmaceuticals Pharmazeutische vorrichtungen und verfahren zur verwendung von lipophilen, mit silikon substituierten cyclooxygenase-2-selektiven nichtsteroidalen entzündungshemmern und derivaten
GB0411951D0 (en) * 2004-05-28 2004-06-30 Lucite Int Uk Ltd Carbonylation of ester
DE102005030400A1 (de) * 2005-06-27 2006-12-28 Archimica Gmbh Verfahren zur Herstellung von Arylaminen, Arylethern und Arylthioethern
GB0516556D0 (en) * 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
MY154959A (en) 2005-11-17 2015-08-28 Lucite Int Uk Ltd Carbonylation of ethylenically unsaturated compounds
JP4621918B2 (ja) * 2005-12-09 2011-02-02 国立大学法人 千葉大学 新規不斉イリジウム触媒の製造方法とこれらを用いる光学活性β−ヒドロキシ−α−アミノ酸誘導体の製造方法
ES2427118T5 (es) * 2005-12-15 2024-03-15 Penn State Res Found Ligandos tetrafosforosos para hidroformilación catalítica y reacciones relacionadas
WO2007073699A1 (fr) * 2005-12-29 2007-07-05 Shanghai Jiaotong University Ligands chiraux de 1,1'-biphenyle axial 5,5'-lie et procedes de preparation de ceux-ci
CN100349880C (zh) * 2005-12-29 2007-11-21 上海交通大学 2,2’,6,6’-四噁唑啉联苯配体及其制备方法
CN100348597C (zh) * 2005-12-29 2007-11-14 上海交通大学 5,5’位连接的1, 1’-联苯类轴手性配体的合成方法
JP5116694B2 (ja) * 2006-01-19 2013-01-09 エージェンシー フォー サイエンス,テクノロジー アンド リサーチ 不均一キラル触媒
GB0607494D0 (en) 2006-04-13 2006-05-24 Lucite Int Uk Ltd Metal complexes
CN105153241B (zh) * 2006-12-02 2020-05-15 卢西特国际英国有限公司 羰基化配体及其在羰基化烯键式不饱和化合物中的用途
GB0625518D0 (en) * 2006-12-21 2007-01-31 Lucite Int Uk Ltd Carbonylation of conjugated dienes
RU2010142900A (ru) * 2008-03-19 2012-04-27 Биал-Портела Энд Ка., С.А. (Pt) Способ каталитического ассиметрического гидрирования
GB0812297D0 (en) * 2008-07-04 2008-08-13 Lucite Int Uk Ltd Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds
JP5011262B2 (ja) * 2008-10-31 2012-08-29 高砂香料工業株式会社 ホスフィン化合物
JP5544756B2 (ja) * 2009-05-18 2014-07-09 東ソー株式会社 ホスフィン化合物及び該ホスフィン化合物と遷移金属化合物からなる触媒
FR2952638A1 (fr) 2009-11-17 2011-05-20 Univ Strasbourg Procede de phosphination catalytique double ou triple de composes di, tri ou tetrahalobiaryles, intermediaires employes, composes obtenus et leurs utilisations
GB201000078D0 (en) 2010-01-05 2010-02-17 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands
BR112012022985A2 (pt) * 2010-03-12 2019-09-24 Councl Of Scient & Industrial Research catalisador heterogêneo quiral por reação de nitroaldol assimétrica.
CN103827126B (zh) * 2011-11-18 2017-05-17 株式会社艾迪科 新型化合物和担载该新型化合物的担载体
CN102592837B (zh) * 2012-03-12 2014-01-15 河北师范大学 制备超级电容器用四氯合金属季铵盐掺杂聚苯胺电极的方法
GB201316410D0 (en) 2013-09-13 2013-10-30 Bial Portela & Ca Sa Processes for preparing peripherally-selective inhibitors of dopamine-?-hydroxylase and intermediates for use therein
CN105985469B (zh) * 2015-02-11 2018-07-10 中国石油天然气股份有限公司 聚丙烯催化剂及其制备方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0398132B1 (de) * 1989-05-18 1995-09-20 F. Hoffmann-La Roche Ag Phosphorverbindungen
ES2091509T3 (es) * 1992-04-16 1996-11-01 Hoffmann La Roche Procedimiento para la obtencion de derivados de isopreno.
US5481008A (en) * 1993-09-13 1996-01-02 Hoffmann-La Roche Inc. Process for the preparation of optically active compounds
DE4422672A1 (de) * 1994-06-30 1996-01-04 Hoechst Ag Halogenierte Biphenyl-2,2'-diyl-bis-diphenylphosphine, ihre Herstellung und ihre Verwendung
IT1270082B (it) 1994-07-12 1997-04-28 Univ Degli Studi Milano Difosfine eteroaromatiche come leganti chirali, complessi tra dette difosfine e metalli di transizione ed impiego di detti complessi come catalizzatori chirali
JP3899542B2 (ja) * 1995-02-24 2007-03-28 日産化学工業株式会社 光学活性二座ホスフィン配位子パラジウム錯体
DE69627834T2 (de) 1995-02-24 2004-04-08 Nissan Chemical Industries, Ltd. Optisch aktiver zweizähniger phosphinligand-palladiumkomplex
US5624128A (en) 1995-03-06 1997-04-29 Owens; Jesse L. Transport system for disabled people
ATE186718T1 (de) * 1995-06-21 1999-12-15 Rolic Ag Herstellung von chiralen alpha- halogencarbonsäuren
JP3493266B2 (ja) * 1996-08-27 2004-02-03 高砂香料工業株式会社 新規な光学活性ジホスフィン化合物、該化合物を製造す る方法、該化合物を配位子とする遷移金属錯体並びに該 錯体を用いた光学活性体の製造方法
CA2290009A1 (en) * 1998-11-19 2000-05-19 Rhony Niklaus Aufdenblatten Chiral diphenyldiphosphines and d-8 metal complexes thereof
ES2243171T3 (es) * 1999-06-17 2005-12-01 Firmenich Sa Isomerizacion estereoespecifica de aminas alilicas con la ayuda de ligandos fosforados quirales.
JP2001131192A (ja) * 1999-10-29 2001-05-15 Takasago Internatl Corp 新規な光学活性ジホスフィン化合物、その製造中間体、該化合物を配位子とする遷移金属錯体並びに該錯体を含む不斉水素化触媒。

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EP1214328B1 (de) 2006-05-03
ES2263487T3 (es) 2006-12-16
US6521769B1 (en) 2003-02-18
CA2385421C (en) 2009-12-15
CA2385421A1 (en) 2001-03-29
WO2001021625A1 (en) 2001-03-29
DE60027734D1 (de) 2006-06-08
AU7590600A (en) 2001-04-24
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EP1214328A4 (de) 2002-11-27
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