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ATE264268T1 - Verfahren zur herstellung von zsm-5 und zsm-11 - Google Patents

Verfahren zur herstellung von zsm-5 und zsm-11

Info

Publication number
ATE264268T1
ATE264268T1 AT00945366T AT00945366T ATE264268T1 AT E264268 T1 ATE264268 T1 AT E264268T1 AT 00945366 T AT00945366 T AT 00945366T AT 00945366 T AT00945366 T AT 00945366T AT E264268 T1 ATE264268 T1 AT E264268T1
Authority
AT
Austria
Prior art keywords
zsm
producing
nnmhq
c2h6n
synthesis
Prior art date
Application number
AT00945366T
Other languages
English (en)
Inventor
Carrie L Kennedy
Louis D Rollmann
John L Schlenker
Original Assignee
Exxonmobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Oil Corp filed Critical Exxonmobil Oil Corp
Application granted granted Critical
Publication of ATE264268T1 publication Critical patent/ATE264268T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/365—Type ZSM-8; Type ZSM-11; ZSM 5/11 intermediate
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • C01B39/40—Type ZSM-5 using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/22—MFI, e.g. ZSM-5. silicalite, LZ-241
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/29—MEL, e.g. ZSM-11

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Inorganic Insulating Materials (AREA)
AT00945366T 1999-07-13 2000-07-13 Verfahren zur herstellung von zsm-5 und zsm-11 ATE264268T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/351,850 US6277355B1 (en) 1999-07-13 1999-07-13 Synthesis of ZSM-5 and ZSM-11
PCT/US2000/019058 WO2001004051A1 (en) 1999-07-13 2000-07-13 Synthesis of zsm-5 and zsm-11

Publications (1)

Publication Number Publication Date
ATE264268T1 true ATE264268T1 (de) 2004-04-15

Family

ID=23382682

Family Applications (1)

Application Number Title Priority Date Filing Date
AT00945366T ATE264268T1 (de) 1999-07-13 2000-07-13 Verfahren zur herstellung von zsm-5 und zsm-11

Country Status (15)

Country Link
US (1) US6277355B1 (de)
EP (1) EP1200347B1 (de)
JP (1) JP4744756B2 (de)
KR (1) KR100681587B1 (de)
CN (1) CN1164491C (de)
AT (1) ATE264268T1 (de)
AU (1) AU5932300A (de)
CA (1) CA2379364C (de)
DE (1) DE60009910T2 (de)
DK (1) DK1200347T3 (de)
MX (1) MXPA02000371A (de)
RU (1) RU2243156C2 (de)
TW (1) TWI234547B (de)
WO (1) WO2001004051A1 (de)
ZA (1) ZA200200144B (de)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6419894B1 (en) * 2000-12-22 2002-07-16 California Institute Of Technology Process for preparing zeolites having MEL structure using 2,2-diethoxyethyltrimethylammonium structure directing agent
US7132042B2 (en) * 2002-10-08 2006-11-07 Exxonmobil Research And Engineering Company Production of fuels and lube oils from fischer-tropsch wax
US6846778B2 (en) * 2002-10-08 2005-01-25 Exxonmobil Research And Engineering Company Synthetic isoparaffinic premium heavy lubricant base stock
US20040065584A1 (en) * 2002-10-08 2004-04-08 Bishop Adeana Richelle Heavy lube oil from fischer- tropsch wax
US7201838B2 (en) * 2002-10-08 2007-04-10 Exxonmobil Research And Engineering Company Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product
US7344631B2 (en) * 2002-10-08 2008-03-18 Exxonmobil Research And Engineering Company Oxygenate treatment of dewaxing catalyst for greater yield of dewaxed product
WO2006050820A1 (de) 2004-11-12 2006-05-18 Süd-Chemie AG Verfahren zur synthese von zeolith beta mit diethylentriamin
CN100372769C (zh) * 2004-12-16 2008-03-05 复旦大学 一种用于合成纳米/亚微米高硅zsm-5沸石的非晶态无机结构导向剂及其制备方法
CN101941710B (zh) * 2009-07-06 2012-02-08 中国石油化工股份有限公司 多孔材料及其合成方法
KR101614544B1 (ko) * 2009-10-20 2016-04-22 에스케이이노베이션 주식회사 나노 크기의 결정성 ｚｓｍ－５ 핵을 사용한 ｚｓｍ－５의 제조 방법
WO2011112503A1 (en) 2010-03-08 2011-09-15 Dow Global Technologies Llc Catalyst composition for direct conversion of ethanol to propylene
CN102372580B (zh) * 2010-08-23 2014-01-22 中国石油化工股份有限公司 苯与乙醇烷基化的方法
CN102502696B (zh) * 2011-11-16 2014-04-23 大连理工大学 一种zsm-5沸石的合成方法
CA2891025C (en) * 2012-12-07 2019-07-30 Exxonmobil Research And Engineering Company Synthesis of zsm-5 crystals with improved morphology
CN104624226B (zh) * 2013-11-13 2017-04-05 中国石油天然气股份有限公司 一种zsm‑5 和zsm‑11 共晶沸石分子筛及其制备和应用
RU2544017C1 (ru) * 2014-01-28 2015-03-10 Ольга Васильевна Малова Катализатор и способ ароматизации с3-с4 газов, легких углеводородных фракций алифатических спиртов, а также их смесей
CN106673002B (zh) * 2015-11-09 2018-11-20 中国石油化工股份有限公司 Zsm-11/zsm-5复合分子筛的合成方法及其合成的复合分子筛
CN106672999B (zh) * 2015-11-09 2018-10-23 中国石油化工股份有限公司 含卤素和稀土金属的zsm-11/zsm-5复合分子筛的合成方法及其合成的复合分子筛
CN106673001B (zh) * 2015-11-09 2018-11-20 中国石油化工股份有限公司 Zsm-11分子筛的合成方法及其合成的zsm-11分子筛
RU2712549C1 (ru) * 2018-11-29 2020-01-29 Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) Способ получения цеолита типа mel
EP3947325A1 (de) 2019-03-29 2022-02-09 ExxonMobil Chemical Patents Inc. Neuartiges zeolith, verfahren zur herstellung davon und verwendung davon in der umwandlung von aromatischen kohlenwasserstoffen
CN113543879A (zh) 2019-03-29 2021-10-22 埃克森美孚化学专利公司 用于转化芳族烃的mel型沸石、所述沸石的制备方法及包含所述沸石的催化组合物
US20230212094A1 (en) * 2020-04-17 2023-07-06 Exxonmobil Chemical Patents Inc. Processes for converting c8 aromatic hydrocarbons
JP2023543595A (ja) * 2020-09-30 2023-10-17 エクソンモービル ケミカル パテンツ インコーポレイテッド Ｃ８芳香族炭化水素の変換プロセス

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3709979A (en) 1970-04-23 1973-01-09 Mobil Oil Corp Crystalline zeolite zsm-11
CA1040187A (en) 1973-09-07 1978-10-10 Mobil Oil Corporation Method of preparing a crystalline aluminosilicate zeolite
US4139600A (en) 1977-04-22 1979-02-13 Mobil Oil Corporation Synthesis of zeolite ZSM-5
US4296083A (en) * 1977-04-22 1981-10-20 Mobil Oil Corporation Zeolite synthesis
US4108881A (en) 1977-08-01 1978-08-22 Mobil Oil Corporation Synthesis of zeolite ZSM-11
US4229424A (en) 1979-04-09 1980-10-21 Mobil Oil Corporation Crystalline zeolite product constituting ZSM-5/ZSM-11 intermediates
NL8006977A (nl) * 1979-12-26 1981-07-16 Chevron Res Werkwijze ter bereiding van kristallijne zeolieten.
DE3006471A1 (de) * 1980-02-21 1981-08-27 Basf Ag, 6700 Ludwigshafen Kristalline isotaktische zeolithe, verfahren zur herstellung derselben sowie deren verwendung als katalysatoren
DE3021580A1 (de) * 1980-06-07 1981-12-24 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von zeolithen und verwendung derselben als katalysatoren
DE3031557C2 (de) * 1980-08-21 1986-05-22 Basf Ag, 6700 Ludwigshafen Kristalliner Borsilikatzeolith ZBM-30 und Verfahren zu seiner Herstellung
NZ208688A (en) * 1983-06-30 1987-10-30 Mobil Oil Corp Preparing siliceous porous crystalline zeolites
DE3402842A1 (de) * 1984-01-27 1985-08-08 Süd-Chemie AG, 8000 München Verfahren zur herstellung von kristallinen zeolithischen alumosilicaten
US4565681A (en) 1984-05-03 1986-01-21 Mobil Oil Corporation Synthetic zeolite ZSM-5 having a dimethylethylpropylammonium component
US5174977A (en) 1991-10-04 1992-12-29 Mobil Oil Corp. Synthesis of crystalline ZSM-5-type material
US5369071A (en) 1992-12-11 1994-11-29 Mobil Oil Corporation Manufacture of improved catalyst
DE4323774A1 (de) * 1993-07-15 1995-02-09 Basf Ag Hohlkugelartig agglomerierte Pentasilzeolithe
CN1041399C (zh) * 1994-12-30 1998-12-30 中国石油化工总公司 一种含稀土的结晶硅酸铝沸石
CN1260126C (zh) * 1999-04-21 2006-06-21 中国石油化工集团公司 超细颗粒五元环型沸石的制备方法

Also Published As

Publication number Publication date
JP4744756B2 (ja) 2011-08-10
DK1200347T3 (da) 2004-08-09
WO2001004051A1 (en) 2001-01-18
ZA200200144B (en) 2002-10-30
JP2003504299A (ja) 2003-02-04
WO2001004051A9 (en) 2002-08-08
RU2243156C2 (ru) 2004-12-27
TWI234547B (en) 2005-06-21
US6277355B1 (en) 2001-08-21
AU5932300A (en) 2001-01-30
EP1200347B1 (de) 2004-04-14
DE60009910D1 (de) 2004-05-19
KR20020048374A (ko) 2002-06-22
CA2379364C (en) 2008-09-30
KR100681587B1 (ko) 2007-02-09
EP1200347A1 (de) 2002-05-02
MXPA02000371A (es) 2005-04-08
CN1164491C (zh) 2004-09-01
CA2379364A1 (en) 2001-01-18
CN1367758A (zh) 2002-09-04
DE60009910T2 (de) 2005-03-10

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