[go: up one dir, main page]

ATE142651T1 - Katalysator und prepolymer für herstellung von polyolefinen - Google Patents

Katalysator und prepolymer für herstellung von polyolefinen

Info

Publication number
ATE142651T1
ATE142651T1 AT90313569T AT90313569T ATE142651T1 AT E142651 T1 ATE142651 T1 AT E142651T1 AT 90313569 T AT90313569 T AT 90313569T AT 90313569 T AT90313569 T AT 90313569T AT E142651 T1 ATE142651 T1 AT E142651T1
Authority
AT
Austria
Prior art keywords
catalyst
prepolymer
solid catalyst
copolymer
ethylene
Prior art date
Application number
AT90313569T
Other languages
English (en)
Inventor
Jean-Claude Andre Bp Ch Bailly
Philippe Bres
Christine Chabrand
Erick Daire
Original Assignee
Bp Chem Int Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd
Application granted granted Critical
Publication of ATE142651T1 publication Critical patent/ATE142651T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
AT90313569T 1989-12-22 1990-12-13 Katalysator und prepolymer für herstellung von polyolefinen ATE142651T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8917402A FR2656314B1 (fr) 1989-12-22 1989-12-22 Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.

Publications (1)

Publication Number Publication Date
ATE142651T1 true ATE142651T1 (de) 1996-09-15

Family

ID=9389117

Family Applications (1)

Application Number Title Priority Date Filing Date
AT90313569T ATE142651T1 (de) 1989-12-22 1990-12-13 Katalysator und prepolymer für herstellung von polyolefinen

Country Status (19)

Country Link
US (2) US5106804A (de)
EP (1) EP0436326B1 (de)
JP (1) JPH04211404A (de)
KR (1) KR910011913A (de)
CN (1) CN1053433A (de)
AT (1) ATE142651T1 (de)
AU (1) AU646004B2 (de)
CA (1) CA2032619A1 (de)
DE (1) DE69028509T2 (de)
ES (1) ES2091229T3 (de)
FI (1) FI906298L (de)
FR (1) FR2656314B1 (de)
HU (1) HU208981B (de)
MY (1) MY105298A (de)
NO (1) NO176571C (de)
PL (1) PL288414A1 (de)
PT (1) PT96343B (de)
SG (1) SG44346A1 (de)
ZA (1) ZA9010048B (de)

Families Citing this family (154)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6025448A (en) 1989-08-31 2000-02-15 The Dow Chemical Company Gas phase polymerization of olefins
FR2659336B1 (fr) * 1990-03-12 1993-05-07 Bp Chemicals Snc Catalyseur a base de zirconium, de titane et/ou de vanadium, supporte sur un chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
FR2659337B1 (fr) * 1990-03-12 1992-06-05 Bp Chemicals Snc Procede de preparation d'un catalyseur a base de zirconium, de titane et/ou de vanadium supporte sur du chlorure de magnesium, et utilisation du catalyseur dans la polymerisation des olefines.
IT1240613B (it) * 1990-03-26 1993-12-17 Enichem Anic Spa Catalizzatore supportato per la polimerizzazione e la copolimerizzazione di composti olefinicamente insaturi, e procedimento di (co) polimerizzazione impiegante lo stesso
US6538080B1 (en) 1990-07-03 2003-03-25 Bp Chemicals Limited Gas phase polymerization of olefins
US5436305A (en) * 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
EP0578838A1 (de) * 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Katalysator für die Olefinpolymerisation, Verfahren zu seiner Herstellung und seine Verwendung
ES2101113T3 (es) * 1992-05-28 1997-07-01 Idemitsu Petrochemical Co Procedimiento de produccion de poliolefina.
US5608019A (en) * 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
EP0699212A1 (de) * 1993-04-26 1996-03-06 Exxon Chemical Patents Inc. Polymerisation von monomeren im wirbelbett
US5397757A (en) * 1993-10-27 1995-03-14 Mobil Oil Corporation Cocatalysts for metallocene-based olefin polymerization catalyst systems
DE4337985A1 (de) * 1993-11-06 1995-05-11 Hoechst Ag Verfahren zur Herstellung eines Poly-1-olefins
FI95276C (fi) * 1993-12-03 1996-01-10 Borealis As Olefiinien polymerointikatalyytti ja menetelmä sen valmistamiseksi
IT1269931B (it) * 1994-03-29 1997-04-16 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1269837B (it) * 1994-05-26 1997-04-15 Spherilene Srl Componenti e catalizzatori per la polimerizzazione delle olefine
US5498581A (en) * 1994-06-01 1996-03-12 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
US5468702A (en) * 1994-07-07 1995-11-21 Exxon Chemical Patents Inc. Method for making a catalyst system
US5712353A (en) * 1994-10-31 1998-01-27 Exxon Chemical Patents Inc. Gas phase polymerization process
TW369547B (en) * 1994-09-21 1999-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization
US5585184A (en) * 1994-09-29 1996-12-17 Union Carbide Chemicals & Plastics Technology Corporation Colorable non-sticky resin core-shell particles
CN1044609C (zh) * 1994-11-07 1999-08-11 中国科学院化学研究所 乙烯聚合载体锆茂催化剂体系及其制法和用途
US5670589A (en) * 1995-02-08 1997-09-23 Phillips Petroleum Company Organoaluminoxy product, catalyst systems, preparation, and use
US6533988B2 (en) 1995-05-02 2003-03-18 Borealis Technology Oy Rotational moulding process of ethylene polymers or copolymers having a controlled particle size and morphology
FI105195B (fi) * 1995-05-02 2000-06-30 Borealis As Polyeteeni, jolla on hallittu partikkelikoko ja morfologia
US5705578A (en) * 1995-05-04 1998-01-06 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
US6399533B2 (en) * 1995-05-25 2002-06-04 Basell Technology Company Bv Compounds and catalysts for the polymerization of olefins
US5565395A (en) * 1995-05-26 1996-10-15 Albemarle Corporation Aluminoxanate compositions
CN1069100C (zh) * 1995-06-16 2001-08-01 中国石油化工集团公司北京化工研究院 一种复合型固体催化剂与其制法及用途
KR970015606A (ko) * 1995-09-01 1997-04-28 윤덕용 폴리올레핀 중합용 메탈로센 담지촉매의 제조방법
US5670682A (en) * 1995-10-19 1997-09-23 Albemarle Corporation Liquid clathrate aluminoxane compositions
US5922631A (en) * 1995-10-19 1999-07-13 Albemarle Corporation Liquid clathrate aluminoxane compositions as co-catalysts with transition metal catalyst compounds
KR19990087479A (ko) * 1996-03-04 1999-12-27 데니스 피. 산티니 성형 제품
US6930071B2 (en) * 1997-01-28 2005-08-16 Fina Technology, Inc. Ziegler-natta catalyst for polyolefins
US6864207B2 (en) * 1997-01-28 2005-03-08 Fina Technology, Inc. Ziegler-Natta catalyst for polyolefins
US6187882B1 (en) * 1997-02-21 2001-02-13 Council Of Scientific & Industrial Research Process for polymerization of olefins
US5965477A (en) * 1997-02-21 1999-10-12 Council Of Scientific & Industrial Research Process for the preparation of supported metallocene catalyst
US5955554A (en) * 1997-03-27 1999-09-21 Council Of Scientific Industrial Research Process for polymerization and copolymerization of olefins
US5962360A (en) * 1997-03-27 1999-10-05 Council Of Scientific And Industrial Research Process for the preparation of a magnesium halide supported metallocene catalyst
US6645506B1 (en) * 1997-04-18 2003-11-11 Ganeden Biotech, Inc. Topical compositions containing extracellular products of Pseudomonas lindbergii and Emu oil
US6268447B1 (en) 1998-12-18 2001-07-31 Univation Technologies, L.L.C. Olefin polymerization catalyst
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6153551A (en) 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
US7232871B2 (en) * 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US6635715B1 (en) * 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US6921794B2 (en) * 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
WO1999021898A1 (en) * 1997-10-28 1999-05-06 Exxon Chemical Patents Inc. Magnesium halide based metallocene catalyst system
US6551955B1 (en) 1997-12-08 2003-04-22 Albemarle Corporation Particulate group 4 metallocene-aluminoxane catalyst compositions devoid of preformed support, and their preparation and their use
DE69821528T2 (de) 1997-12-08 2004-07-01 Albemarle Corp. Katalysatorzusammensetzungen mit gesteigertem leistungsvermögen
US6677265B1 (en) 1997-12-08 2004-01-13 Albemarle Corporation Process of producing self-supported catalysts
AU2760599A (en) * 1998-02-04 1999-08-23 Friedman, Robert F. Method and apparatus for combining transponders on multiple satellites into virtual channels
US6300271B1 (en) 1998-05-18 2001-10-09 Phillips Petroleum Company Compositions that can produce polymers
US6165929A (en) * 1998-05-18 2000-12-26 Phillips Petroleum Company Compositions that can produce polymers
US6107230A (en) * 1998-05-18 2000-08-22 Phillips Petroleum Company Compositions that can produce polymers
CA2331413C (en) * 1998-05-18 2007-04-17 Phillips Petroleum Company Catalyst composition for polymerizing monomers
DE69935815T2 (de) * 1998-07-01 2007-12-27 Exxonmobil Chemical Patents Inc., Baytown Elastische Mischung mit Kristallpolymeren und kristallisierbaren Polymeren des Propens
US6008394A (en) * 1998-08-07 1999-12-28 Arco Chemicals Technology, L.P. Sulfonyl catalysts and method of using the same
US7767203B2 (en) 1998-08-07 2010-08-03 Ganeden Biotech, Inc. Methods for the dietary management of irritable bowel syndrome and carbohydrate malabsorption
EP1719518A1 (de) 1998-08-07 2006-11-08 Ganeden Biotech, Inc. Zusammensetzung enthaltend Bacillus Coagulans zur Erhöhung der Löslichkeit von Mineralien
US6461607B1 (en) * 1998-08-24 2002-10-08 Ganeden Biotech, Inc. Probiotic, lactic acid-producing bacteria and uses thereof
DE19844167A1 (de) * 1998-09-25 2000-04-06 Ticona Gmbh Aktivkohlefilter
DE19843858A1 (de) * 1998-09-25 2000-04-06 Ticona Gmbh Verfahren zur Herstellung eines Polymers
JP3322643B2 (ja) 1998-10-19 2002-09-09 丸善石油化学株式会社 オレフィン重合用固体触媒およびこれを用いたオレフィン系重合体の製造方法
EP2277928B1 (de) 1998-11-02 2018-02-21 Dow Global Technologies LLC Unter Scherwirkung verflüssigbare Ethylen/alpha-Olefin-Interpolymere und ihre Herstellung
US6303719B1 (en) 1998-12-18 2001-10-16 Univation Technologies Olefin polymerization catalyst system
KR100430979B1 (ko) 1999-02-04 2004-05-12 삼성아토피나주식회사 올레핀 중합용 킬레이트 촉매의 제조방법
US6545108B1 (en) 1999-02-22 2003-04-08 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
CN1347423A (zh) * 1999-02-22 2002-05-01 伊斯曼化学公司 含有n－吡咯基取代的氮给电体的催化剂
US6288181B1 (en) 1999-03-30 2001-09-11 Eastman Chemical Company Process for producing polyolefins
US6313236B1 (en) 1999-03-30 2001-11-06 Eastman Chemical Company Process for producing polyolefins
US6265037B1 (en) 1999-04-16 2001-07-24 Andersen Corporation Polyolefin wood fiber composite
KR100546499B1 (ko) * 1999-05-27 2006-01-26 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
KR100524293B1 (ko) 1999-05-27 2005-10-26 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
US6417299B1 (en) * 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6417301B1 (en) 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6417298B1 (en) * 1999-06-07 2002-07-09 Eastman Chemical Company Process for producing ethylene/olefin interpolymers
US6187879B1 (en) 1999-08-31 2001-02-13 Eastman Chemical Company Process for producing polyolefins
CN101195667A (zh) 1999-08-31 2008-06-11 西湖朗维尤公司 聚烯烃生产方法
US6849256B1 (en) * 1999-11-08 2005-02-01 Ganeden Biotech Incorporated Inhibition of pathogens by probiotic bacteria
US6750302B1 (en) 1999-12-16 2004-06-15 Phillips Petroleum Company Organometal catalyst compositions
DE19962129A1 (de) 1999-12-21 2001-06-28 Targor Gmbh Verfahren zur Herstellung eines Katalysatorfeststoffs zur Olefinpolymerisation
US6605677B2 (en) 2000-02-18 2003-08-12 Eastman Chemical Company Olefin polymerization processes using supported catalysts
US6579823B2 (en) * 2000-02-18 2003-06-17 Eastman Chemical Company Catalysts containing per-ortho aryl substituted aryl or heteroaryl substituted nitrogen donors
US20040127658A1 (en) * 2000-02-18 2004-07-01 Eastman Chemical Company Productivity catalysts and microstructure control
US7056996B2 (en) * 2000-02-18 2006-06-06 E. I. Du Pont De Nemours And Company Productivity catalysts and microstructure control
DE10009247C1 (de) * 2000-02-28 2001-10-18 Schoeller Felix Jun Foto Schichtträger
KR100387734B1 (ko) * 2000-06-17 2003-06-18 삼성종합화학주식회사 올레핀 중합용 촉매 및 중합방법
GC0000293A (en) 2000-10-10 2006-11-01 Saudi Basic Ind Corp Catalyst composition and process for olfin polymerization and copolymerization using supported metallocene catalyst systems
US6706891B2 (en) 2000-11-06 2004-03-16 Eastman Chemical Company Process for the preparation of ligands for olefin polymerization catalysts
KR100389475B1 (ko) * 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합 또는 공중합용 촉매의 제조 방법
KR100389476B1 (ko) * 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체 제조방법
KR100389477B1 (ko) * 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체 제조방법
KR100389962B1 (ko) * 2000-11-10 2003-07-02 삼성종합화학주식회사 에틸렌 중합 또는 공중합용 촉매의 제조 방법
CN1131246C (zh) * 2000-12-14 2003-12-17 中国石油化工股份有限公司 用于烯烃聚合或共聚合的催化剂组份及其催化剂和应用
KR100421551B1 (ko) * 2000-12-16 2004-03-09 삼성아토피나주식회사 올레핀 전중합 촉매 및 이를 이용한 올레핀 중합방법
KR100421552B1 (ko) 2000-12-18 2004-03-09 삼성아토피나주식회사 올레핀 중합용 촉매 및 이를 이용한 중합 방법
EP1362080B1 (de) * 2000-12-22 2005-09-28 Samsung General Chemicals Co., Ltd. Polyolefinharzzusammensetzung
JP3921448B2 (ja) * 2000-12-22 2007-05-30 サムソン ジェネラル ケミカルズ カンパニー リミテッド 難燃性ポリプロピレン樹脂組成物
US6872683B2 (en) * 2000-12-22 2005-03-29 Samsung Atofina Co., Ltd. Method for preparing chelated catalyst for olefin polymerization
DE60020750D1 (de) * 2000-12-22 2005-07-14 Samsung General Chemicals Co Polypropylenharzzusammensetzung mit verbesserter oberflächenhärte und kratzfestigkeit
EP1265933B1 (de) 2000-12-22 2008-08-13 Basell Polyolefine GmbH Katalysatorkomponente fur die polymerisation von olefinen
US6534609B2 (en) * 2001-03-13 2003-03-18 Chevron Phillips Chemical Company Lp Method for making and using a metallocene catalyst system
ATE485319T1 (de) * 2001-04-12 2010-11-15 Exxonmobil Chem Patents Inc Verfahren zur polymerisation von propylen und ethylen in lösung
DE60221834T2 (de) 2001-06-13 2008-06-26 Beta Technologie Ag Massenpolymerisation-reaktoren und verfahren zur polymerisation
KR100530794B1 (ko) * 2001-06-21 2005-11-23 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
US6927256B2 (en) 2001-11-06 2005-08-09 Dow Global Technologies Inc. Crystallization of polypropylene using a semi-crystalline, branched or coupled nucleating agent
EP1444276A1 (de) 2001-11-06 2004-08-11 Dow Global Technologies, Inc. Isotaktische propylencopolymere, ihre herstellung und ihre verwendung
US7459500B2 (en) * 2002-11-05 2008-12-02 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US7579407B2 (en) * 2002-11-05 2009-08-25 Dow Global Technologies Inc. Thermoplastic elastomer compositions
US6992034B2 (en) * 2003-07-10 2006-01-31 Formosa Plastics Corporation, U.S.A. Catalyst component for olefin polymerization
US7155295B2 (en) * 2003-11-07 2006-12-26 Paracor Medical, Inc. Cardiac harness for treating congestive heart failure and for defibrillating and/or pacing/sensing
US7399895B2 (en) * 2004-03-16 2008-07-15 Union Carbide Chemicals & Plastics Aluminum phosphate-supported group 6 metal amide catalysts for oligomerization of ethylene
AR048273A1 (es) 2004-03-17 2006-04-12 Dow Global Technologies Inc Composicion catalizadora que comprende un agente de enlace para la formacion de copolimeros de etileno
CA2557870A1 (en) 2004-03-17 2005-09-29 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for higher olefin multi-block copolymer formation
RU2381240C2 (ru) 2004-03-17 2010-02-10 Дау Глобал Текнолоджиз Инк. Состав катализатора, содержащий челночный агент, для формирования мульти-блок-сополимера этилена
US20080051537A1 (en) * 2004-08-09 2008-02-28 Carnahan Edmund M Supported Bis(Hydroxylarylaryloxy) Catalysts For Manufacture Of Polymers
EP1693388A1 (de) * 2005-02-21 2006-08-23 Innovene Europe Limited Polymerisationskatalysatoren
AU2006227977A1 (en) 2005-03-17 2006-09-28 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
US9410009B2 (en) 2005-03-17 2016-08-09 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation
CN101142245B (zh) * 2005-03-17 2012-08-08 陶氏环球技术有限责任公司 用于形成立体无规多嵌段共聚物的包含梭移剂的催化剂组合物
WO2006120916A1 (ja) * 2005-05-12 2006-11-16 Japan Polypropylene Corporation オレフィン重合用触媒、オレフィン重合用触媒の製造方法、及びその保存方法
WO2007035492A1 (en) * 2005-09-15 2007-03-29 Dow Global Technologies Inc. Catalytic olefin block copolymers via polymerizable shuttling agent
EP2392601B1 (de) * 2005-09-15 2015-10-28 Dow Global Technologies LLC Steuerung der polymerarchitektur und der molekulargewichtsverteilung mittels reversiblem multifunktionalem kettenübertragungsreagenz
CN102786619B (zh) * 2006-05-17 2015-01-07 陶氏环球技术有限责任公司 乙烯/α-烯烃/二烯溶液聚合法
HUE045998T2 (hu) 2007-08-29 2020-01-28 Ganeden Biotech Inc Sütött termékek
ES2700855T3 (es) * 2007-10-16 2019-02-19 Ganeden Biotech Inc Composiciones bebibles
US8003741B2 (en) 2008-02-07 2011-08-23 Fina Technology, Inc. Ziegler-Natta catalyst
US7788209B2 (en) * 2008-05-05 2010-08-31 United Technologies Corporation Hybrid fault reasoning and guided troubleshooting system that uses case-based reasoning and model-based reasoning
US9622502B2 (en) 2008-10-16 2017-04-18 Ganeden Biotech, Inc. Probiotic Bacillus pasta compositions
CA2760325A1 (en) 2009-04-29 2010-11-04 Ganeden Biotech, Inc. Dead bacillus coagulans bacteria and uses thereof for boosting the immune system
ES2651292T3 (es) 2009-07-29 2018-01-25 Dow Global Technologies Llc Agentes de transferencia de cadena de doble o múltiple cabeza y su uso para la preparación de copolímeros de bloque
PT2464675T (pt) 2009-11-10 2016-11-16 Total Res & Technology Feluy Utilização de um polietileno bimodal para aplicações de moldagem por injeção e sopro com estiramento
MX2012008436A (es) 2010-02-05 2012-12-10 Total Petrochemicals Res Feluy Proceso para preparar poliolefina.
EP2681275B1 (de) 2011-03-04 2017-05-17 Total Research & Technology Feluy Verfahren zur herstellung von polyethylenmischungen mit ziegler-natta
PL2681274T3 (pl) 2011-03-04 2018-03-30 Total Research & Technology Feluy Sposób wytwarzania mieszanek poliolefinowych w urządzeniu do ciągłego mechanicznego stapiania i mieszania mieszanek
US11235008B2 (en) 2011-03-31 2022-02-01 Ganeden Biotech, Inc. Probiotic sports nutrition compositions
MX356959B (es) 2011-05-20 2018-06-21 The Us Secretary Department Of Health & Human Services Cepa paenibacillus alvei ts-15 y su uso en el control de organismos patogenicos.
EA024389B1 (ru) 2011-09-30 2016-09-30 Тотал Ресерч & Технолоджи Фелай Полиэтилен высокой плотности для средств укупорки
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US9670342B2 (en) 2013-08-12 2017-06-06 Total Research & Technology Feluy Polyethylene for injection stretch blow molding applications
WO2016005265A1 (en) 2014-07-10 2016-01-14 Total Research & Technology Feluy Process for producing high density polyethylene composition having high environmental stress crack resistance from post consumer plastic and articles made of said composition
CA2874344C (en) 2014-12-15 2021-08-31 Nova Chemicals Corporation Spheroidal catalyst for olefin polymerization
CA2890606C (en) 2015-05-07 2022-07-19 Nova Chemicals Corporation Process for polymerization using dense and spherical ziegler-natta type catalyst
JP6832348B2 (ja) 2015-09-30 2021-02-24 ダウ グローバル テクノロジーズ エルエルシー 連鎖シャトリングに有用な多頭性または二頭性組成物、及びそれを調製するためのプロセス
BR112019006150B1 (pt) 2016-09-30 2023-02-28 Dow Global Technologies Llc Composição e processo para preparar a composição
EP3519455B1 (de) 2016-09-30 2024-04-10 Dow Global Technologies Llc Mehr- oder doppelköpfige zusammensetzungen für kettenübertragung und verfahren zur herstellung davon
KR102464765B1 (ko) 2016-09-30 2022-11-09 다우 글로벌 테크놀로지스 엘엘씨 사슬 이동에 유용한 다중 또는 이중 헤드 조성물의 제조 방법
CN115260366B (zh) 2017-03-15 2025-01-28 陶氏环球技术有限责任公司 用于形成多嵌段共聚物的催化剂体系
KR102711048B1 (ko) 2017-03-15 2024-09-27 다우 글로벌 테크놀로지스 엘엘씨 다중-블록 공중합체 형성을 위한 촉매 시스템
SG11201908307XA (en) 2017-03-15 2019-10-30 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation
ES2946762T3 (es) 2017-03-15 2023-07-25 Dow Global Technologies Llc Sistema de catalizador para la formación de copolímero multibloque
WO2018170056A1 (en) 2017-03-15 2018-09-20 Dow Global Technologies Llc Catalyst system for multi-block copolymer formation

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1348655A (en) * 1970-05-22 1974-03-20 Montedison Spa Catalysts for the polymerization of olefins
US4295991A (en) * 1978-09-26 1981-10-20 Exxon Research & Engineering Co. Titanium trichloride catalyst component and the process for the production thereof
EP0099774B2 (de) * 1982-06-24 1995-03-22 BP Chimie Société Anonyme Verfahren zur Polymerisation und Copolymerisation von Alphaolefinen in einem Fliessbett
FR2529207A1 (fr) * 1982-06-24 1983-12-30 Bp Chimie Sa Procede pour la preparation de supports de catalyseurs pour la polymerisation des alpha-olefines et supports obtenus
FR2541683B1 (fr) * 1983-02-28 1986-05-09 Ato Chimie Procede pour la preparation d'un solide hydrocarbone actif utilisable pour polymeriser des olefines, et procede de synthese d'un polymere ou copolymere olefinique faisant appel audit solide hydrocarbone actif comme systeme
US4588703A (en) * 1984-07-18 1986-05-13 Phillips Petroleum Company Polyolefin polymerization process and catalyst
US4897455A (en) * 1985-06-21 1990-01-30 Exxon Chemical Patents Inc. Polymerization process
US4659685A (en) * 1986-03-17 1987-04-21 The Dow Chemical Company Heterogeneous organometallic catalysts containing a supported titanium compound and at least one other supported organometallic compound
US4814314A (en) * 1986-09-26 1989-03-21 Mitsubishi Petrochemical Company Limited Catalyst for olefin polymerization
JPS63168408A (ja) * 1986-12-29 1988-07-12 Showa Denko Kk ポリオレフインの製造方法
JPH07110885B2 (ja) * 1987-06-30 1995-11-29 三井石油化学工業株式会社 オレフインの重合方法
US5026797A (en) * 1987-10-22 1991-06-25 Mitsubishi Petrochemical Co., Ltd. Process for producing ethylene copolymers
FR2628110B1 (fr) * 1988-03-03 1994-03-25 Bp Chimie Catalyseur de polymerisation d'olefines de type ziegler-natta, supporte sur des particules spheriques de chlorure de magnesium, et procede de preparation

Also Published As

Publication number Publication date
EP0436326A1 (de) 1991-07-10
US5106804A (en) 1992-04-21
DE69028509D1 (de) 1996-10-17
HU908438D0 (en) 1991-07-29
NO905439L (no) 1991-06-24
US5439995A (en) 1995-08-08
NO176571B (no) 1995-01-16
PT96343A (pt) 1991-09-30
EP0436326B1 (de) 1996-09-11
KR910011913A (ko) 1991-08-07
SG44346A1 (en) 1997-12-19
HU208981B (en) 1994-02-28
CA2032619A1 (en) 1991-06-23
NO905439D0 (no) 1990-12-17
DE69028509T2 (de) 1997-02-06
JPH04211404A (ja) 1992-08-03
ES2091229T3 (es) 1996-11-01
MY105298A (en) 1994-09-30
FR2656314B1 (fr) 1992-04-17
FI906298L (fi) 1991-06-23
HUT59698A (en) 1992-06-29
NO176571C (no) 1995-04-26
FI906298A0 (fi) 1990-12-20
CN1053433A (zh) 1991-07-31
FR2656314A1 (fr) 1991-06-28
PL288414A1 (en) 1992-02-24
ZA9010048B (en) 1992-08-26
AU6817390A (en) 1991-06-27
AU646004B2 (en) 1994-02-03
PT96343B (pt) 1998-06-30

Similar Documents

Publication Publication Date Title
ATE142651T1 (de) Katalysator und prepolymer für herstellung von polyolefinen
ATE142655T1 (de) Katalysator und prepolymer für polyolefinherstellung
PL289377A1 (en) Solid catalyst for olefin polymerization, method of its synthesis, prepolymer and method of its synthesis, method of ethylene polymerization, and the polymer or copolymer powder
ZA911294B (en) Catalyst and prepolymer used for polymerising olefins,and (co-)polymer of ethylene obtainable therefrom
FI904255A0 (fi) Foerfarande foer framstaellning av elastomera profenkopolymerer i gasfas.
JPS646005A (en) Solid catalyst component for olefin polymerization
JPS646003A (en) Polymerization of olefin

Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification
REN Ceased due to non-payment of the annual fee